CN104761958A - Multi-color coating material and preparation method thereof - Google Patents
Multi-color coating material and preparation method thereof Download PDFInfo
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- CN104761958A CN104761958A CN201410009029.6A CN201410009029A CN104761958A CN 104761958 A CN104761958 A CN 104761958A CN 201410009029 A CN201410009029 A CN 201410009029A CN 104761958 A CN104761958 A CN 104761958A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to the technical field of coating materials, particularly to a multi-color coating material and a preparation method thereof. The multi-color coating material comprises a base paint, a colloid and a synthetic emulsion according to a weight ratio of 30-45:30-45:30-50. According to the present invention, the multi-color coating material can be the whole water-based product and has characteristics of low VOC, no solvent, environmental protection, and good elasticity, the product performance meets the synthetic resin external wall coating material GB/T9755-2001 standard, the coating effect of the multi-color coating material is the same as the coating effect of marbles and granites, and minor cracks on walls can be covered.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of multicolor finish and preparation method thereof.
Background technology
Coating is a kind of finishing material, comprises a variety of, as inner-outer wall building coating, floor coatings material, anticorrosion of steel structure material, water-borne wood coating, uv solidification, and other functional coatings etc.Building coating is that the new industry of support was puted forth effort by government in recent years, is also development in recent years industry rapidly.But building coating traditional is at present mainly based on aqueous latex paint, solvent-borne type synthetic resin coating, and its product sensorial effects is single, color is based on single real look, and the decorative effect of product is not good.Along with the raising that people require decorative effect, market today adopts a large amount of granite building materials or glass curtain wall as finishing material, considerably increase the dependence to natural resources and consumption; This material own wt is heavier simultaneously, and External Wall safety also exists larger hidden danger.The raising required along with energy-saving and environmental protection and the lifting to wall body decoration effect requirements, the multicolor finish market requirement with grouan texture is very big.
At present, market also has the granite multicolor paint being applied to inner-outer wall, but its product is all solvent type or oil-in-water-type, containing a large amount of organic solvents in product, has greater environmental impacts in using.Simultaneously product look grain is stable ' property, product weather resistance also poor.
Existing market also has the production of full-aqueous multicolour paint, but due to its production process complexity, technique controlling difficulty is very large, the reason that the production cycle is longer and product look grain is stable not, inreal formation commercialization and industrialization.
Summary of the invention
The object of the invention is to solve the problems of the technologies described above and a kind of multicolor finish and preparation method thereof is provided.
For achieving the above object, the present invention is by the following technical solutions:
A kind of multicolor finish and preparation method thereof, its moiety comprises, and comprises base paint, colloid and synthetic emulsion, between weight ratio be: 30-45: 30-45: 30-50;
Component and the weight part of described base paint are as follows:
Described base paint mainly provides the particle producing color, and this particle is changeable, requires quite stable, can not be dissolved in colloid.
Described anionic emulsion can select the one of phenylpropyl alcohol, pure third, elasticity or modified silicon acrylic emulsion.
Described hydrophilic gel is selected from the one of polyvinyl alcohol, methylcellulose gum or ethyl cellulose.
Described wetting agent selects nonionic block to gather enzyme type tensio-active agent, and as Block polyoxyethylene one polyoxypropylene enzyme (X-405), it has good wetting effect to all pigment.
Described dispersion agent selects non-ionic surface clean property agent class, and as nonionic polyurethane dispersion agent (TCP-8030N), it has good divergent function to pigment class titanium dioxide.
Described defoamer is optional is the defoamer of major ingredient in order to hydrophobically modified silicon-dioxide and mineral oil, such as defoamer RF-202, and defoaming effect is obvious, has no side effect.
Pigment can select proportion little, and the filler containing a small amount of free metal ion is as weighting material, and it can significantly improve fullness ratio and the stability of particle, and color can select monochrome or secondary color, being advisable generally with mineral dye preparation.
