CN104449165A - Strain-resistant inner wall latex paint and preparation method thereof - Google Patents

Strain-resistant inner wall latex paint and preparation method thereof Download PDF

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Publication number
CN104449165A
CN104449165A CN201410649875.4A CN201410649875A CN104449165A CN 104449165 A CN104449165 A CN 104449165A CN 201410649875 A CN201410649875 A CN 201410649875A CN 104449165 A CN104449165 A CN 104449165A
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parts
water
resistant
latex paint
wall latex
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洪杰
何玲玲
林昌庆
魏欣欣
陈松
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Skshu Paint Co Ltd
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Skshu Paint Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • C09D5/025Preservatives, e.g. antimicrobial agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention particularly relates to a strain-resistant inner wall latex paint and a preparation method thereof. The strain-resistant inner wall latex paint is prepared from the following raw materials in parts by weight: 10-20 parts of water, 0.3-0.4 part of hydroxyethyl cellulose, 0.3-0.4 part of water-based multifunctional auxiliary agents, 1.0-1.2 parts of water-based dispersing agents, 0.5-0.6 part of water-based wetting agents, 0.5-0.6 part of water-based defoaming agents, 0.4-0.6 part of anti-mildew agents, 18-25 parts of titanium dioxide, 5-15 parts of coating mica powder, 5-15 parts of calcium carbonate, 30-35 parts of acrylic ester emulsions, 1-6 parts of styrene-acrylate emulsions, 0.3-0.5 part of strain-resistant auxiliary agents, 1.5-2.0 parts of film-forming auxiliary agents, 1.0-1.2 parts of antifreezing agents, 0.2-0.3 part of sterilizing preservative agents and 1.0-1.5 parts of thickening agents. The strain-resistant inner wall latex paint prepared through the method disclosed by the invention has very good strain-resistant property and can be used for prolonging the optimal wiping time when a coating is polluted.

Description

Spot-resistant interiro wall latex paint and preparation method thereof
Technical field
The present invention relates to a kind of antifouling paint and preparation method thereof, particularly a kind of spot-resistant interiro wall latex paint and preparation method thereof, belongs to architectural decoration material field.
Background technology
In daily life, the metope after covering with paint unavoidably can by being polluted by various household stains, and serious also can have influence on the attractive in appearance of coating, destroys its decorative effect.In the source of pollution of these spots, have from us and the refuses such as unwanted rubbish, what also have comes from the not proper use etc. of other article, the scribble of such as children, scatters the spot etc. of metope in life because of carelessness.But when we find these spots time, all spend the time of best wiping, that is spot is difficult to be wiped.
Summary of the invention
In order to solve the problems referred to above existing for prior art, the invention provides a kind of spot-resistant interiro wall latex paint and preparation method thereof, spot-resistant interiro wall latex paint prepared by the present invention has good spot-resistant performance, in the test of GB9780-2013 building coating coating contamination resistance testing method, average mark can reach more than 90 point, when coating is subject to polluting, can extend the best wiping time, it exceeds more than 25% than existing antifouling paint contamination resistance.
Technical solution of the present invention is as follows:
One) scheme one:
A kind of spot-resistant interiro wall latex paint, it is made up of the raw material of following weight proportioning:
Described water can adopt common tap water or other clean water, and it is as the dispersion of dispersed color, regulates the viscosity of slurry during making beating.
Described Natvosol is the water dissolvable ether of cellulose of non-ionic type, can be the Natvosol of different molecular weight, and it is as thickening material when regulating dispersion to pull an oar, and makes pigment have a good dispersion viscosity;
Described water-soluble multifunctional auxiliary agent adopts 2-amino-2-methyl-1-propanol, and it is mainly used for regulating potential of hydrogen, has the effect of wetting, dispersion and stabilising system;
It is hydrophobically modified ammonium polyacrylate dipersant that described aqueous dispersant adopts, and has splendid color development performance.
Described aqueous wetting agent is EO/PO-segmented copolymer, has good wet and dispersiveness, also has low bubble;
Described water-based defoamer is non-ionic type defoamer or silicone antifoam agent, adopts the defoamer without consistency and recoat problem, plays froth breaking effect in formula system;
Described mould inhibitor is daconil M emulsion, is a kind of efficient, wide spectrum water mildow-proof agent, can effectively killing fungus and algae, does not contain organic solvent;
Described titanium dioxide is anatase thpe white powder or Rutile type Titanium Dioxide, in formula system, provide hiding rare.
