CN104649865A - (r)-苯基乙二醇的一种绿色不对称合成方法 - Google Patents
(r)-苯基乙二醇的一种绿色不对称合成方法 Download PDFInfo
- Publication number
- CN104649865A CN104649865A CN201510080782.9A CN201510080782A CN104649865A CN 104649865 A CN104649865 A CN 104649865A CN 201510080782 A CN201510080782 A CN 201510080782A CN 104649865 A CN104649865 A CN 104649865A
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- Prior art keywords
- phenylglycol
- quality
- asymmetric synthesis
- catalyzer
- vinylbenzene
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
- C07C29/05—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510080782.9A CN104649865B (zh) | 2015-02-13 | 2015-02-13 | (r)-苯基乙二醇的一种绿色不对称合成方法 |
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CN201510080782.9A CN104649865B (zh) | 2015-02-13 | 2015-02-13 | (r)-苯基乙二醇的一种绿色不对称合成方法 |
Publications (2)
Publication Number | Publication Date |
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CN104649865A true CN104649865A (zh) | 2015-05-27 |
CN104649865B CN104649865B (zh) | 2016-05-11 |
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CN201510080782.9A Expired - Fee Related CN104649865B (zh) | 2015-02-13 | 2015-02-13 | (r)-苯基乙二醇的一种绿色不对称合成方法 |
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CN (1) | CN104649865B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109225330A (zh) * | 2018-06-26 | 2019-01-18 | 中北大学 | 一种高负载高稳定性的手性多孔磷钨酸催化剂及制备 |
CN109825534A (zh) * | 2019-01-22 | 2019-05-31 | 江苏理工学院 | 一种超临界co2/缓冲溶液双相体系酶法制备(r)-1-苯基-1,2-乙二醇的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101073783A (zh) * | 2007-06-25 | 2007-11-21 | 陕西师范大学 | 用于烯烃二羟基化反应的固载离子液体催化剂及其制备和用法 |
CN102329823A (zh) * | 2011-10-13 | 2012-01-25 | 华南理工大学 | 一种制备(r)-苯基乙二醇的方法 |
CN103819426A (zh) * | 2013-11-06 | 2014-05-28 | 辽宁石油化工大学 | 一种钼多金属氧酸盐催化烯烃环氧化方法 |
-
2015
- 2015-02-13 CN CN201510080782.9A patent/CN104649865B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101073783A (zh) * | 2007-06-25 | 2007-11-21 | 陕西师范大学 | 用于烯烃二羟基化反应的固载离子液体催化剂及其制备和用法 |
CN102329823A (zh) * | 2011-10-13 | 2012-01-25 | 华南理工大学 | 一种制备(r)-苯基乙二醇的方法 |
CN103819426A (zh) * | 2013-11-06 | 2014-05-28 | 辽宁石油化工大学 | 一种钼多金属氧酸盐催化烯烃环氧化方法 |
Non-Patent Citations (2)
Title |
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XIAN-YING SHI ET AL.: "Peroxophosphotungstate held in an ionic liquid brush: an efficient and reusable catalyst for the dihydroxylation of olefins with H2O2 in neat water", 《APPL. ORGANOMETAL. CHEM.》, vol. 28, 11 August 2014 (2014-08-11), pages 760 - 763 * |
YUNXIANG QIAO ET AL.: "Polyoxometalate-based protic alkylimidazolium salts as reaction-induced phase-separation catalysts for olefin epoxidation", 《GREEN CHEM.》, vol. 11, 14 September 2009 (2009-09-14), pages 1955 - 1960 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109225330A (zh) * | 2018-06-26 | 2019-01-18 | 中北大学 | 一种高负载高稳定性的手性多孔磷钨酸催化剂及制备 |
CN109225330B (zh) * | 2018-06-26 | 2021-03-09 | 中北大学 | 一种高负载高稳定性的手性多孔磷钨酸催化剂及制备 |
CN109825534A (zh) * | 2019-01-22 | 2019-05-31 | 江苏理工学院 | 一种超临界co2/缓冲溶液双相体系酶法制备(r)-1-苯基-1,2-乙二醇的方法 |
CN109825534B (zh) * | 2019-01-22 | 2022-03-25 | 江苏理工学院 | 一种超临界co2/缓冲溶液双相体系酶法制备(r)-1-苯基-1,2-乙二醇的方法 |
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CN104649865B (zh) | 2016-05-11 |
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Inventor after: Liang Dong Inventor after: Zhu Hailin Inventor after: Hu Zhiyong Inventor after: Guo Jianfeng Inventor after: Ma Xuemei Inventor after: Cao Duanlin Inventor before: Liang Dong Inventor before: Hu Zhiyong Inventor before: Zhu Hailin Inventor before: Guo Jianfeng Inventor before: Ma Xuemei Inventor before: Cao Duanlin |
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