CN104446251A - Adhesion agent as well as preparation method and application thereof - Google Patents

Adhesion agent as well as preparation method and application thereof Download PDF

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Publication number
CN104446251A
CN104446251A CN201410705490.5A CN201410705490A CN104446251A CN 104446251 A CN104446251 A CN 104446251A CN 201410705490 A CN201410705490 A CN 201410705490A CN 104446251 A CN104446251 A CN 104446251A
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China
Prior art keywords
component
binding agent
water
weight
agent according
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CN201410705490.5A
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Chinese (zh)
Inventor
严兴李
孙敏
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Long Build Energy Saving Technology (tianjin) Co Ltd
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Long Build Energy Saving Technology (tianjin) Co Ltd
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Priority to CN201410705490.5A priority Critical patent/CN104446251A/en
Publication of CN104446251A publication Critical patent/CN104446251A/en
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Abstract

The invention provides an adhesion agent as well as a preparation method and application thereof, and relates to the technical field of building materials. Raw material components of the adhesion agent comprise a first component and a second component, wherein the first component comprises raw materials in percentage by weight: 30-42% of Portland cement, 50-60% of washed sand, 4-10% of stuffing and 0.2-0.6% of additives; the second component comprises raw materials in percentage by weight: 17-35% of polymer emulsion, 0.1-0.5% of water-based defoamer, 0.1-0.5% of corrosion remover, 0-0.2% of dispersing agents and 64-82% of water. The adhesion agent has the advantages of high adhesive strength, good water resistance, good heat resistance, good weather resistance, good vertical-flowing resistance, good anti-sliding performance, low cost and the like.

Description

Binding agent and its preparation method and application
Technical field
The present invention relates to building material technical field, in particular to a kind of binding agent and its preparation method and application.
Background technology
The ceramic tile bond of dry powder is all kinds face brick in multiple place and the most frequently used binding agents of stickup of stone material such as current metope, ground, indoor, outdoor.One of its main binding composition is re-dispersible glue powder, and re-dispersible glue powder processes by polymer emulsion is spray-dried.But due to the restriction of production technique, destroy the structure of polymer molecular chain after spraying dry, thus make the long molecular chain of emulsion become the short molecular chain structure of solid-state powdery, this process is irreversible.So dry powder ceramic tile bond greatly reduces in cracking resistance, water resistance.
And due to kind and the quality develop rapidly of facing tile and materials for wall now, the water-intake rate of facing tile is lower, size is larger, paste basic unit and position harsher.The ceramic tile bond of dry powder cannot meet the demand in market, and the phenomenon generation cause a lot of tile paste hollowing, coming off, even leads to tragedy.
For these reasons, need a kind of cohesive strength of exploitation high, good combination property, adaptable pair of component ceramic tile bond badly, to meet the requirement of Modern Decorative finishing, improve the living environment of people.
In view of this, special proposition the present invention.
Summary of the invention
 