Coating mica powder adopts proportion to be 2.5-2.9g/cm3, oil number is 16-70, and average specific volume is 35, and refractive index is the white plates mica powder of 1.58-1.63, the wiping time of contaminated rear coating the best can be extended in formulation for coating material system, thus improve the contamination resistance of paint film.
Described calcium carbonate adopts water-ground limestone, and fineness is preferably 700-900 order, plays a part to fill and reduce costs in formula system.
Described acrylic ester emulsion adopts pure acrylic latex, not containing APEO and formaldehyde, low VOC and low smell emulsion, Gu containing being 50.0 ± 1.0%, pH value is 7.0-8.0, MFFT about 5 DEG C, second-order transition temperature about 12 DEG C, proportion is 1.06g/cm3, is a kind of milky white liquid, it is as film forming matter, can provide good cohesive force.
The hollow beads polymer emulsion that described benzene emulsion adopts vinylbenzene and acrylic ester copolymerization to close; Its quality is admittedly containing being 30.0%, and volume contains admittedly: 52.1%, proportion (wetting) 1.025g/ml, proportion (doing) 0.591g/cm3, particle diameter is 0.38 micron, and pH value is 8.0-8.7, in formula system, improve the compactness hiding and increase film, improve the contamination resistance of paint film.Described benzene emulsion is a kind of vinylbenzene and acrylate copolymer dispersion system of film forming firmly and not.By the hard polystyrene and the acrylate shell that have hollow core, be coated with water-filled core and form.When dried coating film, water in shell irreversible diffusion and going out from shell copolymers, leave the difference of the core increasing refracting light incident being replaced water by air, when the shell of light transmission synthetic resins composition is through air, change the refraction angle of incident light, thus generation refraction effect, improve specific refractory power, add the opacity of paint film.
Described anti-soil auxiliary agent is water-based fiuorinated acrylic copolymer, Gu containing being 34-36%, density is 1.1g/ml, flash-point > 93 DEG C, is a kind of limpid amber color liquid, and the main contamination resistance improving paint film.
Described film coalescence aid is 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrates, its chemical constitution for two fat structure, boiling point be 281 DEG C, rate of volatilization is 0.0004, non-VOC, its film coalescence aid as a kind of low smell, can help film forming matter more than 5 DEG C, become a continuous print film;
Described frostproofer adopts triphenyl vinyl phenol ethoxy compound, and it is solid containing being 88.0-92.0%.PH value (5% aqueous solution) 5.0-7.5, containing APEO and solvent, it, as a kind of limpid light yellow liquid to fuzzy shape, can prevent film forming matter freezing when storing for-5 DEG C to 0 DEG C.
Described fungicidal preservative adopts isothiazolinone disinfecting agent, has sterilization and anticorrosion effect;
Described thickening material adopts hydrophobically modified urethane, as the low smell of one, not solvent-laden water-based non-ionic associative type rheology modifier, provides splendid flowing and levelling property, uniform film forming properties, gloss to represent performance and high thickening efficiency.
Two) scheme two: a kind of preparation method for the preparation of spot-resistant interiro wall latex paint described in scheme one, it comprises following step of sequentially carrying out:
(1) 10-20 part water is added in dispersion cylinder, under 350-550r/min rotating speed, add 0.3-0.4 part Natvosol and 0.3-0.4 part water-soluble multifunctional auxiliary agent successively, dispersion 1min-3min;
(2) after improving rotating speed to 800-1000r/min, after adding 1.0-1.2 part aqueous dispersant, 0.5-0.6 part aqueous wetting agent, 0.5-0.6 part water-based defoamer, 0.4-0.6 part mould inhibitor, 18-25 part titanium dioxide, 5-15 part coating mica powder and 5-15 part calcium carbonate successively, again improve rotating speed and disperse 15min-20min to 1800-2000r/min rotating speed, detect fineness whether≤60 μm afterwards, if fineness≤60 μm, continue to perform step (3);
(3), after adding 30-35 acrylic ester emulsion, 1-6 part benzene emulsion, 0.3-0.5 part anti-soil auxiliary agent, 1.5-2.0 part film coalescence aid, 1.0-1.2 part frostproofer, 0.2-0.3 part fungicidal preservative and 1.0-1.5 part thickening material successively under reducing rotating speed to 1000-1200r/min rotating speed, 15-20min is even to mixing liquid in dispersion.
