CN104327400A - Environment-friendly antistatic cable material and preparation method of cable material - Google Patents
Environment-friendly antistatic cable material and preparation method of cable material Download PDFInfo
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- CN104327400A CN104327400A CN201410596696.9A CN201410596696A CN104327400A CN 104327400 A CN104327400 A CN 104327400A CN 201410596696 A CN201410596696 A CN 201410596696A CN 104327400 A CN104327400 A CN 104327400A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/32—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
- C08L23/34—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur by chlorosulfonation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses an environment-friendly antistatic cable material. The environment-friendly antistatic cable material is prepared from the following raw materials in parts by weight: 4-7 parts of silicone, 2-3 parts of dilauryl thiodipropionate, 3-4 parts of aminopropyltriethoxysilane, 2-5 parts of ferric trichloride, 45-65 parts of chlorosulfonated polyethylene rubber, 2-3 parts of octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate, 5-6 parts of aluminium hydroxide, 4-5 parts of 2-hydroxy-4-methoxybenzophenone, 3-5 parts of benzenetricarboxylic trioctyl phosphate, 2-4 parts of tetraphenyl ethylene, 1-3 parts of a titanate coupling agent TMC-TTS, 3-6 parts of 1,6-glycol diacrylate, 6-8 parts of dicumyl peroxide, 15-25 parts of N220 carbon black and 8-12 parts of additives. The cable material has high temperature resistance and ageing resistance; the raw materials such as octadecyl dimethyl hydroxyethyl quaternary ammonium nitrate are added, so that the anti-static performance of the cable material is greatly improved; a halogen-free flame retardant is adopted, so that the cable material is free of pollution to the environment and is a novel cable material which is worthy of bwing popularized and applied.
Description
Technical field
The present invention relates to a kind of technical field of CABLE MATERIALS, particularly a kind of Environmental-friendantistatic antistatic CABLE MATERIALS and preparation method thereof.
Background technology
CABLE MATERIALS is the main application fields of insulating material, at present along with the development of the communications field, increasing to the market requirement of CABLE MATERIALS, simultaneously also more and more higher to the performance requriements of CABLE MATERIALS, as halogen-free cable material, high voltage insulation cable material, internally and externally shielded cable material etc.And the CABLE MATERIALS of domestic production is mostly common PVC CABLE MATERIALS and PE CABLE MATERIALS, not only poor in the performances such as resistance combustion, heat-resisting ageing-resisting, also there is no small pollution to environment, compromise the health of people.The present inventor devises new cable material formula for this reason, is improved the performance of CABLE MATERIALS, to meet the demand of market to high performance cable material.
Summary of the invention
The present invention compensate for the deficiencies in the prior art, provides a kind of Environmental-friendantistatic antistatic CABLE MATERIALS and preparation method thereof.
Technical scheme of the present invention is as follows:
CABLE MATERIALS of the present invention is made up of the raw material of following weight part: silicone 4-7, thio-2 acid two lauryl 2-3, aminopropyl triethoxysilane 3-4, iron trichloride 2-5, chlorosulfonated polyethylene rubber 45-65, octadecyldimethyl hydroxyethyl quaternary ammonium nitrate 2-3, aluminium hydroxide 5-6, ESCALOL 567 4-5, phosphorus benzene tricarboxylic acid three monooctyl ester 3-5, tetraphenyl ethylene 2-4, titanate coupling agent TMC-TTS 1-3,1,6-hexylene glycol double methacrylate 3-6, dicumyl peroxide 6-8, N220 carbon black 15-25, auxiliary agent 8-12;
Described auxiliary agent is made up of the raw material of following weight part: pearl powder 2-4,2-thiol group benzimidazolyl 1-3, diatom ooze 25-35, striate gypsum powder 6-10, Vaseline 5-6, tin protochloride 2-3, Silica hydrogel 2-3, pentaerythritol stearate 2-5, atlapulgite 15-20, Vanay 4-6, polyhexamethylene guanidine 3-4; Its preparation method is high-temperature calcination 2-4 hour at diatom ooze, atlapulgite mixing are placed on 500-600 DEG C, again gained calcinate is mixed with pearl powder, striate gypsum powder, tin protochloride, pentaerythritol stearate, 2-thiol group benzimidazolyl, polyhexamethylene guanidine and speed lapping 4-6 minute, gained grinding product is joined stirring to pulp 20-40 minute in the blended liquid of Silica hydrogel and Vaseline, again gained mixture is dried at 60-80 DEG C, and fine grinding powdered, cross 240-300 mesh sieve and get final product.