The first object of the present invention is to provide a kind of binding agent, and described binding agent has high, the excellent water tolerance of cohesive strength, thermotolerance, weathering resistance, anti-stream and resistant slide ability, the low cost and other advantages of hanging down.The second object of the present invention is to provide a kind of preparation method of described binding agent, and the method is simple to operate, be easy to the advantages such as realization.
In order to realize above-mentioned purpose of the present invention, spy by the following technical solutions:
The invention provides a kind of binding agent, comprise the first component and the second component;
Wherein, in described first component, according to percent by weight, its constitutive material comprises:
In described second component, according to percent by weight, its constitutive material comprises:
This binding agent provided by the invention is dual-component binder, and wherein, the first component is solid material; Second component is liquid material.In the process used, the second component is slowly joined in the first component, stirs into agranular rubber cement; Place to stir again for 5 ~ 10 minutes and once can use afterwards.Owing to containing the effective constituents such as polymerized emulsion in the second component, it has long molecular chain structure, and its cracking resistance, bonding strength and water resistance are all better than loose rubber powder in prior art; The polymkeric substance formed after it mixes with silicate cement, washed-out sand and filler etc. is continuous state, thus makes this polymkeric substance be provided with flexibility, and with good perviousness.By detection validation, this dual-component binder provided by the invention, it has very high bonding strength (detected result is far above technical indicator); In addition, it also has excellent water tolerance, thermotolerance, weathering resistance, anti-stream and resistant slide ability, the low cost and other advantages of hanging down; The requirement of Modern Decorative finishing can be met, the phenomenon generation effectively can prevent tile paste hollowing, coming off.
Optionally, in described first component: described silicate cement is the ordinary Portland cement of label 42.5 grades.
Optionally, in described first component: it is 40-70 order and 70-140 object mixed sand that described washed-out sand comprises particle diameter.
Optionally, in described first component: described filler be dicalcium powder, breeze, flyash, stone flour one or more.
Optionally, in described first component: described admixture is one or more in water-holding agent, resistant slide agent, hardening accelerator.
Optionally, in described second component: described polymer emulsion comprise in ACRYLIC EMULSION, benzene emulsion, styrene-butadiene emulsion one or more.
A preparation method for described binding agent, comprises the following steps:
1), by stirring and evenly mixing after the silicate cement of set weight, washed-out sand, filler, admixture mixing, the first component is obtained;
2), in water, add the sanitas of set weight, add stirring and evenly mixing after the polymer emulsion of set weight, dispersion agent and water-based defoamer after mixing more successively, obtain the second component.
Optionally, in step 1) in: the time of described stirring is: 8-12 minute.
Optionally, in step 2) in: the time of described stirring is 28-32 minute.
Described binding agent is for the application in the metope that bonds, ground, indoor, outdoor face brick and stone material.
Compared with prior art, beneficial effect of the present invention is:
(1), binding agent of the present invention is flexible adhesion agent, can offset and absorption portion deformation stress thus avoid ceramic tile to peel off.
(2), binding agent of the present invention has suitable time of coagulation, is well positioned to meet the requirement of paving and adjustment, easy combing striped, and also has well anti-stream and the resistant slide ability of hanging down, and has good workability.
(3), the present invention is applicable to the stickup of multiple substrate surface, as being applicable to all kinds face brick in multiple place and the stickups of stone material such as metope, ground, indoor, outdoor, and there is superpower cohesive force, excellent water tolerance, thermotolerance, weathering resistance.
(4), nontoxic pollution-free of the present invention, environmental protection, cost be low, and preparation method is simple to operation.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below.
Fig. 1 is the preparation method's schema that the invention provides binding agent.
Embodiment
Below in conjunction with embodiment, embodiment of the present invention are described in detail, but it will be understood to those of skill in the art that the following example only for illustration of the present invention, and should not be considered as limiting the scope of the invention.Unreceipted actual conditions person in embodiment, the condition of conveniently conditioned disjunction manufacturers suggestion is carried out.Agents useful for same or the unreceipted production firm person of instrument, be and can buy by commercially available the conventional products obtained.
The invention provides a kind of binding agent, comprise the first component and the second component; Wherein, in the first component, according to percent by weight, its constitutive material comprises:
In the second component, according to percent by weight, its constitutive material comprises:
In addition, in order to make the adhesive property of binding agent more excellent, or be easier to form polymkeric substance after the mixing of two components; Or the first component can fully be mixed, there is less granularity; Or water conservation, the resistant slide performance in order to increase whole binding agent; Or in order to make binding agent have suitable time of coagulation, the anti-effects such as stream of hanging down.
