CN104793355B - A kind of electric-controlled intelligent minute surface dims substrate assemblies - Google Patents
A kind of electric-controlled intelligent minute surface dims substrate assemblies Download PDFInfo
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- CN104793355B CN104793355B CN201510229735.6A CN201510229735A CN104793355B CN 104793355 B CN104793355 B CN 104793355B CN 201510229735 A CN201510229735 A CN 201510229735A CN 104793355 B CN104793355 B CN 104793355B
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- Prior art keywords
- electric
- minute surface
- dims
- controlled intelligent
- substrate assemblies
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/0102—Constructional details, not otherwise provided for in this subclass
Abstract
Substrate assemblies are dimmed the present invention relates to a kind of electric-controlled intelligent minute surface, its two pieces of substrate including parallel and corresponding setting, the high polymer composite coating being formed between two pieces of substrates, the face that two pieces of substrates are in contact with the polymeric coating layer is conducting surface, and the high polymer composite coating includes poly ion liquid and silver nitrate.By using the high polymer composite coating for including poly ion liquid and silver nitrate, when conducting surface is powered can by silver ion reduction into silver and form minute surface, so as to change the translucency of glass assembly, it is possible to used as mirror to consumer;On the other hand when conducting surface is non-conductive, silver can be acted on poly ion liquid and by silver oxidation, restPosed.
Description
Technical field
The invention belongs to ambetti field, it is related to a kind of substrate assemblies, and in particular to a kind of electric-controlled intelligent minute surface light modulation
Substrate assemblies.
Background technology
Glass is the conventional ornament materials of Discussion on architecture, from glass curtain wall, window, automobile and public transport, shower/sunlight
Room, showcase and show window etc..In many cases, people realize the mesh of heat-insulated, attractive in appearance secrecy usually using the mode of curtain is installed
, and installing curtain not only increases investment, and take the interior space, it is necessary to often cleaning and replacing, and switch curtain ten
Divide inconvenience, therefore people extremely wish a kind of glass of energy auto-changing light transmittance.This glass under normal circumstances with it is general
Logical glass is identical, that in the case of certain condition (as being powered) light transmittance can be changed, plays a part of curtain.
The Chinese utility model patent of Patent No. 200420079163.5 discloses a kind of intelligent dimming glass, the glass
Light modulation layer is acted on using liquid crystal material layer, so as to realize the control to glass transmission rate in the presence of electric current.Although the intelligence
Dimming glass has a variety of advantages, but its liquid crystal material for selecting be it is poisonous, that sealing to it require it is higher, because
And the difficulty of its manufacture craft is improved to a certain extent.
The content of the invention
A kind of electric-controlled intelligent minute surface light modulation substrate assemblies are provided the invention aims to overcome the deficiencies in the prior art.
To reach above-mentioned purpose, the technical solution adopted by the present invention is:A kind of electric-controlled intelligent minute surface dims substrate assemblies, it
Two pieces of substrates including parallel and corresponding setting, the high polymer composite coating being formed between two pieces of substrates, described in two pieces
The face that substrate is in contact with the polymeric coating layer is conducting surface, and the high polymer composite coating includes poly ion liquid and nitric acid
Silver.
Optimally, it also include respectively with electrode slice that the conducting surface is in contact and the corresponding company with the electrode slice
The switch connect.
Optimally, it also includes the glass being bonded in by glue layer on the outer surface of substrate.
Optimally, the high polymer composite coating includes the composition of following parts by weight:
10~50 parts of poly ion liquid;
1~5 part of silver nitrate.
Further, the high polymer composite coating also includes 0.1~1 part of copper chloride.
Further, the high polymer composite coating (3) also includes 20~50 parts of dimethyl sulfoxide (DMSO)s.
Further, the high polymer composite coating (3) also includes 20~50 parts of ions for preparing the poly ion liquid
Liquid monomer.
Further, the ionic liquid monomer is M=0~15, n=1~6, p=1~4, X is Cl, Br or I in formula.
