CN104531076A - Wet-type water-retaining property dustfall agent - Google Patents
Wet-type water-retaining property dustfall agent Download PDFInfo
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- CN104531076A CN104531076A CN201510019262.7A CN201510019262A CN104531076A CN 104531076 A CN104531076 A CN 104531076A CN 201510019262 A CN201510019262 A CN 201510019262A CN 104531076 A CN104531076 A CN 104531076A
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Abstract
The invention provides a wet-type water-retaining property dustfall agent. The wet-type water-retaining property dustfall agent comprises, by weight, 0.2%-0.15% of starch grafting acrylate, 0.5%-2% of lauramidopropyl betaine, 0.01%-0.1% of cetyl trimethyl ammonium bromide, 0.2%-0.6% of sodium dodecyl sulfate, 0.3%-0.8% of sodium dodecyl benzene sulfonate, 0.1%-0.3% of sodium dodecyl sulfate, 0.4%-1.3% of sodium N-oleoyl-N-methyltaurinate, 0.02%-0.3% of dodecyl dimethyl betaine, 0.2%-0.6% of cocoanut fatty acid diethanolamide, 0.1%-1% of sooctyl alcohol sodium sulfate and the balance water. The wet-type water-retaining property dustfall agent is compressed by a hydraulic device and then forms mist spray to be sprayed to dust production points by nozzles, foam collides with dust particles in the air after being sprayed out, hence, high-concentration dust can be caught and settled, the surface tension of the water can be effectively lowered, the water spray can better wrap the dust, the high wetting water-retaining property is achieved, the dust concentration on an excavation working face can be effectively lowered, and the dust on the working face can be restrained for a long time.
Description
Technical field
The present invention relates to dust removing down-hole of coal mine additive, particularly relate to a kind of wet type water-retentivity dustfall agent.
Background technology
Along with the raising of mechanization production level in mining production process, the dust-producing amount of down-hole mining working face also increases thereupon fast.Survey factually, under the condition not taking any dust prevention, the dust concentration of fully mechanized workface can reach 2000mg/m
3-3000mg/m
3, the dust concentration of fully-mechanized mining working can reach 2500mg/m
3-3000mg/m
3, and fully mechanized coal face owing to moving frame, putting the operations such as coal all can volume production dirt greatly, the instantaneous original total dust concentration in some colliery is even up to 8000mg/m
3-10000mg/m
3.High concentrate dust the serious threat safety in production of mine and the healthy of worker.
In order to reduce the high concentrate dust of getting working face severe overweight, at present, the dedusting method extensively adopted both at home and abroad mainly contains dust removal by ventilation, coal-bed flooding, atomizing de-dusting, chemical dust suppression etc.Among numerous dust control technology means, wet spray depositing dust mode is most widely used, but simple water spray can only control the disperse of dust to a certain extent, and dust removing effects is poor.Also occurred more dustfall agent in prior art, but its wettability is poor, evaporation is very fast, easily makes dust again kick up, and forms secondary pollution.
Therefore, prior art needs further improvement and develops.
Summary of the invention
The present invention provides a kind of wet type water-retentivity dustfall agent for the defect in solving the problems of the technologies described above, and after parcel dust, can keep moistening for a long time, to extend the action time of dustfall agent.
For solving the problems of the technologies described above, the present invention program comprises:
A kind of wet type water-retentivity dustfall agent, wherein, it comprises following component according to weight percent:
It effectively can reduce the surface tension of water, enables water spray better wrap up dust, has high wetting water-retentivity, can effectively reduce getting working face dust concentration, suppress for a long time to working face dust.And starch grafted acrylate and cetyl trimethylammonium bromide are water-holding agent, in starch grafted acrylate, starch and acrylate are prepared according to the ratio of 1:4 ~ 1:7, starch grafted acrylate is condensed by high-efficiency water-absorbing performance, and has long-term water-retentivity.Cetyl trimethylammonium bromide water soluble, produces a large amount of foam during concussion, can have good coordinating with positively charged ion, nonionic, amphoterics.The liquid that interpolation water-holding agent is finally formed has high stability, high-moisture-retention.
