CN103849267B - A kind of water-based paint compositions and preparation method thereof - Google Patents
A kind of water-based paint compositions and preparation method thereof Download PDFInfo
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- CN103849267B CN103849267B CN201410122751.0A CN201410122751A CN103849267B CN 103849267 B CN103849267 B CN 103849267B CN 201410122751 A CN201410122751 A CN 201410122751A CN 103849267 B CN103849267 B CN 103849267B
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Abstract
The invention provides a kind of water-based paint compositions, described water-based paint compositions includes the component of following parts by weight: film forming matter 30～50 weight portion, color stuffing 26～40 weight portion, HASE hydrophobic dispersants auxiliary agent 0.3～0.5 weight portion, aqueous fine oxidic polyethylene wax emulsion 1.0～2.0 weight portion, fluorine-containing surfactant 0.3～1.0 weight portion, cosolvent 1.0～2.0 weight portion, coalescents 1.0～2.0 weight portion, other auxiliary agent 2.0～3.0 weight portions, and the water of acceptable amount；The pigment volume concentration (PVC) of water-based paint compositions of the present invention is 30～50%.The double; two thin effect of coating lacquer film water oil that this coating composition is formed is better, it is favorably improved the quality of interior wall coating product, opening up the application made new advances, the requirement of high-environmental adds high-quality anti-soil feature simultaneously, and making this product can be better indoor decoration decoration market service.
Description
Technical field
The present invention relates to a kind of water-based paint compositions and preparation method thereof, particularly relate to a kind of water-based paint compositions of high-dirt-resistance energy with hydrophobic oleophobic double effects and preparation method thereof.
Background technology
The chemical products that coating is a kind of easy construction, cheap, effect is obvious, value-added rates is high.It can not only the surface such as decorative architecture, boats and ships, machinery, and have and prevent its surface corrosion, the function increased the service life, decorative environment is also had to give the enjoyment of U.S. and the function of eye-catching labelling, along with the development of science and technology, coating progressively becomes a kind of specificity strong fine chemistry product strong, functional.
As time goes on, easily there is pollution in various degree to inner-outer wall coating in metope, and mill is spent, come off, and metope fades, wears, and affects the appearance of the city.So preventing metope spot osmosis pollution, it is critically important for extending metope service life.
Traditional inner-outer wall anti-soil product decontamination cleaning way: 1. clean with a large amount of detergents.2. need with hard hair brush outwash back and forth.
What tradition inner-outer wall anti-soil product decontamination was cleaned has drawbacks in that 1, uses a large amount of detergent, and water environment pollution is big；2, using the cleaning meanss such as brush that metope is scrubbed and high-grade metope can be wiped flower, surface becomes rough；Producing local speck, coating surface gloss is inconsistent.
The stain resistance that coating is good is always up the major demands (or attraction) of interior wall coating, but the stain resistance of general interior wall product is all not as strong.The modern life exists a large amount of various spot; having aqueous, oil-dirt, liquid, solid spot, most spots are all not easily wiped out; and paint film would generally occur by not only light by wiping of wiping shedding or paint film but also bright, and there is very big-difference in the metope of surrounding on gloss.This is primarily due to, and general interior wall product hardness of paint film is not high, formula for a product PVC (pigment volume concentration (PVC)) is too high and paint film requires matte effect, and paint film is fine and close not, makes paint film be subject to spot and pollutes to penetrate into and not easily clean and wipe.
In sum, the waterborne wall surface coating that this area lacks a kind of hydrophobic oleophobic double effects, stain resistance is strong.
Summary of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art part to provide the water-based paint compositions of a kind of high-dirt-resistance energy with hydrophobic oleophobic double effects, another object of the present invention is to the preparation method that described water-based paint compositions is provided.
