CN104409341B - The method that Ohm contact electrode is prepared in silicon carbide substrates - Google Patents

The method that Ohm contact electrode is prepared in silicon carbide substrates Download PDF

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Publication number
CN104409341B
CN104409341B CN201410669080.XA CN201410669080A CN104409341B CN 104409341 B CN104409341 B CN 104409341B CN 201410669080 A CN201410669080 A CN 201410669080A CN 104409341 B CN104409341 B CN 104409341B
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silicon carbide
carbide substrates
contact electrode
ohm contact
film layer
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CN104409341A (en
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张永平
辛帅
戴伟忠
舒畅
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INESA ELECTRON CO Ltd
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INESA ELECTRON CO Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Electrodes Of Semiconductors (AREA)

Abstract

The present invention relates to electronic technology field, and in particular to a kind of Ohm contact electrode preparation method.The method that Ohm contact electrode is prepared in silicon carbide substrates, comprises the following steps:Step 1, the silicon carbide substrates of a setting doping concentration are prepared;Step 2, in photoetching Ohmic contact pattern in the silicon carbide substrates;Step 3, deposition film layer, to form composite construction;Step 4, Ohmic contact pattern is removed with the film layer of exterior domain to obtain Ohm contact electrode.The present invention can prepare the low-resistance Ohm contact of high quality so that carbofrax material is used to produce various power devices on a large scale and various novel sensor chips are possibly realized.

