CN103864157A - Preparation method of amorphous nickel sulfide - Google Patents
Preparation method of amorphous nickel sulfide Download PDFInfo
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- CN103864157A CN103864157A CN201410074075.4A CN201410074075A CN103864157A CN 103864157 A CN103864157 A CN 103864157A CN 201410074075 A CN201410074075 A CN 201410074075A CN 103864157 A CN103864157 A CN 103864157A
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- Prior art keywords
- sulfide
- copper
- dispersion agent
- nickel sulfide
- preparation
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- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 title abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000010949 copper Substances 0.000 claims abstract description 46
- 229910052802 copper Inorganic materials 0.000 claims abstract description 46
- 238000003756 stirring Methods 0.000 claims abstract description 38
- 229910052979 sodium sulfide Inorganic materials 0.000 claims abstract description 16
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000000694 effects Effects 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 9
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 56
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 43
- LVIYYTJTOKJJOC-UHFFFAOYSA-N nickel phthalocyanine Chemical compound [Ni+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 LVIYYTJTOKJJOC-UHFFFAOYSA-N 0.000 claims description 43
- 239000007788 liquid Substances 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 33
- 239000006185 dispersion Substances 0.000 claims description 32
- 235000010265 sodium sulphite Nutrition 0.000 claims description 22
- 239000008399 tap water Substances 0.000 claims description 18
- 235000020679 tap water Nutrition 0.000 claims description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 229920001021 polysulfide Polymers 0.000 abstract description 4
- 239000005077 polysulfide Substances 0.000 abstract description 4
- 150000008117 polysulfides Polymers 0.000 abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 3
- 230000003247 decreasing effect Effects 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 230000002829 reductive effect Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 3
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005363 electrowinning Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
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Abstract
The invention relates to a chemical purification method, and in particular relates to a preparation method of amorphous nickel sulfide. The preparation method provided by the invention is obviously different from the traditional nickel sulfide preparation method and is characterized in that a stabilizer is added when sodium sulfide is dissolved, so that the oxidation of the sodium sulfide is avoided and the system reducibility is ensured at the same time; a dispersant is added, so that a polysulfide is prevented from formed in the sodium sulfide; and a reducing agent is added into a copper suspension, so that the reducibility of the system for preparing the nickel sulfide is presented. When the amorphous nickel sulfide is prepared, the adding quantity of the sodium sulfide is controlled and the even stirring is carried out, so that the local excess sulfur source is avoided, namely, the polysulfide formed due to the local excess sulfur source is avoided; and meanwhile, the dispersant is added, so that the collision probability among the nickel sulfides is reduced, namely, the activity of nickel sulfide is maintained for a long time. According to the traditional method, after the prepared nickel sulfide is placed in the air for 24 hours, the copper removal activity of the nickel sulfide is gradually decreased; and after the prepared nickel sulfide is placed in the air for 48 hours, the copper removal activity of the nickel sulfide is decreased to 15% to 20%. According to the method provided by the invention, after the amorphous nickel sulfide is placed in the air for 7 days, the copper removal activity of the amorphous nickel sulfide can be still maintained at 80% to 90%.
Description
Technical field
The present invention relates to chemical industry purifying method, particularly a kind of preparation method of non-crystalline state nickelous sulfide.
Background technology
In traditional nickelous sulfide preparation process, directly sodium sulphite is dissolved, then join after copper reaction in liquid and generate nickelous sulfide.In the time that sodium sulphite dissolves, owing to containing a small amount of dissolved oxygen in solution, can react after running into the sodium sulphite of reductibility, oxidized portion sodium sulphite, the consumption of sodium sulphite rises, and utilization ratio declines; Sodium sulphite joins after copper removal and in liquid, reacts and generate nickel sulphide solids particle, because grain graininess is little, surface atom ratio is large, specific surface area is large, surface can be large, and in energy unsteady state, nickel sulphide solids particle all trends towards flocking together, the reunion of nickelous sulfide occurs, and production efficiency is low.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of with low cost, non-crystalline state nickelous sulfide that production efficiency is high.