On the basis of foregoing, can also increase with the next item down or whole restrictions: as, preferably, in the first component: silicate cement is the normal silicate of label 42.5 grades; It is 40-70 order and 70-140 object mixed sand that washed-out sand comprises particle diameter; Filler be dicalcium powder, breeze, flyash, stone flour one or more; Admixture is one or more in water-holding agent, resistant slide agent, hardening accelerator; Or in the second component: polymer emulsion comprise in ACRYLIC EMULSION, benzene emulsion, styrene-butadiene emulsion one or more.
This binding agent provided by the invention, it has very high bonding strength, and detected result is far above technical indicator.In addition, it also has excellent water tolerance, thermotolerance, weathering resistance, anti-stream and resistant slide ability, the low cost and other advantages of hanging down; The requirement of Modern Decorative finishing can be met, the phenomenon generation effectively can prevent tile paste hollowing, coming off.
Please refer to Fig. 1, the preparation method of the above-mentioned binding agent that the present invention also provides, comprises the following steps:
Step 101: by stirring and evenly mixing after the silicate cement of set weight, washed-out sand, filler, admixture mixing, obtain the first component.
In step 101, in order to make each material component to mix, preferred churning time is 8-12 minute, and completes stirring operation in stirrer.
Step 102: the sanitas adding set weight in water, adds stirring and evenly mixing after the polymer emulsion of set weight, dispersion agent and water-based defoamer more successively, obtains the second component after mixing.
In a step 102, in order to make sanitas mix fully with water, preferably, after being joined water, stir 2 minutes, and then add polymer emulsion, dispersion agent (optional) and water-based defoamer successively, and stirring at low speed 28-32 minute.After obtaining the first component and the second component, separately preserve.During use, by the second component liquid material according to the weight ratio of 1:4 join the first component admittedly expect in (namely the weight of the first component is 4 times of the second component weight), be uniformly mixed rear leave standstill can use after several minutes.
Next, in conjunction with above content, following specific embodiment has been enumerated to binding agent of the present invention and preparation method:
Embodiment 1
The binding agent that the embodiment of the present invention provides, in the first component, according to percent by weight, its constitutive material comprises: silicate cement 30%; Washed-out sand 60%; Filler 9.4%; Admixture 0.6%;
In the second component, according to percent by weight, its constitutive material comprises: ACRYLIC EMULSION 17%; Water-based defoamer 0.5%; Sanitas 0.5%; Water 82%.
Wherein, washed-out sand is particle diameter is 40-70 order and 70-140 object mixed sand; The dicalcium powder of the weight ratios such as filler is and breeze; The water-holding agent of the weight ratios such as admixture is, resistant slide agent and hardening accelerator.
Preparation method
S11: stir after the silicate cement of set weight, washed-out sand, filler, admixture mixing 8 minutes, obtain the first component;
S12: the sanitas adding set weight in water, stirs 28 minutes after stirring the ACRYLIC EMULSION and water-based defoamer adding set weight after 2 minutes more successively, obtains the second component.
Embodiment 2
The binding agent that the embodiment of the present invention provides, in the first component, according to percent by weight, its constitutive material comprises: silicate cement 42%; Washed-out sand 50%; Filler 7.8%; Admixture 0.2%;
In the second component, according to percent by weight, its constitutive material comprises: styrene-butadiene emulsion 35%; Water-based defoamer 0.4%; Sanitas 0.4%; Dispersion agent 0.2%; Water 64%.
Wherein, washed-out sand is particle diameter is 40-70 order and 70-140 object mixed sand; The flyash of the weight ratios such as filler is and stone flour; The water-holding agent of the weight ratios such as admixture is, resistant slide agent and hardening accelerator.
Preparation method
S21: stir after the silicate cement of set weight, washed-out sand, filler, admixture mixing 10 minutes, obtain the first component;
S22: the sanitas adding set weight in water, stirs 30 minutes after stirring styrene-butadiene emulsion, dispersion agent and the water-based defoamer adding set weight after 2 minutes more successively, obtains the second component.
Embodiment 3
The binding agent that the embodiment of the present invention provides, in the first component, according to percent by weight, its constitutive material comprises: silicate cement 40%; Washed-out sand 55.6%; Filler 4%; Admixture 0.4%;
In the second component, according to percent by weight, its constitutive material comprises: benzene emulsion 30%; Water-based defoamer 0.1%; Sanitas 0.1%; Dispersion agent 0.2%; Water 69.6%.
Wherein, washed-out sand is particle diameter is 40-70 order and 70-140 object mixed sand; The dicalcium powder of the weight ratios such as filler is and breeze; The water-holding agent of the weight ratios such as admixture is, resistant slide agent and hardening accelerator.
Preparation method
S31: stir after the silicate cement of set weight, washed-out sand, filler, admixture mixing 10 minutes, obtain the first component;
S32: the sanitas adding set weight in water, stirs 30 minutes after stirring benzene emulsion, dispersion agent and the water-based defoamer adding set weight after 2 minutes more successively, obtains the second component.
Embodiment 4
