CN103466957B - Enameled sheet glass, and preparation method and composite board thereof - Google Patents
Enameled sheet glass, and preparation method and composite board thereof Download PDFInfo
- Publication number
- CN103466957B CN103466957B CN201310391466.4A CN201310391466A CN103466957B CN 103466957 B CN103466957 B CN 103466957B CN 201310391466 A CN201310391466 A CN 201310391466A CN 103466957 B CN103466957 B CN 103466957B
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- China
- Prior art keywords
- plate glass
- glass
- base plate
- colored glaze
- oxide
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- 239000005357 flat glass Substances 0.000 title claims abstract description 316
- 239000002131 composite material Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title abstract description 28
- 238000000137 annealing Methods 0.000 claims abstract description 120
- 239000000203 mixture Substances 0.000 claims abstract description 58
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 46
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 37
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 35
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000000292 calcium oxide Substances 0.000 claims abstract description 35
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 25
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 24
- 238000010521 absorption reaction Methods 0.000 claims abstract description 21
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 10
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 claims abstract description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 102
- 239000000463 material Substances 0.000 claims description 80
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 41
- 229910052791 calcium Inorganic materials 0.000 claims description 41
- 239000011575 calcium Substances 0.000 claims description 41
- 239000013078 crystal Substances 0.000 claims description 34
- 230000008859 change Effects 0.000 claims description 32
- 239000010453 quartz Substances 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000011521 glass Substances 0.000 abstract description 144
- 239000000758 substrate Substances 0.000 abstract description 17
- 239000003086 colorant Substances 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 description 170
- 238000000034 method Methods 0.000 description 134
- 239000010410 layer Substances 0.000 description 97
- 238000005516 engineering process Methods 0.000 description 63
- 230000000694 effects Effects 0.000 description 55
- 238000002844 melting Methods 0.000 description 54
- 230000008018 melting Effects 0.000 description 54
- 230000008569 process Effects 0.000 description 50
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 48
- 229910052796 boron Inorganic materials 0.000 description 48
- 239000000919 ceramic Substances 0.000 description 47
- 238000004519 manufacturing process Methods 0.000 description 38
- 229910052782 aluminium Inorganic materials 0.000 description 36
- 238000007639 printing Methods 0.000 description 35
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 34
- 238000000465 moulding Methods 0.000 description 26
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 21
- 229910052749 magnesium Inorganic materials 0.000 description 21
- 239000011777 magnesium Substances 0.000 description 21
- 239000004411 aluminium Substances 0.000 description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
- 239000005361 soda-lime glass Substances 0.000 description 19
- 229910052708 sodium Inorganic materials 0.000 description 19
- 239000011734 sodium Substances 0.000 description 19
- 239000002994 raw material Substances 0.000 description 18
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 15
- 238000005520 cutting process Methods 0.000 description 15
- 230000007547 defect Effects 0.000 description 15
- 239000010703 silicon Substances 0.000 description 15
- 229910052710 silicon Inorganic materials 0.000 description 15
- 230000007613 environmental effect Effects 0.000 description 14
- 238000005245 sintering Methods 0.000 description 13
- 239000011449 brick Substances 0.000 description 12
- 238000005034 decoration Methods 0.000 description 12
- 238000007667 floating Methods 0.000 description 12
- 239000004575 stone Substances 0.000 description 12
- 238000004134 energy conservation Methods 0.000 description 11
- 239000004033 plastic Substances 0.000 description 11
- 238000005498 polishing Methods 0.000 description 11
- 238000005496 tempering Methods 0.000 description 11
- 238000005265 energy consumption Methods 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 230000008901 benefit Effects 0.000 description 9
- 238000001816 cooling Methods 0.000 description 9
- 239000010432 diamond Substances 0.000 description 9
- 229910003460 diamond Inorganic materials 0.000 description 9
- 239000002023 wood Substances 0.000 description 9
- 241000972773 Aulopiformes Species 0.000 description 8
- 230000004927 fusion Effects 0.000 description 8
- 230000004048 modification Effects 0.000 description 8
- 238000012986 modification Methods 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 235000019515 salmon Nutrition 0.000 description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
- VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 230000035922 thirst Effects 0.000 description 7
- 235000012431 wafers Nutrition 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 238000006124 Pilkington process Methods 0.000 description 6
- 238000010276 construction Methods 0.000 description 6
- 230000009969 flowable effect Effects 0.000 description 6
- 230000000630 rising effect Effects 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 5
- 238000003490 calendering Methods 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000005352 clarification Methods 0.000 description 5
- 229910052593 corundum Inorganic materials 0.000 description 5
- 239000010431 corundum Substances 0.000 description 5
- 239000000428 dust Substances 0.000 description 5
- 238000010304 firing Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 238000007507 annealing of glass Methods 0.000 description 4
- 239000002969 artificial stone Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 230000005496 eutectics Effects 0.000 description 4
- 238000004880 explosion Methods 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 210000004209 hair Anatomy 0.000 description 4
- 238000010309 melting process Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000011265 semifinished product Substances 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 230000003373 anti-fouling effect Effects 0.000 description 3
- 238000010923 batch production Methods 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000004973 liquid crystal related substance Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000003854 Surface Print Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000002742 anti-folding effect Effects 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical compound [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 description 2
- 229910001570 bauxite Inorganic materials 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007688 edging Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000007641 inkjet printing Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 238000003908 quality control method Methods 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 231100000004 severe toxicity Toxicity 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 208000031481 Pathologic Constriction Diseases 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 206010043458 Thirst Diseases 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000005391 art glass Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 208000002352 blister Diseases 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- -1 electricity Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229910052634 enstatite Inorganic materials 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 210000004247 hand Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000009766 low-temperature sintering Methods 0.000 description 1
- BBCCCLINBSELLX-UHFFFAOYSA-N magnesium;dihydroxy(oxo)silane Chemical compound [Mg+2].O[Si](O)=O BBCCCLINBSELLX-UHFFFAOYSA-N 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 229910052664 nepheline Inorganic materials 0.000 description 1
- 239000010434 nepheline Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000005315 stained glass Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 210000001215 vagina Anatomy 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 229910052844 willemite Inorganic materials 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910001720 Åkermanite Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Glass Compositions (AREA)
Abstract
The invention discloses application of taking substrate glass with low viscosity temperature, high strength and high annealing temperature as enameled glass. Fusing points of enameled layers of one to ten colors on the surface of substrate glass range from 540 DEG C to 700 DEG C, the enameled sheet glass is characterized in that the substrate glass comprises the following compositions in percentage by weight: 0-3.9% of boron oxide, 0.01-14% of sodium oxide, 0.01-5% of ferric oxide, 0-2.8% of fluorine oxide, 7-22.2% of magnesium oxide, 0.01-39% of aluminum oxide, and the balance of silicon oxide, and calcium oxide, wherein the content of silicon oxide is 1.9-4.1 times that of calcium oxide, and the content of calcium oxide is 1.0-1.8 times that of magnesium oxide. The thickness difference of the substrate glass is less than 0.3mm; the water absorption ratio of the substrate glass ranges from 0 to 0.3%; the rupture strength of the substrate glass achieves 50-180Mp; the lower annealing temperature of the substrate glass is at 550 DEG C to 710 DEG C. In addition, the invention further discloses a preparation method and a composite board of the enameled sheet glass.
Description
The application is Application No. 201110060913.9, the invention entitled " environmental protection and energy saving of high annealing temperature high intensity
The divisional application of the low melting point colored glaze decorative flat glass of type and preparation method ".
Technical field
The present invention relates to for the ambetti of especially prior art, and substitute ceramic wafer, Ceramic Tiles and plastic-aluminum
Plate, decoration plastic veneer, resinous artificial stone plate, and for inner-outer wall, ground and the household such as deck plate, kitchen cabinet panel
And the sodium oxide having in predetermined requisite special scope of the various decorative panel materials in engineer applied, ferrum oxide, oxygen
Change aluminum, silicon oxide, calcium oxide, magnesium oxide or also titanium oxide, barytic composition and predetermined silicon oxide, calcium oxide, oxygen
Change the factor proportion relationship change invention of the composition of specific proportions relation and the omission invention skill to boron or sodium composition between magnesium
Multiple innovative solution such as art scheme, overcomes and various traditional must form hydrotropy composition with substantial amounts of sodium or boron composition
[account for the annealing temperature lower limit of soda-lime glass of existing plate glass total output 99.9% with the technology prejudice of eutectic composition (i.e.
Endothermic peak origin temp) be only 490 DEG C], and can produce unforeseeable low sodium, no come in the composition of boron economy, low
Become ground production colored glazed glass exceeds 50 DEG C -200 DEG C of prior art annealing temperature lower limit (i.e. endothermic peak origin temp) preferably
Exceed 150 DEG C -200 DEG C of base plate glass, although and uniquely there is high annealing temperature lower limit (i.e. endothermic peak starting point than existing
Temperature) plate glass alkali-free boron glass technical scheme glass, but calcium sodium plate glass and reaches 80-100 times in high cost
Product is it is seen that only of the present invention just have the cost economic feasibility making colored glazed glass ornament materials；And intensity of the present invention
1-3 times can be risen, enable a kind of colored glaze plate glass and preparation method has the controllable costs of really big production and can ensure again
Carry out glaze sintering below annealing point and have the two technological property that has concurrently unprecedented of the yield rate normally not ruptured.
Background technology
The species of modern wall floor decorative material plate or brick is many, but has respective significant deficiency, such as:
(1), the major defect of common calcium soda-lime glass and ambetti and glass Mosaic is, [1] its because of the coefficient of expansion
There is no linear change feature, so change difference is big, annealing point lower limit is endothermic peak starting point (generally 490 DEG C about), by
Both know about in insider, be difficult to make the inorganic glaze of the fusing point less than 490 DEG C, and if due to the nothing higher than 490 DEG C
Machine glaze carrys out printed decoration pattern, it will produces the deformation of glass, especially can produce double annealing technique extremely wayward
And occur greatly have burst rate, insider also, it is understood that about strain point temperature, glass can produce expansion jumpy,
This is the main skill that all calcium soda-lime glass present can not form the fine pattern printing product of applicable inorganic glaze sintering at all
Art obstacle.Thus the minimum Mosaic product of size can only be done, (minimum below 5cm size just will not be produced because annealing bad
Raw explosion)；[2] the tempering printed glass and being only used for now monochrome (can be overcome with formation surface tension and anneal out
Existing problem).And technology tempering product is to be made on-gauge plates as various in 2400 × 1200mm etc. to use final now
Other sizes can be arbitrarily cut in the handss of family；[3] fusing point of the glaze of existing colored glaze safety glass and all mosaic glass
All at 760 DEG C -820 DEG C, because will adapt to soften the temperature having point deformation and mosaic glass softening use during glass tempering
Corner becomes round, and this is known technology；[4] its hardness and wearability are very poor, intensity only 45-50mpa about, nor be used for
Make household and engineering ground uses；[5] its viscosity is 100.5(Pa Sec) and 101(Pa Sec) melting temperature, using the U.S.
Theta rotation high-temperature viscosimeter does not measure at all, can only measure viscosity 101.5Temperature when (Pa Sec) is about 1580 DEG C molten
Change temperature, so having not meltable, the big defect of energy consumption (fusing of per kilogram and molding energy consumption reach 1500 kilocalories) in producing；[6]
Flameproof effect is poor, explosive.
(2), existing aluminium-plastic panel ornament materials, it is typically formed by one layer of plastic plate of folder in the middle of two layers of aluminum book plate, and it lacks
Be trapped in, [1] due to middle plastic layer drenched with rain because exposing to the weather using meeting out of doors and the temperature difference change, and produce serious change
Shape, and because plastic-aluminum flitch is soft, book, glacing flatness, poor flatness；Can not possibly make up to completely such as glass and ceramic
Reach that minute surface is smooth and fineness.[2] its surface printing bag pattern can only use organic material, just inevitable easily aging, variable
Color, so can only be indoor application, can not make outdoor use；
(3), decorate Plastic thick china, have a disadvantage in that, [1] impossible construction case reaches that minute surface is smooth and fineness；[2]
Ground can not possibly be made, because it is not wear-resisting；[3] there is no fireproof flame-retardant effect；[4] product must not make outdoor use, not so easily
Aging, easily deform.So no matter for decorative engineering veneer or house ornamentation engineering or wood furniture veneer, having major defect.
(4), ceramic wafer and Ceramic Tiles, have a disadvantage in that, all present ceramic wafers of [1], due to being squeezed using argillaceous
Go out or be pressed into base re-dry or firing process, volume production can not possibly produce 0.3mm-1.6mm or 2-3mm super book product, and
Volume production size can only accomplish 1800 × 900mm × (5-6) mm it is impossible to produce 2400 × 1200mm × (2-3) mm or 3mm size
Above product；[2] and its product strength is less than 50mpa, rapid wear in construction and transportation, and 99.99% pottery
The thickness of brick product is all 9-15mm；[3] its water absorption rate is larger, reaches 0.5-0.1%, easy soil pick-up；[4] during its product glaze paint stamp
Because firing temperature reaches 1100 DEG C -1200 DEG C, so the crystalline phase (because it can melt) of quartz crystal can not be retained, so its product
Difference of hardness, not wear-resisting；[5] its technique determine its production energy consumption especially big, the discharge of dust and carbon dioxide, sulfur dioxide
Greatly, raw material is big with the weight of finished product, and cost of transportation is high so that the energy consumption of transport is all very big, and water resource waste is big, floor space
Greatly, efficiency is low, and its production of articles is using water law ball-milling technology, spray tower processes, ceramic press technique, water law polishing and to grind
The change system that the advanced ceramics of the compositions such as side technique produces is produced, its energy consumption is big, dust and dusty gass discharge big,
Water consumption is high, so advocating in the whole world today of green economy, energy-conserving and environment-protective, low-carbon economy, under this conventional equipment system
The production technology of ceramic, has significant limitation and shortcoming, has the upgrading being badly in need of new invention product to substitute.
(5), lithotome, has a disadvantage in that, [1] not environmentally, has radioelement；[2] weight is big, especially should in exterior wall
With in, by specification must more than 25mm thickness could make wall surface dry-hang use；[3] high-grade natural stone resource increasingly reduces.
