CN103540064A - Oil-proof flame-retardant modified polyvinyl chloride cable sheathing material - Google Patents
Oil-proof flame-retardant modified polyvinyl chloride cable sheathing material Download PDFInfo
- Publication number
- CN103540064A CN103540064A CN201310519225.3A CN201310519225A CN103540064A CN 103540064 A CN103540064 A CN 103540064A CN 201310519225 A CN201310519225 A CN 201310519225A CN 103540064 A CN103540064 A CN 103540064A
- Authority
- CN
- China
- Prior art keywords
- parts
- polyvinyl chloride
- powder
- oil
- modified polyvinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Insulated Conductors (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention relates to a cable material, and particularly relates to an oil-proof flame-retardant modified polyvinyl chloride cable sheathing material. The material comprises the following raw materials in parts by weight: 35-38 parts of SG-2 polyvinyl chloride, 12-14 parts of light calcium carbonate, 2-3 parts of stearic acid, 7-9 parts of titanium dioxide, 23-26 parts of chlorinated polyethylene, 12-14 parts of isotactic polypropylene, 6-9 parts of acrylonitrile butadiene styrene (ABS) high-glue powder, 7-9 parts of ethylene vinyl acetate (EVA), 14-18 parts of nano celestite powder, 1-2 parts of triethanolamine, 23-24 parts of castor oil, 1-2 parts of bisphenol A, 12-13 parts of semi-refined paraffin wax, and 14-16 parts of assistant. By adopting the insulated material, the advantages of the raw materials such as the SG-2 polyvinyl chloride, the chlorinated polyethylene, the isotactic polypropylene and the like are combined; the prepared material is high in strength, good in weathering resistance, ozone resistance, oil-resistant flame retardancy and chemical stability, safe to use, and wide in market demand prospect, and can be widely applied to fabrication of kinds of cable sheath insulated materials.
Description
Technical field
The present invention relates to a kind of CABLE MATERIALS, be specifically related to flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant and preparation method thereof.
Background technology
Along with expanding economy, need to use the place of cable to become diversified, the performance index of cable jacket material have been had to stricter and various requirement, such as insulativity, tensile strength, use temperature, the indexs such as flame retardant properties all have strict requirement, constantly improve the performance of sheath material, it is the active demand of economy and social development, there is poor fire more in traditional sheath material, poor chemical stability, high temperature is yielding, poor mechanical property, the problems such as work-ing life is short, bring a lot of inconvenience to actual use, even threaten people's the security of the lives and property, therefore, be badly in need of changing original sheath material formula, improve material property, with the various demand in appropriate cable market.
Summary of the invention
The object of the invention is to, provide a kind of oil resistant flame-retardant modified polyvinyl chloride cable sheathing compound, promoted the performance of traditional polychloroethylene blended material, make it possess good mechanical property and processing characteristics, can adapt to specific environment for use condition, to achieve these goals, the technical solution used in the present invention is as follows:
A flame-retardant modified polyvinyl chloride cable sheathing compound, is characterized in that, the component that this invention material comprises following weight part: SG-2 polyvinyl chloride 35-38, light calcium carbonate 12-14, stearic acid 2-3, titanium dioxide 7-9, chlorinatedpolyethylene 23-26, isotatic polypropylene 12-14, ABS high glue powder 6-9, EVA 7-9, nanometer celestite powder 14-18, trolamine 1-2, Viscotrol C 23-24, dihydroxyphenyl propane 1-2, SEMI-REFINED PARAFFIN WAX 12-13, auxiliary agent 14-16.
