CN104194515A - Water-in-water type colorful interior wall coating - Google Patents

Water-in-water type colorful interior wall coating Download PDF

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Publication number
CN104194515A
CN104194515A CN201410483068.XA CN201410483068A CN104194515A CN 104194515 A CN104194515 A CN 104194515A CN 201410483068 A CN201410483068 A CN 201410483068A CN 104194515 A CN104194515 A CN 104194515A
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China
Prior art keywords
parts
water
ethylene glycol
interior wall
wall coating
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Pending
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CN201410483068.XA
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Chinese (zh)
Inventor
马志明
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Suzhou Luotelan New Material Technology Co Ltd
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Suzhou Luotelan New Material Technology Co Ltd
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Priority to CN201410483068.XA priority Critical patent/CN104194515A/en
Publication of CN104194515A publication Critical patent/CN104194515A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a water-in-water type colorful interior wall coating which comprises the following raw materials in parts by weight: 100 parts of styrene-acrylic emulsion, 5-15 parts of isooctyl acetate, 1-10 parts of ethylene glycol monoethyl ether, 10-20 parts of methyl isobutyl ketone, 30-40 parts of tributyl phosphate, 5-25 parts of ethylene glycol ethyl ether acetate, 80-90 parts of deionized water, 25-35 parts of nitrocotton, 10-20 parts of pigment, 15-25 parts of polyvinyl acetate, 20-30 parts of sodium tripolyphosphate, 25-45 parts of ethylene glycol monoethyl ether acetate, 8-10 parts of a plasticizer, 15-35 parts of linseed oil, 20-40 parts of ethylene glycol monobutyl ether and 10-30 parts of sodium hydroxide. The water-in-water type colorful interior wall coating has no toxicity or smell; a coating film resists scrubbing for 2,000-4,000 times without exposing the base; no blistering or picking occurs after the water-in-water type colorful interior wall coating is soaked in water of 20DEG C for 20-40 days; the surface is dried after 0.5-1.5 hours, and resists the alkaline saturated calcium hydroxide solution for 10-30 days; the coating is bright in color and good in decoration, can be widely produced and continuously replaces the existing material.