(6), artificial stone and ambetti, the yield of artificial stone and effect are low, high cost；And the pattern glaze of ambetti is complete
Portion is organic material, easy to change, and pole is not wear-resisting (can not to be used as exterior wall and ground, and the printed patterns stained glass of tempering
The product of specified size can not be made, not cleavable, present inorganic glaze figured plate glass, also can only make the glass within 5cm size
Mosaic, make big a little will because of the 490 of calcium soda-lime glass DEG C about annealing point affect its double annealing, explosion can be produced existing
As because the batch production of the unorganic glass glaze less than 490 DEG C is impossible, industry is intended to the glass more than 5cm
Can the standard-sized product of arbitrarily cutting the occurring overcoming technical barrier of the fine pattern of mosaic.
(7) in addition, a kind of existing Publication No. cn 1053047a's " has the crystallization of natural-marble-like surface patterns
Glass and its production method " patent application, its technique just determines and determines on its inevitable product defects, rather than product composition
Its product defect.
1st, its technique is expressed as preserving pieces of glass material in moulding box, makes ... to crystallize internal from glass surface entrance,
And frit is fuse with one another -- combine, control frit size ..., obtain and there is marble, the outward appearance of granite decorative pattern.
And this file has the mould frame of the statement of mass crystallization technical process it is seen that it uses granule glues the brilliant one kind of liquate
The technique of color decorative pattern devitrified glass.
(8), the pdp of prior art and alkali-free boron glass, representational for us2002/0011080a1 patent, although it has
Improved strain point, but in its technical scheme, defect is: first, because finished product reaches 5-20% containing boron oxide level, so its many 2 times
The volatilization of boron can form the inequality of composition, not only very big to environmental protection harm, and its product strength is not high, only up to 45-
50mpa；Second, its production cost is high, because its viscosity is high, fusing and row's bubble are all difficult, so being only used as price with molding
The electronic displayss glass of 50-100 multiple higher than existing float glass process flat board calcium soda-lime glass, not can be used as ambetti, also from
Publicity not used for colored glazed glass or example.
Defect in view of above-mentioned prior art and deficiency, the present inventor is manufactured for many years based on being engaged in such product design
Pragmatic experience and Professional knowledge, actively in addition research and innovation, to shortcomings and deficiencies of the prior art can be overcome, multiple solving
It is proposed that a kind of sodium oxide having in predetermined requisite special scope, ferrum oxide, oxidation after miscellaneous production technology problem
Aluminum, silicon oxide, calcium oxide, magnesium oxide or also titanium oxide, barytic composition and predetermined silicon oxide, calcium oxide, oxidation
The innovative solution of the composition of specific proportions relation between magnesium, and overcome various traditional composition hydrotropy compositions and be total to
The technology prejudice of melt composition, and the product strength rising 1- of unforeseeable hydrotropy or congruent melting body function and generation can be produced
3 times, environmental protection, the technique effect of energy-saving and emission-reduction etc., and on the glass substrate attachment fusing point in 540 DEG C -730 DEG C of colored glaze
A kind of colored glaze plate glass the present invention.
Content of the invention
First embodiment of the invention discloses a kind of colored glaze plate glass, the coloured silk of the 1-10 kind color on its base plate glass surface
At 540 DEG C -730 DEG C, the base plate glass of its product is characterised by the melting point of glaze layer: this base plate glass comprises silicon oxide, oxygen
Change calcium, magnesium oxide, aluminium oxide, ferrum oxide, the composition of sodium oxide, count as weight percents, boron oxide in this base plate glass
Content is 0-3.9%, and the content of sodium oxide is 0.01-14%, and iron oxide content is 0.01-5%, and the content of fluorine oxide is 0-
2.8%, content of magnesia is 8.1-22.2%, and alumina content is 0.01-39%, and the content of its silicon oxide is calcium oxide content
1.9 times -4.1 times, the content of calcium oxide is 1.2 times -1.6 times of the content of magnesium oxide；The thickness difference of this base plate glass is less than
0.3mm；The water absorption rate of its base plate glass is in the range of 0-0.3%；The rupture strength of its base plate glass reaches 50-180mpa；Its
The annealing temperature lower limit (i.e. endothermic peak origin temp) of base plate glass is 550 DEG C -710 DEG C.
(1), count as weight percents, in its base plate glass content: 1. magnesium oxide accounts for 7-20%, 2. calcium oxide is magnesium oxide
1.0 times -1.8 times in the range of, 3. silicon oxide is in the range of 2.6 times -5.6 times of magnesium oxide, and 4. silicon oxide is calcium oxide
2.2 times -3.8 times in the range of, 5. aluminium oxide be 0.1-30%, 6. sodium oxide be 0-18%, 7. Barium monoxide be 0-5%；
A kind of colored glaze plate glass according to the first embodiment of the present invention it is characterised in that: the composite plate of its product is
A kind of sheet metal (3) complex group by colored glaze plate glass (1) and bonding material layer (2) and 0.1-1mm or 1-5mm thickness
Become.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the base plate glass of its product is characterised by: presses
Terms of weight percent, in its base plate glass, the content of aluminium oxide is less than or equal to 30%, and this base plate glass is 10 in viscosity0.5(handkerchief
Second) when temperature be 1480 DEG C -1640 DEG C；Viscosity is 101Temperature when (Pa Sec) is 1410 DEG C -1600 DEG C；Viscosity is 102
Temperature when (Pa Sec) is 1180 DEG C -1340 DEG C；Viscosity is 103Temperature when (Pa Sec) is 1040 DEG C -1220 DEG C；This base
The thickness difference of glass sheet is less than 0.3mm；The water absorption rate of this base plate glass is in the range of 0-0.3%；The annealing of this base plate glass
In the range of lowest temperature (i.e. endothermic peak origin temp) is 550 DEG C -710 DEG C；The rupture strength of this base plate glass is 50-
180mpa；The difference of the two ends numerical value at 150 DEG C -300 DEG C for the thermal coefficient of expansion of this base plate glass is million/1.0- million
/ 3.0；It is million/1.0- 2.8/1000000ths in the difference of 550 DEG C -600 DEG C of two ends numerical value.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, its product characteristics is: the glaze on its top layer
Quartz crystal containing 20-70% or alpha-alumina crystals in layer.
(2), the strain point temperature of its product is in the range of 560 DEG C -720 DEG C；
(3), the water absorption rate of its product is in the range of 0-0.001%；
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the base plate glass of its product is characterised by: presses
Terms of weight percent, in its product content: calcium oxide is 1.15 times -1.8 times of magnesium oxide.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the base plate glass of its product is characterised by: presses
Terms of weight percent, when in product, alumina content reaches 15-23%: viscosity is 101The melting process temperature of (Pa Sec) is
1360℃-1550℃；Viscosity is 102The clarification of (Pa Sec), aerofluxuss bubble technological temperature are 1250 DEG C -1430 DEG C；Viscosity is 103
The moulding process temperature of (Pa Sec) is 1060 DEG C -1200 DEG C；The rupture strength of its product reaches 100-180mpa.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the base plate glass of its product is characterised by: presses
Terms of weight percent, the content of calcium oxide is 1.0 times -1.6 times of the content of magnesium oxide, more preferably 1.2 times -1.5 times.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the thickness of the base plate glass of its product is 0.3-
1.8mm.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the thickness of the base plate glass of its product is 1.8-
5mm.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the thickness of the base plate glass of its product is 5-
20mm.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the base plate glass of its product is characterised by: presses
Terms of weight percent, the content of sodium oxide is 0.01-2%.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the base plate glass of its product is characterised by: presses
Terms of weight percent, the content of sodium oxide is 2.1-5%.
Second embodiment of the invention provide a kind of preparation method of colored glaze plate glass it is characterised in that:
Step 1, required various have for the base plate glass component configuration of the product according to any one of claim 1-6
Sodium oxide in predetermined requisite special scope, ferrum oxide, aluminium oxide, silicon oxide, calcium oxide, magnesium oxide or also have
The wound of the composition of specific proportions relation between titanium oxide, barytic composition and predetermined silicon oxide, calcium oxide, magnesium oxide
The raw material of new solution, corresponds to the fusion temperature fusing of each glass formula, forms controlled viscosity after blended stirring
With the low viscous vitreous humour optimizing, then homogenizing, clarification, discharge bubble, form flowable molten mass；
Step 2, using any one technique in floating process, horizontal drawing technique, lattice-method process, calendering technology, press over system technique
Glass is carried out with molding, cooled operation is obtained the low melting point colored glaze decorative plate of the environment-friendly and energy-efficient of high annealing temperature high intensity
The base plate glass of glass；
Step 3, the surface printing to the base plate glass of the product of molding or apply cloth last layer by a kind or 2-10 kind color
Fusing point is that 540 DEG C -730 DEG C of colored glaze forms decorative layer.
A kind of according to an embodiment of the invention colored glaze plate glass, the colored glaze pattern decorative on its product surface
Layer, is by arranging 2-100 set, often covering the monolithic being made up of 1-10 plane wire mark or roll printing device or ink jet printing device
Product printing equipment unit, the low melting point in the way of parallel configuration, to the environment-friendly and energy-efficient of described high annealing temperature high intensity
The surface of the base plate glass of colored glaze decorative flat glass, carries out colored glaze material printing, then carries out glaze sintering circuit, obtained
Make in same batch production of articles 2-100 block product surface produce every piece of default different printing pattern having a 1-10 kind color or
A kind of colored glaze final sheet of color glaze decorative layer.
Process according to embodiments of the present invention, wherein: the 2-4 bar of the metallic plate in back end face of the composite plate of its product
Side, a kind of edge of top layer colored glaze final sheet of proportion poststack has stretched out the distance of 10-30mm.
Brief description
Fig. 1 is the environmental protection of the high annealing temperature high intensity of the embodiment of a kind of present invention colored glaze plate glass and preparation method
The floor map of the energy-saving base plate glass of low melting point colored glaze decorative flat glass.
Fig. 2 is the environmental protection of the high annealing temperature high intensity of the embodiment of a kind of present invention colored glaze plate glass and preparation method
The schematic flow sheet of the energy-saving floating process molding of the base plate glass of low melting point colored glaze decorative flat glass.
Fig. 3 is the environment-friendly and energy-efficient of the high annealing temperature high intensity of a kind of present invention colored glaze plate glass and preparation method
The side generalized section of the state of floating process molding of the base plate glass embodiment of low melting point colored glaze decorative flat glass.
Fig. 4 be a kind of present invention colored glaze plate glass and preparation method embodiment size be 1220mm × 2440mm
Colored glaze material through printing predetermined three zone forms a kind of colored glaze plate glass that top layer is predetermined colored glaze material pattern decorative layer
The floor map of product.
Fig. 5 is the size of a kind of present invention colored glaze plate glass and preparation method embodiment is 1220mm × 2440mm thickness
The colored glaze material having printed predetermined three zone of about 2-5mm forms the predetermined colored glaze material figure that top layer is about 0.1-1mm thickness
A kind of generalized section of the colored glaze final sheet of case decorative layer.
Fig. 6 is the top layer of a kind of present invention colored glaze plate glass and preparation method embodiment is a kind of colored glaze plate glass,
The back side is that edge, without departing from the aluminium sheet of top layer silicate colored glaze ambetti size, is mutually pasted multiple by binding agent after overlap
The composite board cross-sectional view being combined into.
Fig. 7 is the top layer of a kind of present invention colored glaze plate glass and preparation method embodiment is a kind of colored glaze plate glass,
The back side is that have 2 sides than top layer silicate colored glaze ambetti size each aluminium sheets having stretched out 10-30mm distance more, mutually viscous
The composite board cross-sectional view of the compound composition of patch.
Fig. 8 be a kind of present invention colored glaze plate glass and preparation method embodiment be a kind of colored glaze flat board glass using top layer
Glass, the back side is that have 2 sides than top layer silicate colored glaze ambetti size each aluminium sheets having stretched out 10-30mm after overlap more,
Mutually paste the composite board of compound composition, after the precalculated position punching on 10-30mm extension, metope can be carried out
The vertical planar structure schematic diagram that screw is installed.
Description of reference numerals
1: a kind of base plate glass of colored glaze plate glass
2: feed bin charging aperture
3: feed bin
4: the predetermined mixed material prepared
5: raw material enters the molten bath kilneye in molten bath
6: molten bath kiln
7: guiding gutter
8: molten tin bath
9: transition roller table
10: annealing kiln
11: cutting panel sub-assembling platform
12: float line matrix
21: oblique line portion represents the first zone colored glaze material pattern area of printing
31: cross hairs part represents the second zone colored glaze material pattern area of printing
41: pore part represents the colored glaze material pattern area of tertiary color area of printing
123: represent the glaze pattern decorative layer having printed predetermined three pattern zone colored glaze material on upper strata
13: indicate the low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of high annealing temperature high intensity of glazed colour layer
14: represent the low melting point colored glaze dress of the environment-friendly and energy-efficient without departing from top layer high annealing temperature high intensity for the edge after overlap
The aluminium sheet of decorations plate glass edge
141: after representing overlap, have the low melting point colored glaze dress of the environment-friendly and energy-efficient of 2 sides annealing temperature high intensity higher than top layer
Decorations plate glass each aluminium sheets having stretched out 10-30mm distance more
15: represent predetermined binding agent
16: represent the low melting point of the environment-friendly and energy-efficient of the high annealing temperature high intensity in ratio top layer of back end aluminium sheet of composite board
Colored glaze decorative flat glass stretches out the screw installing hole in the edge of 10-30mm
Specific embodiment
The present invention has initiated (1) has novelty, creative environment-friendly type glass substrate technical scheme so as to have (2) line
Linear thermal expansion feature, have high annealing point to be annealing temperature lower limit (i.e. endothermic peak origin temp), have the glass of high strength characteristics with
(3) it is limited to (note: the glaze of simple glass mosaic and all glass is all at 760 DEG C -820 of 540 DEG C -730 DEG C of fusion temperature
Fusion temperature more than DEG C) glazed colour layer three technology essential factor combinations of features New function colored glazed glass product, in cost economy
On the premise of feasible, solve the skill that prior art plate glass cannot be used for the big plate face colored printing ambetti of non-tempering
An art difficult problem.
