CN106047505A - Natural-formulation multi-effect cleaning composition and application thereof - Google Patents

Natural-formulation multi-effect cleaning composition and application thereof Download PDF

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Publication number
CN106047505A
CN106047505A CN201610367253.1A CN201610367253A CN106047505A CN 106047505 A CN106047505 A CN 106047505A CN 201610367253 A CN201610367253 A CN 201610367253A CN 106047505 A CN106047505 A CN 106047505A
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surfactant
cleaning combination
sodium
parts
natural
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童星
王金平
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JIANGSU XUEBAO DAILY CHEMICAL CO Ltd
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JIANGSU XUEBAO DAILY CHEMICAL CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/10Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0047Other compounding ingredients characterised by their effect pH regulated compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0073Anticorrosion compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/384Animal products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/34Derivatives of acids of phosphorus
    • C11D1/345Phosphates or phosphites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/78Neutral esters of acids of phosphorus

Abstract

The invention discloses a natural-formulation multi-effect cleaning composition which comprises, by weight, 1-10 parts of surfactant, 0-5 parts of essence, 0.01-2 parts of preservative and 10-100 parts of water. The surfactant is at least one of N-acyl amino acid salt surfactant, lecithin, alkyl glycoside, lauryl alcohol ether sulfate, lauryl alcohol ether phosphate, coconut oil acyl diethanolamine, tallow fatty acid and heterogeneous alcohol ether. Natural products are adopted or used as natural product derivatives for chemical modification of a reaction product, so that the composition is wide in applicable cleaning range, high in detergency and little in damage to skin. The composition can remove dirt of hard-surface floor tiles and heavy oil stain of a kitchen range hood, can serve as tableware cleaning essence and fruit-vegetable cleaner, can serve as a laundry detergent and has a function of killing glucose coccus and Escherichia coli.

