CN103601837B - 一种聚丙烯酸酯乳液及制备方法 - Google Patents
一种聚丙烯酸酯乳液及制备方法 Download PDFInfo
- Publication number
- CN103601837B CN103601837B CN201310579303.9A CN201310579303A CN103601837B CN 103601837 B CN103601837 B CN 103601837B CN 201310579303 A CN201310579303 A CN 201310579303A CN 103601837 B CN103601837 B CN 103601837B
- Authority
- CN
- China
- Prior art keywords
- parts
- weight
- emulsion
- weight part
- mix monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000006185 dispersion Substances 0.000 title claims abstract description 32
- 229920000058 polyacrylate Polymers 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000000839 emulsion Substances 0.000 claims abstract description 156
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000003999 initiator Substances 0.000 claims abstract description 57
- 239000008367 deionised water Substances 0.000 claims abstract description 56
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 56
- 239000012874 anionic emulsifier Substances 0.000 claims abstract description 48
- 239000012875 nonionic emulsifier Substances 0.000 claims abstract description 48
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 52
- 239000008346 aqueous phase Substances 0.000 claims description 49
- 239000000178 monomer Substances 0.000 claims description 48
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 39
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 37
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 30
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 25
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 24
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 21
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 238000010792 warming Methods 0.000 claims description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 8
- RQAVKYPVSDCFJQ-UHFFFAOYSA-N 2-methyl-n-(2-methylpropoxy)prop-2-enamide Chemical compound CC(C)CONC(=O)C(C)=C RQAVKYPVSDCFJQ-UHFFFAOYSA-N 0.000 claims description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 7
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 5
- 239000004160 Ammonium persulphate Substances 0.000 claims description 5
- 239000004159 Potassium persulphate Substances 0.000 claims description 5
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 235000019394 potassium persulphate Nutrition 0.000 claims description 5
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 206010009866 Cold sweat Diseases 0.000 abstract description 13
- 239000003960 organic solvent Substances 0.000 abstract description 11
- 239000007787 solid Substances 0.000 abstract description 9
- 239000004902 Softening Agent Substances 0.000 abstract description 5
- 230000001476 alcoholic effect Effects 0.000 abstract description 5
- 239000000243 solution Substances 0.000 description 49
- 239000010410 layer Substances 0.000 description 25
- 239000002245 particle Substances 0.000 description 22
- 239000004800 polyvinyl chloride Substances 0.000 description 21
- 229920000915 polyvinyl chloride Polymers 0.000 description 21
- 239000007864 aqueous solution Substances 0.000 description 20
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 17
- 239000004816 latex Substances 0.000 description 14
- 229920000126 latex Polymers 0.000 description 14
- 238000004132 cross linking Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 238000009792 diffusion process Methods 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 8
- 241000238367 Mya arenaria Species 0.000 description 7
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 7
- 239000004575 stone Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000002344 surface layer Substances 0.000 description 6
- 230000033228 biological regulation Effects 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 238000004945 emulsification Methods 0.000 description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000011258 core-shell material Substances 0.000 description 3
- 125000003700 epoxy group Chemical group 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310579303.9A CN103601837B (zh) | 2013-11-15 | 2013-11-15 | 一种聚丙烯酸酯乳液及制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310579303.9A CN103601837B (zh) | 2013-11-15 | 2013-11-15 | 一种聚丙烯酸酯乳液及制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103601837A CN103601837A (zh) | 2014-02-26 |