Due to only having the present invention could initiate low cost, make to high efficiency production base plate glass annealing temperature in prior art
Lower limit (i.e. endothermic peak origin temp) rises to minimum 540 DEG C from 490 DEG C of ordinary plate glass, preferably 600 DEG C or 650 DEG C
More than above or 700 DEG C (notes: existing plate glass only display alkali-free boron glass just has this performance, but insider knows
Road its due to factors such as technique and materials, market price is 250,000-30 ten thousand yuans/ton, about 2000 yuan of ratio building soda-lime glass
Expensive 100 times of RMB/ton), the present invention exceeds 150 DEG C -220 DEG C than 490 DEG C of prior art calcium soda-lime glass, and due to having ten
Divide excellent thermal expansion linear character, that is, warm area expansion changes very little near annealing point, so, first, can be using molten
O'clock in 540 DEG C -730 DEG C of glaze, the preferably glaze of 600 DEG C -650 DEG C or 650 DEG C -700 DEG C of fusing points, and this glaze can become
This does not highly produce greatly, and glaze below 540 DEG C for the melting point cannot produce greatly, and has serious environmental issue), by
Printed with fine pattern can be sintered in the present invention under annealing point temperature.So without taking double annealing technique so that it may history
No precedent ground produces the stone materials such as 2400 × 1200mm, 3000 × 1800mm or various such as aluminium plate, layer of wood sheet material, aluminium-plastic panel
A kind of present invention colored glaze flat board glass of the pattern decorative standard board size such as material, composite wood board, wood powder density board, resin plate
The fine colored glaze bag of glass, grain pattern printing color or one color product, and product can be such as above-mentioned first technical standard
Sheet material is equally arbitrarily cut by construction requirement size.
Below, embodiments of the invention are described in detail.
First embodiment:
According to one embodiment of the invention, a kind of colored glaze plate glass, the coloured silk of the 1-10 kind color on its base plate glass surface
At 540 DEG C -730 DEG C, the base plate glass of its product is characterised by the melting point of glaze layer: this base plate glass comprises silicon oxide, oxygen
Change calcium, magnesium oxide, aluminium oxide, ferrum oxide, the composition of sodium oxide, count as weight percents, boron oxide in this base plate glass
Content is 0-3.9%, and the content of sodium oxide is 0.01-14%, and iron oxide content is 0.01-5%, and the content of fluorine oxide is 0-
2.8%, content of magnesia is 8.1-22.2%, and alumina content is 0.01-39%, and the content of its silicon oxide is calcium oxide content
1.9 times -4.1 times, the content of calcium oxide is 1.2 times -1.6 times of the content of magnesium oxide；The thickness difference of this base plate glass is less than
0.3mm；The water absorption rate of its base plate glass is in the range of 0-0.3%；The rupture strength of its base plate glass reaches 50-180mpa；Its
The annealing temperature lower limit (i.e. endothermic peak origin temp) of base plate glass is 550 DEG C -710 DEG C.
Count as weight percents, in this base plate glass, the content of aluminium oxide is less than or equal to 30%, and this base plate glass is in viscosity
For 100.5Temperature when (Pa Sec) is 1480 DEG C -1640 DEG C；Viscosity is 101Temperature when (Pa Sec) is 1410 DEG C -1600
℃；Viscosity is 102Temperature when (Pa Sec) is 1180 DEG C -1340 DEG C；Viscosity is 103Temperature when (Pa Sec) be 1040 DEG C-
1220℃；The thickness difference of this base plate glass is less than 0.3mm；The water absorption rate of this base plate glass is in the range of 0-0.3%；This substrate
The strain point temperature of glass is in the range of 560 DEG C -720 DEG C；The rupture strength of this base plate glass is 50-180mpa；This substrate
The difference of the two ends numerical value at 150 DEG C -300 DEG C for the thermal coefficient of expansion of glass is million/1.0- 3.0/1000000ths；550
The difference of DEG C -600 DEG C of two ends numerical value is million/1.0- 2.8/1000000ths.
In addition, adding aluminium oxide that the intensity of base plate glass can be made to improve but the fusion temperature of glass being increased and other are various
Temperature under viscosity.Base plate glass according to the present embodiment can wanting according to the temperature under the demand and various viscosity to intensity
Ask, the aluminium oxide of proper content can be added.(in addition, in this manual, unless specifically stated otherwise, various one-tenth in base plate glass
The percentage composition dividing all is weight percentage.)
The performance characteristic of product of the present invention
Annealing temperature performance
Note: annealing temperature lower limit described in this specification (i.e. endothermic peak origin temp) is to be measured using synthesis thermal analyzer
's.
The annealing temperature lower limit (i.e. endothermic peak origin temp) of base plate glass of the present invention is 550 DEG C -710 DEG C.The present invention is real
The annealing temperature lower limit (i.e. endothermic peak origin temp) applying the base plate glass of example is preferably at 600 DEG C or 650 DEG C or 650 DEG C -700 DEG C
Purpose be solve at a higher temperature, under annealing point, agglomeration glaze, be not in just existing always perplex colored glaze
The easy explosion technical barrier of the double annealing of glass production.
Strength character
Aforesaid (a) existing industry, building glass, such as calcium sodium plate glass, lcd glass, only aluminium oxide 1% about or
1-3% about, and its technical scheme is difficult to add aluminium oxide, otherwise can not be able to implement because viscosity is too high to produce, intensity
It is only 45-60mpa.
And the base plate glass embodiment according to the present invention, as partly described in front viscosity, it is known that aluminium oxide is added 20-
When 25%, viscosity is also below prior art, and has the platform of a good technical controlling scope, in the intensity side of product
Face, inventive article can easily reach 100-160mpa or 130-180mpa very much.It is related to the embodiment of the present invention in this specification
The rupture strength of glass, by sample being cut into the little bar of 50mm × 5mm × 5mm, using rupture strength instrument, by standard gb/
T3810.4-2006 measures.
Strain point is high, and coefficient of expansion linear character projects, and different temperatures interval expansion changes of value is minimum
The coefficient of expansion of glass according to embodiments of the present invention measures according to standard gb/t7320.1-2000.
When product can drastically be heated or cool down, especially colored glaze does not have excessive modification or explosion when sintering.But root
Can there is more preferable coefficient of expansion linear character according to the technical scheme of the base plate glass of the embodiment of the present invention, the glass producing very little glues
Elasticity mutation, specifically the difference of the two ends numerical value at 150 DEG C -300 DEG C for the thermal coefficient of expansion of its product is million/1- million
/ 3.0；It is million/1- 2.8/1000000ths in the difference of 550 DEG C -600 DEG C of two ends numerical value；Exist for alkali-free glass
The difference of 600 DEG C -650 DEG C of two ends numerical value is million/1- 3.0/1000000ths.Than prior art calcium sodium float glass and
The difference of the thermal expansion system two ends numerical value of 550 DEG C -600 DEG C of pdp or tft glass will be got well for 16/1000000ths and 5-16 times, compare lcd
The difference of the thermal expansion system two ends numerical value of 550 DEG C -600 DEG C of calcium soda-lime glass will be got well for 20/1000000ths and 7-20 times.
This also offers a colored glaze pattern sintering process in rise suddenly temperature or the temperature that plunges and building and ornament materials fireproof
Apply under use environment, have than existing various glass have more preferable deformation little, stable and be not mutated, pole is difficult to burst, in urgency
The glass viscoelasticity sudden turn of events little very big advantage during heating and cooling.
Water absorption rate
The water absorption rate of base plate glass according to embodiments of the present invention is in the range of 0-0.3%.In addition, according to the present invention's
The base plate glass of the low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of high annealing temperature high intensity of embodiment, it is permissible
Selection has good transparent feature and water proofing property.
The water absorption rate of base plate glass according to embodiments of the present invention is to measure according to standard gb/t3810.3-2006.
Thickness is poor
The thickness difference of base plate glass according to embodiments of the present invention is in the range of 0.3mm.
The thickness difference of base plate glass according to embodiments of the present invention is to measure according to standard gb/t1216.
In order to be more fully described the technical scheme of base plate glass according to embodiments of the present invention, enumerate in following table 1
Go out the formula of the sample of base plate glass under glazed colour layer according to an embodiment of the invention and corresponding performance.
The convenience of controllable economy, standardization and detail design
The base plate glass of the present invention can be under conditions of than tens times of existing alkali-free boron plate glass low cost, in annealing temperature
Under conditions of degree lower limit (i.e. endothermic peak origin temp) is in accordance with color glaze glass not double annealing, the condition that high tens times of production efficiency
Under (it is can only to be arranged with expensive platinum channel device due to the alkali-free plate glass of existing boracic condition to steep, a life producing 8 tons daily
Producing line will be invested and be reached hundred million RMB more than 10, but also the annual cold repair of corrosion three months that will be because of boron composition to molten bath, so reaching 25
Ten thousand -30 ten thousand RMB/ton, and the technical scheme of the present invention can reach same various qualities, especially quality intensity also may be used
To exceed 1-2 times, and produced using the process that large-tonnage can produce 300 tons -800 tons daily, invest ability 3-4 hundred million RMB,
So low cost 50-80 times.) can the reasonable Financial cost ground of high-quality big produce.This is not very obvious just energy handle
The property of plate glass and annealing temperature lower limit (i.e. endothermic peak origin temp), intensity, solve at low cost, this is to existing
One kind that technology never occurred the plate glass of an inorganic glaze printing essential technique difficult problem commercially has expectation not
Technical scheme to effect.Insider both knows about, and (and tempering glaze panel is inapplicable to this generates the extensive advantage of new application
, can not as ceramic tile on-site cutting, and be such as patterned, steel plate edge must be have 1-2mm about width figure
Case defect, edging after tempering nor as ceramic tile, and the present invention can be printed as the mark such as 2400 big × 1200mm
Quasi- plate, can edging, cutting as ceramic tile, the zero defect of guarantee pattern and product big plate standardization and use cutting facility
Change.
Subordinate list 1
* do not measured with High Temperature Rotating viscometer, obtain through reckoning.
Table 2 prior art
* do not measured with High Temperature Rotating viscometer, obtain through reckoning.
From upper table 1:
For the boron oxide being illustrated in embodiment in 0-3.9%, in 0.01-5%, titanium oxide is in 0.0003- for ferrum oxide
4.9%, sodium oxide in 0.02-8.8% and magnesium oxide in 8.1-22.2%, and silicon oxide: calcium oxide is 1.9-4.1 times, oxygen
Change calcium: magnesium oxide is the sample in the range of 1.2-1.6 times of technical solution of the present invention, is all better than existing first in viscosity
One incision technology 100.5(Pa Sec), 101Melt viscosity when (Pa Sec), 102Aerofluxuss when (Pa Sec) are steeped, clarify, all
Change viscosity, all than 150 DEG C -400 DEG C of prior art (referring to comparison sheet 2 and table 3).And its coefficient of linear thermal expansion is 150
DEG C -300 DEG C, 550 DEG C -600 DEG C and two ends numerical value at 600 DEG C -650 DEG C difference, also than existing calcium soda-lime glass, pdp glass
Glass, alkali-free liquid crystal display screen high boron glass will be got well.
Sample 6,7,8,9,10 is in 1.3-1.5 times that preferred calcium oxide is magnesium oxide, and silicon oxide is oxidation
Calcium 2.1-3.3 times and alumina content among the more excellent scope of 19-30%, the difference of especially viscosity and linear expansion coefficient
The technique effect index such as value and temperature index is best.
And sample 1,2,3,4,5,11, all within the content of technical solution of the present invention it is seen that its viscosity, intensity, swollen
Swollen coefficient is still than the tft LCDs boron glass of all prior arts, pdp plasma panel glass and all existing skills
Art plate glass is good.
And sample 1,2,3,4 is in the magnesium of this technology scheme of the invention, calcium, the upper limit of silicon ratio, lower limit and the intersection adopting
The example of the proportion of lower limit, and sample 1 and 5 is silicon, calcium, the example of the upper and lower limit for 59.5-99.8% for the magnesium summation.
From sample 10,11, because iron content is 1 to 1.3, and have higher Barium monoxide, titanium oxide content and can become
Opaque brown yellow or brown color, with adapt to when produce each outer surface of glaze layer as glass when the (color glazed brick, imitative as pottery
Ancient brick), due to not minding the light transmission of glass, so cost declining, expand as the common of the unavailable big hundreds of times of clear glass
Quartz sand original profit range of application, the effect of the technique effect economizing on resources and 10 times about of primary raw material cost of reduction is (senior
Silicon materials than more than high ten times of common price) just fairly obvious.
Table 2 lists the glass formula of some prior arts and the performance of correlation.From table 2 it can be seen that being primarily due to four
Boron, ferrum, titanium, sodium, the scope of magnesium and the present invention that kind sample contains are different, and due to silicon and calcium and calcium oxide and oxidation
Proportionate relationship between magnesium is all entirely different with the specific proportions relation of the present invention, its silicon oxide and calcium oxide and calcium oxide with
Magnesium oxide ratio exceeds the present invention significantly, and the ratio of the present invention is 1.2 times -1.6 times, silicon oxide of content of magnesia for calcium oxide
1.9 times -4.1 times of calcium oxide content, and the silicon oxide of these products than calcium oxide and calcium oxide than magnesium oxide content all
It is completely different.As seen from Table 2 in its technology prejudice always all using silicon be as the skeleton of glass and be melted and
It is the matrix of infusibility, so its viscosity, especially 100.5(Pa Sec), 101Melting process temperature when (Pa Sec), using mark
Accurate rotating cylinder viscometer does not all measure (because its viscosity is too high) at all it is seen that its energy consumption to be overcome in fusing, overcomes quarrel point, knot
Stone, the difficulty of improving production efficiency is larger or very big.It is the 10 of normal aerofluxuss bubble and homogenizing2Temperature when (Pa Sec),
Also exceed 150 DEG C -300 DEG C it is seen that the difficulty of its aerofluxuss bubble and homogenizing than table 1 sample of the present invention, and the technique of the present invention is put down
The energy-conservation of platform and comparative advantages easy to control, for 103The moulding process temperature of (Pa Sec), the present invention for molding, for system
The flatness of product, thickness difference also have the manageable comparative advantages of very big technology, and in terms of product strength, inventive article
It is also its 2-3 times, in linear expansion coefficient, be particularly relevant to the line of agglomeration glaze or fire-proof and explosion-proof viscoelasticity value on glass
Property feature the difference change of several important warm area on also have very big advantage.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the thickness of the base plate glass of its product is 0.3-
1.8mm.