The raw material that described auxiliary agent comprises following weight part: lazurite 20-25, linking agent TAC 4-5, Viscoat 295 2-3, Vulcanization accelerator TMTD 1-2, polyisobutene 2-3, aluminate coupling agent DL-411 1-2, ferrocene 2-3, dibasic lead phosphite 1-2, aluminum nitride powder 2-3, nanometer jade powder 2-3, methyl acrylate 2-3, Fructus Zanthoxyli oil 1-2; Preparation method puts into calcining furnace by lazurite to calcine 3-4 hour at 550-570 ℃, cooling, be ground into and put into 12-15% hydrochloric acid soln after 50-100 order and soak 2-3 hour, filter out lazurite powder, clear water is cleaned, and dries, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
The described flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant, its preparation method is: by after SG-2 polyvinyl chloride, chlorinatedpolyethylene, isotatic polypropylene, ABS high glue powder, EVA blend evenly, add other remaining components, send in high-speed kneading machine, at 110-170 ℃, mediate 6-15min, after kneading material is cooling, send into twin screw extruder granulation, obtain insulating material of the present invention.
The present invention combines the advantage of the raw materials such as SG-2 polyvinyl chloride, chlorinatedpolyethylene, isotatic polypropylene, ABS high glue powder, EVA, promoted the performance of traditional polychloroethylene blended material, make it have good processing characteristics and mechanical property, the strength of materials of preparation is high, weather-proof aging, resistance to ozone, oil resistant is fire-retardant, and chemical stability is good, long service life, can meet specific environment for use condition, market application foreground is wide.
Embodiment
Embodiment
The raw material that the present embodiment comprises following weight part: SG-2 polyvinyl chloride 38, light calcium carbonate 14, stearic acid 3, titanium dioxide 9, chlorinatedpolyethylene 26, isotatic polypropylene 14, ABS high glue powder 8, EVA 8, nanometer celestite powder 18, trolamine 2, Viscotrol C 24, dihydroxyphenyl propane 2, SEMI-REFINED PARAFFIN WAX 13, auxiliary agent 15.
The raw material that described auxiliary agent comprises following weight part: lazurite 25, linking agent TAC 5, Viscoat 295 3, Vulcanization accelerator TMTD 2, polyisobutene 3, aluminate coupling agent DL-411 2, ferrocene 3, dibasic lead phosphite 2, aluminum nitride powder 3, nanometer jade powder 3, methyl acrylate 3, Fructus Zanthoxyli oil 2; Preparation method puts into calcining furnace by lazurite at 570 ℃, to calcine 4 hours, cooling, is ground into put into 15% hydrochloric acid soln after 80 orders and soak 3 hours, filters out lazurite powder, clear water is cleaned, and dries, and is ground into 300 order powder, mix with other remaining component, grinding distribution 2 hours, obtains.
The described flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant, its preparation method is: by after SG-2 polyvinyl chloride, chlorinatedpolyethylene, isotatic polypropylene, ABS high glue powder, EVA blend evenly, add other remaining components, send in high-speed kneading machine, at 160 ℃, mediate 10min, after kneading material is cooling, send into twin screw extruder granulation, obtain insulating material of the present invention.
The performance test results of material of the present invention is: tensile strength is 18.8Mpa, elongation at break is 435%, after 90 ℃ * 70h of IRM902 oil processes, tensile strength and elongation at break are respectively 17.9Mpa, 402%, after 136 ℃ * 168h hot air aging, stretching strength retentivity 98.4%, elongation at break conservation rate is that 98.2%, 20 ℃ of volume specific resistance is 1.25 * 10
14Ω m, through 15% the NaCl solution soaking of 60 ℃, after 7 days, the pick up of material is 0.0026%, and after soaking, volume specific resistance velocity of variation is 0.003%, through 80 ℃ of toluene solvants, soak after 7 days, without obviously swelling and cracking phenomena, under the condition of ozone concn 0.025%, 26 ℃ * 20h, without cracking phenomena, after the artificial weathering test through 1000 hours, the slight velocity of variation that stretches is 28.4%, and elongation at break velocity of variation is 29.1%, and oxygen index is 41%.