For achieving the above object, the technical scheme that the present invention takes: a kind of water-based paint compositions, described water-based paint compositions includes the component of following parts by weight: film forming matter 30～50 weight portion, color stuffing 26～40 weight portion, HASE hydrophobic dispersants auxiliary agent 0.3～0.5 weight portion, aqueous fine oxidic polyethylene wax emulsion 1.0～2.0 weight portion, fluorine-containing surfactant 0.3～1.0 weight portion, cosolvent 1.0～2.0 weight portion, coalescents 1.0～2.0 weight portion, other auxiliary agent 2.0～3.0 weight portions, and the water of acceptable amount；The pigment volume concentration (PVC) of water-based paint compositions of the present invention is 30～50%, mean diameter≤0.1 μm of the fine oxidic polyethylene wax emulsion of described aqueous.
Preferably, other auxiliary agents of the present invention comprise the component of following weight portion: defoamer 0.15-0.30 weight portion, thickening agent 1.2-2.0 weight portion, pH adjusting agent 0.05-0.10 weight portion, antifungus agent 0.3～0.5 weight portion, preservative 0.1～0.2 weight portion.
Preferably, in other auxiliary agents described, the mass ratio of defoamer, thickening agent, pH adjusting agent, antifungus agent and preservative is defoamer: thickening agent: pH adjusting agent: antifungus agent: preservative=(0.3 ± 0.1): (1.2 ± 0.1): (0.2 ± 0.05): (0.4 ± 0.1): (0.15 ± 0.05).
Preferably, defoamer of the present invention is at least one in silicone based defoamer, mineral oil defoaming agent；Described thickening agent is at least one in polyurethanes rheology control agent, inorganic bentonite, in a detailed description of the invention, described thickening agent is polyurethanes rheology control agent (solid content is 20%, semi-transparent clear shape, presents similar Newtonian liquid figure) and the bentonitic combination of inorganic thickening agent；Described pH adjusting agent is organic alcohol amine pH adjusting agent, and in a detailed description of the invention, the present invention adopts the AMP-95 of DOW company as pH adjusting agent.
Preferably, defoamer of the present invention is the combination of silicone based defoamer and mineral oil defoaming agent, in defoamer of the present invention, the mass ratio of silicone based defoamer and mineral oil defoaming agent is silicone based defoamer: mineral oil defoaming agent=1:1 or silicone based defoamer: mineral oil defoaming agent=1.5:1.0, in described defoamer, silicone based defoamer and mineral oil defoaming agent collocation use, the froth breaking stability quickly permanent to ensure offer.
Preferably, film forming matter of the present invention is AA emulsion.
Preferably, AA emulsion particle size distribution of the present invention is 150～240nm, and described AA emulsion vitrification point Tg is 18～26 DEG C, and described AA emulsion minimum film formation temperature MFFT is 9～15 DEG C；In a detailed description of the invention, described film forming matter is the AA emulsion of the Dow Chemical Company's commodity PrimalAC-268 by name, its particle size distribution is 150～240nm, mean diameter 215 ± 5nm, solid compositions is between 45～50%, residual monomer 100ppm, TVOCs 100ppm, vitrification point Tg are between 18～26 DEG C, and minimum film formation temperature MFFT is between 9～15 DEG C；The film forming matter that the present invention adopts is the AA emulsion with functions, possesses certain hardness of film after this synthetic emulsion film forming, and the compact in paint film of formation is good, and stain resistance is strong.
Preferably, in color stuffing of the present invention, pigment is Rutile type titanium dioxide, and in described color stuffing, filler is at least one in wollastonite, silicon treasured, mica powder, Pulvis Talci, calcined kaolin, nepheline powder, blanc fixe, triple superphosphate；In a detailed description of the invention, described filler chooses hardness height, polarity is low, the powder of inertia as the choosing of main powder, as precious in wollastonite, silicon etc., need to select other powder matched combined further according to formula, concrete raw material adopts commercially available prod；Titanium dioxide provides painting color, and filler increases hardness of paint film, compactness, crack resistence, scrubbing resistance etc.；Cosolvent of the present invention and coalescents are not specifically limited, it is possible to adopting the commercially available various cosolvents suitable in acrylic coating and coalescents, usual cosolvent has propylene glycol, ethylene glycol and glycol ethers；Preferably, cosolvent of the present invention is glycols cosolvent, and it act as antifreeze, promotes levelling, and described coalescents is alkoxide solvent, and it act as the reduction most end film-forming temperature of film forming, promotes film forming.