The binding agent that the embodiment of the present invention provides, in the first component, according to percent by weight, its constitutive material comprises: silicate cement 35%; Washed-out sand 57.7%; Filler 7%; Admixture 0.3%;
In the second component, according to percent by weight, its constitutive material comprises: ACRYLIC EMULSION 25%; Water-based defoamer 0.2%; Sanitas 0.2%; Water 74.6%.
Wherein, washed-out sand is particle diameter is 40-70 order and 70-140 object mixed sand; The dicalcium powder of the weight ratios such as filler is, breeze, flyash and stone flour; The water-holding agent of the weight ratios such as admixture is, resistant slide agent and hardening accelerator.
Preparation method
S41: stir after the silicate cement of set weight, washed-out sand, filler, admixture mixing 10 minutes, obtain the first component;
S42: the sanitas adding set weight in water, stirs 30 minutes after stirring the ACRYLIC EMULSION and water-based defoamer adding set weight after 2 minutes more successively, obtains the second component.
Embodiment 5
The binding agent that the embodiment of the present invention provides, in the first component, according to percent by weight, its constitutive material comprises: silicate cement 40%; Washed-out sand 54.5%; Filler 5%; Admixture 0.5%;
In the second component, according to percent by weight, its constitutive material comprises: styrene-butadiene emulsion 25%; Water-based defoamer 0.1%; Sanitas 0.2%; Dispersion agent 0.1%; Water 74.6%.
Wherein, washed-out sand is particle diameter is 40-70 order and 70-140 object mixed sand; The dicalcium powder of the weight ratios such as filler is, breeze, flyash and stone flour; The water-holding agent of the weight ratios such as admixture is, resistant slide agent and hardening accelerator.
Preparation method
S51: stir after the silicate cement of set weight, washed-out sand, filler, admixture mixing 10 minutes, obtain the first component;
S52: the sanitas adding set weight in water, stirs 30 minutes after stirring styrene-butadiene emulsion, dispersion agent and the water-based defoamer adding set weight after 2 minutes more successively, obtains the second component.
Embodiment 6
The binding agent that the embodiment of the present invention provides, in the first component, according to percent by weight, its constitutive material comprises: silicate cement 37.7%; Washed-out sand 55.5%; Filler 7%; Admixture 0.3%; ;
In the second component, according to percent by weight, its constitutive material comprises: benzene emulsion 20%; Water-based defoamer 0.2%; Sanitas 0.2%; Water 79.6%.
Wherein, washed-out sand is particle diameter is 40-70 order and 70-140 object mixed sand; The dicalcium powder of the weight ratios such as filler is, breeze, flyash and stone flour; The water-holding agent of the weight ratios such as admixture is, resistant slide agent and hardening accelerator.
Preparation method
S61: stir after the silicate cement of set weight, washed-out sand, filler, admixture mixing 10 minutes, obtain the first component;
S62: the sanitas adding set weight in water, stirs 30 minutes after stirring the benzene emulsion and water-based defoamer adding set weight after 2 minutes more successively, obtains the second component.
In addition, the performance test results of binding agent that provides of various embodiments of the present invention as shown in Table 1 and Table 2.
The performance test results of the binding agent that table 1 embodiment of the present invention 1-3 provides
The performance test results of the binding agent that table 2 embodiment of the present invention 4-6 provides
Can be found out by table 1 and table 2, this dual-component binder provided by the invention, it has very high bonding strength, and its every detected result is far above technical indicator.It also has excellent water tolerance, thermotolerance, weathering resistance, anti-stream and the resistant slide ability of hanging down; The requirement of Modern Decorative finishing can be met, the phenomenon generation effectively can prevent tile paste hollowing, coming off.
In addition, dual-component binder provided by the invention, it is as follows with the concrete using method in the application in stone material for the metope that bonds, ground, indoor, outdoor face brick:
(1), by blending ratio the second component liquid material poured in bucket and slowly add the first component powder again, stir into even agranular rubber cement with electric mixer, place and stir again once for 5 ~ 10 minutes, can use.
(2), with flute profile spatula straight line while a small amount of binding agent is firmly scraped the ceramic tile back side (filling up groove to be as the criterion), appropriate binding agent is coated on construction bottom surface, and be 60 ° ~ 70 ° with suitable profile of tooth spatula, direction is linearly carded to full strip, then being rubbed by ceramic tile is pressed on working face, to guarantee adhere and adjust to appropriate position comprehensively.
(3), the binding agent that stirs should be finished in 4 hours, and per half an hour stirs once, and make it keep good operability, the binding agent solidified prohibits the use.
(4) ceramic tile (or stone material), posted can not move after 15 minutes again, after the binding agent need removing the ceramic tile back side and construction surface, again pastes with binding agent as adjusted again.
(5), the slurry that solidifies is difficult to remove, instrument with after, should clean up with water as early as possible.
Although illustrate and describe the present invention with specific embodiment, however it will be appreciated that can to make when not deviating from the spirit and scope of the present invention many other change and amendment.Therefore, this means to comprise all such changes and modifications belonged in the scope of the invention in the following claims.

