CN103741152B - A kind of rust cleaning of metal glasses frame and protective agent - Google Patents
A kind of rust cleaning of metal glasses frame and protective agent Download PDFInfo
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- CN103741152B CN103741152B CN201410018093.0A CN201410018093A CN103741152B CN 103741152 B CN103741152 B CN 103741152B CN 201410018093 A CN201410018093 A CN 201410018093A CN 103741152 B CN103741152 B CN 103741152B
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- parts
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- glasses frame
- natural phant
- deionized water
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 36
- 239000002184 metal Substances 0.000 title claims abstract description 36
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000011521 glass Substances 0.000 title claims abstract description 27
- 238000004140 cleaning Methods 0.000 title claims abstract description 16
- 239000003223 protective agent Substances 0.000 title claims abstract description 11
- 239000008367 deionised water Substances 0.000 claims abstract description 20
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 230000001681 protective effect Effects 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000013543 active substance Substances 0.000 claims abstract description 12
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 230000002000 scavenging effect Effects 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 11
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 10
- 239000004745 nonwoven fabric Substances 0.000 claims description 10
- 241000220317 Rosa Species 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 5
- 235000018958 Gardenia augusta Nutrition 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 239000006071 cream Substances 0.000 claims description 5
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- -1 polydimethylsiloxane Polymers 0.000 claims description 5
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000001211 (E)-4-phenylbut-3-en-2-one Substances 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 2
- 229960000583 acetic acid Drugs 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 229930008407 benzylideneacetone Natural products 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 2
- 239000012362 glacial acetic acid Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical compound CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 claims description 2
- 230000006378 damage Effects 0.000 abstract description 3
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 241001311547 Patina Species 0.000 description 11
- 239000000047 product Substances 0.000 description 6
- 239000010949 copper Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 235000011054 acetic acid Nutrition 0.000 description 3
- 150000001243 acetic acids Chemical class 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 210000004379 membrane Anatomy 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 208000001491 myopia Diseases 0.000 description 1
- 230000004379 myopia Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 230000003248 secreting effect Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Abstract
The invention discloses a kind of rust cleaning and protective agent of metal glasses frame, comprise rust removing solution, scavenging solution and protective liquid.Rust removing solution comprises weak acid, tensio-active agent, natural phant essence, deionized water, and scavenging solution comprises solvent, tensio-active agent, natural phant essence, and protective liquid comprises inhibiter, natural phant essence, lustering agent, solvent.Rust cleaning of the present invention and protective agent effectively can remove the rust on metal glasses frame surface, and can effectively prevent metal glasses frame from again being corroded, and can not form harm to human body simultaneously, environment friendly and pollution-free.
Description
Technical field
The present invention relates to the field of a kind of metal-derusting and protection, especially the rust cleaning of metal glasses frame and the preparation of protective agent.
Technical background
People are when wearing spectacles or sun glasses, and in order to reach effect attractive in appearance, a lot of people can select the glasses of metal picture frame.Metal picture frame seems more attractive in appearance due to the gloss of metal, and firm, toughness is high, although there is the competition of plastic spectacle frame, still commercially in occupation of very large share.Because copper is a kind of easily processing and lower-cost metal, a lot of metal glasses frame especially low-end product adopts copper as main material.But the corrosion-resistant of general Copper and its alloy, easily to get rusty, wear time is of a specified duration, due to the corrosion of the sweat of human secretory and long-term exposure in atmosphere, spectacle-frame surface especially the place of close contact can not can produce green patina with human body, even some good spectacle-frames, also just outside common alloy, plated the good metal of one deck stability, the metal of outside of long duration is worn away, and the alloy come out still can bear green patina.
The main component of this patina is ventilation breather (Cu
2(0H)
2c0
3), ventilation breather has pungency to human body skin and mucous membrane.Glasses are as the articles for use next to the skin of myopia population, its aesthetic property and security are abnormal important to user, patina on metal glasses frame easily and human contact and very near apart from the eyes of people, if can not effectively remove these patinas, can potential harm be produced on human body and affect the attractive in appearance of wearing spectacles.Also there is no the special product derusting and protect for metal glasses frame in the market.People generally use the mode of common wiping or hard object polishing to remove the patina on metal glasses frame surface, although this means simply can remove patina thoroughly, and cause damage to accelerate the formation of patina next time to metal.
