CN103772892A - 一种abs耐刮擦材料及其制备方法 - Google Patents

一种abs耐刮擦材料及其制备方法 Download PDF

Info

Publication number
CN103772892A
CN103772892A CN201410032867.5A CN201410032867A CN103772892A CN 103772892 A CN103772892 A CN 103772892A CN 201410032867 A CN201410032867 A CN 201410032867A CN 103772892 A CN103772892 A CN 103772892A
Authority
CN
China
Prior art keywords
abs
resistant material
district
parts
scratching
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410032867.5A
Other languages
English (en)
Inventor
石磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NANTONG RED STON TECHNOLOGY DEVELOPMENT Co Ltd
Original Assignee
NANTONG RED STON TECHNOLOGY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NANTONG RED STON TECHNOLOGY DEVELOPMENT Co Ltd filed Critical NANTONG RED STON TECHNOLOGY DEVELOPMENT Co Ltd
Priority to CN201410032867.5A priority Critical patent/CN103772892A/zh
Publication of CN103772892A publication Critical patent/CN103772892A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
    • B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92819—Location or phase of control
    • B29C2948/92857—Extrusion unit
    • B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895—Barrel or housing

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

本发明属于高分子材料领域，公开了一种ABS耐刮擦材料及其制备方法。该复合材料由包含以下重量份的组分制成：将50-80份ABS、10-30份碳酸钙、0.5-10份耐刮擦剂、2-10份硬脂酸镁、10-25份丁腈橡胶和0.1-1份抗氧剂168。该材料是将上述原料加入高速混合机中充分混合，经双螺杆挤出机挤出造粒。本发明提供了一种加工容易、性能均衡性好、耐刮擦的ABS材料，该方法流程简单、连续、节能、高效，且制得的产品质量稳定。

Description

一种ABS耐刮擦材料及其制备方法
技术领域
本发明属于高分子材料领域，尤其涉及一种ABS耐刮擦材料及其制备方法。 
背景技术
ABS树脂具有良好的尺寸稳定性，耐蠕变性，抗冲击性、优良的可加工性，因此被广泛的应用于家电、汽车、电子电器等领域。随着社会的发展、人们生活品质的提高，对材料的要求也越来越多，产品也变的日益专业化，现在对产品又提出了耐刮擦的要求。 
ABS树脂在生产的混合过程中易产生相分离，从而影响到产品的各项力学性能以及表面耐刮擦性，这也使得其应用受到了限制，现有的ABS树脂主要是通过添加相容剂以及减少体系里的橡胶含量，来提高组合物的表面硬度，从而达到耐刮擦的目的，但与此同时，不可避免的降低了组合物的韧性，使得制品的抗冲击性能变差。 
发明内容
为了克服上述现有技术存在的缺陷，本发明的目的在于提供了一种加工容易、性能均衡性好、耐刮擦的ABS材料。 
本发明的另一目的在于提供了一种ABS耐刮擦材料的制备方法，该方法流程简单、连续、节能、高效、产品质量稳定。 
本发明的目的通过以下技术方案来实现： 
一种ABS耐刮擦材料，由包含以下重量份的组分制成：
ABS                 50-80份，
碳酸钙               10-30份，
耐刮擦剂            0.5-10份，
硬脂酸镁             2-10份，
丁腈橡胶            10-25份， 
抗氧剂168           0.1-1份。
所述耐刮擦剂选自硅酮母粒、纳米硅铝酸盐和聚乙烯蜡中的一种或者几种的混合物。 
所述组分还包括0-1重量份的抗紫外剂。 
所述抗紫外剂为UV5411或UV329。 
一种ABS耐刮擦材料的制备方法，包括以下步骤： 
将50-80份ABS、10-30份碳酸钙、0.5-10份耐刮擦剂、2-10份硬脂酸镁、10-25份丁腈橡胶、0.1-1份抗氧剂168和0-1份的抗紫外剂加入高速混合机中充分混合，将混合均匀的物料经双螺杆挤出机挤出造粒；
所述双螺杆挤出机的各区温度设置分别为：一区160-170℃，二区170-180℃，三区180-200℃，四区200-210℃。
有益效果：
本发明采用碳酸钙作为无机填料、通过添加丁腈橡胶提高了ABS树脂的弹性、通过添加耐刮擦剂提高了ABS树脂的耐刮擦性。本发明所制得的材料不仅具有良好的表面光泽度和耐刮擦性能，而且还具有加工方便、性价比高、均衡性好的优点。本发明的制备方法工艺简单、所需温度较低，从而节省了能源，能够得到连续、高效，质量稳定的产品。
具体实施方式
以下结合实施例对本发明作进一步的说明。 
实施例1 
称取50kgABS、20kg碳酸钙、0.5kg硅酮母粒、6kg硬脂酸镁、15kg丁腈橡胶和0.1kg抗氧剂168加入高速混合机中充分混合，将混合均匀的物料经双螺杆挤出机挤出造粒；
所述双螺杆挤出机的各区温度设置分别为：一区160℃，二区170℃，三区180℃，四区200℃。
制得材料的性能测试结果如表1所示。 
实施例2 
称取65kgABS、30kg碳酸钙、5kg纳米硅铝酸盐、2kg硬脂酸镁、10kg丁腈橡胶和0.5kg抗氧剂168加入高速混合机中充分混合，将混合均匀的物料经双螺杆挤出机挤出造粒；
所述双螺杆挤出机的各区温度设置分别为：一区170℃，二区180℃，三区200℃，四区210℃。
制得材料的性能测试结果如表1所示。 
实施例3 
称取80kgABS、10kg碳酸钙、10kg聚乙烯蜡、10kg硬脂酸镁、25kg丁腈橡胶、1kg抗氧剂168和1kgUV5411加入高速混合机中充分混合，将混合均匀的物料经双螺杆挤出机挤出造粒；
所述双螺杆挤出机的各区温度设置分别为：一区165℃，二区175℃，三区190℃，四区205℃。
制得材料的性能测试结果如表1所示。 
表1 
Figure 1