In a detailed description of the invention, described HASE hydrophobic dispersants auxiliary agent is the HASE hydrophobic dispersants auxiliary agent of the commodity DOWMSR3175 by name of DOW Chemical；HASE hydrophobic dispersants auxiliary molecules amount of the present invention is low, cross-linking reaction is there is in-the OH in described HASE hydrophobic dispersants auxiliary agent with the-COOH in film forming matter, form interpenetrative network structure, enhance the stability of emulsion film internal stress closely and resistance to water erosion, nationality gives, with the close internal stress of film, migration and the infiltration that paint film can effectively stop spot, thus enhancing emulsion paint paint film stain resistance, to improving stain resistance, there is synergism.
In a detailed description of the invention, described aqueous fine oxidic polyethylene wax emulsion is a kind of or two kinds and the above mixing in the water-borne wax emulsion UN-580 of the wax emulsion WAX966 of Lubrizol company, ULINKOTE company high-quality aqueous polyethylene wax emulsion W19, outstanding benefactor department；Aqueous spot is had obvious antifouling effect by aqueous of the present invention fine oxidic polyethylene wax emulsion.
In a detailed description of the invention, described fluorine-containing surfactant is at least one in fluorine auxiliary agent FS-61, FS-81 of Dupont company；Fluorine-containing surfactant of the present invention can reduce coating surface tension force, has the performance that the resistance oil repellent dirt of excellence stains, and to improving, paint film oleophobic effects is obvious.
Heretofore described antifungus agent and preservative are not specifically limited, as long as not producing to limit to the goal of the invention of the present invention；In a detailed description of the invention, the consumption of antifungus agent is 0～1 weight portion, it is preferable that 0.1～1 weight portion, more preferably 0.4 ± 0.1 part；In a detailed description of the invention, the consumption of preservative is 0～1 weight portion, it is preferable that 0.1～1 weight portion, more preferably 0.15 ± 0.05 part.
In the present invention, " water of acceptable amount " refers to that described water is primarily used to as disperse medium, and its consumption is not specifically limited, and enough formula systems are uniformly dispersed, and meets required viscosity.
Another object of the present invention is to the preparation method that described water-based paint compositions is provided, for realizing this purpose, the technical scheme that the present invention takes: the preparation method of a kind of water-based paint compositions, comprise the following steps:
(1) water being put into dispersion tank, rotating speed controls at 300～500 revs/min；
(2) then successively defoamer, HASE hydrophobic dispersants auxiliary agent are joined in dispersion tank, stir 3 ± 1 minutes；
(3) color stuffing is added in dispersion tank, improve rotating speed to 1200～1800 revs/min, high speed dispersion 15 ± 3 minutes；
(4) drop rotating speed after high speed dispersion to 600～800 revs/min, add water, stir 3 ± 1 minutes；
(5) it is slowly added to film forming matter, stirs 5 ± 2 minutes；
(6) it is subsequently added into cosolvent and coalescents, stirs 3 ± 1 minutes；
(7) sequentially add antifungus agent and preservative, stir 3 ± 1 minutes；
(8) it is slowly added to the fine oxidic polyethylene wax emulsion of aqueous, stirs 3 ± 1 minutes；
(9) add fluorine-containing surfactant, stir 3 ± 1 minutes；
(10) it is subsequently adding pH adjusting agent, pH value is adjusted to 8-10；
(11) it is eventually adding water and regulates viscosity, obtain described coating composition.