The technical solution adopted for the present invention to solve the technical problems is:
A preparation method for non-crystalline state nickelous sulfide, concrete steps are as follows:
A, sodium sulphite dissolve
The tap water that is 5 ~ 25 ℃ by temperature joins in sodium sulphite dissolving tank, add stablizer, stablizer and tap water volume ratio are 0.18 ~ 0.25:100, stir 10 ~ 20 minutes, add purity 60% industrial sodium sulfide, dissolve postcure na concn and be controlled at 90 ~ 120g/l, stir 1 ~ 1.5 hour, add dispersion agent, dispersion agent and tap water volume ratio are 0.15 ~ 0.2:100 again, stir 0.5 ~ 1 hour;
B, the preparation of non-crystalline state nickelous sulfide
Another extracting container adds liquid after copper removal, nickel concentration 75 ~ 85g/l in liquid after copper removal, temperature is 20 ~ 40 ℃, pH value is 3.2 ~ 3.6, adds sodium sulphite anhydrous 99.3, stirs 0.5 ~ 1 hour, after S-WAT dissolves, concentration is 0.8 ~ 1g/l, add dispersion agent, after dispersion agent and copper, liquid volume ratio is 0.2 ~ 0.25:100 again, stirs 15 ~ 30 minutes; By the sodium sulfide solution of step a and above-mentioned solution by volume 1.0 ~ 1.3:1 mix, stir and within 0.5 ~ 1 hour, make non-crystalline state nickelous sulfide pulp liquid.
In described step b, add dispersion agent and stablizer, can keep for a long time it to remove copper activity.
Described dispersion agent is that polyoxyethylene glycol, the stablizer of purity 99% is the hydrazine hydrate of massfraction 80%.
The present invention has significantly different from traditional nickelous sulfide preparation method: sodium sulphite has added stablizer while dissolving, prevents the oxidation of sodium sulphite, guarantees to add dispersion agent by system reducing simultaneously, prevents from forming between sodium sulphite polysulfide.After copper, liquid adds reductive agent, makes system prepared by nickelous sulfide present reductibility.When preparation, control add-on the uniform stirring of sodium sulphite, prevent that local sulphur source is excessive, form polysulfide, add dispersion agent simultaneously, reduce the probability of collision between nickelous sulfide, can keep for a long time active.Nickelous sulfide prepared by traditional method was placed after 24 hours in air, except copper activity reduces gradually, placed and exceeded after 48 hours, and activity is down to 15% ~ 20%.Non-crystalline state nickelous sulfide of the present invention is placed 7 days in air, except copper activity still can keep 80% ~ 90%.
Accompanying drawing explanation
Fig. 1 is process flow sheet of the present invention.
Embodiment
A preparation method for non-crystalline state nickelous sulfide, concrete steps are as follows:
A, sodium sulphite dissolve
The tap water that is 5 ~ 25 ℃ by temperature joins in sodium sulphite dissolving tank, add stablizer, stablizer and tap water volume ratio are 0.18 ~ 0.25:100, stir 10 ~ 20 minutes, add purity 60% industrial sodium sulfide, dissolve postcure na concn and be controlled at 90 ~ 120g/l, stir 1 ~ 1.5 hour, add dispersion agent, dispersion agent and tap water volume ratio are 0.15 ~ 0.2:100 again, stir 0.5 ~ 1 hour;
B, the preparation of non-crystalline state nickelous sulfide
Another extracting container adds liquid after copper removal, nickel concentration 75 ~ 85g/l in liquid after copper removal, temperature is 20 ~ 40 ℃, pH value is 3.2 ~ 3.6, adds sodium sulphite anhydrous 99.3, stirs 0.5 ~ 1 hour, after S-WAT dissolves, concentration is 0.8 ~ 1g/l, add dispersion agent, after dispersion agent and copper, liquid volume ratio is 0.2 ~ 0.25:100 again, stirs 15 ~ 30 minutes; By the sodium sulfide solution of step a and above-mentioned solution by volume 1.0 ~ 1.3:1 mix, stir and within 0.5 ~ 1 hour, make non-crystalline state nickelous sulfide pulp liquid.