According to a kind of colored glaze plate glass of the first embodiment of the present invention, the thickness of the base plate glass of its product is 1.8-
20mm.
On the basis of above-mentioned first embodiment, composition to base plate glass, limit and count as weight percents, sodium oxide
Content is 0.01-2%.
On the basis of above-mentioned first embodiment, composition to base plate glass, limit and count as weight percents, sodium oxide
Content is 2.1-5%.
On the basis of above-mentioned first embodiment, composition to base plate glass, limit and count as weight percents, sodium oxide
Content is 2.1-8%.
On the basis of above-mentioned first embodiment, composition to base plate glass, limit and count as weight percents, sodium oxide
Content is 2.1-14%.
On the basis of above-mentioned first embodiment, composition to base plate glass, limit and count as weight percents, aluminium oxide
Content is 1-19%.
It is more than the low melting point colored glaze dress of the environment-friendly and energy-efficient to high annealing temperature high intensity according to embodiments of the present invention
The composition of base plate glass of decorations plate glass and its characteristic, it is high that description below manufactures high annealing temperature according to embodiments of the present invention
The method of the low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of intensity.
Second embodiment
Refer to shown in Fig. 1, be that the height of a kind of according to an embodiment of the invention colored glaze plate glass and preparation method moves back
The base plate glass product floor map of the low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of fiery temperature high intensity.From figure
It can be seen that, label 1 represents a kind of base plate glass of colored glaze plate glass.
Refer to shown in Fig. 2, be a kind of present invention colored glaze plate glass and preparation method to high annealing temperature high intensity
The schematic flow sheet of the floating process molding that the base plate glass of the low melting point colored glaze decorative flat glass of environment-friendly and energy-efficient is adopted.
From figure, the flow process of its moulding process is that the raw material of predetermined preparation is put into feeding warehouse, then from feeding warehouse, raw material is defeated
Deliver in the kiln of molten bath, enter molten bath and melted by predetermined temperature and discharged bubble, be followed by the molten mass of liquid, enter into
In molten tin bath (the protective gas station that the side of molten tin bath is provided with nitrogen hydrogen inputs protective gas in molten tin bath), on the stannum face of molten tin bath
Drop down flat, through drawing side, traction, form the smooth semi-finished product band of polishing, enter into annealing kiln from transition roller table and carry out cooling down, and
Obtain the cutting subpackage of preliminary dimension is entered on product, more cleaved panel sub-assembling platform, obtain the environmental protection section of high annealing temperature high intensity
The base plate glass semi-finished product of the low melting point colored glaze decorative flat glass of energy type.
Refer to shown in Fig. 3, be a kind of present invention colored glaze plate glass and preparation method to high annealing temperature high intensity
The side section of the state using floating process molding for the base plate glass of the low melting point colored glaze decorative flat glass of environment-friendly and energy-efficient shows
It is intended to.From figure, label 2 represents feed bin charging aperture, and label 3 represents feed bin, and label 4 represents the predetermined mixed material prepared,
(mixed material of the predetermined preparation shown in label 4 is thus transported to molten the molten bath kilneye in label 5 expression mixed material entrance molten bath
In the molten bath of tank furnace), label 12 represents float glass line matrix, and label 6 represents molten bath kiln, and label 7 represents the liquid molten in molten bath
Raw material body enters the guiding gutter of molten tin bath, and label 8 represents the molten tin bath of floating process, and label 9 represents the semi-finished product band being formed in molten tin bath
Enter the transition roller table of annealing kiln, label 10 represents annealing kiln, label 11 represents the cutting that moulded products carry out cutting packaging
Panel sub-assembling platform.
Refer to shown in Fig. 4, be that the size of a kind of present invention colored glaze plate glass and preparation method embodiment is 1220mm
The colored glaze material having printed predetermined three zone of × 2440mm forms one kind that top layer is predetermined colored glaze material pattern decorative layer
The floor map of colored glaze final sheet.From figure, label 1 represents a kind of base plate glass of colored glaze plate glass, mark
Number 21 oblique line portion represent the first zone colored glaze material pattern area of printing, and label 31 cross hairs part represents the second of printing
Zone colored glaze material pattern area, label 41 pore part represents the colored glaze material pattern area of tertiary color area of printing.
Refer to shown in Fig. 5, be that the size of a kind of present invention colored glaze plate glass and preparation method embodiment is 1220mm
It is about 0.1-1mm thickness that the colored glaze material having printed predetermined three zone of × 2440mm thickness about 2-5mm forms top layer
A kind of generalized section of the colored glaze final sheet of predetermined colored glaze material pattern decorative layer.From figure, label 1 represents a kind of
The base plate glass of colored glaze plate glass, label 123 represents the glaze having printed predetermined three pattern zone colored glaze material on upper strata
Pattern decorative layer.
Refer to shown in Fig. 6, be that the top layer of a kind of present invention colored glaze plate glass and preparation method embodiment is a kind of color
Glaze plate glass, the back side be after overlap edge without departing from the aluminium sheet of top layer silicate colored glaze ambetti size, by bonding
The composite board cross-sectional view of compound composition is mutually pasted in agent.From figure, label 13 indicates glazed colour layer
The low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of high annealing temperature high intensity, after label 14 represents overlap, edge does not surpass
Go out the aluminium sheet of the low melting point colored glaze decorative flat glass edge of the environment-friendly and energy-efficient of top layer high annealing temperature high intensity, label 15 table
Show predetermined binding agent.
Refer to shown in Fig. 7, be that the top layer of a kind of present invention colored glaze plate glass and preparation method embodiment is a kind of color
Glaze plate glass, the back side has that 2 sides each than top layer silicate colored glaze ambetti size more has stretched out 10-30mm distance
Aluminium sheet, mutually pastes the composite board cross-sectional view of compound composition.From figure, label 13 indicates glazed colour layer
The environment-friendly and energy-efficient of high annealing temperature high intensity low melting point colored glaze decorative flat glass, label 141 has 2 after representing overlap
While the low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of annealing temperature high intensity higher than top layer each more has stretched out 10-
The aluminium sheet of 30mm distance, label 15 represents predetermined binding agent.
Refer to shown in Fig. 8, be a kind of present invention colored glaze plate glass and preparation method embodiment be one using top layer
Kind of colored glaze plate glass, the back side is that have that 2 sides each than top layer silicate colored glaze ambetti size more has stretched out 10- after overlap
The aluminium sheet of 30mm, mutually pastes the composite board of compound composition, the precalculated position punching on 10-30mm extension
Afterwards, the vertical planar structure schematic diagram of metope screw installation can be carried out.From figure, label 13 indicates the high annealing temperature of glazed colour layer
The low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of degree high intensity, label 141 has 2 sides higher than top layer after representing overlap
The low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of annealing temperature high intensity each aluminum having stretched out 10-30mm distance more
Plate, label 16 represents the eutectic stippling of the environment-friendly and energy-efficient of the high annealing temperature high intensity in ratio top layer of back end aluminium sheet of composite board
Glaze decorative flat glass stretches out the screw installing hole in the edge of 10-30mm.
Now a kind of for present invention colored glaze plate glass and preparation method made its glass system with float glass process moulding technique
Product simultaneously print colored glaze decorative layer and form product, are described further, and its manufacture process includes following some steps:
[1], first, preparation raw material, calculates proportioning raw materials according to the various compositional range of glass of first embodiment.
[2], get out floating process as shown in Figure 3 includes raw material cabin, molten bath kiln, the stannum kiln containing tin liquor, Yi Jila
The facilities such as side machine, traction machine, transition roller table, annealing kiln cooling system, cutting panel sub-assembling platform are in interior float line.
[3], the production procedure of the floating process as shown in Fig. 3 and Fig. 2, pre- shown in the label 4 that [1st] step is prepared
The fixed compound prepared, the feed bin charging aperture shown in from the label 2 of Fig. 3, it is conveyed into shown in label 3 in raw material conveyer belt mode
In raw material cabin, then through the molten bath kilneye shown in label 5, the compound that [1st] step is prepared is sent to pre- shown in label 6
In the molten bath of fixed resistant to elevated temperatures molten bath kiln, progressively when the humidity province of the fusion temperature corresponding to each glass formula (for oxidation
Aluminium content is less than 30% situation, and fusion temperature can be in the scope of 1360 DEG C -1460 DEG C of temperature or 1460 DEG C -1680 DEG C
Interior) formed good fluidity liquid melting body, progressively discharge the bubble in liquid material through high-temperature region, that is, define and can enter
Enter the mobility preferable mixed material molten mass of molding procedure.
[4], shown in the production procedure of floating process as shown in Figure 2 and Fig. 3, make the flowable performance of [3rd] step relatively
Good mixed material molten mass, the jaws through the guiding gutter shown in label 7 for the molten bath kiln shown in from label 6, it is flowed into float glass process life
On the stannum face of molten tin bath (alternatively referred to as stannum kiln) shown in label 8 of producing line more flat through dropping down, draw leading of side and traction machine through edge machine
Draw, polishing on tin liquor face is thrown and put down, and after formation transition roller table shown in by label 9 for the semi-finished product band goes out stannum kiln, enters label 10
The annealing kiln cooling of the cooling down system of shown roller-way, enters back into the cutting panel sub-assembling platform shown in label 11, cleaved, point
Dress, you can the melting point of the as shown in Figure 1 glazed colour layer of 1-10 kind color on the present invention its base plate glass surface is obtained 540
DEG C -730 DEG C, this base plate glass comprises the one-tenth of silicon oxide, calcium oxide, magnesium oxide, aluminium oxide, ferrum oxide, titanium oxide, sodium oxide
Part, count as weight percents, in this base plate glass, the content of boron oxide is 0-3.9%, the content of sodium oxide is 0.01-
14%, iron oxide content is 0.01-5%, and the content of fluorine oxide is 0-2.8%, and titanium oxide is 0.0003-4.9%, and magnesium oxide contains
Measure as 8.1-22.2%, alumina content is 0.01-39%, and the content of its silicon oxide is 1.9 times -4.1 times of calcium oxide content,
The content of calcium oxide is 1.2 times -1.6 times of the content of magnesium oxide；The thickness difference of this base plate glass is less than 0.3mm；Its substrate glass
The water absorption rate of glass is in the range of 0-0.3%；The rupture strength of its base plate glass reaches 50-180mp；This base plate glass in viscosity is
100.5Temperature when (Pa Sec) is 1480 DEG C -1640 DEG C；Viscosity is 101Temperature when (Pa Sec) is 1410 DEG C -1600 DEG C；
Viscosity is 102Temperature when (Pa Sec) is 1180 DEG C -1340 DEG C；Viscosity is 103Temperature when (Pa Sec) be 1040 DEG C-
1220℃；The thickness difference of this base plate glass is less than 0.3mm；The water absorption rate of this base plate glass is in the range of 0-0.3%；This substrate
The annealing temperature lower limit (i.e. endothermic peak origin temp) of glass is in the range of 550 DEG C -710 DEG C；The anti-folding of this base plate glass is strong
Spend for 50-180mpa；The difference of the two ends numerical value at 150 DEG C -300 DEG C for the thermal coefficient of expansion of this base plate glass be million/
1.0- 3.0/1000000ths；The one kind being million/1.0- 2.8/1000000ths in the difference of 550 DEG C -600 DEG C of two ends numerical value
The base plate glass of colored glaze plate glass.
[5], by the low melting point of the environment-friendly and energy-efficient of the high annealing temperature high intensity of the no glaze pattern of the top layer shown in label 1
The base plate glass of colored glaze decorative flat glass sequentially enters the printing position on pipeline, by predetermined pattern requirement, successively using peace
Equipped with the colored glaze material printing equipment of predetermined first, second, and third zone printed patterns version, respectively white enamel is passed through first
It is high-strength that the printed patterns area shown in label 21 oblique line portion of zone printed patterns version is printed onto the high annealing temperature shown in label 1
The base plate glass top layer of the low melting point colored glaze decorative flat glass of environment-friendly and energy-efficient of degree；Deep orange colour glaze is passed through the second color
It is high-strength that the partly shown printed patterns area of label 31 cross hairs of area's printed patterns version is printed onto the high annealing temperature shown in label 1
The base plate glass top layer of the low melting point colored glaze decorative flat glass of environment-friendly and energy-efficient of degree；Shallow orange colour glaze is passed through tertiary color
It is high-strength that the partly shown printed patterns area of label 41 pore of area's printed patterns version is printed onto the high annealing temperature shown in label 1
The base plate glass top layer of the low melting point colored glaze decorative flat glass of environment-friendly and energy-efficient of degree；So far predetermined white, depth are completed
Salmon pink, the printing of three zone colored glaze material of shallow salmon pink, in operating procedure, control the printing of glaze layer to be about 0.1-
The thickness of 1mm.