The beneficial effects of the present invention is: the invention provides a kind of water-based paint compositions, this coating composition adds the AA emulsion film forming matter with the special anti-soil factor, add the aqueous fine oxidic polyethylene wax emulsion that aqueous spot is had obvious antifouling effect and oil-dirt is had two kinds of specific function auxiliary agents of fluorine-containing surfactant of obvious antifouling effect, the double; two thin effect of coating lacquer film water oil formed is better, the double; two thin high anti-soil product of water oil is favorably improved the quality of interior wall coating product, opens up the application made new advances simultaneously.The requirement of high-environmental adds high-quality anti-soil feature, and making this product can be better indoor decoration decoration market service.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is expanded on further.Should be understood that these embodiments are merely to illustrate the present invention rather than restriction the scope of the present invention.The experimental technique of unreceipted actual conditions in the following example, generally measures according to national standard.If there is no corresponding national standard, then according to general international standard, normal condition or according to manufacturer it is proposed that condition carry out.Unless otherwise indicated, otherwise all of number is weight portion, and all of percentage ratio is weight percentage, and described polymer molecular weight is number-average molecular weight.
Unless otherwise defined or described herein, the same meaning that all specialties used herein are familiar with scientific words and those skilled in the art.In addition any method similar or impartial to described content and material all can be applicable in the inventive method.
Embodiment 1
A kind of embodiment of water-based paint compositions of the present invention, water-based paint compositions described in the present embodiment includes the component of following parts by weight:
The preparation method of water-based paint compositions described in the present embodiment, comprises the following steps:
(1) water being put into dispersion tank, rotating speed controls at 400 revs/min；
(2) then successively defoamer, HASE hydrophobic dispersants auxiliary agent are joined in dispersion tank, stir 3 minutes；
(3) color stuffing is added in dispersion tank, improve rotating speed to 1200 revs/min, high speed dispersion 12 minutes；
(4) drop rotating speed after high speed dispersion to 600 revs/min, add water, stir 4 minutes；
(5) it is slowly added to film forming matter, stirs 3 minutes；
(6) it is subsequently added into cosolvent and coalescents, stirs 3 minutes；
(7) sequentially add antifungus agent and preservative, stir 2 minutes；
(8) it is slowly added to the fine oxidic polyethylene wax emulsion of aqueous, stirs 3 minutes；
(9) add fluorine-containing surfactant, stir 4 minutes；
(10) it is subsequently adding pH adjusting agent, pH value is adjusted to 8-10；
(11) it is eventually adding water and regulates viscosity, obtain described coating composition.
Embodiment 2
A kind of embodiment of water-based paint compositions of the present invention, water-based paint compositions described in the present embodiment includes the component of following parts by weight:
The preparation method of water-based paint compositions described in the present embodiment, comprises the following steps:
(1) water being put into dispersion tank, rotating speed controls at 300 revs/min；
(2) then successively defoamer, HASE hydrophobic dispersants auxiliary agent are joined in dispersion tank, stir 2 minutes；
(3) color stuffing is added in dispersion tank, improve rotating speed to 1600 revs/min, high speed dispersion 15 minutes；
(4) drop rotating speed after high speed dispersion to 800 revs/min, add water, stir 2 minutes；
(5) it is slowly added to film forming matter, stirs 5 minutes；
(6) it is subsequently added into cosolvent and coalescents, stirs 2 minutes；
(7) sequentially add antifungus agent and preservative, stir 3 minutes；
(8) it is slowly added to the fine oxidic polyethylene wax emulsion of aqueous, stirs 2 minutes；
(9) add fluorine-containing surfactant, stir 2 minutes；
(10) it is subsequently adding pH adjusting agent, pH value is adjusted to 8-10；
(11) it is eventually adding water and regulates viscosity, obtain described coating composition.