Description

A kind of water-in-water type multi-color interior wall coating
Technical field
The application belongs to paint field, relates in particular to a kind of water-in-water type multi-color interior wall coating.
Background technology
Coating, in China, tradition name is called paint.So-called coating is to be coated in protected or decorated body surface; and can form with coated article the continuous film of firm attachment; normally taking resin oil or emulsion as main; add or do not add pigment, filler; add corresponding additive, with organic solvent or the formulated thick liquid of tributyl phosphate.China's coating circle more authoritative " coating process " book is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name film forming like this, claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.Benzene emulsion (cinnamic acrylic ester emulsion) is to be obtained through emulsion copolymerization by vinylbenzene and acrylate monomer.Benzene emulsion is in letex polymerization, to study more system, and there are one of ten large non-crosslinked type emulsions of essential industry using value the Ye Shi world today.
Coating refers to the general name that is applied to body surface and can form the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, and ceiling, ground, the coating of toilet is called building coating.Interior wall coating is exactly the emulsion paint of generally fitting up use.Emulsion paint is emulsion coating, according to the difference of base material, is divided into polyvinyl acetate emulsion and the large class of ACRYLIC EMULSION two.Emulsion paint is taking water as thinner, be a kind of easy construction, safe, water-fastness, good permeability coating, it can mix different color and lusters according to different scheme of colo(u)r.Kind: water-based inner wall paint, oiliness interior wall paint, dry powder type interior wall paint, belong to water-borne coatings, mainly by water, emulsion, pigment, filler, five kinds of compositions of additive form.
So-called water-in-water type multi-color interior wall coating is made up of inconsistent two phase compositions, and wherein a phase dispersion medium is external phase, and another is disperse phase mutually, when application, by disposable spray finishing, just can obtain pattern luxurious, attractive in appearance, water-in-water type multi-color.Interior wall paint also makes interior wall coating comprise liquid coating and powder coating, and common emulsion paint, wall paint belong to liquid coating.In the making composition of interior wall coating, be substantially made up of water, pigment, emulsion, weighting agent and various auxiliary agent, these starting material are not contain what toxicity.As emulsion paint, may be toxic be mainly that ethylene glycol in film coalescence aid is with the organic mercury in Fang Mildew agent.And universal along with humanity concept, and the formation of novel harmonious society, the water-in-water type multi-color interior wall coating that designs a kind of water tolerance, scrub resistance and alkali resistance excellence is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of water-in-water type multi-color interior wall coating, solves poor, the ornamental technical problem such as low of existing water-in-water type multi-color interior wall coating water tolerance and scrub resistance.
Technical scheme:
A kind of water-in-water type multi-color interior wall coating, the raw materials by weight portion proportioning of described water-in-water type multi-color interior wall coating is as follows: 100 parts of benzene emulsions; 2-ethyl hexyl ethanoate 5-15 part; Ethylene glycol monoethyl ether 1-10 part; Hexone 10-20 part; Tributyl phosphate 30-40 part; Ethyl cellosolve acetate 5-25 part; Deionized water 80-90 part; Nitro-cotton 25-35 part; Pigment 10-20 part; Vinyl Acetate Copolymer 15-25 part; Tripoly phosphate sodium STPP 20-30 part; Ethylene glycol ether acetate 25-45 part; Softening agent 8-10 part; Linseed oil 15-35 part; Ethylene glycol monobutyl ether 20-40 part; Sodium hydroxide 10-30 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described water-in-water type multi-color interior wall coating is as follows: 100 parts of benzene emulsions; 10 parts of 2-ethyl hexyl ethanoates; 5 parts of ethylene glycol monoethyl ethers; 15 parts of hexones; 35 parts of tributyl phosphates; 15 parts of ethyl cellosolve acetates; 85 parts of deionized waters; 30 parts of nitro-cottons; 15 parts of pigment; 20 parts of Vinyl Acetate Copolymer; 25 parts of tripoly phosphate sodium STPPs; 35 parts of ethylene glycol ether acetates; 9 parts, softening agent; 25 parts of linseed oil; 30 parts of ethylene glycol monobutyl ethers; 20 parts, sodium hydroxide.