Summary of the invention
The object of the present invention is to provide a kind of thoroughly can remove metal glasses frame surface rusty scale and dirt can prevent metal glasses frame from again being corroded, and esy to use, safe and reliable, non-environmental-pollution, non-stimulated to human body, to the rust cleaning of the harmless environment-friendly metal spectacle-frame of metal and protective agent.
The present invention comprises rust removing solution, scavenging solution, protective liquid, and the solution of these three kinds of difference in functionalitys to be immersed in respectively in three blocks of non-woven fabrics and to put into three packing bags.User only need can complete rust cleaning, cleaning, protection three kinds of functions to metal glasses frame with three pieces of non-woven fabrics wiping metal glasses frames successively.
Realizing the technical scheme that object of the present invention takes is:
Rust removing solution is formed by the preparation of raw material of following weight part: weak acid 10 ~ 20 parts, 3 ~ 5 parts, tensio-active agent, 0.1 ~ 0.5 part, natural phant essence, deionized water 75 ~ 85 parts.Scavenging solution is formed by the preparation of raw material of following weight part: solvent 95 ~ 97 parts, 3 ~ 5 parts, tensio-active agent, 0.1 ~ 0.5 part, natural phant essence.Protective liquid is formed by the preparation of raw material of following weight part: inhibiter 0.02 ~ 0.04 part, 0.1 ~ 0.5 part, natural phant essence, lustering agent 1.5 ~ 3.5 parts, solvent 96 ~ 99 parts.
Phosphoric acid 70 ~ 80 parts of mixing acid formed that the glacial acetic acid 20 ~ 30 parts that described weak acid is 99% for concentration, concentration are 85%.
Described tensio-active agent is Sodium dodecylbenzene sulfonate or sodium lauryl sulphate or lauryl alcohol phosphoric acid ester potassium.
Described natural phant essence is cream jasmin france or rose compound.
Described solvent is ethanol 20 ~ 40 parts, deionized water 60 ~ 80 parts of solvents formed.
Described lustering agent is polydimethylsiloxane or benzylideneacetone.
Described inhibiter be tolyltriazole, mercapto benzothiazole, benzotriazole wherein arbitrarily both mass ratioes be the mixture of 1: 1.
Preparation method of the present invention is: weak acid, tensio-active agent, natural phant essence are dissolved in deionized water by (1), stirs and is mixed evenly and obtains rust removing solution; (2) tensio-active agent, natural phant essence are dissolved in the solvent prepared by ethanol and deionized water, are uniformly mixed and obtain scavenging solution; (3) inhibiter, natural phant essence, lustering agent are dissolved in the solvent prepared by ethanol and deionized water, are uniformly mixed and obtain protective liquid; (4) three kinds of solution are immersed respectively in three blocks of non-woven fabrics and namely obtain product of the present invention.
Beneficial effect of the present invention: (1) the present invention adopts the mixing acid of 10 ~ 20% ratios, not only thoroughly can remove the rusty scale on metal glasses frame surface, dirt but also can not cause corrosion to metal; (2) inhibiter of the present invention can form the stable protective membrane of one deck and prevents metal from again being corroded in metallic surface; (3) the present invention is easy to use, only need can reach the object of rust cleaning and protection successively with three pieces of non-woven fabrics wipings of having immersed different solutions; (4) the present invention is not containing any strong acid, highly basic, and nontoxic, stable performance, safe and reliable, the non-woven fabrics adopted is environment-friendly degradable material, environmentally safe.
Embodiment
In order to understand the present invention better, describe technical scheme of the present invention in detail with specific examples below, but the present invention is not limited thereto.
Embodiment 1.
In container A, add the deionized water of 85 parts, 2 parts of glacial acetic acids, 8 parts of phosphoric acid, the Sodium dodecylbenzene sulfonate of 5 parts, 0.2 part of natural rose essence successively, namely dispersed with stirring evenly obtains rust removing solution.In container B, add the deionized water of 70 parts, 27 parts of ethanol, 3 parts of Sodium dodecylbenzene sulfonatees, 0.2 part of natural cream jasmin france successively, namely dispersed with stirring evenly obtains scavenging solution.In container C, add 30 parts of ethanol, 0.01 part of tolyltriazole, 0.01 part of mercapto benzothiazole, 2 parts of polydimethylsiloxanes, the deionized water of 68 parts, 0.2 part of natural rose essence successively, namely dispersed with stirring evenly obtains protective liquid.Three kinds of solution are immersed in three blocks of non-woven fabrics respectively.