In described step b, add dispersion agent and stablizer, can keep for a long time it to remove copper activity.
Described dispersion agent is that polyoxyethylene glycol, the stablizer of purity 99% is the hydrazine hydrate of massfraction 80%.
Embodiment 1
A preparation method for non-crystalline state nickelous sulfide, concrete steps are as follows:
A, sodium sulphite dissolve
The tap water that is 5 ~ 25 ℃ by temperature joins in sodium sulphite dissolving tank, add stablizer, stablizer and tap water volume ratio are 0.18:100, stir 10 ~ 20 minutes, add purity 60% industrial sodium sulfide, dissolve postcure na concn and be controlled at 90g/l, stir 1 ~ 1.5 hour, add dispersion agent, dispersion agent and tap water volume ratio are 0.15:100 again, stir 0.5 ~ 1 hour;
B, the preparation of non-crystalline state nickelous sulfide
Another extracting container adds liquid after copper removal, nickel concentration 75g/l in liquid after copper removal, temperature is 20 ~ 40 ℃, pH value is 3.2 ~ 3.6, adds sodium sulphite anhydrous 99.3, stirs 0.5 ~ 1 hour, after S-WAT dissolves, concentration is 0.8g/l, add dispersion agent, after dispersion agent and copper, liquid volume ratio is 0.2:100 again, stirs 15 ~ 30 minutes; By the sodium sulfide solution of step a and above-mentioned solution by volume 1.0:1 mix, stir and within 0.5 ~ 1 hour, make non-crystalline state nickelous sulfide pulp liquid.
Embodiment 2
A preparation method for non-crystalline state nickelous sulfide, concrete steps are as follows:
A, sodium sulphite dissolve
The tap water that is 5 ~ 25 ℃ by temperature joins in sodium sulphite dissolving tank, add stablizer, stablizer and tap water volume ratio are 0.25:100, stir 10 ~ 20 minutes, add purity 60% industrial sodium sulfide, dissolve postcure na concn and be controlled at 120g/l, stir 1 ~ 1.5 hour, add dispersion agent, dispersion agent and tap water volume ratio are 0.2:100 again, stir 0.5 ~ 1 hour;
B, the preparation of non-crystalline state nickelous sulfide
Another extracting container adds liquid after copper removal, nickel concentration 85g/l in liquid after copper removal, temperature is 20 ~ 40 ℃, pH value is 3.2 ~ 3.6, adds sodium sulphite anhydrous 99.3, stirs 0.5 ~ 1 hour, after S-WAT dissolves, concentration is 1g/l, add dispersion agent, after dispersion agent and copper, liquid volume ratio is 0.25:100 again, stirs 15 ~ 30 minutes; By the sodium sulfide solution of step a and above-mentioned solution by volume 1.3:1 mix, stir and within 0.5 ~ 1 hour, make non-crystalline state nickelous sulfide pulp liquid.
Embodiment 3
A preparation method for non-crystalline state nickelous sulfide, concrete steps are as follows:
A, sodium sulphite dissolve
The tap water that is 5 ~ 25 ℃ by temperature joins in sodium sulphite dissolving tank, add stablizer, stablizer and tap water volume ratio are 0.2:100, stir 10 ~ 20 minutes, add purity 60% industrial sodium sulfide, dissolve postcure na concn and be controlled at 100g/l, stir 1 ~ 1.5 hour, add dispersion agent, dispersion agent and tap water volume ratio are 0.16:100 again, stir 0.5 ~ 1 hour;
B, the preparation of non-crystalline state nickelous sulfide
Another extracting container adds liquid after copper removal, nickel concentration 75 ~ 85g/l in liquid after copper removal, temperature is 20 ~ 40 ℃, pH value is 3.2 ~ 3.6, adds sodium sulphite anhydrous 99.3, stirs 0.5 ~ 1 hour, after S-WAT dissolves, concentration is 0.9g/l, add dispersion agent, after dispersion agent and copper, liquid volume ratio is 0.21:100 again, stirs 15 ~ 30 minutes; By the sodium sulfide solution of step a and above-mentioned solution by volume 1.1:1 mix, stir and within 0.5 ~ 1 hour, make non-crystalline state nickelous sulfide pulp liquid.
