CN104031450B - A kind of quick-drying chlorinated rubber building coating - Google Patents
A kind of quick-drying chlorinated rubber building coating Download PDFInfo
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- CN104031450B CN104031450B CN201410275474.7A CN201410275474A CN104031450B CN 104031450 B CN104031450 B CN 104031450B CN 201410275474 A CN201410275474 A CN 201410275474A CN 104031450 B CN104031450 B CN 104031450B
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Abstract
A kind of quick-drying chlorinated rubber building coating, its raw materials by weight portion proportioning is as follows: 100 parts of chlorinated rubbers; Castor oil 35-45 part; Dimethylbenzene 20-30 part; TBHQ 5-15 part; Butyl acrylate 20-30 part; Styrene 10-30 part; Deionized water 60-80 part; Diethylene glycol 10-20 part; Extender pigment 20-30 part; Maleic anhydride 15-25 part; Chlorinated paraffin wax 15-35 part; Cyclohexanone peroxide 20-40 part; Plasticizer 4-8 part; Cobalt octoate 10-30 part; Rutile titanium white powder 25-35 part; Talcum powder 15-35 part; Product viscosity 45-55s, adhesion strength 35-45MPa; Surface drying 40-60min; Soak 60-80d in water after, nothing is abnormal; The film 2800-3000 of resistance to wiping time, can the not division of history into periods of widespread production replace current material.
Description
Technical field
The application belongs to paint field, relates in particular to a kind of quick-drying chlorinated rubber building coating.
Background technology
Coating, in China, tradition name is called paint. So-called coating is be coated in protected or filledThe body surface of decorations, and can form with coated article the continuous film of firm attachment, normally with treeFat or oil or emulsion are main, add or do not add extender pigment, filler, add corresponding helpingAgent, with organic solvent or the formulated thick liquid of butyl acrylate. Chlorinated rubber is by skyOne of chlorinated high polymers that so rubber or synthetic rubber obtain after chlorination modified. Because it hasGood film forming, adhesiveness, corrosion resistance, anti-flammability and insulating properties, can be widely used in systemMake adhesive, marine paint, container paint, chemical anticorrosion paint, traffic paint, fire resistant coating,Building coating and printing-ink etc. are that rising chlorine is one of fine chemical product.Paint finishing can and form complete and tough and tensile protection with the fine bonding of matrix material in body surfaceThe material of film, is called coating. Coating and paint are identical concepts. Paint is that people are in use for a long timeCustom title, introduce after China, just utilize in building trade always. The effect of coating canTo be summarised as three aspects: protective effect, decoration function, specific function effect. One of coatingAs composition: comprise film forming matter, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can form the material of tough and tensile diaphragm, buildsBuilding coating is an important class in coating, in China, generally will be used for inner wall of building,Exterior wall, ceiling, ground, the coating of toilet is called building coating. Building coating has decorationFunction, defencive function and livability are improved function. The shared proportion of various functions is because of application targetDifferent and be not quite similar. Decoration functions is the appearance value that beautifies to improve it by buildingFunction. Mainly comprise design design and the three-dimensional pattern of plane color, pattern and gloss aspectDesign design. But to match with the size and shape of the moulding of building itself and base material itselfClose, just can fully play out. Defencive function refers to that protection building is not subject to the impact of environmentWith the function of destroying. Also each phase not of the content that different types of protected body requires defencive functionWith. As indoor and outdoor application require the index difference that reaches just very large. Building coating conductOne class is mainly used in the coating products of house decoration, and its market development and real estate industry's development are closeCut is closed.
Chlorinated rubber is that the rubber being obtained after chlorination modified by natural rubber or synthetic rubber spreads outProduction product, are the 1st industrialized rubber derivatives in rubber materials, and chlorinated rubber is relatively closeDegree is 1.596, and its water absorption rate is 0.1 to 0.3, and thermal stable temperature is 130 DEG C, dissolves inIn aromatic hydrocarbon, ester class, ketone, ethers, vegetable and animals oils and chlorinated hydrocarbon solution, but be insoluble to fatFat hydrocarbon, alcohols and water 2. Industrial chlorinated rubber is generally white in color or milk yellow is Powdered, sheetShape or fibrous, chlorine mass fraction, between 62～65, has good heat resistance. From " historyOn the tightest policy of real estate " put into effect since, market of real estate development is absorbed in low ebb, especiallyBe enter 2012 since, the policy of expection is loosening before does not occur, is firmly to build on the contraryPortion clearly represents that in the short time, policy of regulation and control can not change. Some buildings to mildew-resistant, fire prevention,Insulation, corrosion-resistant etc. has particular/special requirement. It is mainly to indoor application that livability is improved function, contribute to exactly to improve the function of living environment, as sound-proofing, sound absorption properties, anti-condensationProperty etc. And universal along with humanity concept, and the formation of novel harmonious society, design is a kind ofViscosity is high, the quick-drying chlorinated rubber building coating of fast drying, resistance to water and resistance to wiping excellence isVery necessary.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of quick-drying chlorinated rubber building coating, separatesThe existing quick-drying chlorinated rubber building coating viscosity of determining is low, dry slow, resistance to water and resistance to wiping poorEtc. technical problem.