[6], the pattern decorative of three zone colored glaze material formation of predetermined white, deep salmon pink, shallow salmon pink will be printed with
The base plate glass of the low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of high annealing temperature high intensity of layer, by pipeline
Enter into the roller kilns of glaze paint sintering circuit, low by the environment-friendly and energy-efficient that should be less than high annealing temperature high intensity known in the industry
The base plate glass of fusing point colored glaze decorative flat glass deforms under the process conditions of softening point temperature, makes silicate glaze to set
Different humidity province needed for different process, is progressively preheated and is heated up and fired, more cooled, you can be obtained as shown in Figure 4
Surface by white, deep salmon pink, three glaze zone of shallow salmon pink form pattern size be 1220mm × 2440mm thickness
It is annealing temperature lower limit within the scope of 550 DEG C -600 DEG C or 600 DEG C -650 DEG C, rupture strength for 2-5mm, thermal strain temperature spot
Reach the product of the low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of high annealing temperature high intensity of 50-160mpa.From Fig. 4
It can be seen that, label 1 represents that the low melting point colored glaze decoration of the top layer no environment-friendly and energy-efficient of high annealing temperature high intensity of glaze pattern is flat
The base plate glass of glass sheet, label 21 oblique line portion represents the first zone colored glaze material pattern area of printing, label 31 cross hairs
Part represents the second zone colored glaze material pattern area of printing, and label 41 pore part represents the tertiary color area colored glaze of printing
Material pattern area.And in terms of its section, be then as shown in figure 5, its label 1 represents the top layer no glaze pattern of about 2-5mm thickness
The base plate glass of the low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of high annealing temperature high intensity, in label 123 expression
Layer printed predetermined white, deep salmon pink, three zone of shallow salmon pink form patterns about 0.1-1mm thickness colored glaze material
Glaze pattern decorative layer.
The modification 1 of second embodiment
Low melting point colored glaze decorative plate glass to the environment-friendly and energy-efficient of the high annealing temperature high intensity of above-mentioned second embodiment
In the selection of the preparation method of the base plate glass of glass, the following process adopting can also be selected to carry out, such as:
Also may be selected 1, adopt horizontal drawing technique: to formed flowable molten mass carry out there be drawing of horizontal drawing technology characteristics
Thin, molding, annealing, cooling, cutting make, then through glaze and the sintering of bedying, the environment-friendly and energy-efficient of high annealing temperature high intensity are obtained
Low melting point colored glaze decorative flat glass base plate glass；
Or also may be selected 2, adopt lattice-method process: the flowable molten mass being formed is adopted lattice-method process molding,
Annealing, cooling, cutting make, then through glaze and the sintering of bedying, the low melting point of the environment-friendly and energy-efficient of high annealing temperature high intensity are obtained
The base plate glass of colored glaze decorative flat glass；
Or also optional 3, adopt calendering technology: the flowable molten mass being formed is pressed using calendering technology
Prolong, molding, annealing, cooling, cutting make, then the environment-friendly and energy-efficient of high annealing temperature high intensity through glaze and the sintering of bedying, is obtained
Low melting point colored glaze decorative flat glass base plate glass；
Or also optional 4, adopt press over system technique: the flowable molten mass being formed is entered using press over system technique
Under row draws, molding, annealing, cooling, cutting make, then the environmental protection section of high annealing temperature high intensity through glaze and the sintering of bedying, be obtained
The base plate glass of the low melting point colored glaze decorative flat glass of energy type；
The modification 2 of second embodiment
Colored glaze pattern decorative layer on its product surface, is by arranging 2-100 set, often covering by 1-10 plane net
The monolith articles printing equipment unit that print or roll printing device or ink jet printing device are formed, in the way of parallel configuration, to institute
State the surface of the base plate glass of low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of high annealing temperature high intensity, carry out coloured silk
Glaze prints, then carries out glaze sintering circuit, and the obtained 2-100 block product surface that makes in same batch production of articles produces
Every piece of default different printing pattern having 1-10 kind color or a kind of colored glaze final sheet of color glaze decorative layer.
The modification 3 of second embodiment
Contain in the glaze of its product surface decorative layer or corundum crystal or quartz crystal or cacoclasite crystal or
Nepheline crystal or merwinite crystal or akermanite crystal or mullite crystal or diopside crystal or wollastonite crystalline substance
Body or willemite crystal or cordierite crystal or monticellite crystal or enstatite crystal or brilliant containing crystalline lithium or point
Stone crystal or rutile crystal.
The modification 4 of second embodiment
The composite plate of its product be by a kind of colored glaze final sheet (1) and bonding material layer (2) and 0.1-1mm or
The sheet metal (3) of 1-5mm thickness is combined composition.
The modification 5 of second embodiment
The 2-4 bar side of the metallic plate in back end face of the composite plate of its product, a kind of top layer colored glaze flat board glass of proportion poststack
The edge of glass product has stretched out the distance of 10-30mm.
The application of the present invention and the feature being different from prior art:
Low melting point colored glaze decorative plate to the environment-friendly and energy-efficient of high annealing temperature high intensity according to embodiments of the present invention
Glass, that is, its fundamental difference with prior art, then induction and conclusion is as follows:
The technical scheme that the present invention has novelty in flat board colored glazed glass field is: the 1-10 kind on its base plate glass surface
At 540 DEG C -730 DEG C, the base plate glass of its product is characterised by the melting point of the glazed colour layer of color: this base plate glass comprises oxygen
SiClx, calcium oxide, magnesium oxide, aluminium oxide, ferrum oxide, the composition of sodium oxide, count as weight percents, oxygen in this base plate glass
The content changing boron is 0-3.9%, and the content of sodium oxide is 0.01-14%, and iron oxide content is 0.01-5%, the content of fluorine oxide
For 0-2.8%, content of magnesia is 8.1-22.2%, and alumina content is 0.01-39%, and the content of its silicon oxide is calcium oxide
1.9 times -4.1 times of content, the content of calcium oxide is 1.2 times -1.6 times of the content of magnesium oxide；The thickness of its base plate glass is poor
Less than 0.3mm；The water absorption rate of its base plate glass is in the range of 0-0.3%；The rupture strength of its base plate glass reaches 50-180mp；
The annealing temperature lower limit (i.e. endothermic peak origin temp) of its base plate glass is 550 DEG C -710 DEG C.
The present invention have annealing temperature lower limit (i.e. endothermic peak origin temp) with existing calcium sodium plate glass is different must
550 DEG C of -710 DEG C of properties that must be higher, and can preferably 600 DEG C or 650 DEG C or 700 DEG C of annealing on the premise of economy
Lowest temperature (i.e. endothermic peak origin temp), the present invention is a kind of component invention first, for colored glaze plate glass, exists first
In the fusion temperature of the glazed colour layer of 1-10 kind color of the present invention have selected 540 DEG C -730 DEG C of scope, and must be matched
Plate glass have the new property feature different from prior art plate glass of following level.
First, for the plate glass of all prior arts under glazed colour layer it is important that using a kind of to aluminum,
Silicon, calcium, magnesium, ferrum, the selection invention of the compositional ranges of sodium and between silicon, calcium, magnesium composition, the proportionate relationship of these technology essential factors
The technical scheme changing invention be silicon: calcium is 2.0-4.1, calcium: magnesium is 1.2-1.6 times of scope, and all of prior art
Plate glass, two end values of an a minimum of factor proportion relation, outside the scope of the invention, that is, above-mentioned the wanting of the present invention
The selection of plain proportionate relationship, within the close limit of all prior arts, has novelty.And the glazed colour layer in the present invention is put down
It was found that newly following product properties in glass sheet purposes, in technique, create following unforeseeable technique effects.
Second, present invention is disclosed the invention type of the new property conversion new application of the product finding, being also to create
Unforeseeable effect (i.e. by various plate glass processing methods, in terms of new plate glass purposes, [1] that can produce
The outstanding new viscosity temperature in different process stage and product, [2] thickness is poor, [3] water absorption rate, [4] rupture strength, and [5] can
See transmittance, [6] percent ripple, the plate glass new property such as [7] thermal linear expansion coefficient feature, new application feature).
Especially in new application, present invention finds the new reduction of the product that prior art never disclosed is glued
Degree temperature and congruent melting volume property, melting process stage viscosity temperature, homogenizing, row's bubble, clarification process stage viscosity temperature, especially
Control the flatness of percent ripple or thickness is poor, the moulding process stage viscosity temperature drawing thin (or the polishing in floating process) technique
Degree.
(a), overcome due to one of new discovery of property of product conventional art prejudice generation to flat board calcium soda-lime glass
Sodium oxide technology a kind of invention of omitting elements: the plate glass of prior art, almost all of more than 99.9% build glass
Glass, general industry glass, its all sodium containing 13% about, it is mainly used to flux, especially silicon composition is fluxed, form each work
The reduction that viscosity can be controlled in skill stage.But technical scheme and the new property of the product finding, have broken this
Technology prejudice, can be invented due to the change of the element relationship between silicon, calcium, magnesium, in the purposes of plate glass, the product of generation
Product new property, when sodium content is within 0-1%, can be more viscous than several operation stages of the high sodium plate glass of prior art
Degree temperature is low 150 DEG C -250 DEG C, and this will produce a large amount of energy-conservations and be conducive to high-quality to control product thickness poor, percent ripple, and molten
The defect such as bubble rate of the plate glass calculus of the bad generation of metallization processes, quarrel point and row's bubble bad generation of technique is it is particularly possible to big
Width lifting has certain requirements the quality of as ultra-thin plate glass in the lcd display of 0.5-1.1mm, reduce quarrel point, calculus rate,
Bubble rate, the unqualified thickness rate of reduction and unqualified percent ripple rate.
In operation, if once producing the defect of any one operation stage, prior art is operationally for prior art
All it is easy to increase the mode of the temperature of each operation stage to solve, but this just easily occurs making molten bath to collapse top very much, greatly shortens use
Life-span.And the invention provides one is advantageous to manipulate the viscosity adjustable extent of the technology manipulation of technique.Fundamentally solve
The product property (" material " said in the industry) of existing sodium (high sodium) plate glass " material property is short " that insider thinks always
Technical barrier.
(b), due to the new property of product discovery two, overcome the prejudice of conventional art, create to alkali-free boron glass
A kind of omitting elements invention of " boron oxide " technology essential factor of glass: the existing alkali-free boron flat board glass being particularly useful for liquid crystal display
Glass, its due to the sodium more than 1% can not be contained, the boron composition employing 8-15% content to make flux composition, have think non-such as
The technology prejudice of this side's row, especially forms and silicon is fluxed, the viscosity of each operation stage of plate glass can form high-quality
The reduction of temperature controls, and the annealing temperature lower limit (i.e. endothermic peak origin temp) that base plate glass can be produced reach 600 DEG C-
730 DEG C of technique effect.But technical scheme and the new property finding, have broken this technology prejudice, can be due to
The change invention of the element relationship between silicon, calcium, magnesium, in plate glass purposes, produces new product property, is not aoxidizing
When Boron contents or only 0-1%, the annealing temperature lower limit (i.e. endothermic peak origin temp) of base plate glass not only can be made to reach 600
DEG C -730 DEG C, can also be than prior art with the viscosity temperature of the product of the boron of 8-15% content, than existing alkali-free boron glass
Several operation stages of plate glass are low 250 DEG C -350 DEG C, and this will form an a wide range of control technique and reach control
The new technology platform of product quality, compares prior art glass, can reach that higher level thickness is poor, percent ripple level and several
Bubble-free, no quarrel point, the no yield rate of the ultrathin products of 0.5-2mm thickness of the quality requirements of calculus defect, quality product rate, especially
It is for aerofluxuss bubble and clarification, homogenizing process stage and molding, draws the viscosity of thin operation stage, both provide a kind of than existing
There are the much better technology controlling and process scope of technology and technology controlling and process platform.
The silicon of the present invention, calcium, the technical scheme of the proportionate relationship change invention of magnesium key element, overcome prior art and only pass through
Aluminum or boron composition increase just to have and produce the technology prejudice that annealing temperature lower limit (i.e. endothermic peak origin temp) rises.The present invention is above-mentioned
Technical scheme can produce the annealing temperature lower limit (endothermic peak origin temp) when boron and aluminum are less than less than 1% and also can rise 100
DEG C about, and when sodium content is less than less than 2%, annealing temperature lower limit (endothermic peak origin temp) also has bigger rising
(seeing attached list sample example).If certainly alumina content is also added on above technical scheme again, can be formed further again
Make the technique effect that annealing temperature lower limit (i.e. endothermic peak origin temp) rises.Make up to the core of the present invention low cost,
The Property requirements of high annealing point.
(c), (1), the present invention a kind of in the existing calcium sodium plate glass accounting for plate glass total amount more than 99%
A kind of above-mentioned omitting elements invention of 13% sodium content creates and the annealing temperature lower limit of base plate glass can be made (to absorb heat
Peak origin temp) it is 610 DEG C -710 DEG C and be preferably 650 DEG C -680 DEG C of product property, and present all flat board calcium soda-lime glass
Annealing temperature lower limit (i.e. endothermic peak origin temp) be only 490 DEG C.And the alkali-free (or only sodium of 0.01-1%) of the present invention
The annealing temperature lower limit (i.e. endothermic peak origin temp) of the no plate glass of boron is 610 DEG C -710 DEG C, because the skill by the present invention
Art scheme magnesium is minimum to be 8.1% (typically up to 12-18%), and calcium is minimum to be 9.6% (generally 15-18%), and this composition is base
The main cause that the annealing temperature lower limit (i.e. endothermic peak origin temp) of glass sheet is substantially increased, can be than common existing flat board calcium
The annealing temperature lower limit (i.e. endothermic peak origin temp) of soda-lime glass exceeds 120 DEG C -200 DEG C, and this is another new product
Matter find that this is particularly significant on the technique effect of colored glazed glass of the present invention, just because of the annealing of existing calcium sodium plate glass
Lowest temperature (i.e. endothermic peak origin temp) is only 490 DEG C, if so the sintering of inorganic colored glaze will be made, a kind of selection is as now
Mosaic glass, can only make the fritter of 2-5cm size, and the lower low temperature glaze of use cost (fusing point is about), its area is little,
Double annealing is less demanding, does not just split.
(2) if wanting the second selection, making 10cm, 20cm and let alone making 60cm × 60cm's or more large scale,
Double annealing is extremely difficult, and rupture rate is high, and prior art and market always successfully occurred less than the big production of product.Big chi
Very little all use organic resin typography, its have necessarily become out of doors normal complexion be combined with glass will not problem well, cannot again
Bond as ceramic tile, because glue for tile can corrode color resin, also glue insecure.The plate glass of prior art can not possibly be used
The sized products of gently, thin glass colored glaze flat board, substitute the thick and heavy tile product of high energy consumption.
