CN103509257A - 105 DEG C low-smoke zero-halogen flame-retardant ethylene-propylene-diene monomer cable material and preparation method thereof - Google Patents

105 DEG C low-smoke zero-halogen flame-retardant ethylene-propylene-diene monomer cable material and preparation method thereof Download PDF

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CN103509257A
CN103509257A CN201310390636.7A CN201310390636A CN103509257A CN 103509257 A CN103509257 A CN 103509257A CN 201310390636 A CN201310390636 A CN 201310390636A CN 103509257 A CN103509257 A CN 103509257A
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parts
propylene
cable material
preparation
rubber
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曹悦煕
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Electric Science And Technology Ltd Of Sky Anhui People
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Electric Science And Technology Ltd Of Sky Anhui People
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911—Cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a 105 DEG C low-smoke zero-halogen flame-retardant ethylene-propylene-diene monomer cable material and a preparation method thereof. The cable material is prepared from the following raw materials in parts by weight: 75-95 parts of ethylene-propylene-diene monomer, 30-40 parts of SG-4 type PVC resin, 10-15 parts of PBT resin, 1-2 parts of antiager DM, 1-2 parts of antiager RD, 2-3 parts of zinc oxide, 3-6 parts of titanium dioxide, 4-8 parts of microcrystalline wax, 10-15 parts of aluminium hydroxide, 5-10 parts of molybdenum trioxide, 8-12 parts of zinc borate, 1-2 parts of promoter TMTD, 2-3 parts of stearic acid, 15-20 parts of fumed silica, 10-15 parts of ultrafine powdered steatile, 10-15 parts of nanometer potter's clay, 1-2 parts of dehydroacetic acid, 5-10 parts of acetyl triethyl citrate, 4-8 parts of tributyl citrate, 2-3 parts of sulphur and 3-5 parts of a composite filler. The cable material of the invention is excellent in flame retardation effect, extremely less in smoke generating amount during combustion, none in generated toxic gas, none in generated corrosive gas, completely environment-friendly, good in high-temperature resistance, usable at 105 DEG C for a long time without deformation or scorch, capable of normally transmitting signals or electric energy, and durable.