The selected various Material cladding collocation of the present invention, component and weight proportion thereof is determined by multinomial experiment, it is a kind of new coating for resistant exploitation, antifouling paint of the present invention tool compared with traditional antifouling paint has the following advantages: in the test of GB9780-2013 building coating coating contamination resistance testing method, average mark can reach more than 90 point, exceeds more than 25% than antifouling paint contamination resistance on the market; When coating is subject to polluting, extend the best wiping time, greatly improve paint film contamination resistance.
Embodiment
Below in conjunction with embodiment, embodiment, content of the present invention is described in detail:
(1) embodiment
A kind of spot-resistant interiro wall latex paint, it is prepared from by following steps by following quality proportioning by following raw material:
(1) 10-20 part water is added in dispersion cylinder, under 350-550r/min rotating speed, add 0.3-0.4 part Natvosol and 0.3-0.4 part water-soluble multifunctional auxiliary agent successively, dispersion 1min-3min;
(2) after improving rotating speed to 800-1000r/min, after adding 1.0-1.2 part aqueous dispersant, 0.5-0.6 part aqueous wetting agent, 0.5-0.6 part water-based defoamer, 0.4-0.6 part mould inhibitor, 18-25 part titanium dioxide, 5-15 part coating mica powder and 5-15 part calcium carbonate successively, again improve rotating speed and disperse 15min-20min to 1800-2000r/min rotating speed, detect fineness whether≤60 μm afterwards, if fineness≤60 μm, continue to perform step (3);
(3), after adding 30-35 acrylic ester emulsion, 1-6 part benzene emulsion, 0.3-0.5 part anti-soil auxiliary agent, 1.5-2.0 part film coalescence aid, 1.0-1.2 part frostproofer, 0.2-0.3 part fungicidal preservative and 1.0-1.5 part thickening material successively under reducing rotating speed to 1000-1200r/min rotating speed, 15-20min is even to mixing liquid in dispersion.
(1) embodiment
Embodiment 1 (most preferred embodiment)
A kind of spot-resistant interiro wall latex paint, it is prepared from by following steps by following quality proportioning by following raw material:
(1) 14.6 parts of water are added in dispersion cylinder, under 450r/min rotating speed, add 0.4 part of Natvosol and 0.4 part of water-soluble multifunctional auxiliary agent successively, dispersion 2min;
(2) after improving rotating speed to 900r/min, after adding 1.0 parts of aqueous dispersants, 0.5 part of aqueous wetting agent, 0.5 part of water-based defoamer, 0.6 part of mould inhibitor, 18 parts of titanium dioxides, 15 parts of coating mica powders and 9 parts of calcium carbonate successively, again improve rotating speed and disperse 18min to 1900r/min rotating speed, detect fineness whether≤60 μm afterwards, if fineness≤60 μm, continue to perform step (3);
(3), after adding 30 acrylic ester emulsions, 6 parts of benzene emulsions, 0.3 part of anti-soil auxiliary agent, 1.5 parts of film coalescence aid, 1.0 parts of frostproofers, 0.2 part of fungicidal preservative and 1.0 parts of thickening materials successively under reducing rotating speed to 1100r/min rotating speed, 18min is even to mixing liquid in dispersion.
Embodiment 2
A kind of spot-resistant interiro wall latex paint, it is prepared from by following steps by following quality proportioning by following raw material:
(1) 16.9 parts of water are added in dispersion cylinder, under 350r/min rotating speed, add 0.3 part of Natvosol and 0.3 part of water-soluble multifunctional auxiliary agent successively, dispersion 3min;
(2) after improving rotating speed to 1000r/min, after adding 1.2 parts of aqueous dispersants, 0.6 part of aqueous wetting agent, 0.6 part of water-based defoamer, 0.4 part of mould inhibitor, 25 parts of titanium dioxides, 12 parts of coating mica powders and 5 parts of calcium carbonate successively, again improve rotating speed and disperse 15min to 2000r/min rotating speed, detect fineness whether≤60 μm afterwards, if fineness≤60 μm, continue to perform step (3);
(3), after adding 33 acrylic ester emulsions, 1 part of benzene emulsion, 0.5 part of anti-soil auxiliary agent, 1.8 parts of film coalescence aid, 1.2 parts of frostproofers, 0.3 part of fungicidal preservative and 1.5 parts of thickening materials successively under reducing rotating speed to 1200r/min rotating speed, 18min is even to mixing liquid in dispersion.