Claims (2)
1. the flame-retardant modified polyvinyl chloride cable sheathing compound of oil resistant, is characterized in that, this Insulation Material is comprised of the raw material of following weight part: SG-2 polyvinyl chloride 35-38, light calcium carbonate 12-14, stearic acid 2-3, titanium dioxide 7-9, chlorinatedpolyethylene 23-26, isotatic polypropylene 12-14, ABS high glue powder 6-9, EVA 7-9, nanometer celestite powder 14-18, trolamine 1-2, Viscotrol C 23-24, dihydroxyphenyl propane 1-2, SEMI-REFINED PARAFFIN WAX 12-13, auxiliary agent 14-16;
The raw material that described auxiliary agent comprises following weight part: lazurite 20-25, linking agent TAC 4-5, Viscoat 295 2-3, Vulcanization accelerator TMTD 1-2, polyisobutene 2-3, aluminate coupling agent DL-411 1-2, ferrocene 2-3, dibasic lead phosphite 1-2, aluminum nitride powder 2-3, nanometer jade powder 2-3, methyl acrylate 2-3, Fructus Zanthoxyli oil 1-2; Preparation method puts into calcining furnace by lazurite to calcine 3-4 hour at 550-570 ℃, cooling, be ground into and put into 12-15% hydrochloric acid soln after 50-100 order and soak 2-3 hour, filter out lazurite powder, clear water is cleaned, and dries, be ground into 200-300 order powder, mix with other remaining component, grinding distribution 1-2 hour, obtains.
2. the flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant as claimed in claim 1, its manufacture craft is: by after SG-2 polyvinyl chloride, chlorinatedpolyethylene, isotatic polypropylene, ABS high glue powder, EVA blend evenly, add other remaining components, send in high-speed kneading machine, at 110-170 ℃, mediate 6-15min, after kneading material is cooling, send into twin screw extruder granulation, obtain insulating material of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310519225.3A CN103540064B (en) | 2013-10-29 | 2013-10-29 | The flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310519225.3A CN103540064B (en) | 2013-10-29 | 2013-10-29 | The flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103540064A true CN103540064A (en) | 2014-01-29 |
| CN103540064B CN103540064B (en) | 2015-12-30 |
Family
ID=49963955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310519225.3A Active CN103540064B (en) | 2013-10-29 | 2013-10-29 | The flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103540064B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881268A (en) * | 2014-02-27 | 2014-06-25 | 安徽伊法拉电力科技有限公司 | Antiflaming shock resistant modified PVC cable sheath material |
| CN103992558A (en) * | 2014-04-25 | 2014-08-20 | 安徽华鸿电气股份有限公司 | Cable material containing mica powder |
| CN104004290A (en) * | 2014-04-22 | 2014-08-27 | 天长市富信电子有限公司 | Power line sheath material for hot and humid areas and preparation method thereof |
| CN104130453A (en) * | 2014-06-26 | 2014-11-05 | 合肥和安机械制造有限公司 | Filler specialized for breakdown-resistant cable sheath material, and preparation method thereof |
| CN104559036A (en) * | 2015-01-23 | 2015-04-29 | 淮南文峰航天电缆有限公司 | Light-power high-light-stability cable material and preparation method thereof |
| CN105175935A (en) * | 2015-08-28 | 2015-12-23 | 苏州莱特复合材料有限公司 | PVC plastic alloy and preparation method therefor |
| CN105482295A (en) * | 2015-12-15 | 2016-04-13 | 中冠电缆有限公司 | High-hydrophobic and high-strength modified polyvinyl chloride (PVC) cable material and preparation method thereof |
| CN105860304A (en) * | 2016-06-01 | 2016-08-17 | 许婷 | Low-temperature-resistant cable material and preparation method thereof |
| CN106750937A (en) * | 2016-12-20 | 2017-05-31 | 安徽华天电缆有限公司 | One kind is unlikely to deform rigid polyvinyl chloride cable material |
| CN107090147A (en) * | 2017-06-16 | 2017-08-25 | 安徽滁州德威新材料有限公司 | A kind of low-temperature impact-resistant modified polyvinyl chloride CABLE MATERIALS |
