CN104149337A - Photocuring material for three-dimensional printing and application method thereof - Google Patents
Photocuring material for three-dimensional printing and application method thereof Download PDFInfo
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- CN104149337A CN104149337A CN201410309767.2A CN201410309767A CN104149337A CN 104149337 A CN104149337 A CN 104149337A CN 201410309767 A CN201410309767 A CN 201410309767A CN 104149337 A CN104149337 A CN 104149337A
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Abstract
The invention discloses a photocuring material for three-dimensional printing. The photocuring material consists of inorganic powder and an organic liquid containing curable components, wherein the inorganic powder accounts for 60%-99.9% of the total weight, and the organic liquid accounts for 0.1%-40% of the total weight; and the inorganic powder material is ceramic powder, or metal powder or composite powder of ceramic and metal. The invention also discloses an application method of the photocuring material. The photocuring material and the application method disclosed by the invention have the advantages that more printing-material selecting space is provided for the three-dimensional printing technology, and the purpose of utilizing the three-dimensional printing technology to prepare the three-dimensional structure with one or more ceramic materials, or metal materials or coexistence of ceramic and metal on the same plane can be achieved.
Description
Technical field
The invention belongs to 3 D-printing and manufacture field, be specifically related to a kind of photo-curing material for 3 D-printing and application process thereof.
Background technology
Three-dimensional printing technology develops rapidly in recent years and becomes study hotspot, its principle is that three-dimensional image is created out by continuous physical layer, its process is as the print procedure of printer, by powder pointwise is printed to stratification, then be successively superimposed as the preparation process of 3D solid, have high, the fireballing feature of precision, its maximum feature is to settle at one go from being designed into moulding, and can prepare the more accurate complicated product of structure.Therefore, three-dimensional printing technology has become rapidly study hotspot since emerging, its range of application is also expanded to rapidly multiple industries such as product prototype design, precision parts, BUILDINGS MODELS, medical operating, the art work, and has developed multiple printing type and printed material rapidly.But existing printing technique and printed material, only support to print at grade a kind of pottery or metal or organic material.Its reason is the printing that the printing principle of different three-dimensional printing technologies has determined can only complete at grade a kind of material.As for existing metal or pottery print three-dimensional printing technology, substantially be all the powder that adopts spreading one deck printed material, then follow procedure carries out the laser sintered or organic bonding of each layer pattern, one deck printed material powder that after the one deck that completes printing down sinks, spreading is new again, circulates successively thereby is difficult to complete at grade the printing of different materials.And for the three-dimensional printing technology of organic solution, as stereolithography technology, its principle be laser beam under the control of computer according to individual-layer data continuous sweep liquid photosensitive resin surface, one deck solidifies aftertable and moves down an accurate distance, the lower one deck of scanning, circulate successively, also can only complete a kind of 3 D-printing of organic material.At present also do not have that a kind of 3 D-printing mode can well be supported in ceramic material or the metal material of in same plane, printing heterogeneity simultaneously, and the mixed of ceramic material and metal material beat, thereby form one by different ceramic components or metal ingredient or 3-D solid structure ceramic and that metal coexists.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the invention provides one can realize and utilize photocuring three-dimensional printing technology to prepare same plane by one or more ceramic materials, or metal material, or photo-curing material and application process thereof ceramic and the 3-D solid structure that metal coexists.
Technical scheme: for solving the problems of the technologies described above, a kind of photo-curing material for 3 D-printing provided by the invention, is made up of inorganic powder and organic liquid, and described inorganic powder accounts for gross weight 60%-99.9%, and described organic liquid accounts for gross weight 0.1-40%; Described inorganic powder material is ceramic powders and metal dust.
Further, described organic liquid is photo curable resin or the organic mixed solution that contains light-cured resin.
Further, described photo curable resin is one or more in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, pure acrylate, silicone oligomer, light-solidifying poly butadiene oligomer, organic-inorganic hybrid resin.
Further, described ceramic powders is one or more of aluminium oxide, aluminium nitride, carborundum, beryllium oxide, clay, calcium carbonate, yittrium oxide, magnesia, silica, calcium oxide, talcum, lead oxide, barium monoxide, bismuth oxide.
Further, described metal dust is one or more in gold, silver, copper, aluminium, nickel, tungsten, titanium, palladium, zinc.
The application process of the above-mentioned photo-curing material for 3 D-printing, comprises the following steps:
1) inorganic powder material is evenly mixed with the organic liquid that contains curable composition, obtain and there is certain fluidity, can utilize photocuring principle 3 D-printing equipment to print curing mixed slurry;
2) by the 3 D-printing equipment of Stereolithography principle, one or more printing slurries of preparation are printed and curing molding; The three-dimensional structure of described curing molding can be that a kind of pottery-light-cured resin slurry printing forms, or multiple pottery-light-cured resin slurry printing forms, or a kind of metal-light-cured resin slurry printing forms, or various metals-light-cured resin slurry prints and form, or the printing of one or more pottery-light-cured resin slurries and one or more metal-light-cured resin slurries forms.
