CN103724133A - 一种利用糖厂酒精废液的腐植酸型缓控释磷肥 - Google Patents
一种利用糖厂酒精废液的腐植酸型缓控释磷肥 Download PDFInfo
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- CN103724133A CN103724133A CN201310742817.1A CN201310742817A CN103724133A CN 103724133 A CN103724133 A CN 103724133A CN 201310742817 A CN201310742817 A CN 201310742817A CN 103724133 A CN103724133 A CN 103724133A
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- Prior art keywords
- sugar refinery
- waste liquid
- phosphate fertilizer
- alcohol waste
- sugar
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 91
- 239000002699 waste material Substances 0.000 title claims abstract description 87
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000004021 humic acid Substances 0.000 title claims abstract description 40
- 239000003337 fertilizer Substances 0.000 title abstract description 20
- 229910052698 phosphorus Inorganic materials 0.000 title abstract description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 4
- 239000011574 phosphorus Substances 0.000 title abstract 4
- 238000013268 sustained release Methods 0.000 title abstract 4
- 239000012730 sustained-release form Substances 0.000 title abstract 4
- 239000002910 solid waste Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims description 90
- 239000002686 phosphate fertilizer Substances 0.000 claims description 62
- 239000002245 particle Substances 0.000 claims description 42
- 238000013270 controlled release Methods 0.000 claims description 36
- 239000005760 Difenoconazole Substances 0.000 claims description 30
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical group O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 30
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical group O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 21
- 229930006000 Sucrose Natural products 0.000 claims description 21
- 229960004793 sucrose Drugs 0.000 claims description 21
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 18
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 16
- 238000012216 screening Methods 0.000 claims description 16
- CZMRCDWAGMRECN-UHFFFAOYSA-N Rohrzucker Natural products OCC1OC(CO)(OC2OC(CO)C(O)C(O)C2O)C(O)C1O CZMRCDWAGMRECN-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 238000005469 granulation Methods 0.000 claims description 14
- 230000003179 granulation Effects 0.000 claims description 14
- 239000004563 wettable powder Substances 0.000 claims description 13
- 239000011247 coating layer Substances 0.000 claims description 12
- 239000000470 constituent Substances 0.000 claims description 12
- 229940045641 monobasic sodium phosphate Drugs 0.000 claims description 12
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 12
- 229920000742 Cotton Polymers 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 9
- 239000006200 vaporizer Substances 0.000 claims description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004202 carbamide Substances 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000004557 technical material Substances 0.000 claims description 5
- 229940062672 calcium dihydrogen phosphate Drugs 0.000 claims description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
- UUVBYOGFRMMMQL-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca].OP(O)(O)=O UUVBYOGFRMMMQL-UHFFFAOYSA-N 0.000 claims description 4
- 210000003608 fece Anatomy 0.000 claims description 4
- 239000010871 livestock manure Substances 0.000 claims description 4
- 239000003595 mist Substances 0.000 claims description 2
- 238000005457 optimization Methods 0.000 claims 1
- 239000000417 fungicide Substances 0.000 abstract description 5
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 20
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 12
- 239000001506 calcium phosphate Substances 0.000 description 12
- 229910000150 monocalcium phosphate Inorganic materials 0.000 description 12
- 241000219146 Gossypium Species 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 7
- 125000003636 chemical group Chemical group 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 235000013339 cereals Nutrition 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 4
- 230000000855 fungicidal effect Effects 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 230000007306 turnover Effects 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000013379 molasses Nutrition 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 230000000050 nutritive effect Effects 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- RMOGWMIKYWRTKW-UONOGXRCSA-N (S,S)-paclobutrazol Chemical compound C([C@@H]([C@@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1 RMOGWMIKYWRTKW-UONOGXRCSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000005985 Paclobutrazol Substances 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 238000009923 sugaring Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CN201310742817.1A CN103724133B (zh) | 2013-12-30 | 2013-12-30 | 一种利用糖厂酒精废液的腐植酸型缓控释磷肥 |
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CN201310742817.1A CN103724133B (zh) | 2013-12-30 | 2013-12-30 | 一种利用糖厂酒精废液的腐植酸型缓控释磷肥 |
Publications (2)
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CN103724133A true CN103724133A (zh) | 2014-04-16 |
CN103724133B CN103724133B (zh) | 2016-01-20 |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06172075A (ja) * | 1992-12-02 | 1994-06-21 | Honen Corp | 緩効性固形肥料 |
JP3136268B2 (ja) * | 1996-06-18 | 2001-02-19 | 電気化学工業株式会社 | 粒状肥料の製造方法 |
CN101041600A (zh) * | 2007-03-16 | 2007-09-26 | 阴高鹏 | 腐植酸复合肥料及其制备方法 |
CN102795946A (zh) * | 2012-07-27 | 2012-11-28 | 山东农大肥业科技有限公司 | 双活双效棉花腐植酸缓释肥的配方及其制备方法 |
CN102850140A (zh) * | 2012-09-29 | 2013-01-02 | 广西力源肥业科技农化有限公司 | 一种防结块的复混肥料及其制备方法 |
-
2013
- 2013-12-30 CN CN201310742817.1A patent/CN103724133B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06172075A (ja) * | 1992-12-02 | 1994-06-21 | Honen Corp | 緩効性固形肥料 |
JP3136268B2 (ja) * | 1996-06-18 | 2001-02-19 | 電気化学工業株式会社 | 粒状肥料の製造方法 |
CN101041600A (zh) * | 2007-03-16 | 2007-09-26 | 阴高鹏 | 腐植酸复合肥料及其制备方法 |
CN102795946A (zh) * | 2012-07-27 | 2012-11-28 | 山东农大肥业科技有限公司 | 双活双效棉花腐植酸缓释肥的配方及其制备方法 |
CN102850140A (zh) * | 2012-09-29 | 2013-01-02 | 广西力源肥业科技农化有限公司 | 一种防结块的复混肥料及其制备方法 |
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C14 | Grant of patent or utility model | ||
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TR01 | Transfer of patent right |
Effective date of registration: 20200117 Address after: 530007, B-2 building, headquarter of China ASEAN enterprise, No. 1, headquarters Road, Nanning hi tech Zone, the Guangxi Zhuang Autonomous Region Patentee after: GUANGXI QINDE TECHNOLOGY CO.,LTD. Address before: 530007, B-2 building, headquarter of China ASEAN enterprise, No. 1, headquarters Road, Nanning hi tech Zone, the Guangxi Zhuang Autonomous Region Patentee before: Ye Changdong |
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TR01 | Transfer of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A Humic Acid Type Slow and Controlled Release Phosphate Fertilizer Utilizing Alcohol Waste Liquid from Sugar Factory Effective date of registration: 20221122 Granted publication date: 20160120 Pledgee: Nanning United Innovation Financing Guarantee Co.,Ltd. Pledgor: GUANGXI QINDE TECHNOLOGY CO.,LTD. Registration number: Y2022450000204 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20231109 Granted publication date: 20160120 Pledgee: Nanning United Innovation Financing Guarantee Co.,Ltd. Pledgor: GUANGXI QINDE TECHNOLOGY CO.,LTD. Registration number: Y2022450000204 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A humic acid type slow-release phosphate fertilizer utilizing alcohol waste liquid from a sugar factory Effective date of registration: 20231120 Granted publication date: 20160120 Pledgee: Nanning United Innovation Financing Guarantee Co.,Ltd. Pledgor: GUANGXI QINDE TECHNOLOGY CO.,LTD. Registration number: Y2023450000145 |