Embodiment 3
A kind of spot-resistant interiro wall latex paint, it is prepared from by following steps by following quality proportioning by following raw material:
(1) 12.15 parts of water are added in dispersion cylinder, under 350r/min rotating speed, add 0.35 part of Natvosol and 0.4 part of water-soluble multifunctional auxiliary agent successively, dispersion 3min;
(2) after improving rotating speed to 1000r/min, after adding 1.0 parts of aqueous dispersants, 0.55 part of aqueous wetting agent, 0.55 part of water-based defoamer, 0.5 part of mould inhibitor, 22 parts of titanium dioxides, 5 parts of coating mica powders and 15 parts of calcium carbonate successively, again improve rotating speed and disperse 15min-20min to 1800r/min rotating speed, detect fineness whether≤60 μm afterwards, if fineness≤60 μm, continue to perform step (3);
(3), after adding 30 acrylic ester emulsions, 4 parts of benzene emulsions, 0.5 part of anti-soil auxiliary agent, 2.0 parts of film coalescence aid, 1.2 parts of frostproofers, 0.3 part of fungicidal preservative and 1.5 parts of thickening materials successively under reducing rotating speed to 1000r/min rotating speed, 20min is even to mixing liquid in dispersion.
Embodiment 4
A kind of spot-resistant interiro wall latex paint, it is prepared from by following steps by following quality proportioning by following raw material:
(1) 13.1 parts of water are added in dispersion cylinder, under 450r/min rotating speed, add 0.4 part of Natvosol and 0.4 part of water-soluble multifunctional auxiliary agent successively, dispersion 2min;
(2) after improving rotating speed to 800r/min, after adding 1.2 parts of aqueous dispersants, 0.5 part of aqueous wetting agent, 0.6 part of water-based defoamer, 0.5 part of mould inhibitor, 20 parts of titanium dioxides, 12.5 parts of coating mica powders and 7.5 parts of calcium carbonate successively, again improve rotating speed and disperse 15min to 2000r/min rotating speed, detect fineness whether≤60 μm afterwards, if fineness≤60 μm, continue to perform step (3);
(3), after adding 34 acrylic ester emulsions, 4 parts of benzene emulsions, 0.5 part of anti-soil auxiliary agent, 1.8 parts of film coalescence aid, 1.2 parts of frostproofers, 0.3 part of fungicidal preservative and 1.5 parts of thickening materials successively under reducing rotating speed to 1200r/min rotating speed, 20min is even to mixing liquid in dispersion.
Embodiment 5
A kind of spot-resistant interiro wall latex paint, it is prepared from by following steps by following quality proportioning by following raw material:
(1) 10 parts of water are added in dispersion cylinder, under 550r/min rotating speed, add 0.4 part of Natvosol and 0.3 part of water-soluble multifunctional auxiliary agent successively, dispersion 1min;
(2) after improving rotating speed to 1000r/min, after adding 1.2 parts of aqueous dispersants, 0.6 part of aqueous wetting agent, 0.5 part of water-based defoamer, 0.6 part of mould inhibitor, 18 parts of titanium dioxides, 15 parts of coating mica powders and 5 parts of calcium carbonate successively, again improve rotating speed and disperse 20min to 1800r/min rotating speed, detect fineness whether≤60 μm afterwards, if fineness≤60 μm, continue to perform step (3);
(3), after adding 35 acrylic ester emulsions, 6 parts of benzene emulsions, 0.3 part of anti-soil auxiliary agent, 1.5 parts of film coalescence aid, 1.2 parts of frostproofers, 0.2 part of fungicidal preservative and 1.5 parts of thickening materials successively under reducing rotating speed to 1000r/min rotating speed, 15min is even to mixing liquid in dispersion.