Description

A kind of 105 ℃ of low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS and preparation method thereof
Technical field
The present invention relates to a kind of CABLE MATERIALS and preparation method thereof, be specifically related to a kind of 105 ℃ of low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS and preparation method thereof.
Background technology
Terpolymer EP rubber, because of its good ageing-resistant, water-fast, heat-resistant deforming and the good performances such as electrical isolation, is subject to the attention of cable industry.At present, its has substituted traditional butylbenzene, natural, isoprene-isobutylene rubber, peculiar to vessel and mobile, with on low, midium voltage cable, is widely used.But the same with most of hydrocarbon macromolecular compounds, terpolymer EP rubber is also easy to burning, and oxygen index is lower, and high thermal resistance is poor, cannot meet the requirement of electric wire.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of 105 ℃ of low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS and preparation method thereof are provided.
The technical solution used in the present invention is as follows:
A kind of 105 ℃ of low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS, raw material by following weight part is made: terpolymer EP rubber 75-95, SG-4 type polyvinyl chloride resin 30-40, PBT resin 10-15, antioxidant D M1-2, anti-aging agent RD 1-2, zinc oxide 2-3, titanium dioxide 3-6, microcrystalline wax 4-8, aluminium hydroxide 10-15, molybdic oxide 5-10, zinc borate 8-12, Vulcanization accelerator TMTD 1-2, stearic acid 2-3, gas-phase silica 15-20, superfine talcum powder 10-15, nanometer potter's clay 10-15, dehydroacetic acid (DHA) 1-2, acetyl triethyl citrate 5-10, tributyl citrate 4-8, sulphur 2-3, compounded mix 3-5,
The preparation method of described compounded mix is as follows: a. takes off the raw material of row weight part: diatomite 8-12, wollastonite 6-10, nano titanium oxide 3-5, nanometer silicon carbide 4-8, vinyl three ('beta '-methoxy oxyethyl group) silane 2-3, lanthanum trioxide 2-3, Praseodymium trioxide 1-2, epoxy soybean oil 10-15, dimethyl silicone oil 3-6, trimethylolpropane trimethacrylate 1-2, clorafin 5-8, brucite powder 3-6, boron rock ground-slag 2-3, accelerant N A-221-2; B, bauxitic clay, wollastonite are calcined to 4-6 hour at 480-520 ℃, be cooled to after room temperature, putting into concentration is that 10-15% hydrochloric acid soln boils 20-30 minute, take out washing to neutral, after drying, pulverizing, mix with nano titanium oxide, nanometer silicon carbide, vinyl three ('beta '-methoxy oxyethyl group) silane, brucite powder and boron rock ground-slag, 3000-5000rpm speed lapping 15-20 minute, crosses 300-400 mesh sieve; C, the powder after sieving is mixed and be get final product with all the other raw materials.
The preparation method of 105 ℃ of low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS, comprises the following steps:
(1) getting terpolymer EP rubber, zinc oxide, aluminium hydroxide, magnesium oxide, molybdic oxide, Vulcanization accelerator TMTD, stearic acid, gas-phase silica, nanometer potter's clay, compounded mix, acetyl triethyl citrate, sulphur adds in rubber mixing machine, at 75-85 ℃, refine glue 10-15min, blanking, obtains sizing material A;
(2) get SG-4 type polyvinyl chloride resin, PBT resin, zinc borate, superfine talcum powder, tributyl citrate, microcrystalline wax and add in rubber mixing machine, refine glue 8-12min at 70-80 ℃, blanking, obtains sizing material B;
(3) gained sizing material A, sizing material B and all the other raw materials are together sent in twin screw extruder, carry out mixing, the processing temperature of each section of twin screw extruder is set as respectively: first paragraph 165-175 ℃, second segment 170-180 ℃, the 3rd section of 175-185 ℃, the 4th section of 180-190 ℃, the 5th section of 190-210 ℃, die head temperature 180-200 ℃, finally by air-cooled granulation, obtain required CABLE MATERIALS.
Beneficial effect of the present invention:
CABLE MATERIALS flame retardant effect of the present invention is excellent, and during burning, the amount of being fuming is considerably less, does not produce toxic gas, does not produce corrosive gases, completely environmental protection, and high thermal resistance is good, can be at 105 ℃ life-time service, indeformable, incipient scorch not, can normal transmission signal or electric energy, durable in use.
Embodiment
A ℃ low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS, is made by the raw material of following weight (kg): terpolymer EP rubber 85, SG-4 type polyvinyl chloride resin 35, PBT resin 12, antioxidant D M1.5, anti-aging agent RD 1, zinc oxide 2.5, titanium dioxide 4, microcrystalline wax 6, aluminium hydroxide 15, molybdic oxide 6, zinc borate 10, Vulcanization accelerator TMTD 1.5, stearic acid 2, gas-phase silica 15, superfine talcum powder 15, nanometer potter's clay 10, dehydroacetic acid (DHA) 1.5, acetyl triethyl citrate 8, tributyl citrate 6, sulphur 2, compounded mix 4;
The preparation method of described compounded mix is as follows: a. takes off the raw material of column weight amount (kg): diatomite 10, wollastonite 8, nano titanium oxide 4, nanometer silicon carbide 6, vinyl three ('beta '-methoxy oxyethyl group) silane 2, lanthanum trioxide 3, Praseodymium trioxide 1, epoxy soybean oil 10, dimethyl silicone oil 4, trimethylolpropane trimethacrylate 1.5, clorafin 6, brucite powder 4, boron rock ground-slag 2, accelerant N A-221.5; B, bauxitic clay, wollastonite are calcined 5 hours at 510 ℃, be cooled to after room temperature, putting into concentration is that 15% hydrochloric acid soln boils 25 minutes, take out washing to neutral, after drying, pulverizing, mix with nano titanium oxide, nanometer silicon carbide, vinyl three ('beta '-methoxy oxyethyl group) silane, brucite powder and boron rock ground-slag, 4000rpm speed lapping 15 minutes, crosses 400 mesh sieves; C, the powder after sieving is mixed and be get final product with all the other raw materials.
The preparation method of 105 ℃ of low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS, comprises the following steps:
(1) getting terpolymer EP rubber, zinc oxide, aluminium hydroxide, magnesium oxide, molybdic oxide, Vulcanization accelerator TMTD, stearic acid, gas-phase silica, nanometer potter's clay, compounded mix, acetyl triethyl citrate, sulphur adds in rubber mixing machine, at 80 ℃, refine glue 12min, blanking, obtains sizing material A;
(2) get SG-4 type polyvinyl chloride resin, PBT resin, zinc borate, superfine talcum powder, tributyl citrate, microcrystalline wax and add in rubber mixing machine, refine glue 10min at 75 ℃, blanking, obtains sizing material B;
(3) gained sizing material A, sizing material B and all the other raw materials are together sent in twin screw extruder, carry out mixing, the processing temperature of each section of twin screw extruder is set as respectively: 170 ℃ of first paragraphs, 175 ℃ of second segments, the 3rd section 180 ℃, the 4th section 190 ℃, the 5th section 205 ℃, 195 ℃ of die head temperatures, finally by air-cooled granulation, obtain required CABLE MATERIALS.
The performance test results of the CABLE MATERIALS making is as follows:

Claims (2)