3) finally by binder removal processing, high-sintering process is removed organic principle, obtains pottery, the metal of desired structure and composition, or the three-dimensional structure product of ceramet mixing.Described three-dimensional structure product is made up of one or more ceramic components, or one or more metal ingredients composition, or one or more ceramic components and one or more metal ingredients form jointly.There is not binder removal processing procedure in general 3 D-printing process, for the peculiar treatment process of the present invention, detailed process is to contain inorganic constituents and organic principle in the sample after printing, sample is heated to high temperature and carries out binder removal processing, organic principle in sample can decompose ablation, only retains required inorganic constituents.
Further, described high-sintering process comprises sintering under air atmosphere, oxidizing atmosphere, reducing atmosphere or vacuum environment.
Further, described ceramic powders is one or more of aluminium oxide, aluminium nitride, carborundum, beryllium oxide, clay, calcium carbonate, yittrium oxide, magnesia, silica, calcium oxide, talcum, lead oxide, barium monoxide, bismuth oxide.
Further, described metal dust is one or more in gold, silver, copper, aluminium, nickel, tungsten, titanium, palladium, zinc.
Further, described photo curable resin is one or more in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, pure acrylate, silicone oligomer, light-solidifying poly butadiene oligomer, organic-inorganic hybrid resin.
Principle of the present invention is: utilize the synthetic composite mortar with mobility of inorganic powder (can be ceramic powders or metal dust) and light-cured resin, this slurry can curing molding under UV-irradiation, utilize ultra-violet curing 3 D-printing equipment to print, because having many shower nozzles, the type equipment can realize spraying of different materials, therefore can in Different Plane, print the inorganic-organic hybrid slurry that contains variety classes inorganic constituents, after solidify on printing limit, limit, by the at high temperature heat treatment of inorganic-organic hybrid base of moulding, organic principle can decompose completely before 600 DEG C, base substrate is the inorganic constituents of remaining design only.The base substrate heat treatment under higher temperature again these inorganic constituents being formed, can make these inorganic constituents (pottery or metal) thereby sintering is densified, obtains the finished product of design.This scheme has absorbed ultra-violet curing moulding three-dimensional printing technology can print the advantage of multiple material simultaneously, provide a set of inorganic-organic hybrid of preparing to print slurry, and follow-up binder removal, sintering process after printing curing molding, formed utilize the preparation of Stereolithography 3 D-printing can pottery, metal, the system scheme that ceramic and metal coexists.
The photo-curing material of the 3 D-printing in the present invention, can make the hybrid three-dimensional infrastructure product of light curable type 3 D-printing equipment preparation pottery, metal and pottery and metal, and three-dimensional printing technology can be realized on same plane, print mixing of multiple ceramic material, metal material or ceramic material and metal material.The photo-curing material of described 3 D-printing and application process thereof have enriched 3 D-printing material, have widened 3 D-printing preparation field.
Beneficial effect: the present invention in terms of existing technologies, can select space for three-dimensional printing technology provides more printed material, and can realize and utilize three-dimensional printing technology to prepare same plane by one or more ceramic materials, or metal material, or 3-D solid structure ceramic and that metal coexists.
Detailed description of the invention
According to specific embodiment, the present invention is further described below.
embodiment 1:
A kind of application of the photo-curing material for 3 D-printing:
1) getting mass ratio is 60% alumina powder jointed and 40% acrylate, both is mixed to the slurry that obtains certain viscosity;
2) utilize the 3 D-printing equipment with photocuring function that three-dimensional structure is printed and be solidified into the slurry preparing;
3) sample of curing molding is carried out to binder removal processing at 200-600 DEG C, remove organic principle, and carry out sintering processes at 1500-1800 DEG C, obtain the aluminium oxide ceramics of required composition, shape.
embodiment 2:
A kind of application of the photo-curing material for 3 D-printing:
1) get the acrylate that mass ratio is 99.9% aluminium nitride powder and 0.1%, both are mixed to the slurry that obtains certain viscosity;
2) utilize the 3 D-printing equipment with photocuring function that three-dimensional structure is printed and be solidified into the slurry preparing;
3) sample of curing molding is carried out to binder removal processing at 200-600 DEG C, remove organic principle, and carry out sintering processes at 1500-1800 DEG C, obtain the aluminium oxide ceramics of required composition, shape.
embodiment 3:
A kind of application of the photo-curing material for 3 D-printing:
1) getting mass ratio is 70% alumina powder jointed and 30% polyurethane acrylic resin, both is mixed to the slurry that obtains certain viscosity;
2) utilize the 3 D-printing equipment with photocuring function that three-dimensional structure is printed and be solidified into the slurry preparing;
3) sample of curing molding is carried out to binder removal processing at 200-600 DEG C, remove organic principle, and carry out sintering processes at 1500-1800 DEG C, obtain the aluminium oxide ceramics of required composition, shape.