As a preferred technical solution of the present invention: described pigment adopts red iron oxide, medium chrome yellow medium yellow or iron oxide black.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of water-in-water type multi-color interior wall coating of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product is nontoxic, tasteless, and film scrubbing resistance 2000-4000 time is not show-through; 2, non-foaming soak 20-40d in 20 DEG C of water after, dry linting not; 3, surface drying 0.5-1.5h, the saturated aqua calcis 10-30d of alkali resistance; 4, bright in luster, the good decorative property of film, can the not division of history into periods of widespread production for current material.
Embodiment
Embodiment 1:
A kind of water-in-water type multi-color interior wall coating, its raw materials by weight portion proportioning is as follows: 100 parts of benzene emulsions; 5 parts of 2-ethyl hexyl ethanoates; 1 part of ethylene glycol monoethyl ether; 10 parts of hexones; 30 parts of tributyl phosphates; 5 parts of ethyl cellosolve acetates; 80 parts of deionized waters; 25 parts of nitro-cottons; 10 parts of iron oxide blacks; 15 parts of Vinyl Acetate Copolymer; 20 parts of tripoly phosphate sodium STPPs; 25 parts of ethylene glycol ether acetates; 8 parts of dibutyl phthalates; 15 parts of linseed oil; 20 parts of ethylene glycol monobutyl ethers; 10 parts, sodium hydroxide.
Benzene emulsion, ethylene glycol monoethyl ether, hexone, tributyl phosphate and ethyl cellosolve acetate are added in deionized water, be heated to 40 DEG C and stir 3h, add nitro-cotton, Vinyl Acetate Copolymer, tripoly phosphate sodium STPP, ethylene glycol ether acetate, ethylene glycol monobutyl ether and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add 2-ethyl hexyl ethanoate and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 2000 times, non-foaming soak 20d in 20 DEG C of water after, dry linting not; Surface drying 1.5h, the saturated aqua calcis 10d of alkali resistance.
Embodiment 2:
A kind of water-in-water type multi-color interior wall coating, its raw materials by weight portion proportioning is as follows: 100 parts of benzene emulsions; 15 parts of 2-ethyl hexyl ethanoates; 10 parts of ethylene glycol monoethyl ethers; 20 parts of hexones; 40 parts of tributyl phosphates; 25 parts of ethyl cellosolve acetates; 90 parts of deionized waters; 35 parts of nitro-cottons; 20 parts of medium chrome yellow medium yellows; 25 parts of Vinyl Acetate Copolymer; 30 parts of tripoly phosphate sodium STPPs; 45 parts of ethylene glycol ether acetates; 10 parts of dibutyl phthalates; 35 parts of linseed oil; 40 parts of ethylene glycol monobutyl ethers; 30 parts, sodium hydroxide.
Benzene emulsion, ethylene glycol monoethyl ether, hexone, tributyl phosphate and ethyl cellosolve acetate are added in deionized water, be heated to 40 DEG C and stir 3h, add nitro-cotton, Vinyl Acetate Copolymer, tripoly phosphate sodium STPP, ethylene glycol ether acetate, ethylene glycol monobutyl ether and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add 2-ethyl hexyl ethanoate and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 3000 times, non-foaming soak 30d in 20 DEG C of water after, dry linting not; Surface drying 1h, the saturated aqua calcis 20d of alkali resistance.
Embodiment 3:
A kind of water-in-water type multi-color interior wall coating, its raw materials by weight portion proportioning is as follows: 100 parts of benzene emulsions; 10 parts of 2-ethyl hexyl ethanoates; 5 parts of ethylene glycol monoethyl ethers; 15 parts of hexones; 35 parts of tributyl phosphates; 15 parts of ethyl cellosolve acetates; 85 parts of deionized waters; 30 parts of nitro-cottons; 15 parts of red iron oxides; 20 parts of Vinyl Acetate Copolymer; 25 parts of tripoly phosphate sodium STPPs; 35 parts of ethylene glycol ether acetates; 9 parts of dibutyl phthalates; 25 parts of linseed oil; 30 parts of ethylene glycol monobutyl ethers; 20 parts, sodium hydroxide.
Benzene emulsion, ethylene glycol monoethyl ether, hexone, tributyl phosphate and ethyl cellosolve acetate are added in deionized water, be heated to 40 DEG C and stir 3h, add nitro-cotton, Vinyl Acetate Copolymer, tripoly phosphate sodium STPP, ethylene glycol ether acetate, ethylene glycol monobutyl ether and dibutyl phthalate, be warming up to 50 DEG C with ball mill ball milling 10min, add 2-ethyl hexyl ethanoate and surplus stock, be warming up to 60 DEG C and both stir after 10h to obtain finished product.
Film scrubbing resistance 4000 times, non-foaming soak 40d in 20 DEG C of water after, dry linting not; Surface drying 0.5h, the saturated aqua calcis 30d of alkali resistance.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.