Description

A kind of natural formula multiple-effect cleaning combination and application thereof
Technical field
The present invention relates to detergent technical field, be specifically related to a kind of natural formula multiple-effect cleaning combination and application thereof.
Background technology
Detergent the most on the market is of a great variety, and common kind has: the kitchen oil stain dirty for kitchen heavy oil cleans Agent, the fruit-vegetable clear lotion of removal fruit and vegetable surfaces residual pesticide, the floor cleaner for floor use, the detergent for tableware With the detergent being exclusively used in Child tableware.The function of abluent is mainly passed through the selection of surfactant and compounds realization.Existing Have in technology abluent conventional surfactant include: fatty alcohol polyethenoxy ether class, fatty alcohol polyoxyethylene ether sulfate, Long-chain alkyl benzene sulfonate.Above-mentioned surfactant mostly is organic synthesis and obtains, although have a stronger dirt-removing power, but table Face activating agent can cause the lipid dissolution of skin surface, amino acid and protein dissolution, transdermal penetration etc., for commonly used person Hand skin stimulate and injury bigger.The particular make-up of surfactant and the kind the most district of applicable article-cleaning Not, cleanout fluid classification is relatively thin, consumer need to buy multiple have clean product targetedly, some use relatively low clear of frequencies Lotion can be dropped because of the shelf-life, thus cause the wasting of resources and increase environmental pollution.
Summary of the invention
It is an object of the invention to overcome defect present in prior art, it is provided that a kind of natural formula multiple-effect cleans combination Thing, said composition uses natural surfactant, and strong detergency, little to skin damage, biological degradability is good, and is applicable to ground The cleaning of article during plate, fruit and vegerable, tableware etc. are many.
For achieving the above object, the technical scheme is that a kind of natural formula multiple-effect cleaning combination, its feature exists In, mark meter by weight includes: surfactant 1~10 parts, essence 0~5 parts, preservative 0.01~2 parts and water 10~100 Part, described surfactant is selected from N-acylamino acid salt form surfactant, lecithin, alkyl polyglucoside, lauryl alcohol sulfur At least one in hydrochlorate, lauryl alcohol phosphate ester salt, cocos nucifera oil acyl diethanolamine, tallow fatty acids and isomery alcohol ether.
Surfactant in above-mentioned cleansing composition is natural goods, or using natural goods as reactant chemical modification Prepare, make abluent have cleaning and the moisturizing effect of gentleness.The scope that the water yield is added is relatively wide, and this abluent can be concentrated type, Also can be used directly.
Preferably technical scheme is that cleaning combination also includes pH value regulator, and the pH value of cleaning combination is 8~9.5. The weak alkaline aqueous solution of the abluent formation soluble in water of alkalescence has dissolving peptizaiton, aqueous solution heating or rush to protein Enter protein macromolecule hydrolysis;But the saponification of weak alkaline aqueous solution and emulsification aqueous solution penetrate deep into oils and fats and article Between surface, accelerate the dissolving of oils and fats.The wettability of the too strong then abluent aqueous solution of alkalescence is poor, thus is unfavorable for ensureing oil Fat cleaning performance.It addition, above-mentioned surfactant has excellent stability in the basic conditions.
Preferably technical scheme is that described preservative is at least one in sodium hydroxy methyl glycinate, sodium lactate.Hydroxyl Methylglycine sodium, sodium lactate, calcium propionate are respectively provided with antibacterial effect, have good biocompatibility, to skin irritation simultaneously Little.
Preferably technical scheme is that surfactant is by N-acylamino acid salt form surfactant, lecithin and is selected from Alkyl polyglucoside, lauryl alcohol sulfate, lauryl alcohol phosphate ester salt, cocos nucifera oil acyl diethanolamine, tallow fatty acids and isomery alcohol ether In at least one compounding form, in compound surfactant, the percentage by weight of N-acylamino acid salt form surfactant is 50~80%, in compound surfactant, the percentage by weight of lecithin is 2~6%.Alkyl polyglucoside, cocos nucifera oil acyl diethanolamine, cattle Fat fatty acid and isomery alcohol ether belong to nonionic surfactant, and lauryl alcohol sulfate, lauryl alcohol phosphate ester salt are anion Surfactant, uses anionic surfactant N-acyl amino hydrochlorate, amphoteric surfactant lecithin compounding and another One anionic surfactant or nonionic surfactant compound, compared with the abluent containing single surfactant, clearly Clean dose has the wider pH value scope of application, and emulsion dispersion wettability is improved simultaneously, contribute to pesticide residues, oils and fats, The dispersion of protein etc..Preferred technical scheme is, nonionic surfactant alkyl polyglucoside, cocos nucifera oil acyl diethanolamine, cattle At least one during fat fatty acid and isomery alcohol ether belong to compounds with N-acyl amino hydrochlorate, lecithin.
Preferably technical scheme is that pH value regulator is selected from solubility weak acid sodium salt, solubility weak acid potassium salt, diethanol At least one in amine, triethanolamine.Solubility weak acid sodium salt is specially in sodium carbonate, sodium bicarbonate, sodium phosphate, sodium acetate A kind of.The addition of sodium phosphate also regulates the viscosity of cleaning agent.
Preferably technical scheme is that described preservative is combined by sodium hydroxy methyl glycinate and sodium lactate, combination anticorrosion In agent, the percentage by weight of sodium lactate is 55~75%.Organic anti-corrosive agent is easier to the article surface remained after cleaning, by two kinds Preservative is applied in combination, it is possible to expand antimicrobial spectrum, and sodium hydroxy methyl glycinate and sodium lactate have cooperative effect on bacteriostasis, More higher than single sodium hydroxy methyl glycinate or sodium lactate fungistatic effect.
Preferably technical scheme is that N-acyl amino acid type surfactant is sodium lauroyl sarcosine, the sweet ammonia of cocos nucifera oil acyl At least one in acid potassium, sodium cocoyl glutamate.
Preferably technical scheme is, cleaning combination also comprises natural thickener 0.01~5 parts.Natural thickener is specially Arabic gum, gelatin, pectin, Konjac glucomannan, agar etc..Add thickening agent and contribute to increasing the viscosity of abluent, contribute to cleaning Agent in the holding of article surface, reduces sagging and the waste that causes.