The concrete steps of the preparation of described CABLE MATERIALS are as follows:
(1) silicone, phosphorus benzene tricarboxylic acid three monooctyl ester, tetraphenyl ethylene, titanate coupling agent TMC-TTS, the two lauryl of thio-2 acid, aminopropyl triethoxysilane, octadecyldimethyl hydroxyethyl quaternary ammonium nitrate, ESCALOL 567 are placed in high-speed mixer and mix material, for subsequent use;
(2) chlorosulfonated polyethylene rubber is placed in the refining glue that Banbury mixer carries out 2-4 minute, after until banburying glue cooling after step 1 gained mixture is joined in Banbury mixer, prior to 50-70 DEG C of mixing 4-6 minute, again temperature is risen to 90-110 DEG C and continue mixing 4-5 minute, for subsequent use by taking out after the cooling of gained material;
(3) by aluminium hydroxide, 1,6-hexylene glycol double methacrylate, iron trichloride, dicumyl peroxide, N220 carbon black, step 2 gained material and leftover materials mix, join extruding pelletization in twin screw extruder, the screw slenderness ratio of twin screw extruder is 32:1-44:1, and rotating speed is 350-550 rev/min;
(4) step 3 gained particle is put in storage through inspection screening, packaging.
Beneficial effect of the present invention:
CABLE MATERIALS of the present invention is high temperature resistant, ageing-resistant, the interpolation of the raw materials such as octadecyldimethyl hydroxyethyl quaternary ammonium nitrate also strengthens the antistatic effect of CABLE MATERIALS greatly, the halogen-free flame retardants environmentally safe simultaneously adopted is a kind of novel cable material be worth of widely use.
The interpolation of auxiliary agent effectively can improve the performance of CABLE MATERIALS goods, the pentaerythritol stearate added can increase the thermostability of whole system, the interpolation of polyhexamethylene guanidine can increase the biocidal property of CABLE MATERIALS product, greatly strengthens the use value of final CABLE MATERIALS finished product.
Specific embodiments
Below in conjunction with following embodiment, the present invention is described in further detail:
The raw material taking following weight part (kg) is made: silicone 6, thio-2 acid two lauryl 2, aminopropyl triethoxysilane 3, iron trichloride 4, chlorosulfonated polyethylene rubber 55, octadecyldimethyl hydroxyethyl quaternary ammonium nitrate 2, aluminium hydroxide 5, ESCALOL 567 4, phosphorus benzene tricarboxylic acid three monooctyl ester 4, tetraphenyl ethylene 3, titanate coupling agent TMC-TTS 2,1,6-hexylene glycol double methacrylate 5, dicumyl peroxide 7, N220 carbon black 20, auxiliary agent 10;
Described auxiliary agent is made up of the raw material of following weight part (kg): pearl powder 3,2-thiol group benzimidazolyl 2, diatom ooze 30, striate gypsum powder 8, Vaseline 5, tin protochloride 2, Silica hydrogel 2, pentaerythritol stearate 4, atlapulgite 18, Vanay 5, polyhexamethylene guanidine 3; Its preparation method is high-temperature calcination 3 hours at diatom ooze, atlapulgite mixing are placed on 550 DEG C, again gained calcinate is mixed with pearl powder, striate gypsum powder, tin protochloride, pentaerythritol stearate, 2-thiol group benzimidazolyl, polyhexamethylene guanidine and speed lapping 5 minutes, gained grinding product to be joined in the blended liquid of Silica hydrogel and Vaseline stirring to pulp 30 minutes, again gained mixture is dried at 70 DEG C, and fine grinding powdered, cross 270 mesh sieves and get final product.
The concrete steps of the preparation of described CABLE MATERIALS are as follows:
(1) silicone, phosphorus benzene tricarboxylic acid three monooctyl ester, tetraphenyl ethylene, titanate coupling agent TMC-TTS, the two lauryl of thio-2 acid, aminopropyl triethoxysilane, octadecyldimethyl hydroxyethyl quaternary ammonium nitrate, ESCALOL 567 are placed in high-speed mixer and mix material, for subsequent use;
(2) chlorosulfonated polyethylene rubber is placed in the refining glue that Banbury mixer carries out 3 minutes, after until banburying glue cooling after step 1 gained mixture is joined in Banbury mixer, mixing prior to 60 DEG C 5 minutes, again temperature is risen to 100 DEG C to continue mixing 4 minutes, for subsequent use by taking out after the cooling of gained material;
(3) by aluminium hydroxide, 1,6-hexylene glycol double methacrylate, iron trichloride, dicumyl peroxide, N220 carbon black, step 2 gained material and leftover materials mix, join extruding pelletization in twin screw extruder, the screw slenderness ratio of twin screw extruder is 38:1, and rotating speed is 450 revs/min;
(4) step 3 gained particle is put in storage through inspection screening, packaging.
CABLE MATERIALS tensile strength of the present invention is 17.9MPa after tested, and elongation at break is 394%, oxygen index be at 34%, 200 DEG C static heat steady time be 151 minutes.