Described wet type water-retentivity dustfall agent, wherein, it comprises following component according to weight percent:
Described wet type water-retentivity dustfall agent, wherein, it comprises following component according to weight percent:
Described wet type water-retentivity dustfall agent, wherein, it comprises following component according to weight percent:
Described wet type water-retentivity dustfall agent, wherein, it comprises following component according to weight percent:
Described wet type water-retentivity dustfall agent, wherein, it comprises following component according to weight percent:
The invention provides a kind of wet type water-retentivity dustfall agent, described wet type water-retentivity dustfall agent is sprayed to product dirt pits via forming spraying by shower nozzle after hydraulic efficiency plant pressurization, after foam ejection, collide with the grit in air, thus catch and sedimentation high concentrate dust, sodium lauryl sulphate belongs to anion surfactant, soluble in water, and compatibleness is good again with negatively charged ion, nonionic, has good emulsifying, foaming and dispersing property, cetyl trimethylammonium bromide is a kind of cats product, there is stronger water-absorbent, energy and positively charged ion, nonionic, amphoterics has good coordinating, therefore spraying is made to have good water retention property, dust can be suppressed for a long time, and the dust after preventing sedimentation dissociates in air again, this wet type water-retentivity dustfall agent is added in spraying water according to a certain percentage, when carrying out atomizing de-dusting operation, its dust reduction rate can reach more than 96%, and this propellant has good biological degradability, after parcel dust, the action time of dustfall agent can be extended, can keep moistening for a long time, prevent dust from kicking up once again, catch the dust near ground simultaneously, finally achieve effective sedimentation of high concentrate dust.
Embodiment
The invention provides a kind of wet type water-retentivity dustfall agent, for making object of the present invention, technical scheme and effect clearly, clearly, the present invention is described in more detail below.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
The invention provides a kind of wet type water-retentivity dustfall agent, it comprises following component according to weight percent: the starch grafted acrylate of 0.02%-0.15%, the lauroylamidopropyl betaine of 0.5%-2%, the cetyl trimethylammonium bromide of 0.01%-0.1%, the sodium lauryl sulphate of 0.2%-0.6%, the Sodium dodecylbenzene sulfonate of 0.3%-0.8%, the sodium laurylsulfonate of 0.1%-0.3%, the oleoyl methylamine ethyl sulfonic acid sodium of 0.4%-1.3%, the Varion CDG-K of 0.02%-0.3%, the coconut oil diethanol amide of 0.2%-0.6%, the isooctyl alcohol sodium sulfate of 0.1%-1%, then surplus is water.
And above-mentioned wetting agent is the sodium lauryl sulphate of 0.2%-0.6% and the Sodium dodecylbenzene sulfonate of 0.3%-0.8%.Compared with existing dustfall agent, wet type water-retentivity dustfall agent of the present invention has not only had obvious rising at the instant dust-laying effect of spraying, and water retention property makes that spraying liquid dehydration is slow, water suction is fast, have the ability of long-time bonding dust, the sustainable 8-10 of water retention property hour.After the dustfall agent adding this water-holding agent carries out spray for dust suppression work, can be bondd dust for a long time, dust is avoided again to kick up with distinguished and admirable because ground is dry, reduce reentrainment of dust rate, long-term parcel dust source, control dust-producing amount, fundamentally improve the operating environment of getting working face, ensure mine safety High-efficient Production
Individual in another preferred embodiment of the present invention, it comprises the starch grafted acrylate of 0.05%-0.1% according to weight percent, the lauroylamidopropyl betaine of 0.8%-1.5%, the cetyl trimethylammonium bromide of 0.05%-0.08%, the sodium lauryl sulphate of 0.3%-0.5%, the Sodium dodecylbenzene sulfonate of 0.4%-0.7%, the sodium laurylsulfonate of 0.15%-0.25%, the oleoyl methylamine ethyl sulfonic acid sodium of 0.5%-1.0%, the Varion CDG-K of 0.05%-0.2%, the coconut oil diethanol amide of 0.3%-0.5%, the isooctyl alcohol sodium sulfate of 0.2%-0.8%, then surplus is water.Or it comprises the starch grafted acrylate of 0.06%-0.08% according to weight percent, the lauroylamidopropyl betaine of 1.0%-1.2%, the cetyl trimethylammonium bromide of 0.06%-0.08%, the sodium lauryl sulphate of 0.35%-0.45%, the Sodium dodecylbenzene sulfonate of 0.45%-0.6%, the sodium laurylsulfonate of 0.18%-0.2%, the oleoyl methylamine ethyl sulfonic acid sodium of 0.6%-0.8%, the Varion CDG-K of 0.1%-0.15%, the coconut oil diethanol amide of 0.35%-0.4%, the isooctyl alcohol sodium sulfate of 0.4%-0.6%, then surplus is water.