In above each embodiment:
Described hydromining ordinary tap water;
Described Natvosol adopts the sub-250HBR produced across dragon;
The AMP-95 that described water-soluble multifunctional auxiliary agent adopts Tao Shi to produce;
The CA-2500 that described aqueous dispersant adopts ROHM AND HAAS to produce;
The PF-20 that described aqueous wetting agent adopts Ke Laien to produce;
The A10 that 334 and Hai Chuan that described water-based defoamer employing section rather produces produce;
The EPW that described mould inhibitor adopts Troy to produce;
The BLR-699 that described titanium dioxide adopts one hundred profit connection to produce;
Described coating mica powder adopts the U.S. high mica powder produced;
The 700 order coarse whitings that described calcium carbonate adopts agriculture-countryside-farmer to produce;
The SF-266 emulsion that described benzene emulsion adopts Tao Shi to produce;
The anti-wax crayon auxiliary agent of FS-87 that described anti-soil auxiliary agent adopts E.I.Du Pont Company to produce;
The OE-300 that described film coalescence aid adopts Yi Shiman to produce;
Described frostproofer adopts the sub-FT-100 freeze-thaw stabiliser produced in sieve ground;
The RS that described fungicidal preservative adopts the Troy produced to produce;
Described thickening material adopts the WT-204 of the modest production of moral.
In each embodiment of spot-resistant interiro wall latex paint prepared by the present invention according to the property indices measured by interior wall coating coating contamination resistance test method in GB9780-2013 " building coating coating contamination resistance testing method " and technical indicator as shown in following table:
The experimental data that in each embodiment GB9780-2013 " building coating coating contamination resistance testing method " of the spot-resistant interiro wall latex paint prepared by table one-the present invention, interior wall coating coating contamination resistance test method records
As apparent from table one can, various embodiments of the present invention all meet the requirement of the salable product of GB9780-2013 building coating coating contamination resistance testing method, and average mark can reach more than 90 point, exceeds more than 25% than antifouling paint contamination resistance on the market; When coating is subject to polluting, extend the best wiping time, greatly improve paint film contamination resistance.
Above-mentioned embodiment is just explained in detail technical scheme of the present invention; the present invention has more than and is only confined to above-described embodiment; those skilled in the art should be understood that; every improvement on basis of the present invention according to above-mentioned principle and spirit, substitute, all should within protection scope of the present invention.

Claims (10)

1. a resistant interiro wall latex paint, is characterized in that: it is made up of the raw material of following weight proportioning:
2. resistant interiro wall latex paint as claimed in claim 1, is characterized in that:
Described Natvosol is the water dissolvable ether of cellulose of non-ionic type;
Described water-soluble multifunctional auxiliary agent adopts 2-amino-2-methyl-1-propanol;
It is hydrophobically modified ammonium polyacrylate dipersant that described aqueous dispersant adopts.
3. resistant interiro wall latex paint as claimed in claim 1, is characterized in that:
Described aqueous wetting agent is EO/PO-segmented copolymer;
Described water-based defoamer is non-ionic type defoamer or silicone antifoam agent;
Described mould inhibitor is daconil M emulsion;
Described titanium dioxide is anatase thpe white powder or Rutile type Titanium Dioxide.
4. resistant interiro wall latex paint as claimed in claim 1, is characterized in that:
Described calcium carbonate adopts water-ground limestone.
5. resistant interiro wall latex paint as claimed in claim 1, is characterized in that:
Described acrylic ester emulsion adopts pure acrylic latex.
6. resistant interiro wall latex paint as claimed in claim 1, is characterized in that:
The hollow beads polymer emulsion that described benzene emulsion adopts vinylbenzene and acrylic ester copolymerization to close.
7. resistant interiro wall latex paint as claimed in claim 1, is characterized in that:
Described anti-soil auxiliary agent is water-based fiuorinated acrylic copolymer.
8. resistant interiro wall latex paint as claimed in claim 1, is characterized in that:
Described film coalescence aid is 2,2,4-trimethylammonium-1,3 pentanediol mono isobutyrate;
Described frostproofer adopts triphenyl vinyl phenol ethoxy compound.
9. resistant interiro wall latex paint as claimed in claim 1, is characterized in that:
Described fungicidal preservative adopts isothiazolinone disinfecting agent;
Described thickening material is hydrophobically modified urethane.