(3), the 3rd select be using existing 490 DEG C about fusing points glaze (note: ceramic tile glaze fusing point 950 DEG C-
1200 DEG C), such as make the little lines of normal cup, applique product on bottle, minimum area accounts for refutes using high, no
May using in a large number, not having ornament materials large area, large-tonnage economy can say, so there is no the example of any application.
(4) and the 4th is chosen as using existing alkali-free boron plate glass, that is, due to the glass of liquid crystal display, its
Prior art production cost is high, existing about 300,000 yuan/ton of market price, if 0.7mm thickness to reach 600 yuans/m2,
What pdp plasma glass 1.8-2.8mm was thick also reaches 1000 yuans/m2, so while the annealing temperature lower limit of its glass is (i.e.
Endothermic peak origin temp) 580 DEG C -680 DEG C or 700 DEG C can be reached, can be with there being 600 DEG C -650 DEG C of economy of fusing point
Glaze, but the cost of its glass may not have the substrate as ornament materials, substitutes Ceramic Tiles, even up to holds Ceramic Tiles
Economic feasibility.And a kind of newfound annealing of the plate glass of omitting elements invention of the above-mentioned no boron alkali-free of the present invention
Lowest temperature (i.e. endothermic peak origin temp) is up to 600 DEG C -730 DEG C, and Financial cost can be had as previously described low, and
The big mode of production of quality better, yield, produces the glass substrate of the present invention, again can using have 600 DEG C of economic feasibility-
730 DEG C of colored glaze material come to be combined produce.So this be a kind of have unforeseeable technique effect solve replacement pottery
Brick, the people solving existing ornament materials thirst for solving the difficult problem without solving for a long time.
(5) although it will be clear that increase calcium, magnesium content as reach 19-50% (containing only the common 10- of calcium+magnesium
12%) the calcium soda-lime glass exceeding prior art, it is convenient to omit boron composition can be so that the annealing temperature lower limit of glass (absorbs heat
Peak origin temp) significantly rise, and there is sodium oxide to reach 2-13% and also can significantly rise, simply than the product of no sodium or low sodium
Annealing temperature lower limit (i.e. endothermic peak origin temp) rise smaller, but be not to say that the composition adding calcium and magnesium just can reach
The purpose of production, because also will must simultaneously have the work being appropriate to the especially relatively low viscosity temperature of aerofluxuss bubble of plate glass
Skill condition.The plate glass of prior art, if only increasing the content of calcium and magnesium, rather than have the silicon of the present invention, calcium, magnesium it
Between mutual proportionate relationship be exactly that to increase its viscosity temperature of calcium-magnesium content still can be higher than the present invention 150 than all prior arts
DEG C -300 DEG C, and such as alkali-free boron plate glass, it adds the flux boron composition of 8-15%, just only adds 8-10%'s
Aluminium oxide, is 10 in viscosity2Row when (Pa Sec) steeps up to more than 1500 DEG C of the temperature of technique it is necessary to use a kind of shallow pool
The high platinum row of (depth of metal only 5-10cm) steeps passage to complete aerofluxuss bubble operation, and produces only several tons daily.So
Its low viscosity with the present invention, have a high technical scheme of annealing temperature lower limit (i.e. endothermic peak origin temp) can be with several again
Hundred tons of daily output technique productions (row's bleb district pool depth reaches 70-100cm) compare, and its quantum of output differs from tens times, and will reach
Large-tonnage production capacity of the present invention, will go up tens lines, and invests many tens times of meeting.Namely say, solving annealing temperature lower limit
The rising of (i.e. endothermic peak origin temp), is allowed in accordance with various display plate glass and colored glaze and the plate glass such as fire-proof and explosion-proof
Requirement, an existing incision technology plate glass, or simply increase the technical scheme that calcium+magnesium reaches 20-50%, rather than take this
The change invention of bright factor proportion relation, the technical scheme of selection invention, are all to take into account cost and annealing temperature lower limit
The unforeseeable combination technique effect of (i.e. endothermic peak origin temp).
(6), it produces unforeseeable technique effect be not only in that can be in no sodium or the low aluminum of boron and the present invention of high alumina
Annealing temperature lower limit (the i.e. endothermic peak origin temp) property of product and at 150 DEG C -300 DEG C and at 600 DEG C -650 DEG C or 680 DEG C
Linear expansion coefficient value, high-quality, low cost, high tens times of production efficiencys etc. can be also had completely to reach with taking into account simultaneously
Produce the technical requirements of high-quality flat board colored glazed glass and form more preferable Financial cost target.
(d), due to product new product property discovery four, the one kind overcoming classic flat-plate glass thinks increasing
Aluminium oxide necessarily leads to the technology prejudice that viscosity temperature is substantially increased.As prior art calcium soda-lime glass, 1% about can only be added
Aluminium oxide, and existing alkali-free boron plate glass, also general adds 8% about aluminium oxide to improve strain point, has just added
A viscosity temperature of very high each stage process can be made it is impossible to control the QT Quality Target that technique should reach higher.It is also considered as
Aluminium oxide cannot be added to 25-30%, to improve product strength under controlled process conditions that can be inexpensive.But this
Bright technical scheme and the new flat glass product property finding, have broken this technology prejudice, the present invention in not boracic, no
Containing sodium, not fluorine-containing composition when (during 0-1%), alumina content be when 3.1% or 16% or 20% or 25% about big across
During degree change, prior art thinks that viscosity can be substantially increased, but the change of the viscosity temperature of the present invention is only it is simply that aluminium oxide is
When 30% about, viscosity temperature also only rises 80 DEG C about (seeing attached list 1 11 sample examples).
And viscosity temperature also lower 100 DEG C than the flat glass product adding 13% sodium oxide or 8-15% boron oxide-
200℃.This demonstrate that silicon in technical scheme, calcium, the inventive technique side of the factor proportion relationship change scope of magnesium
Case, can produce a kind of new product property, here it is a kind of new high-alumina contains with aluminium oxide in 25% or 30% content
Amount aluminum, silicon, magnesium, the congruent melting volume property of calcium, can produce high aluminium content the unforeseeable technique effect of low viscosity temperature and
And then the unforeseeable technique effect of the high product high intensity producing.
The present invention especially because when the content that can increase aluminium oxide reaches 19-28%, intensity up to about 140-160mpa or
180mpa, is much higher than 2-3 times of various prior art plate glass intensity, and due to viscosity temperature also compared with prior art only
Low 150 DEG C -250 DEG C during 1-25% alumina content, if so technical solution of the present invention forms the viscosity of alkali-free high boron glass
When, that should also be equivalent to the larger sky adding the viscosity space that can dissolve to 29-39% for the aluminium oxide and intensity rising
Between (rupture strength of this specification and embodiment of the present invention glass, by sample being cut into the little bar of 50mm × 50mm × 5mm,
Using rupture strength instrument, measure by standard gb/t3810,4-2006.).The alkali-free high boron product of prior art, because boron oxide becomes
The volatilization process of part, can cause the inequality of composition, the material network structural damage making aluminium oxide participate in, and largely effect on due strong
Degree.This is also intensity poor major reason during alkali-free high boron glass aluminium oxide containing 7-15%.
So the present invention when having high aluminium content and no Boron contents, can produce the anti-folding of 90-145mpa or 145-180mpa
Intensity, and have concurrently more energy efficient, processing range that is more inexpensive and having bigger viscosity temperature, this is all colored glaze flat boards present
Glass make less than, and the present invention also can melt in melting process viscosity temperature stage control, overcomes calculus and prevents do not have
Have the quarrel point being melted, when clarifying and control molding the thickness of plate glass poor (because viscosity is lower, the putting down of this operation stage
Glass sheet product is more soft more scope that have control, otherwise viscosity is higher, and this operation stage flat glass product is harder, more not fortunately
Pull, horizontal drawing or calendering or float glass process drop down flat, draw thin, polishing etc. operation stage control thickness difference and percent ripple).
Above-mentioned preferably with the quality of prior art and also intensity can reach higher than existing plate glass 2 times, this
Plant the new discovery of product property and generation, make the component invention with glazed colour layer create reaching of the thickness that can produce 1-2mm
This product invention flooring product of the metope product of intensity and 2-3mm thickness, the exterior wall cladding 12mm to the national standard of existing pottery
The high intensity of flooring product of thick product and various other 10mm thickness, lightening replacement, produce the energy, resource, logistics, storehouse
The unforeseeable effect of several times of saving work of storage.
(e), due to employing the invention that a kind of technology essential factor is omitted, to prior art such as alkali-free boron glass, Er Qie
Can be on the premise of the poor quality control of more more preferable calculus than prior art, quarrel point, bubble rate, flatness degree, thickness, in technique
Temperature do not rise before reduce and energy-conservation on the premise of, save omit boron composition, can have plate process fusing, row bubble, molding,
The better properties drawing thin each stage and the rupture strength property that more aluminium oxidies can be added and produce, and unforeseeable right
Flat faced display alkali-free boron glass can be added without the boron composition of 8-15%, and ensure that bubble rate is high-quality, flatness, thickness are poor,
The guarantee of the product quality of percent ripple, can solve prior art alkali-free boron glass process units can only add platinum with press over system technique
The technology prejudice of the technique of golden passage, more highest is to adopt floating process, is ensureing that thickness is poor, flatness, percent ripple
Quality under the premise of, can be with improve production efficiency decades of times, can be with tens times of investment reduction, the expectation that 20 times of Economization on land Factory Building
Less than effect.So cost is greatly reduced, it is the component invention of colored glaze plate glass of the present invention, limit (i.e. at an annealing temperature
Endothermic peak origin temp) can as the alkali-free boron display glass of prior art in accordance with the big production of colored glazed glass premise it
Under, and produce the colored glaze base plate glass of new property, thus substantially reducing cost, produce unforeseeable economic feasibility
The unforeseeable effect of technical foundation generation.
Third, due to the announcement of the property of new the said goods and discovery, overcoming above-mentioned multiple prior art prejudice,
In various architectural decoration colored glaze plate glass fields, (1) that creates following unforeseeable technique effect is due to viscous
Degree temperature property define can be lifted well and control the molten quality of technique, bubble quality, flatness, thickness difference and
The technique effect of percent ripple quality；(2) unforeseeable due to viscosity temperature decline more than 200 DEG C of energy-conservation 30% about
Effect；(3) unforeseeable due to congruent melting volume property add substantial amounts of aluminum (being added to 25% or 25-30% from 1%), generation strong
Degree rises 2-3 times of technique effect；(4) due to intensity rises thus producible colored glaze plate glass can frivolous 2-3 times of section
, can economize on resources, save logistics, the unforeseeable technique effect of 2-3 times of storage；(5) the new technique effect of the present invention also exists
In due to can be used in ornament materials plate glass opaque or that transparency is not high increasing on iron oxide content, permissible
Save the high-quality frit resource of increasingly minimizing, major glass cost of material declines 10 times.Conventional art thinks that iron-holder is high
The raw material of some affects the defect that glass produces blue green, but the present invention can lift intensity 2-3 times in plate glass,
So can be thin 2-3 times, light transmittance can rise on the contrary, and blue greenness is less obvious on the contrary, does not affect colored glaze glass transparent and upwards
The use of glass.And colored glaze towards upper when, more can use the big Radix Achyranthis Bidentatae of equivalent high iron material, more do not mind transparency, more can save
The about raw material of various medium levels of glass and resource, greatly save cost.So this component invention is to produce a kind of expectation
Less than light, thin, high intensity, greatly save the colored glaze plate glass of the high-end resource of glass, the resultant effect of the cost that economizes in raw materials
Product.This be other prior arts do not reach existing high intensity, the light not only thin, resource that not only economizes in raw materials but also greatly save former not only
The technique effect of 10 times of cost of material.(6) due to employing the invention that a kind of technology essential factor is omitted, to prior art such as alkali-free boron
Glass, and can the poor quality control of more more preferable calculus than prior art, quarrel point, bubble rate, flatness, thickness premise
Under, before technological temperature does not rise reduce and energy-conservation on the premise of, save omit boron composition, can have plate process fusing,
Row's bubble, molding, the better properties drawing thin each stage and the rupture strength property that more aluminium oxidies can be added and produce, and in advance
The boron composition that flat board alkali-free boron glass can be added without with 8-15% unexpectedly, and ensure that bubble rate is high-quality, flatness, thickness
Difference, the guarantee of the product quality of percent ripple, can solve prior art alkali-free boron glass process units and can only use press over system technique
Plus the technology prejudice of the daily output of the platinum channel only technique of 6-8 ton, more highest is to adopt 400-800 ton big ton made in Japan
Position such as float glass process, horizontal drawing, calendering etc. technique, ensureing that thickness is poor, under the premise of flatness quality, can be several with improve production efficiency
Ten times, can be with tens times of investment reduction, the unforeseeable effect of 20 times of Economization on land Factory Building.Technical solution of the present invention with existing
All plate glass or colored glaze plate glass Technical comparing, have and always do not have revealed and disclosed new property, and this
Planting property is to speculate it is impossible to predict with reasoning out in advance, and it is inclined to overcome the technology of traditional plate glass technology
See, solve the above-mentioned significant problem that people thirst for solving in the industry, technique effect creates " matter " and " measuring " change of the two
Change, technical scheme right and wrong being described it will be apparent that having prominent substantive distinguishing features, there is significant technological progress, there is wound
The property made.