1. 105 ℃ of low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS, it is characterized in that, raw material by following weight part is made: terpolymer EP rubber 75-95, SG-4 type polyvinyl chloride resin 30-40, PBT resin 10-15, antioxidant D M 1-2, anti-aging agent RD 1-2, zinc oxide 2-3, titanium dioxide 3-6, microcrystalline wax 4-8, aluminium hydroxide 10-15, molybdic oxide 5-10, zinc borate 8-12, Vulcanization accelerator TMTD 1-2, stearic acid 2-3, gas-phase silica 15-20, superfine talcum powder 10-15, nanometer potter's clay 10-15, dehydroacetic acid (DHA) 1-2, acetyl triethyl citrate 5-10, tributyl citrate 4-8, sulphur 2-3, compounded mix 3-5,
The preparation method of described compounded mix is as follows: a. takes off the raw material of row weight part: diatomite 8-12, wollastonite 6-10, nano titanium oxide 3-5, nanometer silicon carbide 4-8, vinyl three ('beta '-methoxy oxyethyl group) silane 2-3, lanthanum trioxide 2-3, Praseodymium trioxide 1-2, epoxy soybean oil 10-15, dimethyl silicone oil 3-6, trimethylolpropane trimethacrylate 1-2, clorafin 5-8, brucite powder 3-6, boron rock ground-slag 2-3, accelerant N A-22 1-2; B, bauxitic clay, wollastonite are calcined to 4-6 hour at 480-520 ℃, be cooled to after room temperature, putting into concentration is that 10-15% hydrochloric acid soln boils 20-30 minute, take out washing to neutral, after drying, pulverizing, mix with nano titanium oxide, nanometer silicon carbide, vinyl three ('beta '-methoxy oxyethyl group) silane, brucite powder and boron rock ground-slag, 3000-5000rpm speed lapping 15-20 minute, crosses 300-400 mesh sieve; C, the powder after sieving is mixed and be get final product with all the other raw materials.
2. the preparation method of 105 ℃ of low smoke halogen-free flame retardant ethylene-propylene-diene rubber CABLE MATERIALS as claimed in claim 1, is characterized in that comprising the following steps:
Getting terpolymer EP rubber, zinc oxide, aluminium hydroxide, magnesium oxide, molybdic oxide, Vulcanization accelerator TMTD, stearic acid, gas-phase silica, nanometer potter's clay, compounded mix, acetyl triethyl citrate, sulphur adds in rubber mixing machine, at 75-85 ℃, refine glue 10-15min, blanking, obtains sizing material A;
Get SG-4 type polyvinyl chloride resin, PBT resin, zinc borate, superfine talcum powder, tributyl citrate, microcrystalline wax and add in rubber mixing machine, refine glue 8-12min at 70-80 ℃, blanking, obtains sizing material B;
By gained sizing material A, sizing material B and all the other raw materials together send in twin screw extruder, carry out mixing, the processing temperature of each section of twin screw extruder is set as respectively: first paragraph 165-175 ℃, second segment 170-180 ℃, the 3rd section of 175-185 ℃, the 4th section of 180-190 ℃, the 5th section of 190-210 ℃, die head temperature 180-200 ℃, finally by air-cooled granulation, obtain required CABLE MATERIALS.
CN201310390636.7A 2013-08-30 2013-08-30 105 DEG C low-smoke zero-halogen flame-retardant ethylene-propylene-diene monomer cable material and preparation method thereof Pending CN103509257A (en)

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CN104007524A (en) * 2014-04-23 2014-08-27 晶锋集团股份有限公司 Optical fiber bundle protection wire
CN104130531A (en) * 2014-08-18 2014-11-05 沈太英 Polyvinyl chloride composite cable material for field of electricity and manufacturing method of composite cable material
CN104592650A (en) * 2015-01-09 2015-05-06 芜湖航天特种电缆厂 Flame-retardant ethylene-propylene diene copolymer rubber sleeve for cables and preparation method thereof
CN104592648A (en) * 2015-01-09 2015-05-06 芜湖航天特种电缆厂 Flame-retardant ethylene propylene diene monomer for cable and preparation method of flame-retardant ethylene propylene diene monomer
CN105602143A (en) * 2016-01-26 2016-05-25 安徽新亚特电缆集团有限公司 Formulation for polyvinyl chloride cable sheath for coal mine
CN107248428A (en) * 2017-06-22 2017-10-13 安徽电缆股份有限公司 Environment-friendly type power cable
CN107815025A (en) * 2017-10-24 2018-03-20 芜湖航天特种电缆厂股份有限公司 Halogen-free flame-retardant cable and preparation method thereof
CN109671532A (en) * 2018-12-11 2019-04-23 安徽天康(集团)股份有限公司 A kind of termite-proof LSOH anti-flaming fireproof power cable of environment protection, rat
CN109887667A (en) * 2019-01-15 2019-06-14 安徽天康(集团)股份有限公司 A kind of control cable for flame-retardant fireproof boat and its manufacturing method
CN112164490A (en) * 2020-09-25 2021-01-01 安徽德尔电气集团有限公司 High-strength pull-resistant cable and preparation method thereof
IT202000022543A1 (en) * 2020-09-24 2022-03-24 Col Tar Gomma Sud S R L PROCESS FOR COATING ROLLS FOR STAMPING TECHNIQUES