Description

The method that Ohm contact electrode is prepared in silicon carbide substrates
Technical field
The present invention relates to electronic technology field, and in particular to a kind of Ohm contact electrode preparation method.
Background technology
Carborundum has that energy gap is big, high saturated electron drift velocity, high breakdown field strength, high heat conductance and anti-spoke The ability excellent physicochemical characteristics such as strong and electrology characteristic are penetrated, in high temperature, high-frequency, high-power, radioresistance, non-volatile storage The application scenarios such as device and short-wavelength light electronic device and photoelectricity are integrated are one of preferable semi-conducting materials, are particularly suitable in pole Applied under end condition and adverse circumstances.
Although carbofrax material has very excellent property, yet with metal electrode and carbon under existing process conditions The Ohmic contact of high quality can not be obtained between SiClx semi-conducting material, constrains its large-scale application.
The content of the invention
It is an object of the present invention to provide a kind of method that Ohm contact electrode is prepared in silicon carbide substrates, more than solution Technical problem.
Technical problem solved by the invention can be realized using following technical scheme:
The method that Ohm contact electrode is prepared in silicon carbide substrates, wherein, comprise the following steps:
Step 1, the silicon carbide substrates of a setting doping concentration are prepared;
Step 2, in photoetching Ohmic contact pattern in the silicon carbide substrates;
Step 3, deposition film layer, to form composite construction;
Step 4, the Ohmic contact pattern is removed with the film layer of exterior domain to obtain Ohm contact electrode.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, the step 3 comprise the following steps that:
Step 31a, the first metal film layer is deposited in the silicon carbide substrates in an inert gas atmosphere;
Step 32a, in the second metal film layer is deposited on first metal film layer.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, the step 3 comprise the following steps that:
Step 31b, the first metal film layer is deposited in the silicon carbide substrates in an inert gas atmosphere;
Step 32b, in deposition Si layers on first metal film layer;
Step 33b, in the second metal film layer is deposited on the Si layers.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, in addition to step 5, in a design temperature bar It is heat-treated under part.
Prepare the method for Ohm contact electrode in the silicon carbide substrates of the present invention, the design temperature is 400 DEG C, 500 DEG C, 600 DEG C or 700 DEG C.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, the doping concentration of the silicon carbide substrates are 3.2×10 18cm-3
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, the silicon carbide substrates use n-type 4H- SiC substrate.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, first metal film layer is Ti layers.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, second metal film layer is Au layers.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, it is multiple in being prepared in the silicon carbide substrates The Ohm contact electrode, the spacing between the Ohm contact electrode are 50 μm, 100 μm, 150 μm, 200 μm or 250 μm.
Beneficial effect:Due to using above technical scheme, the present invention can prepare the low-resistance Ohm contact of high quality, make Carbofrax material is used to produce various power devices and various novel sensor chips are possibly realized on a large scale.
Brief description of the drawings
Fig. 1 is the method flow schematic diagram of the present invention;
Fig. 2 is a kind of schematic flow sheet of embodiment of step 3 of the present invention;
Fig. 3 is the schematic flow sheet of another embodiment of step 3 of the present invention;
I-V curves of the Fig. 4 for Au/Ti/SiC systems in the case of unannealed;
Fig. 5 is corresponding with Fig. 4 than contact position resistivity calculated curve;
Fig. 6 is the I-V curve of 600 DEG C of annealings of Au/Ti/SiC systems;
Fig. 7 is corresponding with Fig. 6 than contact position resistivity calculated curve;
Fig. 8 is I-V curve relation of the Au/Si/Ti/SiC systems in different heat treatment temperature conditionss.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art obtained on the premise of creative work is not made it is all its His embodiment, belongs to the scope of protection of the invention.
It should be noted that in the case where not conflicting, the feature in embodiment and embodiment in the present invention can phase Mutually combination.
The invention will be further described with specific embodiment below in conjunction with the accompanying drawings, but not as limiting to the invention.
Due under some extreme conditions and adverse circumstances, the performance of silicon carbide device is considerably beyond silicon (Si) device and arsenic Change gallium (GaAs), in order to capture the technological difficulties that carbofrax material substrate contacts with metal, carry out substantial amounts of research, and obtain Very big progress.But applicant has found in research process, although achievement in research can form Ohmic contact in the past, It is required for carrying out high-temperature heat treatment, this low power consuming low stain requirement advocated with current countries in the world is not inconsistent, and easily causes resource wave Take, environmental pollution and cost rise violently.
Reference picture 1, the present invention provide a kind of method that Ohm contact electrode is prepared in silicon carbide substrates, wherein, including with Lower step:
Step 1, the silicon carbide substrates of a setting doping concentration are prepared;
Step 2, in photoetching Ohmic contact pattern in silicon carbide substrates;
Step 3, deposition film layer, to form composite construction;
Step 4, Ohmic contact pattern is removed with the film layer of exterior domain to obtain Ohm contact electrode.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, a kind of specific embodiment,
Reference picture 2, the specific steps of step 3 can be as follows:
Step 31a, deposit the first metal film layer on silicon carbide substrates in an inert gas atmosphere;
Step 32a, in the second metal film layer is deposited on the first metal film layer.
The first metallic film can be deposited in high vacuum argon gas atmosphere on silicon carbide substrates using magnetically controlled sputter method Layer, photoresist cover whole first metal film layer, and Ohmic contact pattern the first metal of overlying regions is peeled off using stripping technology Photoresist in film layer, then the second metal film layer is deposited, the film layer of designated area is peeled off finally to obtain Au/ The Ohm contact electrode of Ti/SiC systems.It should be noted that:Change and film layer of the designated area according to semiconductor technology Sedimentary sequence and change, be not limited herein.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, another specific embodiment, reference picture 3, Step 3 comprises the following steps that:
Step 31b, deposit the first metal film layer on silicon carbide substrates in an inert gas atmosphere;
Step 32b, in deposition Si layers on the first metal film layer;
Step 33b, in the second metal film layer is deposited on Si layers.
Equally the first metal can be deposited in high vacuum argon gas atmosphere on silicon carbide substrates using magnetically controlled sputter method Film layer, redeposited Si layers, is then deposited the second metal film layer, is needed during step 3 according to technique to specifying area The film layer in domain is peeled off finally to obtain the Ohm contact electrode of Au/Si/Ti/SiC systems.It should be noted that:Specify Region changes according to the change of semiconductor technology and the sedimentary sequence of film layer, is not limited herein.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, the doping concentration of silicon carbide substrates is 3.2 ×1018cm-3
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, silicon carbide substrates are served as a contrast using n-type 4H-SiC Bottom.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, the first metal film layer can be Ti layers.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, the second metal film layer can be Au layers.
The method of Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, in preparing multiple ohms in silicon carbide substrates Electrode is contacted, the spacing range between Ohm contact electrode is 50 μm to 250 μm.
Prepare the method for Ohm contact electrode in the silicon carbide substrates of the present invention, the spacing between Ohm contact electrode can be with Arranged in arithmetic progression, be 50 μm, 100 μm, 150 μm, 200 μm or 250 μm.
The method that Ohm contact electrode is prepared in the silicon carbide substrates of the present invention, can also include step 5, in a setting temperature It is heat-treated under the conditions of degree.Design temperature can be 400 DEG C or 500 DEG C or 600 DEG C or 700 DEG C.
The present invention is analyzed the performance of the Ohm contact electrode of preparation by test system, for Au/Ti/SiC bodies The Ohm contact electrode of system, shown in reference picture 4, with regard to Ohmic contact can be obtained in the case of unannealed, reference picture 5, it can calculate It is 1.26 × 10 to its ohmic contact resistance-6Ω·cm2.Further to verify influence of the rapid thermal treatment to electric property, again Heat treatment test, reference picture 6 and Fig. 7 have been carried out at different temperature, under 600 DEG C of heat treatment conditions of argon gas atmosphere, have been obtained Minimum ohmic contact resistance is 6.4 × 10-7Ω·cm2.When higher than 700 DEG C, ohm electrical properties are deteriorated;800 DEG C are quickly moved back An ohm property is just lost completely after fire processing.
For the Ohm contact electrode of Au/Si/Ti/SiC systems, reference picture 8, in the case where not carrying out heat treatment condition, equally Ohmic contact property is shown, by ohmic contact resistance is calculated as 1.18 × 10-5Ω·㎝2.With annealing temperature Rise, ohmic contact resistance are gradually reduced, and at 500 DEG C, obtain minimal-contact resistance, are 5.6 × 10-6Ω·cm2.Work as annealing Treatment temperature is higher than after 500 DEG C, and ohm contact performance is deteriorated, and laboratory sample just gradually loses after higher than 700 DEG C processing The property of Ohmic contact.
In order to probe into influence of the surface topography to ohm contact performance, using SEM SEM to sample surfaces Studied.When without heat treatment or the surface topography of Au/Ti/SiC systems all compares Au/Si/Ti/ after being heat-treated The surface of SiC systems is smooth.Smooth sample surfaces, there is very big facilitation to the performance for improving Ohmic contact.With The continuous progress of growing silicon carbice crystals technology, the large-sized carborundum crystals material of high quality are progressively applied to the biography of a new generation In the power electronic devices such as sensor, high-frequency high-power switch, and various power devices, microelectronics core will be produced by large-scale use Piece, especially in various novel sensor chip fields.The present invention can prepare the low-resistance Ohm contact of high quality so that carbon Silicon nitride material is used to produce various power devices on a large scale and various novel sensor chips are possibly realized.
Preferred embodiments of the present invention are the foregoing is only, not thereby limit embodiments of the present invention and protection model Enclose, to those skilled in the art, should can appreciate that all with made by description of the invention and diagramatic content Scheme obtained by equivalent substitution and obvious change, should be included in protection scope of the present invention.