CN103601837B true CN103601837B (zh) | 2015-10-28 |
Family
ID=50120109
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310579303.9A Active CN103601837B (zh) | 2013-11-15 | 2013-11-15 | 一种聚丙烯酸酯乳液及制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103601837B (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106398605A (zh) * | 2016-09-29 | 2017-02-15 | 东莞市冠力胶业有限公司 | 一种自交联型纸塑复合胶黏剂及其制备方法 |
CN108203488B (zh) * | 2016-12-20 | 2020-12-15 | 中国制浆造纸研究院有限公司 | 纤维密封材料用丙烯酸乳液及其合成方法 |
CN107674490B (zh) * | 2017-07-26 | 2021-03-30 | 福建格林春天新材料股份有限公司 | 一种软质pvc印刷专用水性油墨 |
CN107384017A (zh) * | 2017-09-11 | 2017-11-24 | 杭州海维特化工科技有限公司 | 一种木纹纸专用数码喷绘水墨及其制备方法 |
CN108424488B (zh) * | 2018-03-29 | 2020-06-16 | 杭州海维特化工科技有限公司 | 一种抗污、耐水硅丙乳液及其制备方法 |
CN109825126B (zh) * | 2019-02-27 | 2020-09-22 | 华南理工大学 | Pvc薄膜专用氟-硅-环氧改性水性丙烯酸酯乳液油墨及其制备方法 |
JP7304276B2 (ja) * | 2019-11-28 | 2023-07-06 | 花王株式会社 | 樹脂粒子分散体 |
CN113980587B (zh) * | 2021-12-03 | 2023-10-03 | 深圳市科泰顺科技有限公司 | 一种具有核壳结构的纯胶膜及制备方法 |
CN114085327A (zh) * | 2021-12-23 | 2022-02-25 | 广州富思德化工科技有限公司 | 一种聚丙烯酸脂乳液、涂料、啤酒标签用纸张及制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3807531A1 (de) * | 1988-03-08 | 1989-09-21 | Basf Ag | Herstellung von waessrigen polyalkylmethacrylat-dispersionen durch emulsionspolymerisation in zwei stufen und deren verwendung in holzlacken |
DE102004035937A1 (de) * | 2004-07-23 | 2006-02-16 | Röhm GmbH & Co. KG | Plastisole mit verringerter Wasseraufnahme |
CN102516904B (zh) * | 2011-11-16 | 2013-11-27 | 东莞市星宇高分子材料有限公司 | 一种蒸发式降温湿帘用单组分水性胶粘剂及其制备方法 |
CN102603960B (zh) * | 2012-03-02 | 2014-04-02 | 上海三瑞高分子材料有限公司 | 一种可再分散胶粉用核壳结构丙烯酸乳液的制备方法 |
CN102719145B (zh) * | 2012-06-29 | 2014-03-26 | 广州大学 | 一种热升华数码印花喷墨墨水用分散染料纳米胶囊及其制备方法 |
-
2013
- 2013-11-15 CN CN201310579303.9A patent/CN103601837B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN103601837A (zh) | 2014-02-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103601837B (zh) | 一种聚丙烯酸酯乳液及制备方法 | |
CN104277172B (zh) | 一种水性防水丙烯酸酯乳液及其制备方法 | |
CN101456965B (zh) | 干式水性彩色岩片的制备方法 | |
CN102134296B (zh) | 氟硅改性水溶性丙烯酸树脂分散体及其用途 | |
CN104672403A (zh) | 一种环保硅丙乳液及其制备方法 | |
CN102619103B (zh) | 涂料印花仿活性印花粘合剂及其制备方法 | |
CN101649153A (zh) | 有机硅改性丙烯酸酯水性木器漆乳液及其合成方法 | |
CN103554341A (zh) | 核壳结构的低温自交联丙烯酸酯乳液及其制备方法与应用 | |
CN105237675A (zh) | 一种具有核壳双交联结构的聚丙烯酸木器乳液及其制备方法 | |
CN101343525B (zh) | 在人造革静电植真皮纤维的产品中使用的水性粘合剂及其制备方法 | |
CN104910319B (zh) | 一种延缓染料迁移的聚丙烯酸酯乳液及其制备方法 | |
CN106749857A (zh) | 一种用于pvc水性油墨用丙烯酸乳液及其制备方法 | |
CN105408437B (zh) | 由多阶段乳液聚合制备用于保护膜的压敏胶粘剂分散体 | |
CN107163761A (zh) | 一种性能优异的多彩基础漆乳液及其制备方法 | |
CN110183904A (zh) | 阻燃油墨及其制备方法和阻燃膜 | |
CN103030914A (zh) | 丙烯酸酯组合物及其制备方法以及应用有该组合物的胶带 | |
CN104194684A (zh) | 一种抗粘连、耐水白的丙烯酸酯乳液及其制备方法 | |
CN102417601B (zh) | 聚苯乙烯板的改性方法及所用聚醋酸乙烯酯乳液 | |
CN107722882A (zh) | 一种丙烯酸酯乳液压敏胶及其制备方法 | |
CN105732909B (zh) | 一种丙烯酸聚硅氧烷水性乳液的制备方法 | |
CN109749558A (zh) | 一种应用于车标的多角度变色涂料及其制备方法 | |
CN105348446A (zh) | 一种聚苯乙烯/丙烯酸丁酯基复合核壳乳液的制备方法及其高硬度乳胶膜的制备方法 | |
CN108531042A (zh) | 一种耐磨水性哑光漆的制备方法 | |
CN107476063A (zh) | 柔软、耐寒、弹性、牢度、耐静水压性能好的纺织品用水性丙烯酸酯涂层胶及其制备方法 | |
CN102911418B (zh) | 超浓乳液制备聚丙烯酸酯-有机p阻燃剂的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB02 | Change of applicant information |
Address after: Dong Yun Lu Linglong Industrial Zone in Ling'an city of Hangzhou City, Zhejiang province 311300 Applicant after: HANGZHOU HIWETECH CHEMICAL TECHNOLOGY Co.,Ltd. Address before: Dong Yun Lu Linglong Industrial Zone in Ling'an city of Hangzhou City, Zhejiang province 311300 Applicant before: HANGZHOU ZHEDA HIWETECH CHEMICAL TECHNOLOGY CO.,LTD. |
|
COR | Change of bibliographic data | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20140226 Assignee: Lishui Hewitt New Material Co.,Ltd. Assignor: HANGZHOU HIWETECH CHEMICAL TECHNOLOGY Co.,Ltd. Contract record no.: X2023330000866 Denomination of invention: A polyacrylate lotion and its preparation method Granted publication date: 20151028 License type: Common License Record date: 20231120 |
|
EE01 | Entry into force of recordation of patent licensing contract |