Because above-mentioned technical proposal is used, the present invention has following advantages compared with prior art:Electric-controlled intelligent of the present invention
Minute surface dims substrate assemblies, by using the high polymer composite coating for including poly ion liquid and silver nitrate, is powered in conducting surface
When silver ion reduction into silver can be formed minute surface, so as to change the translucency of glass assembly, it is possible to as mirror to being disappeared
Expense person uses;On the other hand when conducting surface is non-conductive, silver can act on poly ion liquid and by silver oxidation, recover initial shape
State.
Brief description of the drawings
Accompanying drawing 1 is the structural representation that electric-controlled intelligent minute surface of the present invention dims substrate assemblies;
Wherein, 1, substrate;2nd, substrate;3rd, high polymer composite coating;4th, glass;5th, glass;6th, glue layer;7th, electrode slice;
8th, switch;9th, electrode slice;10th, switch.
Embodiment
The preferred embodiment of the invention is described in detail below in conjunction with accompanying drawing:
Electric-controlled intelligent minute surface light modulation substrate assemblies as shown in Figure 1, it is compound that it mainly includes substrate 1, substrate 2 and macromolecule
Coating 3.
Wherein, substrate 1 and substrate 2 are parallel to each other and are correspondingly arranged, and define their opposite one sides for inner surface, support or oppose
It is simultaneously outer surface, then the inner surface of substrate 1 and substrate 2 is conducting surface;Substrate 1 and substrate 2 can be electro-conductive glass, can also
It is flexible conductive film material or Traditional flexible or non-flexible material other transparent and with conducting surface.Macromolecule is combined
Coating 3 is formed between substrate 1 and substrate 2, i.e., it is in contact with the inner surface of substrate 1, substrate 2;The high polymer composite coating 3
Comprising poly ion liquid and silver nitrate, so when conducting surface is powered can by silver ion reduction into silver and form minute surface so that
Change the translucency of glass assembly, it is possible to used to consumer as mirror;On the other hand when conducting surface is non-conductive, silver-colored energy
Enough and poly ion liquid is acted on and by silver oxidation, restPosed.
In the present embodiment, electric-controlled intelligent minute surface light modulation substrate assemblies also include the electricity being in contact with the conducting surface of substrate 1
Pole piece 7, the electrode slice 9 being in contact with the conducting surface of substrate 2, and be connected respectively with electrode slice 7, electrode slice 9 switch 8,
Switch 10.Electrode slice 7 and electrode slice 9 are arranged on substrate 1, the marginal portion of the conducting surface of substrate 2, L-shaped.Switch 8, switch 10 can
Think regular tap, it is dimmer switch, light-operated switch, light-operated dimmer switch, audio-switch, remote control switch, remote-control light-modulating switch, remote
Infrared switch, the switch based on NFC technique, switch based on wireless transmission technique etc., and then realize the control in the present embodiment
Function, the long-range network control switch that can also be controlled with remote control, computer, the long-range network control of mobile phone development of Mobile Internet technology control
Switch is designed to all kinds of controlling switches as needed.
In the present embodiment, electric-controlled intelligent minute surface light modulation substrate assemblies also include being bonded in the appearance of substrate 1 by glue layer 6
Glass 4 on face and the glass 5 on the outer surface of substrate 2 is bonded in by glue layer 6, glue layer 6 is transparent, can be that light is consolidated
Change glue, heat-curable glue etc..
In the present embodiment, high polymer composite coating 3 includes the composition of following parts by weight:Poly ion liquid 10~50
Part;1~5 part of silver nitrate.In order to stablize silver mirror, high polymer composite coating 3 also includes 0.1~1 part of copper chloride.In order to improve high score
The circulation of sub- composite coating, so as to reduce the difficulty of its coating process, high polymer composite coating 3 also includes 20~50 parts of diformazans
Base sulfoxide or/and 20~50 parts prepare the ionic liquid monomer of above-mentioned poly ion liquid, advantageously reduce influence of the oxygen to it,
Service life is improved, these ionic liquid monomers are preferably M=0~15, n=1~6, p=1~4, X is Cl, Br or I in formula.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention, all according to the present invention
The equivalent change or modification that Spirit Essence is made, should all be included within the scope of the present invention.