Claims (7)

1. the method for Ohm contact electrode is prepared in silicon carbide substrates, it is characterised in that comprise the following steps:
Step 1, prepare the silicon carbide substrates of a setting doping concentration, the doping concentrations of the silicon carbide substrates for 3.2 × 1018cm-3
Step 2, in photoetching Ohmic contact pattern in the silicon carbide substrates;
Step 3, deposition film layer, to form composite construction;
Step 4, the Ohmic contact pattern is removed with the film layer of exterior domain to obtain Ohm contact electrode;
Also include step 5, be heat-treated under the conditions of a design temperature, the design temperature is 400 DEG C, 500 DEG C, 600 DEG C 700 DEG C or without heat treatment.
2. the method for Ohm contact electrode is prepared in silicon carbide substrates according to claim 1, it is characterised in that the step Rapid 3 comprise the following steps that:
Step 31a, the first metal film layer is deposited in the silicon carbide substrates in an inert gas atmosphere;
Step 32a, in the second metal film layer is deposited on first metal film layer.
3. the method for Ohm contact electrode is prepared in silicon carbide substrates according to claim 1, it is characterised in that the step Rapid 3 comprise the following steps that:
Step 31b, the first metal film layer is deposited in the silicon carbide substrates in an inert gas atmosphere;
Step 32b, in deposition Si layers on first metal film layer;
Step 33b, in the second metal film layer is deposited on the Si layers.
4. the method for Ohm contact electrode is prepared in silicon carbide substrates according to claim 1, it is characterised in that the carbon Silicon substrate uses n-type 4H-SiC substrates.
5. the method for Ohm contact electrode is prepared in the silicon carbide substrates according to Claims 2 or 3, it is characterised in that institute It is Ti layers to state the first metal film layer.
6. the method for Ohm contact electrode is prepared in the silicon carbide substrates according to Claims 2 or 3, it is characterised in that institute It is Au layers to state the second metal film layer.
7. the method for Ohm contact electrode is prepared in silicon carbide substrates according to claim 1, it is characterised in that in described Prepare multiple Ohm contact electrodes in silicon carbide substrates, the spacing between the Ohm contact electrode is 50 μm, 100 μm, 150 μm, 200 μm or 250 μm.
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Publication number Priority date Publication date Assignee Title
CN107123593A (en) * 2017-04-11 2017-09-01 山东大学 One kind mixes germanium carborundum Ohmic contact forming method
CN107369617B (en) * 2017-07-06 2019-12-24 西安交通大学 SiC high-temperature ohmic contact electrode and manufacturing method thereof
CN108899756B (en) * 2018-06-06 2020-04-28 青岛海信宽带多媒体技术有限公司 Method for depositing metal electrode

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201032635Y (en) * 2006-12-23 2008-03-05 厦门三优光机电科技开发有限公司 PIN structure 4H-SiC ultraviolet photoelectric detector
CN102859661A (en) * 2010-04-14 2013-01-02 住友电气工业株式会社 Silicon carbide semiconductor device and method for manufacturing same
CN103094073A (en) * 2013-01-17 2013-05-08 上海师范大学 Preparation method of semi-insulating silicon carbide substrate titanium ohmic contact electrode

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201032635Y (en) * 2006-12-23 2008-03-05 厦门三优光机电科技开发有限公司 PIN structure 4H-SiC ultraviolet photoelectric detector
CN102859661A (en) * 2010-04-14 2013-01-02 住友电气工业株式会社 Silicon carbide semiconductor device and method for manufacturing same
CN103094073A (en) * 2013-01-17 2013-05-08 上海师范大学 Preparation method of semi-insulating silicon carbide substrate titanium ohmic contact electrode

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