Embodiment 2.
In container A, add the deionized water of 80 parts, 5 parts of glacial acetic acids, 11 parts of phosphoric acid, the Sodium dodecylbenzene sulfonate of 4 parts, 0.2 part of natural rose essence successively, namely dispersed with stirring evenly obtains rust removing solution.In container B, add the deionized water of 65 parts, 30 parts of ethanol, 5 parts of Sodium dodecylbenzene sulfonatees, 0.1 part of natural cream jasmin france successively, namely dispersed with stirring evenly obtains scavenging solution.In container C, add 25 parts of ethanol, 0.015 part of tolyltriazole, 0.015 part of mercapto benzothiazole, 2.5 parts of polydimethylsiloxanes, the deionized water of 72 parts, 0.3 part of natural rose essence successively, namely dispersed with stirring evenly obtains protective liquid.Three kinds of solution are immersed in three blocks of non-woven fabrics respectively.
Embodiment 3.
In container A, add the deionized water of 75 parts, 7 parts of glacial acetic acids, 15 parts of phosphoric acid, the Sodium dodecylbenzene sulfonate of 3 parts, 0.4 part of natural rose essence successively, namely dispersed with stirring evenly obtains rust removing solution.In container B, add the deionized water of 77 parts, 20 parts of ethanol, 3 parts of Sodium dodecylbenzene sulfonatees, 0.3 part of natural cream jasmin france successively, namely dispersed with stirring evenly obtains scavenging solution.In container C, add 20 parts of ethanol, 0.02 part of tolyltriazole, 0.02 part of mercapto benzothiazole, 3 parts of polydimethylsiloxanes, the deionized water of 77 parts, 0.3 part of natural rose essence successively, namely dispersed with stirring evenly obtains protective liquid.Three kinds of solution are immersed in three blocks of non-woven fabrics respectively.
Product performance are tested: use the product of three embodiments to eliminate rust, clean, protect with brand with money metal glasses frame close three of rusting rate respectively.Using method is: carry out wiping to metal glasses frame successively with block non-woven fabrics of three in product of the present invention.Check after rust cleaning and protective treatment and the rust cleaning effect of three sections of metal glasses frames after then three sections of metal glasses frames normally being worn six months, again check the situation of getting rusty of its metallic surface.Its test result is in table 1.
Table 1: each embodiment product performance test result
| Project | Security | To derust effect | Metal protection performance |
| Embodiment 1 | Non-corrosiveness, safety | There are a small amount of remnants | Using after 6 months has a small amount of patina to produce |
| Embodiment 2 | Non-corrosiveness, safety | Thoroughly remove fast | Use and produce without patina after 6 months |
| Embodiment 3 | Non-corrosiveness, safety | Thoroughly remove fast | Use and produce without patina after 6 months |
Claims (5)
1. the rust cleaning of a metal glasses frame and protective agent, it is characterized in that: comprise rust removing solution, scavenging solution and protective liquid, formed by the preparation of raw material of following weight part: rust removing solution: weak acid 10 ~ 20 parts, 3 ~ 5 parts, tensio-active agent, 0.1 ~ 0.5 part, natural phant essence, deionized water 75 ~ 85 parts, scavenging solution: solvent 95 ~ 97 parts, 3 ~ 5 parts, tensio-active agent, 0.1 ~ 0.5 part, natural phant essence, protective liquid: inhibiter 0.02 ~ 0.04 part, 0.1 ~ 0.5 part, natural phant essence, lustering agent 1.5 ~ 3.5 parts, solvent 96 ~ 99 parts;
Described weak acid is formulated by the component of following weight part: concentration be 99% glacial acetic acid 20 ~ 30 parts, concentration be 85% phosphoric acid 70 ~ 80 parts;
Described solvent is formulated by the component of following weight part: ethanol 20 ~ 40 parts, deionized water 60 ~ 80 parts;
Described inhibiter is any both mixture in tolyltriazole, mercapto benzothiazole, benzotriazole, and its mass ratio is 1: 1.
2. the rust cleaning of metal glasses frame according to claim 1 and protective agent, described tensio-active agent is Sodium dodecylbenzene sulfonate or sodium lauryl sulphate or lauryl alcohol phosphoric acid ester potassium.
3. the rust cleaning of metal glasses frame according to claim 1 and protective agent, described natural phant essence is cream jasmin france or rose compound.