| CN107163444A (en) * | 2017-07-03 | 2017-09-15 | 安徽真劲智能科技有限公司 | A kind of electronic tag PVC printing layer rapidoprints |
| CN114479434A (en) * | 2021-12-28 | 2022-05-13 | 苏州爱得华塑化有限公司 | Preparation process of flame-retardant material for cable protective sleeve of charging pile |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1235175A (en) * | 1998-05-12 | 1999-11-17 | 广州金发科技发展有限公司 | Halide-free smokeless flame-resistant thermoplatstic polyolefine composition and preparation thereof |
| CN102352057A (en) * | 2011-09-08 | 2012-02-15 | 西北师范大学 | Non-halogen composite flame retardant and application thereof in preparation of flame retardant thermoplastic elastomer composite |
| CN103122097A (en) * | 2013-01-22 | 2013-05-29 | 安徽华津电缆集团有限公司 | Thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables and preparation method thereof |
| CN103232631A (en) * | 2013-06-03 | 2013-08-07 | 北京理工大学 | Halogen-free low-smoke flame-retardant cable sheath material and preparation method of same |
| CN103265740A (en) * | 2013-04-27 | 2013-08-28 | 安徽省康利亚实业有限公司 | Ozone-resistant cable sheath material |
-
2013
- 2013-10-29 CN CN201310519225.3A patent/CN103540064B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1235175A (en) * | 1998-05-12 | 1999-11-17 | 广州金发科技发展有限公司 | Halide-free smokeless flame-resistant thermoplatstic polyolefine composition and preparation thereof |
| CN102352057A (en) * | 2011-09-08 | 2012-02-15 | 西北师范大学 | Non-halogen composite flame retardant and application thereof in preparation of flame retardant thermoplastic elastomer composite |
| CN103122097A (en) * | 2013-01-22 | 2013-05-29 | 安徽华津电缆集团有限公司 | Thermoplastic low-smoke halogen-free flame-retardant environment-friendly sheath material for power cables and preparation method thereof |
| CN103265740A (en) * | 2013-04-27 | 2013-08-28 | 安徽省康利亚实业有限公司 | Ozone-resistant cable sheath material |
| CN103232631A (en) * | 2013-06-03 | 2013-08-07 | 北京理工大学 | Halogen-free low-smoke flame-retardant cable sheath material and preparation method of same |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881268B (en) * | 2014-02-27 | 2016-03-09 | 安徽伊法拉电力科技有限公司 | A kind of flame-proof impact resistant-modified PVC cable sheath material |
| CN103881268A (en) * | 2014-02-27 | 2014-06-25 | 安徽伊法拉电力科技有限公司 | Antiflaming shock resistant modified PVC cable sheath material |
| CN104004290A (en) * | 2014-04-22 | 2014-08-27 | 天长市富信电子有限公司 | Power line sheath material for hot and humid areas and preparation method thereof |
| CN103992558A (en) * | 2014-04-25 | 2014-08-20 | 安徽华鸿电气股份有限公司 | Cable material containing mica powder |
| CN104130453A (en) * | 2014-06-26 | 2014-11-05 | 合肥和安机械制造有限公司 | Filler specialized for breakdown-resistant cable sheath material, and preparation method thereof |
| CN104559036A (en) * | 2015-01-23 | 2015-04-29 | 淮南文峰航天电缆有限公司 | Light-power high-light-stability cable material and preparation method thereof |
| CN105175935A (en) * | 2015-08-28 | 2015-12-23 | 苏州莱特复合材料有限公司 | PVC plastic alloy and preparation method therefor |
| CN105482295A (en) * | 2015-12-15 | 2016-04-13 | 中冠电缆有限公司 | High-hydrophobic and high-strength modified polyvinyl chloride (PVC) cable material and preparation method thereof |
| CN105860304A (en) * | 2016-06-01 | 2016-08-17 | 许婷 | Low-temperature-resistant cable material and preparation method thereof |
| CN106750937A (en) * | 2016-12-20 | 2017-05-31 | 安徽华天电缆有限公司 | One kind is unlikely to deform rigid polyvinyl chloride cable material |
| CN107090147A (en) * | 2017-06-16 | 2017-08-25 | 安徽滁州德威新材料有限公司 | A kind of low-temperature impact-resistant modified polyvinyl chloride CABLE MATERIALS |
| CN107163444A (en) * | 2017-07-03 | 2017-09-15 | 安徽真劲智能科技有限公司 | A kind of electronic tag PVC printing layer rapidoprints |