Non-crystalline state nickelous sulfide prepared by embodiment 1 is placed the non-crystalline state nickelous sulfide of 7 days, embodiment 2 preparing and is placed the non-crystalline state nickelous sulfide of 14 days, embodiment 3 preparing and place 20 days, carry out copper-stripping reaction and check that it removes copper activity, non-crystalline state nickelous sulfide add-on be after iron liquid 0.7%, after copper removal, liquid is containing copper number all in 0.8 ~ 2.5ppm value range, and non-crystalline state nickelous sulfide copper removal activity keeping is better.
Non-crystalline state nickelous sulfide temporal evolution copper removal active testing data sheet 1.As can be seen from Table 1, non-crystalline state nickelous sulfide, placing respectively after 7 days, 14 days and 20 days, carries out copper removal test, and after copper removal, the requirement of hydroful foot nickel electrowinning, illustrates that non-crystalline state nickelous sulfide copper removal activity keeping is better.
In table, refer to " storage period " the aerial storage period of non-crystalline state nickelous sulfide of preparation, " liquid cupric before copper removal " is to place 7 days at non-crystalline state nickelous sulfide, liquid copper content after the iron got at the scene when 14 days and 20 days, " nickelous sulfide and copper additional proportion " refer to liquid after non-crystalline state nickelous sulfide adds volume to be iron in test non-crystalline state nickelous sulfide activity test process long-pending 0.7%, " liquid cupric after copper removal " refers to non-crystalline state nickelous sulfide placement 7 days, after 14 days and 20 days, " copper removal before liquid " carried out to liquid copper content after copper removal that copper removal obtains, " cupric ion decreasing ratio " refers to that the cupric ion of removing accounts for the total amount of total ion.
Claims (3)
1. a preparation method for non-crystalline state nickelous sulfide, is characterized in that concrete steps are as follows:
A, sodium sulphite dissolve
The tap water that is 5 ~ 25 ℃ by temperature joins in sodium sulphite dissolving tank, add stablizer, stablizer and tap water volume ratio are 0.18 ~ 0.25:100, stir 10 ~ 20 minutes, add purity 60% industrial sodium sulfide, dissolve postcure na concn and be controlled at 90 ~ 120g/l, stir 1 ~ 1.5 hour, add dispersion agent, dispersion agent and tap water volume ratio are 0.15 ~ 0.2:100 again, stir 0.5 ~ 1 hour;
B, the preparation of non-crystalline state nickelous sulfide
Another extracting container adds liquid after copper removal, nickel concentration 75 ~ 85g/l in liquid after copper removal, temperature is 20 ~ 40 ℃, pH value is 3.2 ~ 3.6, adds sodium sulphite anhydrous 99.3, stirs 0.5 ~ 1 hour, after S-WAT dissolves, concentration is 0.8 ~ 1g/l, add dispersion agent, after dispersion agent and copper, liquid volume ratio is 0.2 ~ 0.25:100 again, stirs 15 ~ 30 minutes; By the sodium sulfide solution of step a and above-mentioned solution by volume 1.0 ~ 1.3:1 mix, stir and within 0.5 ~ 1 hour, make non-crystalline state nickelous sulfide pulp liquid.
2. require described a kind of copper-removing method according to right 1, it is characterized in that adding dispersion agent and stablizer in described step b, can keep for a long time it to remove copper activity.
