CN104357845B - A kind of aluminium alloy polisher and preparation method thereof - Google Patents
A kind of aluminium alloy polisher and preparation method thereof Download PDFInfo
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- CN104357845B CN104357845B CN201410639606.XA CN201410639606A CN104357845B CN 104357845 B CN104357845 B CN 104357845B CN 201410639606 A CN201410639606 A CN 201410639606A CN 104357845 B CN104357845 B CN 104357845B
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Abstract
The present invention provides a kind of aluminium alloy polisher and preparation method thereof, and this polisher includes the following raw material according to mass fraction meter: methyl acetate 30~50 parts, Triton X-100 3~9 parts, butyl acrylate 15~25 parts, sal glauberi 2~6 parts, sodium borate 1~3 parts, azodiisobutyronitrile 0.5~1.5 parts, silicones 3~7 parts, styrene 3~7 parts, lignite wax 2~9 parts, methyl hydroxybenzoate 1~5 parts, dibutyl phthalate 0.3~0.9 part, dehydrated alcohol 10~24 parts.The clean effect of the polisher that the present invention provides is good, and adhesive force is strong, energy digestion resistant, and polishing effect is good, can form layer protective layer in aluminum alloy surface, effectively protect aluminium alloy.
Description
Technical field
The present invention relates to a kind of abluent, particularly relate to a kind of aluminium alloy polisher and preparation method thereof.
Background technology
Aluminium alloy is a most widely used class non-ferrous metal structural material in industry, at Aeronautics and Astronautics, automobile, machinery
Manufacture, boats and ships and chemical industry are widely applied.Aluminium alloy density is low, but strength ratio is higher, near or above high-quality steel, moulds
Property is good, can be processed into various section bar, has excellent electric conductivity, heat conductivity and a corrosion stability, industrial is widely used, and usage amount is only
Inferior to steel.Some aluminium alloys can use heat treatment to obtain good mechanical performance, physical property and corrosion resistance.Aluminium alloy
After long-term use, surface is oxidizable and adheres to dirt, loses original gloss, accordingly, it would be desirable to maintain.
The most existing maintenance glazing agent being exclusively used in aluminium alloy is little, and existing maintenance glazing agent is to aluminum
Maintenance and the polishing effect of alloy are poor, and can not effectively remove dirt.Such as Chinese invention patent (the patent No.
201410018093.0, applying date 2014-01-16) disclose rust cleaning and the protective agent of a kind of metal glasses frame, this protective agent
Can effectively remove the rust on metal glasses frame surface, but the poor processing effect to aluminum alloy surface;Chinese invention patent (patent
Number 00103600.9, applying date 2000-04-04) disclose a kind of refractory polishing agent of aluminium foil and preparation method thereof, this glazing agent
Having good adhesive strength and the compatibility good with ink, but can not effectively go out dirt, polishing effect is poor.
Summary of the invention
Solving the technical problem that: the shortcoming existed for existing glazing agent, the present invention provides a kind of aluminium alloy with polishing
Agent and preparation method thereof, the clean effect of this polisher is good, and adhesive force is strong, can digestion resistant, and polishing effect is good, can be
Aluminum alloy surface forms layer protective layer, effectively protects aluminium alloy.
Technical scheme: a kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 30~
50 parts, Triton X-100 3~9 parts, butyl acrylate 15~25 parts, sal glauberi 2~6 parts, sodium borate 1~3
Part, azodiisobutyronitrile 0.5~1.5 parts, silicones 3~7 parts, styrene 3~7 parts, lignite wax 2~9 parts, methyl hydroxybenzoate 1
~5 parts, dibutyl phthalate 0.3~0.9 part, dehydrated alcohol 10~24 parts.
A kind of aluminium alloy polisher described above, the following raw material including according to mass fraction meter: methyl acetate 33
~45 parts, Triton X-100 4~8 parts, butyl acrylate 18~23 parts, sal glauberi 3~5 parts, sodium borate 1.5
~2.5 parts, azodiisobutyronitrile 0.8~1.3 parts, silicones 4~6 parts, styrene 4~6 parts, lignite wax 3~8 parts, nipalgin
Methyl ester 2~4 parts, dibutyl phthalate 0.4~0.8 part, dehydrated alcohol 13~20 parts.