In order to more detailed description technical solution of the present invention, below enumerate more detailed embodiment and be described.
Embodiment 1
Take respectively according to following quality standard: the oleoyl methylamine ethyl sulfonic acid sodium of the Sodium dodecylbenzene sulfonate of the cetyl trimethylammonium bromide of the starch grafted acrylate of 0.02g, the lauroylamidopropyl betaine of 0.5g, 0.01g, the sodium lauryl sulphate of 0.2g, 0.3g, the sodium laurylsulfonate of 0.1g, 0.4g, the Varion CDG-K of 0.02g, the coconut oil diethanol amide of 0.2g, the isooctyl alcohol sodium sulfate of 0.1g.Add in the clear water of 98.15kg by above formula material, fully after mixing, preparation forms the wet type water-retentivity dustfall agent of 100kg.This wet type water-retentivity dustfall agent is applied in the middle of spray for dust suppression, homogeneous, and stability is better.
Wherein, in this formula, various raw material percentage is respectively: the starch grafted acrylate of 0.02%, the lauroylamidopropyl betaine of 0.5%, 0.01% cetyl trimethylammonium bromide, the sodium lauryl sulphate of 0.2%, Sodium dodecylbenzene sulfonate, 0.1% sodium laurylsulfonate, the oleoyl methylamine ethyl sulfonic acid sodium of 0.4%, Varion CDG-K, the coconut oil diethanol amide of 0.2%, the isooctyl alcohol sodium sulfate of 0.1% of 0.02% of 0.3%.
Embodiment 2
Take respectively according to following quality standard: the Sodium dodecylbenzene sulfonate of the cetyl trimethylammonium bromide of the starch grafted acrylate of 0.05g, the lauroylamidopropyl betaine of 0.8g, 0.05g, the sodium lauryl sulphate of 0.3g, 0.4g, 0.15g sodium laurylsulfonate, the oleoyl methylamine ethyl sulfonic acid sodium of 0.5g, the Varion CDG-K of 0.05g, the coconut oil diethanol amide of 0.3g, the isooctyl alcohol sodium sulfate of 0.2g.Add in the clear water of 97.20kg by above formula material, fully after mixing, preparation forms the wet type water-retentivity dustfall agent of 100kg.This wet type water-retentivity dustfall agent is applied in the middle of spray for dust suppression, homogeneous, and stability is better.
Wherein, in this formula, various raw material percentage is respectively: the starch grafted acrylate of 0.05%, the lauroylamidopropyl betaine of 0.8%, 0.05% cetyl trimethylammonium bromide, the sodium lauryl sulphate of 0.3%, Sodium dodecylbenzene sulfonate, 0.15% sodium laurylsulfonate, the oleoyl methylamine ethyl sulfonic acid sodium of 0.5%, Varion CDG-K, the coconut oil diethanol amide of 0.3%, the isooctyl alcohol sodium sulfate of 0.2% of 0.05% of 0.4%.
Embodiment 3
Take respectively according to following quality standard: the Sodium dodecylbenzene sulfonate of the cetyl trimethylammonium bromide of the starch grafted acrylate of 0.06g, the lauroylamidopropyl betaine of 1.0g, 0.06g, the sodium lauryl sulphate of 0.35g, 0.45g, 0.18g sodium laurylsulfonate, the oleoyl methylamine ethyl sulfonic acid sodium of 0.6g, the Varion CDG-K of 0.1g, the coconut oil diethanol amide of 0.35g, the isooctyl alcohol sodium sulfate of 0.4g.Add in the clear water of 96.45kg by above formula material, fully after mixing, preparation forms the wet type water-retentivity dustfall agent of 100kg.This wet type water-retentivity dustfall agent is applied in the middle of spray for dust suppression, homogeneous, and stability is better.
