CN103627330A - Composite rubber material - Google Patents
Composite rubber material Download PDFInfo
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- CN103627330A CN103627330A CN201210312167.2A CN201210312167A CN103627330A CN 103627330 A CN103627330 A CN 103627330A CN 201210312167 A CN201210312167 A CN 201210312167A CN 103627330 A CN103627330 A CN 103627330A
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Abstract
The invention relates to a bonding rubber material, especially provides a binder or a thermosetting molding rubber cement for bonding and reinforcement of door cores of a fireproof door an antitheft door and bonding and production of building and decoration materials, and aims to provide a composite rubber material, with low cost, good bonding strength and rapid surface dry, which can be cured at room temperature. The composite rubber material is characterized in that the composite rubber material is composed of a water-based A material and a polyurethane prepolymer-containing B material, the ratio (weight ratio) of the A material to the B material is 0.5-1:0.5-1, the A material comprises 30-70% of water and/or water glass and/or silica sol, 19.5-48% of organic modifiers, and 12-55% of additives, the B material comprises polyurethane prepolymers with a content of being more than 30%, 8-24% of -NCO group, and 0-30% of synergists, The synergists are one or combination of more than one selected from a polymerization inhibitor, a blocking agent, a water glass curing agent and a diluting agent. The composite rubber material is advantaged by good bonding strength, flame retardance, thermal insulation, low price and environmental protection.
Description
Technical field
The present invention relates to a kind of bonding glue material, be particularly useful for fire door security door core bonding with enhancing and building, finishing material is bonding and processing binding agent or thermoset forming rubber cement.
Background technology
The bonding sizing material of existing fire door and antitheft door core and door face board is mostly polyurethane foam glue, its cohesive strength requires to be not less than 0.5mPa, it is mainly that polyester polyol or polyether glycol react the base polyurethane prepolymer for use as containing remaining-NCO group forming with polyisocyanates, conventionally be also added with the organic solvent of proper catalyst, stablizer and 10-50%, general-about 2%--6% of NCO group content, flexible is better, bonding strength is higher, advantage easy to use, but price is higher; Performed polymer and solvent are inflammable, and burning produces dense black smoke and discharges toxic gas; Foamed glue solidifies by the effect of water in air vapour, usually in order to obtain the initial bonding strength that is enough to fixing core body and strengthens structure, particularly when relative humidity is lower than 50% time, often need to be after applying glue atomized water spray, otherwise easily because solidifying slowly and reacting insufficient formation hollowing; If directly add water to foamed glue, tend to cause foamed glue fragility to increase, cohesive strength reduces, and it is bad that performance becomes; Because performed polymer in foamed glue is containing a small amount of activity-NCO group, in storage process-the constantly minimizing of NCO group, retrogradation is solidified or is reacted and solidify with moisture in air and staving gradually, and the quality guaranteed period is short.For improving package stability, reducing thickening and gel machine can extend the shelf life, and simultaneously in order to reduce costs, often needs to add acid or acyl chloride used as stabilizers during production, with a large amount of methylene dichloride, makes thinner, deposits potential corrosion risk.Because market competition is day by day fierce, many enterprises attempt to substitute foamed glue with lower-cost inorganic sizing material, but inorganic sizing material to metal and intermetallic and metal and nonmetal initial bonding strength that is difficult to overcome a little less than, surface drying time is long, fragility is large, cohesive strength is little, the common fault of the moisture absorption that absorbs water causes its test to baffle repeatedly.
And the organic binder bonds such as foamed glue and epoxy resin glue, acrylic size, neoprene latex are squeegeeed etc. for building, building materials and decoration ranks especially energy saving building decorative block or insulation blocks stickup and are also existed cost high, the inflammable Similar Problems that waits, have also containing obnoxious flavour.
Water glass or silicon sol, as a kind of inorganic adhesive material, have feature high temperature resistant, cheap environmental protection, be used for preparation fire prevention rubber cement, but bonding strength and acidproof water tolerance still have some deficits.Due to the inorganic water solubles particularly water glass and silicon sol and various organic gel material physico-chemical property totally different, select or the improper fusion of proportioning after or solidify immediately or in the short period of time retrogradation then solidify, induration is breaking and Dusting very easily.A little less than its blend glue stuff adhesive power, intensity difference.Market in urgent need is a kind of a price advantage, to having compared with high initial bonding strength and bonding strength, surface drying between the multiple materials such as metal and solidifying comparatively fast, has the bonding sizing material of anti-flaming thermal-insulation performance simultaneously.
Summary of the invention
For above problem, contriver has carried out arduous exploration and lot of experiments.The object of this invention is to provide a kind of cost lower, to metal and nonmetally have a good bonding strength, dry environment also can ambient cure, and surface drying is cheap fire-retardant compound sizing material faster.Another object of the present invention is further to strengthen sizing material anti-flaming thermal-insulation of the present invention and/or inhibition rustless property.The present invention seeks to realize like this:
A compound sizing material, is characterized in that being expected and the B material that contains base polyurethane prepolymer for use as forms by water-based A, and A material is (weight ratio) with the proportioning of B material:
A：B=?0.5--1：0.5--1
Wherein A expects moisture and/or water glass and/or silicon sol and additive,
In A material, each composition weight percent is:
Water and/or water glass and/or silicon sol 27-100%
Organic synergist 0-48%
Additive 0-55%
Described additive is one or more combination in dispersion agent, tensio-active agent, tackifier, coupling agent, toughener, anti-heavy agent, fire retardant, rust-preventive agent, antiaging agent, flow agent, defoamer, thinner; Described organic synergist for containing thiazolinyl, hydroxyl, carboxyl and/or other with active hydrogen can with the active substance of-NCO group generation crosslinking reaction; Base polyurethane prepolymer for use as content >30% in B material, containing-NCO group 5-25%, synergistic agent 0-30%, described synergistic agent is one or more combination in stopper, stablizer, encapsulant, water glass curing agent, thinner.
Described compound sizing material, is characterized in that, A material is (weight ratio) with the proportioning of B material:
A：B=?1：0.5--1
In A material, each composition weight percent is:
Water and/or water glass and/or the organic synergist 15-48% of silicon sol 30-70% additive 12-55%
Described organic synergist is acrylic resin or emulsion, organosilicon acrylic resin or emulsion, styrene-acrylic resin or emulsion, epoxy resin, regeneration composite glue solution, Synolac, aldehyde ketone resin, terpolycyantoamino-formaldehyde resin, vibrin, urea-formaldehyde resin, one or more combination in re-dispersible glue powder, polyvalent alcohol; In described B material, contain polyisocyanates ,-NCO group accounts for 8-20% in B material.
Described compound sizing material, is characterized in that the organic synergist described in A material is one or more combination in epoxy resin resin, acrylic resin/emulsion or re-dispersible glue powder; Described additive toughener is one or more combination in breeze, metal powder, micro mist or expansible black lead; Base polyurethane prepolymer for use as described in B material is foamed glue, and described polyisocyanates is black material; For A material and the weight ratio of B material are: A:B=1:1
In additive B material, each composition weight percent is:
Foamed glue 50-70%
Black material 30-50%
Synergistic agent 0-20%.
Described compound sizing material, is characterized in that in A material, each composition weight percent is:
Water glass and/or silicon sol 40-70%, organic synergist 19-40%, additive 20-70%;
In described water and/or water glass and/or silicon sol, water glass accounts for 50-100%, and described organic synergist is one or both the combination of epoxy resin or acrylic resin/emulsion; One or more the combination of described additive in toughener, tensio-active agent, fire retardant, rust-preventive agent or thinner; In B material, each composition weight percent is:
The black material 30-40% of foamed glue 50-60% synergistic agent 4.5-16%;
In described black material, also comprise 0-30% blocked polyisocyanate; Described synergistic agent is water glass curing agent, the expansible black lead through removing water treatment or the thinner that does not contain organic ester.