Described film coalescence aid is alkoxide, such as HY-1800, has good film-formation result.
Described thickening material is the swelling associative thickener of alkali, such as TT-615.
The major function of described colloid is that base paint is wrapped up by colloid, and base paint acts on mutually with the polar material in colloid, forms a reticulated structure, base paint is firmly wrapped, and form particle stable one by one, it comprises following component and weight proportion:
Described synthetic resin solution can select the one of cationic polyacrylamide and fluorine richness copolymer emulsion.
Described retardant can select the salt of calcium, magnesium, aluminium or ammonium etc.
The one of the optional spent glycol butyl ether of described film coalescence aid, 2-Butoxyethyl acetate.
Described synthetic emulsion can select the one in phenylpropyl alcohol, pure third, elasticity or fluorine richness emulsion.
The present invention absorbs mutually due to the polar material of colloid and the anisotropic particles on base paint look grain surface; colloid is attracted to the surface of look grain; the emulsion of the polar component in colloid and base paint particle surface and pigment react; form the hard layer of half gel state, thus gluey protect system is stablized in formation one.This system can not interpenetrate, and is stably suspended in transparent emulsion, can not sinks to the bottom.This gelatinization reaction generally needs 2-3h.
The preparation method of multicolor finish of the present invention, it comprises the steps:
1, first mixed by each composition of base paint, viscosity controller is at 100-105ku;
2, then each composition of protecting glue is mixed;
3, finally base paint is joined in protecting glue, stir, gelatinization reaction 1-2h, then add synthetic emulsion, and continuation reaction 1-2h forms.
Concrete production technique is as follows:
1) preparation of base paint
To partly water, hydrophilic gel, wetting agent, dispersion agent, defoamer mix, be stirred to uniform state, more slowly add pigment, middling speed is dispersed to fineness 50um.Finally add anionic emulsion, water, film coalescence aid, for subsequent use with thickening material adjustment viscosity to 100 scholar 5ku.
2) toning of base paint
The base paint prepared is added in paint mixing cylinder, moderate-speed mixer, slowly add aqueous color paste (can allocating by the mill base that this area is conventional), be mixed to uniform state, be adjusted to the color designed in advance, for subsequent use.
3) preparation of protecting glue
Be added to by retardant in water, middling speed is dispersed to dissolves completely, then adds synthetic resins, and middling speed dispersion about 30min, to being dissolved to colourless transparent solution completely, and then adding film coalescence aid, mixing.
4) preparation of look grain paint
Respectively by suitable grain equipment, the base paint after toning is added in granulating equipment, particle can have been made by setting size of particles and join in protective colloid, stirring at low speed; mix; look grain gelatinization reaction 1-2h, adds negatively charged ion synthetic emulsion, and forms stable look grain paint after continuing reaction 1-2h.
5) preparation of multicolor finish
Look grain paint that is not of the same race and ratio is mixed, and stirring at low speed is even.
Multicolor finish of the present invention is full aqueous product, product performance meet synthetic resins exterior coating GB/T9755-2001 standard, and VOC is low, solvent-free, environmental protection, and has good elasticity, its painting effect not only can match in excellence or beauty with marble, grouan, can also cover the slight slight crack of body of wall.
Embodiment
Below, in conjunction with example, substantive distinguishing features of the present invention and advantage are further described, but the present invention is not limited to listed embodiment.
Embodiment 1
The multicolor finish of the present embodiment, comprises base paint, colloid and benzene emulsion, between weight ratio be 30: 40: 40.
Component and the weight part of base paint are as follows:
Anionic emulsion (benzene emulsion 296DS) 40 parts, hydrophilic gel (methylcellulose gum) 3 parts, wetting agent (Block polyoxyethylene one polyethenoxy ether X-405) 0.2 part, nonionic polyurethane dispersion agent TCP-8030N0.1 part, defoamer RF-2020.3 part, pigment R-902 titanium white 12 parts, 30 parts, water, film coalescence aid HY-18002 part, thickening material TT-6150.1 part.