Preferably technical scheme is, cleaning combination also comprises additive 0.5~2 parts, and described additive is selected from Fructus Citri Limoniae At least one in acid sodium, potassium citrate, sodium gluconate, potassium gluconate.Additive is chelating agen, can chelate rapidly hard water In magnesium ion and calcium ion, it is to avoid the phenomenons such as medicated clothing is hardening, contribute to reduce abluent consumption.
Present invention also offers a kind of application according to the natural formula multiple-effect cleaning combination described in above-mentioned any one, Be applied to the cleaning of article, described article include floor, carpet, floor tile, kitchen weight oil fouling equipment kitchen tools, tableware, fruit and vegerable, Medicated clothing.
Advantages of the present invention and having the beneficial effects that:
The component of natural formula multiple-effect cleaning combination of the present invention uses natural goods or using natural goods as reactant chemical modification The natural goods derivant prepared, is suitable for that clean range is wide, strong detergency and little to skin damage, belongs to Green Product.Should The dirt of abluent the most removable crust floor tiles, exhauster for removing kitchen fumes heavy oil are dirty, the most capable of washing as tableware detergent and Fruit-vegetable clear lotion, can be used as liquid detergent, possesses and kills glucose coccus and escherichia coli function.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is further described.Following example are only used for more Add and clearly demonstrate technical scheme, and can not limit the scope of the invention with this.
Embodiment 1
Consisting of of the natural formula multiple-effect cleaning combination of embodiment 1: 1 part of surfactant, preservative 2 parts and water 100 Part, surfactant is two (pungent amino-ethyl) Glycine sodium, and preservative is sodium lactate.Detecting through acid-base value, this cleaning is combined The pH value of thing is neutral.
Embodiment 2
Consisting of of the natural formula multiple-effect cleaning combination of embodiment 2: 10 parts of surfactant, 5 parts of essence, preservative 0.01 Part, sodium citrate 2 parts and 10 parts of water, surfactant is sodium cocoyl glutamate, and preservative is tallow fatty acids and methylol Glycine sodium, essence selects orange peel extracting solution.Detecting through acid-base value, the pH value of this cleaning combination is alkalescence.This enforcement Example 2 is the abluent of concentrated type.
Embodiment 3
Consisting of of the natural formula multiple-effect cleaning combination of embodiment 3: 5 parts of surfactant, 3 parts of essence, preservative 1 part, Sodium citrate 2 parts and 100 parts of water, surfactant is sodium cocoyl glutamate, and preservative is sodium hydroxy methyl glycinate, and essence selects Select orange peel extracting solution.Embodiment 3 adds 1 part of thickening agent gelatin.
Embodiment 4
Embodiment 4 is distinguished as with embodiment 3: surfactant is that lecithin, alkyl polyglucoside and lauryl alcohol sulfate are with weight The amount combination than 1:1:1, is 8 with sodium carbonate liquor regulation pH value.
Embodiment 5
Embodiment 5 is with the difference of embodiment 4: surfactant be lauryl alcohol phosphate ester salt, cocos nucifera oil acyl diethanolamine and Isomery alcohol ether, with the combination of weight ratio 1:1:1, is 9.5 with sodium radio-phosphate,P-32 solution regulation pH value.
Embodiment 6
Embodiment 6 is with the difference of embodiment 5, is 8.7 with sodium bicarbonate solution regulation pH value.
Embodiment 7
Embodiment 7 is with the difference of embodiment 6, and surfactant is by sodium lauroyl sarcosine, lecithin and cocos nucifera oil acyl diethyl Hydramine is compounding to be formed, and in compound surfactant, the percentage by weight of N-acylamino acid salt form surfactant is 50%, compounding In surfactant, the percentage by weight of lecithin is 6%.Preservative is combined by sodium hydroxy methyl glycinate and sodium lactate, group Closing the percentage by weight of sodium lactate in preservative is 55%.
Embodiment 8
Embodiment 8 is with the difference of embodiment 7: surfactant is by cocos nucifera oil acyl glycine potassium, lecithin and lauryl alcohol sulfur Hydrochlorate is compounding to be formed, and in compound surfactant, the percentage by weight of N-acylamino acid salt form surfactant is 80%, compounding In surfactant, the percentage by weight of lecithin is 2%;In preservative, the percentage by weight of sodium lactate is 75%.
Embodiment 9
Embodiment 9 is with the difference of embodiment 7: in compound surfactant, the percentage by weight of sodium cocoyl glutamate is 65%, in compound surfactant, the percentage by weight of lecithin is 4%;In preservative, the percentage by weight of sodium lactate is 65%。
Comparative example
Comparative example uses fatty alcohol-polyoxyethylene ether and the table of polyoxyethylenated alcohol sodium sulfate 1:1 mixing alternate embodiment 1 Face activating agent, preservative uses parabens, and consumption is same as in Example 2.
The sample that embodiment 3 is adds the water dilution of 90 parts, carries out performance contrast test with embodiment 1-2 and 4-9.
Detergency test: according to GB/T13174-2008 detection by detergent use in the detergency of cleaning dress material, with decontamination Ratio meter;
Anti-microbial property is tested: preparation contains glucose coccus respectively and escherichia coli bacterium number is 108 ~109Bacterium solution, will The embodiment of 9.9ml and comparative example sample stock solution add in 0.1ml bacterium solution, after contacting 30 seconds, add inactivator at 9ml Phosphate buffer adds this solution of 1ml, carries out gradient dilution the most at once.At 37 DEG C, 48 are cultivated with plate count agar Viable count is measured after hour and after 7 days.Log reduction is calculated, according to following judgement by the logarithmic difference of inoculation bacterium number with viable count Benchmark is evaluated.Grading is evaluated as follows:
Log reduction >=5 in A+ test organisms;
Log reduction 4~5 in A test organisms;
Log reduction 3~4 in B test organisms;
Log reduction≤3 in C test organisms.
Pesticide residues remove test: use in GB/T 24691 fruit and vegerable dish washing detergent compositions and remain in appendix A The verification method of pesticide eccysis effect is measured.
Comparatively speaking, natural goods and/or natural goods are all used due to the surfactant contained in embodiment 1 and preservative etc. Derivant, the abluent after water dilutes is alkalescence, and therefore long-time use is little to skin damage.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, on the premise of without departing from the technology of the present invention principle, it is also possible to make some improvements and modifications, these improvements and modifications Also should be regarded as protection scope of the present invention.