Described compound sizing material, is characterized in that
A expects (weight part):
Water glass 40-100
Epoxy resin or acrylic resin 30-50
Tensio-active agent 1-6
Silica powder and/or 80-180 order expansible black lead 15-80
Thinner and/or flow agent 0-20
B expects (weight part):
Foamed glue 50-100
The black material 25-80 of urethane
Blocked polyisocyanate and/or encapsulant 0-30.
Described compound sizing material, is characterized in that,
A expects (weight part):
Water glass 40-100
Epoxy resin 15-20
Acrylic resin/emulsion 15-20
Tensio-active agent 1-6
Silica powder and/or expansible black lead 5-50
Thinner 0-20
B expects (weight part):
Foamed glue 50-100
The black material 25-80 of urethane
Stopper or thinner or polyamide resin 0-20.
Described compound sizing material, is characterized in that described additive is one or more the combination in tackifier, fire retardant, rust-preventive agent;
A material is (weight part):
Water glass and/silicon sol 100
Sodium sulfate anhydrous.min(99) 10-35
Silica powder and/or expansible black lead 0-50
Rust-preventive agent 0-8
Thinner or polyvalent alcohol 0-20.
Described compound sizing material, is characterized in that, described toughener and fire retardant at least comprise 80-180 order expansible black lead;
A expects (weight part): water 20-30 acrylic resin 30-50 expansible black lead 5-30 silica powder 0-30 ammonium polyphosphate 4-8
Rust-preventive agent 0.5-5 tensio-active agent 0.5-5
B expects (weight part): black material 30-40 foamed glue 40-60
A:B is 1:1.
Described compound sizing material, it is characterized in that described organic synergist comprises waste and old plastic through regeneration glue and/or the epoxidation propylene acid modification waste oil pulverized and organic solvent dissolution dispersion makes, its content occupies machine synergist total amount (weight) 30-100%.
The making method of described compound sizing material, it is characterized in that described B material is to react and reach after terminal with polyester polyol and/or polyether glycol at excessive polyisocyanates, cool to lower than after 60 ℃, in protection atmosphere with under stirring, add polyisocyanates, in blend glue stuff, do not add catalyzer, with organic ester content, lower than 5% thinner, adjust viscosity, add if desired appropriate synergistic agent, fully mix; Or directly black material is fully mixed with foamed glue at lower than 40 ℃, add if desired synergistic agent.
Compound sizing material described in a kind of utilization is made light flame-retardant insulation blocks, it is characterized in that, described sizing material blade coating maybe can form on the mould of closed cavity at two steel plates, and light material is filled in the cavity in sizing material layer or directly at the surface layer of lightweight plate, scrapes and smear described sizing material layer.
Described polyisocyanates can be in different fluorine diketone vulcabond (IPDI), hexamethylene-diisocyanate (HDI) diphenylmethanediisocyanate (MDI), polymeric MDI, tolylene diisocyanate (TDI) and pentamethylene vulcabond, dicyclohexyl methane diisocyanate, two phenyl diisocyanate, phenyl diisocyanate one or more combination, can be that polyurethane foam is thick MDI or polymeric MDI with black material, fat or alicyclic cyanate ester react gentleer with water composition, are suitable for some complicated slow work and high temperature occasion; Organic synergist also can be vinylchlorid-vinylidene chloride emulsion copolymer, terpolycyantoamino-formaldehyde resin, resol, gelatin etc.; Dispersion agent in described additive is silicates, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, trisodium phosphate; Tensio-active agent is Sodium dodecylbenzene sulfonate, AMONYL 380LC, Pluronic F68, TX-10, AES, OP-10, one or more in K12; Coupling agent is silane coupling agent; Thickening material is ether of cellulose and derivative, starch and derivative thereof, sodium alginate, guar gum, soybean glue; Anti-sludging agent is wilkinite, attapulgite, pure aluminium silicate, diatomite; It is phosphoric acid salt that rust-preventive agent can be antirust, borate, sulfonate, nitrite, aluminium powder, zinc powder, heterogeneous ring compound, phytic acid and derivative thereof and composite antirust agent rust proof paint; Fire retardant is expansible black lead, ammonium polyphosphate, zinc borate; Tackifier can be Gum Rosin, rosin compound water, rosin water-based terpenes Tackified emulsion, paracril liquid; Toughener can be breeze, metal powder, such as silica powder, and titanium dioxide, talcum powder, Sodium sulfate anhydrous.min(99), mica powder, perlite powder, tourmaline powder, fine silica powder, fine titanium dioxide powder, zinc powder, aluminium powder, iron powder, rubber powder or glue, aluminium hydroxide, magnesium hydroxide, Magnesium Silicate q-agent, calcium carbonate, magnesium oxide, aluminum oxide, zinc oxide, ferric oxide, zirconium white, cement, flyash, Attapulgite, one or more combination in kaolin.
Preparation A material can simply and economically first add water, water glass and/or silicon sol in container, then adds liquid composition, and limit edged stirs, and finally adds other component, is stirred well to evenly.In solid state component, tensio-active agent and not diffluent composition can first add.Before adding with the bad resin of water, water glass and/or silicon sol consistency or emulsion, can first add dispersion agent and/or tensio-active agent, be aided with if desired high speed shear and disperse, grind homogenate, heating (40-80 ℃) filtration treatment to form fine even plasmid.Scale production or can utilize colloidal mill while preparing high-quality sizing material or reactor preparation.B material can be when preparing foamed glue, in polyethers or polyester polyol except after water for cooling under nitrogen protection by being metered into, limit edged stirs, after making react-the excessive degree of NCO group is 5-25%, preferably 8-20%(needs with reference to concrete formula ratio).Also can be after performed polymer makes reaction terminating temperature of reaction kettle to be brought down below 60 ℃ under nitrogen protection, add thick MDI is disposable, after stirring, emit and be B material.A small amount of use also can dissolve lower than 40 ℃ in proportion with foamed glue and black material.During mixing, reduce dimer and trimerical generation that temperature can suppress polyisocyanates, to keep enough-NCO group, extend staging life.Certainly, also can at the construction field (site) the various raw materials that form A material and B material be added respectively in proportion and be stirred.Water glass curing agent can add in use, adds in B material after also can dewatering before use.Add if desired stopper or stablizer to extend shelf-time and hybrid reaction time.In B material, can also add end encapsulant and/or blocked polyisocyanate, especially the lower blocked polyisocyanate of deblocking temperature, make sizing material have the initial bonding strength that meets processing requirement, unlikely reaction is too fast again, and the product after applying glue can complete final curing reaction in conventional hot pressing process.Generally A material is packed respectively with B material, during use, concoct, in particular cases, can by performed polymer and polyisocyanates especially fat or alicyclic ring polyisocyanates-NCO group is with after 120 ℃ of following cold sealing agent sealings, A material and B material are merged into a single whole, baking after using.Can also adopt the additive adjustment A material such as thinner levelling agent or B material viscosity to adapt to the mixed construction of high pressure spray.