embodiment 4:
A kind of application of the photo-curing material for 3 D-printing:
1) get modification acrylate, the terpinol mixing material that mass ratio is 80% aluminium oxide, clay, calcium carbonate mixed powder and 20%, mix the slurry that obtains certain viscosity;
2) utilize the 3 D-printing equipment with photocuring function that three-dimensional structure is printed and be solidified into the slurry preparing;
3) sample of curing molding is carried out to binder removal processing at 200-600 DEG C, remove organic principle, and carry out sintering processes at 1500-1800 DEG C, obtain the aluminium oxide ceramics of required composition, shape.
embodiment 5:
A kind of application of the photo-curing material for 3 D-printing:
1) getting weight ratio is 87% tungsten powder, and 3% alumina powder jointedly mixes with 10% acrylate liquid, obtains the slurry with certain viscosity.
2) to get weight ratio be that 80%-is alumina powder jointed mixes with 20% acrylate liquid, obtains the slurry with certain viscosity.
3) utilize the 3 D-printing equipment of photocuring principle by two kinds of slurries that prepare, by print different materials curing molding in same plane zones of different.
4) sample of curing molding is carried out to binder removal processing at 200-600 DEG C, remove organic principle, and carry out sintering processes at 1500-1800 DEG C, obtain the aluminium oxide of required composition, shape, the three-dimensional sample of hybrid three-dimensional of tungsten.
embodiment 6:
A kind of application of the photo-curing material for 3 D-printing:
1) getting weight ratio is that 80% magnesia, calcium oxide, silica mixed powder mix with 20% acrylate liquid, obtains the slurry with certain viscosity.
2) getting weight ratio is that 60%-99.9% bronze body mixes with the acrylate liquid of 0.1-40%, obtains the slurry with certain viscosity.
3) utilize the 3 D-printing equipment of photocuring principle by two kinds of slurries that prepare, by print different materials curing molding in same plane zones of different.
4) sample of curing molding is carried out to binder removal processing at 200-600 DEG C, remove organic principle, and carry out sintering processes at 800-1000 DEG C, obtain LTCC, the metal mixed 3 D stereo sample of required composition, shape.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. for a photo-curing material for 3 D-printing, it is characterized in that: form by inorganic powder with containing curable composition organic liquid, described inorganic powder accounts for gross weight 60%-99.9%, the described curable composition organic liquid that contains accounts for gross weight 0.1-40%; Described inorganic powder material is ceramic powders or metal dust or pottery and composite metal powder.
2. the photo-curing material for 3 D-printing according to claim 1, is characterized in that: described is photo curable resin or the organic mixed solution that contains light-cured resin containing curable composition organic liquid.
3. the photo-curing material for 3 D-printing according to claim 2, is characterized in that: described photo curable resin is one or more in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, pure acrylate, silicone oligomer, light-solidifying poly butadiene oligomer, organic-inorganic hybrid resin.
4. the photo-curing material for 3 D-printing according to claim 1, is characterized in that: described ceramic powders is one or more of aluminium oxide, aluminium nitride, carborundum, beryllium oxide, clay, calcium carbonate, yittrium oxide, magnesia, silica, calcium oxide, talcum, lead oxide, barium monoxide, bismuth oxide.
5. the photo-curing material for 3 D-printing according to claim 1, is characterized in that: described metal dust is one or more in gold, silver, copper, aluminium, nickel, tungsten, titanium, palladium, zinc.
6. according to an application process for the photo-curing material for 3 D-printing described in claim 1 ~ 5, it is characterized in that: comprise the following steps:
1) get the photocuring composition organic liquid that mass ratio is 60%-99.9% inorganic powder and 0.1-40%, inorganic powder material is mixed and obtains a kind of mixed slurry with the organic liquid that contains curable composition;
2) utilize the 3 D-printing equipment with photocuring function that three-dimensional structure is printed and be solidified into the slurry preparing;
3) finally carry out binder removal processing and remove organic principle, and by high-sintering process, obtain the three-dimensional structure sample of required composition.
7. the application process of the photo-curing material for 3 D-printing according to claim 6, is characterized in that: described high-sintering process comprises 1500-1800 DEG C of sintering under air atmosphere, oxidizing atmosphere, reducing atmosphere or vacuum environment.
8. a class according to claim 6, for the application process of the photo-curing material of 3 D-printing, is characterized in that: described ceramic powders is one or more of aluminium oxide, aluminium nitride, carborundum, beryllium oxide, clay, calcium carbonate, yittrium oxide, magnesia, silica, calcium oxide, talcum, lead oxide, barium monoxide, bismuth oxide.
9. a class according to claim 6, for the application process of the photo-curing material of 3 D-printing, is characterized in that: described metal dust is one or more in gold, silver, copper, aluminium, nickel, tungsten, titanium, palladium, zinc.
10. a class according to claim 6, for the application process of the photo-curing material of 3 D-printing, is characterized in that: described photo curable resin is one or more in epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, pure acrylate, silicone oligomer, light-solidifying poly butadiene oligomer, organic-inorganic hybrid resin.
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