Claims (10)

1. a natural formula multiple-effect cleaning combination, it is characterised in that mark meter by weight includes: surfactant 1~10 Part, essence 0~5 parts, preservative 0.01~2 parts and water 10~100 parts, described surfactant is selected from N-acyl amino hydrochlorate Type surfactant, lecithin, alkyl polyglucoside, lauryl alcohol sulfate, lauryl alcohol phosphate ester salt, cocos nucifera oil acyl diethanolamine, At least one in tallow fatty acids and isomery alcohol ether.
Natural formula multiple-effect cleaning combination the most according to claim 1, it is characterised in that cleaning combination also includes pH Value regulator, the pH value of cleaning combination is 8~9.5.
Natural formula multiple-effect cleaning combination the most according to claim 1 and 2, it is characterised in that described preservative is choosing At least one in sodium hydroxy methyl glycinate, sodium lactate.
Natural formula multiple-effect cleaning combination the most according to claim 1, it is characterised in that surfactant is by N-acyl group Aminoacid salt form surfactant, lecithin with selected from alkyl polyglucoside, lauryl alcohol sulfate, lauryl alcohol phosphate ester salt, coconut palm At least one in oleoyl diethanolamine, tallow fatty acids and isomery alcohol ether is compounding to be formed, N-acyl group in compound surfactant The percentage by weight of aminoacid salt form surfactant is 50~80%, the percentage by weight of lecithin in compound surfactant It is 2~6%.
Natural formula multiple-effect cleaning combination the most according to claim 2, it is characterised in that pH value regulator can for being selected from At least one in dissolubility weak acid sodium salt, solubility weak acid potassium salt, diethanolamine, triethanolamine.
Natural formula multiple-effect cleaning combination the most according to claim 3, it is characterised in that described preservative is by methylol Glycine sodium and sodium lactate combine, and in preservative, the percentage by weight of sodium lactate is 55~75%.
7. according to the natural formula multiple-effect cleaning combination described in claim 1 or 4, it is characterised in that N-acyl amino acid type Surfactant is at least one in sodium lauroyl sarcosine, cocos nucifera oil acyl glycine potassium, sodium cocoyl glutamate.
Natural formula multiple-effect cleaning combination the most according to claim 1, it is characterised in that cleaning combination also comprises sky So thickening agent 0.01~5 parts.
Right formula multiple-effect cleaning combination the most according to claim 1, it is characterised in that cleaning combination also comprises interpolation Agent 0.5~2 parts, described additive is at least in sodium citrate, potassium citrate, sodium gluconate, potassium gluconate Kind.
10. an application for natural formula multiple-effect cleaning combination as claimed in any of claims 1 to 9, by it Being applied to the cleaning of article, described article include floor, carpet, floor tile, kitchen weight oil fouling equipment kitchen tools, tableware, fruit and vegerable, clothing Thing.
CN201610367253.1A 2016-05-30 2016-05-30 Natural-formulation multi-effect cleaning composition and application thereof Pending CN106047505A (en)

