WO2016054872A1 - Application of fire-proof explosion-proof plate glass having high softening point, low differential high-temperature region thermal expansion coefficient, and low crystallisation speed - Google Patents

Application of fire-proof explosion-proof plate glass having high softening point, low differential high-temperature region thermal expansion coefficient, and low crystallisation speed Download PDF

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Publication number
WO2016054872A1
WO2016054872A1 PCT/CN2015/000508 CN2015000508W WO2016054872A1 WO 2016054872 A1 WO2016054872 A1 WO 2016054872A1 CN 2015000508 W CN2015000508 W CN 2015000508W WO 2016054872 A1 WO2016054872 A1 WO 2016054872A1
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glass
substrate
thermal expansion
low
high temperature
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PCT/CN2015/000508
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French (fr)
Chinese (zh)
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杨德宁
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杨德宁
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Application filed by 杨德宁 filed Critical 杨德宁
Priority to TW104137767A priority Critical patent/TW201627243A/en
Priority to PCT/CN2015/000795 priority patent/WO2016086501A1/en
Priority to CN201510779888.8A priority patent/CN105645758A/en
Publication of WO2016054872A1 publication Critical patent/WO2016054872A1/en

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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass

Definitions

  • the invention belongs to the field of flat glass, and relates to a special flat glass, in particular to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass.
  • the invention mainly belongs to a new use invention of a chemical product
  • First Comparative Technology 1 The inventor's prior invention: application and related components of flat glass with high annealing point, high strength, high flatness and low viscosity characteristics with environmental protection, energy saving and emission reduction, Patent No. 201110060944.4,
  • First Invention 2 The inventor's 201510161553.61, a flat glass having a low coefficient of thermal expansion and a preparation process thereof.
  • prior invention 4 The inventor's: 201110060913.9, a high annealing temperature and high intensity environmental protection and energy-saving low melting point glaze decorative flat glass,
  • the patent name is: crystallizable glass for fiber production
  • (B) A method for testing the low difference in the coefficient of thermal expansion of the high temperature zone, the coefficient of expansion of the glass is determined in accordance with the standard GB/T7320.1-2000. It is currently measured using the world's best thermal resistance instrument from the German company Nitz; the result is from 60 ° C to 800 ° C, a thermal expansion value of E-06 / ° C per 10 ° C, or from 60 ° C It has a thermal expansion value of E-06/°C per 10°C at 740°C; from which the difference in thermal expansion rate in the more severe high temperature range of 650°C-700°C is within 0.1-0.99 parts per million, at a more severe high temperature.
  • the difference in thermal expansion coefficient between 700 ° C and 740 ° C in the high temperature region of 1-5.9 or 6-8 is a comparison of the lower differential coefficients of the prior art.
  • the magnitude of the minute value of all the crystallization rates, and thus the speed of the crystallization rate are determined by the same glass melting furnace specified in the lower part, and the analysis of the different glasses specified in the lower part.
  • the data obtained from the test method of crystal velocity is based on:
  • the characteristics of the selected glass melting furnace are:
  • the glass melting furnace is provided with a display for accurately measuring the temperature inside the furnace for observing and recording temperature changes.
  • the overall thermal insulation performance of the selected glass melting furnace should be good.
  • the temperature in the furnace should be kept at least 1500-850 °C for a period of 150 minutes or more; that is, the glass liquid is in the furnace. It is sufficient time for the temperature inside to remain at least 150 minutes or more to complete the natural temperature lowering process of the furnace temperature of 1300-850 °C. (Because the upper line range of the glass crystallization temperature zone of the product of the invention is mostly within the range of 1300--850 ° C, for example, the upper line range of the glass crystallization temperature zone of a product is: 1230--920 ° C)
  • the product of the present invention has the characteristic that the upper line [highest point] of the crystallization temperature is higher than the molding temperature, in order to study the selective use of glass having a relatively slow crystallization rate in large production, it is advantageous to form before molding in large production.
  • the glass liquid cooling process stage reducing the risk of devitrification of the glass liquid; in particular, in the cooling work part of the liquid line edge and corners and bottoms, which are easy to devitrify, add some heating control devices, and add The temperature is controlled to be higher than the crystallization temperature on the line 50-80 ° C;
  • the glass product having the relatively slow crystallization rate of the present invention should be selectively used, because of its relatively slow crystallization rate: 60-90 when the temperature of the glass liquid starts to fall from the apex of the crystallization temperature. No crystallization occurred within minutes or 60-150 minutes.
  • the slow crystallization rate of the glass liquid of the glass material discovered by the invention can be beneficial to solve the problem of local devitrification in the corners and bottom of the cooling working part, and in some slow-flowing areas; Slow, so in some flow In the slower area, it is possible to overcome the risk of unqualified products which tend to cause local crystallization and devitrification during the forming stage of the flat glass.
  • the temperature of the crystal ladder is measured first, and the on-line [highest point] and the lower line [lowest point] of the crystallization temperature of various glass materials to be measured are measured.
  • the temperature of the internal temperature of the furnace is observed to be more accurate (for example, 1230 ° C) Time to the time period required for the measurement;
  • the melting pot is taken out after 20 minutes, the glass liquid will be quickly cooled to glass and observed for crystallization.
  • the glass to be measured is obtained from the upper line of the crystallization temperature [highest point].
  • the melting pot was taken out; the nature of the crystallization rate of the glass to be measured, which was naturally lowered from the upper line [highest point] of the crystallization temperature of 20, 45, 60, 90, 120, and 150 minutes.
  • a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of a fireproof and explosion-proof flat glass characterized in that the alumina content is 0.01% - 39% by weight, magnesium oxide The content is 7%-20%, the silicon oxide content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness difference of the flat glass within the thickness of 20 mm is 0.01 mm-0.4. Mm.
  • a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass characterized in that the alumina content is 0.01% - 39% by weight, sodium oxide The content is 0.001%-18%, the magnesium oxide content is 7%-20%, the silica content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1,8 times of the magnesium oxide content, and the thickness is less than 20mm.
  • the thickness of the flat glass is between 0.01 mm and 0.4 mm.
  • a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass characterized in that the alumina content is 0.01% - 39% by weight, sodium oxide The content is 0.001%-0.9% or 0.91-8.8% or 8.9-18%, the magnesium oxide content is 7%-20%, and the silica content is 2.51-4.09 times or 3.61-4.09 times or 3.61-4.8 of the calcium oxide content. Times.
  • the calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness difference of the flat glass within the thickness of 20 mm is 0.01 mm-0.4 mm.
  • the invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the softening point is 750 ° C - 860 ° C;
  • the folding strength is 60-240Mpa.
  • a flat glass according to claim 1, wherein the low temperature expansion rate in the high temperature region is characterized by a difference in thermal expansion rate within 1.2 parts per million in a high temperature region of 550 ° C to 600 ° C. In the high temperature range of 600 ° C to 650 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million, and in the high temperature range 650 ° C - 700 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million.
  • the invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass according to claim 1, characterized in that the alumina content is 4% by weight. --8% or 8.1-12% or 12.1-23% or 23.1-32% or 32.1-39%,
  • the predetermined component and the predetermined raw material of the composition of the specific ratio between the silicon oxide, the calcium oxide and the magnesium oxide are mixed and stirred, and melted at a melting temperature corresponding to each glass formulation to form a glass liquid having a predetermined viscosity, and then To clarify, discharge bubbles, and form a flowable melt;
  • the glass is formed by a float process, a flat pull process, a lattice process, a calendering process, an overflow process, or any one of the processes.
  • the step 1 includes:
  • the various raw materials prepared are placed in the respective raw material containers, and the various raw materials are passed through the raw material conveying line, and after being metered, they are sent to the raw material mixing and stirring device in the required proportion, stirred and mixed, and then loaded into the raw materials.
  • the matched raw materials are introduced into the molten pool and melted at a melting temperature corresponding to each glass formulation to form
  • the float process is used in step 2: in the process, the tin kiln must be prepared in advance, and after the step of step 1, the flowable melt at the tail of the molten pool is poured into the tin kiln for flattening, polishing, and thinning.
  • the present invention it is possible to provide a high softening point, a low crystallization rate, a special aluminum-free alkali-free, fire-proof and explosion-proof flat glass.
  • a preparation method suitable for the high softening point, low crystallization rate, special aluminum non-alkali, fireproof and explosion-proof flat glass can be provided.
  • a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass characterized in that the alumina content is 4% to -29% by weight, and oxidation
  • the sodium content is 0.011-0.99%
  • the magnesium oxide content is 7%-20%
  • the silica content is 2.52-4,08 times of the calcium oxide content
  • the calcium oxide content is 1,0-1,8 times of the magnesium oxide content.
  • a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass characterized in that the alumina content is 16.1 to 35% by weight percent, and the sodium oxide content is 1 to 18%, the boron oxide content is 0.0001 to 3%, the magnesium oxide content is 7% to 20%, the silicon oxide content is 2.53 to 4.09 times the calcium oxide content, and the calcium oxide content is 1.0 to 1.8 times the magnesium oxide content.
  • a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass characterized in that the alumina content is 16.1 to 35% by weight percent, and the sodium oxide content is 1 to 13%, the magnesium oxide content is 7% to 20%, characterized in that the content of silicon oxide is 2.52 to 4.08 times of the content of calcium oxide, and the content of calcium oxide is 1.0 to 1.8 times of the content of magnesium oxide.
  • a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass characterized in that the alumina content is 4%-29%, and the sodium oxide content is 0.011-0.99 %, the content of lithium oxide is 0.0001 to 3%, the content of boron oxide is 0.0001 to 3%, the content of magnesium oxide is 7% to -20%, the content of silicon oxide is 2.53-4, 09 times of the content of calcium oxide, and the content of calcium oxide is The magnesium oxide content is 1.0-1.8 times.
  • the thickness of the glass is 1.5-2 mm.
  • New [a. low crystallization rate] material properties were found; well known to known compounds [b. difference in thermal expansion coefficient in high temperature zone] and [c. high softening point] and [d. low viscosity and The properties of the eutectic of aluminum, silicon, calcium and magnesium at high aluminum content] and the various effects produced are substantially improved and improved.
  • a high-performance color glazed flat glass characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the substrate thereof
  • the surface of the glass has a glaze layer of 1-10 colors.
  • Non-obvious technical effects Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thus, the high-quality fire-proof and explosion-proof flat glass of the present invention without any crystallization due to the influence of light transmittance is produced.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the [higher softening point] of the flat glass of the present invention, [better thermal expansion difference in high temperature region, [high performance such as higher strength], the shape of the glass can be maintained, and fire, fire, and separation can be achieved.
  • the non-obvious technical effect of the heat wave; the invention has special fireproof and explosion-proof effects of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • the invention can be printed into a large one because of the characteristics of a high softening point and a low thermal expansion rate in a high temperature region.
  • the first comparative technique [1][2][3][4] has a flexural strength vertex from 180 MPa, substantial improvement and improvement to a bending strength apex of 240 MPa;
  • the flexural strength is substantially improved and increased by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa;
  • the flexural strength of the touch screen glass containing 12-15% of aluminum is increased by about 2.4 times, and the bending strength of the calcium sodium glass is increased by about 5 times.
  • the flexural strength can be substantially improved and improved by 1/4 compared with the prior art [1][2][3][4]; the flexural strength of the existing boron-containing glass is 80Mpa. It is increased by about 3 times; it is about 2.4 times higher than the existing 20-15% touch screen glass flexural strength 100Mpa; it is about 5 times higher than the calcium sodium glass bending strength 50Mpa.
  • It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It can also be edged and cut like a tile to ensure the defect-free pattern and standardization of the product board and the use of cutting convenience. It can replace the high-energy thick tile (8-15mm) and the 15-25 stone wall with the 1-4mm thick product of the invention, and the product is 5 times lighter and thinner.
  • the high-strength, light-thinning replacement of existing ceramic products resulting in several times lighter and thinner energy, resources, logistics, and warehousing, can produce 4-8 times less energy-saving non-obvious technical effects.
  • a high-performance wear-resistant color glaze flat plate glass characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass
  • the surface of the substrate glass has a glaze layer of 1-10 colors, and the glaze layer of the surface layer contains 15-70% quartz crystal or alumina crystal.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effect [3]: Since the product of the invention can sinter the colored glaze layer below 650-740 ° C, the printing glaze layer can be sintered, and a large amount of various crystals such as 30-80% can be added to the glaze layer, especially Low-cost quartz or steel jade crystal powder or granules, forming an unprecedented hardness of 0.2-3mm wear-resistant surface layer (quartz up to 7 grade hardness, while steel jade can reach grade 9 hardness), and this is in ceramic production Can not be done, because the ceramic firing temperature is 1100 ° C -1200 ° C, at this time the ceramic surface of the quartz or steel jade can only become the glass phase, and below 730 ° C, quartz or steel jade crystals can remain crystal Phase; this can also form an unprecedented decorative glass polished quartz crystal with a hardness of 7 grade wear surface; with non-obvious technical effects.
  • Non-obvious technical effect [4] The quartz surface layer can be polished due to the hardness of 7 grade, which becomes the optimal surface quartz glaze combination polishing and wear-resistant product; while the 9-grade hardness of steel jade is not polished, but Unexpectedly, it is an optimal durable anti-slip or wear-resistant steel jade enamel layer combination application invention product, so the invention can form an alternative upgrade technology of energy saving, environmental protection, low cost and high quality wear resistance. It also poses an alternative challenge to the ceramic industry's high energy consumption, high pollution, high dust emissions, high water consumption, low output, low quality products and the entire equipment process system. Has a non-obvious technical effect.
  • Non-obvious technical effect [5] The present invention compares the apex of the first comparative technique [1][2][3][4] from 180Mpa, substantial improvement and improvement to the apex of bending strength 240Mpa; Compared with the prior art [1][2][3][4], the flexural strength is substantially improved and increased by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; The flexural strength of the touch screen glass containing 12-15% of aluminum is increased by about 2.4 times, and the bending strength of the calcium sodium glass is increased by about 5 times.
  • the quartz surface layer can be polished due to the hardness of 7 grade, which becomes the best surface quartz glazed combination polishing and wear-resistant product, or becomes the best durable non-slip matte carpet pattern with wear-resistant steel jade enamel layer.
  • a high-performance ultra-thin wall-faced glazed flat glass characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof
  • the surface of the substrate glass has a glaze layer of 1-10 colors, and the thickness thereof is 0.5-1.5 mm.
  • Non-obvious technical effect In the application place, the present invention compares the prior art [1][2][3][4] in the case of fire or high temperature, in the state of high temperature zone, due to the invention
  • Non-obvious technical effects The invention has special fireproof and explosion-proof effects of building materials, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technical effect.
  • the invention has the prior art [1][2][3][4] bending strength apex from 180Mpa, substantial improvement and improvement to the bending strength apex 240Mpa;
  • a high-performance ultra-thin veneer glazed flat glass can achieve a strength of 2.5-7.5 mm calcium soda glass under a very lightweight condition of 0.5-1.5 mm.
  • Non-obvious technical effects [1]: a high-performance ultra-thin veneer glazed flat glass, a. using electrospray process to make all decorative wall paper patterns; b. using matt inorganic glaze materials, in glass The surface can be used to make a pattern of all decorative wall paper without reflection; c. or use the prior art to create a higher level of pattern pattern than any decorative wall paper, such as gold, silver, silver gray;
  • Non-obvious technical effect [2]: A high-performance ultra-thin veneer glazed flat glass: a. The flatness of the veneer can be like a mirror surface, and the flatness of the traditional decorative wall paper is incomparable; b. Basically flat, laminated with a thin layer of tile adhesive, the base is simpler than the decorative wall paper, saving labor time; c. Now using the decorative wall paper 100cm x 350cm or 200cm x 350cm size, can be used in continuous wall stitching, More accurate alignment of the pattern than the soft decorative wall paper, which has a better overall wall surface than the decorative wall paper; d. It can be more convenient than the soft decorative wall paper when the continuous wall is spliced. e.
  • a high-performance ultra-thin veneer glazed flat glass, in the use of alternative decorative wall paper, has better characteristics of not easy to accumulate dust, easy to clean and care; f. decorative wall paper for 2-3 years
  • the seam is easy to roll up, the quality cycle is only about 3 years, and the wallpaper has a service life of 3-6 years.
  • the high-performance ultra-thin veneer glazed flat glass of the invention can never be used.
  • the left and right seams are easy to roll. High-performance inorganic glaze layer and enamel strength glass life of 100-300 years On.
  • Non-obvious technical effect [3]: A high-performance ultra-thin veneer glazed flat glass, especially suitable for wood interior wall applications of wooden building villas: a. because it can be very thick in 0.5-1.0mm Under light conditions, it can overcome the problem that the total support of the wooden building villa and the inner wall of the wooden board can not bear too much weight; b. can also reach the strength of 2.5-6mm calcium soda glass; c. can reach the inner wall of the wooden building villa The surface is unprecedentedly more than the overall sense of the decorative wall paper plane, and the mirror flatness; d. It can reach and exceed the pattern texture effect of all the decorative wall paper of the traditional decorative wall paper.
  • the present invention provides a high-performance ultra-thin veneer glazed flat glass instead of decorative wall paper.
  • the inner wall of the wooden board has a slightly modified application; or to prevent new The wall surface of the wooden board has been slightly modified after many years.
  • the countermeasures are: [1] the improvement of the softness characteristics of the traditional porcelain glue; [2] the double-sided glue on the inner wall of the board is set in the ultra-thin veneer
  • the structure of the back surface of the glazed flat glass can greatly increase the sticking convenience and efficiency; [3] in the mounting size of a high performance ultra-thin veneer glazed flat glass of the present invention, from 100cm x 350cm or 200cm x 350cm Dimensions, changed to 60cm x 60cm or 90cm x 90cm or 120cm x 120cm or 150cm x 150cm size: to achieve a. can adapt to the inner wall of the board with a slightly modified application; b. installation can not only save labor, but also reach When splicing the wall continuously, it can accurately align the pattern with the soft decorative wall paper, and it can have the effect of never rolling up the upper, lower, left and right seams;
  • the utility model relates to a high performance marine glazing structure, characterized in that the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass.
  • a resin frame or a metal frame support device is mounted on the periphery of the four sides.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effect In the application place, the present invention is compared with the prior art 1.2.3 in the high temperature state in the case of fire or high temperature, due to the higher softening of the flat glass of the present invention.
  • High performance such as difference in thermal expansion between high temperature zones and higher strength, can have the shape of maintaining glass, and can achieve non-obvious technical effects of fireproof, fireproof and heat insulation waves;
  • the fireproof and explosion-proof effect of the building materials will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [3]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
  • the ballistic performance can also be better than the conventional 25mm thick F79-class full glass bulletproof glass (the steel core bullet for the pistol), and the invention is also thin and light. 5 times. Since the invention can manufacture a full glass bulletproof glass with a special strength of only 8-9 mm, the ballistic performance can also be superior to the conventional 40 mm thick F56 grade (anti-56/AK47 submachine gun or 81 rifle steel core projectile) full glass bulletproof glass; It is also five times lighter and thinner, which is a new material property that is impossible for all existing existing glass.
  • the marine glass window structure of the invention is used, and the anti-pirate robbery boat mooring has the effect of preventing and increasing the response time. Has a non-obvious technical effect.
  • a high performance aircraft glazing structure characterized in that: the window glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass.
  • a resin frame or a metal frame support device is mounted on the periphery of the four sides.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; There are TFT boron-containing glass, which is 1/3 lighter and thinner than calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
  • the glazing structure of the invention [a] with a covering product, a higher strength of 4-5 times the geometric multiple, will be against the flying aircraft, which is extremely demanding for such safety.
  • the sudden change of pressure inside and outside of the aircraft caused the aircraft glass to rupture. Due to the increased strength of several times, it can prevent man-made damage to the aircraft side window and other accidents, provide new flight safety guarantees, and have non-obvious technical effects;
  • [b] The more lightweight and thinner aircraft glazing products with 4-5 times the geometric multiples provide the option of reducing the weight of the aircraft and saving energy while ensuring safety. Has a non-obvious technical effect.
  • a high-performance glazing structure for an automobile characterized in that: the automobile glazing is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass
  • the application has a resin frame or a metal frame support device mounted on the periphery thereof.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of fire or high temperature, in the state of high temperature region,
  • the higher softening point of the flat glass of the invention, the better high temperature zone thermal expansion difference, higher strength and the like, can have the shape of maintaining the glass, and can be used for fire prevention, fire insulation and heat insulation.
  • the invention has special fireproof and explosion-proof effect of building materials, and greatly enhances the ability of bursting in the high temperature region when the glass volume is rapidly increased, and has non-obvious technical effects.
  • Non-obvious technical effects [3]: The present invention has a special fire and explosion-proof effect: it will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased. It can help to avoid people or cars from escaping from the fire area when it comes to fire outside the car. It has non-obvious technical effects.
  • Non-obvious technical effects In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; Existing TFT boron-containing glass, light and thin 1/3; ratio Calcium soda glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
  • a high-performance building glazing structure characterized in that: the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass
  • the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass
  • a resin frame or a metal frame support device is mounted on the periphery of the four sides.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [3]: The invention has special fire and explosion-proof effects of buildings:
  • the softening point is higher [from 780 ° C to 860 ° C], the more the shape of the glass can be maintained in a high temperature region when fire or high temperature is encountered, and fireproofing and separation can be achieved.
  • the present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region; It greatly enhances the ability to resist bursting when the volume of glass in the high temperature zone is rapidly increased; it can prevent or greatly delay the fire from being extinguished by other floors through the external window glass to accelerate the overall fire of the whole building; or can prevent or greatly delay the fire Extinguish the transfer from other indoors to the outer wall to speed up the overall fire of the whole building; it can produce good indoor fire safety for human beings and gain confidence in long-term escape and rescue; it can be beneficial when it comes to building fires. It is good for people to escape from the fire area for a long time; it has non-obvious technical effects.
  • Non-obvious technical effects In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; Existing TFT boron-containing glass, light and thin 1/3; ratio Calcium soda glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
  • a high-performance insulating glass characterized in that: the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass; A support device is attached to the periphery; there is a 3-50 mm vacuumed isolation space between the layers of glass.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
  • the invention can create a new energy-saving market, and form a super-high-strength and light-thin 3-5 layer hollow efficiency energy-saving glass for building covering:
  • the traditional hollow energy-saving glass is limited to 6mm glass + vacuum insulation layer +6mm due to strength limitation.
  • Glass, only one layer of vacuum insulation layer; and the invention can be 1.2mm glass + vacuum insulation layer +1.2mm glass + vacuum insulation layer +1.2mm glass + vacuum insulation layer +1.2mm glass, equal to three layers of vacuum
  • the temperature insulation layer, but the total thickness of the glass is only 4.8mm, which is not only lighter than the total thickness of the traditional two-layer glass hollow energy-saving product, but also has a heat insulation effect of 3-5 layers of vacuum insulation layer than the traditional one.
  • the effect of the layer vacuum insulation layer is too good, which can create a new history of efficiency and energy saving of insulating glass, and has non-obvious technical effects.
  • a high-performance building glass curtain wall characterized in that: the glass curtain wall is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is fixed to the upper metal support device.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [3]: The invention has special fire and explosion-proof effects of buildings:
  • the softening point of the present invention since the content of the oxidizing pot is low, the softening point is greatly increased; and the higher the softening point of the present invention [from 780 ° C to 860 ° C], the more likely it is in the high temperature region when it hits a fire or a high temperature. Keeping the shape of the glass, it can play the role of fire prevention, fire separation and heat insulation;
  • the present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region;
  • Non-obvious technical effects [4] In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the high-performance building glass curtain wall strength to be five times higher than the existing calcium soda glass strength at the same weight.
  • a high-performance super-large area thin glass window or glass curtain wall characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass Application; the thickness of the glass is 4-10mm, the size of the glass is 3-40 square meters, or the thickness of the glass is 10.1-20mm, and the size of the glass is 15.1-80 square meters;
  • Non-obvious technical effects [1]: In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight. It also enables the strength of the glass to be five times higher than the strength of the existing calcium soda glass at the same weight.
  • the technical effect of the coating of the invention is that the glass materials for construction are all sodium soda glass, the strength is only 50Mpa; and the performance glass of the invention can reach 180-240Mpa, and the geometric multiple of 4-5 times is higher.
  • the strength can make the building glass anti-collision, explosion-proof, anti-shock performance, etc., and the safety is increased by 4 times to 5 times; it can be designed as an unobstructed panorama of the super-large board without being divided by the aluminum alloy skeleton.
  • Architectural glass especially in various office buildings, hotel and apartment buildings, and indoor visuals of buildings and villas, can display a wide range of beautiful panoramic views of the window (such as garden, mountain, water, sea, city) Scenery), creating a new functional life experience of the covered window building, can also cover the façade of the super-large glass of various buildings, create a new consumer market, create a new history of architectural design value; Business and users bring new value with non-obvious technical effects:
  • the present invention can withstand high temperature for a long time because there is no traditional aluminum alloy window frame in the use of large-area windows or curtain walls (because the softening point of the glass of the invention reaches 780 ° C - 880 ° C, much higher than aluminum alloy
  • the frame softening point is 400-450 ° C), so increasing the glass area can improve the overall fire, fire and heat insulation of the building, and has non-obvious technical effects.
  • the present invention has a 4-5 times higher strength than the soda lime glass [fracture strength of only 45-50 Mpa], and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technique. effect.
  • the invention can prevent or greatly delay the fire from being extinguished by other floors through the outer wall window glass to accelerate the overall fire of the whole building; or can prevent or greatly delay the fire from being transferred from other indoors to the external wall to accelerate the whole building as a whole Fire; can generate good indoor fire safety for humans and strive for longer escapes and Rescuing confidence is a life experience with the effect of human security. It can create new consumer markets and create a new history of building fireproof glass with non-obvious technical effects.
  • D It has 4-5 times higher strength than the existing calcium-sodium architectural glass; it can be designed as an unobstructed panoramic architectural glass with no large plate surface, especially in various office buildings and hotels. And the indoor vision of the apartment building, and the buildings such as the house and the villa, can display a large range of beautiful panoramic views of the window (such as garden, mountain, water, sea, city), creating new windows.
  • the functional life experience can also cover the façade of the super-large glass of various buildings, create a new history of architectural design value, and bring new value to builders and users, with non-obvious technical effects.
  • Non-obvious technical effects Discovered low crystallization rate crystal velocity properties, resulting in high quality, large production technical effects.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • a high-performance tempered glass characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass, chemically tempered or Made of physical tempering.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thereby producing a high quality flat glass of the invention without any crystallization due to crystallization;
  • Non-obvious technical effects [2] In the application place, the present invention compares with the prior art [1][2][3][4] in the state of high temperature when encountering fire or high temperature, Due to the flat glass of the present invention High softening point, better high temperature zone thermal expansion difference, higher strength and other high performance, can maintain the shape of the glass, can play a non-obvious technical effect of fire, fire, heat wave;
  • the invention has special fireproof and explosion-proof effects of building materials, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effect [3]: The invention has special fireproof and explosion-proof effects of building materials, and the glass of the invention is strengthened, which greatly enhances the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technology. effect.
  • Non-obvious technical effects [4] In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
  • a high-performance glass, or tempered glass, or a glass-top furniture of laminated glass characterized in that the glass table top is a low difference and a low coefficient of thermal expansion coefficient of a high softening point and a high temperature zone according to claim 1.
  • the crystallization rate, fireproof and explosion-proof flat glass are made, and the lower part of the table has support means.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the strength of high-performance glass countertops to be five times higher than the existing calcium soda glass at the same thickness and weight.
  • a high-performance laminated glass characterized in that the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the layers thereof There is a layer of resin material between the glass.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the performance of high-performance laminated glass to be five times higher than the strength of existing calcium-sodium laminated glass at the same thickness and weight.
  • the utility model relates to a high performance bulletproof and explosion-proof glass, which comprises: bulletproof explosion-proof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, a fireproof and explosion-proof flat glass Application; each of the glass sheets is bonded by a resin sheet.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • the softening point is greatly increased; and the higher the softening point of the present invention, the more the shape of the glass can be maintained in a high temperature region when it hits a fire or a high temperature. Play a role in fire prevention, fire separation, and heat insulation;
  • the present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region;
  • Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
  • the invention can manufacture a 6-7 mm thick bulletproof and explosion-proof glass composed of three layers of glass with special strength, the ballistic performance can also be superior to the conventional 25 mm thick F79 class full glass bulletproof glass composed of three layers of glass ( The steel core of the pistol), the invention is also 4-5 times thinner. Since the present invention can manufacture a full-glass bulletproof glass of only 8-9 mm thick composed of three layers of glass, the ballistic performance can also be superior to the conventional 40 mm thick F56 grade consisting of three layers of glass (anti-56/AK47 submachine gun or 81 rifle steel core bullet) full glass bulletproof glass; also thin and light 4-5 times, which is the new material nature of other existing existing glass. Therefore, for bulletproof and explosion-proof glass of transparent armored ships, ships, yachts, buildings, residences, etc.;
  • the invention relates to a high-performance color glazed glass plate combination cabinet, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass
  • the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass
  • a high-performance sliding door cabinet glass panel furniture characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass
  • the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass
  • the utility model relates to a high-performance color glazed glass plate combined wardrobe, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass a glaze layer of 1-10 colors on the surface or the back surface; the flat glass is surrounded by a metal frame to form a composite panel; and a metal coupling device is formed between the metal frames to make it a glazed glass Board combination wardrobe.