Embodiment 3
A kind of embodiment of water-based paint compositions of the present invention, water-based paint compositions described in the present embodiment includes the component of following parts by weight:
The preparation method of water-based paint compositions described in the present embodiment, comprises the following steps:
(1) water being put into dispersion tank, rotating speed controls at 500 revs/min；
(2) then successively defoamer, HASE hydrophobic dispersants auxiliary agent are joined in dispersion tank, stir 4 minutes；
(3) color stuffing is added in dispersion tank, improve rotating speed to 1800 revs/min, high speed dispersion 18 minutes；
(4) drop rotating speed after high speed dispersion to 700 revs/min, add water, stir 3 minutes；
(5) it is slowly added to film forming matter, stirs 7 minutes；
(6) it is subsequently added into cosolvent and coalescents, stirs 4 minutes；
(7) sequentially add antifungus agent and preservative, stir 4 minutes；
(8) it is slowly added to the fine oxidic polyethylene wax emulsion of aqueous, stirs 4 minutes；
(9) add fluorine-containing surfactant, stir 3 minutes；
(10) it is subsequently adding pH adjusting agent, pH value is adjusted to 8-10；
(11) it is eventually adding water and regulates viscosity, obtain described coating composition.
Embodiment 4
A kind of embodiment of water-based paint compositions of the present invention, water-based paint compositions described in the present embodiment includes the component of following parts by weight:
The preparation method of water-based paint compositions described in the present embodiment, comprises the following steps:
(1) water being put into dispersion tank, rotating speed controls at 350 revs/min；
(2) then successively defoamer, HASE hydrophobic dispersants auxiliary agent are joined in dispersion tank, stir 2 minutes；
(3) color stuffing is added in dispersion tank, improve rotating speed to 1400 revs/min, high speed dispersion 14 minutes；
(4) drop rotating speed after high speed dispersion to 800 revs/min, add water, stir 3 minutes；
(5) it is slowly added to film forming matter, stirs 5 minutes；
(6) it is subsequently added into cosolvent and coalescents, stirs 2 minutes；
(7) sequentially add antifungus agent and preservative, stir 3 minutes；
(8) it is slowly added to the fine oxidic polyethylene wax emulsion of aqueous, stirs 2 minutes；
(9) add fluorine-containing surfactant, stir 2 minutes；
(10) it is subsequently adding pH adjusting agent, pH value is adjusted to 8-10；
(11) it is eventually adding water and regulates viscosity, obtain described coating composition.
Embodiment 5
The spot-resistant of product embodiments 1～4 of the present invention, water-fast, alkaline-resisting, the full performance such as adhesive force, scrubbing resistance are tested, and wherein main performance test is with reference to GB/T9756-2009 interior wall coating national standard and GB/T9780-2013 building coating coating stain resistant test method national standard.Test result is in Table 1 and table 2
Table 1 performance test 1
| Inspection project name | Unit | Technology requirement | Assay |
| Condition in container | / | Without lump, in all there being state after stirring | Meet |
| Application property | / | Brush two roads accessible | Meet |
| Resistance to water | / | 48h is without exception | Meet |
| Alkali resistance | / | 48h is without exception | Meet |
| Scrub resistance | Secondary | ≥1000 | By 20000 |
| Efflorescence | Level | ≤1 | 0 |
| Variable color | Level | ≤2 | 0 |
| Freeze-thaw stability | / | 3 circulations are without exception | Meet |
| Adhesive force | Level | ≤ 1 grade | 0 grade |
Table 2 performance test 2
By above-mentioned table 1, product of the present invention is carried out the full performance tests such as water-fast, alkaline-resisting, adhesive force, scrubbing resistance and table 2 product spot-resistant of the present invention test data result is shown: the high-dirt-resistance water paint excellent performance of the present invention, antifouling effect is excellent, is the double; two high-dirt-resistance energy water paint dredged of a kind of water oil.
Finally be should be noted that; above example is only in order to illustrate technical scheme but not limiting the scope of the invention; although the present invention being explained in detail with reference to preferred embodiment; it will be understood by those within the art that; technical scheme can be modified or equivalent replacement, without deviating from the spirit and scope of technical solution of the present invention.