(f), because inventive article can sinter glazed colour layer below 700 DEG C it is possible to sinter printing glaze layer, Ke Yi
Glaze layer adds the substantial amounts of quartz of various crystal especially low cost as 30-80% or diamond spar crystal powder or grain, forms history no
The wearing coat high rigidity (hardness up to 7 grades for the quartz, and add diamond spar then up to 9 grades of hardness) of the 0.2-3mm of precedent, and this
Production of Ceramics is made less than because the firing temperature of pottery is at 1100 DEG C -1200 DEG C, the now quartz of ceramic surface or steel
Jade can only become glass phase, and below 730 DEG C, quartz or diamond spar crystal also can keep crystalline phase, and it is unmatched that this just can form history
The quartz crystal hardness of the ambetti polishing of example reaches 7 grades of wear-resistant surface top layers or corundum crystal hardness reaches 9 grades of wearing coat, right
Pottery or the wearability of stone material, zero water absorption rate, zero soil pick-up rate, high slip, are revolutionary challenging (anti-skidding can be used for
Bathroom, kitchen surface, subway, harbour and the big public place ground of all flows of the people), wherein quartzy top layer because of 7 grades of hardness is
Can polish, become optimum top layer quartz glaze paint combination polishing high abrasion goods, and the 9 of diamond spar grades of hardness are to polish
, but it is anticipated that becoming optimum durable anti-skidding or wear-resisting diamond spar glaze paint component invention product less than ground, so energy of the present invention
The wear-resisting replacement upgrade technique of formation energy-conserving and environment-protective, inexpensive high-quality.And can be to the highly energy-consuming of ceramics, high pollution, Gao Fen
Dirt discharge, high water consume, low output, inferior product and whole equipment process system propose substituting challenge.
G (), the present invention can make 0.5-5mm ultrathin, the state processing in the surface stress not carrying out tempering
Under, what rupture strength reached 50-180mpa is preferably the ultrathin type high annealing temperature high intensity of 90-145mpa or 145-180mpa
The low melting point colored glaze decorative flat glass product of environment-friendly and energy-efficient, and with its be used for and thin layer metallic plate be compounded to form new
Composite board, with the purpose of light, thin, high intensity decorative effect, reaches and meets more preferable feature use demand.
But also can be using the high annealing in the top layer of the 2-4 bar side proportion poststack of bottom-side metal sheet material making composite board temperature
The edge of the low melting point colored glaze decorative flat glass of environment-friendly and energy-efficient of degree high intensity has stretched out the distance of 10-30mm, stretches at this
The edge going out directly hammers into body of wall or the metope application with the hard-wired innovation of wall body keel frame using screw after being punched
Simplicity mounting means, the breakage rate that makes to fracture substantially reduces, and has new product property existing good unforeseeable technology again
Effect.
H a kind of (), present invention colored glaze plate glass, the thickness of the base plate glass of its product is 0.3-1.8mm.Particularly lightweight
Thin, it is particularly suitable for metope and use, special energy-conservation, and also equipment output capacity is high.
I a kind of (), present invention colored glaze plate glass, the thickness of the base plate glass of its product is 1.8-20mm.Intensity is high, fits
Close ground, the exterior wall of especially super large plate uses product.
J a kind of (), present invention colored glaze plate glass, in the composition of the base plate glass of its product, the content of aluminium oxide is 19-
When 39%, product strength highest, the special product that especially suitable high intensity requires.
The decorative effects such as the senior imitative stone material in colored glazed glass of the invention described above technical scheme, imitation wood material simultaneously have relatively low one-tenth
The discovery of the various new property on the premise of this, produces unforeseeable technique effect, especially solves people in building dress
Exterior material industry thirsts for major technique great difficult problem that is solving and having not been successful for a long time:
First, in annual over ten billion m produced per year in the whole world2Ceramic Tiles and sheet material in.Ceramic brick product whole year has 30 every year
Hundred million m2For metope market.But the thickness of its product is in 8-15mm, indoor wall for 8-10mm, outdoor 12-15mm.And this
Printed patterns (no matter the monochromatic or 2-10 kind color) product of invention, can make the product of 0.5-1.5mm, can make ceramic wall
Lightening 6-10 times of face product.
Ceramic brick product ground market has about 7,000,000,000 m every year2For ground market.But the thickness of its product is in 9-12mm.
And colored glaze printed patterns (no matter the monochromatic or 2-10 kind color) product of the present invention, because intensity is up to ceramic three times, so only
3-4mm is wanted just to have the same intensity.Wherein, transparent glass one side is placed on surface, the effect of print colored glaze pattern is with regard to phase behind
When in existing glazed tile (adding layer of transparent glaze on ceramic pattern surface, re-polishing forms a glass glaze).The whole world has 10
Hundred million m2Yield.The Antique Imitation Tiles forming one layer of colored glaze pattern in glass surface, being equivalent to pottery of the wherein present invention, the whole world is every
Nian Youyue 3000000000 m2Yield.Wherein the surface low-temperature sintering in glass of the present invention forms one layer of colored glaze containing crystal such as quartz etc.
Layer, re-polishing, (but quartz content crystal of the present invention reaches 50%-60%, abrasion resistance, hard to be equivalent to the polished bricks of pottery now
Degree, antifouling property are well more a lot of than ceramic polished brick), the whole world has 3,000,000,000 m every year2Left and right.Namely say, the high annealing temperature of the present invention
The low melting point colored glaze decorative flat glass of the environment-friendly and energy-efficient of high intensity can make annual 6000000000-100 hundred million m2The falling of ceramic product
Production technology changes afterwards.
[1], can be thin 6 times than furring tile with the invention described above product, can be thin 3 times than floor tile.This just can solve
Thirst for the light-weighted resource that economizes in raw materials solving before Ceramic Tiles industry for a long time, save oil, electric energy, reduce carbon emission and powder
An industrial strategy difficult problem for dirt discharge.Namely say, the present invention can make annual 10000000000 m of building decoration pottery2And by annual 10% with
The industry of upper growth saves material 70%-80% in production link, energy-conservation 70%-80%, reduces carbon emission 70%-80%.
If (according to calculating the change that global technological equipment presses the floating process of the present invention, three Yangtze River Gorges of year can be saved
The energy consumption of the generated energy in power station)
[2], due to large-sized light sheet such as 2400 × 1200mm or 3000 × 1800mm can be produced into, can also replace
Generation many metopes and finishing aluminium sheet or standard-sized aluminium-plastic panel, save bauxite resource, and the resource of the present invention compare bauxite resource
How tens thousand of times of reserves, cost is also much lower, and product is again more resistant to corrosion, more smooth well-pressed, more has pattern decorative representability, Ke Yiyin
Brush the patterns such as all stone materials, wood grain.And the present invention is also than ceramic wafer, slabstone, aluminium sheet, aluminium-plastic panel side on metope installation method
Just, low cost.
[3], due to can under the secure performance condition of intensity, adopt all potteries existing and glass make less than have again
The product of the 1-2mm thickness of programmable wood grain, bag and color, for American-European and Australia, Russia, East Asia, South Asia wood
Veneer on the plank of the exterior wall in the house of matter structure, the non-bearing metope substituting brick and cement analysis reaches top grade, fire prevention, gently
The effect that thin and sun-resistant, sleet corrodes, and for wooden structures metope upstairs, there is magnificent attractive in appearance and frivolous waterproof
Effect also have new use value.
(2), for the ambetti of prior art, it is due to can only make colored glaze substrate with present common calcium soda-lime glass
Selection, but its annealing point is at 490 DEG C about, and can not can manufacture less than 480 DEG C of glaze and (first must be introduced into
Substantial amounts of lead has severe toxicity, and two is high by cost), so can only print on the glass Bo Saike below 5cm size (because its chi
Very little minimum, be difficult to burst in annealing), so never producing the printing inorganic glaze glass plate of oversized dimensions in history.In addition have
With tempering technology in 750 DEG C of -830 DEG C of glaze melt above, annealing stress is solved the problems, such as using reinforcement process.But this kind of product chi
Very little specific, not cleavable, do not adapt to require in decorative engineering application, and the intensity difference of calcium soda-lime glass is it is impossible to make ground
Application.
And the technology of the present invention, [1] is due to can make base plate glass annealing temperature lower limit (i.e. endothermic peak origin temp) preferably
Rise to 600 DEG C or 650 DEG C or 730 DEG C, exceed 150 DEG C -200 DEG C than calcium soda-lime glass, but swollen due to having very excellent heat
Swollen linear character, that is, near annealing point, warm area expansion changes very little, so, first, can be using fusing point at 540 DEG C -730
DEG C glaze (this glaze is different from less than 480 DEG C of glaze, and this glaze highly can not produced greatly with cost, and does not have assorted
Environmental issue), sinter the fine pattern of printing under annealing point temperature.So without taking double annealing technique so that it may
Produce the conventional various on-gauge plates of the decorative panels such as 2400 × 1200mm, 3000 × 1800mm or stone material or glass unprecedentedly
The fine colored glaze bag of size, grain pattern product, and product can arbitrarily be cut by construction requirement size, the present invention
It is the formation of standard size order, production, supply and sales, logistics, the full-range convenience of cleavable construction, high efficiency and low cost
Feature.[2] because the present invention can be higher than the intensity of the calcium sodium plate glass of prior art and ceramic wafer, the about 50mpa of brick
Go out 2-3 times, you can preferably up to 90-145mpa or 145-180mpa.So product can be obtained 2-3 times of book, and have same strong
Degree.Especially substitute ceramic product, this be all colored glaze agates existing hold high up gram or tempering colored glazed glass make less than.
(3), because inventive article can be permissible in 540 DEG C of -730 DEG C of agglomeration glazes it is possible to sintering printing glaze layer
Add the substantial amounts of quartz as 20-65% or corundum crystal powder or grain, the abrasion-proof gauge of beyond example formation 0.2-3mm in glaze layer
Floor height hardness (reaches 7 grades), and this is to make less than because the firing temperature of pottery is at 1100 DEG C -1200 DEG C, now making pottery in pottery
The quartz on porcelain top layer can only become glass phase, and at 600 DEG C, 650 DEG C, 700 DEG C, quartz or corundum also can keep crystalline phase, and this is just
Beyond example can form the quartz-crystal dignity top layer of ambetti polishing, or non-polished surface forms the wear-resisting antiskid of corundum crystal
Layer, to pottery and [1] anti-wear performance of stone material, [2] non-skid property, [3] especially surface of polished almost zero water absorption rate and pole
High antifouling property, [4] high intensity and ultra-thin performance, [5] ultralight super large plate face product size feature, [6] upper wall and cladding side
Formula etc. defines the technological progress of six great revolutions, and insider both knows about, and the dust of glass melting compares ceramic
Make technique and will lack tens times, and the generation of waste material will lack hundreds of times.This can to whole ceramic process equipment efficiency, energy-conservation,
The progress of environmental protection.The present invention in environmental protection, to the highly energy-consuming of ceramics, high pollution, high dust emission, high water consume, low output, low
The trend of the progress of entirely ceramic equipment manufacturing industry system industry of quality has revolutionary significance.
In sum, three above is in building decoration industry, especially in pottery and ambetti industry product and technique,
People thirst for the technical scheme of three significant technology issues that is solving and not succeeding and technique side always
Method, is not that in field, technical staff only leans on the general logical reasoning technical scheme that simple experiment can be formed in other words or can reach
The obvious technique effect arriving, this explanation present invention has significantly substantial technological progress, so the present invention is that have
Creative.
The household such as the especially inner-outer wall of prior art, ground and deck plate, kitchen cabinet panel and the decoration of engineer applied
Glass material, compares with ambetti of the present invention:
1st, for the ambetti of prior art, it is because the annealing point of common calcium soda-lime glass is at 490 DEG C about, and technology
(first must be introduced into substantial amounts of lead has severe toxicity to glaze that is upper and can not can manufacture less than 540 DEG C, second cost pole
Height, three can not possibly produce greatly), so can only print on the glass Bo Saike below 5cm size (because its size is minimum,
It is difficult to burst in annealing), so never producing the printing inorganic glaze glass plate of oversized dimensions in history.In addition useful tempering skill
Art, in 750 DEG C of glaze melt above, solves the problems, such as annealing stress using reinforcement process.But this kind of product size is specific, can not cut
Cut, do not adapt in decorative engineering application popular on-gauge plate can the arbitrarily convenience such as the application and construction of cutting, collocation special
Levy the requirement of demand.And the intensity difference of calcium soda-lime glass is it is impossible to make Ground Application, there is damaged back edge sharp, unsafe again
Defect.
And the technology of the present invention:
[1], can unprecedented ground high finished product rate, low energy consumption, high value, high intensity, light and thin type (0.5-3mm thickness),
Modular size ground produce 2400 × 1200mm, the high accuracy prints glaze pattern of 3000 × 1800mm, including stone material stricture of vagina, wood grain,
All kinds of senior carpet patterns (this is existing pottery and ambetti technology is not accomplished at all).
[2], because inventive article can sinter more than 650 DEG C it is possible to sinter printing glaze layer, can in glaze layer plus
Enter the substantial amounts of quartz of various crystal especially low cost as 30-80% or diamond spar crystal powder or grain, formed beyond example
The wearing coat high rigidity (reaching 7 grades or 9 grades of hardness) of 0.2-3mm, especially quartz or diamond spar are through 540 DEG C to 700 DEG C of burning
System, can be very white, and the hardness of this ultrawhite that can also initiate zero water absorption rate reaches the extremely wear-resisting three spy of 7-9 level unprecedentedly
Levy the Ground Application product being integrated.And the surface layer containing quartz crystal can be finished to the high abrasion goods of bright and clean layer, containing diamond spar
The not polished product on top layer can be the New function decorative materials product of best anti-skid wearable.And this all ceramic products,
In the existing technique of technique and ambetti product, be definitely make less than, the present invention is beyond example, because the burning till of pottery
At 1100 DEG C -1200 DEG C, now the quartz of ceramic surface or diamond spar can only become glass phase to temperature, can become fragile, be changed into not wear-resisting,
It is changed into the effect of the impossible ultrawhite of transparent area；And 540 DEG C -730 DEG C in the present invention burn till warm area, quartz also can keep crystallizing
Phase, this just can form the quartz-crystal dignity top layer of beyond example ambetti polishing, to pottery or stone material or ambetti table
The wearability of layer, zero water absorption rate, zero soil pick-up rate, high slip, are revolutionary challenging (anti-skidding to be used for bathroom, kitchen
Premises face, subway, harbour and the big public place ground of all flows of the people), energy-conserving and environment-protective, inexpensive high-quality can be formed wear-resisting
Replacement upgrade technique.And can be to the highly energy-consuming of ceramics, high pollution, high dust emission, high water consume, low output, low-quality
Product and whole equipment process system substituting challenge is proposed.And all pottery, ambetti technology of prior art, from
Not disclose or to pay close attention to above technical solution of the present invention and the non-obvious Substantial technical effect of energy.