  • a high-performance color glazed countertop glass furniture characterized in that: the countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass Application: There are 1-10 colors of glaze layer on the surface or back of the table top, and there are support devices on the lower part of the table.
  • Non-obvious technical effects [1] In the application place of furniture, the present invention compares the prior comparative techniques [1][2][3][4] in the high temperature zone when it encounters fire or high temperature. Next, due to the [higher softening point] of the flat glass of the present invention, [better high temperature zone thermal expansion difference, [higher strength and other high performance], it can have the shape of holding glass, and can be fireproof and fireproof.
  • the non-obvious technical effect of the heat-insulating wave; the invention has special fire-proof and explosion-proof effect of the furniture, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [2]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass.
  • [a] such as 15cm thick wood material and 6-8mm calcium soda glass strength; the invention can only use 1.5-1.8mm products can be comparable to 15cm thick wood material; lighter than wood products 2-3
  • Non-obvious technical effects [3] various high-performance glazed glass homes have: a., the appearance of high-simulated wood grain, stone arteology and appropriate product design entry point; b. brand new inorganic type The unique technical characteristics of the sturdy and wear-resistant high-strength glass of the glaze combination; c. sturdy and suitable, convenient and environmentally friendly, can lead to the change of the global invention of timber board, fiberboard products and wood furniture combination The trend of high chemical pollution and dust pollution in the production of products overcomes its historical difficulties and benefits the international community;
  • Non-obvious technical effect [4] The invention has special furniture fireproof and explosion-proof effect: and the glass of the invention can be strengthened for a longer period of time after being strengthened; it will greatly enhance the bursting resistance when the glass volume in the high temperature region is rapidly increased.
  • Ability
  • a high-performance photovoltaic solar device comprising: a solar cell, and a glass substrate or a cover plate; the glass substrate or the cover plate is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. Low crystallization rate, application of fireproof and explosion-proof flat glass.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better high temperature zone thermal expansion difference, higher strength and the like, high performance, the shape of the glass can be maintained to prevent fire, fire, and heat waves.
  • Technical effects The invention has a special fireproof and explosion-proof effect, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [3]: High-performance photovoltaic solar installations in applications, due to their glass, can also be light and thin at the same intensity, compared with the prior art [1][2][3][4] Light and thin is 3/4; lighter than 1/3 of the existing TFT boron-containing glass; lighter than 1/5 of calcium soda glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
  • the support frame and the frame body can also greatly reduce the weight; especially suitable for the roof installation of the wooden villa with poor carrying capacity, which has non-obvious technical effects.
  • a high performance thin film solar device comprising: a thin film solar cell; and a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass according to claim 1 .
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • High-performance thin-film solar devices can be used at the same intensity due to their glass, and they are lighter and thinner than the prior art [1][2][3][4] Light and thin is 3/4; lighter than 1/3 of the existing TFT boron-containing glass; lighter than 1/5 of calcium soda glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
  • the support frame and the frame body can also greatly reduce the weight; especially suitable for the roof installation of the wooden villa with poor carrying capacity, which has non-obvious technical effects.
  • Non-obvious technical effects 4] The perfect combination of high-quality life and environmental protection concepts: [a] thin film solar technology can be successfully grafted with cars; [b] large-scale off-grid power supply can be realized by using solar energy rapid power station; Thin-film solar enclosures can be used to mobilely charge electronic devices; [d] Thin-film solar energy can be used in ships and urban buildings with non-obvious technical effects.
  • a roll-to-roll process for producing a film transistor on a glass substrate, and a liquid crystal display produced thereby including
  • the LCD screen includes:
  • An array substrate comprising a substrate and a pixel structure produced on the substrate by a roll-to-roll process, wherein the substrate has a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution according to claim 1. Crystal speed, fireproof and explosion-proof flat glass;
  • the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
  • the existing TFT-LCD liquid crystal display panel roll-to-roll production process is in a difficult development period; the present invention can solve a variety of difficult problems in the development period, and make the TFT-LCD liquid crystal display panel roll-to-roll production.
  • the process enters a high-quality, high-yield, high-yield production capacity, and low-cost large-scale production stage [see the production process of the panel roll-to-roll of the invention].
  • a touch display screen produced on a glass substrate by a roll-to-roll process comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution
  • the application of crystal speed, fireproof and explosion-proof flat glass is provided with a conductive film thereon;
  • the LCD screen includes:
  • An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
  • the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
  • a high performance roll-to-roll flat glass for a liquid crystal screen or touch screen comprising:
  • the glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass according to claim 1; wherein the thickness of the flat glass is 0.05-3.5 mm, and the glass can be collected.
  • the inner roll of the roll has a diameter of 20-80 cm and a length of 200 cm-2000 cm or 2001-10000 cm.
  • a high performance low temperature polysilicon display screen comprising:
  • the LCD screen includes:
  • a low temperature polysilicon array substrate comprising a substrate and a pixel structure produced on the substrate by a low temperature polysilicon process, wherein the base glass has a high softening point and a low difference in thermal expansion coefficient of a high temperature region according to claim 1. Crystallization speed, fireproof and explosion-proof flat glass;
  • the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
  • the invention can solve the problem of the new process of the low-temperature polysilicon technology for the liquid crystal display product [see the new process part of the low-temperature polysilicon technology for the purpose of the invention].
  • a flat glass for high performance low temperature polysilicon display characterized by comprising:
  • the base glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass;
  • a high performance wear resistant and high strength liquid crystal display comprising:
  • An array substrate comprising a substrate and a pixel structure on the substrate, wherein the substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof explosion-proof plate according to claim 1.
  • the substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof explosion-proof plate according to claim 1.
  • the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • a high-performance wear-resistant and high-strength touch display screen comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass Application with a conductive film attached thereto;
  • the LCD screen includes:
  • An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
  • the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effect For example, when the upper glass of the two-layer TFT glass is subjected to the composite touch screen process by using the cover glass layer, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained.
  • the rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;
  • the better thermal expansion difference in the high temperature zone, and higher High performance such as strength can maintain the shape of the glass; especially the difference in thermal expansion of the high temperature region, which will greatly enhance the color alignment accuracy of the phase element and the beam splitter, which can produce a higher 2 than the prior art 2 -5 times the resolution of the display's non-obvious technical effects;
  • the substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion proof flat glass according to claim 1, and a conductive film is attached thereon;
  • An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
  • the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
  • Non-obvious technical effect For example, when the upper glass of the two-layer TFT glass is subjected to the composite touch screen process by using the cover glass layer, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained.
  • the rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;
  • Non-obvious technical effects Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thereby producing a high quality fire-proof and explosion-proof flat glass of the invention without any crystallization due to crystallization;
  • the present invention is especially useful in comparison with the prior art [1][2][3][4]: in the process of thin film transistor or touch conductive film
  • the shape of the glass can be maintained; especially the better thermal expansion in the high temperature zone
  • the value will greatly enhance the color alignment accuracy of the phase element and the beam splitter, which can produce a higher 2-5 times resolution of the non-obvious technical effect of the display than the prior art 2; it can also withstand better
  • the harsh high-temperature process used in the production of the most advanced high-definition display under the high-temperature process conditions, the temperature range of the process control platform can be expanded, not only the dimensional stability is good, but also the production is improved while ensuring the quality.
  • Non-obvious technical effect [4]: In the ultra-high aluminum scratch-resistant and tough glass material of the present invention, the alumina content can reach 25-39%, and the alumina chemical bond is a prior art float method or a down-draw method. Or the continuous bonding chemical bond with the highest tensile strength in the flat glass material such as the turbulence method, so the scratch-resistant strength and toughness characteristics of the ultra-high aluminum scratch-resistant and tough glass material of the present invention are much better, as explained below;
  • the chemical bond of the tetrahedron formed by alumina in the glass network structure has the highest tensile strength, so the tetrahedron and alumina formed by alumina
  • the continuous bonding of SiO4 tetrahedrons with chemical bonds constitutes a continuous network structure, which is the highest tensile strength of the network structure in the glass materials such as the float method or the down-draw method or the turbulence method (the tensile strength is not the hardness), so
  • the tetrahedron formed by alumina and the SiO4 tetrahedron form a continuous network structure, which is the most fragile, least crackable, most scratch-resistant, and most wear-resistant nanometer in flat glass materials such as float or down-draw or turbulent flow.
  • Grade size chemical and physical properties materials; in the display glass, comparing the scratch resistance to the toughness is to compare the degree of damage of the glass network structure after repeatedly scraping the surface of the glass with a
  • the hardness index is only one scratch test; while the scratch test is worn several times, and the cover glass of the mobile phone is adapted to several times of metal hard scratching;
  • the tetrahedral formed by alumina and the SiO4 tetrahedron form a continuous network structure of alumina chemical bonds, and have the highest tensile tensile mechanical strength of flat glass materials such as the float method or the down-draw method or the turbulent flow method, and
  • 25% of the alumina tetrahedron is combined with a 25% SiO4 tetrahedron continuously bonded by the alumina chemical bond to form a continuous network structure.
  • the ultra-high aluminum scratch-resistant low-alkali glass material of the present invention compares the three-dimensional density of the tough continuous network structure of the existing low-aluminum medium-low alkali glass material (such as GORILLA scratch-resistant glass). Therefore, judging from the basics, the ultra-high aluminum scratch-resistant low-alkali glass material of the present invention has the most non-fragile, most non-cracking, most scratch-resistant, most wear-resistant, most scratch-resistant, strong toughness characteristics. It will be better than the existing low-aluminum medium-low alkali glass materials (such as medium-aluminum glass scratch-resistant glass) several times. (There will be accurate wear test comparison data in the future)
  • the tetrahedral and SiO4 tetrahedrons formed by a finer 50,000 times smaller than 50 micrometers constitute a continuous network structure of the fracture (nano-scale chemical and physical properties change), not only invisible to the naked eye, general microscope and 30000 The electron microscope below the magnification is not visible.
  • the characteristics of the sag of the flat glass are determined by the flexural strength; the higher the flexural strength, the smaller the downward sag of the same weight and the same thickness of the flat glass; the higher the flexural strength, the better it is.
  • the damage rate is reduced in the process of the large-sized surface, and the non-obvious technical effect is obtained.
  • a liquid crystal display screen produced by a process of first printing and re-sintering a thin film transistor which comprises
  • the LCD screen includes:
  • An array substrate comprising a glass substrate, and a pixel structure produced by a process for printing a thin film transistor raw material on a glass substrate and then sintering the thin film transistor on the glass substrate;
  • the glass substrate is the one according to claim 1. High softening point, low difference of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass;
  • the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
  • the process of first printing a thin film transistor raw material and then sintering the thin film transistor is the latest technology research and development direction.
  • Non-obvious technical effect [1]:
  • the ⁇ performance electronic glass of the present invention has a difference in thermal expansion rate in the more severe high temperature region of 650 ° C to 700 ° C within 0.1-0.99 parts per million, in a more severe high temperature area 700
  • the difference in thermal expansion rate at °C-740 °C is within 1-5.9 or 6-8 parts per million. This increases the controllable range of the high temperature process; because of the poor thermal expansion rate of all the high temperature regions of the glass, the sintering temperature cannot be increased by 70 ° C; therefore, the present invention can use the film transistor raw material printed on the roll-to-roll glass substrate first.
  • Non-obvious technical effect [2] The present invention can achieve a thin film transistor that overcomes the prior art printing technology by increasing the sintering temperature of the thin film transistor, because the thermal expansion coefficient of the high temperature region of the glass is poor, and the sintering temperature cannot be raised.
  • the film transistor is not sufficiently sintered, resulting in poor precision, poor quality and low yield; the prior art also has a problem that the glass is too thin after thermal expansion, the precision is poor, the quality is poor, and the yield is low;
  • a high performance curved liquid crystal display comprising:
  • the substrate glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;
  • An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
  • the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2]: In the application place, the invention is in the zone, especially comparing the prior art of comparison [1][2][3][4]: in the process of thin film transistor or touch conductive film
  • the high temperature zone state due to the higher softening point of the flat glass of the invention, better high temperature zone thermal expansion difference, higher strength and the like, the shape of the glass can be maintained; especially the better thermal expansion in the high temperature zone
  • the value will greatly enhance the color registration accuracy of the phase element and the beam splitter, which can produce a higher 2-5 times resolution of the non-obvious technical effect of the display than the prior art 2;
  • Non-obvious technical effects [3]: Existing LEDs can make curved mobile phones and TVs with a certain degree of curvature, but since the substrate glass is too thick to 0,5-0,7mm, the strength is poor, so the 0 of the present invention cannot be produced. , 1-0, 3mm high-strength substrate glass; this new material invention, because the invention can produce the latest ultra-thin high tensile strength characteristics, has excellent Young's modulus of elasticity (previous material description), Provides high-strength substrate glass material properties of 0,1-0,3mm that are impossible for other TFT electronic glasses. It can produce more curved surfaces and the most rupture, ⁇ ⁇ yield, more ergonomic Curved phones and TVs with a higher curved curvature. Therefore, the invention can support the development direction of the curved touch screen industry such as mobile phones, tablet computers, notebook computers, and liquid crystal televisions, and has non-obvious technical effects.
  • Non-obvious technical effect For example, in the case of adopting a cover glass layer, only the upper glass of the two-layer TFT glass is subjected to the composite touch screen process, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained.
  • the rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;
  • Non-obvious technical effects [5]: The curved liquid crystal display is more in line with the physiological principles of the human eye, enabling people to see the screen more clearly.
  • a high-performance OLED organic light-emitting display screen comprising: a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;
  • Non-obvious technical effect [1]: The upper line range of the crystallization temperature zone of the present invention and the natural temperature drop condition of the specified instrument, after 45 minutes - 2 hours, will be in the upper line range of the glass crystallization temperature zone. Under the conditions of gradual cooling, crystallization is started under the conditions, and the crystallization rate is slow; this can form extremely important precision in the cooling part and the forming part, especially for the float process and various flat glass processes. There are much better process control parameters for contrast technology, so that you can control large production with precise and precise control. Thereby producing a high quality ultra-high strength, thinner electronic flat glass of the invention without any crystallization due to crystallization;
  • the OLED organic light-emitting display has the advantages of being lighter and thinner, requiring no backlight, more power saving, better color effect, and faster response.
  • the fireproof and explosion-proof flat electronic glass of the invention has an alumina content of 25-39% and a detonation strength of 150-240 MPa, so the present invention has the strength ability to resist deformation and cracking of too thin glass.
  • Non-obvious technical effects a wearable and high-strength mobile phone, or a transparent glass back casing of a tablet or laptop or desktop computer; can be combined with a transparent display of a mobile phone or a tablet computer to form a transparent and wear-resistant And high-strength mobile phones that are resistant to falling, or products of tablet computers.
  • a high performance bulletproof and explosion proof vehicle comprising:
  • the bulletproof glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass;
  • Each piece of glass plate is bonded by a resin sheet;
  • instrument panel instrument panel; direction controller; car shell; car chassis; car brakes;
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. Technical effect.
  • Non-obvious technical effects [4]: It can help to prevent people or cars from escaping from the fire zone when the vehicle is hit by fire. It increases the safety of the people inside the vehicle and prolongs the chance of driving away.
  • Non-obvious technical effects [5]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
  • Non-obvious technical effect [6]: Since the present invention can manufacture a 5-6 mm thick bulletproof and explosion-proof glass made of 3-layer glass with special strength, the ballistic performance can also be superior to the conventional 25 mm thick composed of 3 layers of glass.
  • the F79 grade full glass bulletproof glass (steel core bullet for anti-pistol), the invention is also light and thin 4-5 times.
  • the ballistic performance can also be superior to the conventional 40 mm thick F56 grade consisting of three layers of glass (anti-56/AK47 submachine gun or 81 rifle steel core bullet) full glass bulletproof glass ; also thin and light 4-5 times, which is the new material nature of other existing existing glass.
  • a new comprehensive function car combination invention terminal that is bulletproof, explosion-proof, anti-robbery theft and anti-injury, anti-rolling injury, anti-collision damage, and overwhelming safety level plus gorgeous and light.
  • the product has a new comprehensive function car combination with anti-ballistic, explosion-proof, anti-robbery theft and anti-injury, anti-rolling damage, gorgeous and lightweight, anti-collision, inventing the terminal product, and the light and beautiful car life experience also has both Preventing theft, burglary, and robbing of the window of the window due to the axe or steel hammer hitting is a kind of peace of mind and the feeling of driving and riding life experience (people only need to be in the car) Not afraid of being robbed, not afraid of being injured by the robbers, not afraid of being shot, not afraid of being blown up by grenades)
  • a high-performance anti-robbery, anti-theft, explosion-proof, anti-collision, anti-rolling injury car which includes:
  • bulletproof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass;
  • instrument panel instrument panel; direction controller; car shell; car chassis; car brakes;
  • Non-obvious technical effect [1]: The invention has a beautiful, lightweight and anti-collision new integrated function automobile combination invention terminal product, which is light and attractive, and has a gorgeous car life experience, and also has protection against an axe or a steel hammer. Strike, destroy the anti-stolen, anti-robbery, anti-robbery function of the window of the car window, is a kind of peace of mind and the feeling of driving and riding life experience (people are not afraid of being robbed in the car, not afraid Personal being injured by the robbers)
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. Technical effect.
  • Non-obvious technical effects [4]: It can help to prevent people or cars from escaping from the fire zone when the vehicle is hit by fire. It increases the safety of the people inside the vehicle and prolongs the chance of driving away.
  • Non-obvious technical effects [5]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
  • Non-obvious technical effects [6] Therefore, we can creatively produce new types of anti-robbing theft and anti-injury, anti-rolling damage, anti-collision and injury, and a level of safety plus gorgeous and lightweight.
  • the support force is greatly increased, so the anti-vehicle tumbling damage function of the present invention has a non-obvious technical effect.
  • Non-obvious technical effects [6]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • a high performance solar aircraft having a propeller power for propelling flight, a wing, a driving control system device, and a thin film solar device comprising: a thin film solar cell; a substrate glass on a thin film solar device, According to the invention as claimed in claim 1, a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass are provided.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effect [2]: A solar powered aircraft of the present invention can be filled with a machine due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in a high temperature region, higher strength, and the like.
  • the solar glass panel of the wing is more heat and temperature resistant than all existing solar glass panels.
  • Non-obvious technical effects [3]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
  • Non-obvious technical effect [4]:
  • the solar aircraft of the present invention can reduce the solar glass panel covered with the fuselage wing to only 1/4-1 due to the 4-5 times improvement in strength. /5, can also make the frame supporting the solar glass plate light and thin to only 1/4-1/5; can also greatly reduce the design of the fuselage support supporting the solar glass plate; and because the above part of the traditional solar aircraft occupies A large portion of the total weight, which produces the solar powered aircraft of the present invention,:
  • the solar energy of the invention may be greatly reduced due to the innovation, so that the same solar power can achieve faster air flight speed;
  • the utility model relates to a composite board of high-performance color glaze flat glass and metal layer, wherein the glass composition is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof explosion-proof
  • the flat glass has a glaze layer of 1-10 colors on the surface of the substrate glass, a metal plate with a thickness of 0.1-5 mm, and a layer of adhesive material between the glass plate and the metal plate.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. Technical effect There is a special building material fireproof and explosion-proof effect, which will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects In the installation of interior and exterior walls of buildings, it has the convenience and lightness of construction and use of aluminum-plastic composite panels and aluminum panels; it also has many times more strength and flatness than aluminum-plastic composite panels. And the pattern texture of stone and wood that does not change color for hundreds of years. Has a non-obvious technical effect. It represents a new trend in decorative materials in the installation of interior and exterior walls of buildings.
  • Non-obvious technical effects [4]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
  • Non-obvious technical effects [5]: In the above-mentioned better quality with the prior art and the strength can be 4-5 times higher than the existing flat glass, the discovery and production of this new product property makes color
  • the combined invention of the glaze layer produces a [composite board product of high performance glazed flat glass and metal layer] capable of producing a thickness of 1-3 mm [equal to the strength of calcium-sodium silicate glass of 5-15 mm], for the current country Standard external wall hanging board 12mm thick ceramic products and 25mm thickness stone product standard, the invention of high strength, thin and light [4-25 times] replacement, resulting in energy, resources, logistics, storage 4-25 times savings Unexpected effect.
  • Non-obvious technical effect [6]: a. A high-performance color glaze flat glass and metal layer composite board product, which can overcome the expansion and contraction deformation of the aluminum-plastic panel after being used for the outer wall due to the plastic plate being exposed to the sun for one year. Defects with poor flatness; b. It can overcome the printing of aluminum-plastic plate pattern as organic material, and can not be used as the outer wall defect in the outer wall for 1-2 years; c. The composite plate with aluminum film layer of the invention has fine patterns. None fade, the flatness is excellent, and the life expectancy is 50-80 years.
  • Non-obvious technical effect A high-performance color glaze flat glass and metal layer composite board product, which can be installed as easy as aluminum-plastic board;
  • Non-obvious technical effect [8]: A high-performance color glaze flat glass and metal layer composite board product: a. It can be installed as easy as the external wall dry hanging aluminum plate; b. There is also an external wall dry hanging aluminum plate Less than Flatness and appearance of fine stone or wood grain pattern; c. or external wall dry hanging aluminum plate can not be used, all kinds of 300 years of non-fading inorganic color glaze yellow, blue, gray, white, black and other monochrome Decorative effect
  • a high-performance glazed glass composite material board having a simple structure installed on a wall surface, the structural composition thereof is that the glass is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. , low crystallization rate, application of fireproof and explosion-proof flat glass, the surface of the substrate glass has 1-10 colors of glaze layer, 0.1-5mm thickness of metal plate, there is a layer of bonding material between the glass plate and the metal plate
  • the layer is characterized in that: 2-4 sides of the metal plate on the back bottom surface of the composite board of the product, and the edge of the surface glazed decorative flat glass product of the specific gravity protrudes by a distance of 10-30 mm.
  • Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
  • Non-obvious technical effects [4]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
  • Non-obvious technical effects [5]: In the above-mentioned better quality with the prior art and the strength can be 4-5 times higher than the existing flat glass, the discovery and production of this new product property makes color
  • the combined invention of the glaze layer produces a sufficient strength to produce a thickness of 1-2 mm [equivalent to 5-15 mm of calcium soda glass strength] [a high-performance, glazed glass composite with a simple structure installed on the wall surface) Material board Product], for the current national standard external wall hanging board 12mm thick ceramic products and 25mm thickness stone product standard, the invention is high-strength, light and thin [6-25 times] replacement, generating energy, resources, logistics, warehousing Unexpected results of 6-25 times savings.
  • Non-obvious technical effect [6]: a. A high-performance, glazed glass composite board product with a simple structure installed on the wall surface, which can overcome the use of aluminum-plastic composite panels on the outer wall after the plastic panels are exposed to the sun. 1 year, the expansion and contraction deformation, the flatness is very poor; b. can overcome the aluminum-plastic plate pattern printing as an organic material, the outer wall 1-2 years discoloration can not be used as the outer wall defect; c. the invention of the aluminum film layer
  • the composite board has the advantages of fine pattern, never fade, excellent flatness and long life of 50-80 years.
  • Non-obvious technical effect [7]: A high-performance, glazed glass composite board with a simple structure installed on the wall: a. It has the same advantages as the dry hanging aluminum panel on the outer wall; b. There is also the effect that the outer wall can not be used for hanging aluminum plates, the surface is flat and has the effect of fine stone or wood grain pattern; c. or the outer wall can not be used for hanging aluminum plates, all kinds of inorganic glazes that are not faded for 300 years. Monochrome decorative effects such as yellow, blue, gray, white, and black;
  • the tile and stone construction is not allowed to be pasted; and the present invention is a high-performance, glazed glass composite material having a simple structure installed on the wall surface.
  • the board, the safe and firm wall used for construction, is directly nailed into the wall with the expansion boring nail, and the 4-6 strips of 4-8cm wide on the back are used to level the way [ie safe and secure, labor-saving and efficient way) Mainly, a small amount of tile adhesive is leveled and pasted as an auxiliary method];
  • the present invention can solve the problem that when the decorative panel is pasted and installed in a certain degree of external wall [such as 4-60M]:
  • Non-obvious technical effect [3]: The thin and light-colored glazed decorative flat glass has a side extending 10-30mm away, and is punched directly into the wood or brick after the perforated side is punched.
  • the material or the concrete wall; or the innovative installation fixed with the wall dragon skeleton, the characteristics of the inner and outer wall applications are: [1] the installation method is very simple and quick and effective; [2] the product is more than the stone and the tile Light and thin 6-20 times; [3] The safety after installation is much higher than that of the stone and tile attached to the wall, and will never fall; [4] There is also a stone with strong strength and flatness and no discoloration for hundreds of years. And wood pattern texture; [5] is particularly suitable for interior and exterior wall applications in wooden villas or low-rise buildings; with non-obvious technical effects. It represents a new trend in decorative materials in the installation of interior and exterior walls of buildings.
  • a high-performance, glazed glass composite floor with an easy-to-assemble structure is a high-performance, glazed glass composite floor with an easy-to-assemble structure:
  • a high-performance, glazed glass composite flooring with easy-to-assemble structure including: [1] surface glazed glass substrate, [2] adhesive layer, [3] bottom layer, features It is: the surface layer of glazed glass material substrate is a high softening point, low differential coefficient of thermal expansion coefficient, low crystallization rate, fireproof and explosion-proof flat glass; 1-2 sides of the bottom layer, the bottom layer has protruding glass The outer edge of the face is 1-25mm; the other 1-2 sides of the bottom layer, the bottom layer has a feature of 1-25mm concave edge of the glass surface; the thickness of the bottom layer of the convex or concave glass surface is the material of the bottom layer 10%-90% of the thickness.
  • a high-performance, glazed glass composite flooring with an easy-to-assemble structure the bottom layer: either a wood board; or a metal material board; or a wood board composite board; or a wood powder composite board; or It is a resin material board.
  • Non-obvious technical effects [1]: The low crystallization rate properties found, resulting in the technical effects of high quality and large production.
  • Non-obvious technical effects [2] In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the invention, better high temperature zone thermal expansion difference, higher strength and the like, high performance, the shape of the glass can be maintained, and the non-obvious technical effect of fireproofing and fireproofing can be achieved.
  • the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and the ability to prolong the fireproof and explosion-proof time and prolong the ignition time, and has a non-obvious technical effect.
  • the product of the invention solves the technical problem that the wood floor and the wood composite floor material are eager to solve without successful fireproofing, fireproofing, prolonging the fireproof and explosion-proof time and prolonging the ignition time, and represents a high level of ground decoration.
  • the development trend of material technology is a great to solve without successful fireproofing, fireproofing, prolonging the fireproof and explosion-proof time and prolonging the ignition time, and represents a high level of ground decoration.
  • the invention compares the apex of the first comparative technique [1][2][3][4] from 180Mpa, substantially improves and improves to the apex of the flexural strength 240Mpa; compared with the prior art [1][2 ][3][4]
  • the flexural strength is substantially improved and improved by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; compared with the existing aluminum-containing 12-15% touch screen glass
  • the flexural strength of 100 Mpa is increased by about 2.4 times; it is about 5 times higher than that of calcium sodium glass.
  • wood floor and wood type composite floor are generally 18mm thick; the invention can be only 4-5mm thick when the resisting strength is higher than wood;
  • the product of the invention solves the technical problem of the high-strength and light-weight effect which is solved by the people who are eager to solve the wooden floor and the wooden composite floor material, and represents the development of the high-level floor decoration material technology. trend.
  • the printing glaze layer can be sintered, and a large amount of various crystals such as 30-80% can be added to the glaze layer, especially the low cost. Quartz or steel jade crystal powder or granules, forming an unprecedented hardness of 0.2-3mm wear-resistant surface layer (quartz can reach 7 grade hardness, while adding steel jade can reach 9 grade hardness), and this is not in ceramic production
  • the firing temperature of the ceramic is between 1100 ° C and 1200 ° C
  • the quartz or steel jade of the ceramic surface can only become the glass phase, and below 730 ° C, the quartz or steel jade crystal can maintain the crystal phase; It can also form an unprecedented decorative glass polished quartz crystal with a hardness of 7 grade wear surface; it has non-obvious technical effects.
  • the product of the invention solves the technical problems of the high-level floor decoration material technology in the materials of the wooden floor and the wood composite floor, which people are eager to solve without successful abrasion resistance and easy drawing.
  • the surface substrate material is floated, it is more flat.