Water and/or water glass and/or silicon sol are as the main body composition as necessary, can reduce production costs, make raw material more press close to environmental protection, especially water glass and/or silicon sol can also strengthen the resistance to elevated temperatures of sizing material, give sizing material flame retardant resistance, and can regulate compound viscosity to improve adhesive power, can promote crosslinking reaction simultaneously, and intert the complicated and rational space structure of chimeric formations with other component, thereby produce some beyond thought effects.But its addition is unsuitable excessive, otherwise to the organic composition of glue-line microbubble structure and composite gum and structure generation disadvantageous effect, can cause bonding strength to decline, fragility increases, curing bad, the phenomenons such as thermal insulation variation; Addition is too small, is not enough to reduce costs, and is unfavorable for adjusting easy and property and the rheological of sizing material, is also unfavorable for fast setting, is more unfavorable for the formation of sizing material anti-flaming thermal-insulation, weather-proof inhibition, high sticky tough and tensile over-all properties structure.In some combinations, add water and can reach water glass or the close effect of silicon sol, but the acquisition of its anti-flaming thermal-insulation performance need to be added certain fire retardant; The reacting of water and/or water glass and/or silicon sol and B material in A material, may be in water and polyisocyanates-NCO radical reaction carboxylamine decomposition generation amine and the carbonic acid gas of generation.Amine has chain extension to act under excess isocyanate existence, and further reaction generates urea, and resultant of reaction carbonic acid gas rises and helps foaming effect to form equally distributed high rate of closed hole microvesicle.Under normal temperature 10-60 minute starts gelling, the about 0.5-4 hour of surface drying, and 4-12 hour is substantially curing.Reach maximum strength, generally need two to three day left and right time.Heating can be shortened set time greatly.For the impact of surface drying and set time, water glass is the fastest, and silicon sol takes second place, and water is the slowest, and this may be the impact of Ph value.In B material-and the increase of NCO%, such as suitably reducing the ratio of foamed glue/black material, curing reaction also will ease up to some extent.
The proportional quantity of organic synergist is excessive, and cost is high, and for part oleoresin, VOC also can increase, and the increase of cohesive strength is not directly proportional, and sometimes even has too much of a good thing.Moreover, excessive interpolation is also unfavorable for the acquisition of the over-all propertieies such as sizing material cost performance and anti-flaming thermal-insulation.For the adhering object of having relatively high expectations and construction environment and appropriate being added with of some combination, help the raising of cohesive strength and mechanical property.Not very few add or do not add seem to be more of value to environmental protection and fire-retardant.
Additive has auxiliary synergism, its selection is determined according to material combination, the adjustable sizing material thixotropy of appropriate interpolation, increase cohesive strength and physical strength and flame retardant effect, also can reduce interfacial tension, improve the intermiscibility of different properties different dosage form raw material, prevent flocculation and sedimentation, and can make sizing material there are more special performances.Wherein, silica powder especially 800 orders is above so that micro mist can obviously improve sizing material cohesive strength, increase sizing material hardness, and low price; 80-180 order expansible black lead can not only increase cohesive strength, also can produce good anti-flaming thermal-insulation effect under high temperature, lower with respect to the powder cost of high order number.Sodium sulfate anhydrous.min(99) has obvious thickening tackify and synergy to water glass.But additive add-on is excessive, may make the bad change of properties of rubber, reduce cohesive strength, increase sizing material fragility; And add very few often not having, should there is effect.A small amount of polyvalent alcohol or polyol can increase the gas release of sizing material, and this is suitable for rough plate face bonding, in addition, also may extend set time sometimes, increases sizing material initial bonding strength and toughness
.because organic ester can accelerate water glass, solidify, and cured article has collapsibility, thinner does not preferably add or adds less the organic esters such as ethyl acetate.
In the present invention-and NCO group can be remaining in performed polymer, can be also in performed polymer, to add polyisocyanates ,-NCO% surpasses 25% high cost not only, also not environmental protection, and soft section of deficiency in block structure, sizing material fragility toughness bigger than normal is inadequate, and over-all properties is not good; But lower than 8%, especially lower than 5%, sizing material cohesive strength is not enough, and curing fast, physical strength is inadequate.Blocked polyisocyanates that can fusion 10-30% in polyisocyanates, also can add the appropriate stoppers such as Resorcinol.The water glass curing agents such as polymer phosphate aluminium, Sodium Silicofluoride, silicon phosphate can promote water glass synchronously to solidify, and strengthen cohesive strength, can add separately, if mix B material, must fully toast before and dewater, and are preferably in use and a few days ago add.Before use, stir, otherwise the stability of possibility impact effect.It adds excessive, and water glass solidifies too fast, also affects uniformity and the rheological of sizing material, even makes properties of rubber variation.Do not have condition not add.Sometimes in B material, add the not hydroxyl of 3-10% and the low molecule pa resin of carboxyl to contribute to further to improve the toughness of sizing material, but water content need be controlled in ammonia ester level, and use as early as possible.While preferably mixing before use, add.
Positively effect of the present invention:
Sizing material of the present invention is meeting under basic cohesive strength prerequisite, utilizes water and/or water glass and/or silicon sol and part inorganic additives to make active principle, can greatly reduce production costs; In test, find that in foamed glue, adding black material can extend the seasoning phase, avoid or reduce the loss causing because solidifying, also can stop or reduce and add excessively the negative effect that acidity or acyl chloride stablizer and methylene dichloride thinner are brought, indirectly reduce sizing material cost; The cost of sizing material of the present invention is 1/3rd left and right of commercially available epoxy resin glue, and more commercially available foamed glue is cheap approximately 1/4th to 1/5th even more, thereby inexpensive.
The composite mesh structure that the appropriate polyureas that enough active groups in B material and the water cross-linking reaction in A material (comprising water glass and silicon sol) form and other effective constituent crosslinking reaction form, can make sizing material there is good initial bonding strength and sticking power, the large multipotency of cohesive strength meets or exceeds the requirement of building adhesive 0.5mPa, normal temperature solidified, surface drying time mostly between 30 minutes to 120 minutes, strong and unyielding having concurrently.
Owing to adding water glass and/or silicon sol and/or other anti-flaming thermal-insulation additive itself in a large number with good fire retardation, in addition in foamed glue or polyisocyanates, there is enough-NCO group to react and produce carbon dioxide with amount of water in A material and other active ingredient, compound sizing material interts and moves in an attached ancient piece of jade, round, flat and with a hole in its centre and dressing solidification process crosslinked, and whole adhesive layer can form independently microbubble structure of a large amount of sealings.In addition, the additives such as water glass and/or silicon sol, Sodium sulfate anhydrous.min(99) or expansible black lead are embedded in glued membrane and micella after solidifying, and melt phase change or expansion also can occur under high temperature, can form complex protection barrier, thereby sizing material have anti-flaming thermal-insulation effect.
That water glass and silicon sol have itself is bonding, dispersion, emulsification, anti-settling and corrosion inhibition, also have and catch and the effect that neutralizes acidity and some latent acidic corrosive media, can prevent in sizing material the corrosion of metal such as acidic component counter plate, anchor suspension member and keel in acidity or acyl chloride additive and phenol formaldehyde foam.