Claims (2)
1. an Environmental-friendantistatic antistatic CABLE MATERIALS, it is characterized in that, be made up of the raw material of following weight part: silicone 4-7, the two lauryl 2-3 of thio-2 acid, aminopropyl triethoxysilane 3-4, iron trichloride 2-5, chlorosulfonated polyethylene rubber 45-65, octadecyldimethyl hydroxyethyl quaternary ammonium nitrate 2-3, aluminium hydroxide 5-6, ESCALOL 567 4-5, phosphorus benzene tricarboxylic acid three monooctyl ester 3-5, tetraphenyl ethylene 2-4, titanate coupling agent TMC-TTS 1-3, 1, 6-hexylene glycol double methacrylate 3-6, dicumyl peroxide 6-8, N220 carbon black 15-25, auxiliary agent 8-12,
Described auxiliary agent is made up of the raw material of following weight part: pearl powder 2-4,2-thiol group benzimidazolyl 1-3, diatom ooze 25-35, striate gypsum powder 6-10, Vaseline 5-6, tin protochloride 2-3, Silica hydrogel 2-3, pentaerythritol stearate 2-5, atlapulgite 15-20, Vanay 4-6, polyhexamethylene guanidine 3-4; Its preparation method is high-temperature calcination 2-4 hour at diatom ooze, atlapulgite mixing are placed on 500-600 DEG C, again gained calcinate is mixed with pearl powder, striate gypsum powder, tin protochloride, pentaerythritol stearate, 2-thiol group benzimidazolyl, polyhexamethylene guanidine and speed lapping 4-6 minute, gained grinding product is joined stirring to pulp 20-40 minute in the blended liquid of Silica hydrogel and Vaseline, again gained mixture is dried at 60-80 DEG C, and fine grinding powdered, cross 240-300 mesh sieve and get final product.
2. the Environmental-friendantistatic antistatic CABLE MATERIALS according to claims 1, is characterized in that, the concrete steps of preparation method are as follows:
(1) silicone, phosphorus benzene tricarboxylic acid three monooctyl ester, tetraphenyl ethylene, titanate coupling agent TMC-TTS, the two lauryl of thio-2 acid, aminopropyl triethoxysilane, octadecyldimethyl hydroxyethyl quaternary ammonium nitrate, ESCALOL 567 are placed in high-speed mixer and mix material, for subsequent use;
(2) chlorosulfonated polyethylene rubber is placed in the refining glue that Banbury mixer carries out 2-4 minute, after until banburying glue cooling after step 1 gained mixture is joined in Banbury mixer, prior to 50-70 DEG C of mixing 4-6 minute, again temperature is risen to 90-110 DEG C and continue mixing 4-5 minute, for subsequent use by taking out after the cooling of gained material;
(3) by aluminium hydroxide, 1,6-hexylene glycol double methacrylate, iron trichloride, dicumyl peroxide, N220 carbon black, step 2 gained material and leftover materials mix, join extruding pelletization in twin screw extruder, the screw slenderness ratio of twin screw extruder is 32:1-44:1, and rotating speed is 350-550 rev/min;
(4) step 3 gained particle is put in storage through inspection screening, packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410596696.9A CN104327400A (en) | 2014-10-30 | 2014-10-30 | Environment-friendly antistatic cable material and preparation method of cable material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410596696.9A CN104327400A (en) | 2014-10-30 | 2014-10-30 | Environment-friendly antistatic cable material and preparation method of cable material |
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| CN104327400A true CN104327400A (en) | 2015-02-04 |
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| CN201410596696.9A Pending CN104327400A (en) | 2014-10-30 | 2014-10-30 | Environment-friendly antistatic cable material and preparation method of cable material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009696A (en) * | 2016-06-30 | 2016-10-12 | 安徽智博新材料科技有限公司 | Insulating particle and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102372877A (en) * | 2011-06-28 | 2012-03-14 | 江苏远洋东泽电缆股份有限公司 | Cable sheath material for deep sea oil exploration and production method thereof |
| CN102417668A (en) * | 2011-11-15 | 2012-04-18 | 中天科技装备电缆有限公司 | Cable sheath material for wind power generation and production method thereof |
| CN102964705A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Nano-kieselguhr modified chlorosulfonated polyethylene rubber cable material |
| CN102964707A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Nano-kaolin modified chlorosulfonated polyethylene rubber cable material |
| CN103524907A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Mine cable rubber sheath material and preparation method |
-
2014
- 2014-10-30 CN CN201410596696.9A patent/CN104327400A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102372877A (en) * | 2011-06-28 | 2012-03-14 | 江苏远洋东泽电缆股份有限公司 | Cable sheath material for deep sea oil exploration and production method thereof |
| CN102417668A (en) * | 2011-11-15 | 2012-04-18 | 中天科技装备电缆有限公司 | Cable sheath material for wind power generation and production method thereof |
| CN102964705A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Nano-kieselguhr modified chlorosulfonated polyethylene rubber cable material |
| CN102964707A (en) * | 2012-11-13 | 2013-03-13 | 安徽春辉仪表线缆集团有限公司 | Nano-kaolin modified chlorosulfonated polyethylene rubber cable material |
| CN103524907A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | Mine cable rubber sheath material and preparation method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106009696A (en) * | 2016-06-30 | 2016-10-12 | 安徽智博新材料科技有限公司 | Insulating particle and preparation method thereof |
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Application publication date: 20150204 |