  • the non-obvious technical effect [6] is better than the pattern of wood flooring and wood composite flooring:
  • the product of the invention is used for designing and replacing all kinds of wood grain and stone grain and carpet products, not only has high strength, but is light and convenient to install and transport, and can also be printed by computer to ensure various wood grain and stone grain, and Carpet products such as wool, chemical fiber, silk material and other realistic carpet patterns;
  • the invention adopts the wooden material floor layer, and does not cause the glass edge to be winged or deformed from the whole wood floor and the wood composite floor, and has the traditional full wood floor and wood composite. Unmatched advantages of the floor;
  • the waterproof glue can be used for the purpose of completely waterproofing the invention, and has the advantages that the traditional wooden floor and the wooden composite floor are incomparable;
  • the invention compares the installation manner of wood grain tile, various tiles and stone paste on the ground;
  • the invention has the characteristics of innovative combination structure, so that the non-obvious technical effect of the installation is easy, and the installation method is as convenient as the wooden floor, the time is cheap, the labor is saved, the installation is 50-60 square meters for one day; the wood grain tile, Tiles, stone 50-60 square meters installation maintenance to 3-5 days.
  • the present invention compares wood grain tiles, various tiles, stone installation methods, cleaner, hygienic, environmentally friendly; and no excess sand, cement, please remove and transport;
  • the invention not only has the above-mentioned 7 kinds of technical effects, but also has the technical effect of convenient installation of the wooden floor; the invention solves the wood grain tile and various ceramic tiles which are desired to be solved without success in the floor decoration material.
  • the installation of stone is time-consuming, labor-intensive, and environmentally-friendly. It represents the development trend of high-level floor decoration materials technology.
  • the invention compares the way of wood grain tiles, various tiles, and stone paste on the ground:
  • the joint with the ground should be dismantled with a large drill or a sledgehammer, and 50-60 square meters should be dismantled, and 3-5 days may not be completed; the building is highly destructive, and the waste cargo is large and environmentally friendly;
  • the invention not only has the above-mentioned 7 kinds of technical effects, but also has the technical effect of dismantling conveniently like a wooden floor; and solves the wood grain tile, various ceramic tiles and stone removal technology which are desired and solved without success in the floor decoration material.
  • the problem represents the technical development trend of high-level floor decoration materials.
  • the invention has a layer below: either a wood board; or a wood board composite board; or a wood powder composite board; or a bottom layer of a resin material; but since it is installed like a wooden floor, there is a layer of bottoming a layer of wood or a wooden strip; that is, a combination of a 'recessed outer lower portion of the bottom layer' and a layer of bottomed wood or wooden strip, which is formed by a number of small nails (ie, wood)
  • the installation method of the floor) and the pressure of the floor layer this can produce the same elasticity under the feet as the wooden floor.
  • the invention can also be assembled directly on the surface quickly; the installation construction is cleaner than cement, high efficiency, convenient, and can also produce high simulation wood texture or stone texture. Decorative effect.
  • the invention is not only used for the imitation wood grain product, especially when used in various ground products with high embellished stone pattern ornate decorative effect, comparing the tile, stone product and directly pasting on the cement floor: non-obvious technology
  • the effect is:
  • the present invention in the use of a high-performance, glazed glass composite flooring having an easy-to-assemble structure, utilizes these new properties and utilizes the combined inventive functional features of the easy-to-assemble structure to produce Unexpected technical effects are also unclear in common sense and cannot be inferred from common sense. The nature of these new discoveries and the unpredictable technical effects of using these new properties have not been disclosed by all prior art.
  • a high-performance glass wash basin produced by a thermal deformation process which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold, characterized in that:
  • the flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass.
  • a high-performance glazed glass wash basin produced by a thermal deformation process which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold.
  • the utility model is characterized in that: the flat glass material is a high softening point, a low difference of a thermal expansion coefficient in a high temperature zone, a low crystallization rate, a fireproof and explosion-proof flat glass; and a color shaft layer is attached to the glass.
  • a high-performance glazed glass lifting panel and a combined wash basin produced by a thermal deformation process the structural features of which are: 1. a flat-shaped lifting panel; 2. another part of the joint is a flat panel Glass material consists of a desired wash basin-shaped mold, a glass wash basin produced by a thermal deformation process; 3. The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, and a low resolution Crystal speed, fireproof and explosion-proof flat glass; 4. The glass surface is attached with a color shaft layer.
  • a high-performance glazed glass washbasin countertop for a bathroom characterized in that: 1.
  • the countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, and a low analysis Crystal speed, application of fireproof and explosion-proof flat glass; 2. glazed layer of 1-10 colors on the surface or back of the table; 3. There is a hole for installing the wash basin on the surface of the table; 4. Supporting device at the lower part of the table .
  • Non-obvious technical effects [1]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it is exposed to fire or high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious.
  • the technical effect of the invention has the special fireproof and explosion-proof effect of the furniture, which greatly enhances the ability of bursting in the high temperature region when the glass volume is rapidly increased, and has non-obvious technical effects.
  • Non-obvious technical effects [2]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4];
  • the existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass.
  • Non-obvious technical effects [3], various high-performance glazed glass lifting panels: a., the appearance of high-simulation wood grain, stone artefact and appropriate product design entry point; b. brand new inorganic Glaze set The unique technical characteristics of the sturdy and wear-resistant of the high-strength glass; c. It is stronger than the traditional stone or artificial stone lifting panel, high strength, light and thin, easy to install, and very environmentally friendly.
  • An ultra-long glass plate for a balcony protection barrier is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is characterized in that the length of the glass plate of the balcony protection barrier is 3-8 m.
  • Non-obvious technical effect In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior comparison technology [1][2][3][4]; compared with the existing TFT Boron-containing glass, light and thin 1/3; lighter than calcium sodium glass, 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight. It also enables the strength of the glass to be five times higher than the strength of the existing calcium soda glass at the same weight.
  • the technical effect of the coating of the invention is that the glass materials for construction are all sodium soda glass, the strength is only 50Mpa; and the performance glass of the invention can reach 180-240Mpa, and the geometric multiple of 4-5 times is higher.
  • the strength of the building glass can be prevented from impact, explosion-proof, anti-shock performance, etc., and the safety is increased by 4 times -5 times;
  • the length of the glass plate which can be designed as a balcony protection barrier is 3-8m in length, not all in the length of 3-8m, and is divided and blocked by the erect aluminum alloy frame; it is an unobstructed panoramic building balcony glass, When sitting on the curtain of the balcony, the eyesight is only about 70cm.
  • the height of the glass plate of the balcony protection barrier can be designed to be 0.9m-1.3m. If there is a horizontal protection armrest with a length of 3-8m, it is also designed to be 0.9m-1.3m);
  • the balcony building space can have: outdoor scenery + tea bar for family members or guests, or outdoor scenery + coffee bar or family for family, or guests; Or the outdoor beauty + bar with the guests; or the family, or the outdoor scenery + reading bar with the guests; or the family, or the outdoor beauty + computer bar with the guests; innovative balcony building space function;
  • FIG. 1 is a schematic plan view showing a high softening point, a low crystallization rate, a special aluminum non-alkali, fireproof and explosion-proof flat glass according to the present invention
  • FIG. 2 is a schematic flow chart of a float process for preparing a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a preparation process of fireproof and explosion proof flat glass;
  • FIG. 3 is a side cross-sectional view showing a state in which a high softening point, a low crystallization rate, a special aluminum non-alkali, and a fireproof and explosion-proof flat glass are prepared by a float process.
  • the size of the embodiment is 1220 mm ⁇ 2440 mm and the thickness is about 2-5 mm.
  • the color glaze of the three color zones forms a plan view of a glazed flat glass article whose surface layer is a predetermined glaze pattern decorative layer of about 0.1-1 mm thickness.
  • Figure 5 is a high softening point, low crystallization rate, special aluminum non-alkali, fireproof and explosion-proof flat glass of the present invention
  • the back side is an aluminum plate with overlapping rear side without exceeding the size of the surface silicate glaze decorative glass, through the sticking
  • Figure 6 is a high softening point, low temperature coefficient of thermal expansion coefficient of low temperature, low crystallization rate, application of fireproof and explosion-proof flat glass, the back is overlapped with two sides than the surface silicate glaze decoration The glass sizes are each extended.
  • the back side has two sides than the surface silicate glaze decorative glass size
  • An aluminum plate with a distance of 10-30 mm is extended, and a cross-sectional structure diagram of a new composite plate composed of a composite material is adhered to each other.
  • the crosshair portion indicates the printed second color area glaze pattern area
  • the small black dot portion indicates the printed third color area glaze pattern area
  • Inventive Example 1 (preferably an alkali-free product example)
  • the alumina content is 29.2%
  • the sodium oxide content is 0.1%
  • the silica content is 47.2%
  • the calcium oxide content is 13%
  • the magnesium oxide content is 10.5%, which is characterized by: the silica content is oxidized.
  • the calcium content is 3.6 times and the calcium oxide content is 1.2 times the magnesium oxide content.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1540 ° C; in this example, when the glass bubbles are discharged, the glass temperature is 10 2 (Pa ⁇ s) and the viscosity temperature is 1390 ° C.
  • the anti-analytical strength is 192 MPa.
  • the crystallization rate of the present invention will be relatively slow, and the crystallization will start after 60-120 minutes under the condition that the upper line range of each glass crystallization temperature zone is gradually lowered.
  • the prior art 2 has a difference in thermal expansion rate between 550 ° C and 600 ° C in the high temperature region and 600 ° C to 650 ° C in the high temperature region. Values range from 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 2-5 parts per million in the high temperature region of 700 ° C to 740 ° C.
  • the difference in thermal expansion rate of the other glass in the high temperature region is much lower;
  • This example of the invention has a high softening point of up to 825 °C.
  • Inventive Example 2 (preferably an alkali-free product example)
  • the alumina content is 23.9%, the sodium oxide content is 0.1%, the silica content is 53%, the calcium oxide content is 15.5%, and the magnesium oxide content is 9.5%, which is characterized by: the silica content is oxidized.
  • the calcium content is 3.9 times and the calcium oxide content is 1.4 times the magnesium oxide content.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1570 ° C; in this example, the actual glass discharge bubble viscosity temperature 10 2 (Pa ⁇ s) 1435 ° C.
  • the analytical strength is 172 MPa.
  • crystallization is started after 60-90 minutes under the condition of gradually lowering the upper line range of each glass crystallization temperature zone.
  • the prior art 2 has a difference in thermal expansion rate between 550 ° C and 600 ° C in the high temperature region and 600 ° C to 650 ° C in the high temperature region. Values range from 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 2-5.5 parts per million in the high temperature range of 700 ° C to 740 ° C.
  • the present invention has a high softening point of up to 825 ° C;
  • Inventive Example 3 (preferably an alkali-free product example):
  • the alumina content is 36.5%
  • the sodium oxide content is 0.2%
  • the silica content is 40.3%
  • the calcium oxide content is 12%
  • the magnesium oxide content is 11%, which is characterized by: the silica content is oxidized.
  • the calcium content is 3.35 times and the calcium oxide content is 1.1 times the magnesium oxide content.
  • the actual melting time was 10 1.5 (Pa ⁇ s) viscosity temperature of 1660 ° C; in this example, the bubble temperature of 10 2 (Pa ⁇ s) was 1475 ° C.
  • the anti-analytical strength is 228 MPa.
  • the upper line range of the crystallization temperature zone is naturally cooled, the upper line range of each glass crystallization temperature zone is gradually lowered under the condition of 60-120 minutes. Start crystallization.
  • This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 2-4 parts per million in the high temperature range of 700 ° C to 740 ° C.
  • the difference in thermal expansion rate of the other glass in the high temperature region is much lower;
  • the present invention is greatly increased in softening point by 840 ° C;
  • This example also has a very wide range of special glass, electronic glass, architectural glass, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increasing, and can be used in the display of electronic glass display products.
  • the nature of the resolution level can be substantially improved and improved.
  • Inventive Example 4 (preferably an alkali-free product example)
  • the alumina content is 16.5%
  • the sodium oxide content is 0.1%
  • the silica content is 52%
  • the calcium oxide content is 18%
  • the magnesium oxide content is 15.4%, which is characterized in that the silica content is oxidized.
  • the calcium content is 2.9 times and the calcium oxide content is 1.2 times the magnesium oxide content.
  • the actual melting time is 10 1.5 (Pa ⁇ s) and the viscosity temperature is 1460 ° C.
  • the glass temperature is 10 2 (Pa ⁇ s) and the viscosity temperature is 1360 ° C.
  • the analytical strength is 126 Mpa.
  • the upper line range of the crystallization temperature zone is naturally cooled, the upper line range of each glass crystallization temperature zone is gradually lowered under the condition of 60-90 minutes. Start crystallization.
  • This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 6-8 parts per million in the high temperature region of 700 ° C to 740 ° C.
  • the difference in thermal expansion rate of the other glass in the high temperature region is much lower;
  • the softening point of the present invention is as high as 785 ° C;
  • Embodiment 5 of the present invention is a diagrammatic representation of Embodiment 5 of the present invention.
  • the alumina content is 24%
  • the sodium oxide content is 3.4%
  • the silica content is 49.6%
  • the calcium oxide content is 15%
  • the magnesium oxide content is 10%, which is characterized by: the silicon oxide content is oxidized.
  • the calcium content is 3.8 times and the calcium oxide content is 1.3 times that of the magnesium oxide.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1520 ° C; in this example, when the glass bubbles are discharged, the glass temperature is 10 2 (Pa ⁇ s) and the viscosity temperature is 1400 ° C.
  • the anti-analytical strength is 161 MPa.
  • the crystallization rate of the present invention is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled under the condition of 60-120 minutes. After that, crystallization will begin under the conditions of the upper line of the glass crystallization temperature zone and the gradual cooling.
  • This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million 0.1-0.99 Within the high temperature region of 700 ° C - 740 ° C, the difference in thermal expansion rate is within 1-5.9 or 6-8 parts per million.
  • the difference in thermal expansion rate of the other glass in the high temperature region is much lower; in addition, the softening point of the present invention is greatly increased to 765 ° C;
  • Embodiment 6 of the present invention is a diagrammatic representation of Embodiment 6 of the present invention.
  • the alumina content is 20.8%
  • the sodium oxide content is 3.2%
  • the silica content is 53%
  • the calcium oxide content is 15.5%
  • the magnesium oxide content is 9.5%, which is characterized by: the silica content is oxidized.
  • the calcium content is 3.9 times and the calcium oxide content is 1.4 times the magnesium oxide content.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1510 ° C; in this example, the actual glass discharge bubble viscosity temperature 10 2 (Pa ⁇ s) 1385 ° C.
  • the analytical strength is 148 MPa.
  • crystallization rate is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled, crystallization is started after 60-90 minutes.
  • the present invention has a high softening point of 775 ° C;
  • This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, and the difference between the thermal expansion rates of 650 ° C and 700 ° C in the high temperature range is in parts per million.
  • the difference in thermal expansion rate is within 1-5.9 or 6-8 parts per million. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;
  • Embodiment 7 of the present invention is a diagrammatic representation of Embodiment 7 of the present invention.
  • the alumina content is 35.4%
  • the sodium oxide content is 2.1%
  • the silica content is 42%
  • the calcium oxide content is 12%
  • the magnesium oxide content is 8.5%, which is characterized by: the silica content is oxidized.
  • the calcium content is 3.5 times and the calcium oxide content is 1.4 times the magnesium oxide content.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1580 ° C; in this example, the bubble temperature is 10 2 (Pa ⁇ s) viscosity temperature 1425 ° C.
  • the anti-segregation strength is 213 MPa.
  • the present invention has a much lower content ratio of calcium oxide (the content of calcium oxide is too high, and the crystallization rate is accelerated), and the content ratio of silicon oxide is higher, so the crystallization rate of the present invention is relatively slow.
  • the softening point of the present invention is as high as 820 ° C;
  • This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 or 6-8 in the high temperature range of 700 ° C to 740 ° C.
  • the difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.
  • Embodiment 8 of the present invention is a diagrammatic representation of Embodiment 8 of the present invention.
  • the alumina content is 36.5%
  • the sodium oxide content is 2.2%
  • the silica content is 40.3%
  • the calcium oxide content is 12%
  • the magnesium oxide content is 9%, which is characterized by: the silica content is oxidized.
  • the calcium content is 3.35 times and the calcium oxide content is 1.3 times the magnesium oxide content.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1630 ° C; in this example, the bubble temperature is 10 2 (Pa ⁇ s) viscosity temperature 1415 ° C.
  • the analytical strength is 221 MPa.
  • the crystallization rate of the invention will be relatively slow, and the crystallization of the upper line of the crystallization temperature zone will naturally begin after 60-150 minutes.
  • the softening point of the present example of the present invention is as high as 830 °C.
  • This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C.
  • the difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.
  • the alumina content is 16.6%
  • the sodium oxide content is 0.3%
  • the silica content is 59.3%
  • the calcium oxide content is 13.8%
  • the magnesium oxide content is 10%, which is characterized by: the silica content is oxidized.
  • the calcium content is 4.3 times and the calcium oxide content is 1.38 times the magnesium oxide content.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1580 ° C; in this example, 10 2 (Pa ⁇ s) viscosity temperature is 1460 ° C; the anti-segregation strength is 134 Mpa.
  • the crystallization rate of the invention will be relatively slow, and the crystallization of the upper line of the crystallization temperature zone will naturally begin after 60-150 minutes.
  • the softening point of this example of the present invention is very high, up to 810 °C.
  • This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C.
  • the difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.
  • Inventive Example 10 (preferably an alkali-free product example)
  • the alumina content is 17.8%
  • the sodium oxide content is 0.3%
  • the silica content is 59.3%
  • the calcium oxide content is 12.51%
  • the magnesium oxide content is 10%, which is characterized by: the silica content is oxidized.
  • the calcium content is 4.7 times and the calcium oxide content is 1.26 times the magnesium oxide content.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1620 ° C; in this example, 10 2 (Pa ⁇ s) viscosity temperature is 1480 ° C; the anti-segregation strength is 138 Mpa.
  • the crystallization rate of the invention will be relatively slow, and the crystallization of the upper line of the crystallization temperature zone will naturally begin after 60-150 minutes.
  • the softening point of the present example of the present invention is as high as 830 °C.
  • This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C.
  • the difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.
  • prior contrast technology [1]: The inventor's prior invention: the application of high-strength, high-level, low-viscosity flat glass with high annealing point and environmental protection and energy saving, and related components, patent number 201110060944.4 ,
  • the glass of this specific composition has sharp crystallization peaks in the DSC curve at the strong crystallization temperature range, and the conversion time of the glass from liquid to crystallization devitrification is short and fast, and there is a technical difficulty in crystallization and devitrification in the cooling process.
  • the content of silicon oxide is 1.9 times -4.1 times the content of calcium oxide, and the content of calcium oxide is 1.0 times -1.8 times the content of magnesium oxide;
  • the content of silicon oxide is 4.11 times - 5.48 times of the content of calcium oxide, and the content of calcium oxide is 0.8 times - 1.99 times of the content of magnesium oxide;
  • the content of silicon oxide is 1.6-5.8 times that of calcium oxide, and the content of calcium oxide is 0.8--2.1 times of magnesium oxide;
  • the invention belongs to a new use invention of a chemical product: in the technical solution, the content of silicon oxide is 2.51 times to 4.8 times of the content of calcium oxide, and the content of calcium oxide is 1.0 times to 1.8 times of the content of magnesium oxide;
  • the invention belongs to a new invention invention of chemical products:
  • the silicon oxide is 2.51 times-4.8 times that of calcium oxide; the calcium oxide is 1.0 times of magnesium oxide-
  • the technical solutions other than the front and back ends of the 1.8-fold range cannot have [the formation of the above four properties of abcd and the various effects produced, and substantial improvements and improvements], and there are several defects:
  • Comparative Example 2 The technical content of the comparative technique [3] has a silica content of 4.11 times to 5.48 times of the calcium oxide content of 4.11 times to 5.48 times, and a back end of 1.6 to 5.8 times of the comparative technique [4]. In the range of 4.81 times to 5.8 times: Comparative Example 2 [Comparative Example of SiO2 content which is 5.3 times of calcium oxide content]. The silica content of the present invention is outside the range of 2.51 to 4.8 times the calcium oxide content.
  • Comparative Example 2 In terms of weight percent, the alumina content was 20%, the sodium oxide content was 1%, the silica content was 58%, the calcium oxide content was 11%, and the magnesium oxide content was 10%, which was characterized by: [The content of silicon oxide is 5.3 times that of calcium oxide], and the content of calcium oxide is 1.1 times that of magnesium oxide.
  • the viscosity temperature is too high, which can not be measured by the US THETA rotary high-temperature viscometer; in this example, the bubble temperature is 10 2 (Pa ⁇ s) viscosity temperature is 1610 ° C [than calcium sodium glass row When the bubble is 10 2 (Pa ⁇ s), the viscosity temperature is 1430 ° C and ⁇ 180 ° C; it is difficult to discharge bubbles during large production;
  • the first comparison technology [1].[2].[3] the technical solution: such as 1.9 times -4.1 times the front end of the comparison technology 2 1.9-2.5 times and the front end of the comparative technology 4 1.6-5.8 times 1.6- 2.5 times, outside the scope of the present invention, results in a known knowledge of known compounds [a. faster crystallization rate of material properties];
  • Comparative Example 1 This is the prior art [2] technical solution, the silicon oxide content is 1.9 times -4.1 times the front end of the calcium oxide content is 1.9-2.5 times, and the front end of the comparative technology [4] is 1.6-5.8 times. In the range of 1.9-2.5 times in the range of 1.6-2.5 times, [the silica content is a comparative example of 2.0 times the calcium oxide content]. The silica content of the present invention is outside the range of 2.51 to 4.8 times the calcium oxide content.
  • Comparative Example 1 In terms of weight percent, the alumina content was 20%, the sodium oxide content was 8%, the silica content was 38%, the calcium oxide content was 19%, and the magnesium oxide content was 15%, which was characterized by: [The content of silicon oxide is 2.0 times that of calcium oxide], and the content of calcium oxide is 1.3 times that of magnesium oxide.
  • the actual melting time is 10 1.5 (Pa ⁇ s) viscosity temperature 1440 ° C; in this example, 10 2 (Pa ⁇ s) viscosity temperature is 1330 ° C;
  • the anti-semination strength is 136 Mpa.
  • Comparative Example 1 The crystallization rate will be relatively fast, and in the upper line range of the glass crystallization temperature zone, under gradual cooling conditions, crystallization will begin within 10 to 31 minutes. Therefore, it has great difficulties in large production; because of the bottom of the cooling part, the corners, or the glass area before the molding, the heating device and the temperature measuring device are added. However, due to the difference in heating time from the temperature point to the start of heating and the instability of the fluidity of the molten glass, in the large production, the crystallization rate is too fast, causing local crystallization, which also causes difficulty in producing flat glass. .
  • Comparative Example 1 In the high temperature region 550 ° C - 600 ° C, the difference in thermal expansion rate at 600 ° C - 650 ° C is 1-2.8 or 1-3 parts per million.
  • the difference between the thermal expansion rates of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, and in the high temperature range 650 ° C - 700 ° C, the difference in thermal expansion rate is Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C.
  • the difference in thermal expansion rate of the flat glass in the high temperature region is much lower than that of the present invention.
  • the invention belongs to a new invention invention of chemical products:
  • the product of the present invention and the prior comparative techniques [1][2][3][4] have the characteristics that the upper line [highest point] of the crystallization temperature is higher than the molding temperature; it is a glass material having two-sided characteristics: one side is The glass of this specific composition has sharp crystal peaks in the DSC curve at the strong crystallization temperature range, and the glass transition from liquid to crystallization devitrification is shorter and faster than other glasses; but the other side has low viscosity and high Aluminum and silicon, calcium, magnesium eutectic properties and other excellent characteristics; so in order to study the selective use of glass with slow crystallization rate in large production, it is beneficial to cool the glass in the cooling working part before molding. Process stage to reduce the risk of crystallization;
  • the process must be controlled by the crystallization temperature, and some heating control will be added especially in the liquid crystal edge and the corner and bottom which are easy to devitrify in the cooling working part.
  • the device in the glass liquid at the corners and bottom of the cooling working part, there will also be some products that flow slowly in the upper line range of the glass crystallization temperature zone, and the product with faster crystallization rate under the condition of gradual cooling, (such as There are comparative techniques [1][2][3][4]), the glass will produce partial crystallization within 10 to 31 minutes, there will be the risk of unqualified products entering the forming stage and causing partial devitrification of the flat glass. ;
  • the material properties of the present invention should be selectively used: [the glass liquid having a relatively slow crystallization rate after 60-150 minutes, the upper line range of the inner glass crystallization temperature zone, under the condition of gradual cooling, The crystallization of the glass material is 5 times slower than that of the prior art prior art [1][2][3][4], which can be especially used in the cooling section and the forming section. And a variety of flat glass processes, forming extremely important and precise process control parameters that are much better than the prior art, so as to accurately control the large production; thus overcoming the partial devitrification of the flat glass during the forming stage. The risk of a qualified product; thereby producing a high quality sheet glass of the present invention without any crystallization due to its influence on light transmittance;
  • the present invention has substantial improvements and improvements in the known properties of the known compounds [difference in the coefficient of thermal expansion of the high temperature region] and [softening point] properties and effects;
  • the difference in thermal expansion rate between 600 ° C and 650 ° C is 1-2.8 parts per million or 1-3
  • the difference in thermal expansion rate between 600 ° C and 650 ° C is 1-2.8 or 1-3 parts per million.
  • the invention has a difference in thermal expansion rate between 1500 ° C and 600 ° C in a high temperature region of from 1500 ° C to 650 ° C within a range of from 0.1 to 0.99 parts per million; and a thermal expansion rate in a more severe high temperature region of from 650 ° C to 700 ° C.
  • the difference is between 0.1-0.99 parts per million, and the difference in thermal expansion rate is between 1-5.9 parts per million in the harsher high temperature zone 700 °C-740 °C;
  • the softening point disclosed by the prior art [1] [2] [3] [4] is only 720 ° C; the softening point disclosed in the present invention is only 750-860 ° C.
  • the present invention is substantially improved and improved in view of the [difference in the coefficient of thermal expansion of the high temperature region] and the [softening point] properties and effects.
  • the glass of the invention is applied to: [1] automotive glass; architectural glass; marine glass; railway car glass; aircraft glass; fireproof, explosion-proof glass; special glass; [2] wall ground with glazed glass decoration Plate; [3] various glass furniture; [4] solar glass application products and other fields of use, when encountering fire or high temperature, it is not easy to burst due to the rapid increase of the glass volume in the high temperature zone, can be in the high temperature zone state The shape of the glass cannot be maintained; the comparative technology [1][2][3][4] has the effect of improving the technical effect of fire prevention, fire separation and heat insulation;
  • the comparison technology is first [1][2][3][ 4], it is not easy to cause bursting due to the rapid increase of the glass volume in the high temperature zone; it has the effect of improving the technical level of the technical effect.
  • the invention represents a technical development trend of electronic liquid crystal display glass and combined invention terminal products with high resolution level.
  • the present invention provides substantial improvements and improvements in the properties of the eutectic of aluminum, silicon, calcium, and magnesium at low viscosity and high aluminum content.
  • the product of the present invention in the application of flat glass is also substantially improved and improved by 1/3 times compared with the inventors of the prior art [1][2][3][4];
  • the flexural strength of the boron-containing glass is increased by about 3 times, which is about 3 times higher than that of the existing aluminum-containing 12-15% touch screen glass, and about 5 times higher than the calcium-sodium glass bending strength of 50 MPa.
  • the same strength of the present invention is also 1/3 times lighter than the prior art [1][2][3][4]; it is 3 times lighter than the existing TFT boron-containing glass; compared with the conventional soda lime glass bottle Light and thin 5 times;
  • Prior Invention 4 The inventor's: 201110060913.9, a high-annealing high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass.
  • the patent name is: crystallizable glass for fiber production
  • the present invention pertains to a novel use of a chemical product; an overview of the inventive features and objects of the invention:
  • the invention represents a trend in the development of the technology of the end product of the electronic liquid crystal display glass and the electronic liquid crystal display combination invention with high resolution level.
  • the present invention has found substantial improvements and improvements - [difference in coefficient of thermal expansion in high temperature regions] (i.e., difference in thermal expansion at high temperatures) and [material properties at high softening points]; thereby utilizing these properties,
  • difference in coefficient of thermal expansion in high temperature regions i.e., difference in thermal expansion at high temperatures
  • material properties at high softening points thereby utilizing these properties.
  • the difference in thermal expansion rate of the TFT-LCD substrate glass in the high temperature region of 550 ° C to 630 ° C is generally about 6 parts per million; but the thermal expansion of the soda lime glass high temperature region at 550 ° C to 600 ° C The difference in rate is 20 parts per million; if the 40-inch diagonal TFT-LCD color LCD screen produces an improper shrinkage of 6-20 parts per million, it will change due to its viscosity and elastic characteristics. Large and curved, irregular Shape, and heat shrinkage; there will be problems with certain pixel points on the surface of the TFT-LCD substrate glass and the front color filter film and polarizer, resulting in quality problems with several black spots on the LCD screen.
  • TFT-LCD liquid crystal glass is very demanding both internal and external performance and inch requirements.