The especially combination of water glass and/or silicon sol of water composition in the NCO group of compound sizing material mesopodium amount and appropriate performed polymer and A material, be aided with the effect of additive and synergistic agent, plural gel structure is interted to interweave, in addition the film forming of chimeric and organic gum material of toughener is coated, and the composite structure after solidifying also has good physical strength and waterproof and weather resistance.In addition, because a large amount of water compositions substitute oiliness organic composition, can reduce the consumption of organic sizing material, and not containing formaldehyde, and the glue that can utilize waste plastic and rubber to produce, thereby also have certain environment protection significance.
embodiment
During the embodiment of the present invention is raw materials used, foamed glue is mainly the polyurethane foam glue that Chongqing region door factory is generally used, the about 3%--5% of-NCO group content, and Chongqing Ba Nan binding agent factory produces.Epoxy resin is E-44(6101), Feicheng De Yuan Chemical Co., Ltd. produces.Polyamide resin (650 low molecule), Zhao Tan chemical plant, Xiangtan, Hunan Province city produces.Black material is polyurethane foam component (polymeric MDI, NCO content 28-32%), water glass (modulus 2.6-2.9, solid content 30--40%), acrylic resin, ACRYLIC EMULSION and other industrial chemicals are purchased from Chongqing Shi Pingqiao Chemical market, silica powder 800-1250 order wherein, expansible black lead 80 orders.Test wooden stick diameter 25mm used, long 225mm; Large screw and long spiro nail are round end, and diameter is respectively 15mm, 12mm, and screw overall length is respectively 87mm, 93mm, and after ailhead end face is all used flat file file finishing, gluing is bonding.Wooden stick is bonded on the vertical wall of the can (spraying paint) of being made by 1.2mm steel plate, large screw is bonded on the vertical wall with the plank of the Yang Song wood made one-tenth of surface smoothing, wooden stick or large screw axial are all vertical with wall, and long spiro nail is bonded on 20mm*30mm*100mm and the wooden unit same quality of plank; The thick 0.3-0.5mm of iron block, the band paint of specification 40mm*105mm, gluing height 40mm, is bonded on the wide region of the can top 40mm of paint film, and iron block is parallel to the ground.After gluing dry 24-48 hour (except part heated baking, most Air drying).During test, to fill the mineral water bottle of tap water, serve as counterweight, 580 grams every bottle, on bottleneck, fasten and draw nylon ferrule, during many bottles of suspensions, with a rope, run through a plurality of lassos commanders.Mineral water bottle is suspended on wooden stick, large screw or iron block away from the other end of bonding end face, intermittently cumulative, until adhesive linkage destroys, record carries bottle amount; On long bolt, fasten nylon rope, keep screw rod vertically downward, nylon rope with pass through the rope of set rope sling on bottleneck and bind, make mineral water bottle liftoff, increase progressively at every turn, until come unstuck, drop, record transfusion bottle amount; Not falling row more equal 30 seconds raises the price.3--5 repetition established in each processing, and rejecting abnormalities sample, averages.Bonding strength is calculated with bound weight in average, only for referencial use.
Comparative example 1
Foamed glue
Can--large screw (Φ 15 L67.5) carries 3 bottles of <4 bottles of bottle amount >
Can--wooden stick (Φ 25 L225) carries bottle amount >4 bottle <5 bottle
Can-iron block (40*40*105) carries bottle amount >6 bottle <7 bottle
Wooden unit--long spiro nail transfusion bottle amount >15 bottle <16 bottle bonding strength (mPa) 0.78
Comparative example 2
Water glass 2 foamed glues 2
Plank--large screw carries bottle amount >2 bottle <3 bottle
Wooden unit--long spiro nail transfusion bottle amount >8 bottle <9 bottle bonding strength (mPa) 0.45
Comparative example 3.1
Epoxy resin 10 T-31 2
Plank--large screw carries bottle amount >3.5 bottle <4.5 bottle
Wooden unit--long spiro nail transfusion bottle amount >11 bottle <12 bottle bonding strength (mPa) 0.58
Comparative example 3.2
Epoxy resin 10 polyamide resins (650) 10
Wooden frame---large screw carries bottle amount .>7 bottle <7.5 bottle
Wooden unit--long spiro nail transfusion bottle amount >23 bottle <24 bottle bonding strength (mPa) 1.18
Comparative example 4
Black material 20 foamed glues 20 of acrylic resin 40
Wooden frame---large screw carries bottle amount >3 bottle <4 bottle
Wooden unit--long spiro nail transfusion bottle amount >10 bottle <11 bottle bonding strength (mPa) 0.51
Embodiment 1
A material: 2 grams, 40 grams of zinc oxide of 10 grams of silica powders of 30 grams of re-dispersible glue powders of 100 grams of acrylic resins of water glass
B material: 91 grams of 91 grams of foamed glues of black material
Water glass is added in container, drop into successively silica powder, zinc oxide and re-dispersible glue powder, stir a moment, finally add acrylic resin while stirring until evenly, be A material, encapsulate standby.Black material and foamed glue are pressed to formula balanced mix, stir and be B material.A material, B material are deposited respectively, during use, A material and B material are poured into and are stirred and can use by formula 1:1, preferably in a quarter, are finished.Be below that large screw level is bonded on vertical plank, bearing capacity when screw rod end hangs bottled water carries bottle amount.
Plank---large screw carries bottle amount >3.5 bottle <4.5 bottle
Embodiment 2
A material: 2 grams of tributyl phosphates of 0.5 gram of barium mahogany sulfonate of 0.5 gram of zinc oxide of 0.5 gram of Sodium dodecylbenzene sulfonate of 0.5 gram of trisodium phosphate of 2 grams of tripoly phosphate sodium STPPs of 18 grams of titanium dioxides of 10 grams of talcum powder of 10 grams of epoxy resin of 50 grams of acrylic resins of water glass a little
B material: 62.7 grams of 31.3 grams of foamed glues of black material
First water glass is added in container, drop into successively tripoly phosphate sodium STPP, trisodium phosphate, Sodium dodecylbenzene sulfonate, defoamer, zinc oxide, barium mahogany sulfonate, talcum powder, titanium dioxide, epoxy resin, stir a moment, finally add acrylic resin while stirring until evenly, be A material.Black material is mixed in foamed glue, be stirred well to and be evenly B material.During use, amount is as required poured A material and B material in agitation vat into by 1:1, high-speed stirring 30 seconds to 1 minute.Be ordinary method.Following examples dissolve class of operation seemingly, and A material, repeats no more all to dissolve calculating completely with the proportioning of B material.
