CN103820786B - 用于碳钢的绿色环保气相缓蚀剂及其制备方法 - Google Patents
用于碳钢的绿色环保气相缓蚀剂及其制备方法 Download PDFInfo
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- CN103820786B CN103820786B CN201410041375.2A CN201410041375A CN103820786B CN 103820786 B CN103820786 B CN 103820786B CN 201410041375 A CN201410041375 A CN 201410041375A CN 103820786 B CN103820786 B CN 103820786B
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- solution
- ala
- benzoate
- vapour
- ammonium benzoate
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- 239000003112 inhibitor Substances 0.000 title claims abstract description 37
- 230000007613 environmental effect Effects 0.000 title claims abstract description 23
- 229910000975 Carbon steel Inorganic materials 0.000 title claims abstract description 20
- 239000010962 carbon steel Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- KWIPUXXIFQQMKN-UHFFFAOYSA-N 2-azaniumyl-3-(4-cyanophenyl)propanoate Chemical compound OC(=O)C(N)CC1=CC=C(C#N)C=C1 KWIPUXXIFQQMKN-UHFFFAOYSA-N 0.000 claims abstract description 52
- 229940090948 ammonium benzoate Drugs 0.000 claims abstract description 52
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 claims abstract description 50
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 45
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 36
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 36
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 36
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 31
- 238000003756 stirring Methods 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012153 distilled water Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 14
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 27
- 230000007797 corrosion Effects 0.000 abstract description 27
- 230000005764 inhibitory process Effects 0.000 abstract description 19
- 239000002131 composite material Substances 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 230000003245 working effect Effects 0.000 abstract description 3
- 239000012071 phase Substances 0.000 description 28
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 230000003449 preventive effect Effects 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000012467 final product Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 229910000926 A-3 tool steel Inorganic materials 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- -1 inorganic acid salt Chemical class 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 239000012808 vapor phase Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000000116 mitigating effect Effects 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GTLQZNKUEFUUIS-UHFFFAOYSA-N carbonic acid;cyclohexanamine Chemical compound OC(O)=O.NC1CCCCC1 GTLQZNKUEFUUIS-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- ZFAKTZXUUNBLEB-UHFFFAOYSA-N dicyclohexylazanium;nitrite Chemical compound [O-]N=O.C1CCCCC1[NH2+]C1CCCCC1 ZFAKTZXUUNBLEB-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000019249 food preservative Nutrition 0.000 description 1
- 239000005452 food preservative Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
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CN201410041375.2A CN103820786B (zh) | 2014-01-28 | 2014-01-28 | 用于碳钢的绿色环保气相缓蚀剂及其制备方法 |
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CN103820786B true CN103820786B (zh) | 2015-11-18 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104762623A (zh) * | 2014-12-30 | 2015-07-08 | 武汉江南铁依环保产业发展有限公司 | 一种环保型镀锌钢板用复配气相缓蚀剂及其制备方法 |
CN107829092A (zh) * | 2017-12-26 | 2018-03-23 | 辽宁师范大学 | 一种绿色环保型碳钢缓蚀剂 |
CN108425118B (zh) * | 2018-03-21 | 2019-12-24 | 西安理工大学 | 一种用于碳钢和黄铜的四元复配气相缓蚀剂及其制备方法 |
CN110983341A (zh) * | 2019-12-31 | 2020-04-10 | 苏州启阳新材料科技股份有限公司 | 一种氨基酸型气相防锈剂及其制备方法 |
CN113529089B (zh) * | 2021-07-02 | 2023-06-06 | 北京首融汇科技发展有限公司 | 一种环保型气相缓蚀剂及气相防锈材料 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL141585B (nl) * | 1961-10-04 | 1974-03-15 | Basf Ag | Werkwijze voor het verhinderen van corrosie door waterhoudende antivriesmiddelen op basis van 1,2-diolen. |
CN102021581A (zh) * | 2009-09-17 | 2011-04-20 | 曹军 | 一种金属气相缓蚀剂 |
CN202898545U (zh) * | 2012-08-31 | 2013-04-24 | 沈阳防锈包装材料有限责任公司 | 一种气相防锈发散体 |
CN103215599A (zh) * | 2013-03-01 | 2013-07-24 | 西安理工大学 | 用于碳钢的气相缓蚀剂及其制备方法、使用方法和用途 |
CN103276397A (zh) * | 2013-04-07 | 2013-09-04 | 马鞍山采石矶涂料有限公司 | 一种环保型工序间水性防锈液及其制备方法 |
-
2014
- 2014-01-28 CN CN201410041375.2A patent/CN103820786B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL141585B (nl) * | 1961-10-04 | 1974-03-15 | Basf Ag | Werkwijze voor het verhinderen van corrosie door waterhoudende antivriesmiddelen op basis van 1,2-diolen. |
CN102021581A (zh) * | 2009-09-17 | 2011-04-20 | 曹军 | 一种金属气相缓蚀剂 |
CN202898545U (zh) * | 2012-08-31 | 2013-04-24 | 沈阳防锈包装材料有限责任公司 | 一种气相防锈发散体 |
CN103215599A (zh) * | 2013-03-01 | 2013-07-24 | 西安理工大学 | 用于碳钢的气相缓蚀剂及其制备方法、使用方法和用途 |
CN103276397A (zh) * | 2013-04-07 | 2013-09-04 | 马鞍山采石矶涂料有限公司 | 一种环保型工序间水性防锈液及其制备方法 |
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CB03 | Change of inventor or designer information |
Inventor after: Huang Yingwei Inventor after: Yang Yonglian Inventor after: Zhang Yingying Inventor after: Huang Ruixiang Inventor before: Huang Yingwei Inventor before: Yang Yonglian Inventor before: Zhang Yingying |
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Effective date of registration: 20170724 Address after: 710200, No. 17, middle section of Jing Gao Nan Road, Jing Wei Industrial Park, Xi'an economic and Technological Development Zone, Shaanxi Patentee after: Xi'an Yu Kun Industrial Co., Ltd. Address before: 710048 Shaanxi city of Xi'an Province Jinhua Road No. 5 Patentee before: Xi'an University of Technology |
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Denomination of invention: Environmental-friendly volatile corrosion inhibitor for carbon steel and preparation method of environmental-friendly volatile corrosion inhibitor Effective date of registration: 20190410 Granted publication date: 20151118 Pledgee: Xi'an innovation financing Company limited by guarantee Pledgor: Xi'an Yu Kun Industrial Co., Ltd. Registration number: 2019990000311 |
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Date of cancellation: 20200601 Granted publication date: 20151118 Pledgee: Xi'an innovation financing Company limited by guarantee Pledgor: Xi'an Yu Kun Industrial Co.,Ltd. Registration number: 2019990000311 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Environmental-friendly volatile corrosion inhibitor for carbon steel and preparation method of environmental-friendly volatile corrosion inhibitor Effective date of registration: 20200601 Granted publication date: 20151118 Pledgee: Xi'an innovation financing Company limited by guarantee Pledgor: Xi'an Yu Kun Industrial Co.,Ltd. Registration number: Y2020990000546 |
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