  • TFT-LCD has the same requirements as integrated circuit chip, even more stringent than IC chip. Since the circuit and the semiconductor are formed on the surface of the substrate glass, it is required to have the same or higher precision as the silicon wafer. The smaller the difference in the thermal expansion coefficient of the high temperature region of the substrate glass, the higher the yield and the higher the resolution display product. On the contrary, because the difference in the coefficient of thermal expansion of the high temperature region is greater, the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; some pixel points on the surface of the TFT-LCD substrate glass are generated. The front color filter film and the polarizer produce a problem that is not good, resulting in a quality problem of several black spots on the liquid crystal panel.
  • the processing of diodes on the surface of the substrate glass, thin film transistors and the like provide a switching process for each phase, and the final temperature of the heating process is 625 ° C.
  • This poses a very high difficulty for the existing conventional substrate glass because the difference in thermal expansion rate of the conventional TFT-LCD substrate glass in the high temperature region of 550 ° C to 630 ° C is generally about 6 parts per million for heating.
  • the final temperature of the process is 625 ° C, which provides only a narrow process control range. Only provides technical support for display products that can produce low-level resolution with a resolution of approximately [100-200 ppi - that is, about 100-200 pixels per square inch of thin film transistors);
  • Prior Art Difficulties The prior art inventors have prior art in 2011. Difficulties in prior art: The prior art has the above difficulties in comparison with the prior art 2, with a little progress, mainly taking the material properties of the high temperature zone from 550 ° C. -630 ° C rose to 600 ° C -650 ° C; and the difference in thermal expansion rate from about 6 parts per million, to 2-3 parts per million range. Therefore, compared with the conventional technology, the newly provided process control range is improved; because the thin film transistor of the conductive layer is sintered above the TFT-LCD liquid crystal glass surface after the rapid heating between 600-650 ° C, the high temperature is provided.
  • the smaller difference in the coefficient of thermal expansion of the region can produce higher definition resolution, and the resolution [about 400-600 ppi - that is, the pixel position of the thin film transistor per square inch is about 400-600]
  • Technical effect of support but since it can only provide process control range from 600 °C to 650 °C,
  • the substrate glass surface processing diode, thin film transistor, etc. provide a switching process for the 400-600 ppi-phase position, so the production efficiency and the yield are defective.
  • TFT-LCD liquid crystal glass is very demanding both internal and external performance and inch requirements, TFT-LCD has the same requirements as integrated circuit chip, even more stringent than IC chip. Since the circuit and the semiconductor are formed on the surface of the substrate glass, it is required to have the same or higher precision as the silicon wafer. The smaller the difference property of the thermal expansion coefficient of the high temperature region of the substrate glass is, the smaller the total pitch deviation performance property is, the higher the yield can be, and the higher the resolution display product can be produced.
  • the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; some pixel points on the surface of the TFT-LCD substrate glass are generated.
  • the front color filter film and the polarizer produce a problem that is not good, resulting in a quality problem of several black spots on the liquid crystal panel.
  • the difference in thermal expansion coefficient of the high temperature region that is, the difference in thermal expansion rate in the more severe high temperature region of 650 ° C to 700 ° C is within 0.1-0.99 parts per million, the difference in thermal expansion rate between 700 °C and 740 °C is within 1-5.9 parts per million, which has higher performance than all prior art comparison techniques;
  • the present invention can have excellent total pitch deviation performance (i.e., thermal expansion difference performance at high temperature) under severe temperature conditions of 650-700 ° C and 700-740 ° C, and the prior art is in parts per million. 6 or so; the total pitch deviation performance of the present invention is 0.1-0.9 parts per million; several times smaller than the difference of the prior art thermal expansion (ie, The total pitch deviation performance is stable); therefore, the control range of the process is increased; the production rhythm can be accelerated, the production capacity of the panel can be improved, and the non-obvious technical effect is obtained with a higher yield.
  • total pitch deviation performance i.e., thermal expansion difference performance at high temperature
  • the invention has the technical effect that the material property of the crystallization rate is slow, which is not obvious: the upper line range of the crystallization temperature zone of the invention is under the condition of natural cooling in the designated instrument, and the analysis starts after 45 minutes - 1 hour and 5 hours. Crystal, which has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, which are much more important than the prior art. In order to accurately control the large production. Thus, the high-quality electronic liquid crystal display glass plate glass of the present invention without any crystallization due to the influence of crystallization is produced; and a non-obvious technical effect is produced.
  • the invention represents the technical development trend of the thin and light, high-strength, high-wear-resistant electronic liquid crystal display glass and the combined invention terminal product.
  • the present invention has found substantial improvements and enhancements in the properties of the flexural strength material; thereby utilizing these properties, in touch screen electronic glass and TFT electronic glass, and mobile phones, tablet computers, laptop computers, desktop computers, televisions, etc., liquid crystal
  • the substantial improvement and the technical effect of the light weight, high strength and high wear resistance are not improved.
  • the product of the present invention in the application of flat glass is also substantially improved and improved by 1/3 times compared with the inventors of the prior art [1][2][3][4]; Boron-containing glass bending strength 80 Mpa is increased by about 3 times; it is about 2.4 times higher than the existing 12-15% aluminum touch screen glass flexural strength 100Mpa; it is about 2.4 times higher than the existing aluminum-containing 12-15% touch screen glass bending strength 100Mpa. ;
  • the invention is also lighter and thinner than the prior art [1][2][3][4] at the same intensity; it is 3 times lighter than the existing TFT boron-containing glass; lighter than the existing touch screen glass 2.4 times;
  • the invention is a new process of roll-to-roll liquid crystal display in a difficult development period, solving the fundamental problem:
  • the present invention has found substantial improvement and improvement of [difference in coefficient of thermal expansion coefficient in high temperature region] and material properties of [high softening point] and [reduction strength]; thereby utilizing these properties, it is difficult to develop during development
  • the difficulty of the new process of roll-to-roll liquid crystal display can be overcome, and the production process of the panel roll-to-roll which can make the panel production mode change and the high efficiency, cost reduction, lightness and thinness and high branching rate are produced. It can enter the large production stage of high finished product qualification rate, and there are unexpected technical effects.
  • the existing liquid crystal glass material can not withstand the severe high temperature properties.
  • the thin film transistor of the conductive layer is sintered onto the thin liquid crystal glass surface of the TFT-LCD 0.1-0.2mm, it will be due to the long distance winding pair.
  • the strong tension of the roll retracting process is modified.
  • the thin film transistor of the conductive layer has been sintered to the liquid crystal glass of the TFT-LCD, which is also unqualified due to the planar deformation, and cannot enter the liquid crystal panel production of the next process.
  • the thin film transistor of the conductive layer has been sintered to a thin liquid crystal glass of 0.1-0.2mm TFT-LCD Above the surface of the liquid crystal glass; [1] or because of the large difference in expansion and contraction in the coil (the prior art is about 6 parts per million), so the severe sintering temperature is close to the conversion point temperature of the prior art glass. The viscosity is generated, and the elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage. [2] Or because the softening point of the glass is low, it becomes soft when heated, and it is deformed by the strong tension in the roll-to-roll retracting process. [3] Or the part of the variant is fractured due to the difference in strength of the glass.
  • the present invention has substantial improvement and improvement in material properties of [difference in coefficient of thermal expansion in high temperature region] and [high softening point] and [strength], and in the roll-to-roll application, it is possible to overcome the above three items. Difficult new technology effects:
  • the thin film transistor of the conductive layer is sintered to the liquid crystal glass above the very thin liquid crystal glass surface of the TFT-LCD 0.1-0.2 mm, and the present invention can overcome or have a large difference due to expansion and contraction in the coil (the prior art is 6 parts per million)
  • the total pitch deviation performance of the present invention is 0.1-0.9 parts per million); the present invention does not cause viscosity due to the severe sintering temperature, which is close to the conversion point temperature of the prior art glass, and the elastic characteristics vary greatly. Bending, irregular deformation, and heat shrinkage; can overcome the major problem of the production of liquid crystal panels that cannot pass the material into the next process.
  • the technical heating temperature is only 630 ° C, the invention is that the rising heating temperature is 650-700-740 ° C, and is also much lower than the softening point of 800-860 ° C; therefore, it is not because of the strong tension of the long-distance roll-to-roll retracting process.
  • the modification or the low softening point of the glass is softened when heated, and is changed by the strong tension in the roll-to-roll retracting process; and the major problem of the liquid crystal panel of the transmitted material can be overcome.
  • the inventors' prior art [2] has a strength of up to 180 mpa; and the present invention can reach a strength of 240 mpa; therefore, the present invention can overcome the winding in the roll.
  • the invention can be overcome: when there is a roll-to-roll winding, when the lower process is unwinding into a flat product, the thin film transistor which has been sintered to the TFT-LCD liquid crystal glass is also unqualified due to the planar deformation, and cannot A major problem in the production of liquid crystal panels entering the next process; producing non-obvious technical effects.
  • the invention can be overcome: after the liquid crystal glass roll is wound up, the thin glass of 0.1-0.2 mm in the roll which is generated due to the tight winding in the roll, is not flattened due to the deformation. Under normal pressure, the deformed part is fractured, so there is a major problem that cannot be formed in a normal production process; a non-obvious technical effect is produced.
  • the present invention overcomes the above-mentioned problems in the roll-to-roll process at the development stage:
  • the thin film transistor of the conductive layer In the roll-to-roll process, the thin film transistor of the conductive layer must be sintered to the liquid crystal glass of the TFT-LCD by means of a heating process, but the temperature of this process of the prior art is 600-630 ° C, which is according to the prior art.
  • the total pitch deviation performance of the liquid crystal glass of the TFT-LCD ie, the difference in thermal expansion at high temperature is determined by 550-630 ° C;
  • TFT-LCD liquid crystal glass is very demanding both internal and external performance and inch requirements, TFT-LCD has the same requirements as integrated circuit chip, even more stringent than IC chip. Since the circuit and the semiconductor are formed on the surface of the substrate glass, it is required to have the same or higher precision as the silicon wafer. The smaller the difference property of the thermal expansion coefficient of the high temperature region of the substrate glass is, the smaller the total pitch deviation performance property is, the higher the yield can be, and the higher the resolution display product can be produced.
  • the temperature of the process such as ⁇ 630 ° C, will exceed the total pitch deviation performance of the prior art liquid crystal glass (that is, the difference in thermal expansion at a high temperature of 630 ° C is about 6 parts per million), resulting in high temperature
  • the total pitch deviation performance of the liquid crystal glass with thermal expansion coefficient [the coefficient of thermal expansion coefficient is not up to standard], the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; TFT-LCD substrate glass is produced.
  • Some of the pixels on the surface are inconsistent with the front color filter film and the polarizer, resulting in quality problems with several black spots on the LCD screen.
  • the present invention because of the difference in thermal expansion coefficient of the high temperature region, the material properties of the liquid crystal glass material: the present invention can be more 650-700 ° C and at a temperature of 550-630 ° C or 600-650 ° C than the conventional technology.
  • the transformation point temperature of the glass produces viscosity, and the elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage; therefore, the invention not only has a wider control range but also has the property of being able to withstand certain severe high temperatures.
  • the thin film transistor of the conductive layer is sintered onto the thin liquid crystal glass surface of 0.1-0.2mm of TFT-LCD, which can achieve the flatness of the thin film transistor.
  • the square inch pixel position is about 200 resolutions.
  • the technical quality of the product is designed to achieve a more ambiguous level of pixel quality per square inch of 800-1600 resolution.
  • the invention overcomes major problems; it produces non-obvious technical effects.
  • the invention can make the production process of the TFT-LCD display panel roll-to-roll in the difficult development period overcome the major problems and carry out the large production stage; the invention can make the panel production mode change, generate high efficiency and reduce cost.
  • the new panel production method with light weight and high distribution rate represents the technical development trend of the invention of high-level electronic liquid crystal display glass and liquid crystal display combined terminal products.
  • the invention can be a new technology of low temperature polysilicon liquid crystal display technology and solve major problems:
  • the present invention finds substantial improvement and improvement of [difference in thermal expansion coefficient in high temperature region] and material properties of [high softening point] and [reduction strength]; thereby utilizing these properties, it can be a low temperature polycrystalline silicon liquid crystal display technology
  • the new technology solves the problem that the total pitch deviation performance of the liquid crystal glass of the TFT-LCD is poor, the flat glass is deformed after the laser irradiation, the yield is not high, and the resolution of the liquid crystal display technology is not bad, and there is an unexpected technology. effect.
  • the temperature of this process of the prior art is 600-630 ° C, which is determined according to the total pitch deviation performance of the liquid crystal glass of the TFT-LCD of the prior art (ie, the thermal expansion difference performance at high temperature) of 550-630 ° C. ;
  • the temperature of the process such as ⁇ 630 ° C, will exceed the total pitch deviation performance of the prior art liquid crystal glass (that is, the difference in thermal expansion at a high temperature of 630 ° C is about 6 parts per million), resulting in high temperature
  • the total pitch deviation performance of the liquid crystal glass with thermal expansion coefficient [the coefficient of thermal expansion coefficient is not up to standard], the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; TFT-LCD substrate glass is produced.
  • Some of the pixels on the surface are inconsistent with the front color filter film and the polarizer, resulting in quality problems with several black spots on the LCD screen.
  • the temperature of 630 ° C does not convert the amorphous silicon structure on the glass substrate into a polycrystalline silicon structure, or is generated.
  • the effect of the conversion of the amorphous silicon structure into the polysilicon structure cannot be formed due to insufficient thermal energy. Low yield is the main problem.
  • the thin film transistor of the conductive layer is sintered to the liquid crystal glass.
  • the total pitch deviation performance (that is, the thermal expansion difference performance at high temperature) due to the conventional technology at a high temperature of 550-630 ° C is only about 6 parts per million, and can only reach the pixel position per square inch of the thin film transistor.
  • the technical quality of the product of about 200 resolutions is a major problem;
  • the present invention has substantial improvement and improvement due to the difference in the coefficient of thermal expansion of the high temperature region and the material properties of the high softening point.
  • a new technical effect capable of overcoming the above three difficulties is produced:
  • the invention can work under the conditions of 550-630 ° C or 600-650 ° C of the conventional technology, and has a more severe 650-700 ° C and 700-740 ° C harsh temperature process conditions, and Better overall pitch deviation performance (ie, thermal expansion difference performance at high temperatures), several times smaller than the prior art thermal expansion difference (ie, total pitch deviation performance is stable); [2] and there is a comparison technique Very much 750-860 ° C softening point properties;
  • the temperature of the process is 700-740 ° C, it does not exceed the total pitch deviation performance of the liquid crystal glass of the present invention (that is, the difference in thermal expansion at a high temperature of 700-740 ° C is 1-5.9 parts per million),
  • the total pitch deviation performance of the liquid crystal glass due to the thermal expansion coefficient of the high temperature zone [the coefficient of thermal expansion coefficient difference is not required], and the viscosity and elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage;
  • Certain pixel points on the surface of the TFT-LCD substrate glass are incompatible with the front color filter film and the polarizer, resulting in quality problems of appearing black spots on the liquid crystal panel;
  • the temperature of 700-740 ° C can change the amorphous silicon structure on the glass substrate into the polysilicon junction.
  • the thermal energy is greatly increased to form a good yield effect of converting the amorphous silicon structure into the polycrystalline silicon structure.
  • the softening point of the liquid crystal glass of the TFT-LCD of the present invention has a softening point property of 750-860 ° C which is much higher than that of the prior art, so in the new process of low-temperature polysilicon technology, it is necessary to make the glass
  • the plate glass of the present invention does not have a problem of deformation after being irradiated by the laser at a temperature of 700-740 ° C under severe temperature, and the yield can be greatly increased.
  • the softening point of the liquid crystal glass of the TFT-LCD of the present invention has a softening point property of 750-860 ° C which is much higher than that of the prior art, so in the new process of low-temperature polysilicon technology, it is necessary to make the glass
  • the plate glass of the present invention does not have a problem of deformation after being irradiated by the laser at a temperature of 700-740 ° C under severe temperature, and the yield can be greatly increased.
  • the present invention because of the difference in thermal expansion coefficient of the high temperature region, the material properties of the liquid crystal glass material: the present invention can be more 650-700 ° C and 700-740 at a temperature of 550-630 ° C than the conventional technology. °C work under severe temperature conditions, and has better overall pitch deviation performance (ie, differential thermal expansion performance at high temperatures), which is several times smaller than the difference in thermal expansion of the prior art (ie, the total pitch deviation performance is stable) Therefore, the invention not only has a larger control range of the process, but also has the requirement of being able to withstand a certain severe high temperature, and the thin film transistor of the conductive layer is sintered on the thin liquid crystal glass surface of the TFT-LCD 0.1-0.4 mm.
  • the present invention can overcome the new process problem of low temperature polysilicon technology 3; and produce a non-obvious technical effect of the lower resolution of low temperature polysilicon technology. It represents a high-level electronic liquid crystal display glass and liquid crystal display combination invention technology product development trend.
  • the first comparative technique [1][2][3][4] has a flexural strength apex from 180 MPa, substantial improvement and improvement to a flexural strength apex of 240 MPa; compared with the prior art [1] ][2][3][4]
  • the flexural strength is substantially improved and improved by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; 12-15% than the existing aluminum containing aluminum
  • the touch screen glass has a flexural strength of 100 Mpa which is increased by about 2.4 times; it is about 5 times higher than that of the calcium sodium glass.
  • the electronic glass product can provide a higher strength product for the electronic glass product, or provide a light and thin 5 times, or a light and thin 2.5 times, or a light and thin 1/4 when the strength is the same;
  • the technical effect of the present invention represents a technical development trend of a high level of electronic liquid crystal display glass and liquid crystal display combined invention terminal products.
  • the present invention has found substantial improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature zone] and the material properties of the [high softening point]; thereby utilizing these properties, it is possible to improve the resistance of the flat glass material and the end product application. High temperature fireproof, explosion-proof performance, there are unexpected technical effects.
  • the present invention because of the difference in thermal expansion coefficient of the high temperature region and the material properties of the high softening point:
  • the difference in thermal expansion rate in the more severe high temperature zone 650 ° C -700 ° C is in the millions Within 0.1-0.99, the difference in thermal expansion rate in the more severe high temperature range of 700 ° C - 740 ° C is within 1-5.9 or 6-8 parts per million. Its non-obvious new technology effects are:
  • the invention has been greatly improved as 1. glass for construction; 2. glass for automobile; 3. glass for ship; 4. glass for railway car; 5 aircraft glass; 6. glass for fireproofing and explosion-proof; High temperature resistant fireproof and explosion proof performance;
  • invention terminal products such as: 1. high-performance glazed glass furniture, 2. high-performance automotive, 3. high-performance solar aircraft, 4. high-performance solar power generation equipment, and other combined invention end products for high temperature and fire resistance applications Explosion-proof performance.
  • the present invention has a material having a slow crystallization rate: a non-obvious technical effect [1]: the upper line range of the crystallization temperature zone of the present invention and under the condition of natural cooling in a specified instrument, at 45 minutes -1, After 5 hours, the crystallization will start under the condition of the upper line of the glass crystallization temperature zone and gradually lowering the temperature, and the crystallization rate is slow; this can be especially in the cooling part and the forming part, especially the float process and various
  • the flat glass process creates extremely important and precise process control parameters that are much better than the prior art, so that precise production can be controlled with precision and confidence.
  • the high-quality flat glass of the above seven uses of the present invention which does not have any crystallinity and which affects the light transmittance, is produced, and provides acceptable product support for the application of the above-mentioned four types of combined invention terminal products.
  • the present invention has been found to have substantial improvements and improved [softening point] properties - "softening point up to 750-860 ° C", and [difference in the coefficient of thermal expansion of the high temperature zone] - "in the more severe
  • the difference in thermal expansion between 650 ° C and 700 ° C in the high temperature range is within 0.1-0.99 parts per million, and the difference in thermal expansion rate in the more severe high temperature range of 700 ° C to 740 ° C is 1-5.9 or 6 parts per million.
  • the present invention is particularly superior to the prior art [1][2][3][4] in the case of fire or high temperature, in the high temperature zone state.
  • the [higher softening point] of the flat glass of the present invention [better thermal expansion difference in high temperature region], [high performance such as higher strength], the shape of the glass can be maintained, and fireproofing and separation can be achieved.
  • the non-obvious technical effect of fire and heat insulation wave; the invention has special fireproof and explosion-proof effect of building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has non-obvious technical effects.
  • the softening point of the existing soda-lime plate glass is only 525 ° C; the material properties of the soft glass having a softening point of up to 720 ° C have only been found in the prior invention of the flat glass in the comparative document.
  • the present invention has found a material having a softening point of 750-860 ° C, so that in all the use of glazed flat glass, it can produce unexpected materials:
  • the invention can make the color glaze flat glass without quality defects of cracking or cracking, and has unexpected technical effects
  • the invention can overcome the glaze raw materials, because the temperature is low and the cost is more difficult, and there is a technical effect that the production cost is not expected;
  • the invention can overcome the raw materials of the colored glaze, because the lower the temperature, the more difficult it is to emit the color of red, blue, green, yellow, etc., and the lower the temperature of the raw material of the colored glaze, the higher the cost of color development. Difficulties; the unexpected technical effects of red, blue, green, yellow and other colors that produce better quality, and the unexpected technical effects of reducing the cost of glaze raw materials.
  • Prior Invention 4 which is closer to the present invention: Comparative Document
  • the present inventor 201110060913.9, a low-melting-point glaze decorative flat glass with high annealing temperature and high strength and environmental protection and energy saving type.
  • This prior art does not indicate a substantial improvement and improvement of the [high softening point property] found by the present invention; nor does it indicate a substantial improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature region] found by the present invention; Substantial improvements and improvements in the [fracture strength properties] found by the present invention are not indicated;
  • the present invention has been found to have substantial improvements and improved [fracture strength] material properties; thereby utilizing these properties, it is possible to improve the lightness and thinness properties of flat glass materials and end products applications, and there are unexpected technologies. effect.
  • the invention compares the apex of the first comparative technique [1][2][3][4] from 180Mpa, substantially improves and improves to the apex of the flexural strength 240Mpa; compared with the prior art [1][2 ][3][4]
  • the flexural strength is substantially improved and improved by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; compared with the existing aluminum-containing 12-15% touch screen glass
  • the flexural strength of 100 Mpa is increased by about 2.4 times; it is about 5 times higher than that of calcium sodium glass.
  • the flexural strength can be substantially improved and improved by 1/4 compared with the prior art [1][2][3][4]; the flexural strength of the existing boron-containing glass is 80Mpa. It is increased by about 3 times; it is about 2.4 times higher than the existing 20-15% touch screen glass flexural strength 100Mpa; it is about 5 times higher than the calcium sodium glass bending strength 50Mpa.
  • the present invention discloses new material properties that reduce the crystallization rate of glass in production.
  • the present invention has discovered a new material property with substantial improvements and improved [glass crystallization rate]; thus utilizing these properties, a non-obvious unique technical effect is produced: especially prior comparison
  • the technology [1][2][3][4] can overcome the defects caused by the crystallization of the unique technical weakness of the product of the invention, and can carry out a better level of process quality control and improve production. Feasibility and product quality rate.
  • the product of the present invention has the characteristic that the upper line [highest point] of the crystallization temperature is higher than the molding temperature, in order to study the selective use of glass having a relatively slow crystallization rate in large production, it is advantageous for cooling before molding.
  • the working temperature of the glass liquid cooling process in the working part reduces the risk of crystallization; because it is required to cool the temperature of the glass in the working part, the process must be controlled by the crystallization temperature, especially in the liquid line edge of the cooling working part.
  • the material properties of the present invention should be selectively used in large-scale production: [the upper-line range of the inner glass crystallization temperature zone after the glass liquid having a relatively slow crystallization rate is 45-60 minutes or 60-150 minutes, and the condition of gradually lowering the temperature Underneath, there is no crystallization of the glass material, which is 5 times slower than the prior art prior art [1][2][3][4], thus overcoming the forming stage to make the flat glass appear locally. The risk of devitrified substandard products.
  • the invention finds: (1) the difference of the thermal expansion coefficient in the high temperature zone and (2) the softening point of the crucible, (3) the more flexural strength property; (4) in the flat glass
  • new glass products [low crystallization rate] material properties were found; these (1).(2).(3).(4) properties, substantial improvements and improvements, and the use of these (1). (2). (3). (4)
  • the nature of the class has produced unexpected technical effects.
  • any of the specifications relates to unexpected technical effects of improving product performance, or yield quality, or increasing throughput; it is to be judged that the present invention is substantially progressive and inventive.

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Abstract

Application of fire-proof explosion-proof plate glass having a high softening point, a low differential high-temperature region thermal expansion coefficient, and a low crystallisation speed, comprising, according to percentage by weight, 0.01%-39% aluminium oxide content, 7%-20% magnesium oxide content, silicon oxide content being 2.51-4.8 times that of calcium oxide content, and the calcium oxide content being 1.0-1.8 times that of the magnesium oxide content; the difference in thickness of the plate glass under 20mm is less than 0.01-0.4mm.

Description

一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用A high softening point, low difference of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass 技术领域Technical field
本发明属于平板玻璃领域，涉及一种特种平板玻璃，尤其是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用。The invention belongs to the field of flat glass, and relates to a special flat glass, in particular to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass.
本发明主要属于一种化学产品新用途发明；The invention mainly belongs to a new use invention of a chemical product;
A.在新用途中，发现了新的玻璃产品[低析晶速度]材料性质，这是公知常识中沒有明确的并不能由常识推论得到的。A. In new applications, new glass products [low crystallization rate] material properties have been discovered, which are unclear in common knowledge and cannot be inferred from common sense.
B.针对已知化合物的巳知的[高温区热膨胀系数的差值]及[软化点]性质和[抗折强度性质]与由这些新性质产生的予料不到的技术效果，有实质性的改进和提高；这也是公知常识中沒有明确的并不能由常识推论得到的。B. Known for the known compounds [difference in the coefficient of thermal expansion of the high temperature region] and [softening point] properties and [bending strength properties] and the unexpected technical effects produced by these new properties, there is substantial Improvements and improvements; this is also not clear in common sense and cannot be inferred from common sense.
C.在新用途领域应用范围，如：1.建筑用玻璃；2.汽车用玻璃；3.船用玻璃；4.铁道车厢用玻璃；5飞机玻璃；6.防火、防爆用玻璃；7特种玻璃；8.墙地面用彩釉玻璃装饰板等应用产品用途；及各种组合发明终端产品如：1.高性能彩釉玻璃傢俱、2.高性能汽車、3.高性能太阳能飞行器、4.高性能太阳能发电装置、等组合发明终端产品应用用途，本发明在发现的新性质及由这些新性质产生的予料不到的技术效果。代表了这些应用用途领域中，一种技术发展趋势；本发明也克服了上述这些用途领域中，人们渴望解决但始终沒得获得成功的技术难题。C. Application range in new applications, such as: 1. Glass for construction; 2. Glass for automobile; 3. Glass for ship; 4. Glass for railway car; 5 aircraft glass; 6. Glass for fireproof and explosion-proof; ; 8. Wall-mounted glazed glass decorative panels and other application products; and various combinations of inventions such as: 1. High-performance glazed glass furniture, 2. High-performance cars, 3. High-performance solar aircraft, 4. High The performance of the solar power generation device, the combined use of the terminal product of the invention, the new properties discovered by the present invention and the unexpected technical effects resulting from these new properties. It represents a technological development trend in the field of application applications; the present invention also overcomes the technical problems in the above-mentioned fields of use that people are eager to solve but have never succeeded.
背景技术Background technique
(1)、先有对比技术1：本发明人的先有发明：有高退火点及环保节能减排的高强度高平整度低粘度特征的平板玻璃的应用及相关部件，专利号201110060944.4，(1) First Comparative Technology 1: The inventor's prior invention: application and related components of flat glass with high annealing point, high strength, high flatness and low viscosity characteristics with environmental protection, energy saving and emission reduction, Patent No. 201110060944.4,
(2)、先有发明之2：本发明人的201510161553.61，一种具有低热膨胀系数的平板玻璃及其制备工艺。(2) First Invention 2: The inventor's 201510161553.61, a flat glass having a low coefficient of thermal expansion and a preparation process thereof.
(3)、先有发明之3：本发明人的201410408822.3，一种冷却部防析晶方法生产的平板玻璃， (3) Inventive 3: Inventor's 201410408822.3, a flat glass produced by a cooling portion anti-crystallization method,
(4)、先有发明之4：本发明人的：201110060913.9，一种高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃，(4), prior invention 4: The inventor's: 201110060913.9, a high annealing temperature and high intensity environmental protection and energy-saving low melting point glaze decorative flat glass,
(5)先有对比技术之5：(5) There is a comparison technology 5:
首先对比例，日本国际公开01/034531专利技术方案范围，与本发明不是同一的技术方案范围。First of all, the scope of the technical solution of the Japanese International Publication No. 01/034531 is not the same as the scope of the technical solution of the present invention.
(6)、先有对比技术之6：(6), prior to the comparison of technology 6:
针对对比例US005925583A专利技术要术的比例关系：Proportional relationship to the patented technology of the comparative US005925583A:
范围技术方案与本发明技术要术的比例关系范围技术方案，与本发明不相同的说明：Scope of the technical solution and the technical scope of the present invention, the technical solution is different from the description of the present invention:
(7)先有发明之：(7) First invention:
针对美国专利通报US3929497(1975年12月30日)专利。U.S. Patent No. 3,929,497 (December 30, 1975) patent.