The component of colloid and weight proportion:
Synthetic resins (polyacrylamide) 15 parts, 4 parts, retardant calcium carbonate, film coalescence aid butyl glycol ether 1 part, 90 parts, water.
The production technique of the multicolor finish of the present embodiment is as follows:
1, the preparation of base paint
To partly water, hydrophilic gel, ravine humectant, dispersion agent, defoamer mix, be stirred to uniform state, more slowly add pigment, middling speed is dispersed to fineness < 50um.Finally add anionic emulsion, water, film coalescence aid, for subsequent use to 100ku by thickening material adjustment viscosity.
2, the toning of base paint
The base paint prepared is added in paint mixing cylinder, moderate-speed mixer, slowly add aqueous color paste, be mixed to uniform state, be adjusted to the color designed in advance, for subsequent use.
The 0.1-20% of paint amount based on the consumption of aqueous color paste, the formula of general mill base is: water 30-68%, Mierocrystalline cellulose 1-3%, pigment 30-68%.
Mill base preparation process is: first water and Mierocrystalline cellulose are stirred, Mierocrystalline cellulose is fully expanded, adds rear pigment, stir.Selection and the preparation process of each composition of mill base are well known to the skilled person.
3, the preparation of protecting glue
Be added to by retardant in water, middling speed is dispersed to dissolves completely, then adds synthetic resins, and middling speed dispersion about 30min, to being dissolved to colourless transparent solution completely, and then adding film coalescence aid, mixing.
4, the preparation of look grain paint
Respectively by granulating equipment, each colored paint is added in granulating equipment, made particle by setting size of particles and joined in protective colloid, stirring at low speed; mix; look grain gelatinization reaction 2h, adds negatively charged ion synthetic emulsion, and forms stable look grain paint after continuing reaction 1h.
5, the preparation of multicolor finish
By the requirement of colour table requirement or client, look grain paint that is not of the same race and ratio is mixed, and stirring at low speed is even.
The colorful elastic exterior coating material of fully water based granite is full aqueous product, and VOC is low, environmental protection, solvent-free, has good elasticity, and painting effect not only can compare favourably with marble, granite, can also cover the slight slight crack of exterior wall.
Embodiment 2
The present embodiment primary process with embodiment 1, unlike, multicolor finish, comprises base paint, colloid and pure-acrylic emulsion, between weight ratio be 40: 30: 30.
Component and the weight part of base paint are as follows:
Anionic emulsion (pure-acrylic emulsion AD-2) 50 parts, hydrophilic gel (ethyl cellulose) 1 part, wetting agent (Block polyoxyethylene-polyethenoxy ether X-405) 0.5 part, nonionic polyurethane dispersion agent (TCP-8030N) 0.3 part, defoamer (RF-202) 0.5 part, pigment (R-902 titanium dioxide) 10 parts, filler (600 order coarse whiting and talcum powder) 10 parts, 25 parts, water, film coalescence aid (HY-1800) 1 part, thickening material (TT-615) 0.5 part.
The component of colloid and weight proportion:
Synthetic resins (polyacrylamide) 10 parts, 2 parts, retardant magnesiumcarbonate, film coalescence aid 2-Butoxyethyl acetate 2 parts, 80 parts, water.
Embodiment 3
The present embodiment primary process with embodiment 1, unlike, multicolor finish, comprises base paint, colloid and fluorine richness emulsion, between weight ratio be 35: 40: 40.
Component and the weight part of base paint are as follows: anionic emulsion (modified silicon acrylic emulsion BD-309) 45 parts, hydrophilic gel (polyvinyl alcohol) 2 parts, wetting agent (Block polyoxyethylene one polyethenoxy ether X-405) 0.1 part, nonionic polyurethane dispersion agent TCP-8030N0.5 part, defoamer RF-2020.1 part, pigment R-902 titanium dioxide 15 parts, filler (600 order coarse whiting) 10 parts, 20 parts, water, film coalescence aid HY-18002 part, thickening material TT-6150.3 part.