10., for the preparation of a preparation method for resistant interiro wall latex paint according to any one of claim 1-9, it is characterized in that: it comprises following step of sequentially carrying out:
(1) 10-20 part water is added in dispersion cylinder, under 350-550r/min rotating speed, add 0.3-0.4 part Natvosol and 0.3-0.4 part water-soluble multifunctional auxiliary agent successively, dispersion 1min-3min;
(2) after improving rotating speed to 800-1000r/min, after adding 1.0-1.2 part aqueous dispersant, 0.5-0.6 part aqueous wetting agent, 0.5-0.6 part water-based defoamer, 0.4-0.6 part mould inhibitor, 18-25 part titanium dioxide, 5-15 part coating mica powder and 5-15 part calcium carbonate successively, again improve rotating speed and disperse 15min-20min to 1800-2000r/min rotating speed, detect fineness whether≤60 μm afterwards, if fineness≤60 μm, continue to perform step (3);
(3), after adding 30-35 part acrylic ester emulsion, 1-6 part benzene emulsion, 0.3-0.5 part anti-soil auxiliary agent, 1.5-2.0 part film coalescence aid, 1.0-1.2 part frostproofer, 0.2-0.3 part fungicidal preservative and 1.0-1.5 part thickening material successively under reducing rotating speed to 1000-1200r/min rotating speed, 15-20min is even to mixing liquid in dispersion.
CN201410649875.4A 2014-11-14 2014-11-14 Strain-resistant inner wall latex paint and preparation method thereof Pending CN104449165A (en)

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Cited By (20)

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Publication number Priority date Publication date Assignee Title
CN105001732A (en) * 2015-08-10 2015-10-28 苏州科淼新材料有限公司 Emulsion paint and preparation method thereof
CN105462315A (en) * 2015-12-15 2016-04-06 三棵树涂料股份有限公司 High-stain-resistance elastic and tip-shaped broom-finish emulsion paint and preparation method thereof
CN105505055A (en) * 2015-12-18 2016-04-20 三棵树涂料股份有限公司 Water-based woodware one-third-gloss brushmark shaping white finish and preparation method thereof
CN105505016A (en) * 2015-12-31 2016-04-20 辛范范 Improved building paint and preparation method thereof
CN106118415A (en) * 2016-06-27 2016-11-16 安徽金联地矿科技有限公司 A kind of anti-soil inner wall of building decorative water coating and preparation method thereof
CN106752428A (en) * 2015-11-25 2017-05-31 湖南开磷雁峰塔涂料有限公司 A kind of interior wall coating
CN107189676A (en) * 2017-07-19 2017-09-22 合肥广民建材有限公司 A kind of waterproof sun-proof exterior coating and preparation method thereof
CN107365533A (en) * 2017-08-11 2017-11-21 芜湖凌梦电子商务有限公司 A kind of interiro wall latex paint
CN107365541A (en) * 2017-09-22 2017-11-21 苏州振振好新型建材科技有限公司 A kind of efficiently hydrophilic anti-mould proof coating and its preparation and application process
CN107603387A (en) * 2017-09-22 2018-01-19 苏州振振好新型建材科技有限公司 Third finish of a kind of environment-friendly waterproof resistant silicon and preparation method thereof
CN107603371A (en) * 2017-09-22 2018-01-19 苏州振振好新型建材科技有限公司 A kind of long-acting type antibiotic fungus-resisting paint and its preparation and application process
CN108587355A (en) * 2018-05-22 2018-09-28 河北晨阳工贸集团有限公司 Water paint and preparation method thereof
CN110317509A (en) * 2019-07-30 2019-10-11 德美特涂料(北京)有限公司 The preparation method of interior wall latex finishing coat suitable for mopping wallpaper
CN110396313A (en) * 2019-07-30 2019-11-01 德美特涂料(北京)有限公司 Interior wall latex finishing coat suitable for mopping wallpaper
CN110527383A (en) * 2019-09-10 2019-12-03 深圳市瑞福联合新材料发展有限公司 A kind of fungi-proofing interior wall coating of water mildow-proof
CN111154306A (en) * 2020-01-17 2020-05-15 浙江壁灵宝建材科技有限公司 Double-component waterproof interior wall putty
CN113801525A (en) * 2021-09-23 2021-12-17 河北三棵树涂料有限公司 Ultralow VOC mildew-proof interior wall latex paint with super stain-resistant and aldehyde-removing functions and preparation method thereof
CN114395301A (en) * 2021-12-29 2022-04-26 上海申得欧有限公司 Anti-scratch stain-resistant interior wall coating and preparation method thereof