Claims (7)
1. a water-based paint compositions, it is characterized in that, component including following parts by weight: film forming matter 30～50 weight portion, color stuffing 26～40 weight portion, HASE hydrophobic dispersants auxiliary agent 0.3～0.5 weight portion, aqueous fine oxidic polyethylene wax emulsion 1.0～2.0 weight portion, fluorine-containing surfactant 0.3～1.0 weight portion, cosolvent 1.0～2.0 weight portion, coalescents 1.0～2.0 weight portion, other auxiliary agent 2.0～3.0 weight portions, and the water of acceptable amount；
The pigment volume concentration (PVC) of described water-based paint compositions is 30～50%；
Mean diameter≤0.1 μm of the fine oxidic polyethylene wax emulsion of described aqueous；
Described film forming matter is AA emulsion, described AA emulsion particle size distribution is 150～240nm, described AA emulsion vitrification point Tg is 18～26 DEG C, and described AA emulsion minimum film formation temperature MFFT is 9～15 DEG C.
2. water-based paint compositions as claimed in claim 1, it is characterized in that, other auxiliary agents described comprise the component of following weight portion: defoamer 0.15-0.30 weight portion, thickening agent 1.2-2.0 weight portion, pH adjusting agent 0.05-0.10 weight portion, antifungus agent 0.3～0.5 weight portion, preservative 0.1～0.2 weight portion.
3. water-based paint compositions as claimed in claim 2, it is characterized in that, described defoamer is at least one in silicone based defoamer, mineral oil defoaming agent, described thickening agent is at least one in polyurethanes rheology control agent, inorganic bentonite, and described pH adjusting agent is organic alcohol amine pH adjusting agent.
4. water-based paint compositions as claimed in claim 3, it is characterized in that, described defoamer is the combination of silicone based defoamer and mineral oil defoaming agent, and in described defoamer, the mass ratio of silicone based defoamer and mineral oil defoaming agent is silicone based defoamer: mineral oil defoaming agent=1:1 or silicone based defoamer: mineral oil defoaming agent=1.5:1.0.
5. water-based paint compositions as claimed in claim 1, it is characterized in that, in described color stuffing, pigment is Rutile type titanium dioxide, and in described color stuffing, filler is at least one in wollastonite, mica powder, Pulvis Talci, calcined kaolin, nepheline powder, blanc fixe, triple superphosphate.
6. water-based paint compositions as claimed in claim 1, it is characterised in that described cosolvent is glycols cosolvent, and described coalescents is alkoxide solvent.
7. the preparation method of water-based paint compositions as described in claim 1 or 5 or 6, it is characterised in that comprise the following steps:
(1) water being put into dispersion tank, rotating speed controls at 300～500 revs/min；
(2) then successively defoamer, HASE hydrophobic dispersants auxiliary agent are joined in dispersion tank, stir 3 ± 1 minutes；
(3) color stuffing is added in dispersion tank, improve rotating speed to 1200～1800 revs/min, high speed dispersion 15 ± 3 minutes；
(4) drop rotating speed after high speed dispersion to 600～800 revs/min, add water, stir 3 ± 1 minutes；
(5) it is slowly added to film forming matter, stirs 5 ± 2 minutes；
(6) it is subsequently added into cosolvent and coalescents, stirs 3 ± 1 minutes；
(7) sequentially add antifungus agent and preservative, stir 3 ± 1 minutes；
(8) it is slowly added to the fine oxidic polyethylene wax emulsion of aqueous, stirs 3 ± 1 minutes；
(9) add fluorine-containing surfactant, stir 3 ± 1 minutes；
(10) it is subsequently adding pH adjusting agent, pH value is adjusted to 8-10；
(11) it is eventually adding water and regulates viscosity, obtain described coating composition.
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| CN113088143B (en) * | 2019-12-23 | 2022-03-29 | 立邦涂料（中国）有限公司 | High-density low-water-permeability water-based outer wall polymer coating material and preparation method thereof |
| CN112111203A (en) * | 2020-09-18 | 2020-12-22 | 邓健 | Water-based paint composition |
| CN116426200A (en) * | 2023-04-28 | 2023-07-14 | 广东坚派新材料有限公司 | Waterproof finish paint for outer wall and preparation method thereof |
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