Plank---large screw carries bottle amount >3 bottle <4 bottle
Embodiment 3
A material: 0.3 gram of 0.5 gram of Sodium dodecylbenzene sulfonate of 20 grams of Sodium hexametaphosphate 99s of 20 grams of wollastonite powder of 50 grams of epoxy resin of water glass
B material: 0.9 gram of 54 grams of Sodium Silicofluoride of 36 grams of foamed glues of black material
Plank---large screw carries bottle amount >.4.5 bottle <5.5 bottle
Embodiment 4
A material: 3 grams of 20 grams of Sodium Selenites of 20 grams of silica powders of 10 grams of acrylic resins of 10 grams of re-dispersible glue powders of 100 grams of Synolac of water glass
B material: 84 grams of 56 grams of foamed glues of black material
Between dry epoch, through 60-90 ℃, toasting 2 hours planks---large screw carries a bottle amount >3 bottle <4.5 bottle
Embodiment 5
A material: 0.5 gram, 0.5 gram of zinc oxide of 20 grams of tripoly phosphate sodium STPPs of 5 grams of silica powders of 5 grams of re-dispersible glue powders of 20 grams of Synolac of 5 grams of acrylic resins of 11 grams of Gum Rosin liquid of 55 grams of silicon sol of water glass
B material: 51 grams of 71 grams of foamed glues of black material
Plank---large screw carries bottle amount >3 bottle <4 bottle
Embodiment 6
A material: 20 grams of 40 grams of silica powders of 40 grams of acrylic resins of water glass
B material: 25 grams of 25 grams of foamed glues of black material
Carry bottle amount plank---large screw >3 bottle <4 bottle
Embodiment 7
A material: 5 grams of 50 grams of amylans of 50 grams of urine aldehyde glue of silicon sol
B material: 50 grams of 50 grams of foamed glues of black material
Between dry epoch, through 60-90 ℃, toasting 2 hours planks--large screw carries a bottle amount >2.5 bottle <3.5 bottle
Embodiment 8
A material: 0.2 gram of 44 grams of tackifier A of 11 grams of acrylic resins of 10 grams of re-dispersible glue powders of 100 grams of Synolac of water glass
B material: 120 grams of 45 grams of foamed glues of black material
Plank---large screw carries bottle amount >3 bottle <4 bottle
Embodiment 9
A material: 20 grams of 40 grams of silica powders of 40 grams of acrylic resins of water glass
B material: 50 grams of 50 grams of foamed glues of black material
Plank---large screw carries bottle amount >6 bottle <7 bottle
Embodiment 10
A material: 2.5 grams of methyl-silicone oils of 2.5 grams of trisodium phosphates of 40 grams of Sodium dodecylbenzene sulfonatees of 6 grams of silica powders of 2 grams of wilkinites of 1 gram of zinc oxide of 2.5 grams of tripoly phosphate sodium STPPs of 10 grams of re-dispersible glue powders of 10 grams of Synolac of 20 grams of pure-acrylic emulsions of 100 grams of epoxy resin of water glass a little
B material: 119 grams of 99 grams of foamed glues of black material
Plank--large screw carries bottle amount >3 bottle <4.5 bottle
Embodiment 11
A material: 3 grams of 3 grams of TriMethylolPropane(TMP)s of 10 grams of zinc oxide of 10 grams of talcum powder of 3 grams of silica powders of 1.5 grams of Sodium Nitrites of 3 grams of tripoly phosphate sodium STPPs of 7 grams of aluminium hydrate powders of 10 grams of acrylic resins of 100 grams of re-dispersible glue powders of water glass
B material: 50 grams of 120 grams of foamed glues of black material
Between dry epoch, through 60-90 ℃, toast approximately 4 hours
Can---iron block (40*40*105) carries bottle amount >14 bottle (distortion of bending)
Embodiment 12
A material: 1 gram of 1 gram of iron oxide red of 18 grams of aluminium hydroxides of 19 grams of acrylic resins of 90 grams of re-dispersible glue powders of 100 grams of silicon sol of water glass (neutrality), 10 grams of zinc oxide of 10 grams of talcum powder of 3 grams of tripoly phosphate sodium STPP .5 gram silica powder
B material: 100 grams of 90 grams of foamed glues of black material
Between dry epoch, through 60-90 ℃, toast approximately 4 hours
Can---iron block (40*40*105) carries bottle amount >14 bottle (distortion of bending)
Embodiment 13
A material: 1 gram of 3 grams of liquid butadiene-acrylonitrile rubber of 1.5 grams of Sodium Nitrites of 1.5 grams of tripoly phosphate sodium STPPs of 6 grams of aluminium hydrate powders of 10 grams of acrylic resins of 100 grams of re-dispersible glue powders of water glass
B material: 40 grams of 90 grams of foamed glues of black material
Between dry epoch, through 60-90 ℃, toast approximately 4 hours
Can---iron block (40*40*105) carries bottle amount >11 bottle (distortion of bending)
Embodiment 14
A material: 8 grams of 3 grams of acrylic resins of 1.5 grams of Sodium Nitrites of 1.5 grams of tripoly phosphate sodium STPPs of 10 grams of aluminium hydrate powders of 77 grams of re-dispersible glue powders of 100 grams of silicon sol of water glass
B material: 0.5 gram of 200 grams of (-NCO% is 12%) silane coupling agent of polyether-type foamed glue
Between dry epoch, through 60-90 ℃, toast approximately 4 hours
Can---iron block (40*40*105) carries 7 bottles of <8 bottles of bottle amount (distortion of bending)
Embodiment 15
A material: 40 grams of 20 grams of silica powders of 20 grams of re-dispersible glue powders of 100 grams of acrylic resins of water glass
B material: 90 grams of 10 grams of foamed glues of black material 80 dead front type vulcabond (low temperature deblocking)
Between dry epoch, through 80-120 ℃, toasting approximately 4 hours cans----wooden stick (Φ 25 L225) carries a bottle amount >4 bottle <5 bottle
Embodiment 16
A material: 1 gram of 40 grams of tripoly phosphate sodium STPP of 30 grams of aldehyde ketone resins of 100 grams of acrylic resins of silicon sol, 10 grams of silica powders of 5 grams of (being dissolved in acrylic resin) re-dispersible glue powders
1 gram, zinc oxide
B material: 98 grams of 30 grams of foamed glues of 98 grams of anhydrous sodium sodium pyrosulfates of black material
Between dry epoch, through 80-120 ℃, toast 2 hours
Can----wooden stick (Φ 25 L225) carries bottle amount >4 bottle <5 bottle
Embodiment 17
A material: 40 grams of 40 grams of silica powders of 100 grams of acrylic resins of water glass
B material: 90 grams of 10 grams of foamed glues of 90 grams of dead front type vulcabond of black material (low temperature deblocking)
Between dry epoch, through 80-120 ℃, toasting approximately 4 hours cans----wooden stick (Φ 25 L225) carries a bottle amount >4 bottle <5 bottle
Embodiment 18
A material: 0.5 gram, 0.5 gram of zinc oxide of 0.5 gram of Sodium dodecylbenzene sulfonate of 0.5 gram of trisodium phosphate of 20 grams of tripoly phosphate sodium STPPs of 10 grams of silica powders of 10 grams of epoxy resin of 50 grams of acrylic resins of water glass
B material: 23 grams of 23 grams of foamed glues of black material
Carry can--wooden stick bottle amount >4.5 bottle <5 bottle
Embodiment 19
A material: 20 grams of 0.5 gram of silica powders of 0.5 gram of zinc oxide of 5 grams of tripoly phosphate sodium STPPs of 5 grams of re-dispersible glue powders of 15 grams of Synolac of 3 grams of acrylic resins of 12 grams of water-soluble rosin resins of 58 grams of silicon sol of water glass (neutrality)
B material: 71 grams of 48 grams of foamed glues of black material
Can--wooden stick (Φ 25 L225) carries bottle amount >4 bottle <5 bottle
Embodiment 20
A material: 23 grams of alkaline stabilisers of 40 gram of 191 resin of 40 grams of mica powders of 100 grams of acrylic resins of water glass a little
B material: 78 grams of 78 grams of foamed glues of black material
Can---wooden stick (Φ 25 L225) carries bottle amount >6 bottle <7 bottle
Embodiment 21
A material: 5 grams of 3 grams of wilkinites of 20 grams of Sodium Nitrites of 30 grams of talcum powder of 3 grams of silica powders of 1 gram of magnesium hydroxide of 1 gram of zinc oxide of 5 grams of tripoly phosphate sodium STPPs of 10 grams of re-dispersible glue powders of 10 grams of acrylic resins of 100 grams of Synolac of water glass
5 grams of 3 grams of rosin tackify liquid of aluminium silicate wool
B material: 120 grams of 60 grams of foamed glues of black material
Can--wooden stick (Φ 25 L225) carries bottle amount >3 bottle <4 bottle
Embodiment 22
A material: 0.2 gram of 20 grams of antiaging agent of 40 grams of silica powders of 40 grams of epoxy resin of water glass
B material: 1 gram of 65 grams of polyamide resin of 35 grams of foamed glues of black material
Plank---large screw carries bottle amount >4 bottle <5.5 bottle
Wooden unit--long spiro nail transfusion bottle amount >24 bottle <25 bottle bonding strength (mPa) 1.23
Embodiment 23
A material: 0.5 gram of 0.5 gram of AES of water 28 grams of acrylic resins, 40 grams of expansible black leads, 5 grams of rust-preventive agent of 20 grams of ammonium polyphosphates (SL360) 1 Sodium dodecylbenzene sulfonate
B material: 62 grams of 31 grams of foamed glues of black material
Plank---large screw carries bottle amount >3 bottle <4 bottle
Wooden unit--long spiro nail transfusion bottle amount >12 bottle <13 bottle bonding strength (mPa) 0.63
Embodiment 24
A material: 30 grams of 40 grams of silica powders of 40 grams of acrylic resins of water glass
B material: 62 grams of 31 grams of foamed glues of black material
Plank-large screw carries bottle amount >4 bottle <5 bottle
Wooden unit--long spiro nail transfusion bottle amount >25 bottle <26 bottle bonding strength (mPa) 1.28
With the present embodiment sizing material head to head bonding 6 pairs of long spiro nails and Screw (hex hd, length of side 10mm, the long 40mm of screw rod), baking at 60-90 ℃, after 6 hours, get 3 opposed freezer compartment of refrigerator, after 10 freeze-thaw cycle, by the aforementioned bottle method of hanging, survey cohesive strength (average 2.5mPa), each test specimen result and 3 pairs of results in room temperature environment are relatively without significant difference.