A kind of aluminium alloy polisher described above, the following raw material including according to mass fraction meter: methyl acetate 35
~40 parts, Triton X-100 5~7 parts, butyl acrylate 20~22 parts, sal glauberi 3.5~4.5 parts, boric acid
Sodium 1.7~2.3 parts, azodiisobutyronitrile 0.9~1.2 parts, silicones 4.3~5.5 parts, styrene 4.5~5.5 parts, lignite wax 4
~6 parts, methyl hydroxybenzoate 2.5~3.5 parts, dibutyl phthalate 0.5~0.7 part, dehydrated alcohol 15~18 parts.
A kind of aluminium alloy polisher described above, the following raw material including according to mass fraction meter: methyl acetate 36
Part, Triton X-100 5.5 parts, butyl acrylate 21 parts, sal glauberi 3.8 parts, sodium borate 1.9 parts, azo two
Isopropyl cyanide 1 part, silicones 4.6 parts, styrene 4.8 parts, lignite wax 4.5 parts, methyl hydroxybenzoate 2.8 parts, phthalic acid two fourth
Ester 0.58 part, dehydrated alcohol 16 parts.
A kind of aluminium alloy polisher described above, the following raw material including according to mass fraction meter: methyl acetate 38
Part, Triton X-100 6 parts, butyl acrylate 21 parts, sal glauberi 4 parts, sodium borate 2 parts, azodiisobutyronitrile
1.1 parts, silicones 5 parts, styrene 5 parts, lignite wax 5 parts, methyl hydroxybenzoate 3 parts, dibutyl phthalate 0.6 part, anhydrous
Ethanol 17 parts.
The preparation method of a kind of aluminium alloy polisher described above, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 100~120 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 100~120 DEG C, insulation 1~3h, i.e.
Obtain finished product.
Step (1) described above is warming up to 110 DEG C.
Keeping temperature in step (3) described above is 110 DEG C, is incubated 2h.
Beneficial effect: compared with prior art, a kind of aluminium alloy polisher that the present invention provides and preparation method thereof, should
The clean effect of polisher is good, and adhesive force is strong, energy digestion resistant, and polishing effect is good, can form one in aluminum alloy surface
Layer protective layer, protects aluminium alloy effectively.
Detailed description of the invention
Embodiment 1
A kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 30 parts, Polyethylene Glycol
Octyl phenyl ether 3, butyl acrylate 15 parts, sal glauberi 2 parts, sodium borate 1 part, azodiisobutyronitrile 0.5 part, silicones 3
Part, styrene 3 parts, lignite wax 2 parts, methyl hydroxybenzoate 1 part, dibutyl phthalate 0.3 part, dehydrated alcohol 10 parts.
The preparation method of a kind of aluminium alloy polisher, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 100 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 100 DEG C, is incubated 1h, gets product.
Embodiment 2
A kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 50 parts, Polyethylene Glycol
Octyl phenyl ether 9 parts, butyl acrylate 25 parts, sal glauberi 6 parts, sodium borate 3 parts, azodiisobutyronitrile 1.5 parts, silicones
7 parts, styrene 7 parts, lignite wax 9 parts, methyl hydroxybenzoate 5 parts, dibutyl phthalate 0.9 part, dehydrated alcohol 24 parts.
The preparation method of a kind of aluminium alloy polisher, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 120 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 120 DEG C, is incubated 3h, gets product.
Embodiment 3
A kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 33 parts, Polyethylene Glycol
Octyl phenyl ether 4 parts, butyl acrylate 18 parts, sal glauberi 3 parts, sodium borate 1.5 parts, azodiisobutyronitrile 0.8 part, silicon tree
4 parts of fat, styrene 4 parts, lignite wax 3 parts, methyl hydroxybenzoate 2 parts, dibutyl phthalate 0.4 part, dehydrated alcohol 13 parts.
The preparation method of a kind of aluminium alloy polisher, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 100 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 100 DEG C, is incubated 1h, gets product.