The component of colloid and weight proportion:
Synthetic resins (fluorine richness copolymer emulsion PF919) 20 parts, retardant amine sulfate 2 parts, film coalescence aid propylene glycol 1 part, 89 parts, water.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (5)
1. multicolor finish and preparation method thereof, is characterized in that, the composition of multicolor finish comprises base paint, colloid and synthetic emulsion, and described base paint, weight ratio between colloid and synthetic emulsion are 30-45: 30-45: 30-50;
1) component of described base paint and weight part as follows:
2) component of described colloid and weight part as follows:
3) described synthetic emulsion comprises anionic emulsion, wetting ability protecting glue, and described anionic emulsion selects the one of phenylpropyl alcohol, pure third, elasticity or modified silicon acrylic emulsion; Described wetting ability protecting glue selects the one of polyvinyl alcohol, methylcellulose gum or ethyl cellulose.
2. multicolor finish and preparation method thereof according to claim 1, it is characterized in that, described synthetic resins selects the one of cationic polyacrylamide or fluorine richness copolymer emulsion.
3. multicolor finish and preparation method thereof according to claim 1, it is characterized in that, the salt of calcium, magnesium, aluminium or ammonium selected by described retardant.
4. multicolor finish and preparation method thereof according to claim 1-3 any one, is characterized in that, described film coalescence aid selects the one of butyl glycol ether, 2-Butoxyethyl acetate.
5. multicolor finish and preparation method thereof according to claim 1-4 any one, is characterized in that, comprise the steps:
1) preparation of base paint
To partly water, hydrophilic gel, wetting agent, dispersion agent, defoamer mix, be stirred to uniform state, more slowly add pigment, middling speed is dispersed to fineness 50um; Finally add anionic emulsion, water, film coalescence aid, by thickening material adjustment viscosity to 100-105ku, for subsequent use;
2) toning of base paint
Join in paint mixing cylinder by the base paint prepared, moderate-speed mixer, slowly add aqueous color paste, the mill base conventional by this area is allocated, and is mixed to uniform state, is adjusted to the color designed in advance, for subsequent use;
3) preparation of protecting glue
Be added to by retardant in water, middling speed is dispersed to dissolves completely, then adds synthetic resins, and middling speed dispersion about 30min, to being dissolved to colourless transparent solution completely, and then adding film coalescence aid, mixing;
4) preparation of look grain paint
Respectively by granulating equipment, the base paint after toning is added in granulating equipment, made particle by setting size of particles and joined in protective colloid, stirring at low speed, mix, look grain gelatinization reaction 1-2h, adds synthetic emulsion, and forms stable look grain paint after continuing reaction 1-2h;
5) preparation of multicolor finish
Look grain paint that is not of the same race and ratio is mixed, and stirring at low speed is even, obtained multicolor finish.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410009029.6A CN104761958A (en) | 2014-01-07 | 2014-01-07 | Multi-color coating material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410009029.6A CN104761958A (en) | 2014-01-07 | 2014-01-07 | Multi-color coating material and preparation method thereof |
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| CN104761958A true CN104761958A (en) | 2015-07-08 |