Wherein, in this formula, various raw material percentage is respectively: the starch grafted acrylate of 0.06%, the lauroylamidopropyl betaine of 1.0%, 0.06% cetyl trimethylammonium bromide, the sodium lauryl sulphate of 0.35%, Sodium dodecylbenzene sulfonate, 0.18% sodium laurylsulfonate, the oleoyl methylamine ethyl sulfonic acid sodium of 0.6%, Varion CDG-K, the coconut oil diethanol amide of 0.35%, the isooctyl alcohol sodium sulfate of 0.4% of 0.1% of 0.45%.
Embodiment 4
Take respectively according to following quality standard: the Sodium dodecylbenzene sulfonate of the cetyl trimethylammonium bromide of the starch grafted acrylate of 0.08g, the lauroylamidopropyl betaine of 1.2g, 0.08g, the sodium lauryl sulphate of 0.45g, 0.6g, 0.2g sodium laurylsulfonate, the oleoyl methylamine ethyl sulfonic acid sodium of 0.8g, the Varion CDG-K of 0.15g, the coconut oil diethanol amide of 0.4g, the isooctyl alcohol sodium sulfate of 0.6g.Add in the clear water of 95.44kg by above formula material, fully after mixing, preparation forms the wet type water-retentivity dustfall agent of 100kg.This wet type water-retentivity dustfall agent is applied in the middle of spray for dust suppression, homogeneous, and stability is better.
Wherein, in this formula, various raw material percentage is respectively: the starch grafted acrylate of 0.08%, the lauroylamidopropyl betaine of 1.2%, 0.08% cetyl trimethylammonium bromide, the sodium lauryl sulphate of 0.45%, Sodium dodecylbenzene sulfonate, 0.2% sodium laurylsulfonate, the oleoyl methylamine ethyl sulfonic acid sodium of 0.8%, Varion CDG-K, the coconut oil diethanol amide of 0.4%, the isooctyl alcohol sodium sulfate of 0.6% of 0.15% of 0.6%.
Certainly, in the above-described embodiments can according to concrete site technique, adjust the weight percent of each component, this is no longer going to repeat them.
Certainly; more than illustrate and be only preferred embodiment of the present invention; the present invention is not limited to enumerate above-described embodiment; should be noted that; any those of ordinary skill in the art are under the instruction of this specification sheets; made all equivalently to substitute, obvious variant, within the essential scope all dropping on this specification sheets, protection of the present invention ought to be subject to.
Embodiment 1, embodiment 2, embodiment 3 have been carried out test in place with the fully-mechanized mining working of dust-inhibitor in certain colliery shown in embodiment 4, and determine working face respectively and do not adopt any dust prevention, only adopt clear water spraying and the dust concentration of carrying out add the present invention's 4 embodiments in clear water after in spraying situation, as shown in table 1, table 1 is the dust data that when adopting different measure, fully-mechanized mining working respectively measures.
Table 1
As can be seen from the above table, after Application Example 1, embodiment 2, embodiment 3 and dust-inhibitor described in embodiment 4, the full dirt of the average dust reduction rate of working face fog system and exhale dirt to be respectively: 71.8% and 65.2%, 73.0% and 66.1%, 75.1% and 70.1%, 76.1% and 71.7%.Compared with clear water, embodiment 1, embodiment 2, embodiment 3 are with the average full dirt of dust reduction rate of embodiment 4 and exhale dirt to improve respectively: 28.2 percentage points and 23.3 percentage points, 29.4 percentage points and 24.2 percentage points, 31.5 percentage points and 28.2 percentage points, 32.5 percentage points and 29.8 percentage points, having increased substantially dustfall efficiency and dust-laying effect, is the tremendous improvement of prior art.
Certainly; more than illustrate and be only preferred embodiment of the present invention; the present invention is not limited to enumerate above-described embodiment; should be noted that; any those of ordinary skill in the art are under the instruction of this specification sheets; made all equivalently to substitute, obvious variant, within the essential scope all dropping on this specification sheets, protection of the present invention ought to be subject to.