3. require described a kind of copper-removing method according to right 1, it is characterized in that described dispersion agent is that polyoxyethylene glycol, the stablizer of purity 99% is the hydrazine hydrate of massfraction 80%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410074075.4A CN103864157B (en) | 2014-02-28 | 2014-02-28 | A kind of preparation method of amorphous state nickel sulfide |
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| CN201410074075.4A CN103864157B (en) | 2014-02-28 | 2014-02-28 | A kind of preparation method of amorphous state nickel sulfide |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110156093A (en) * | 2019-05-30 | 2019-08-23 | 重庆交通大学 | The method of nickel sulfide ultra-fine grain is efficiently prepared under a kind of temperate condition |
| CN113151863A (en) * | 2021-03-18 | 2021-07-23 | 金川集团股份有限公司 | Method for removing copper ions in nickel production process by electrodeposition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09249421A (en) * | 1996-03-14 | 1997-09-22 | Taiheiyo Kinzoku Kk | Method for removing water from nickel-cobalt mixture |
| CN1459663A (en) * | 2002-05-21 | 2003-12-03 | 中国科学院理化技术研究所 | Nickel sulfide nano particle sensitizing agent and its preparation method |
| CN101186346A (en) * | 2007-12-19 | 2008-05-28 | 扬州大学 | Low-temperature solid-phase synthesizing method for hexagonal-phase nickel sulfide submicron crystal |
| CN102633309A (en) * | 2012-01-13 | 2012-08-15 | 沈阳理工大学 | Hydrothermal preparation method for NiS2 with controllable shape |
| US20130252798A1 (en) * | 2012-03-21 | 2013-09-26 | National Tsing Hua University | Metallic sulfide photocatalyst for carbon dioxide reduction and the preparation for the same |
-
2014
- 2014-02-28 CN CN201410074075.4A patent/CN103864157B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09249421A (en) * | 1996-03-14 | 1997-09-22 | Taiheiyo Kinzoku Kk | Method for removing water from nickel-cobalt mixture |
| CN1459663A (en) * | 2002-05-21 | 2003-12-03 | 中国科学院理化技术研究所 | Nickel sulfide nano particle sensitizing agent and its preparation method |
| CN101186346A (en) * | 2007-12-19 | 2008-05-28 | 扬州大学 | Low-temperature solid-phase synthesizing method for hexagonal-phase nickel sulfide submicron crystal |
| CN102633309A (en) * | 2012-01-13 | 2012-08-15 | 沈阳理工大学 | Hydrothermal preparation method for NiS2 with controllable shape |
| US20130252798A1 (en) * | 2012-03-21 | 2013-09-26 | National Tsing Hua University | Metallic sulfide photocatalyst for carbon dioxide reduction and the preparation for the same |
Non-Patent Citations (3)
| Title |
|---|
| 代岚: ""配制硫化钠标准溶液存在问题的研究"", 《当代化工》 * |
| 郎雷鸣等: ""海胆状硫化镍空心球的制备及电化学性能研究"", 《高等学校化学学报》 * |
| 陈德良等: ""水热微乳液法制备低维硫化镍纳米晶"", 《高等学校化学学报》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110156093A (en) * | 2019-05-30 | 2019-08-23 | 重庆交通大学 | The method of nickel sulfide ultra-fine grain is efficiently prepared under a kind of temperate condition |
| CN110156093B (en) * | 2019-05-30 | 2022-03-11 | 重庆交通大学 | Method for efficiently preparing nickel sulfide ultrafine particles under mild condition |
| CN113151863A (en) * | 2021-03-18 | 2021-07-23 | 金川集团股份有限公司 | Method for removing copper ions in nickel production process by electrodeposition |
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| CN103864157B (en) | 2016-06-08 |
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Effective date of registration: 20240204 Address after: 737100 No. 2 Lanzhou Road, Beijing Road Street, Jinchuan District, Jinchang City, Gansu Province Patentee after: Jinchuan Group Nickel Cobalt Co.,Ltd. Country or region after: China Patentee after: Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences Address before: 737103 No. 98, Jinchuan Road, Jinchang, Gansu Patentee before: JINCHUAN GROUP Co.,Ltd. Country or region before: China Patentee before: Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences |
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