Embodiment 4
A kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 45 parts, Polyethylene Glycol
Octyl phenyl ether 8 parts, butyl acrylate 23 parts, sal glauberi 5 parts, sodium borate 2.5 parts, azodiisobutyronitrile 1.3 parts, silicon tree
6 parts of fat, styrene 6 parts, lignite wax 8 parts, methyl hydroxybenzoate 4 parts, dibutyl phthalate 0.8 part, dehydrated alcohol 20 parts.
The preparation method of a kind of aluminium alloy polisher, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 120 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 120 DEG C, is incubated 3h, gets product.
Embodiment 5
A kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 35 parts, Polyethylene Glycol
Octyl phenyl ether 5 parts, butyl acrylate 20 parts, sal glauberi 3.5 parts, sodium borate 1.7 parts, azodiisobutyronitrile 0.9 part, silicon
Resin 4.3 parts, styrene 4.5 parts, lignite wax 4 parts, methyl hydroxybenzoate 2.5 parts, dibutyl phthalate 0.5 part, anhydrous second
Alcohol 15 parts.
The preparation method of a kind of aluminium alloy polisher, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 110 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 110 DEG C, is incubated 2h, gets product.
Embodiment 6
A kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 40 parts, Polyethylene Glycol
Octyl phenyl ether 7 parts, butyl acrylate 22 parts, sal glauberi 4.5 parts, sodium borate 2.3 parts, azodiisobutyronitrile 1.2 parts, silicon
Resin 5.5 parts, styrene 5.5 parts, lignite wax 6 parts, methyl hydroxybenzoate 3.5 parts, dibutyl phthalate 0.7 part, anhydrous second
Alcohol 18 parts.
The preparation method of a kind of aluminium alloy polisher, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 110 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 110 DEG C, is incubated 2h, gets product.
Embodiment 7
A kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 36 parts, Polyethylene Glycol
Octyl phenyl ether 5.5 parts, butyl acrylate 21 parts, sal glauberi 3.8 parts, sodium borate 1.9 parts, azodiisobutyronitrile 1 part, silicon
Resin 4.6 parts, styrene 4.8 parts, lignite wax 4.5 parts, methyl hydroxybenzoate 2.8 parts, dibutyl phthalate 0.58 part, anhydrous
Ethanol 16 parts.
The preparation method of a kind of aluminium alloy polisher, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 110 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 110 DEG C, is incubated 2h, gets product.
Embodiment 8
A kind of aluminium alloy polisher, the following raw material including according to mass fraction meter: methyl acetate 38 parts, Polyethylene Glycol
Octyl phenyl ether 6 parts, butyl acrylate 21 parts, sal glauberi 4 parts, sodium borate 2 parts, azodiisobutyronitrile 1.1 parts, silicones
5 parts, styrene 5 parts, lignite wax 5 parts, methyl hydroxybenzoate 3 parts, dibutyl phthalate 0.6 part, dehydrated alcohol 17 parts.
The preparation method of a kind of aluminium alloy polisher, comprises the steps:
(1) methyl acetate is added in reactor, be warming up to 110 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo are added
Bis-isobutyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 110 DEG C, is incubated 2h, gets product.
Performance test
Testing the performance of the embodiment of the present invention 1 ~ 8 product, test result is shown in Table 1.
Table 1 properties of product test data
Above the present invention is described in detail, for one of ordinary skill in the art, according to the embodiment of the present invention
Thought, the most all will change, in sum, this specification content should not be understood
For limitation of the present invention.
Claims (8)
1. an aluminium alloy polisher, it is characterised in that be made up of the raw material of following mass fraction meter: methyl acetate 30~50
Part, Triton X-100 3~9 parts, butyl acrylate 15~25 parts, sal glauberi 2~6 parts, sodium borate 1~3 parts,
Azodiisobutyronitrile 0.5~1.5 parts, silicones 3~7 parts, styrene 3~7 parts, lignite wax 2~9 parts, methyl hydroxybenzoate 1~5
Part, dibutyl phthalate 0.3~0.9 part, dehydrated alcohol 10~24 parts.