Technical scheme:
A kind of quick-drying chlorinated rubber building coating, the raw material of described quick-drying chlorinated rubber building coatingProportioning is as follows by weight: 100 parts of chlorinated rubbers; Castor oil 35-45 part; Dimethylbenzene20-30 part; TBHQ 5-15 part; Butyl acrylate 20-30 part; Styrene10-30 part; Deionized water 60-80 part; Diethylene glycol 10-20 part; Extender pigment 20-30Part; Maleic anhydride 15-25 part; Chlorinated paraffin wax 15-35 part; Cyclohexanone peroxide 20-40Part; Plasticizer 4-8 part; Cobalt octoate 10-30 part; Rutile titanium white powder 25-35 part; TalcumPowder 15-35 part.
As a preferred technical solution of the present invention: described quick-drying chlorinated rubber building coatingRaw materials by weight portion proportioning is as follows: 100 parts of chlorinated rubbers; 40 parts of castor oil; Dimethylbenzene25 parts; 10 parts of TBHQs; 25 parts of butyl acrylates; 20 parts of styrene; Go70 parts of ionized waters; 15 parts of diethylene glycols; 28 parts of extender pigments; 20 parts of maleic anhydrides;25 parts of chlorinated paraffin waxs; 30 parts of cyclohexanone peroxides; 6 parts, plasticizer; 20 parts of cobalt octoates;30 parts, rutile titanium white powder; 25 parts of talcum powder.
As a preferred technical solution of the present invention: described extender pigment adopts lightweight carbonic acidCalcium.
As a preferred technical solution of the present invention: described plasticizer adopts phthalic acid twoButyl ester.
Beneficial effect:
A kind of quick-drying chlorinated rubber building coating of the present invention adopts above technical scheme with existingThere is technology to compare, there is following technique effect: 1, product viscosity 45-55s, adhesion strength35-45MPa; 2, surface drying 40-60min; Soak 60-80d in water after, nothing is abnormal; 3, be coated withThe film 2800-3000 of resistance to wiping time, can the not division of history into periods of widespread production replace current material.
Detailed description of the invention
Embodiment 1:
A kind of quick-drying chlorinated rubber building coating, its raw materials by weight portion proportioning is as follows: chlorination100 parts of rubber; 35 parts of castor oil; 20 parts of dimethylbenzene; 5 parts of TBHQs; Third20 parts of olefin(e) acid butyl esters; 10 parts of styrene; 60 parts of deionized waters; 10 parts of diethylene glycols; Gently20 parts, matter calcium carbonate; 15 parts of maleic anhydrides; 15 parts of chlorinated paraffin waxs; Peroxidating hexamethylene20 parts of ketone; 4 parts of dibutyl phthalates; 10 parts of cobalt octoates; Rutile titanium white powder 25Part; 15 parts of talcum powder.
After castor oil is added in deionized water and to be dissolved, add chlorinated rubber, dimethylbenzene, propyleneAcid butyl ester, precipitated calcium carbonate, dibutyl phthalate, chlorinated paraffin wax, rutile titanium white powder,With ball mill ball milling 30min, then add TBHQ, styrene and surplus stock,Ball milling 30min had both obtained finished product.
Product viscosity 45s, adhesion strength 35MPa; Surface drying 60min; In water, soak 60dAfterwards without abnormal; The resistance to wiping of film 2800 times.
Embodiment 2:
A kind of quick-drying chlorinated rubber building coating, its raw materials by weight portion proportioning is as follows: chlorination100 parts of rubber; 45 parts of castor oil; 30 parts of dimethylbenzene; 15 parts of TBHQs;30 parts of butyl acrylates; 30 parts of styrene; 80 parts of deionized waters; 20 parts of diethylene glycols;30 parts of precipitated calcium carbonates; 25 parts of maleic anhydrides; 35 parts of chlorinated paraffin waxs; Peroxidating ring40 parts of hexanones; 8 parts of dibutyl phthalates; 30 parts of cobalt octoates; Rutile titanium white powder35 parts; 35 parts of talcum powder.
After castor oil is added in deionized water and to be dissolved, add chlorinated rubber, dimethylbenzene, propyleneAcid butyl ester, precipitated calcium carbonate, dibutyl phthalate, chlorinated paraffin wax, rutile titanium white powder,With ball mill ball milling 30min, then add TBHQ, styrene and surplus stock,Ball milling 30min had both obtained finished product.
Product viscosity 50s, adhesion strength 40MPa; Surface drying 50min; In water, soak 70dAfterwards without abnormal; The resistance to wiping of film 2900 times.
Embodiment 3:
A kind of quick-drying chlorinated rubber building coating, its raw materials by weight portion proportioning is as follows: chlorination100 parts of rubber; 40 parts of castor oil; 25 parts of dimethylbenzene; 10 parts of TBHQs;25 parts of butyl acrylates; 20 parts of styrene; 70 parts of deionized waters; 15 parts of diethylene glycols;28 parts of precipitated calcium carbonates; 20 parts of maleic anhydrides; 25 parts of chlorinated paraffin waxs; Peroxidating ring30 parts of hexanones; 6 parts of dibutyl phthalates; 20 parts of cobalt octoates; Rutile titanium white powder30 parts; 25 parts of talcum powder.