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| CN201410009029.6A Pending CN104761958A (en) | 2014-01-07 | 2014-01-07 | Multi-color coating material and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105754442A (en) * | 2016-04-05 | 2016-07-13 | 佛山市顺德区金涂宝涂料有限公司 | Formula and production method of waterproof breathable water-in-water multicolour coating |
| CN105820636A (en) * | 2016-05-11 | 2016-08-03 | 广东中涂联涂料科技有限公司 | Colorful coating and making method of basic paint of colorful coating |
| CN106147467A (en) * | 2015-04-01 | 2016-11-23 | 山西亮龙涂料有限公司 | A kind of water-soluble colorful coating and preparation technology thereof |
| CN107312461A (en) * | 2017-07-29 | 2017-11-03 | 南通戈雅石业有限公司 | A kind of marble coating |
| CN107603484A (en) * | 2017-09-30 | 2018-01-19 | 太仓市美航涂料有限公司 | A kind of preparation method of exterior wall multicolor finish feature aqueous colorful base paint |
| CN107629531A (en) * | 2017-09-30 | 2018-01-26 | 太仓市美航涂料有限公司 | A kind of exterior wall multicolor finish feature aqueous colorful base paint |
| CN111187550A (en) * | 2018-04-27 | 2020-05-22 | 金华联创塑粉科技有限公司 | Water-based paint suitable for wooden products and preparation method thereof |
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| CN101591491A (en) * | 2008-05-26 | 2009-12-02 | 亚士漆(上海)有限公司 | A kind of fully water based granite multicolor paint and preparation method thereof |
| CN101845260A (en) * | 2010-03-10 | 2010-09-29 | 杭州德尔福涂料有限公司 | Full-aqueous multicolour paint and preparation method thereof |
| CN102660181A (en) * | 2012-05-08 | 2012-09-12 | 上海大学 | Water-in-water imitation granite multicolor coating and preparation method thereof |
| CN103333566A (en) * | 2013-06-05 | 2013-10-02 | 新疆屯河涂料有限公司 | Environmentally-friendly waterborne multicolor paint, preparation method and application method thereof |
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- 2014-01-07 CN CN201410009029.6A patent/CN104761958A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101591491A (en) * | 2008-05-26 | 2009-12-02 | 亚士漆(上海)有限公司 | A kind of fully water based granite multicolor paint and preparation method thereof |
| CN101845260A (en) * | 2010-03-10 | 2010-09-29 | 杭州德尔福涂料有限公司 | Full-aqueous multicolour paint and preparation method thereof |
| CN102660181A (en) * | 2012-05-08 | 2012-09-12 | 上海大学 | Water-in-water imitation granite multicolor coating and preparation method thereof |
| CN103333566A (en) * | 2013-06-05 | 2013-10-02 | 新疆屯河涂料有限公司 | Environmentally-friendly waterborne multicolor paint, preparation method and application method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106147467A (en) * | 2015-04-01 | 2016-11-23 | 山西亮龙涂料有限公司 | A kind of water-soluble colorful coating and preparation technology thereof |
| CN105754442A (en) * | 2016-04-05 | 2016-07-13 | 佛山市顺德区金涂宝涂料有限公司 | Formula and production method of waterproof breathable water-in-water multicolour coating |
| CN105754442B (en) * | 2016-04-05 | 2019-01-18 | 佛山市顺德区金涂宝涂料有限公司 | Water-resistant breathable water-in-water multicolor coating formula and preparation method thereof |
| CN105820636A (en) * | 2016-05-11 | 2016-08-03 | 广东中涂联涂料科技有限公司 | Colorful coating and making method of basic paint of colorful coating |
| CN107312461A (en) * | 2017-07-29 | 2017-11-03 | 南通戈雅石业有限公司 | A kind of marble coating |
| CN107603484A (en) * | 2017-09-30 | 2018-01-19 | 太仓市美航涂料有限公司 | A kind of preparation method of exterior wall multicolor finish feature aqueous colorful base paint |
| CN107629531A (en) * | 2017-09-30 | 2018-01-26 | 太仓市美航涂料有限公司 | A kind of exterior wall multicolor finish feature aqueous colorful base paint |
| CN111187550A (en) * | 2018-04-27 | 2020-05-22 | 金华联创塑粉科技有限公司 | Water-based paint suitable for wooden products and preparation method thereof |
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