Embodiment 25
A material: 16 grams of 2 grams of expansible black leads of 1 gram of AES of 1 gram of Sodium dodecylbenzene sulfonate of 1 gram of trisodium phosphate of 40 grams of tripoly phosphate sodium STPPs of 20 grams of silica powders of 20 grams of organosilicon crylic acid latexs of 70 grams of epoxy resin of water
B material: 103 grams of 52 grams of foamed glues of black material
Plank---large screw carries bottle amount 3> bottle <4 bottle
Wooden unit--long spiro nail transfusion bottle amount >13 bottle <14 bottle bonding strength (mPa) 0.68
Embodiment 26
A material: 40 grams of 20 grams of silica powders of 20 grams of acrylic resins of 100 grams of epoxy resin of water glass
0.5 gram of 2 grams of AES of 1 gram of Sodium dodecylbenzene sulfonate of 1 gram of trisodium phosphate of 1 gram of zinc oxide of tripoly phosphate sodium STPP
B material: 18 grams of 95 grams of expansible black leads of 60 grams of foamed glues of black material
Plank---large screw carries bottle amount >4 bottle <5 bottle
Wooden unit--long spiro nail transfusion bottle amount >20 bottle <21 bottle bonding strength (mPa) 1.03
Embodiment 27
A material: 0.5 gram of 2 grams of AES of 1 gram of Sodium dodecylbenzene sulfonate of 1 gram of trisodium phosphate of 1 gram of zinc oxide of 20 grams of tripoly phosphate sodium STPPs of 40 grams of expansible black leads of 20 grams of silica powders of 20 grams of acrylic resins of 100 grams of epoxy resin of water glass
B material: 116 grams of 60 grams of foamed glues of black material
Plank---large screw carries bottle amount >4 bottle <5. bottle
Wooden unit--long spiro nail transfusion bottle amount >18 bottle <19 bottle bonding strength (mPa) 0.93
Embodiment 28
A material: 3 grams of 1 gram of AES of 1 gram of Sodium dodecylbenzene sulfonate of 1 gram of zinc oxide of 40 grams of tripoly phosphate sodium STPPs of 20 grams of silica powders of 20 grams of acrylic resins of 100 grams of epoxy resin of water glass
B material: 35 grams of 100 grams of expansible black leads of 55 grams of foamed glues of black material
Plank---large screw carries bottle amount >5 bottle <6 bottle
Wooden unit--long spiro nail transfusion bottle amount >26 bottle <27 bottle bonding strength (mPa) 1.33
Embodiment 29
Reclaimed rubber is produced:
1.5 grams of 1.5 grams of colophonium powders of 1.5 grams of useless PVC powders of 5 grams of useless polyphenyl foams of No. 200 solvent oils
0.3 gram of Zinic stearas 0.3--0.5 of Sodium dodecylbenzene sulfonate gram AMONYL 380LC 0.3--0.5 gram
40 grams of 0.5 gram of water glass of 5 grams of epoxy soybean oils of wilkinite
First useless polyphenyl foam and the useless PVC powder pulverized are dissolved in to solvent oil No. 200, then add water glass, colophonium powder and, Sodium dodecylbenzene sulfonate, Zinic stearas, AMONYL 380LC and wilkinite, in water-bath during 80-100 ℃ of stirring heating 1.
A material: get 0.5 gram, 0.5 gram of zinc oxide of 0.5 gram of Sodium dodecylbenzene sulfonate of 0.5 gram of trisodium phosphate of 20 grams of tripoly phosphate sodium STPPs of 10 grams of silica powders of 10 grams of epoxy resin of 50 grams of acrylic resins of 92 grams of water glass of reclaimed rubber
B material: 10 grams of 110 grams of Sodium Silicofluorides of 66 grams of foamed glues of black material
Plank---large screw carries bottle amount >3 bottle <3.5 bottle (ailhead band portion rubber)
Wooden unit--long spiro nail transfusion bottle amount >11 bottle <12 bottle bonding strength (mPa) 0.58
Embodiment 30
Reclaimed rubber is produced:
First useless polyphenyl foam and waste polyethylene, polyvinyl chloride powder and the recyclable rubber pulverized are dissolved in the solvent being comprised of solvent oil and dimethylbenzene by 2:1:1:0.5, add again the tensio-active agents such as the dispersion agents such as alkali lye, colophonium powder and wilkinite and benzene sulfonic acid sodium salt, Zinic stearas, AMONYL 380LC and a small amount of silane coupling agent, in water-bath, 50-80 ℃ of stirring heating is 30 minutes to 2 hours, produce glue, be routine techniques, get
50 grams of reclaimed rubbers
80 grams of water glass
60 grams of planks of black material---large screw
60 grams of >2 bottle <3 bottles of foamed glue (ailhead band glue)
Wooden unit--long spiro nail transfusion bottle amount >10 bottle <11 bottle bonding strength (mPa) 0.53
Embodiment 31
A material: 1 gram, 1 gram of zinc oxide of 20 grams of flyash of 20 grams of epoxy resin of 100 grams of benzene emulsions of water glass (800-100 order), 1 gram of Sodium dodecylbenzene sulfonate of 1 gram of trisodium phosphate of 20 grams of tripoly phosphate sodium STPPs of 20 grams of silica powder
B material: 18.5 grams of 100 grams of Sodium Silicofluorides of 66 grams of foamed glues of black material
Wooden unit-large screw carries bottle amount >3 bottle <4 bottle
Wooden unit--long spiro nail transfusion bottle amount >10 bottle <11 bottle bonding strength (mPa) 0.53
Embodiment 32
A material: 2 grams, 10 grams of zinc oxide of 10 grams of silica powders of water glass
B material: 14 grams of 8 grams of foamed glues of black material
During mixing, separately add 0.5 gram of Sodium Silicofluoride
Wooden unit-large screw carries bottle amount >3 bottle <3.5 bottle
Wooden unit--long spiro nail transfusion bottle amount >10 bottle <11 bottle bonding strength (mPa) 0.53
Embodiment 33
A material: 20 grams of water glass
B material: 10 grams of 10 grams of foamed glues of black material
Wooden unit-large screw carries bottle amount >2.5 bottle <3.5 bottle
Wooden unit--long spiro nail transfusion bottle amount >10 bottle <11 bottle bonding strength (mPa) 0.53
Embodiment 34
A material: 2 grams of 10 grams of Sodium sulfate anhydrous.min(99) of water glass
B material: 5 grams of 7 grams of foamed glues of black material
Wooden unit-large screw carries bottle amount >3 bottle <4 bottle
Wooden unit--long spiro nail transfusion bottle amount >13 bottle <14 bottle bonding strength (mPa) 0.68
Embodiment 35
A material: 1 gram of 12.5 grams of tetramethylolmethane of 50 grams of Sodium sulfate anhydrous.min(99) of water glass
B material: 42.3 grams of 21.2 grams of foamed glues of black material
Wooden unit--long spiro nail transfusion bottle amount >13 bottle <14 bottle bonding strength (mPa) 0.68
Embodiment 36
A material: 4 grams of 5 grams of Sodium sulfate anhydrous.min(99) of 20 grams of expansible black leads of water glass
B material: 19.3 grams of 9.7 grams of foamed glues of black material
Wooden unit--long spiro nail transfusion bottle amount >11 bottle <12 bottle bonding strength (mPa) 0.58
Embodiment 37
A material: 10 grams of rust-preventive agent 2 of 20 grams of Sodium sulfate anhydrous.min(99) of water glass
B material: 15 grams of 15 grams of foamed glues of black material
Wooden unit--long spiro nail transfusion bottle amount >11 bottle <12 bottle bonding strength (mPa) 0.58
Embodiment 38