CN115073977A (en) * 2022-07-05 2022-09-20 上海涂固安高科技有限公司 Preparation method of washable high-grade water-based interior wall coating for children's houses
CN115109472A (en) * 2022-07-29 2022-09-27 东莞大宝化工制品有限公司 Low-side gloss high-weather-resistance exterior wall coating and preparation method thereof

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CN1657580A (en) * 2004-02-18 2005-08-24 方学平 Surpergrade scrubbing-resistant interior wall paint and its prearation method
CN1844281A (en) * 2006-03-31 2006-10-11 广东华润涂料有限公司 Environment-friendly antifouling weather-resistant heat-reflecting thermal-insulating coating and method for preparing same

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Publication number Priority date Publication date Assignee Title
EP0955345A1 (en) * 1998-05-07 1999-11-10 Nikolaos Goumas Method of forming flat/satin paints with improved scattering efficiency and lowered percentage of titanium dioxide
CN1557889A (en) * 2004-02-10 2004-12-29 方学平 Water wall paint for external wall
CN1657580A (en) * 2004-02-18 2005-08-24 方学平 Surpergrade scrubbing-resistant interior wall paint and its prearation method
CN1844281A (en) * 2006-03-31 2006-10-11 广东华润涂料有限公司 Environment-friendly antifouling weather-resistant heat-reflecting thermal-insulating coating and method for preparing same

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105001732A (en) * 2015-08-10 2015-10-28 苏州科淼新材料有限公司 Emulsion paint and preparation method thereof
CN106752428A (en) * 2015-11-25 2017-05-31 湖南开磷雁峰塔涂料有限公司 A kind of interior wall coating
CN105462315A (en) * 2015-12-15 2016-04-06 三棵树涂料股份有限公司 High-stain-resistance elastic and tip-shaped broom-finish emulsion paint and preparation method thereof
CN105505055A (en) * 2015-12-18 2016-04-20 三棵树涂料股份有限公司 Water-based woodware one-third-gloss brushmark shaping white finish and preparation method thereof
CN105505016A (en) * 2015-12-31 2016-04-20 辛范范 Improved building paint and preparation method thereof
CN106118415A (en) * 2016-06-27 2016-11-16 安徽金联地矿科技有限公司 A kind of anti-soil inner wall of building decorative water coating and preparation method thereof
CN107189676A (en) * 2017-07-19 2017-09-22 合肥广民建材有限公司 A kind of waterproof sun-proof exterior coating and preparation method thereof
CN107365533A (en) * 2017-08-11 2017-11-21 芜湖凌梦电子商务有限公司 A kind of interiro wall latex paint
CN107603371A (en) * 2017-09-22 2018-01-19 苏州振振好新型建材科技有限公司 A kind of long-acting type antibiotic fungus-resisting paint and its preparation and application process
CN107603387A (en) * 2017-09-22 2018-01-19 苏州振振好新型建材科技有限公司 Third finish of a kind of environment-friendly waterproof resistant silicon and preparation method thereof
CN107365541A (en) * 2017-09-22 2017-11-21 苏州振振好新型建材科技有限公司 A kind of efficiently hydrophilic anti-mould proof coating and its preparation and application process
CN108587355A (en) * 2018-05-22 2018-09-28 河北晨阳工贸集团有限公司 Water paint and preparation method thereof
CN110317509A (en) * 2019-07-30 2019-10-11 德美特涂料(北京)有限公司 The preparation method of interior wall latex finishing coat suitable for mopping wallpaper
CN110396313A (en) * 2019-07-30 2019-11-01 德美特涂料(北京)有限公司 Interior wall latex finishing coat suitable for mopping wallpaper
CN110527383A (en) * 2019-09-10 2019-12-03 深圳市瑞福联合新材料发展有限公司 A kind of fungi-proofing interior wall coating of water mildow-proof
CN111154306A (en) * 2020-01-17 2020-05-15 浙江壁灵宝建材科技有限公司 Double-component waterproof interior wall putty
CN113801525A (en) * 2021-09-23 2021-12-17 河北三棵树涂料有限公司 Ultralow VOC mildew-proof interior wall latex paint with super stain-resistant and aldehyde-removing functions and preparation method thereof
CN114395301A (en) * 2021-12-29 2022-04-26 上海申得欧有限公司 Anti-scratch stain-resistant interior wall coating and preparation method thereof
CN115073977A (en) * 2022-07-05 2022-09-20 上海涂固安高科技有限公司 Preparation method of washable high-grade water-based interior wall coating for children's houses
CN115109472A (en) * 2022-07-29 2022-09-27 东莞大宝化工制品有限公司 Low-side gloss high-weather-resistance exterior wall coating and preparation method thereof

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Application publication date: 20150325