此专利名称就是：适用于纤维生产的可结晶玻璃The patent name is: crystallizable glass for fiber production
有关产品性质测试的设备及方法：Equipment and methods for testing the nature of products:
(A)有关测试软化点的方法：采用日本TAS-100型综合热分析仪。(A) Method for testing the softening point: a Japanese TAS-100 type comprehensive thermal analyzer was used.
(B)有关测试高温区热膨胀系数的低差值的方法，玻璃的膨胀系数按照标准GB/T7320.1-2000测定。目前都是采用世界上最好的德国耐茨公司的热膨胀仪所测的数据；其结果是从60℃起到800℃，每10℃有一个热膨胀值E-06/℃，或从60℃起到740℃每10℃有一个热膨胀值E-06/℃；从中得到在更严酷的高温区650℃-700℃时热膨胀率的差值在百万分之0.1-0.99以内，在更严酷的高温区700℃-740℃时热膨胀率的差值在百万分之1-5.9或6-8以内的高温区热膨胀系数的比较一切先有对比技术更低差值的结论。(B) A method for testing the low difference in the coefficient of thermal expansion of the high temperature zone, the coefficient of expansion of the glass is determined in accordance with the standard GB/T7320.1-2000. It is currently measured using the world's best thermal resistance instrument from the German company Nitz; the result is from 60 ° C to 800 ° C, a thermal expansion value of E-06 / ° C per 10 ° C, or from 60 ° C It has a thermal expansion value of E-06/°C per 10°C at 740°C; from which the difference in thermal expansion rate in the more severe high temperature range of 650°C-700°C is within 0.1-0.99 parts per million, at a more severe high temperature. The difference in thermal expansion coefficient between 700 ° C and 740 ° C in the high temperature region of 1-5.9 or 6-8 is a comparison of the lower differential coefficients of the prior art.
(C)采用测析晶梯温炉，测得各种需要测得的玻璃材料的--析晶温度的上线[最高点]和下线[最低点]。(C) Using the temperature-measuring ladder temperature furnace, the on-line [highest point] and the lower line [lowest point] of the crystallization temperature of various glass materials to be measured were measured.
(D)采用一种玻璃溶化炉，在玻璃析晶温度区的上线[即最高点]开始，逐步降温的条件下，对不同玻璃的析晶速度进行测试方法：(不是受先有对比技术启示的，就连玻璃析晶速度的新材料性质的测试目的特征和测试设备及测试方法，也是根据本发明类型产品在大生产中独有的技术弱点形成的析晶造成的缺陷，而独创的和首创的)： (D) Using a glass melting furnace, the crystallization rate of different glasses is tested at the upper line [ie, the highest point] of the crystallization temperature region of the glass, and the temperature is gradually lowered: (not inspired by the prior art) The test purpose characteristics and test equipment and test methods of the new material properties of the glass crystallization rate are also defects caused by the crystallization of the unique technical weakness of the type products of the present invention, and the original First):
在本发明说明书中，所有析晶速度的分钟数值的大小，及从而判断析晶速度的快慢，都以采用此下部分指明的同一种玻璃溶化炉，和此下部分指明的对不同玻璃的析晶速度的测试方法所得出的数据为基础：In the specification of the present invention, the magnitude of the minute value of all the crystallization rates, and thus the speed of the crystallization rate, are determined by the same glass melting furnace specified in the lower part, and the analysis of the different glasses specified in the lower part. The data obtained from the test method of crystal velocity is based on:
a.选择的玻璃溶化炉的特征是：a. The characteristics of the selected glass melting furnace are:
1.玻璃溶化炉备有，对炉内部的温度的准确测温的显示仪，用来观测和记录温度的变化。1. The glass melting furnace is provided with a display for accurately measuring the temperature inside the furnace for observing and recording temperature changes.
2.选择的玻璃溶化炉的总体保温性能要好，要使炉内的温度，最少在保持150分钟或以上时间，才完成炉内的温度1300-850℃的自然降温过程；即完成玻璃液在炉内的温度最少保持150分钟或以上的是夠时间，才完成炉内的温度1300-850℃的自然降温过程。(因为本发明产品的玻璃析晶温度区的上线范围，绝大多数都在1300--850℃之内，例如某产品的玻璃析晶温度区的上线范围为：1230--920℃)2. The overall thermal insulation performance of the selected glass melting furnace should be good. The temperature in the furnace should be kept at least 1500-850 °C for a period of 150 minutes or more; that is, the glass liquid is in the furnace. It is sufficient time for the temperature inside to remain at least 150 minutes or more to complete the natural temperature lowering process of the furnace temperature of 1300-850 °C. (Because the upper line range of the glass crystallization temperature zone of the product of the invention is mostly within the range of 1300--850 ° C, for example, the upper line range of the glass crystallization temperature zone of a product is: 1230--920 ° C)
b.测试目的：b. Test purpose:
由于本发明产品具有析晶温度的上线[最高点]高于成型温度的特点，所以为了研究在大生产中如选择性采用具有析晶速度比较慢的玻璃，就有利于在大生产中成型前的尤其冷却工作部，玻璃液降温工艺阶段，减少玻璃液析晶的风险；会特别在冷却工作部的液线边沿及拐角和底部这些易于析晶的地方增加一些加热控制装置，而且加求把温度控制到高于析晶温度上线50-80℃；Since the product of the present invention has the characteristic that the upper line [highest point] of the crystallization temperature is higher than the molding temperature, in order to study the selective use of glass having a relatively slow crystallization rate in large production, it is advantageous to form before molding in large production. Especially in the cooling work part, the glass liquid cooling process stage, reducing the risk of devitrification of the glass liquid; in particular, in the cooling work part of the liquid line edge and corners and bottoms, which are easy to devitrify, add some heating control devices, and add The temperature is controlled to be higher than the crystallization temperature on the line 50-80 ° C;
但实际的状态是，在冷却工作部的拐角和底部，由于玻璃液存在着一些流动较慢的区域，所以某些产品，当一些流动较慢的区域里，玻璃液温度下降较快，从析晶温度顶点开始下降，仅在31分钟内，这类产品的玻璃液就产生局部析晶。这将会使这类产品，在大生产中，在进入成型阶段后，易于出现平板玻璃局部失透的产品不合格的风险。However, the actual state is that in the corners and bottom of the cooling working part, due to the slow flow of some areas of the molten glass, some products, in some areas with slower flow, the temperature of the molten glass drops faster. The apex of the crystal temperature began to drop, and in only 31 minutes, the glass of such products produced local crystallization. This will make such products, in large production, after entering the molding stage, is prone to the risk of product failure of the partial devitrification of the flat glass.
所以应在大生产中，选择性采用本发明具有析晶速度比较慢的玻璃产品，由于其具有析晶速度比较慢的性质：当玻璃液温度从析晶温度顶点开始下降的条件下60-90分钟内或60-150分钟内，都不产生析晶。本发明发现的这种玻璃材料的玻璃液析晶速度慢的性质，能有利于解决在冷却工作部的拐角和底部，当一些流动较慢的区域里局部失透的问题；由于玻璃液析晶速度慢，所以在一些流动较 慢的区域里，能克服易于使平板玻璃成型阶段出现局部析晶失透的不合格产品的风险。Therefore, in large production, the glass product having the relatively slow crystallization rate of the present invention should be selectively used, because of its relatively slow crystallization rate: 60-90 when the temperature of the glass liquid starts to fall from the apex of the crystallization temperature. No crystallization occurred within minutes or 60-150 minutes. The slow crystallization rate of the glass liquid of the glass material discovered by the invention can be beneficial to solve the problem of local devitrification in the corners and bottom of the cooling working part, and in some slow-flowing areas; Slow, so in some flow In the slower area, it is possible to overcome the risk of unqualified products which tend to cause local crystallization and devitrification during the forming stage of the flat glass.
c.不同玻璃的析晶速度的测试方法：c. Test method for crystallization rate of different glasses:
第一步，首先采用测析晶梯温炉，测得各种需要测得的玻璃材料的--析晶温度的上线[最高点]和下线[最低点]。In the first step, the temperature of the crystal ladder is measured first, and the on-line [highest point] and the lower line [lowest point] of the crystallization temperature of various glass materials to be measured are measured.
第二步，The second step,
把玻璃原料放入溶化干锅中；Put the glass raw material into the melting pot;
2.再放入一种玻璃溶化炉中；2. Put it in a glass melting furnace;
3.溶化后关闭电源，使玻璃溶化炉自然降温；3. Turn off the power after melting to make the glass melting furnace cool naturally;
4.根据这种被测定的玻璃的析晶温度的上线[最高点](如为1230--920℃)，观察炉内部的温度的较准确的测温显示仪的自然降温到(如1230℃)的时间到所需测定的时间段；4. According to the upper line [highest point] of the crystallization temperature of the glass to be measured (for example, 1230--920 °C), the temperature of the internal temperature of the furnace is observed to be more accurate (for example, 1230 ° C) Time to the time period required for the measurement;
5.如当20分钟后取出溶化干锅，玻璃液会很快冷却为玻璃，观察其是否有析晶现象；从而得出这种被测定的玻璃，从析晶温度的上线[最高点]的自然降温20分钟的析晶速度的性质；或45分钟后取出溶化干锅；或60分钟后取出溶化干锅；或90分钟后取出溶化干锅；或120分钟后取出溶化干锅；或150分钟后取出溶化干锅；就得到这种被测定的玻璃，从析晶温度的上线[最高点]的自然降温20、45、60、90、120、150分钟的析晶速度的性质。5. If the melting pot is taken out after 20 minutes, the glass liquid will be quickly cooled to glass and observed for crystallization. Thus, the glass to be measured is obtained from the upper line of the crystallization temperature [highest point]. Naturally cool down the nature of the crystallization rate for 20 minutes; or take out the melting pot after 45 minutes; or remove the melting pot after 60 minutes; or remove the melting pot after 90 minutes; or remove the melting pot after 120 minutes; or 150 minutes After that, the melting pot was taken out; the nature of the crystallization rate of the glass to be measured, which was naturally lowered from the upper line [highest point] of the crystallization temperature of 20, 45, 60, 90, 120, and 150 minutes.
(E)有关测试 粘度温度的方法，采用美国THETA旋转高温粘度计。(E) A method for testing the viscosity temperature using a US THETA rotary high temperature viscometer.
(F)有关测试抗折强度，通过把样品切成50mm×50mm×5mm的小条，采用抗折强度仪，按标准GB/T3810、4-2006测定。(F) For the test flexural strength, the sample was cut into 50 mm × 50 mm × 5 mm strips and measured by a flexural strength tester according to the standard GB/T3810, 4-2006.
发明内容Summary of the invention
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为0.01％--39％，氧化镁含量为7％--20％，氧化硅含量是氧化钙含量的2.51-4.8倍，氧化钙含量是氧化镁含量的1.0-1、8倍，厚度20mm以内的平板玻璃厚薄差在0.01mm-0.4mm。 A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of a fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, magnesium oxide The content is 7%-20%, the silicon oxide content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness difference of the flat glass within the thickness of 20 mm is 0.01 mm-0.4. Mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为0.01％--39％，氧化钠含量为0.001％-18％，氧化镁含量为7％--20％，氧化硅含量是氧化钙含量的2.51-4.8倍，氧化钙含量是氧化镁含量的1.0-1、8倍，厚度20mm以内的平板玻璃厚薄差在0.01mm-0.4mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, sodium oxide The content is 0.001%-18%, the magnesium oxide content is 7%-20%, the silica content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1,8 times of the magnesium oxide content, and the thickness is less than 20mm. The thickness of the flat glass is between 0.01 mm and 0.4 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为0.01％--39％，氧化钠含量为0.001％-0.9％或0.91-8.8％或8.9-18％，氧化镁含量为7％--20％，氧化硅含量是氧化钙含量的2.51-4.09倍或3.61-4.09倍或3.61-4.8倍。，氧化钙含量是氧化镁含量的1.0-1、8倍，厚度20mm以内的平板玻璃厚薄差在0.01mm-0.4mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, sodium oxide The content is 0.001%-0.9% or 0.91-8.8% or 8.9-18%, the magnesium oxide content is 7%-20%, and the silica content is 2.51-4.09 times or 3.61-4.09 times or 3.61-4.8 of the calcium oxide content. Times. The calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness difference of the flat glass within the thickness of 20 mm is 0.01 mm-0.4 mm.
根据权利要求1所述的一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：其软化点为750℃-860℃；其抗折强度达60-240Mpa。The invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the softening point is 750 ° C - 860 ° C; The folding strength is 60-240Mpa.
根据权利要求1所述的一种平板玻璃，其特征在于：其高温区低热膨胀率的特征在于，在高温区550℃-600℃时，热膨胀率的差值在百万分之1.2以内，在高温区600℃-650℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内。A flat glass according to claim 1, wherein the low temperature expansion rate in the high temperature region is characterized by a difference in thermal expansion rate within 1.2 parts per million in a high temperature region of 550 ° C to 600 ° C. In the high temperature range of 600 ° C to 650 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million, and in the high temperature range 650 ° C - 700 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million.
根据权利要求1所述的一种平板玻璃，特征在于：在高温区700℃-710℃时，热膨胀率的差值在百万分之1-5.9或6-8以内。A flat glass according to claim 1, wherein the difference in thermal expansion rate is in the range of 1-5.9 or 6-8 parts per million in the high temperature region of 700 ° C to 710 ° C.
根据权利要求1所述的一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为4％--8％或8.1-12％或12.1-23％或23.1-32％或32.1-39％，The invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass according to claim 1, characterized in that the alumina content is 4% by weight. --8% or 8.1-12% or 12.1-23% or 23.1-32% or 32.1-39%,
根据权利要求1-6所述的任一项所述的一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用的制备方法，其特征在于：The method for preparing a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass according to any one of claims 1 to 6, wherein:
步骤1，根据权利要求1-6所述的任一项所述的玻璃配方配置所需的各种有 Step 1. Various types of glass formulation configurations according to any one of claims 1-6
预定的成份以及预定的氧化硅、氧化钙、氧化镁之间的特殊比例关系的成份的原料，经混合搅拌之后在对应于各玻璃配方的熔化温度熔化，形成预定的粘度的玻璃液，再均化，澄清，排出气泡，形成可流动的熔融体；The predetermined component and the predetermined raw material of the composition of the specific ratio between the silicon oxide, the calcium oxide and the magnesium oxide are mixed and stirred, and melted at a melting temperature corresponding to each glass formulation to form a glass liquid having a predetermined viscosity, and then To clarify, discharge bubbles, and form a flowable melt;
步骤2，采用浮法工艺、平拉工艺、格法工艺、压延工艺、溢流法工艺、中任一种工艺对玻璃进行成型。In step 2, the glass is formed by a float process, a flat pull process, a lattice process, a calendering process, an overflow process, or any one of the processes.
根据权利要求7所述的一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用的制备方法，其特征在于：The method for preparing a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion proof flat glass according to claim 7, wherein:
所述步骤1包括：The step 1 includes:
将所备之各类原料，放置于各自的原料容器之中，使各种原料通过原料输送线，经过计量后，按所需比例送入原料混合搅拌装置中，搅拌混合后进入装The various raw materials prepared are placed in the respective raw material containers, and the various raw materials are passed through the raw material conveying line, and after being metered, they are sent to the raw material mixing and stirring device in the required proportion, stirred and mixed, and then loaded into the raw materials.
载配料的大料罆或料仓中；In the bulk material or silo containing the ingredients;
使配合好的原料进入熔池中，在对应于各玻璃配方的熔化温度熔化，形成The matched raw materials are introduced into the molten pool and melted at a melting temperature corresponding to each glass formulation to form
预定的粘度的玻璃液，再均化，澄清，排出气泡，形成可流动的熔融体；a predetermined viscosity of the molten glass, which is homogenized, clarified, and discharged to form a flowable melt;
步骤2中使用浮法工艺：在本工艺中还须预先备好锡窑，在步骤1的工序后，使熔池的尾部的可流动的熔融体流入锡窑中进行淌平、抛光、拉薄的工艺过程，并经拉边机在工艺规定的方向的导拉和牵引机的牵引，拉出锡槽，并经在玻璃析晶温度区的上线范围，逐步降温的条件下，、退火，待冷却后，经切割，即可制得所述玻璃。The float process is used in step 2: in the process, the tin kiln must be prepared in advance, and after the step of step 1, the flowable melt at the tail of the molten pool is poured into the tin kiln for flattening, polishing, and thinning. The process, and the pulling of the puller in the direction specified by the process and the traction of the tractor, pull out the tin bath, and through the upper line range of the glass crystallization temperature zone, under the condition of gradually cooling, annealing, waiting After cooling, the glass is obtained by cutting.
发明效果：根据本发明，能提供一种高软化点、低析晶速度、特髙铝无碱、防火防爆平板玻璃。另外，还能提供适于该高软化点、低析晶速度、特髙铝无碱、防火防爆平板玻璃的制备方法。Effect of the Invention According to the present invention, it is possible to provide a high softening point, a low crystallization rate, a special aluminum-free alkali-free, fire-proof and explosion-proof flat glass. In addition, a preparation method suitable for the high softening point, low crystallization rate, special aluminum non-alkali, fireproof and explosion-proof flat glass can be provided.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为4％--29％，氧化 钠含量为0.011-0.99％，氧化镁含量为7％--20％，氧化硅含量是氧化钙含量的2.52-4、08倍，氧化钙含量是氧化镁含量的1、0-1、8倍。A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 4% to -29% by weight, and oxidation The sodium content is 0.011-0.99%, the magnesium oxide content is 7%-20%, the silica content is 2.52-4,08 times of the calcium oxide content, and the calcium oxide content is 1,0-1,8 times of the magnesium oxide content. .
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为16.1～35％，氧化钠含量为1～18％，氧化硼含量0.0001-3％，氧化镁含量为7％～20％，氧化硅含量是氧化钙含量的2.53～4.09倍，氧化钙含量是氧化镁含量的1.0～1.8倍。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 16.1 to 35% by weight percent, and the sodium oxide content is 1 to 18%, the boron oxide content is 0.0001 to 3%, the magnesium oxide content is 7% to 20%, the silicon oxide content is 2.53 to 4.09 times the calcium oxide content, and the calcium oxide content is 1.0 to 1.8 times the magnesium oxide content.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为16.1～35％，氧化钠含量为1～13％，氧化镁含量为7％～20％，其特征在于：氧化硅含量是氧化钙含量的2.52～4.08倍，氧化钙含量是氧化镁含量的1.0～1.8倍。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 16.1 to 35% by weight percent, and the sodium oxide content is 1 to 13%, the magnesium oxide content is 7% to 20%, characterized in that the content of silicon oxide is 2.52 to 4.08 times of the content of calcium oxide, and the content of calcium oxide is 1.0 to 1.8 times of the content of magnesium oxide.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：其氧化铝含量为4％--29％，氧化钠含量为0.011-0.99％，氧化锂含量为0.0001～3％，氧化硼含量为0.0001～3％，氧化镁含量为7％--20％，氧化硅含量是氧化钙含量的2.53-4、09倍，氧化钙含量是氧化镁含量的1.0-1.8倍。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 4%-29%, and the sodium oxide content is 0.011-0.99 %, the content of lithium oxide is 0.0001 to 3%, the content of boron oxide is 0.0001 to 3%, the content of magnesium oxide is 7% to -20%, the content of silicon oxide is 2.53-4, 09 times of the content of calcium oxide, and the content of calcium oxide is The magnesium oxide content is 1.0-1.8 times.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化硅含量是氧化钙含量的2.6-4.09倍，A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the silicon oxide content is 2.6-4.09 times of the calcium oxide content,
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化铝含量为6-29％。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 6-29%.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化铝含量为8-29％。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 8-29%.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化铝含量为10-29％。A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 10-29%.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化铝含量为16.1-29％。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 16.1-29%.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化铝含量为25-39％。 A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 25-39%.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化铝含量为23-29％。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 23-29%.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化钠含量为0.001-0.99％或0.001-2.99％或3-9％。A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the sodium oxide content is 0.001-0.99% or 0.001-2.99% or 3-9%.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：氧化钠含量为0.001-0.45％。A high softening point, a low difference in thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the sodium oxide content is 0.001-0.45%.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为0.1-0.2mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of a fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 0.1-0.2 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为0.51-0.7mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass, characterized in that the thickness of the glass is 0.51-0.7 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为0.21-0.5mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 0.21-0.5 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为0.31-0.4mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 0.31-0.4 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为0.1-0.2mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of a fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 0.1-0.2 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为0.71-1.5mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass, characterized in that the thickness of the glass is 0.71-1.5 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass
特征在于：该玻璃的厚度为1.5-2mm。It is characterized in that the thickness of the glass is 1.5-2 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为2.1-5mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass, characterized in that the thickness of the glass is 2.1-5 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为5.1-8mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass, characterized in that the thickness of the glass is 5.1-8 mm.
一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，特征在于：该玻璃的厚度为8.1-20mm。 A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the thickness of the glass is 8.1-20 mm.
以下41类一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用的结抅组合应用发明，首先因为一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃，在平板玻璃用途中：The following 41 types of high softening point, low differential coefficient of thermal expansion coefficient in low temperature zone, low crystallization rate, and application of the composite combination of fireproof and explosion-proof flat glass, first because of a high softening point, low temperature coefficient of thermal expansion Difference, low crystallization rate, fireproof and explosion-proof flat glass, in the use of flat glass:
发现了新的[a.低析晶速度]材料性质；又对已知化合物的巳知的[b.高温区热膨胀系数的差值]及[c.高软化点]和[d.低粘度与高铝含量下的铝、硅、钙、镁的共熔体的性质]和产生的各种效果，都有实质性的改进和提高。New [a. low crystallization rate] material properties were found; well known to known compounds [b. difference in thermal expansion coefficient in high temperature zone] and [c. high softening point] and [d. low viscosity and The properties of the eutectic of aluminum, silicon, calcium and magnesium at high aluminum content] and the various effects produced are substantially improved and improved.
这些材料性质和技术效果，都有融入了每项结抅组合发明中，形成了42类中每类结抅组合内容的互相关联和彼此支持支撑；对于相应的42类传统产品而言，都产生了新的予料不到的功能和予料不到的技术效果；是一切先有42类传统产品，从没揭示过的非显而易见的技术效果；又因为这些非显而易见的技术效果，是也是公知常识中沒有明确的并不能由常识推论得到的；所以都有实质性的进步性及创造性。These material properties and technical effects are integrated into each of the combination inventions, forming an interrelated and supportive support for each of the 42 categories of crust combinations; for the corresponding 42 categories of traditional products, New unanticipated functions and unpredictable technical effects; all of the 42 traditional products that have never been revealed, and the non-obvious technical effects that have never been revealed; and because of these non-obvious technical effects, they are also known. Common sense is not clear and cannot be inferred from common sense; therefore, there is substantial progress and creativity.
也可以把这些材料性质和形成的每类新结抅组合，判断为是一种要素关系变化的发明；发明内容中，42类中每类不同结抅组合要素关系的变化后，对于相应的42类传统产品而言，都产生了新的予料不到的功能和予料不到的技术效果，是也是公知常识中沒有明确的并不能由常识推论得到的；所以都有实质性的进步性及创造性。It is also possible to combine the properties of these materials with each new type of knot formed, and judge that it is an invention of a change in the relationship of the elements; in the invention, the relationship between the different elements of each of the 42 types of the combination is changed for the corresponding 42 In the case of traditional products, new and unpredictable functions and unexpected technical effects are produced. It is also unclear in common sense and cannot be inferred from common sense; therefore, there is substantial progress. And creativity.
(A类)装饰建材从属权利要求应用用途发明与组合发明终端产品3类结抅组合应用发明：(Class A) Decorative Building Materials Dependent Claims Application Use Invention and Combination Invention Terminal Product Category 3 Scarf Combination Application Invention:
(A类1)从属权利要求与结抅组合应用发明或要素变化的发明，之1：(Class A) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 1:
一种高性能彩釉平板玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其基板玻璃表面有1-10种色彩的彩釉层。A high-performance color glazed flat glass, characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the substrate thereof The surface of the glass has a glaze layer of 1-10 colors.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。有析晶速度慢的特征；这能在冷却部和成型部尤其为浮法工艺及各种平板玻璃工艺，形成极为重要的精确的比先有对比技术好得多的工艺控制参数，从而才能精确的有把握的控制大生产。从而制造无任何因析晶而影响透光率的，高质量的本发明防火防爆平板玻璃。 Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thus, the high-quality fire-proof and explosion-proof flat glass of the present invention without any crystallization due to the influence of light transmittance is produced.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的[更高的软化点]、[更好的高温区热膨胀差值、[更高的强度等高性能]，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the [higher softening point] of the flat glass of the present invention, [better thermal expansion difference in high temperature region, [high performance such as higher strength], the shape of the glass can be maintained, and fire, fire, and separation can be achieved. The non-obvious technical effect of the heat wave; the invention has special fireproof and explosion-proof effects of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：彩釉平板玻璃的可控制经济性、标准化及施工设计的便利性：Non-obvious technical effects [3]: Controllable economy, standardization and ease of construction design of glazed flat glass:
本发明由于一种高软化点与高温区低热膨胀率的特征，所以能印刷成大的The invention can be printed into a large one because of the characteristics of a high softening point and a low thermal expansion rate in a high temperature region.
2400×1200mm的超薄厚度为1-4mm的标准板，提供装饰材料的运输及使用的适用性和便利性；(这是陶瓷及石材等产品是不可能实现的)。2400 × 1200mm ultra-thin thickness of 1-4mm standard board, providing the suitability and convenience of transportation and use of decorative materials; (this is impossible to achieve such as ceramics and stone products).
非显而易见的技术效果[4]：本发明，把先有对比技术[1][2][3][4]抗折强度顶点从180Mpa，实质性的改进和提高到抗折强度顶点240Mpa；比先有对比技术[1][2][3][4]抗折强度实质性的改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。Non-obvious technical effects [4]: According to the present invention, the first comparative technique [1][2][3][4] has a flexural strength vertex from 180 MPa, substantial improvement and improvement to a bending strength apex of 240 MPa; Compared with the prior art [1][2][3][4], the flexural strength is substantially improved and increased by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; The flexural strength of the touch screen glass containing 12-15% of aluminum is increased by about 2.4 times, and the bending strength of the calcium sodium glass is increased by about 5 times.
在本用途领域中，抗折强度；可实质性的比先有对比技术[1][2][3][4]改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。In the field of application, the flexural strength; can be substantially improved and improved by 1/4 compared with the prior art [1][2][3][4]; the flexural strength of the existing boron-containing glass is 80Mpa. It is increased by about 3 times; it is about 2.4 times higher than the existing 20-15% touch screen glass flexural strength 100Mpa; it is about 5 times higher than the calcium sodium glass bending strength 50Mpa.
也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。又可以如瓷砖一样磨边、切割，保障图案的无缺陷和产品大板标准化和使用切割便利化。能用1-4mm厚的本发明产品，替代高能耗的厚重瓷砖(8-15mm)和15-25的石材的墙，地面产品，又轻薄化5倍。It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It can also be edged and cut like a tile to ensure the defect-free pattern and standardization of the product board and the use of cutting convenience. It can replace the high-energy thick tile (8-15mm) and the 15-25 stone wall with the 1-4mm thick product of the invention, and the product is 5 times lighter and thinner.
对现陶瓷产品的高强度、轻薄化的替代，产生能源、资源、物流、仓储的因几倍的轻薄化，能产生的节能4-8倍的非显而易见的技术效果。 The high-strength, light-thinning replacement of existing ceramic products, resulting in several times lighter and thinner energy, resources, logistics, and warehousing, can produce 4-8 times less energy-saving non-obvious technical effects.
对陶瓷和石材的[1]耐磨性能、[2]防滑性能、[3]极低水率和防污性能、[4] 高强度及超薄性能、[5]超轻超大板面制品尺寸特征、[6]上墙及干挂方式等，具有六大革命性的优势；能克服整个传统陶瓷工艺装备的效率、节能、环保的难点；而且能克服陶瓷业的高耗能、高污染、高粉尘排放、高水耗、低产出效率的难点；有非显而易见的技术效果。 [1] wear resistance to ceramics and stone , [2] non-slip performance, [3] extremely low water and antifouling properties, [4] high strength and ultra-thin properties, [5] ultra-light oversized panel products Features, [6] upper wall and dry hanging method, etc., have six revolutionary advantages; can overcome the difficulties of efficiency, energy saving and environmental protection of the entire traditional ceramic process equipment; and can overcome the high energy consumption, high pollution and high of ceramic industry Difficulties in dust emissions, high water consumption, and low output efficiency; there are non-obvious technical effects.