Claims (4)

1. a water-in-water type multi-color interior wall coating, is characterized in that the raw materials by weight portion proportioning of described water-in-water type multi-color interior wall coating is as follows: 100 parts of benzene emulsions; 2-ethyl hexyl ethanoate 5-15 part; Ethylene glycol monoethyl ether 1-10 part; Hexone 10-20 part; Tributyl phosphate 30-40 part; Ethyl cellosolve acetate 5-25 part; Deionized water 80-90 part; Nitro-cotton 25-35 part; Pigment 10-20 part; Vinyl Acetate Copolymer 15-25 part; Tripoly phosphate sodium STPP 20-30 part; Ethylene glycol ether acetate 25-45 part; Softening agent 8-10 part; Linseed oil 15-35 part; Ethylene glycol monobutyl ether 20-40 part; Sodium hydroxide 10-30 part.
2. a kind of water-in-water type multi-color interior wall coating according to claim 1, is characterized in that the raw materials by weight portion proportioning of described water-in-water type multi-color interior wall coating is as follows: 100 parts of benzene emulsions; 10 parts of 2-ethyl hexyl ethanoates; 5 parts of ethylene glycol monoethyl ethers; 15 parts of hexones; 35 parts of tributyl phosphates; 15 parts of ethyl cellosolve acetates; 85 parts of deionized waters; 30 parts of nitro-cottons; 15 parts of pigment; 20 parts of Vinyl Acetate Copolymer; 25 parts of tripoly phosphate sodium STPPs; 35 parts of ethylene glycol ether acetates; 9 parts, softening agent; 25 parts of linseed oil; 30 parts of ethylene glycol monobutyl ethers; 20 parts, sodium hydroxide.
3. a kind of water-in-water type multi-color interior wall coating according to claim 1, is characterized in that: described pigment adopts red iron oxide, medium chrome yellow medium yellow or iron oxide black.
4. a kind of water-in-water type multi-color interior wall coating according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
CN201410483068.XA 2014-09-19 2014-09-19 Water-in-water type colorful interior wall coating Pending CN104194515A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817917A (en) * 2015-05-21 2015-08-05 黎司华 Water-in-water type colorful interior wall coating
CN105086647A (en) * 2015-08-03 2015-11-25 苏州舒而适纺织新材料科技有限公司 Polystyrene multi-color coating

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Publication number Priority date Publication date Assignee Title
CN1083504A (en) * 1993-09-10 1994-03-09 王衡新 Mutually intersecting network polymer multi-colour water-coluble figure paint
CN1097782A (en) * 1994-05-20 1995-01-25 苏州市建筑材料科学研究所 Water-in-water aromatic multi-colour pattern paint
CN1103092A (en) * 1993-11-26 1995-05-31 中国矿业大学 Water-in-water type multi-colour figure paint
CN1109901A (en) * 1994-05-25 1995-10-11 湘潭市南方高新技术研究所 Dual-water-phase colour pattern paint
EP2452987A1 (en) * 2010-11-12 2012-05-16 Toupret SA Coating containing a pH indicator
CN103421395A (en) * 2013-08-19 2013-12-04 南通市通州区俊朗建筑工程有限公司 Water-in-water multicolor paint

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1083504A (en) * 1993-09-10 1994-03-09 王衡新 Mutually intersecting network polymer multi-colour water-coluble figure paint
CN1103092A (en) * 1993-11-26 1995-05-31 中国矿业大学 Water-in-water type multi-colour figure paint
CN1097782A (en) * 1994-05-20 1995-01-25 苏州市建筑材料科学研究所 Water-in-water aromatic multi-colour pattern paint
CN1109901A (en) * 1994-05-25 1995-10-11 湘潭市南方高新技术研究所 Dual-water-phase colour pattern paint
EP2452987A1 (en) * 2010-11-12 2012-05-16 Toupret SA Coating containing a pH indicator
CN103421395A (en) * 2013-08-19 2013-12-04 南通市通州区俊朗建筑工程有限公司 Water-in-water multicolor paint

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北京市油漆厂编: "《涂料工业》", 31 August 1975, 石油化学工业出版社 *
崔春芳等: "《美术涂料与装饰技术手册》", 31 July 2010, 化学工业出版社 *
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817917A (en) * 2015-05-21 2015-08-05 黎司华 Water-in-water type colorful interior wall coating
CN105086647A (en) * 2015-08-03 2015-11-25 苏州舒而适纺织新材料科技有限公司 Polystyrene multi-color coating

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Application publication date: 20141210