| CN114479434A (en) * | 2021-12-28 | 2022-05-13 | 苏州爱得华塑化有限公司 | Preparation process of flame-retardant material for cable protective sleeve of charging pile |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103540064B (en) | 2015-12-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103540064B (en) | The flame-retardant modified polyvinyl chloride cable sheathing compound of a kind of oil resistant | |
| CN103524949B (en) | A kind of low-temperature impact-resistant modified polyvinyl chloride cable jacket material | |
| CN103540065B (en) | The anti-aging modified polyvinyl chloride cable jacket material of a kind of oil resistant | |
| CN103540063B (en) | A kind of modified polyvinyl chloride cable jacket material | |
| CN103881223B (en) | A kind of modified EVA cable jacket material of resistance to ozone aging | |
| CN103554753A (en) | Flexible oil-proof modified polyvinyl chloride (PVC) cable sheath material | |
| CN103554922A (en) | Temperature-resistant damp-proof and insulating methyl vinyl silicone rubber cable material | |
| CN103881210B (en) | A kind of heat resist modification PE cable protective cover material | |
| CN103602012A (en) | Impact and temperature resistant modified fluorubber cable material | |
| CN105017668A (en) | Polystyrene electric cable sheath material with characteristics of light weight, water resistance and fire retardation | |
| CN103509235A (en) | Environment-friendly polyethylene cable material and preparation method thereof | |
| CN103540003A (en) | Modified flexible ozone-resistant polyethylene cable sheath material | |
| CN103589039B (en) | A kind of weather-proof toughening modifying Polyethylene insulated cable sheath material | |
| CN103554795A (en) | High-temperature steam-resistant and ageing resistant modified fluororubber cable material | |
| CN103756080B (en) | A kind of ageing-resistant flame-retardant modified polyolefin elastomer cable jacket material | |
| CN103642138A (en) | Weather-proof ozone-proof modified chlorinated polyethylene cable sheath material | |
| CN103756117A (en) | Weather-proof and ozone-proof modified polyethylene cable sheath material | |
| CN103772784A (en) | Halogen-free flame-retardant modified polyethylene cable sheath material | |
| CN103554777A (en) | Polyvinyl chloride insulating material for wire harness of communication equipment | |
| CN103540067A (en) | Oil-proof modified terafluoroethylene-propylene rubber cable material with chemical resistance | |
| CN103554754A (en) | Temperature-resistant and flame-retardant modified polyvinyl chloride cable sheath material | |
| CN105001547A (en) | Modified polyvinyl chloride cable sheath material capable of resisting ultraviolet radiation aging | |
| CN103881250A (en) | Damp-proof flexible modified chlorinated polyethylene cable sheath material | |
| CN103756168B (en) | The flame-retardant modified chlorinatedpolyethylene cable jacket material of a kind of shock resistance oil resistant | |
| CN103554778A (en) | Modified polyvinyl chloride insulating material for wire harness of communication equipment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Guo Xiaojing Inventor before: Xie Hua |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170920 Address after: 300000 Tianjin city Wuqing District Chen Zui town Mei Shi highway on the south side of the Yueyuan 2-4-301 Patentee after: Guo Xiaojing Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei Patentee before: Lvbao Cable (Group) Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190730 Address after: 214500 No. 1 Wei2 Road, Chengnan Park, Jingjiang City, Taizhou City, Jiangsu Province Patentee after: Jiangsu Xiangyun Plastic Technology Co., Ltd. Address before: 300000 Wenyueyuan 2-4-301, South Side of Meishi Highway, Chenzui Town, Wuqing District, Tianjin Patentee before: Guo Xiaojing |
|
| TR01 | Transfer of patent right |