(A类2)从属权利要求与结抅组合应用发明或要素变化的发明，之2：(Class A 2) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 2:
一种高性能耐磨彩釉层平板玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其基板玻璃表面有1-10种色彩的彩釉层，其特征在于：其表层的釉料层中含有15-70％的石英晶体或氧化铝晶体。A high-performance wear-resistant color glaze flat plate glass, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass The surface of the substrate glass has a glaze layer of 1-10 colors, and the glaze layer of the surface layer contains 15-70% quartz crystal or alumina crystal.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：由于本发明制品可在650-740℃以下烧结彩釉层，所以可以烧结印刷釉层，可以在釉层加入大量的如30-80％的各种晶体尤其是成本低的石英或钢玉晶体粉或粒，形成史无前例的0.2-3mm的耐磨表层高硬度(石英可达7级的硬度，而加入钢玉则可达9级硬度)，而这在陶瓷生产中作不到的，因为陶瓷的烧成温度在1100℃-1200℃，此时陶瓷表层的石英或钢玉只能变成玻璃相，而在730℃以下，石英或钢玉晶体还可保持结晶相；这还能形成史无前例的装饰玻璃抛光的石英晶体硬度达7级耐磨面表层；具有非显而易见的技术效果。Non-obvious technical effect [3]: Since the product of the invention can sinter the colored glaze layer below 650-740 ° C, the printing glaze layer can be sintered, and a large amount of various crystals such as 30-80% can be added to the glaze layer, especially Low-cost quartz or steel jade crystal powder or granules, forming an unprecedented hardness of 0.2-3mm wear-resistant surface layer (quartz up to 7 grade hardness, while steel jade can reach grade 9 hardness), and this is in ceramic production Can not be done, because the ceramic firing temperature is 1100 ° C -1200 ° C, at this time the ceramic surface of the quartz or steel jade can only become the glass phase, and below 730 ° C, quartz or steel jade crystals can remain crystal Phase; this can also form an unprecedented decorative glass polished quartz crystal with a hardness of 7 grade wear surface; with non-obvious technical effects.
非显而易见的技术效果[4]：其中石英表层因7级硬度是可以抛光的，成为最优的表层石英釉面组合抛光耐磨制品；而钢玉的9级硬度是不能抛光的，但 可预料不到地成为最优的耐久的防滑或耐磨钢玉釉层结抅组合应用发明制品，所以本发明能形成节能环保、低成本优质耐磨的替代升级技术。而且会对陶瓷业的高耗能、高污染、高粉尘排放、高水耗、低产出、低质量的制品及整个装备工艺***提出替代性挑战。具有非显而易见的技术效果。Non-obvious technical effect [4]: The quartz surface layer can be polished due to the hardness of 7 grade, which becomes the optimal surface quartz glaze combination polishing and wear-resistant product; while the 9-grade hardness of steel jade is not polished, but Unexpectedly, it is an optimal durable anti-slip or wear-resistant steel jade enamel layer combination application invention product, so the invention can form an alternative upgrade technology of energy saving, environmental protection, low cost and high quality wear resistance. It also poses an alternative challenge to the ceramic industry's high energy consumption, high pollution, high dust emissions, high water consumption, low output, low quality products and the entire equipment process system. Has a non-obvious technical effect.
非显而易见的技术效果[5]：本发明，把先有对比技术[1][2][3][4]抗折强度顶点从180Mpa，实质性的改进和提高到抗折强度顶点240Mpa；比先有对比技术[1][2][3][4]抗折强度实质性的改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。Non-obvious technical effect [5]: The present invention compares the apex of the first comparative technique [1][2][3][4] from 180Mpa, substantial improvement and improvement to the apex of bending strength 240Mpa; Compared with the prior art [1][2][3][4], the flexural strength is substantially improved and increased by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; The flexural strength of the touch screen glass containing 12-15% of aluminum is increased by about 2.4 times, and the bending strength of the calcium sodium glass is increased by about 5 times.
在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。In this field of application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is lighter than the existing TFT boron-containing glass. 1/3; lighter than calcium sodium glass, 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
所以，能使一种高性能耐磨彩釉层平板玻璃，替代高能耗的厚重耐磨瓷砖(8-15mm)和15-25的石材的地面产品，又轻薄化5-6倍，还对现陶瓷产品的高强度、轻薄化的替代，产生能源、资源、物流、仓储的因几倍的轻薄化，能产生的节能4-8倍的非显而易见的技术效果。Therefore, it can make a high-performance wear-resistant glaze layer flat glass, instead of high-energy thick and wear-resistant ceramic tile (8-15mm) and 15-25 stone ground products, it is 5-6 times lighter and thinner. The high-strength, light-thinning replacement of ceramic products, resulting in several times lighter and thinner energy, resources, logistics, and warehousing, can produce 4-8 times less energy-saving non-obvious technical effects.
非显而易见的技术效果[6]：a.2-5mm厚的可等于10-25mm厚的钙钠玻璃强度]；b.160cm x240cm 200cm x300cm或300cm x400cm大尺寸的本发明高性能耐磨彩釉层平板玻璃产品，用于设计和替代各类地毯时，不但强度高，安装运输轻巧方便，还可以采用电脑喷印，有保障形成各种羊毛、化纤、丝材质等逼真质感的地毯图案；c.其中石英表层因7级硬度是可以抛光的，成为最优的表层石英釉面组合抛光耐磨制品，或成为最优的耐久的防滑的混有耐磨钢玉釉层结抅的亚光地毯图案的应用发明制品。Non-obvious technical effect [6]: a. 2-5mm thick can be equal to 10-25mm thick calcium soda glass strength]; b.160cm x240cm 200cm x 300cm or 300cm x 400cm large size of the high performance wear-resistant glaze layer of the present invention Flat glass products, used to design and replace all kinds of carpets, not only high strength, light and convenient installation and transportation, but also can be printed by computer, which guarantees the formation of various realistic carpet textures such as wool, chemical fiber and silk material; c. Among them, the quartz surface layer can be polished due to the hardness of 7 grade, which becomes the best surface quartz glazed combination polishing and wear-resistant product, or becomes the best durable non-slip matte carpet pattern with wear-resistant steel jade enamel layer. Application of the invention.
(A类3)从属权利要求与结抅组合应用发明或要素变化的发明，之3：(Class A 3) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 3:
一种高性能超薄型墙面贴面彩釉平板玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其基板玻璃表面有1-10种色彩的彩釉层，其特征在于：其厚度在0.5-1.5mm。 A high-performance ultra-thin wall-faced glazed flat glass, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof For the application of flat glass, the surface of the substrate glass has a glaze layer of 1-10 colors, and the thickness thereof is 0.5-1.5 mm.
非显而易见的技术效果：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的[更高的软化点]、[更好的高温区热膨胀差值、[更高的强度等高性能]，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effect: In the application place, the present invention compares the prior art [1][2][3][4] in the case of fire or high temperature, in the state of high temperature zone, due to the invention Flat glass [higher softening point], [better high temperature zone thermal expansion difference, [higher strength and other high performance], can maintain the shape of the glass, can play fire, fire, heat wave Non-obvious technical effects; The invention has special fireproof and explosion-proof effects of building materials, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technical effect.
本发明，把先有对比技术[1][2][3][4]抗折强度顶点从180Mpa，实质性的改进和提高到抗折强度顶点240Mpa；The invention has the prior art [1][2][3][4] bending strength apex from 180Mpa, substantial improvement and improvement to the bending strength apex 240Mpa;
在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。In this field of application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is lighter than the existing TFT boron-containing glass. 1/3; lighter than calcium sodium glass, 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
所以，一种高性能超薄型贴面彩釉平板玻璃，可以在其厚度在0.5-1.5mm的很轻量条件下，达到2.5-7.5mm钙钠玻璃的强度。Therefore, a high-performance ultra-thin veneer glazed flat glass can achieve a strength of 2.5-7.5 mm calcium soda glass under a very lightweight condition of 0.5-1.5 mm.
所以用以替代传统的装饰墙壁纸：So to replace the traditional decorative wall paper:
非显而易见的技术效果[1]：一种高性能超薄型贴面彩釉平板玻璃，a.采用电喷工艺能制造一切装饰墙壁纸的图案；b.采用亚光无机彩釉材料，在玻璃表面可以制造无反光的一切装饰墙壁纸的图案；c.或用现有技术制造出金色，银色，银灰色等比一切装饰墙壁纸更高水平的图案花纹；Non-obvious technical effects [1]: a high-performance ultra-thin veneer glazed flat glass, a. using electrospray process to make all decorative wall paper patterns; b. using matt inorganic glaze materials, in glass The surface can be used to make a pattern of all decorative wall paper without reflection; c. or use the prior art to create a higher level of pattern pattern than any decorative wall paper, such as gold, silver, silver gray;
非显而易见的技术效果[2]：一种高性能超薄型贴面彩釉平板玻璃：a.比贴面平整度可如镜面，传统装饰墙壁纸平整度不可比；b.墙面打底要求基本平整，用一层薄瓷砖胶贴合，打底比采用装饰墙壁纸简单，省工时；c.现采用装饰墙壁纸的100cm x 350cm或200cm x 350cm的尺寸，能在连续贴墙拼接时，比软性装饰墙壁纸更能准确对准花纹图案，比装饰墙壁纸有更好的墙面平面整体感；d.并能在连续贴墙拼接时，比软性装饰墙壁纸更方便，髙效率；e.一种高性能超薄型贴面彩釉平板玻璃，在替代装饰墙壁纸用途中，有更好的不易积灰，易于清洁打理的特点；f.装饰墙壁纸2-3年左右边缝易卷起，髙质量周期仅3年左右，壁纸使用寿命一般3-6年；而本发明高性能超薄型贴面彩釉平板玻璃可永不上.下.左.右边缝易卷起，高性能无机彩釉层及髙强度玻璃使用寿命达100-300年以上。 Non-obvious technical effect [2]: A high-performance ultra-thin veneer glazed flat glass: a. The flatness of the veneer can be like a mirror surface, and the flatness of the traditional decorative wall paper is incomparable; b. Basically flat, laminated with a thin layer of tile adhesive, the base is simpler than the decorative wall paper, saving labor time; c. Now using the decorative wall paper 100cm x 350cm or 200cm x 350cm size, can be used in continuous wall stitching, More accurate alignment of the pattern than the soft decorative wall paper, which has a better overall wall surface than the decorative wall paper; d. It can be more convenient than the soft decorative wall paper when the continuous wall is spliced. e. A high-performance ultra-thin veneer glazed flat glass, in the use of alternative decorative wall paper, has better characteristics of not easy to accumulate dust, easy to clean and care; f. decorative wall paper for 2-3 years The seam is easy to roll up, the quality cycle is only about 3 years, and the wallpaper has a service life of 3-6 years. The high-performance ultra-thin veneer glazed flat glass of the invention can never be used. The left and right seams are easy to roll. High-performance inorganic glaze layer and enamel strength glass life of 100-300 years On.
非显而易见的技术效果[3]：一种高性能超薄型贴面彩釉平板玻璃，尤其适合于木建筑别墅的木板内墙面应用：a.因为可以在其厚度在0.5-1.0mm的很轻量条件下，能克服木建筑别墅的总支架和木板内墙面都不能太多承重的难题；b.还能达到2.5-6mm钙钠玻璃的强度；c.能达到木建筑别墅的内墙面，前所未有的大大超过装饰墙壁纸平面整体感，和镜面平整度；d.又能达到和超过传统的装饰墙壁纸的一切装饰墙壁纸的图案质感效果。Non-obvious technical effect [3]: A high-performance ultra-thin veneer glazed flat glass, especially suitable for wood interior wall applications of wooden building villas: a. because it can be very thick in 0.5-1.0mm Under light conditions, it can overcome the problem that the total support of the wooden building villa and the inner wall of the wooden board can not bear too much weight; b. can also reach the strength of 2.5-6mm calcium soda glass; c. can reach the inner wall of the wooden building villa The surface is unprecedentedly more than the overall sense of the decorative wall paper plane, and the mirror flatness; d. It can reach and exceed the pattern texture effect of all the decorative wall paper of the traditional decorative wall paper.
但本发明一种高性能超薄型贴面彩釉平板玻璃，替代装饰墙壁纸，为了适应对房屋历史太长的木建筑别墅，其木板内墙面巳有略为变型的应用；或为了防止新木板内墙面在多年后略为变型，应对办法是：[1]对传统瓷胶作增加软度特征的改进；[2]在木板内墙面采用双面胶予设在超薄型贴面彩釉平板玻璃背面的结构，能大大增加贴粘便利性和效率；[3]在本发明一种高性能超薄型贴面彩釉平板玻璃的安装尺寸上，从100cm x 350cm或200cm x 350cm的尺寸，改变为60cm x 60cm或90cm x 90cm或120cm x 120cm或150cm x 150cm的尺寸：达到a.能适应木板内墙面巳有略为变型的应用；b.安装不但能省工快捷，也能达到在连续贴墙拼接时，比软性装饰墙壁纸更能准确对准花纹图案，可有永不在上.下.左.右边缝易卷起的效果；However, the present invention provides a high-performance ultra-thin veneer glazed flat glass instead of decorative wall paper. In order to adapt to the wooden building villa which has a long history of the house, the inner wall of the wooden board has a slightly modified application; or to prevent new The wall surface of the wooden board has been slightly modified after many years. The countermeasures are: [1] the improvement of the softness characteristics of the traditional porcelain glue; [2] the double-sided glue on the inner wall of the board is set in the ultra-thin veneer The structure of the back surface of the glazed flat glass can greatly increase the sticking convenience and efficiency; [3] in the mounting size of a high performance ultra-thin veneer glazed flat glass of the present invention, from 100cm x 350cm or 200cm x 350cm Dimensions, changed to 60cm x 60cm or 90cm x 90cm or 120cm x 120cm or 150cm x 150cm size: to achieve a. can adapt to the inner wall of the board with a slightly modified application; b. installation can not only save labor, but also reach When splicing the wall continuously, it can accurately align the pattern with the soft decorative wall paper, and it can have the effect of never rolling up the upper, lower, left and right seams;
(B类)建筑与工业配套深加工，从属权利要求应用用途发明与结构结抅组合应用发明10类产品：(Class B) Construction and industrial supporting deep processing, dependent claims Application use Invention and structure knot combination application invention 10 products:
(B类1)从属权利要求与结抅组合应用发明或要素变化的发明，之4：(Class B 1) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 4:
一种高性能船用玻璃窗结构，其特征在于：其窗玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其四周边上安装有树脂边框或金属边框支撑装置。The utility model relates to a high performance marine glazing structure, characterized in that the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass. A resin frame or a metal frame support device is mounted on the periphery of the four sides.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术1.2.3在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别 的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effect [2]: In the application place, the present invention is compared with the prior art 1.2.3 in the high temperature state in the case of fire or high temperature, due to the higher softening of the flat glass of the present invention. High performance, such as difference in thermal expansion between high temperature zones and higher strength, can have the shape of maintaining glass, and can achieve non-obvious technical effects of fireproof, fireproof and heat insulation waves; The fireproof and explosion-proof effect of the building materials will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：在本用途领域中，抗折强度；可实质性的比先有对比技术[1][2][3][4]改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。Non-obvious technical effects [3]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
由于本发明可以制造特髙强度的5-6mm厚的防弹、防爆玻璃，防弹性能也可优于常规的25mm厚的F79级全玻防弹玻璃(防***的钢芯弹)，本发明还要轻薄5倍。由于本发明可以制造特髙强度仅8-9mm厚全玻防弹玻璃，其防弹性能也可优于常规的40mm厚F56级(防56/AK47冲锋枪或81步枪的钢芯弹)全玻防弹玻璃；还要轻薄5倍，这是其它现有一切现有玻璃不可能作到的新材料性质。所以尤其在船的驾驶室的门窗采用本发明船用玻璃窗结构，对防海盗抢劫船泊，有防范和增加应对时间的作用。具有非显而易见的技术效果。Since the invention can manufacture the special-strength 5-6mm thick bullet-proof and explosion-proof glass, the ballistic performance can also be better than the conventional 25mm thick F79-class full glass bulletproof glass (the steel core bullet for the pistol), and the invention is also thin and light. 5 times. Since the invention can manufacture a full glass bulletproof glass with a special strength of only 8-9 mm, the ballistic performance can also be superior to the conventional 40 mm thick F56 grade (anti-56/AK47 submachine gun or 81 rifle steel core projectile) full glass bulletproof glass; It is also five times lighter and thinner, which is a new material property that is impossible for all existing existing glass. Therefore, especially in the door and window of the cab of the ship, the marine glass window structure of the invention is used, and the anti-pirate robbery boat mooring has the effect of preventing and increasing the response time. Has a non-obvious technical effect.
(B类2)从属权利要求与结抅组合应用发明或要素变化的发明，之5：(Class B 2) Inventions in which the dependent claims and the combination of the invention apply the changes in the elements, 5:
一种高性能飞机玻璃窗结构，其特征在于：其窗玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其四周边上安装有树脂边框或金属边框支撑装置。A high performance aircraft glazing structure, characterized in that: the window glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass. A resin frame or a metal frame support device is mounted on the periphery of the four sides.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。 Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：在本用途领域中也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; There are TFT boron-containing glass, which is 1/3 lighter and thinner than calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
本发明玻璃窗结构：[a]用巅覆性的产品，4--5倍的几何倍数的更高的强度，将对这种安全性要求极髙的航空飞机，的在防飞鸟撞击，防飞行中内外压差急变引起飞机玻璃破裂，因几倍的强度上升而更可防人为破坏飞机侧窗玻璃等易发事故，提供新的飞行安全保障，具有非显而易见的技术效果；[b]用巅覆性的4-5倍的几何倍数的更轻薄化的飞机窗玻璃产品，在保障安全的前提下，提供降低飞机重量而节能的选择。具有非显而易见的技术效果。The glazing structure of the invention: [a] with a covering product, a higher strength of 4-5 times the geometric multiple, will be against the flying aircraft, which is extremely demanding for such safety. The sudden change of pressure inside and outside of the aircraft caused the aircraft glass to rupture. Due to the increased strength of several times, it can prevent man-made damage to the aircraft side window and other accidents, provide new flight safety guarantees, and have non-obvious technical effects; [b] The more lightweight and thinner aircraft glazing products with 4-5 times the geometric multiples provide the option of reducing the weight of the aircraft and saving energy while ensuring safety. Has a non-obvious technical effect.
(B类3)从属权利要求与结抅组合应用发明或要素变化的发明，之6：(Class B 3) Inventions in which the dependent claims and the combination are applied to the invention or the elements are changed, 6:
一种高性能汽车用玻璃窗结构，其特征在于：其汽车窗玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其四周边上安装有树脂边框或金属边框支撑装置。A high-performance glazing structure for an automobile, characterized in that: the automobile glazing is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass The application has a resin frame or a metal frame support device mounted on the periphery thereof.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of fire or high temperature, in the state of high temperature region, The higher softening point of the flat glass of the invention, the better high temperature zone thermal expansion difference, higher strength and the like, can have the shape of maintaining the glass, and can be used for fire prevention, fire insulation and heat insulation. Technical effect; The invention has special fireproof and explosion-proof effect of building materials, and greatly enhances the ability of bursting in the high temperature region when the glass volume is rapidly increased, and has non-obvious technical effects.
非显而易见的技术效果[3]：本发明有特别的防火防爆效果：将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力。能有利于在碰到车外着火时，因车玻璃防火而有利于人或车逃离着火区，具有非显而易见的技术效果。Non-obvious technical effects [3]: The present invention has a special fire and explosion-proof effect: it will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased. It can help to avoid people or cars from escaping from the fire area when it comes to fire outside the car. It has non-obvious technical effects.
非显而易见的技术效果[4]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比 钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [4]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; Existing TFT boron-containing glass, light and thin 1/3; ratio Calcium soda glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
(B类4)从属权利要求与结抅组合应用发明或要素变化的发明，之7：(Class B 4) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 7:
一种高性能建筑物玻璃窗结构，其特征在于：其窗玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其四周边上安装有树脂边框或金属边框支撑装置。A high-performance building glazing structure, characterized in that: the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass A resin frame or a metal frame support device is mounted on the periphery of the four sides.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：本发明有特别的建筑物防火防爆效果：Non-obvious technical effects [3]: The invention has special fire and explosion-proof effects of buildings:
[a]本发明由于钠含量低，软化点越高[为780℃-860℃]则越能在碰到火灾或高温时，在高温区状态下保持玻璃的形状，更能起到防火、隔火、隔热浪的作用；[a] In the present invention, since the sodium content is low, the softening point is higher [from 780 ° C to 860 ° C], the more the shape of the glass can be maintained in a high temperature region when fire or high temperature is encountered, and fireproofing and separation can be achieved. The role of fire and heat insulation waves;
[b]本发明比其它玻璃在高温区的热膨胀率的差值低很多，所以在玻璃在碰到火灾或高温时，则越不易于因在高温区的玻璃体积急速变大而爆裂；所以将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力；能防止或大大延缓火灭由其它楼层通过外墙窗玻璃向自已室内转移而加快全楼整体火势；或能防止或大大延缓火灭由其它室内向外墙转移而加快全楼整体火势；能产生很好的室内生活的人类防火安全和争取更长的逃生及营救的信心；能有利于在碰到建筑物着火时，有较长时间利于人们逃离着火区；具有非显而易见的技术效果。[b] The present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region; It greatly enhances the ability to resist bursting when the volume of glass in the high temperature zone is rapidly increased; it can prevent or greatly delay the fire from being extinguished by other floors through the external window glass to accelerate the overall fire of the whole building; or can prevent or greatly delay the fire Extinguish the transfer from other indoors to the outer wall to speed up the overall fire of the whole building; it can produce good indoor fire safety for human beings and gain confidence in long-term escape and rescue; it can be beneficial when it comes to building fires. It is good for people to escape from the fire area for a long time; it has non-obvious technical effects.
非显而易见的技术效果[4]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比 钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [4]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; Existing TFT boron-containing glass, light and thin 1/3; ratio Calcium soda glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
(B类5)从属权利要求与结抅组合应用发明或要素变化的发明，之8：(Class B 5) Inventions in which the dependent claims and the combination of the invention apply the changes in the elements, 8:
一种高性能中空玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；各层玻璃四周边上粘贴有支撑装置；各层玻璃之间有3-50mm的经抽真空的隔离空间。A high-performance insulating glass characterized in that: the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass; A support device is attached to the periphery; there is a 3-50 mm vacuumed isolation space between the layers of glass.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
本发明能创造新节能市场，形成巅覆性的建筑用超高强度又轻薄化的3-5层中空髙效节能玻璃：传统中空节能玻璃因强度制约最少为6mm玻璃+真空隔温层+6mm玻璃，仅1层真空隔温层；而本发明可1.2mm玻璃+真空隔温层+1.2mm玻璃+真空隔温层+1.2mm玻璃+真空隔温层+1.2mm玻璃，等于有3层真空隔温层，但玻璃总厚度仅4.8mm，不但比传统的二层玻璃的中空节能产品的玻璃总厚度12mm轻，而且有3-5层真空隔温层的隔热节能效果比传统的仅1层真空隔温层的产品效果好得太多，能开创中空玻璃的髙效节能的新历史，具有非显而易见的技术效果。The invention can create a new energy-saving market, and form a super-high-strength and light-thin 3-5 layer hollow efficiency energy-saving glass for building covering: the traditional hollow energy-saving glass is limited to 6mm glass + vacuum insulation layer +6mm due to strength limitation. Glass, only one layer of vacuum insulation layer; and the invention can be 1.2mm glass + vacuum insulation layer +1.2mm glass + vacuum insulation layer +1.2mm glass + vacuum insulation layer +1.2mm glass, equal to three layers of vacuum The temperature insulation layer, but the total thickness of the glass is only 4.8mm, which is not only lighter than the total thickness of the traditional two-layer glass hollow energy-saving product, but also has a heat insulation effect of 3-5 layers of vacuum insulation layer than the traditional one. The effect of the layer vacuum insulation layer is too good, which can create a new history of efficiency and energy saving of insulating glass, and has non-obvious technical effects.
(B类6)从属权利要求与结抅组合应用发明或要素变化的发明，之9： (Class B 6) Inventions in which the dependent claims and the combination of the invention apply the invention or the elements, 9:
一种高性能建筑物玻璃幕墙，其特征在于：其玻璃幕墙是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其被固定在上金属支撑装置上。A high-performance building glass curtain wall, characterized in that: the glass curtain wall is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is fixed to the upper metal support device.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：本发明有特别的建筑物防火防爆效果：Non-obvious technical effects [3]: The invention has special fire and explosion-proof effects of buildings:
[a]本发明由于氧化锅的含量低，软化点会大大上升；而本发明由于软化点越高[为780℃-860℃]则越能在碰到火灾或高温时，在高温区状态下保持玻璃的形状，更能起到防火、隔火、隔热浪的作用；[a] In the present invention, since the content of the oxidizing pot is low, the softening point is greatly increased; and the higher the softening point of the present invention [from 780 ° C to 860 ° C], the more likely it is in the high temperature region when it hits a fire or a high temperature. Keeping the shape of the glass, it can play the role of fire prevention, fire separation and heat insulation;
[b]本发明比其它玻璃在高温区的热膨胀率的差值低很多，所以在玻璃在碰到火灾或高温时，则越不易于因在高温区的玻璃体积急速变大而爆裂；[b] The present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region;
所以将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力；能防止或大大延缓火灭由其它楼层通过外墙窗玻璃向自已室内转移而加快全楼整体火势；或能防止或大大延缓火灭由其它室内向外墙转移而加快全楼整体火势；能产生很好的室内生活的人类防火安全和争取更长的逃生及营救的信心；能有利于在碰到建筑物着火时，有较长时间利于人们逃离着火区；具有非显而易见的技术效果。Therefore, it will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased; it can prevent or greatly delay the fire from being extinguished by other floors through the external window glass to accelerate the overall fire of the whole building; or can prevent or greatly Delaying the fire from the other indoors to the external wall to speed up the overall fire of the whole building; can produce good indoor fire safety and strive for greater escape and rescue confidence; can help when the building hits the fire, It has a long time to help people escape from the fire zone; it has non-obvious technical effects.
非显而易见的技术效果[4]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能建筑物玻璃幕墙强度，比现有钙钠玻璃强度在同等重量时高5倍。Non-obvious technical effects [4]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the high-performance building glass curtain wall strength to be five times higher than the existing calcium soda glass strength at the same weight.
(B类7)从属权利要求与结抅组合应用发明或要素变化的发明，之10： (Class B 7) Inventions in which the dependent claims and the combination are applied to the invention or the elements are changed, 10:
一种高性能超大面积的薄玻璃窗或玻璃幕墙，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；其玻璃的厚度为4-10mm，其玻璃的尺寸为3-40平方米，或其玻璃的厚度为10.1-20mm，其玻璃的尺寸为15.1-80平方米；A high-performance super-large area thin glass window or glass curtain wall, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass Application; the thickness of the glass is 4-10mm, the size of the glass is 3-40 square meters, or the thickness of the glass is 10.1-20mm, and the size of the glass is 15.1-80 square meters;
非显而易见的技术效果[1]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。也能使玻璃强度，比现有钙钠玻璃强度在同等重量时高5倍。Non-obvious technical effects [1]: In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight. It also enables the strength of the glass to be five times higher than the strength of the existing calcium soda glass at the same weight.
本发明的巅覆性的技术效果在于：建筑用玻璃材料都是钙钠玻璃，强度仅为50Mpa；而本发明髙性能玻璃可达180-240Mpa，达4--5倍的几何倍数的更高的强度，可以使建筑玻璃的防撞击、防爆裂、防各种击打爆性能等、安全性上升4倍-5倍；可设计成无被铝合金骨架分割的、超大板面的无遮挡全景建筑玻璃，尤其在各类办公楼、酒店及公寓楼、及往宅楼及别墅等建筑的室内视觉，能展现超大范围的完整的窗外美丽景观画面(如花园、山景、水景、海景、城市景色)，产生巅覆性窗建筑的新功能生活体验，也能巅覆各类建筑的超大面积玻璃的外立面观感，能创造新消费市场，开创建筑设计价值的新历史；更能为建筑商及用户带来崭新的价值，具有非显而易见的技术效果：The technical effect of the coating of the invention is that the glass materials for construction are all sodium soda glass, the strength is only 50Mpa; and the performance glass of the invention can reach 180-240Mpa, and the geometric multiple of 4-5 times is higher. The strength can make the building glass anti-collision, explosion-proof, anti-shock performance, etc., and the safety is increased by 4 times to 5 times; it can be designed as an unobstructed panorama of the super-large board without being divided by the aluminum alloy skeleton. Architectural glass, especially in various office buildings, hotel and apartment buildings, and indoor visuals of buildings and villas, can display a wide range of beautiful panoramic views of the window (such as garden, mountain, water, sea, city) Scenery), creating a new functional life experience of the covered window building, can also cover the façade of the super-large glass of various buildings, create a new consumer market, create a new history of architectural design value; Business and users bring new value with non-obvious technical effects:
A、本发明由于没有传统的在大面积窗或幕墙使用中的，多个铝合金窗架，所以能耐更长时间高温(因本发明玻璃软化点达780℃-880℃，大大高于铝合金框软化点400-450℃)，所以加大玻璃面积能提升建筑物整体防火、隔火、隔热浪的能力，具有非显而易见的技术效果。A. The present invention can withstand high temperature for a long time because there is no traditional aluminum alloy window frame in the use of large-area windows or curtain walls (because the softening point of the glass of the invention reaches 780 ° C - 880 ° C, much higher than aluminum alloy The frame softening point is 400-450 ° C), so increasing the glass area can improve the overall fire, fire and heat insulation of the building, and has non-obvious technical effects.