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CN106675818A (en) * 2016-12-27 2017-05-17 江西宜信堂医疗科技有限公司 Oil removing agent and preparation method thereof
CN107216957A (en) * 2017-07-20 2017-09-29 苏州龙腾万里化工科技有限公司 A kind of cleaning agent for Kitchen Ventilator and Cooking Stove
CN107723121A (en) * 2017-11-02 2018-02-23 青昊环保科技(上海)有限公司 A kind of multifunctional cleaning agent
CN108394153A (en) * 2018-01-10 2018-08-14 合肥盛鼎包装材料有限公司 A kind of preparation process of PVA composite membranes
CN108857856A (en) * 2018-07-23 2018-11-23 宁波江丰电子材料股份有限公司 CMP fixed ring cleaning method
CN108913379A (en) * 2018-06-29 2018-11-30 杭州白鹭清洁剂厂 A kind of emulsifier and preparation method thereof
CN109456856A (en) * 2018-12-04 2019-03-12 浙江大学自贡创新中心 A kind of natural fruit and vegetables detergent
CN109797055A (en) * 2019-03-21 2019-05-24 冠道(广州)科技有限公司 A kind of multifunctional detergent and preparation method thereof that addition amino acid table is living
CN109957460A (en) * 2017-12-25 2019-07-02 浙江神英科技有限公司 A kind of cleaning agent for dinnerware and preparation method thereof containing bactericide
CN110079399A (en) * 2019-05-31 2019-08-02 深圳市润贝化工有限公司 One kind being used for aircraft passenger compartment carpet cleaner
CN111714402A (en) * 2020-06-10 2020-09-29 广东柏俐臣生物科技有限公司 Mild cleansing composition and preparation method thereof
CN113174300A (en) * 2021-04-14 2021-07-27 大连工业大学 Grease-based acyl amino acid salt infant laundry detergent and preparation method thereof
CN113444586A (en) * 2021-07-28 2021-09-28 巴建 Composition for removing pesticide residues on surfaces of fruits and vegetables and preparation method thereof
CN115368971A (en) * 2022-08-08 2022-11-22 南京华狮新材料有限公司 Detergent for dish-washing machine

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CN106675818A (en) * 2016-12-27 2017-05-17 江西宜信堂医疗科技有限公司 Oil removing agent and preparation method thereof
CN107216957A (en) * 2017-07-20 2017-09-29 苏州龙腾万里化工科技有限公司 A kind of cleaning agent for Kitchen Ventilator and Cooking Stove
CN107723121A (en) * 2017-11-02 2018-02-23 青昊环保科技(上海)有限公司 A kind of multifunctional cleaning agent
CN109957460A (en) * 2017-12-25 2019-07-02 浙江神英科技有限公司 A kind of cleaning agent for dinnerware and preparation method thereof containing bactericide
CN108394153A (en) * 2018-01-10 2018-08-14 合肥盛鼎包装材料有限公司 A kind of preparation process of PVA composite membranes
CN108913379A (en) * 2018-06-29 2018-11-30 杭州白鹭清洁剂厂 A kind of emulsifier and preparation method thereof
CN108857856A (en) * 2018-07-23 2018-11-23 宁波江丰电子材料股份有限公司 CMP fixed ring cleaning method
CN109456856A (en) * 2018-12-04 2019-03-12 浙江大学自贡创新中心 A kind of natural fruit and vegetables detergent
CN109797055A (en) * 2019-03-21 2019-05-24 冠道(广州)科技有限公司 A kind of multifunctional detergent and preparation method thereof that addition amino acid table is living
CN109797055B (en) * 2019-03-21 2021-06-08 广东站成研创科技有限公司 Multifunctional detergent added with amino acid surfactant and preparation method thereof
CN110079399A (en) * 2019-05-31 2019-08-02 深圳市润贝化工有限公司 One kind being used for aircraft passenger compartment carpet cleaner
CN111714402A (en) * 2020-06-10 2020-09-29 广东柏俐臣生物科技有限公司 Mild cleansing composition and preparation method thereof
CN113174300A (en) * 2021-04-14 2021-07-27 大连工业大学 Grease-based acyl amino acid salt infant laundry detergent and preparation method thereof
CN113444586A (en) * 2021-07-28 2021-09-28 巴建 Composition for removing pesticide residues on surfaces of fruits and vegetables and preparation method thereof
CN115368971A (en) * 2022-08-08 2022-11-22 南京华狮新材料有限公司 Detergent for dish-washing machine

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