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998052197A1 (en) * 1997-05-15 1998-11-19 Pirelli Cavi E Sistemi S.P.A. Cable with impact-resistant coating
CN101531789A (en) * 2009-04-20 2009-09-16 宝胜科技创新股份有限公司 Radiation-resistant halogen-free low smoke flame retardant insulating material for cables of nuclear power plants and preparation method
CN101613504A (en) * 2009-07-24 2009-12-30 青岛中阳消防科技有限公司 A kind of material and preparation method with temperature sensing cable material of CRT characteristic
CN102746546A (en) * 2012-06-15 2012-10-24 安徽华通电缆集团有限公司 Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method
CN102911439A (en) * 2012-09-18 2013-02-06 铜陵市铜都特种线缆厂 Fire-resistant control cable material for ships and method for preparing same
CN102964697A (en) * 2012-11-13 2013-03-13 安徽春辉仪表线缆集团有限公司 Nano-wollastonite powder modified ethylene propylene diene copolymer cable material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998052197A1 (en) * 1997-05-15 1998-11-19 Pirelli Cavi E Sistemi S.P.A. Cable with impact-resistant coating
CN101531789A (en) * 2009-04-20 2009-09-16 宝胜科技创新股份有限公司 Radiation-resistant halogen-free low smoke flame retardant insulating material for cables of nuclear power plants and preparation method
CN101613504A (en) * 2009-07-24 2009-12-30 青岛中阳消防科技有限公司 A kind of material and preparation method with temperature sensing cable material of CRT characteristic
CN102746546A (en) * 2012-06-15 2012-10-24 安徽华通电缆集团有限公司 Halogen-free environmentally-friendly power cable material for wind power generation, and its preparation method
CN102911439A (en) * 2012-09-18 2013-02-06 铜陵市铜都特种线缆厂 Fire-resistant control cable material for ships and method for preparing same
CN102964697A (en) * 2012-11-13 2013-03-13 安徽春辉仪表线缆集团有限公司 Nano-wollastonite powder modified ethylene propylene diene copolymer cable material

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
D.R.保罗 等: "《聚合物共混物：组成与性能（下卷）》", 31 May 2004, article "相容性图表", pages: 860 *
君轩: "溶解度参数", 《世界橡胶工业》, vol. 34, no. 7, 20 July 2007 (2007-07-20), pages 47 *
罗河胜: "《塑料材料手册》", 31 January 2004, article "共混改性" *

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* Cited by examiner, † Cited by third party
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CN104130531A (en) * 2014-08-18 2014-11-05 沈太英 Polyvinyl chloride composite cable material for field of electricity and manufacturing method of composite cable material
CN104130531B (en) * 2014-08-18 2016-03-09 沈太英 For polyvinyl chloride composite cable material and the manufacture method thereof of power domain
CN104592650A (en) * 2015-01-09 2015-05-06 芜湖航天特种电缆厂 Flame-retardant ethylene-propylene diene copolymer rubber sleeve for cables and preparation method thereof
CN104592648A (en) * 2015-01-09 2015-05-06 芜湖航天特种电缆厂 Flame-retardant ethylene propylene diene monomer for cable and preparation method of flame-retardant ethylene propylene diene monomer
CN105602143A (en) * 2016-01-26 2016-05-25 安徽新亚特电缆集团有限公司 Formulation for polyvinyl chloride cable sheath for coal mine
CN107248428A (en) * 2017-06-22 2017-10-13 安徽电缆股份有限公司 Environment-friendly type power cable
CN107815025A (en) * 2017-10-24 2018-03-20 芜湖航天特种电缆厂股份有限公司 Halogen-free flame-retardant cable and preparation method thereof
CN109671532A (en) * 2018-12-11 2019-04-23 安徽天康(集团)股份有限公司 A kind of termite-proof LSOH anti-flaming fireproof power cable of environment protection, rat
CN109887667A (en) * 2019-01-15 2019-06-14 安徽天康(集团)股份有限公司 A kind of control cable for flame-retardant fireproof boat and its manufacturing method
IT202000022543A1 (en) * 2020-09-24 2022-03-24 Col Tar Gomma Sud S R L PROCESS FOR COATING ROLLS FOR STAMPING TECHNIQUES
CN112164490A (en) * 2020-09-25 2021-01-01 安徽德尔电气集团有限公司 High-strength pull-resistant cable and preparation method thereof

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Application publication date: 20140115