A material: 10 grams of ethylene glycol 2 of 50 grams of Sodium sulfate anhydrous.min(99) of water glass
B material: 41.4 grams of 20.6 grams of foamed glues of black material
Wooden unit--long spiro nail transfusion bottle amount >10 bottle <11 bottle bonding strength (mPa) 0.53
Embodiment 39
A material: 12.5 grams of glycerol 2.5 of 50 grams of Sodium sulfate anhydrous.min(99) of water glass
B material: 43.4 grams of 21.7 grams of foamed glues of black material
Wooden unit--long spiro nail transfusion bottle amount >13 bottle <14 bottle bonding strength (mPa) 0.68
Embodiment 40
A material: 15 grams of glycerol of 50 grams of Sodium sulfate anhydrous.min(99) of water glass, 5 rust-preventive agent 1
B material: 46.7 grams of 23.3 grams of foamed glues of black material
Wooden unit--long spiro nail transfusion bottle amount >10 bottle <11 bottle bonding strength (mPa) 0.53
Embodiment 41
A material: 3 grams of 20 grams of pure aluminium silicate of 20 grams of Sodium sulfate anhydrous.min(99) of 100 grams of silica powders of water glass
B material: 4 grams of 8 grams of ammonium polyphosphates of 60 grams of expansible black leads of 30 grams of foamed glues of black material
Before adding B material, expansible black lead needs to dewater, ammonium polyphosphate can add in use, the slurry blade coating of making after stirring is on phenolic foam board surface, water proof fire retardant not only, also can stop the corrosion of acidic medium to metal decking or metal joist in phenol formaldehyde foam, can make heat insulating board, sandwich board, fire-resistant door core.
Embodiment 36
A material: 100 grams of water glass can disperse 20 grams of 20 grams of Sodium sulfate anhydrous.min(99) of 10 grams of silica powders of rubber powder
B material: 80 grams of 50 grams of foamed glues of black material
After being mixed well, A material and B material be coated in mould or metal decking; form the isolated protective layer that six faces surround, thickness 0.5-3mm, quantitatively injects to cavity the resol sent out that adds foamed glue and solidifying agent after surface drying; then matched moulds or upper and lower metal sheet is closed fixing, sends out after full and becames one.
Embodiment 36
Coating release agent in forming mould, then by compound rubber cement: the table material that stalk compound mixes by 1:1 is close to mould lay, rice husk or straw and high temperature resistant light skeletal and common fire-resistant binder or A:B press core material that 3-5:1 forms with common flame retardant glue material mix after cold pier or the moulding of Hot pier, the demoulding after curing molding.Certainly, also can be on the lightweight heat-proof building block forming containing rice husk or straw and high temperature resistant light skeletal and fire-resistant binder or foamed building block the direct above-mentioned rubber cement of blade coating.
From comparative example and embodiment, can find out, the obvious variation of cohesive strength after common foamed glue and water glass allotment, B material in the present invention and suitable quantity of water and/or water glass and/or silicon sol or while coordinating with water and/or water glass and/or silicon sol, organic synergist and/or additive simultaneously, its speed of response and physical strength are all improved significantly, more than cohesive strength can reach 0.5 mPa mostly, what have also surpasses foamed glue.With the effect of B material assembly, A material with low cost approaches or the high acrylic resin that exceeds the price, even can be comparable with epoxy resin glue.Sizing material of the present invention also has obvious fire retardation, from fire, certainly puts out.
The viscosity of sizing material of the present invention is water, silicon sol etc. and conventional organic thinner, flow agent adjustment as required; Also can be by the known stoppers such as Resorcinol, methyl ethyl ketoxime, acetone, butanone, sodium bisulfite or encapsulant reaction speed to adapt to different occasions and needs.Be used for repairing Pearl stone drying plate, chlorine oxygen magnesium central layer, timber, solidify and be difficult for peeling off after 3 days.Peel off by force and often cause central layer fragmentation or timber to tear.In embodiment, get at random 5 wooden stick terminations that are stained with different ingredients cull and be soaked in the plastic cup that fills tap water one week, during cleaning, have no softening and burst and separate, adhere to still firm.Get at random 5 plastic cup water fillings that are attached with the cured article of different ingredients and with extensive test paper, test pH value, neutrality or weakly alkaline after 24 hours.During test, get at random 3 kinds of different ingredients sizing materials and be applied in iron plate, with plastic film encapsulation, contrast with the iron plate that gets wet simultaneously, be placed in balcony, after 4 months, contrast is got rusty, test sample strip off cured layer light as new.
Claims (10)
1. a compound sizing material, is characterized in that being expected and the B material that contains base polyurethane prepolymer for use as forms by water-based A, A material is (weight ratio) with the proportioning of B material: A:B=0.5--1:0.5--1
Wherein A expects moisture and/or water glass and/or silicon sol and additive, and in A material, each composition weight percent is:
Water and/or water glass and/or the organic synergist 0-48% of silicon sol 27-100% additive 0-55%
Described additive is one or more combination in dispersion agent, tensio-active agent, tackifier, coupling agent, toughener, anti-heavy agent, fire retardant, rust-preventive agent, antiaging agent, flow agent, defoamer, thinner; Described organic synergist for containing thiazolinyl, hydroxyl, carboxyl and/or other with active hydrogen can with the active substance of-NCO group generation crosslinking reaction; Base polyurethane prepolymer for use as content >30% in B material, containing-NCO group 5-25%, synergistic agent 0-30%, described synergistic agent is one or more combination in stopper, stablizer, encapsulant, water glass curing agent, thinner.
2. according to the compound sizing material described in claim 1, it is characterized in that, A material is (weight ratio) with the proportioning of B material:
A：B=?1：0.5--1
In A material, each composition weight percent is:
Water and/or water glass and/or the organic synergist 19.5-48% of silicon sol 30-70% additive 12-55%
Described organic synergist is acrylic resin or emulsion, organosilicon acrylic resin or emulsion, styrene-acrylic resin or emulsion, epoxy resin, regeneration composite glue solution, Synolac, aldehyde ketone resin, terpolycyantoamino-formaldehyde resin, vibrin, urea-formaldehyde resin, one or more combination in re-dispersible glue powder, polyvalent alcohol; In described B material, contain polyisocyanates ,-NCO group accounts for 8-20% in B material.