B、本发明比钠钙玻璃其[抗折强度仅45-50Mpa]强度高4-5倍，也更将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。B. The present invention has a 4-5 times higher strength than the soda lime glass [fracture strength of only 45-50 Mpa], and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technique. effect.
C、本发明能防止或大大延缓火灭由其它楼层通过外墙窗玻璃向自已室内转移而加快全楼整体火势；或能防止或大大延缓火灭由其它室内向外墙转移而加快全楼整体火势；能产生很好的室内生活的人类防火安全和争取更长的逃生及 营救的信心，是一种人类安全感的效果的生活体验，能巅覆性的创造新消费市场，开创建筑防火玻璃的新历史，具有非显而易见的技术效果。C. The invention can prevent or greatly delay the fire from being extinguished by other floors through the outer wall window glass to accelerate the overall fire of the whole building; or can prevent or greatly delay the fire from being transferred from other indoors to the external wall to accelerate the whole building as a whole Fire; can generate good indoor fire safety for humans and strive for longer escapes and Rescuing confidence is a life experience with the effect of human security. It can create new consumer markets and create a new history of building fireproof glass with non-obvious technical effects.
D、因比现有钙钠建筑玻璃有4-5倍的更高的强度；可设计成无被铝合金骨架分割的、超大板面的无遮挡全景建筑玻璃，尤其在各类办公楼、酒店及公寓楼、及往宅楼及别墅等建筑的室内视觉，能展现超大范围的完整的窗外美丽景观画面(如花园、山景、水景、海景、城市景色)，产生巅覆性窗建筑的新功能生活体验，也能巅覆各类建筑的超大面积玻璃的外立面观感，开创建筑设计价值的新历史；更能为建筑商及用户带来崭新的价值，具有非显而易见的技术效果。D. It has 4-5 times higher strength than the existing calcium-sodium architectural glass; it can be designed as an unobstructed panoramic architectural glass with no large plate surface, especially in various office buildings and hotels. And the indoor vision of the apartment building, and the buildings such as the house and the villa, can display a large range of beautiful panoramic views of the window (such as garden, mountain, water, sea, city), creating new windows The functional life experience can also cover the façade of the super-large glass of various buildings, create a new history of architectural design value, and bring new value to builders and users, with non-obvious technical effects.
非显而易见的技术效果[3]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [3]: Discovered low crystallization rate crystal velocity properties, resulting in high quality, large production technical effects.
非显而易见的技术效果[4]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [4]: In the application place, the present invention is especially in comparison with the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
(B类8)从属权利要求与结抅组合应用发明或要素变化的发明，之11：(Class B 8) Inventions in which the dependent claims and the combination are applied to the invention or the elements are changed, 11:
一种高性能钢化玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，经化学钢化或物理钢化制成。A high-performance tempered glass characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass, chemically tempered or Made of physical tempering.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。有析晶速度慢的特征；这能在冷却部和成型部尤其为浮法工艺及各种平板玻璃工艺，形成极为重要的精确的比先有对比技术好得多的工艺控制参数，从而才能精确的有把握的控制大生产。从而制造无任何因析晶而影响透光率的，高质量的本发明平板玻璃；Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thereby producing a high quality flat glass of the invention without any crystallization due to crystallization;
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃 的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares with the prior art [1][2][3][4] in the state of high temperature when encountering fire or high temperature, Due to the flat glass of the present invention High softening point, better high temperature zone thermal expansion difference, higher strength and other high performance, can maintain the shape of the glass, can play a non-obvious technical effect of fire, fire, heat wave; The invention has special fireproof and explosion-proof effects of building materials, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：本发明有特别的建材防火防爆效果，而且本发明玻璃经过强化后，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effect [3]: The invention has special fireproof and explosion-proof effects of building materials, and the glass of the invention is strengthened, which greatly enhances the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technology. effect.
非显而易见的技术效果[4]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [4]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
(B类9)从属权利要求与结抅组合应用发明或要素变化的发明，之12：(Class B 9) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 12:
一种高性能玻璃，或钢化玻璃，或夾胶玻璃的玻璃台面傢具，其特征在于：其玻璃台面，是由权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃制成，其台面下部有支撑装置。A high-performance glass, or tempered glass, or a glass-top furniture of laminated glass, characterized in that the glass table top is a low difference and a low coefficient of thermal expansion coefficient of a high softening point and a high temperature zone according to claim 1. The crystallization rate, fireproof and explosion-proof flat glass are made, and the lower part of the table has support means.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃台面的强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the strength of high-performance glass countertops to be five times higher than the existing calcium soda glass at the same thickness and weight.
(B类10)从属权利要求与结抅组合应用发明或要素变化的发明，之13： (Class B 10) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 13:
一种高性能夹胶玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其各层玻璃的之间有树脂材料层。A high-performance laminated glass, characterized in that the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the layers thereof There is a layer of resin material between the glass.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能夹胶玻璃强度，比现有钙钠夹胶玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables the performance of high-performance laminated glass to be five times higher than the strength of existing calcium-sodium laminated glass at the same thickness and weight.
(B类11)从属权利要求与结抅组合应用发明或要素变化的发明，之14：(Class B 11) The invention of the invention or the change of the elements of the dependent claims and the combination of the following, 14:
一种高性能防弹防爆玻璃，其特征在于，其包括：防弹防爆玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；其各片玻璃板之由树脂片粘合。The utility model relates to a high performance bulletproof and explosion-proof glass, which comprises: bulletproof explosion-proof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, a fireproof and explosion-proof flat glass Application; each of the glass sheets is bonded by a resin sheet.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。 Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
[1]本发明由于氧化钠的含量低，软化点会大大上升；而本发明由于软化点越高，则越能在碰到火灾或高温时，在高温区状态下保持玻璃的形状，更能起到防火、隔火、隔热浪的作用；[1] In the present invention, since the content of sodium oxide is low, the softening point is greatly increased; and the higher the softening point of the present invention, the more the shape of the glass can be maintained in a high temperature region when it hits a fire or a high temperature. Play a role in fire prevention, fire separation, and heat insulation;
[2]本发明比其它玻璃在高温区的热膨胀率的差值低很多，所以在玻璃在碰到火灾或高温时，则越不易于因在高温区的玻璃体积急速变大而爆裂；[2] The present invention has a much lower difference in thermal expansion rate than other glasses in a high temperature region, so that when the glass is exposed to fire or high temperature, the less likely it is to burst due to the rapid increase in the volume of the glass in the high temperature region;
所以将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力；能防止或大大延缓火灭由其它楼层通过外墙窗玻璃向自已室内转移而加快全楼整体火势；或能防止或大大延缓火灭由其它室内向外墙转移而加快全楼整体火势；能产生很好的室内生活的人类防火安全和争取更长的逃生及营救的信心；能有利于在碰到建筑物着火时，有较长时间利于人们逃离着火区；具有非显而易见的技术效果。Therefore, it will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased; it can prevent or greatly delay the fire from being extinguished by other floors through the external window glass to accelerate the overall fire of the whole building; or can prevent or greatly Delaying the fire from the other indoors to the external wall to speed up the overall fire of the whole building; can produce good indoor fire safety and strive for greater escape and rescue confidence; can help when the building hits the fire, It has a long time to help people escape from the fire zone; it has non-obvious technical effects.
非显而易见的技术效果[3]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [3]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
又由于本发明可以制造特髙强度的由3层玻璃组成的6-7mm厚的防弹、防爆玻璃，防弹性能也可优于常规的由3层玻璃组成的25mm厚的F79级全玻防弹玻璃(防***的钢芯弹)，本发明还要轻薄4-5倍。由于本发明可以制造特髙强度由3层玻璃组成的仅8-9mm厚全玻防弹玻璃，其防弹性能也可优于常规的由3层玻璃组成的40mm厚F56级(防56/AK47冲锋枪或81步枪的钢芯弹)全玻防弹玻璃；还要轻薄4-5倍，这是其它现有一切现有玻璃不可能作到的新材料性质。所以，对于透明装甲型船、舰、游艇、建筑物、居住等防弹防爆玻璃；Moreover, since the invention can manufacture a 6-7 mm thick bulletproof and explosion-proof glass composed of three layers of glass with special strength, the ballistic performance can also be superior to the conventional 25 mm thick F79 class full glass bulletproof glass composed of three layers of glass ( The steel core of the pistol), the invention is also 4-5 times thinner. Since the present invention can manufacture a full-glass bulletproof glass of only 8-9 mm thick composed of three layers of glass, the ballistic performance can also be superior to the conventional 40 mm thick F56 grade consisting of three layers of glass (anti-56/AK47 submachine gun or 81 rifle steel core bullet) full glass bulletproof glass; also thin and light 4-5 times, which is the new material nature of other existing existing glass. Therefore, for bulletproof and explosion-proof glass of transparent armored ships, ships, yachts, buildings, residences, etc.;
特髙强度的更安全的火车及高铁玻璃等的下游终端使用者：飞机制造商、舰船制造商、汽车制造商、银行及金融类业主、珠宝业业主、保安场所业主等，能形成顶级技术的唯一性支撑，具有非显而易见的技术效果。Specially safer trains and downstream end users such as high-speed rail glass: aircraft manufacturers, shipbuilders, car manufacturers, bank and financial owners, jewellery owners, security owners, etc., can form top technology The unique support of the non-obvious technical effect.
(C类)家具4类从属权利要求与结抅组合应用发明或要素变化的发明，组合发明终端产品：(Class C) Furniture 4 category dependent claims and knot combination invention invention or element change invention, combined invention terminal product:
(C类1)从属权利要求与结抅组合应用发明或要素变化的发明，之15： (C Category 1) Inventions in which the invention or the element change is applied in a dependent claim and a combination of the following:
一种高性能彩釉玻璃板组合橱柜，其特征在于：其玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其表面或背面有1-10种色彩的彩釉层，平板玻璃四周有金属边框包围，使之形成组合板；在金属边框之间有金属联接装置，使之成为一种彩釉玻璃板组合橱柜。The invention relates to a high-performance color glazed glass plate combination cabinet, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass There are 1-10 kinds of color glaze layer on the surface or back surface, and the flat glass is surrounded by a metal frame to form a composite board; there is a metal connecting device between the metal frames, making it a glazed glass plate combination cupboard.
(C类2)从属权利要求与结抅组合应用发明或要素变化的发明，之16：(C Category 2) Inventions in which the invention or element changes are applied in the dependent claims and the combination of the elements, 16:
一种高性能推拉门柜玻璃面板家俱，其特征在于：其玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其表面或背面有1-10种色彩的彩釉层，四周有金属边框，金属边框的上下有滚轮。A high-performance sliding door cabinet glass panel furniture, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass There are 1-10 colors of glaze on the surface or back, surrounded by metal frames, and the metal frame has rollers on the top and bottom.
(C类3)从属权利要求与结抅组合应用发明或要素变化的发明，之17：(C Class 3) Inventions in which the invention or the element change is applied in the dependent claims and the combination, 17:
一种高性能彩釉玻璃板组合衣柜，其特征在于：其玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其表面或背面有1-10种色彩的彩釉层；所述平板玻璃四周有金属边框包围，使之形成组合板；在金属边框之间有金属联接装置，使之成为一种彩釉玻璃板组合衣柜。The utility model relates to a high-performance color glazed glass plate combined wardrobe, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass a glaze layer of 1-10 colors on the surface or the back surface; the flat glass is surrounded by a metal frame to form a composite panel; and a metal coupling device is formed between the metal frames to make it a glazed glass Board combination wardrobe.
(C类4)从属权利要求与结抅组合应用发明或要素变化的发明，之18：(C Category 4) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 18:
一种高性能彩釉台面玻璃家俱，其特征在于：其台面玻璃，是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，台面的表面或背面有1-10种色彩的彩釉层，其台面下部有支撑装置。A high-performance color glazed countertop glass furniture, characterized in that: the countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass Application: There are 1-10 colors of glaze layer on the surface or back of the table top, and there are support devices on the lower part of the table.
以上4类结构结抅组合应用发明家俱，发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。有析晶速度慢的特征；这能在冷却部和成型部尤其为浮法工艺及各种平板玻璃工艺，形成极为重要的精确的比先有对比技术好得多的工艺控制参数，从而才能精确的有把握的控制大生产。从而制造无任何因析晶而影响透光率的，高质量的本发明防火防爆平板玻璃；The above four types of structural knots are combined with the invention of furniture, and the low crystallization rate of the crystal speed property is found, resulting in the technical effect of high quality and large production. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thereby producing a high quality fire-proof and explosion-proof flat glass of the invention without any crystallization due to crystallization;
上述家俱发明，比较传统的木质、复合板、多层板、纤维板材、玻璃类家俱，具有非显而易见的技术效果： The above furniture invention, compared with traditional wood, composite board, multi-layer board, fiber board, glass type furniture, has non-obvious technical effects:
非显而易见的技术效果[1]：在家具的应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的[更高的软化点]、[更好的高温区热膨胀差值、[更高的强度等高性能]，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的家具防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [1]: In the application place of furniture, the present invention compares the prior comparative techniques [1][2][3][4] in the high temperature zone when it encounters fire or high temperature. Next, due to the [higher softening point] of the flat glass of the present invention, [better high temperature zone thermal expansion difference, [higher strength and other high performance], it can have the shape of holding glass, and can be fireproof and fireproof. The non-obvious technical effect of the heat-insulating wave; the invention has special fire-proof and explosion-proof effect of the furniture, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[2]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。Non-obvious technical effects [2]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass.
也能使各种高性能彩釉玻璃家俱的强度，比现有钙钠强化玻璃强度，在同等厚度及重量时高5倍。It can also make the strength of various high-performance glazed glass furniture 5 times higher than the existing calcium-sodium tempered glass strength at the same thickness and weight.
[a]、如15cm厚的木质材料与6-8mm钙钠玻璃强度相当；本发明仅用1.5-1.8mm的产品就能与15cm厚的木质材料强度相当；比木质产品轻量化2-3[a], such as 15cm thick wood material and 6-8mm calcium soda glass strength; the invention can only use 1.5-1.8mm products can be comparable to 15cm thick wood material; lighter than wood products 2-3
非显而易见的技术效果[3]，各种高性能彩釉玻璃家俱有：a.，外观的高模拟的木纹、石纹的装饰艺术性及合适的产品设计切入点；b.全新的无机型彩釉组合特高强度玻璃的坚固性耐磨的唯一性技术特征；c.坚固又适用又方便、又十分环保，可主导巅覆性改变全球有关木材板、纤维板产品及木材类家俱组合发明终端产品的生产中的高化工污染及粉尘污染的趋势，克服其历史性的难点，造福国际社会；Non-obvious technical effects [3], various high-performance glazed glass homes have: a., the appearance of high-simulated wood grain, stone arteology and appropriate product design entry point; b. brand new inorganic type The unique technical characteristics of the sturdy and wear-resistant high-strength glass of the glaze combination; c. sturdy and suitable, convenient and environmentally friendly, can lead to the change of the global invention of timber board, fiberboard products and wood furniture combination The trend of high chemical pollution and dust pollution in the production of products overcomes its historical difficulties and benefits the international community;
d.对于薄型铝合金框架与安全型彩釉玻璃的组装所有生产过程，都较易于设计高度自动化的组合，组装的标准化生产在线生产；e.尤其包括贴近高人工成本的各个终端市场的组装生产，达到提升组装效率、大幅降成本、又无环保问题、尤其又可解决人员就业的难点。d. For the assembly of thin aluminum alloy frame and safety glazed glass, all production processes are easier to design a highly automated combination, standardized production of assembled production online; e. Especially including assembly production in various end markets close to high labor costs To achieve the difficulty of improving assembly efficiency, significantly reducing costs, and no environmental problems, especially to solve the employment of personnel.
分类为：1、安全型彩釉玻璃类台面家具；2、安全台面透明玻璃类台面家具；3、安全型彩釉玻璃与薄型铝合金框架设计的板式组合家具、及橱柜家具、及橱房台面家具；4、安全型彩釉玻璃与薄型铝合金框架设计的拉门柜家具； Classified as: 1, safe glazed glass countertop furniture; 2, safety countertop transparent glass countertop furniture; 3, safe glazed glass and thin aluminum alloy frame design of panel combination furniture, and cabinet furniture, and cabinet countertops Furniture; 4, safe glazed glass and thin aluminum alloy frame design of the sliding door cabinet furniture;
非显而易见的技术效果[4]：本发明有特别的家具防火防爆效果：而且本发明玻璃经过强化后，可在更长时间抗高温；将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力。Non-obvious technical effect [4]: The invention has special furniture fireproof and explosion-proof effect: and the glass of the invention can be strengthened for a longer period of time after being strengthened; it will greatly enhance the bursting resistance when the glass volume in the high temperature region is rapidly increased. Ability.
[D]新能源2类从属权利要求与结抅组合应用发明或要素变化的发明，组合发明终端产品：[D] New energy category 2 dependent claims and scar tissue combination invention invention or element change invention, combined invention terminal products:
(D类1)从属权利要求与结抅组合应用发明或要素变化的发明，之19：(Class D 1) Invention of the invention or element change in the dependent claims and the combination, 19:
一种高性能光伏太阳能装置，其特征在于：包含太阳能电池，以及玻璃基板或外罩板；玻璃基板或外罩板是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用。A high-performance photovoltaic solar device, comprising: a solar cell, and a glass substrate or a cover plate; the glass substrate or the cover plate is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. Low crystallization rate, application of fireproof and explosion-proof flat glass.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better high temperature zone thermal expansion difference, higher strength and the like, high performance, the shape of the glass can be maintained to prevent fire, fire, and heat waves. Technical effects; The invention has a special fireproof and explosion-proof effect, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：高性能光伏太阳能装置在应用场所，由于其玻璃，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [3]: High-performance photovoltaic solar installations in applications, due to their glass, can also be light and thin at the same intensity, compared with the prior art [1][2][3][4] Light and thin is 3/4; lighter than 1/3 of the existing TFT boron-containing glass; lighter than 1/5 of calcium soda glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
1.所以其支撑框和架体也能大大降重量；尤其适用于承载力较差的木别墅房顶安装，有非显而易见的技术效果。1. Therefore, the support frame and the frame body can also greatly reduce the weight; especially suitable for the roof installation of the wooden villa with poor carrying capacity, which has non-obvious technical effects.
2.因为其玻璃，也可在同等强度时，有薄化性质，所以可以加大阳光透过率，提升太阳能效率，有非显而易见的技术效果。2. Because of its glass, it can also be thinned at the same strength, so it can increase the transmittance of sunlight and improve the efficiency of solar energy. It has non-obvious technical effects.
(D类2)从属权利要求与结抅组合应用发明或要素变化的发明，之20： (Class D 2) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 20:
一种高性能薄膜太阳能装置，该装置包含：薄膜太阳能电池；以及根据上述权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用。A high performance thin film solar device comprising: a thin film solar cell; and a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass according to claim 1 .
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到大大增强在太阳能电池薄膜生产中，本发明在高温区的玻璃体积急速变大时的抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it encounters fire or high temperature, Due to the higher softening point of the flat glass of the present invention, better high temperature zone thermal expansion difference, higher strength and the like, high performance, the shape of the glass can be maintained, which can greatly enhance the production of the solar cell film, the present invention The ability to resist bursting when the glass volume in the high temperature region is rapidly increased has a non-obvious technical effect.
非显而易见的技术效果[3]：高性能薄膜太阳能装置在应用场所，由于其玻璃，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。Non-obvious technical effects [3]: High-performance thin-film solar devices can be used at the same intensity due to their glass, and they are lighter and thinner than the prior art [1][2][3][4] Light and thin is 3/4; lighter than 1/3 of the existing TFT boron-containing glass; lighter than 1/5 of calcium soda glass. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
1.所以其支撑框和架体也能大大降重量；尤其适用于承载力较差的木别墅房顶安装，有非显而易见的技术效果。1. Therefore, the support frame and the frame body can also greatly reduce the weight; especially suitable for the roof installation of the wooden villa with poor carrying capacity, which has non-obvious technical effects.
2.因为其玻璃，也可在同等强度时，有薄化性质，所以可以加大阳光透过率，提升太阳能效率，有非显而易见的技术效果。2. Because of its glass, it can also be thinned at the same strength, so it can increase the transmittance of sunlight and improve the efficiency of solar energy. It has non-obvious technical effects.
非显而易见的技术效果4]：能让高质量生活与环保理念完美融合：[a]如薄膜太阳能技术能与汽车成功嫁接；[b]利用太阳能快装电站可以实现大规模离网供电；[c]薄膜太阳能外壳能为电子设备移动充电；[d]薄膜太阳能可用于船舶和城市建筑，具有非显而易见的技术效果。Non-obvious technical effects 4]: The perfect combination of high-quality life and environmental protection concepts: [a] thin film solar technology can be successfully grafted with cars; [b] large-scale off-grid power supply can be realized by using solar energy rapid power station; Thin-film solar enclosures can be used to mobilely charge electronic devices; [d] Thin-film solar energy can be used in ships and urban buildings with non-obvious technical effects.
(E类9)电子显示器类从属权利要求与结抅组合应用发明或要素变化的发明，类半成品或组合发明终端产品：(E-Class 9) Electronic Display Class Dependent Claims and Scarf Combination Inventions Inventions or elements change inventions, semi-finished products or combined invention terminal products:
(E类1)从属权利要求与结抅组合应用发明或要素变化的发明，之21：(E-Class 1) Inventions in which the invention or element change is applied in a dependent claim and a combination of the following, 21:
一种采用卷对卷的工艺，来在玻璃基板上生产的簿膜晶体管，及由此生产的液晶显示屏，其包括A roll-to-roll process for producing a film transistor on a glass substrate, and a liquid crystal display produced thereby, including
液晶显示屏，该液晶显示屏包括： LCD screen, the LCD screen includes:
数组基板，该数组基板包括基底，及采用卷对卷的工艺在该基底上生产的像素结构，该基底为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；An array substrate comprising a substrate and a pixel structure produced on the substrate by a roll-to-roll process, wherein the substrate has a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution according to claim 1. Crystal speed, fireproof and explosion-proof flat glass;
滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
背光源***。Backlight system.
现有的TFT-LCD液晶显示面板卷对卷的生产工艺，是处于困难的研发期；本发明能解决其多种处于困难的研发期重大难题，使TFT-LCD液晶显示面板卷对卷的生产工艺进入高品质，高成品率，高生产产能，又低成本的大生产阶段[祥見发明目的面板卷对卷的生产工艺部分]。The existing TFT-LCD liquid crystal display panel roll-to-roll production process is in a difficult development period; the present invention can solve a variety of difficult problems in the development period, and make the TFT-LCD liquid crystal display panel roll-to-roll production. The process enters a high-quality, high-yield, high-yield production capacity, and low-cost large-scale production stage [see the production process of the panel roll-to-roll of the invention].
一种采用卷对卷的工艺，来在玻璃基板上生产的的触摸显示屏，其包括：基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其上附有一层导电膜；A touch display screen produced on a glass substrate by a roll-to-roll process, comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution The application of crystal speed, fireproof and explosion-proof flat glass is provided with a conductive film thereon;
液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
数组基板，该数组基板包括基底及在该基底上的像素结构，该基底为玻璃板；An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
背光源***。Backlight system.
(E类2)从属权利要求与结抅组合应用发明或要素变化的发明，之22：(Class E 2) Inventions in which the invention or element changes are applied in the dependent claims and the combination of the elements, 22:
一种液晶屏或触摸屏用的高性能卷对卷的平板玻璃，其包括：A high performance roll-to-roll flat glass for a liquid crystal screen or touch screen, comprising:
该玻璃为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；其特征在于：平板玻璃的厚度为0.05-3.5mm，其能收卷的内卷筒直径为20-80cm，其长度在200cm-2000cm或2001-10000cm。The glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass according to claim 1; wherein the thickness of the flat glass is 0.05-3.5 mm, and the glass can be collected. The inner roll of the roll has a diameter of 20-80 cm and a length of 200 cm-2000 cm or 2001-10000 cm.
(E类3)从属权利要求与结抅组合应用发明或要素变化的发明，之23：(Class E 3) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 23:
一种高性能低温多晶硅显示屏，其特征在于包括： A high performance low temperature polysilicon display screen comprising:
液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
低温多晶硅数组基板，该数组基板包括基底及在该基底上的采用低温多晶硅工艺生产的像素结构，该基底玻璃为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；a low temperature polysilicon array substrate comprising a substrate and a pixel structure produced on the substrate by a low temperature polysilicon process, wherein the base glass has a high softening point and a low difference in thermal expansion coefficient of a high temperature region according to claim 1. Crystallization speed, fireproof and explosion-proof flat glass;
滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
背光源***。Backlight system.
本发明能为液晶显示产品，解决低温多晶硅技术新工艺的难题[祥見发明目的低温多晶硅技术新工艺部分]。The invention can solve the problem of the new process of the low-temperature polysilicon technology for the liquid crystal display product [see the new process part of the low-temperature polysilicon technology for the purpose of the invention].
(E类4)从属权利要求与结抅组合应用发明或要素变化的发明，之24：(E-Class 4) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 24:
一种高性能低温多晶硅显示屏用途的平板玻璃，其特征在于包括：A flat glass for high performance low temperature polysilicon display, characterized by comprising:
该基底玻璃为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；The base glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass;
(E类5)从属权利要求与结抅组合应用发明或要素变化的发明，之25：(E-Class 5) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 25:
一种高性能耐磨又高强度的液晶显示屏，其包括：A high performance wear resistant and high strength liquid crystal display comprising:
数组基板，该数组基板包括基底及在该基底上的像素结构，该基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；An array substrate comprising a substrate and a pixel structure on the substrate, wherein the substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof explosion-proof plate according to claim 1. Application of glass;
滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
背光源***。Backlight system.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在区时，尤其比较本人的先有对比技术[1][2][3][4]：在TFT薄膜晶体管的工艺中的高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高 性能，可具有保持玻璃的形状；尤其更好的高温区热膨胀差值，将大大增强相素位与分光片的彩色对位精度，比先有对比技术2可产生更高的2-5倍的分辩率显示屏的非显而易见的技术效果；本发明因其出色的总间距偏差性能，从而能实现精密的部件定位和高效的面板生产；Non-obvious technical effects [2]: In the application place, the present invention is especially useful in comparison with the prior art [1][2][3][4]: high temperature region in the process of TFT thin film transistor In the state, due to the higher softening point of the flat glass of the invention, better thermal expansion difference in the high temperature region, higher strength, etc. Performance, can have the shape of the glass; especially the difference in thermal expansion in the high temperature zone, which will greatly enhance the color alignment accuracy of the phase element and the beam splitter, which can produce 2-5 times higher than the prior art 2 Non-obvious technical effects of the resolution display; the present invention enables precise component positioning and efficient panel production due to its excellent overall pitch deviation performance;
能够更好地承受最先进高清显示器生产中所采用的严酷的高温工艺；能在高温工艺条件下，还能扩大了工艺控制平台的温度范围，不但尺寸稳定性好，而且还会在保障质量的同时提高产量。It can better withstand the harsh high temperature process used in the production of the most advanced HD display; it can expand the temperature range of the process control platform under high temperature process conditions, not only the dimensional stability, but also the quality assurance. At the same time increase production.
(E类6)从属权利要求与结抅组合应用发明或要素变化的发明，之26：(E-Class 6) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 26:
一种高性能耐磨又高强度的触摸显示屏，其包括：基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其上附有一层导电膜；A high-performance wear-resistant and high-strength touch display screen comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass Application with a conductive film attached thereto;
液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
数组基板，该数组基板包括基底及在该基底上的像素结构，该基底为玻璃板；An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
背光源***。Backlight system.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：比如在采用省去盖板玻璃层，只有二层TFT玻璃的上层玻璃进行复合触模屏工艺时，可把本发明无碱玻璃专利范围内的高铝玻璃含量上升为25-39％；其一是，可省去盖板玻璃及加工，从而降成本，又减薄手机、平板、笔电产品；其二是，不化学强化也十分耐磨，也有很高的强度和抗摔性能；Non-obvious technical effect [2]: For example, when the upper glass of the two-layer TFT glass is subjected to the composite touch screen process by using the cover glass layer, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained. The rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;
非显而易见的技术效果[3]：在应用场所，本发明在区时，尤其比较本人的先有对比技术[1][2][3][4]：在薄膜晶体管或者触摸导电膜的工艺中的高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的 强度等高性能，可具有保持玻璃的形状；尤其更好的高温区热膨胀差值，将大大增强相素位与分光片的彩色对位精度，比先有对比技术2，可产生更高的2-5倍的分辩率显示屏的非显而易见的技术效果；Non-obvious technical effects [3]: In the application place, the present invention is especially useful in comparison with the prior art [1][2][3][4]: in the process of thin film transistor or touch conductive film In the high temperature zone state, due to the higher softening point of the flat glass of the invention, the better thermal expansion difference in the high temperature zone, and higher High performance such as strength, can maintain the shape of the glass; especially the difference in thermal expansion of the high temperature region, which will greatly enhance the color alignment accuracy of the phase element and the beam splitter, which can produce a higher 2 than the prior art 2 -5 times the resolution of the display's non-obvious technical effects;
也能够更好地承受最先进高清显示器生产中所采用的严酷的高温工艺；能在高温工艺条件下，还能扩大了工艺控制平台的温度范围，不但尺寸稳定性好，而且还会在保障质量的同时提高产量。It can also better withstand the harsh high temperature process used in the production of the most advanced HD display; it can also expand the temperature range of the process control platform under high temperature process conditions, not only the dimensional stability, but also the quality assurance. At the same time increase production.