Claims (8)
1. a kind of electric-controlled intelligent minute surface dims substrate assemblies, it includes two pieces of substrates (1,2) of parallel and corresponding setting, formed
High polymer composite coating (3) between two pieces of substrates (1,2), two pieces of substrates (1,2) and the compound painting of the macromolecule
The face that layer (3) is in contact is conducting surface, it is characterised in that the high polymer composite coating (3) includes poly ion liquid and nitric acid
Silver.
2. electric-controlled intelligent minute surface according to claim 1 dims substrate assemblies, it is characterised in that:It also include respectively with institute
State electrode slice (7,9) that conducting surface is in contact and the switch (8,10) with the electrode slice (7,9) corresponding connection.
3. electric-controlled intelligent minute surface according to claim 1 or 2 dims substrate assemblies, it is characterised in that:It also includes passing through
Glue layer (6) is bonded in the glass (4,5) on the substrate (1,2) outer surface.
4. electric-controlled intelligent minute surface according to claim 1 dims substrate assemblies, it is characterised in that the macromolecule is compound to be applied
Layer (3) includes the composition of following parts by weight:
10~50 parts of poly ion liquid;
1~5 part of silver nitrate.
5. electric-controlled intelligent minute surface according to claim 4 dims substrate assemblies, it is characterised in that:The macromolecule is compound to be applied
Layer (3) also includes 0.1~1 part of copper chloride.
6. the electric-controlled intelligent minute surface light modulation substrate assemblies according to claim 4 or 5, it is characterised in that:The macromolecule is answered
Closing coating (3) also includes 20~50 parts of dimethyl sulfoxide (DMSO)s.
7. electric-controlled intelligent minute surface according to claim 1 dims substrate assemblies, it is characterised in that:The macromolecule is compound to be applied
Layer (3) also includes 20~50 parts of ionic liquid monomers for preparing the poly ion liquid.
8. electric-controlled intelligent minute surface according to claim 7 dims substrate assemblies, it is characterised in that:The ionic liquid monomer is M=0~15, n=1~6, p=in formula
1~4, X are Cl, Br or I.
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CN108711366B (en) * | 2018-05-22 | 2020-06-02 | 六安市匠心信息科技有限公司 | Advertisement playing device |
CN109031835A (en) * | 2018-08-06 | 2018-12-18 | 康曦 | A kind of electric-controlled intelligent light modulation device liquid-crystal composition and its application |
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CN104317129A (en) * | 2014-10-28 | 2015-01-28 | 电子科技大学 | High-throughput screening electrochromic device for electrochromic materials and method for manufacturing high-throughput screening electrochromic device |
CN104614913A (en) * | 2015-03-05 | 2015-05-13 | 哈尔滨工业大学 | Method for preparing flexible adhesive electrochromic device capable of being switched between mirror state and transparent state |
CN104788022A (en) * | 2015-03-31 | 2015-07-22 | 哈尔滨工业大学 | Preparation method and application of flaky nano-silver electrochromic film |
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US6798556B2 (en) * | 2003-01-31 | 2004-09-28 | Rockwell Scientific Licensing, Llc. | Locally-switched reversible electrodeposition optical modulator |
US20050248825A1 (en) * | 2004-05-04 | 2005-11-10 | Rockwell Scientific Licensing, Llc | Reversible electrodeposition optical modulation device with conducting polymer counter electrode |
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CN104317129A (en) * | 2014-10-28 | 2015-01-28 | 电子科技大学 | High-throughput screening electrochromic device for electrochromic materials and method for manufacturing high-throughput screening electrochromic device |
CN104614913A (en) * | 2015-03-05 | 2015-05-13 | 哈尔滨工业大学 | Method for preparing flexible adhesive electrochromic device capable of being switched between mirror state and transparent state |
CN104788022A (en) * | 2015-03-31 | 2015-07-22 | 哈尔滨工业大学 | Preparation method and application of flaky nano-silver electrochromic film |
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Effective date of registration: 20170928 Address after: 244002 No. 695, north section of Taishan Avenue, Tongling Economic Development Zone, Anhui Patentee after: Anhui Mcgee Mstar Technology Ltd Address before: 215121 city garden, Suzhou Industrial Park, Jiangsu 34-804, China Patentee before: Yan Feng |