3. according to the compound sizing material described in claim 1 or 2, it is characterized in that the organic synergist described in A material is one or more combination in epoxy resin resin, acrylic resin/emulsion or re-dispersible glue powder; Described additive toughener is one or more combination in breeze, metal powder, micro mist or expansible black lead; Base polyurethane prepolymer for use as described in B material is foamed glue, and described polyisocyanates is black material; For A material and the weight ratio of B material are: A:B=1:1
In additive B material, each composition weight percent is:
The black material 30-50% of foamed glue 50-70% synergistic agent 0-20%.
4. according to the compound sizing material described in claim 2 or 3, it is characterized in that in A material, each composition weight percent is:
Organic synergist 19-40% additive 20-70% of water glass and/or silicon sol 40-70%;
In described water and/or water glass and/or silicon sol, water glass accounts for 50-100%, and described organic synergist is one or both the combination of epoxy resin or acrylic resin/emulsion; One or more the combination of described additive in toughener, tensio-active agent, fire retardant, rust-preventive agent or thinner; In B material, each composition weight percent is:
The black material 30-40% of foamed glue 50-60% synergistic agent 4.5-16%
In described black material, also comprise 0-30% blocked polyisocyanate; Described synergistic agent is water glass curing agent, the expansible black lead through removing water treatment or the thinner that does not contain organic ester.
5. according to the compound sizing material described in claim 2,3 or 4, it is characterized in that
A expects (weight part): water glass 40-100 epoxy resin or acrylic resin 30-50 tensio-active agent 1-6 silica powders and/or 80-180 order expansible black lead 15-80 thinner and/or flow agent 0-20
B expects (weight part): foamed glue black material 25-80 blocked polyisocyanates of 50-100 urethane and/or encapsulant 0-30.
6. according to the compound sizing material described in claim 2,3 or 4, it is characterized in that
A expects (weight part): water glass 40-100 epoxy resin 15-20 acrylic resins/emulsion 15-20 tensio-active agent 1-6 silica powders and/or expansible black lead 5-50 thinners 0-20
B expects (weight part): foamed glue black material 25-80 stoppers of 50-100 urethane or thinner 0-20.
7. according to the compound sizing material described in claim 1, it is characterized in that,
A expects (weight part): water glass and/silicon sol 100 Sodium sulfate anhydrous.min(99) 10-35 silica powders and/or expansible black lead 0-50 rust-preventive agent 0-8 thinner or polyvalent alcohols 0-20.
8. according to the compound sizing material described in claim 1 or 2, it is characterized in that, described toughener and fire retardant at least comprise 80-180 order expansible black lead;
A expects (weight part): water 20-30 acrylic resin 30-50 expansible black lead 5-30 silica powder 0-30 ammonium polyphosphate 4-8
Rust-preventive agent 0.5-5 tensio-active agent 0.5-5
B expects (weight part): black material 30-40 foamed glue 40-60
A:B (weight ratio) is 1:1.
9. according to the compound sizing material described in claim 1 or 2, it is characterized in that described organic synergist comprises waste and old plastic through regeneration glue and/or the epoxidation propylene acid modification waste oil pulverized and organic solvent dissolution dispersion makes, its content occupies machine synergist total amount (weight) 30-100%.
10. according to the making method of the compound sizing material described in claim 1-9 any one, it is characterized in that described B material is to react and reach after terminal with polyester polyol and/or polyether glycol at excessive polyisocyanates, cool to lower than 60 ℃ of conditions, in protection atmosphere with under stirring, add polyisocyanates, in blend glue stuff, do not add catalyzer, with organic ester content, lower than 5% thinner, adjust viscosity, add if desired appropriate synergistic agent, fully mix; Or directly black material is fully mixed with foamed glue at low 40 ℃, add if desired synergistic agent.
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| CN201910234465.6A CN110564307A (en) | 2012-08-29 | 2012-08-29 | Environment-friendly composite adhesive |
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2117776A (en) * | 1982-01-23 | 1983-10-19 | Epsilon Dev Ltd | Silicate-containing polyisocyanate-expanded polymer composite |
| JPH0517722A (en) * | 1991-07-15 | 1993-01-26 | Tokiwa Denki:Kk | Adhesive |
| CN1155290A (en) * | 1994-08-31 | 1997-07-23 | 汉克尔股份两合公司 | Physically and/or chemically setting binders |
| JP2001279219A (en) * | 2000-03-30 | 2001-10-10 | Nippon Polyurethane Ind Co Ltd | Adhesive composition for hot-pressed product, hot-pressed product produced by using the composition and method for producing the same |
| JP2002020716A (en) * | 2000-07-05 | 2002-01-23 | Crk Kk | Adhesive composition for joining body part of built-up manhole or adhering step to manhole |
| JP2002020698A (en) * | 2000-07-07 | 2002-01-23 | Nippon Polyurethane Ind Co Ltd | Adhesive composition for concrete and filler composition |
| US20040112525A1 (en) * | 2002-09-04 | 2004-06-17 | Cheri Pereira | Adhesive and sealing layers for electrophoretic displays |
| CN1788064A (en) * | 2003-05-15 | 2006-06-14 | 亨茨曼国际有限公司 | Polyisocyanate-based adhesive formulation for use in sandwich panels |
| CN101838513A (en) * | 2010-01-27 | 2010-09-22 | 北京高盟新材料股份有限公司 | Preparation method of bi-component siloxane modified polyurethane sealant |
| CN101845288A (en) * | 2010-06-18 | 2010-09-29 | 天津博苑高新材料有限公司 | Aqueous polyurethane adhesive for tape adhesive film for manufacturing card and preparation method thereof |
-
2012
- 2012-08-29 CN CN201210312167.2A patent/CN103627330A/en active Pending
- 2012-08-29 CN CN201910234465.6A patent/CN110564307A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2117776A (en) * | 1982-01-23 | 1983-10-19 | Epsilon Dev Ltd | Silicate-containing polyisocyanate-expanded polymer composite |
| JPH0517722A (en) * | 1991-07-15 | 1993-01-26 | Tokiwa Denki:Kk | Adhesive |
| CN1155290A (en) * | 1994-08-31 | 1997-07-23 | 汉克尔股份两合公司 | Physically and/or chemically setting binders |
| JP2001279219A (en) * | 2000-03-30 | 2001-10-10 | Nippon Polyurethane Ind Co Ltd | Adhesive composition for hot-pressed product, hot-pressed product produced by using the composition and method for producing the same |
| JP2002020716A (en) * | 2000-07-05 | 2002-01-23 | Crk Kk | Adhesive composition for joining body part of built-up manhole or adhering step to manhole |
| JP2002020698A (en) * | 2000-07-07 | 2002-01-23 | Nippon Polyurethane Ind Co Ltd | Adhesive composition for concrete and filler composition |
| US20040112525A1 (en) * | 2002-09-04 | 2004-06-17 | Cheri Pereira | Adhesive and sealing layers for electrophoretic displays |
| CN1788064A (en) * | 2003-05-15 | 2006-06-14 | 亨茨曼国际有限公司 | Polyisocyanate-based adhesive formulation for use in sandwich panels |
| CN101838513A (en) * | 2010-01-27 | 2010-09-22 | 北京高盟新材料股份有限公司 | Preparation method of bi-component siloxane modified polyurethane sealant |
| CN101845288A (en) * | 2010-06-18 | 2010-09-29 | 天津博苑高新材料有限公司 | Aqueous polyurethane adhesive for tape adhesive film for manufacturing card and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| N.CASTLLA.S 等: "《Hybrid resins from polyisocyanate,epoxy resin and water glass：chemistry,structure and properties》", 《JOURNAL OF MATERIAL SCIENCE》 * |
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