4. the rust cleaning of metal glasses frame according to claim 1 and protective agent, described lustering agent is polydimethylsiloxane or benzylideneacetone.
5. the rust cleaning of metal glasses frame according to claim 1 and the preparation method of protective agent, it is characterized in that, concrete steps are as follows: weak acid, tensio-active agent, natural phant essence are dissolved in deionized water for stirring and are mixed evenly and obtain rust removing solution by (1); (2) tensio-active agent, natural phant essence are dissolved in the solvent prepared by ethanol and deionized water and are uniformly mixed and obtain scavenging solution; (3) inhibiter, natural phant essence, lustering agent are dissolved in the solvent prepared by ethanol and deionized water and are uniformly mixed and obtain protective liquid; (4) three kinds of solution are immersed in three blocks of non-woven fabrics respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410018093.0A CN103741152B (en) | 2014-01-16 | 2014-01-16 | A kind of rust cleaning of metal glasses frame and protective agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410018093.0A CN103741152B (en) | 2014-01-16 | 2014-01-16 | A kind of rust cleaning of metal glasses frame and protective agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103741152A CN103741152A (en) | 2014-04-23 |
| CN103741152B true CN103741152B (en) | 2015-11-25 |
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| CN201410018093.0A Expired - Fee Related CN103741152B (en) | 2014-01-16 | 2014-01-16 | A kind of rust cleaning of metal glasses frame and protective agent |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104357845B (en) * | 2014-11-13 | 2016-11-23 | 无锡伊佩克科技有限公司 | A kind of aluminium alloy polisher and preparation method thereof |
| CN104525959B (en) * | 2014-12-25 | 2016-09-07 | 安徽旭晶粉体新材料科技有限公司 | A kind of water fog method produces the composite antioxidant of copper powder |
| CN106118898A (en) * | 2016-06-20 | 2016-11-16 | 苏州科斯曼照明工程有限公司 | A kind of outdoor landscape lights surface clean Precerving liquid and preparation method thereof |
| CN106190624A (en) * | 2016-07-18 | 2016-12-07 | 谷亚利 | Glasses abluent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4381249A (en) * | 1979-05-14 | 1983-04-26 | Bouffard Joseph O | Rust removing and metal surface protecting composition |
| CN101353793A (en) * | 2007-07-26 | 2009-01-28 | 江苏海迅实业集团股份有限公司 | Copper alloy antirust agent |
| CN101555440A (en) * | 2008-12-08 | 2009-10-14 | 东莞市松山湖微电子材料研发中心 | Method for producing cleaning agent for removing wax and oil |
| WO2012024680A1 (en) * | 2010-08-20 | 2012-02-23 | 3M Innovative Properties Company | Rust removing composition |
| CN103160839A (en) * | 2011-12-19 | 2013-06-19 | 顾向军 | Metal rust removing and preventing liquid |
-
2014
- 2014-01-16 CN CN201410018093.0A patent/CN103741152B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4381249A (en) * | 1979-05-14 | 1983-04-26 | Bouffard Joseph O | Rust removing and metal surface protecting composition |
| CN101353793A (en) * | 2007-07-26 | 2009-01-28 | 江苏海迅实业集团股份有限公司 | Copper alloy antirust agent |
| CN101555440A (en) * | 2008-12-08 | 2009-10-14 | 东莞市松山湖微电子材料研发中心 | Method for producing cleaning agent for removing wax and oil |
| WO2012024680A1 (en) * | 2010-08-20 | 2012-02-23 | 3M Innovative Properties Company | Rust removing composition |
| CN103160839A (en) * | 2011-12-19 | 2013-06-19 | 顾向军 | Metal rust removing and preventing liquid |
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| CN103741152A (en) | 2014-04-23 |
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Inventor after: Shi Zeyou Inventor after: Feng Yuanshou Inventor before: Duan Yunhao |
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| TR01 | Transfer of patent right |
Effective date of registration: 20171225 Address after: 404600 Building No. 1 building A and B building, building No. 1 of Xingyuan Road, Xingyuan Road, Chongqing Fengjie County immigrant Ecological Industrial Park Patentee after: CHONGQING YAMEIOU GLASS CO.,LTD. Address before: No. 58 10-4-602 Jiefang Road, Ji'nan, Shandong Province, 10-4-602 Patentee before: Duan Yunhao |
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Granted publication date: 20151125 Termination date: 20220116 |