Claims (10)

1. a binding agent, is characterized in that, comprises the first component and the second component:
Wherein, in described first component, according to percent by weight, its constitutive material comprises:
In described second component, according to percent by weight, its constitutive material comprises:
2. binding agent according to claim 1, is characterized in that, in described first component:
Described silicate cement is the ordinary Portland cement of label 42.5 grades.
3. binding agent according to claim 1, is characterized in that, in described first component:
It is 40-70 order and 70-140 object mixed sand that described washed-out sand comprises particle diameter.
4. the binding agent according to any one of claim 1-3, is characterized in that, in described first component:
Described filler be dicalcium powder, breeze, flyash, stone flour one or more.
5. binding agent according to claim 4, is characterized in that, in described first component:
Described admixture is one or more in water-holding agent, resistant slide agent, hardening accelerator.
6. binding agent according to claim 5, is characterized in that, in described second component:
Described polymer emulsion comprise in ACRYLIC EMULSION, benzene emulsion, styrene-butadiene emulsion one or more.
7. a preparation method for the binding agent according to any one of claim 1-6, is characterized in that, comprises the following steps:
1), by stirring and evenly mixing after the silicate cement of set weight, washed-out sand, filler, admixture mixing, the first component is obtained;
2), in water, add the sanitas of set weight, add stirring and evenly mixing after the polymer emulsion of set weight, dispersion agent and water-based defoamer after mixing more successively, obtain the second component.
8. the preparation method of binding agent according to claim 7, is characterized in that, in step 1) in:
The time of described stirring is: 8-12 minute.
9. the preparation method of binding agent according to claim 8, is characterized in that, in step 2) in:
The time of described stirring is 28-32 minute.
10. the binding agent described in any one of claim 1-6 is for the application in the metope that bonds, ground, indoor, outdoor face brick and stone material.
CN201410705490.5A 2014-11-27 2014-11-27 Adhesion agent as well as preparation method and application thereof Pending CN104446251A (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104973835A (en) * 2015-07-03 2015-10-14 上海力阳道路加固科技股份有限公司 Modified cement mortar for concrete repair and preparation method thereof
CN105349070A (en) * 2015-09-30 2016-02-24 广州雷邦仕化工建材有限公司 Ceramic tile sticking anti-falling reinforcing agent
CN105645860A (en) * 2015-12-29 2016-06-08 舜坦(上海)新材料有限公司 Flexible tile adhesive
CN105778832A (en) * 2016-03-10 2016-07-20 程小妹 Emulsion-type acrylate adhesive and manufacturing method thereof
CN105777027A (en) * 2016-03-31 2016-07-20 济南维高建材技术有限公司 Early strength two-component polymer emulsion modified cement tile binder and using method thereof
CN106116693A (en) * 2016-06-20 2016-11-16 广州番禺职业技术学院 A kind of high-strength interfacial agents of composite polymer emulsion being applicable to vitrified tile and preparation
CN106380125A (en) * 2015-07-30 2017-02-08 蒋其同 Two-component ceramic tile adhesive
CN107555910A (en) * 2017-09-29 2018-01-09 佛山市涂无忧建材有限公司 A kind of adhesion strength height and patch block gum of resistant slide and preparation method thereof
CN107602014A (en) * 2017-09-29 2018-01-19 佛山市涂无忧建材有限公司 A kind of waterproof coating material of cement based polymer and preparation method thereof
CN107651895A (en) * 2017-10-03 2018-02-02 江苏联禹智能工程有限公司 A kind of building intellectualization installs decorative engineering ceramic tile adhesive
CN107954637A (en) * 2017-12-20 2018-04-24 安徽力峰建材科技有限公司 A kind of ceramic tile marble binding agent of superpower water resistance
CN108658495A (en) * 2017-08-08 2018-10-16 苏州金螳螂建筑装饰股份有限公司 Bond reinforcing agent and preparation method thereof and binding material and its construction method
CN109265069A (en) * 2018-11-09 2019-01-25 广西里尔新材料有限公司 A kind of ceramic tile adhesive glue
CN109970413A (en) * 2019-04-10 2019-07-05 江苏霖生美家园艺有限公司 A kind of gardens solid waste environmentally friendly binder and preparation method thereof
CN113307588A (en) * 2021-06-25 2021-08-27 广州市凯聚新材料有限公司 Paste-like flexible ceramic tile binder and preparation method thereof
CN115557747A (en) * 2022-09-26 2023-01-03 苏州金螳螂建筑装饰股份有限公司 Double-component bonding material and preparation method and construction method thereof