After castor oil is added in deionized water and to be dissolved, add chlorinated rubber, dimethylbenzene, propyleneAcid butyl ester, precipitated calcium carbonate, dibutyl phthalate, chlorinated paraffin wax, rutile titanium white powder,With ball mill ball milling 30min, then add TBHQ, styrene and surplus stock,Ball milling 30min had both obtained finished product.
Product viscosity 55s, adhesion strength 45MPa; Surface drying 40min; In water, soak 80dAfterwards without abnormal; The resistance to wiping of film 3000 times.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, because ofThis any change in implication and the scope suitable with claims of the present invention, all shouldThink to be included in the scope of claims.
Claims (2)
1. a quick-drying chlorinated rubber building coating, is characterized in that described quick-drying chlorinated rubberThe raw materials by weight portion proportioning of building coating is as follows: 100 parts of chlorinated rubbers; Castor oil 35-45Part; Dimethylbenzene 20-30 part; TBHQ 5-15 part; Butyl acrylate 20-30Part; Styrene 10-30 part; Deionized water 60-80 part; Diethylene glycol 10-20 part; PhysiquePigment 20-30 part; Maleic anhydride 15-25 part; Chlorinated paraffin wax 15-35 part; PeroxidatingCyclohexanone 20-40 part; Plasticizer 4-8 part; Cobalt octoate 10-30 part; Rutile titanium white powder25-35 part; Talcum powder 15-35 part;
Described extender pigment adopts precipitated calcium carbonate;
Described plasticizer adopts dibutyl phthalate.
2. a kind of quick-drying chlorinated rubber building coating according to claim 1, its featureThe raw materials by weight portion proportioning that is described quick-drying chlorinated rubber building coating is as follows: chlorination rubber100 parts, glue; 40 parts of castor oil; 25 parts of dimethylbenzene; 10 parts of TBHQs; Third25 parts of olefin(e) acid butyl esters; 20 parts of styrene; 70 parts of deionized waters; 15 parts of diethylene glycols; Body28 parts of matter pigment; 20 parts of maleic anhydrides; 25 parts of chlorinated paraffin waxs; Cyclohexanone peroxide30 parts; 6 parts, plasticizer; 20 parts of cobalt octoates; 30 parts, rutile titanium white powder; Talcum powder 25Part.
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| CN201410275474.7A CN104031450B (en) | 2014-06-19 | 2014-06-19 | A kind of quick-drying chlorinated rubber building coating |
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| CN104194445A (en) * | 2014-09-19 | 2014-12-10 | 苏州洛特兰新材料科技有限公司 | Chlorinated rubber exterior wall coating |
| CN105602308A (en) * | 2015-12-22 | 2016-05-25 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Quick-drying paint material composition for metal surface and preparation method of quick-drying paint |
| CN107473699A (en) * | 2017-08-22 | 2017-12-15 | 佛山市因诺维生物科技有限公司 | A kind of indoor mildew resistant paint |
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| JPS5433538A (en) * | 1977-08-22 | 1979-03-12 | Nippon Zeon Co Ltd | Improved chlorinated rubber composition for coating |
| KR100644770B1 (en) * | 2005-12-30 | 2006-11-15 | (주)디피아이 홀딩스 | Transparent fireproofing coating composition and method of fireproofing an object using the same |
| CN101113295A (en) * | 2006-07-28 | 2008-01-30 | 中宏（天津）实业有限公司 | Waterproofing paint capable of constructing on building damp and moisture-free basis |
| CN102993836B (en) * | 2012-11-23 | 2015-09-09 | 南通市晗泰化工有限公司 | The preparation method of aqueous acrylic modified high chlorinated polyethylene anti-corrosive paint |
| CN103627259A (en) * | 2013-11-14 | 2014-03-12 | 江苏博思源防火材料科技有限公司 | Chlorinated rubber fire-retardant paint |
| CN103820011A (en) * | 2014-02-26 | 2014-05-28 | 南通顺阳化工有限公司 | Chlorinated rubber coating with rust |
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Effective date of registration: 20201228 Address after: 215200 No.478 Jinhua Road, Jinjiaba, Lili Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: West clean environmental protection technology (Suzhou) Co.,Ltd. Address before: 215200 Lao Wu Tong Highway, Songling Town, Wujiang District, Suzhou, Jiangsu Patentee before: WUJIANG HUACHENG COMPOSITE MATERIAL SCIENCE & TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20221109 Address after: 215200 No. 18, Suzhou River Road, Songling Town, Wujiang District, Suzhou City, Jiangsu Province (Science Park of Taihu New Town) Patentee after: SUZHOU HUANYAN ELECTRICAL Co.,Ltd. Address before: 215200 No.478 Jinhua Road, Jinjiaba, Lili Town, Wujiang District, Suzhou City, Jiangsu Province Patentee before: West clean environmental protection technology (Suzhou) Co.,Ltd. |