A kind of aluminium alloy polisher the most according to claim 1, it is characterised in that by the raw material of following mass fraction meter
Composition: methyl acetate 33~45 parts, Triton X-100 4~8 parts, butyl acrylate 18~23 parts, sal glauberi 3
~5 parts, sodium borate 1.5~2.5 parts, azodiisobutyronitrile 0.8~1.3 parts, silicones 4~6 parts, styrene 4~6 parts, brown coal
Wax 3~8 parts, methyl hydroxybenzoate 2~4 parts, dibutyl phthalate 0.4~0.8 part, dehydrated alcohol 13~20 parts.
A kind of aluminium alloy polisher the most according to claim 1, it is characterised in that by the raw material of following mass fraction meter
Composition: methyl acetate 35~40 parts, Triton X-100 5~7 parts, butyl acrylate 20~22 parts, sal glauberi
3.5~4.5 parts, sodium borate 1.7~2.3 parts, azodiisobutyronitrile 0.9~1.2 parts, silicones 4.3~5.5 parts, styrene 4.5
~5.5 parts, lignite wax 4~6 parts, methyl hydroxybenzoate 2.5~3.5 parts, dibutyl phthalate 0.5~0.7 part, dehydrated alcohol
15~18 parts.
A kind of aluminium alloy polisher the most according to claim 1, it is characterised in that by the raw material of following mass fraction meter
Composition: methyl acetate 36 parts, Triton X-100 5.5 parts, butyl acrylate 21 parts, sal glauberi 3.8 parts, boric acid
1.9 parts of sodium, azodiisobutyronitrile 1 part, silicones 4.6 parts, styrene 4.8 parts, lignite wax 4.5 parts, methyl hydroxybenzoate 2.8 parts,
Dibutyl phthalate 0.58 part, dehydrated alcohol 16 parts.
A kind of aluminium alloy polisher the most according to claim 1, it is characterised in that by the raw material of following mass fraction meter
Composition: methyl acetate 38 parts, Triton X-100 6 parts, butyl acrylate 21 parts, sal glauberi 4 parts, sodium borate 2
Part, azodiisobutyronitrile 1.1 parts, silicones 5 parts, styrene 5 parts, lignite wax 5 parts, methyl hydroxybenzoate 3 parts, phthalic acid two
Butyl ester 0.6 part, dehydrated alcohol 17 parts.
The preparation method of a kind of aluminium alloy polisher the most as claimed in claim 1, it is characterised in that comprise the steps:
(1) methyl acetate is added in reactor, be warming up to 100~120 DEG C;
(2) in reactor, Triton X-100, butyl acrylate, sal glauberi, sodium borate, azo two are added different
Butyronitrile, silicones, lignite wax, methyl hydroxybenzoate and dibutyl phthalate, be uniformly mixed;
(3) adding styrene and dehydrated alcohol, stir, keeping temperature is 100~120 DEG C, is incubated 1~3h, must become
Product.
The preparation method of a kind of aluminium alloy polisher the most according to claim 6, it is characterised in that in described step (1)
It is warming up to 110 DEG C.
The preparation method of a kind of aluminium alloy polisher the most according to claim 6, it is characterised in that in described step (3)
Keeping temperature is 110 DEG C, is incubated 2h.
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CN1122092C (en) * | 2000-04-04 | 2003-09-24 | 蒋勤军 | Refractory polishing agent of aluminium foil and its preparing process |
NZ563934A (en) * | 2006-05-02 | 2012-06-29 | Whiteley Corp Pty Ltd | Safety coatings |
KR20140044482A (en) * | 2012-10-05 | 2014-04-15 | 동우 화인켐 주식회사 | Cleaning composition for electronic devices |
CN103741152B (en) * | 2014-01-16 | 2015-11-25 | 段云豪 | A kind of rust cleaning of metal glasses frame and protective agent |
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Effective date of registration: 20170710 Address after: 523900 Guangdong province Dongguan city Humen town gate five MINCHANG Road 5 Lane 7, first floor workshop Patentee after: Dongguan vanle Hardware Products Co. Ltd. Address before: Room 214000, science and Technology Park, No. 7 Changjiang Road, New District, Wuxi, Jiangsu, China Patentee before: Wuxi Epic Technology Co., Ltd. |