CN103665259B - 一种耐高温且抗剪切的水溶性支化聚合物及其制备方法 - Google Patents
一种耐高温且抗剪切的水溶性支化聚合物及其制备方法 Download PDFInfo
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- CN103665259B CN103665259B CN201310683285.9A CN201310683285A CN103665259B CN 103665259 B CN103665259 B CN 103665259B CN 201310683285 A CN201310683285 A CN 201310683285A CN 103665259 B CN103665259 B CN 103665259B
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- branched polymer
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- high temperature
- temperature resistant
- stable water
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- 229920000642 polymer Polymers 0.000 title claims abstract description 77
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000000178 monomer Substances 0.000 claims abstract description 31
- UUGLSEIATNSHRI-UHFFFAOYSA-N 1,3,4,6-tetrakis(hydroxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound OCN1C(=O)N(CO)C2C1N(CO)C(=O)N2CO UUGLSEIATNSHRI-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 claims abstract description 16
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 16
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004160 Ammonium persulphate Substances 0.000 claims abstract description 14
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000004141 Sodium laurylsulphate Substances 0.000 claims abstract description 14
- 235000019395 ammonium persulphate Nutrition 0.000 claims abstract description 14
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- 230000001186 cumulative effect Effects 0.000 claims description 6
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 6
- 239000006085 branching agent Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 abstract description 6
- 239000003999 initiator Substances 0.000 abstract description 3
- 239000003995 emulsifying agent Substances 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 238000011161 development Methods 0.000 abstract 1
- 230000018109 developmental process Effects 0.000 abstract 1
- 239000000843 powder Substances 0.000 description 14
- 239000000126 substance Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 229960000935 dehydrated alcohol Drugs 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006073 displacement reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 238000004621 scanning probe microscopy Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
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- 238000011160 research Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 241000555268 Dendroides Species 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- -1 amino, imino- Chemical class 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
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- 238000009826 distribution Methods 0.000 description 1
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- 229960004756 ethanol Drugs 0.000 description 1
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- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
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- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000005311 nuclear magnetism Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- 238000001370 static light scattering Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 229940126680 traditional chinese medicines Drugs 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
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Abstract
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CN201310683285.9A CN103665259B (zh) | 2013-12-13 | 2013-12-13 | 一种耐高温且抗剪切的水溶性支化聚合物及其制备方法 |
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CN103665259A CN103665259A (zh) | 2014-03-26 |
CN103665259B true CN103665259B (zh) | 2015-12-09 |
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CN105294900B (zh) * | 2015-04-09 | 2017-09-12 | 中国石油化工股份有限公司 | 一种支化型粘弹性粉末状驱油剂及制备方法 |
CN112794953A (zh) * | 2020-12-31 | 2021-05-14 | 中国石油大学(华东) | 一种支化聚合物型酸液稠化剂的制备方法 |
CN113831450B (zh) * | 2021-10-27 | 2022-11-15 | 山东大学 | 一种支化型阳离子聚丙烯酰胺絮凝剂及其制备方法与应用 |
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CN1056856C (zh) * | 1994-01-20 | 2000-09-27 | 中国科学院感光化学研究所 | 耐温抗盐水溶性光聚合物 |
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Non-Patent Citations (2)
Title |
---|
Fabrication of the weak gel based on hydrolyzed polyacrylamide crosslinked by inorganic-organic mixed crosslinker;Haipeng Xin, et al;《Journal of Polymer Research》;20131112;第20卷(第12期);第311页 * |
丙烯酰胺/2-丙烯酰胺基-2-甲基丙磺酸钠/全氟己基乙基甲基丙烯酸酯三元共聚物的疏水缔合性质;宋新旺等;《石油化工》;20090415;第38卷(第4期);第400-405页 * |
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Effective date of registration: 20191224 Address after: No. 15-1, Qingnian Road East section, Dongzhou District, Fushun City, Liaoning Province Patentee after: Fushun Dragon Chemical Plant Address before: 250012 No. 44 West Wenhua Road, Lixia District, Shandong, Ji'nan Patentee before: Shandong University |
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Denomination of invention: A water-soluble branched polymer with high temperature resistance and shear resistance and its preparation method Granted publication date: 20151209 Pledgee: Fushun Dongzhou sub branch of Bank of China Ltd. Pledgor: FUSHUN DRAGON CHEMICAL PLANT Registration number: Y2024210000041 |
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