Claims (5)

1. 一种ABS耐刮擦材料，其特征在于，由包含以下重量份的组分制成：
ABS                 50-80份，
碳酸钙               10-30份，
耐刮擦剂             0.5-10份，
硬脂酸镁               2-10份，
丁腈橡胶              10-25份， 
抗氧剂168             0.1-1份。
2. 根据权利要求1所述的ABS耐刮擦材料，其特征在于，所述耐刮擦剂选自硅酮母粒、纳米硅铝酸盐和聚乙烯蜡中的一种或者几种的混合物。
3. 根据权利要求1所述的ABS耐刮擦材料，其特征在于，所述组分还包括0-1重量份的抗紫外剂。
4. 根据权利要求3所述的ABS耐刮擦材料，其特征在于，所述抗紫外剂为UV5411或UV329。
5. 一种ABS耐刮擦材料的制备方法，其特征在于，包括以下步骤：
将50-80份ABS、10-30份碳酸钙、0.5-10份耐刮擦剂、2-10份硬脂酸镁、10-25份丁腈橡胶、0.1-1份抗氧剂168和0-1份的抗紫外剂加入高速混合机中充分混合，将混合均匀的物料经双螺杆挤出机挤出造粒；所述双螺杆挤出机的各区温度设置分别为：一区160-170℃，二区170-180℃，三区180-200℃，四区200-210℃。
CN201410032867.5A 2014-01-24 2014-01-24 一种abs耐刮擦材料及其制备方法 Pending CN103772892A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410032867.5A CN103772892A (zh) 2014-01-24 2014-01-24 一种abs耐刮擦材料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410032867.5A CN103772892A (zh) 2014-01-24 2014-01-24 一种abs耐刮擦材料及其制备方法

Publications (1)

Publication Number Publication Date
CN103772892A true CN103772892A (zh) 2014-05-07