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CN102674772A (en) * 2012-05-21 2012-09-19 张立功 Preparation method, products and construction method for renovation putties for surfaces of old ceramic tiles
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CN102515668A (en) * 2011-12-16 2012-06-27 吴江市利达上光制品有限公司 Strongly anti-falling adhesive for ceramic tile and preparation method for same
CN102674772A (en) * 2012-05-21 2012-09-19 张立功 Preparation method, products and construction method for renovation putties for surfaces of old ceramic tiles
CN103159440A (en) * 2013-02-27 2013-06-19 同济大学 Cement-based shrinkage-free wall hole-penetrating blocking material and preparation method and construction method

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Publication number Priority date Publication date Assignee Title
CN104973835A (en) * 2015-07-03 2015-10-14 上海力阳道路加固科技股份有限公司 Modified cement mortar for concrete repair and preparation method thereof
CN106380125A (en) * 2015-07-30 2017-02-08 蒋其同 Two-component ceramic tile adhesive
CN105349070B (en) * 2015-09-30 2018-02-27 广州雷邦仕化工建材有限公司 A kind of tile paste peel reinforcing agent
CN105349070A (en) * 2015-09-30 2016-02-24 广州雷邦仕化工建材有限公司 Ceramic tile sticking anti-falling reinforcing agent
CN105645860A (en) * 2015-12-29 2016-06-08 舜坦(上海)新材料有限公司 Flexible tile adhesive
CN105778832A (en) * 2016-03-10 2016-07-20 程小妹 Emulsion-type acrylate adhesive and manufacturing method thereof
CN105777027A (en) * 2016-03-31 2016-07-20 济南维高建材技术有限公司 Early strength two-component polymer emulsion modified cement tile binder and using method thereof
CN106116693A (en) * 2016-06-20 2016-11-16 广州番禺职业技术学院 A kind of high-strength interfacial agents of composite polymer emulsion being applicable to vitrified tile and preparation
CN106116693B (en) * 2016-06-20 2018-11-13 广州番禺职业技术学院 It is a kind of suitable for the high-strength interfacial agents of composite polymer lotion of vitrified tile and preparation
CN108658495A (en) * 2017-08-08 2018-10-16 苏州金螳螂建筑装饰股份有限公司 Bond reinforcing agent and preparation method thereof and binding material and its construction method
CN107602014A (en) * 2017-09-29 2018-01-19 佛山市涂无忧建材有限公司 A kind of waterproof coating material of cement based polymer and preparation method thereof
CN107555910A (en) * 2017-09-29 2018-01-09 佛山市涂无忧建材有限公司 A kind of adhesion strength height and patch block gum of resistant slide and preparation method thereof
CN107651895A (en) * 2017-10-03 2018-02-02 江苏联禹智能工程有限公司 A kind of building intellectualization installs decorative engineering ceramic tile adhesive
CN107954637A (en) * 2017-12-20 2018-04-24 安徽力峰建材科技有限公司 A kind of ceramic tile marble binding agent of superpower water resistance
CN109265069A (en) * 2018-11-09 2019-01-25 广西里尔新材料有限公司 A kind of ceramic tile adhesive glue
CN109265069B (en) * 2018-11-09 2020-05-08 广西里尔新材料有限公司 Ceramic tile adhesive
CN109970413A (en) * 2019-04-10 2019-07-05 江苏霖生美家园艺有限公司 A kind of gardens solid waste environmentally friendly binder and preparation method thereof
CN113307588A (en) * 2021-06-25 2021-08-27 广州市凯聚新材料有限公司 Paste-like flexible ceramic tile binder and preparation method thereof
CN113307588B (en) * 2021-06-25 2021-12-07 广州市凯聚新材料有限公司 Paste-like flexible ceramic tile binder and preparation method thereof
CN115557747A (en) * 2022-09-26 2023-01-03 苏州金螳螂建筑装饰股份有限公司 Double-component bonding material and preparation method and construction method thereof

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