Claims (6)
1. a wet type water-retentivity dustfall agent, is characterized in that, it comprises following component according to weight percent:
2. wet type water-retentivity dustfall agent according to claim 1, it is characterized in that, it comprises following component according to weight percent:
3. wet type water-retentivity dustfall agent according to claim 1, it is characterized in that, it comprises following component according to weight percent:
4. wet type water-retentivity dustfall agent according to claim 1, it is characterized in that, it comprises following component according to weight percent:
5. wet type water-retentivity dustfall agent according to claim 1, it is characterized in that, it comprises following component according to weight percent:
6. wet type water-retentivity dustfall agent according to claim 1, it is characterized in that, it comprises following component according to weight percent:
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Cited By (9)
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CN105733510A (en) * | 2016-03-23 | 2016-07-06 | 湖南安全技术职业学院 | Dust settling agent |
CN106178765A (en) * | 2016-08-31 | 2016-12-07 | 无锡华东琛科环保科技有限公司 | The charged ultrapurification plant of mist formula |
CN106701023A (en) * | 2016-11-28 | 2017-05-24 | 山东国元新材料有限公司 | Foam precipitator |
CN107828380A (en) * | 2017-11-14 | 2018-03-23 | 广东电网有限责任公司电力科学研究院 | A kind of coal stream dust suppressant and its preparation method and application |
CN108531134A (en) * | 2017-03-06 | 2018-09-14 | 山东科技大学 | A kind of enhancing droplet catches the mine dustfall agent of dirt ability |
CN108865068A (en) * | 2017-05-08 | 2018-11-23 | 山东科技大学 | A kind of moisture-absorption water-retention type mine foam propellant and preparation method thereof |
CN109971426A (en) * | 2019-03-26 | 2019-07-05 | 山东科技大学 | A kind of high coagulability dust suppressant of Eco-friendly |
CN110041889A (en) * | 2019-05-31 | 2019-07-23 | 中科盛联(北京)新材料有限公司 | Environmentally friendly crust type dust suppressant and preparation method thereof and application method |
CN113209846A (en) * | 2021-04-30 | 2021-08-06 | 山东农业工程学院 | Mine dust treatment foaming liquid and preparation thereof |
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CN101717617A (en) * | 2009-11-25 | 2010-06-02 | 山东科技大学 | Dedusting agent composition and using method thereof |
CN103805141A (en) * | 2013-12-27 | 2014-05-21 | 山东科技大学 | Coagulant capable of improving coupling and sedimentation of fogdrops and dust particles |
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Cited By (13)
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CN105733510A (en) * | 2016-03-23 | 2016-07-06 | 湖南安全技术职业学院 | Dust settling agent |
CN106178765B (en) * | 2016-08-31 | 2021-07-27 | 朱琳 | Fog type charged super-purifying device |
CN106178765A (en) * | 2016-08-31 | 2016-12-07 | 无锡华东琛科环保科技有限公司 | The charged ultrapurification plant of mist formula |
CN106701023A (en) * | 2016-11-28 | 2017-05-24 | 山东国元新材料有限公司 | Foam precipitator |
CN108531134A (en) * | 2017-03-06 | 2018-09-14 | 山东科技大学 | A kind of enhancing droplet catches the mine dustfall agent of dirt ability |
CN108865068A (en) * | 2017-05-08 | 2018-11-23 | 山东科技大学 | A kind of moisture-absorption water-retention type mine foam propellant and preparation method thereof |
CN107828380A (en) * | 2017-11-14 | 2018-03-23 | 广东电网有限责任公司电力科学研究院 | A kind of coal stream dust suppressant and its preparation method and application |
CN109971426A (en) * | 2019-03-26 | 2019-07-05 | 山东科技大学 | A kind of high coagulability dust suppressant of Eco-friendly |
CN109971426B (en) * | 2019-03-26 | 2022-02-18 | 山东科技大学 | Eco-friendly high-coagulability dust suppressant |
CN110041889A (en) * | 2019-05-31 | 2019-07-23 | 中科盛联(北京)新材料有限公司 | Environmentally friendly crust type dust suppressant and preparation method thereof and application method |
CN110041889B (en) * | 2019-05-31 | 2019-12-31 | 中科盛联(北京)新材料有限公司 | Environment-friendly crusting dust suppressant and preparation method and use method thereof |
CN113209846A (en) * | 2021-04-30 | 2021-08-06 | 山东农业工程学院 | Mine dust treatment foaming liquid and preparation thereof |
CN113209846B (en) * | 2021-04-30 | 2022-06-28 | 山东农业工程学院 | Mine dust treatment foaming liquid and preparation thereof |
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