Family

ID=50565689

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410032867.5A Pending CN103772892A (zh) 2014-01-24 2014-01-24 一种abs耐刮擦材料及其制备方法

Country Status (1)

Country Link
CN (1) CN103772892A (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108164909A (zh) * 2017-11-30 2018-06-15 苏州启虹塑业有限公司 一种耐刮擦abs透红外材料及其制备方法
JP2018123285A (ja) * 2017-02-03 2018-08-09 コニカミノルタ株式会社 熱可塑性樹脂組成物および熱可塑性樹脂組成物の製造方法
CN113004650A (zh) * 2021-05-06 2021-06-22 青岛海尔新材料研发有限公司 一种超耐候、耐低温冲击、耐刮擦性的吹塑abs材料

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532781A (zh) * 2010-12-07 2012-07-04 合肥杰事杰新材料股份有限公司 一种高光泽耐刮擦abs类树脂及其制备方法
CN103044847A (zh) * 2012-12-30 2013-04-17 苏州旭光聚合物有限公司 一种abs复合材料及其制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532781A (zh) * 2010-12-07 2012-07-04 合肥杰事杰新材料股份有限公司 一种高光泽耐刮擦abs类树脂及其制备方法
CN103044847A (zh) * 2012-12-30 2013-04-17 苏州旭光聚合物有限公司 一种abs复合材料及其制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018123285A (ja) * 2017-02-03 2018-08-09 コニカミノルタ株式会社 熱可塑性樹脂組成物および熱可塑性樹脂組成物の製造方法
CN108164909A (zh) * 2017-11-30 2018-06-15 苏州启虹塑业有限公司 一种耐刮擦abs透红外材料及其制备方法
CN113004650A (zh) * 2021-05-06 2021-06-22 青岛海尔新材料研发有限公司 一种超耐候、耐低温冲击、耐刮擦性的吹塑abs材料

Similar Documents

Publication Publication Date Title
CN101885895B (zh) 一种abs树脂的改性方法及改性abs树脂
CN101831136A (zh) 一种高强度高韧性阻燃abs复合材料及其制备方法
CN104194300B (zh) 耐老化抗菌pc/abs共混合金及其制备方法
CN104672759B (zh) 高光抗冲耐划伤abs/pmma/petg合金及其制备方法
CN104592667B (zh) 一种高流动、高抗冲asa材料及其制备方法
CN105419319A (zh) 一种高抗uv玻纤增强尼龙6材料及其制备方法
CN109777105A (zh) 一种高流动聚砜复合材料及其制备方法
CN103772885A (zh) 一种消光pc/abs汽车仪表盘材料及其制备方法
CN104292741A (zh) 一种abs复合材料及其制备方法
CN103772892A (zh) 一种abs耐刮擦材料及其制备方法
CN103173015A (zh) 一种高强度pps材料及其制备方法
CN106939112B (zh) 一种高光泽hips/回收pet瓶片复合材料及其制备方法
CN103709710B (zh) 加工性能优异的pc/abs合金材料及其制备方法
CN105237873A (zh) 一种新型改性复合塑料
CN102863771A (zh) 一种轻量化的聚碳酸酯组合物及其制备方法
CN105237874A (zh) 一种改性复合塑料
CN103756299A (zh) 一种高性能玻纤增强pa/abs合金材料及其制备方法
CN104072974A (zh) 一种ppo-pa66合成塑料的制备方法
CN103980645A (zh) 汽车内饰件用抗老化耐高温hips塑料及制备方法
CN104119653A (zh) 阻燃聚酯复合材料及其制备方法
CN103724993B (zh) 一种快速吸水玻璃纤维增强尼龙6复合材料及其制备方法
CN108530859B (zh) 一种颗粒强化橡胶增强复合材料的制备方法
CN106905628A (zh) 一种可用于3d打印的聚苯乙烯材料及其制备方法
CN103665707A (zh) 一种高刚性高光泽聚苯乙烯改性材料的制备方法
CN103665710A (zh) 一种高刚性高光泽聚苯乙烯改性材料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20140507