2nd, top layer printing or the cloth crystal layer product of the present invention, the artificial stone based article of prior art, its yield are compared
And effect is low, high cost, the raw not line of one bar is produced daily only in 200-300m2, and float glass process Wiring technology adds the day of double-firing process
Produce up to 30,000-8 ten thousand m2.
3rd, existing aluminium-plastic panel ornament materials, and the present invention adds the composite plate of aluminum, and it can be overcome using because moulding in exterior wall
Plate is organic material by dilation gross distortion after Exposure to Sunlight and pattern printing, so the defect of exterior wall can not be made.The present invention adds
The composite plate of aluminum has pattern fine, and will never fade, flatness is fabulous, and energy simple installation the same with aluminium-plastic panel, cost is significantly
Decline, the advantage of work efficiency rising significantly.But also a large amount of mounting materials and work can be saved more easily without dry-hanging keel frame
When, directly it is fixed on body of wall with expandable nail, then in side seam gluing, form stone material dry suspending finishing effect.And prior art
All pottery, ambetti technology, always disclose or paid close attention to above technical solution of the present invention and energy is non-obvious
Substantial technical effect.
4th, for the decorative pattern Plastic panel of prior art, the present invention especially 0.3mm-1.6mm ultrathin product,
For table top, defend kitchen panel, sliding door face, furniture surfacing, have intensity good, hardness is high, and ultra-thin, ultralight, abrasion resistance is good, pattern effect
Good, flatness very degree of scraping is good, corrosion resistant, waterproof, moisture proof aliquation, the comprehensive advantage such as fire-retardant, safe and environment-friendly.
Existing all glaze first having a colored glaze base plate glass technology, all always disclosing or focus on or disclose the present invention
Property and a kind of overall technical architecture of the component invention being formed according to the technical scheme of the base plate glass of the present invention.Especially existing
All first have colored glaze base plate glass technology, for " individually contrast principle " convention, all always disclose or focus on or take off
Showed technical scheme according to a first embodiment of the present invention, especially the annealing temperature of the technical scheme about base plate glass and glass
The technical scheme of the fusing point of degree lower limit (i.e. endothermic peak origin temp) feature and glaze, so inventive article not only can replace
Many architectural pottery products, because its manufacturing process is totally different from international and domestic advanced ceramics production-line technique equipment technology,
Especially do not adopt the high energy consumptions such as water law ball milling operation therein, spraying procedure, ceramic press operation, polishing process, high pollution,
Highly water intensive link；Due also to the innovation of technique and maturity, intensity is that (pottery is 50mpa to ceramic 2-3 times, system of the present invention
Product are up to 130-160mpa), the ultrathin products of only 2-2.3mm thickness can be produced, just replacing modern architecture ceramic wafer can only produce
The product (ceramic tile of a large amount of production of modern mature technology is the product of 9-15mm thickness) of the thinnest technique for 6mm thickness.So,
Present invention process for advanced ceramics, can: 1. energy-conservation [oil, electricity, coal] reaches 60%-80%；2. because product is only 2-5mm
Thick, will polish the 10mm grinding off 1mm thickness than traditional technique advanced ceramics product, save material 50-80%；3. economize on water
Reach 80%；4. gdp CO2 emission reduces 60-80%；5. due to the big wooden frame packaging of big plate can be adopted, compare pottery now
Carton, bubble chamber, save packing cost more than 50%.
So the present invention not only technical scheme be not a kind of think afterwards with simple logical reasoning or simple experiment
The technical scheme with novelty that just can be formed, and its technique effect is not the technique effect that can obviously reach.
And this exactly nearly ten to two ten years, global architectural decorative glass industry, building decoration ceramic industry, decoration board industry thousands of
Enterprise and hundreds thousand of technical staff of family, all in researching and solving and problem that never solve.Technical side due to the present invention
Case solves to adhere to the colored glaze that fusing point is at 540 DEG C -730 DEG C on the glass substrate；There is predetermined requisite special scope
Interior sodium oxide, ferrum oxide, aluminium oxide, silicon oxide, calcium oxide, magnesium oxide or also titanium oxide, barytic composition and pre-
The innovative solution of the composition of specific proportions relation between fixed silicon oxide, calcium oxide, magnesium oxide；Overcome various tradition
Composition hydrotropy composition and eutectic composition technology prejudice, and unforeseeable hydrotropy or congruent melting body function and product can be produced
The technique effect of 1-3 times of the product strength rising of life, environmental protection, energy-saving and emission-reduction etc.；It is added without the boron oxide composition of environmental protection harm
When, in addition to the presence except viscosity advantage and strength advantage of the present invention, the environmental protection of practicality, substantial amounts of energy-conservation can be produced, reduce
CO2 emission, makes various final sheet lightening, especially compares alkali-free high boron glass, improves equipment Production Life 6-
10 times generation cost-effective and enhance production capacities 10-20 times, and the raw material resources after 3-6 times of product lightweight several times saving,
Decline of 3-6 times of energy-conservation of the logistics of inland and transport by sea and storage and cost etc. has the technical effect that to industry and professional
A difficult problem important technical contribution the above-mentioned ambetti new material that global decorative building material industry is opened up industry neck
It is great that the people of the technology trends of domain and alternative ceramic wafer brick product thirst for solving and never succeed
What technical barrier and this specification were mentioned also have many other people thirst for solve and have not been successful due to colored glaze material
Fusing point innovation and the excellent linear expansion coefficient feature of strain point of this base plate glass, low viscosity, high strength characteristics, ability
The large scale on-gauge plate of real existing product, big plate, ultra thin plate, high-strength plate, ultrawhite zero water absorption rate but also the extremely wear-resisting height of high rigidity not only
The sheet material of antifouling feature, fine pattern printing board material, fine pattern printing wearable plate, ultra-thin high strength glass composite board etc.
The various technical barriers of the unexampled new decorative material respectively having feature.
Above-mentioned unforeseeable technique effect, overcomes multiple prior art prejudice, especially (such as contains in low boron, low aluminum
Amount is in below 1-2%) the technology prejudice that can not rise of annealing temperature, save especially by the technology essential factor of boron and aluminum and sodium
Invention slightly and above-mentioned key element change annealing temperature lower limit (the i.e. endothermic peak starting point temperature of the glass inventing and being found that generation
Degree) update method property, and due to employ a kind of change technology essential factor proportionate relationship change invention and select send out
Bright and found because finding to create new product in one of colored glaze plate glass purposes Diversion An invention, arrange bubble, clarification, equal
Change, molding and draw the viscosity temperature of the operation stage such as thin, intensity, thickness poor and newfound flux or the property such as eutectic, and
Consequent increase the property that alumina content makes intensity can rise 1-2 times, and these product properties can also exist simultaneously
Produce in plate colored glaze product and have concurrently, and have unforeseeable technique effect plus a kind of of the special glaze layer of fusion temperature
The generation of component invention and the present invention that realizes is compared with the coloured lustre ware of all prior arts, create multi-level invention and add
Component invention a kind of cannot speculate in advance, unpredictable and reasoning above-mentioned multiple technologies effect out, create technology effect
The change of " matter " and " measuring " of fruit, illustrates technical scheme right and wrong it will be apparent that having prominent substantive distinguishing features and significant skill
Art progress, so the present invention is creative.
The above, merely to the explanation preferable preferred embodiment of the present invention, it is not limitation of the present invention,
Anyone familiar with this technology possibly also with the disclosure above technology contents changed or be modified to equivalent variations etc.
Effect embodiment, can implement a kind of colored glaze plate glass and preparation method by different requirements and performance.It can be seen that, every without departing from
The content of the content of technical solution of the present invention, especially claim, the technical spirit of the foundation present invention is to above example institute
Any simple modification, equivalent variations and the modification made, all still belongs in the range of technical solution of the present invention.
Claims (8)
1. a kind of application of the base plate glass having colored glaze decorative layer, the glazed colour layer of 1-10 kind color on its base plate glass surface molten
Change point at 540 DEG C -700 DEG C it is characterised in that: count as weight percents, in this base plate glass the content of boron oxide be 0-
3.9%, the content of sodium oxide is 0.01-14%, and iron oxide content is 0.01-5%, and the content of fluorine oxide is 0%, and magnesium oxide contains
Measure as 7-22.2%, alumina content is 0.01-39%, and the content of silicon oxide is 1.9 times -4.1 times of calcium oxide content, oxidation
The content of calcium is 1.0 times -1.8 times of the content of magnesium oxide；
The thickness difference of its base plate glass is less than 0.3mm；
The water absorption rate of its base plate glass is in the range of 0-0.3%；
The rupture strength of its base plate glass reaches 50-180mp；
The annealing temperature lower limit of its base plate glass is 550 DEG C -710 DEG C；
The difference of the two ends numerical value at 550 DEG C -600 DEG C for the thermal coefficient of expansion of its base plate glass be million/1.0- million/
2.8,
This base plate glass is used for preparing colored glaze plate glass.
2. the base plate glass having colored glaze decorative layer according to claim 1 application it is characterised in that: as weight percents
Meter, in described base plate glass, the content of aluminium oxide is 19-39%.
3. the base plate glass having colored glaze decorative layer according to claim 1 application it is characterised in that: be used for preparing colored glaze
The thickness of the base plate glass of plate glass is 0.3-1.8mm.
4. the base plate glass having colored glaze decorative layer according to claim 1 application it is characterised in that: be used for preparing colored glaze
The thickness of the base plate glass of plate glass is 1.8-20mm.
5. the base plate glass having colored glaze decorative layer according to claim 1 application it is characterised in that: as weight percents
Meter, in its base plate glass, the content of aluminium oxide is 0.01 to 30%, and this base plate glass is 10 in viscosity0.5Pa Sec when temperature
For 1480 DEG C -1640 DEG C；Viscosity is 101Pa Sec when temperature be 1410 DEG C -1600 DEG C；Viscosity is 102Pa Sec when temperature
For 1180 DEG C -1340 DEG C；Viscosity is 103Pa Sec when temperature be 1040 DEG C -1220 DEG C；The thickness difference of this base plate glass is less than
0.3mm；The water absorption rate of this base plate glass is in the range of 0-0.3%；The strain point temperature of this base plate glass is at 560 DEG C -720 DEG C
In the range of；The rupture strength of this base plate glass is 50-180mpa；The thermal coefficient of expansion of this base plate glass is at 150 DEG C -300 DEG C
Two ends numerical value difference be million/1.0- 3.0/1000000ths；It is million in the difference of 550 DEG C -600 DEG C of two ends numerical value
/ 1.0- 2.8/1000000ths.
6. the base plate glass having colored glaze decorative layer according to claim 1 application it is characterised in that: the colored glaze on its surface
Quartz crystal containing 20-70% or alpha-alumina crystals in layer.
7. have described in a kind of claim 1 that colored glaze plate glass in the application of base plate glass of colored glaze decorative layer makes is compound
Plate it is characterised in that: described composite plate is by the metallic plate of described colored glaze plate glass and bonding material layer and 0.1-5mm thickness
Material is combined composition.
8. have described in a kind of claim 1 that colored glaze plate glass in the application of base plate glass of colored glaze decorative layer makes is compound
Plate it is characterised in that: described composite plate is combined by described colored glaze plate glass and bonding material layer and sheet metal and forms, institute
State the 2-4 bar side of the metallic plate of the bottom surface of composite plate, the edge of the top layer colored glaze plate glass of proportion poststack has stretched out 10-30mm
Distance.
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| CN201310391466.4A CN103466957B (en) | 2010-03-18 | 2011-03-15 | Enameled sheet glass, and preparation method and composite board thereof |
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| CN2010101265849 | 2010-03-18 | ||
| CN201010126584 | 2010-03-18 | ||
| CN201010126584.9 | 2010-03-18 | ||
| CN2011100609139A CN102260045A (en) | 2010-03-18 | 2011-03-15 | Environment-friendly, energy-saving and low-melting-point color glaze decoration flat glass with high annealing temperature and strength and preparation method thereof |
| CN201310391466.4A CN103466957B (en) | 2010-03-18 | 2011-03-15 | Enameled sheet glass, and preparation method and composite board thereof |
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| CN2011100609139A Division CN102260045A (en) | 2010-03-18 | 2011-03-15 | Environment-friendly, energy-saving and low-melting-point color glaze decoration flat glass with high annealing temperature and strength and preparation method thereof |
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| CN 201110060944 Expired - Fee Related CN102285759B (en) | 2010-03-18 | 2011-03-15 | Use of plate glass with characteristics of high annealing point, environmental friendliness, energy saving, emission reduction, high strength, high flatness and low viscosity, and related components |
| CN201310246790.7A Active CN103420608B (en) | 2010-03-18 | 2011-03-15 | The preparation technology of glass and the application of glass |
| CN 201110060915 Expired - Fee Related CN102234181B (en) | 2010-03-18 | 2011-03-15 | Process for preparing high-strength, energy-saving, environmentally-friendly and low-viscosity glass |
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| CN201310246790.7A Active CN103420608B (en) | 2010-03-18 | 2011-03-15 | The preparation technology of glass and the application of glass |
| CN 201110060915 Expired - Fee Related CN102234181B (en) | 2010-03-18 | 2011-03-15 | Process for preparing high-strength, energy-saving, environmentally-friendly and low-viscosity glass |
| CN2011100609139A Pending CN102260045A (en) | 2010-03-18 | 2011-03-15 | Environment-friendly, energy-saving and low-melting-point color glaze decoration flat glass with high annealing temperature and strength and preparation method thereof |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN103420608B (en) | 2016-12-28 |
| CN103482875B (en) | 2015-11-25 |
| CN103420608A (en) | 2013-12-04 |
| CN102234181B (en) | 2013-07-24 |
| CN103482875A (en) | 2014-01-01 |
| CN103466957A (en) | 2013-12-25 |
| CN102260045A (en) | 2011-11-30 |
| CN102285759B (en) | 2013-07-24 |
| CN102234181A (en) | 2011-11-09 |
| CN102285759A (en) | 2011-12-21 |
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