(E类7)从属权利要求与结抅组合应用发明或要素变化的发明，之27：(E-Class 7) Invention in which a dependent claim and a scar combination are applied to an invention or a change in the element, 27:
一种高性能耐磨又高强度的触摸显示屏手机、或触摸显示屏平板计算机、或触摸显示屏笔记本电脑、或触摸显示屏电视、其包括：A high performance wear resistant and high intensity touch display mobile phone, or a touch display tablet computer, or a touch display notebook computer, or a touch display television, comprising:
基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其上附有一层导电膜；The substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion proof flat glass according to claim 1, and a conductive film is attached thereon;
数组基板，该数组基板包括基底及在该基底上的像素结构，该基底为玻璃板；An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
背光源***；Backlight system;
显示屏包边装置及支撑装置。Display edge device and support device.
非显而易见的技术效果[1]：比如在采用省去盖板玻璃层，只有二层TFT玻璃的上层玻璃进行复合触模屏工艺时，可把本发明无碱玻璃专利范围内的高铝玻璃含量上升为25-39％；其一是，可省去盖板玻璃及加工，从而降成本，又减薄手机、平板、笔电产品；其二是，不化学强化也十分耐磨，也有很高的强度和抗摔性能；Non-obvious technical effect [1]: For example, when the upper glass of the two-layer TFT glass is subjected to the composite touch screen process by using the cover glass layer, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained. The rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;
非显而易见的技术效果[2]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。有析晶速度慢的特征；这能在冷却部和成型部尤其为浮法工艺及各种平板玻璃工艺，形成极为重要的精确的比先有对比技术好得多的工艺控制参数，从而才能精确的有把握的控制大生产。从而制造无任何因析晶而影响透光率的，高质量的本发明防火防爆平板玻璃； Non-obvious technical effects [2]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects. It has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, so as to be accurate. Able to control large production. Thereby producing a high quality fire-proof and explosion-proof flat glass of the invention without any crystallization due to crystallization;
非显而易见的技术效果[3]：在应用场所，本发明在区时，尤其比较本人的先有对比技术[1][2][3][4]：在薄膜晶体管或者触摸导电膜的工艺中的高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状；尤其更好的高温区热膨胀差值，将大大增强相素位与分光片的彩色对位精度，比先有对比技术2可产生更高的2-5倍的分辩率显示屏的非显而易见的技术效果；也能够更好地承受最先进高清显示器生产中所采用的严酷的高温工艺；能在高温工艺条件下，还能扩大了工艺控制平台的温度范围，不但尺寸稳定性好，而且还会在保障质量的同时提高产量。Non-obvious technical effects [3]: In the application place, the present invention is especially useful in comparison with the prior art [1][2][3][4]: in the process of thin film transistor or touch conductive film In the high temperature zone state, due to the higher softening point of the flat glass of the invention, better high temperature zone thermal expansion difference, higher strength and the like, the shape of the glass can be maintained; especially the better thermal expansion in the high temperature zone The value will greatly enhance the color alignment accuracy of the phase element and the beam splitter, which can produce a higher 2-5 times resolution of the non-obvious technical effect of the display than the prior art 2; it can also withstand better The harsh high-temperature process used in the production of the most advanced high-definition display; under the high-temperature process conditions, the temperature range of the process control platform can be expanded, not only the dimensional stability is good, but also the production is improved while ensuring the quality.
非显而易见的技术效果[4]：而本发明超高铝耐划伤强韧性玻璃材料中，由于氧化铝含量，能达到25-39％，又由于氧化铝化学键是现有技术浮法或下拉法或谥流法等平板玻璃材料中抗拉裂机械强度最高的连续联结的化学键，所以本发明超高铝耐划伤强韧性玻璃材料的耐划伤强韧性特征会好得多，作如下说明；Non-obvious technical effect [4]: In the ultra-high aluminum scratch-resistant and tough glass material of the present invention, the alumina content can reach 25-39%, and the alumina chemical bond is a prior art float method or a down-draw method. Or the continuous bonding chemical bond with the highest tensile strength in the flat glass material such as the turbulence method, so the scratch-resistant strength and toughness characteristics of the ultra-high aluminum scratch-resistant and tough glass material of the present invention are much better, as explained below;
按照玻璃组成不规则网络学说的观点，根据玻璃组成氧化物(纳米级尺寸化学物理性质变化)在玻璃结构中的作用，通常可以分为三类：网络形成体、网络外体和中间体。所以，要从玻璃产品的化学物理结抅基理上，从不规则网络学说的观点，了解耐划伤强韧性特征：According to the theory of irregular network of glass composition, the role of glass composition oxides (changes in chemical and physical properties of nanoscale size) in glass structures can generally be divided into three categories: network formers, network exosomes and intermediates. Therefore, it is necessary to understand the characteristics of scratch resistance and toughness from the point of view of the chemical physics of glass products and from the point of view of irregular network theory:
在现有浮法或下拉法或谥流法等平板玻璃材料中，玻璃网络结构体中氧化铝形成的四面体的化学键有最高的抗拉裂机械强度，所以氧化铝形成的四面体与氧化铝化学键连续联结的SiO4四面体组成连续的网络结构，是现有技术浮法或下拉法或谥流法等玻璃材料中抗拉裂机械强度最高的网络结构(抗拉裂机械强度不是硬度)，所以氧化铝形成的四面体与SiO4四面体组成连续的网络结构，是浮法或下拉法或谥流法等平板玻璃材料中，最不易碎、最不易裂、最不易刮伤、最耐磨的纳米级尺寸化学物理性质材料；在显示器玻璃中，比较抗划伤的韧性，就是比较用树脂类笔尖在玻璃表面反复刮划后玻璃网络结构的破坏程度；In the existing flat glass materials such as float or down-draw or turbulent flow, the chemical bond of the tetrahedron formed by alumina in the glass network structure has the highest tensile strength, so the tetrahedron and alumina formed by alumina The continuous bonding of SiO4 tetrahedrons with chemical bonds constitutes a continuous network structure, which is the highest tensile strength of the network structure in the glass materials such as the float method or the down-draw method or the turbulence method (the tensile strength is not the hardness), so The tetrahedron formed by alumina and the SiO4 tetrahedron form a continuous network structure, which is the most fragile, least crackable, most scratch-resistant, and most wear-resistant nanometer in flat glass materials such as float or down-draw or turbulent flow. Grade size chemical and physical properties materials; in the display glass, comparing the scratch resistance to the toughness is to compare the degree of damage of the glass network structure after repeatedly scraping the surface of the glass with a resin pen tip;
首先要了解硬度指标只是一次的刮划测试；而耐磨若干次的刮划测试，而手机盖板玻璃是要适应若干次的金属硬物刮划； First of all, we must understand that the hardness index is only one scratch test; while the scratch test is worn several times, and the cover glass of the mobile phone is adapted to several times of metal hard scratching;
为了理解抗拉裂机械强度即韧性耐磨度的纳米级尺寸化学物理性质基理，再举例如下：正如有机高分子树脂材料的韧性耐磨度的基理是，不同的有机高分子树脂材料的[不同的纳米级尺寸]分子连接的化学键的抗拉裂机械强度越高，韧性耐磨度就越好；用作运动鞋底的各种改性聚脂材料、聚四氟乙稀材料、改性聚甲醛材料等，都是分子连接的化学键抗拉裂机械强度高的材料，所以耐磨度就好；而如聚氯乙稀树脂材料虽硬度好，但分子连接的化学键抗拉裂机械强度很低，所以确易碎、易裂、易刮伤、不耐磨，所以不适于作运动鞋底。In order to understand the nano-scale chemical and physical properties of tensile strength, that is, toughness and wear resistance, another example is as follows: just as the toughness of organic polymer resin materials is based on the principle of different organic polymer resin materials. [Different nanoscale size] The higher the tensile strength of the chemical bond of the molecular bond, the better the toughness and wear resistance; the various modified polyester materials used for sports soles, polytetrafluoroethylene materials, modification Polyacetal materials, etc., are all chemically bonded to the molecular bond, and the mechanical strength is high, so the wear resistance is good; while the polyvinyl chloride resin material has good hardness, the chemical bond resistance of the molecular connection is very strong. Low, so it is fragile, easy to crack, easy to scratch, not wearable, so it is not suitable for sports soles.
而氧化铝形成的四面体与SiO4四面体组成连续的网络结构的氧化铝化学键，有现有技术浮法或下拉法或谥流法等平板玻璃材料中最高的抗拉裂机械强度，又由于本发明特高铝耐刮划中低碱玻璃材料中，占25％的氧化铝四面体又加上由氧化铝化学键连续联结的25％SiO4四面体组成连续的网络结构。The tetrahedral formed by alumina and the SiO4 tetrahedron form a continuous network structure of alumina chemical bonds, and have the highest tensile tensile mechanical strength of flat glass materials such as the float method or the down-draw method or the turbulent flow method, and In the invention of the ultra-high aluminum scratch-resistant low alkali glass material, 25% of the alumina tetrahedron is combined with a 25% SiO4 tetrahedron continuously bonded by the alumina chemical bond to form a continuous network structure.
而从三维空间看，每单位长度上是50个结构；平面宽度上又是50个结构；深度方向又是50个结构。所以每单位三维空间有5 0X 5 0X 50＝本发明每三维空间单位有75000个由氧化铝化学键连续联结SiO4四面体组成的网络结构点。而有技术中铝玻璃只有8％的氧化铝四面体又加上由氧化铝化学键连续联结的8％SiO4四面体组成连续的网络结构。而从三维空间看，每单位长度上是16个结构；平面宽度上又是16个结构；深度方向又是16个结构。所以每单位三维空间有16 X 16 X 16＝中铝玻璃只4096有个由氧化铝化学键连续联结SiO4四面体组成的网络结构点；所以本发明每三维空间单位的75000个比中铝玻璃只4096个由氧化铝化学键连续联结SiO4四面体组成的网络结构点，多了18倍。From the three-dimensional space, there are 50 structures per unit length; 50 structures in the plane width; and 50 structures in the depth direction. Therefore, there are 50X 5 0X 50 per unit three-dimensional space. According to the invention, there are 75,000 network structure points consisting of SiO4 tetrahedrons continuously bonded by alumina chemical bonds per three-dimensional space unit. In the prior art, aluminum glass has only 8% alumina tetrahedron and 8% SiO4 tetrahedron continuously bonded by alumina chemical bonds to form a continuous network structure. From the perspective of three-dimensional space, there are 16 structures per unit length; 16 structures in the plane width; and 16 structures in the depth direction. Therefore, there are 16 X 16 X 16 in the three-dimensional space per unit. Only 4096 medium-aluminum glass has a network structure point consisting of SiO4 tetrahedrons continuously bonded by alumina chemical bonds; therefore, the invention has 75,000 per cubic space units of only 4096 aluminum glass. The network structure consisting of SiO4 tetrahedrons continuously bonded by alumina chemical bonds is 18 times more.
可见，本发明特高铝耐刮划中低碱玻璃材料，比较现有低铝中低碱玻璃材料(如GORILLA耐刮划玻璃)这种强韧的连续的网络结构的三维空间密度是其18倍；所以从基理上判断，本发明特高铝耐刮划中低碱玻璃材料，有最不易碎、最不易裂、最不易刮伤、最耐磨、最耐划伤、强韧性特征，会好于现有技术低铝中低碱玻璃材料(如中铝玻璃耐刮划玻璃)数倍。(以后会有准确的耐磨测试比较数据)It can be seen that the ultra-high aluminum scratch-resistant low-alkali glass material of the present invention compares the three-dimensional density of the tough continuous network structure of the existing low-aluminum medium-low alkali glass material (such as GORILLA scratch-resistant glass). Therefore, judging from the basics, the ultra-high aluminum scratch-resistant low-alkali glass material of the present invention has the most non-fragile, most non-cracking, most scratch-resistant, most wear-resistant, most scratch-resistant, strong toughness characteristics. It will be better than the existing low-aluminum medium-low alkali glass materials (such as medium-aluminum glass scratch-resistant glass) several times. (There will be accurate wear test comparison data in the future)
尤其是，网络结构中氧化铝和SiO4形成的四面体的尺寸小于1纳米，而肉眼仅能在特别的光线及角度下，看到50微米以上(即为0、05毫米＝50000纳米) In particular, the size of the tetrahedron formed by alumina and SiO4 in the network structure is less than 1 nm, and the naked eye can only see 50 micrometers or more under special light and angle (ie, 0,05 mm = 50000 nm).
的划痕；所以比50微米细小50000倍的氧化铝形成的四面体与SiO4四面体组成连续的网络结构的断裂(纳米级尺寸化学物理性质变化)，不仅肉眼看不到，一般的显微镜和30000倍以下的电子显微镜都看不到。Scratches; therefore, the tetrahedral and SiO4 tetrahedrons formed by a finer 50,000 times smaller than 50 micrometers constitute a continuous network structure of the fracture (nano-scale chemical and physical properties change), not only invisible to the naked eye, general microscope and 30000 The electron microscope below the magnification is not visible.
所以，比较之下：要刮划破坏本发明特高铝耐刮划中低碱玻璃材料中占整个玻璃体积50％以上的高抗拉网络结构的网络结构，要使超过50000层厚度的四方八面的三维空间的网络结构其全部断裂，使其用肉眼看到连续的网络结构全部断裂(纳米级尺寸化学物理性质的破坏变化)，才会出现肉眼可见的划痕，具有非显而易见的技术效果；Therefore, in comparison, it is necessary to scratch the network structure of the high tensile network structure which destroys the ultra-alkali glass material of the present invention and accounts for more than 50% of the entire glass volume in the ultra-high aluminum scratch-resistant low-alkali glass material, so that the square of more than 50,000 layers is required. The network structure of the three-dimensional space of the surface is completely broken, so that it can be seen with the naked eye that all the continuous network structures are broken (destructive changes of the chemical and physical properties of the nano-scale size), and visible scratches can be seen by the naked eye, and the non-obvious technical effect is obtained. ;
但先有对比技术中铝耐刮划玻璃，高抗拉网络结构仅有占整个玻璃体积16--20％，防刮划防护水平差很远，较易于出现肉眼可见的划痕断裂，However, there is a contrast-resistant aluminum scratch-resistant glass. The high tensile network structure only accounts for 16-20% of the total glass volume. The scratch-resistant protection level is far away, and it is prone to visible scratches and fractures.
平板玻璃垂悬度性质特征，则是由抗折强度决定的；抗折强度越高，同等重量、同等厚度的平板玻璃的向下垂悬度就越小；抗折强度越高，就越有利于在TFT面板的工艺流程中，尤真在大尺寸面的工艺流程中减少破损率，具有非显而易见的技术效果。The characteristics of the sag of the flat glass are determined by the flexural strength; the higher the flexural strength, the smaller the downward sag of the same weight and the same thickness of the flat glass; the higher the flexural strength, the better it is. In the process flow of the TFT panel, the damage rate is reduced in the process of the large-sized surface, and the non-obvious technical effect is obtained.
(E类8)从属权利要求与结抅组合应用发明或要素变化的发明，之28：(E-Class 8) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 28:
一种先印刷再烧结薄膜晶体管工艺所生产的液晶显示屏，其包括A liquid crystal display screen produced by a process of first printing and re-sintering a thin film transistor, which comprises
液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
数组基板，该数组基板包括玻璃基底，及采用先在玻璃基底上印刷薄膜晶体管原料，再该玻璃基底上烧结成薄膜晶体管的生产工艺所产生的像素结构；该玻璃基底为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；An array substrate comprising a glass substrate, and a pixel structure produced by a process for printing a thin film transistor raw material on a glass substrate and then sintering the thin film transistor on the glass substrate; the glass substrate is the one according to claim 1. High softening point, low difference of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass;
滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
背光源***。Backlight system.
所述的一种先印刷薄膜晶体管原料，再烧结薄膜晶体管的工艺，是最新的技术研发方向。 The process of first printing a thin film transistor raw material and then sintering the thin film transistor is the latest technology research and development direction.
代表着电子液晶显示玻璃技术发展趋势，采用先在玻璃基底上印刷薄膜晶体管原料，再该玻璃基底上烧结成薄膜晶体管的生产工艺所产生的像素结构，这种印刷烧结技术中，人们一直希望解决而又没获得成功的难题。Representing the development trend of electronic liquid crystal display glass technology, the pixel structure produced by the process of printing thin film transistor raw materials on a glass substrate and then sintering the thin film transistor on the glass substrate, in the printing and sintering technology, people have been hoping to solve And there is no problem with success.
非显而易见的技术效果[1]：本发明髙性能电子玻璃，在更严酷的高温区650℃-700℃时热膨胀率的差值在百万分之0.1-0.99以内，在更严酷的高温区700℃-740℃时热膨胀率的差值在百万分之1-5.9或6-8以内。这加大了高温工艺可控范围；因一切先有玻璃高温区热膨胀率性质差，不能使烧结温度上升70℃；所以本发明能采用先在卷对卷的玻璃基底上印刷薄膜晶体管原料，再该玻璃基底上烧结成薄膜晶体管的生产工艺所产生的像素结构；此工艺比采用高温磁控溅射再印刷蚀刻薄膜晶体管的生产工艺，效率很髙很多，成本又低，良品率又高，具有非显而易见的技术效果；而传统TFT液晶玻璃的薄膜晶体管面板加工，采用高温磁控溅射再印刷蚀刻薄膜晶体管的生产工艺，生产效率低，又成本较贵，良品率又不高。Non-obvious technical effect [1]: The 髙 performance electronic glass of the present invention has a difference in thermal expansion rate in the more severe high temperature region of 650 ° C to 700 ° C within 0.1-0.99 parts per million, in a more severe high temperature area 700 The difference in thermal expansion rate at °C-740 °C is within 1-5.9 or 6-8 parts per million. This increases the controllable range of the high temperature process; because of the poor thermal expansion rate of all the high temperature regions of the glass, the sintering temperature cannot be increased by 70 ° C; therefore, the present invention can use the film transistor raw material printed on the roll-to-roll glass substrate first. The pixel structure produced by the process of sintering the thin film transistor on the glass substrate; the process is much more efficient, lower in cost, and higher in yield than the production process of etching the thin film transistor by high temperature magnetron sputtering. Non-obvious technical effects; while the thin film transistor panel processing of the conventional TFT liquid crystal glass uses the high-temperature magnetron sputtering to reprint the etched thin film transistor production process, the production efficiency is low, the cost is relatively high, and the yield rate is not high.
非显而易见的技术效果[2]：本发明可以通过提高对薄膜晶体管的烧结温度，来达到既克服了现有技术的印刷技术的薄膜晶体管，因玻璃高温区热膨胀率性质差，不能上升烧结温度，而造成薄膜晶体管烧结不充分，而造成精度差又品质差又成品率低的难题；现有技术也存在太薄的玻璃热膨胀后大的变形而精度差又品质差又成品率低的难题；Non-obvious technical effect [2]: The present invention can achieve a thin film transistor that overcomes the prior art printing technology by increasing the sintering temperature of the thin film transistor, because the thermal expansion coefficient of the high temperature region of the glass is poor, and the sintering temperature cannot be raised. The film transistor is not sufficiently sintered, resulting in poor precision, poor quality and low yield; the prior art also has a problem that the glass is too thin after thermal expansion, the precision is poor, the quality is poor, and the yield is low;
(E类9)从属权利要求与结抅组合应用发明或要素变化的发明，之29：(E-Class 9) Inventions in which the invention or element change is applied in the dependent claims and the combination, 29:
一种高性能曲面液晶显示屏，其包括：A high performance curved liquid crystal display comprising:
基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；The substrate glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;
数组基板，该数组基板包括基底及在该基底上的像素结构，该基底为玻璃板；An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
背光源***； Backlight system;
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在区时，尤其比较本人的先有对比技术[1][2][3][4]：在薄膜晶体管或者触摸导电膜的工艺中的高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状；尤其更好的高温区热膨胀差值，将大大增强相素位与分光片的彩色对位精度，比先有对比技术2可产生更高的2-5倍的分辩率显示屏的非显而易见的技术效果；Non-obvious technical effects [2]: In the application place, the invention is in the zone, especially comparing the prior art of comparison [1][2][3][4]: in the process of thin film transistor or touch conductive film In the high temperature zone state, due to the higher softening point of the flat glass of the invention, better high temperature zone thermal expansion difference, higher strength and the like, the shape of the glass can be maintained; especially the better thermal expansion in the high temperature zone The value will greatly enhance the color registration accuracy of the phase element and the beam splitter, which can produce a higher 2-5 times resolution of the non-obvious technical effect of the display than the prior art 2;
还能够更好地承受最先进高清显示器生产中所采用的严酷的高温工艺；能在高温工艺条件下，还能扩大了工艺控制平台的温度范围，不但尺寸稳定性好，而且还会在保障质量的同时提高产量。It can also better withstand the harsh high temperature process used in the production of the most advanced HD display; it can also expand the temperature range of the process control platform under high temperature process conditions, not only the dimensional stability, but also the quality assurance. At the same time increase production.
非显而易见的技术效果[3]：现有LED已可制作一定弧度的曲面手机和电视，但由于基板玻璃太厚达0，5-0，7mm，强度又差，所以不能生产出本发明的0，1-0，3mm的高强设基板玻璃；本新材料发明，由于本发明可生产最新的超薄的高抗拉强度特征，具有优良的杨氏弹性模量(前已有材料说明)，可提供其它TFT电子玻璃不可能作到的0，1-0，3mm的高强设基板玻璃材料性质，能制作出有更大曲面度和最不会破裂、髙成品率的、更合乎人体工程学的更高弯曲弧度的曲面手机和电视。所以本发明更是能支撑手机、平板计算机、笔记本电脑、液晶电视等曲面触摸屏产业发展方向，具有非显而易见的技术效果。Non-obvious technical effects [3]: Existing LEDs can make curved mobile phones and TVs with a certain degree of curvature, but since the substrate glass is too thick to 0,5-0,7mm, the strength is poor, so the 0 of the present invention cannot be produced. , 1-0, 3mm high-strength substrate glass; this new material invention, because the invention can produce the latest ultra-thin high tensile strength characteristics, has excellent Young's modulus of elasticity (previous material description), Provides high-strength substrate glass material properties of 0,1-0,3mm that are impossible for other TFT electronic glasses. It can produce more curved surfaces and the most rupture, 髙 髙 yield, more ergonomic Curved phones and TVs with a higher curved curvature. Therefore, the invention can support the development direction of the curved touch screen industry such as mobile phones, tablet computers, notebook computers, and liquid crystal televisions, and has non-obvious technical effects.
非显而易见的技术效果[4]：比如在采用省去盖板玻璃层，只有二层TFT玻璃的上层玻璃进行复合触模屏工艺时，可把本发明无碱玻璃专利范围内的高铝玻璃含量上升为25-39％；其一是，可省去盖板玻璃及加工，从而降成本，又减薄手机、平板、笔电产品；其二是，不化学强化也十分耐磨，也有很高的强度和抗摔性能；Non-obvious technical effect [4]: For example, in the case of adopting a cover glass layer, only the upper glass of the two-layer TFT glass is subjected to the composite touch screen process, the high aluminum glass content in the patent range of the alkali-free glass of the present invention can be obtained. The rise is 25-39%; the first is that the cover glass and processing can be omitted, thereby reducing the cost and thinning the mobile phone, tablet, and notebook products; the second is that it is not very resistant to chemical strengthening and is also very high. Strength and drop resistance;
非显而易见的技术效果[5]：曲面液晶显示屏，更合乎人体眼球生理学原理，使人能更清楚的观看屏幕。Non-obvious technical effects [5]: The curved liquid crystal display is more in line with the physiological principles of the human eye, enabling people to see the screen more clearly.
(E类10)从属权利要求与结抅组合应用发明或要素变化的发明，之30： (E-Class 10) Inventions in which the invention or element change is applied in the dependent claims and the combination, 30:
一种高性能OLED有机发光显示屏，其特征在于包括：权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；A high-performance OLED organic light-emitting display screen comprising: a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;
以及有机电激发光器件。And organic electroluminescent devices.
非显而易见的技术效果[1]：本发明析晶温度区的上线范围并在指定的仪器中的自然降温的条件下，在45分钟-2小时后，才会在玻璃析晶温度区的上线范围，逐步降温的条件下，的条件下开始析晶，有析晶速度慢的特征；这能在冷却部和成型部尤其为浮法工艺及各种平板玻璃工艺，形成极为重要的精确的比先有对比技术好得多的工艺控制参数，从而才能精确的有把握的控制大生产。从而制造无任何因析晶而影响透光率的，高质量的本发明超高强度、更薄的电子平板玻璃；Non-obvious technical effect [1]: The upper line range of the crystallization temperature zone of the present invention and the natural temperature drop condition of the specified instrument, after 45 minutes - 2 hours, will be in the upper line range of the glass crystallization temperature zone. Under the conditions of gradual cooling, crystallization is started under the conditions, and the crystallization rate is slow; this can form extremely important precision in the cooling part and the forming part, especially for the float process and various flat glass processes. There are much better process control parameters for contrast technology, so that you can control large production with precise and precise control. Thereby producing a high quality ultra-high strength, thinner electronic flat glass of the invention without any crystallization due to crystallization;
OLED有机发光显示屏具有更轻薄、不需要背光源、更节电、更好的色彩效果、更快的回应等优点。The OLED organic light-emitting display has the advantages of being lighter and thinner, requiring no backlight, more power saving, better color effect, and faster response.
非显而易见的技术效果[1]：Non-obvious technical effects [1]:
先有对比技术2如果作电子玻璃卷对卷工艺最大的瓶颈：1、尤其目前市场要求终端显示屏产品越来越轻薄；2先技术2抗拉强度比本发明低的难点，导致电子玻璃基材在卷对卷的加工中，会导致更薄的玻璃更为容易变形或破裂，也影响对位的精准度，也影响电路线宽与线距的分辨率。First, there is a comparison bottleneck 2 if it is the biggest bottleneck of the electronic glass roll-to-roll process: 1. In particular, the current market requires terminal display products to become more and more light and thin; 2 prior art 2 tensile strength is lower than the difficulty of the present invention, resulting in an electronic glass base In the roll-to-roll process, thinner glass is more likely to be deformed or broken, which also affects the accuracy of alignment and affects the resolution of circuit line width and line spacing.
非显而易见的技术效果[2]：Non-obvious technical effects [2]:
本发明防火防爆平板电子玻璃的由于氧化铝含量能达25-39％，抗析强度能达150-240Mpa，所以本发明，有对抗太薄的玻璃的变形和破裂的强度能力。The fireproof and explosion-proof flat electronic glass of the invention has an alumina content of 25-39% and a detonation strength of 150-240 MPa, so the present invention has the strength ability to resist deformation and cracking of too thin glass.
A、可来对抗收卷和放卷运动过程中超薄厚度的卷对卷的电子玻璃变形或破裂。A. It can be used to resist the deformation or rupture of the ultra-thin thickness of the roll-to-roll electronic glass during the winding and unwinding movements.
B、在用于OLED的常规平面玻璃基板时，也有比先有对比技术2和一切先有对比技术，更好的对抗太薄的玻璃的变形和破裂的强度能力：B. In conventional flat glass substrates for OLEDs, there are also better strengths against deformation and cracking of too thin glass than prior art 2 and all prior art comparisons:
(E类11)从属权利要求与结抅组合应用发明或要素变化的发明，之31：(E Class 11) Inventions in which the invention or the element change is applied in the dependent claims and the combination, 31:
一种高性能耐磨又高强度的手机、或平板计算机或笔记本电脑或台式计算机的透明玻璃后背外壳，其特征在于：其透明玻璃后背外壳，是采用权利要求1 所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用。A high-performance wear-resistant and high-strength mobile phone, or a transparent glass back casing of a tablet computer or a notebook computer or a desktop computer, characterized in that the transparent glass back casing is according to claim 1. The high softening point, the low difference of the thermal expansion coefficient of the high temperature zone, the low crystallization rate, and the application of the fireproof and explosion-proof flat glass.
非显而易见的技术效果：一种耐磨又高强度的手机、或平板计算机或笔记本电脑或台式计算机的透明玻璃后背外壳；能与手机、或平板计算机的透明显示屏组合，形成透明又耐磨、又耐摔的高强度手机、或平板计算机的产品。Non-obvious technical effects: a wearable and high-strength mobile phone, or a transparent glass back casing of a tablet or laptop or desktop computer; can be combined with a transparent display of a mobile phone or a tablet computer to form a transparent and wear-resistant And high-strength mobile phones that are resistant to falling, or products of tablet computers.
[F]耐用终端工业产品类结抅组合应用发明：[F] Durable terminal industrial product type combination application invention:
(F类1)从属权利要求与结抅组合应用发明或要素变化的发明，之32：(Class F) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 32:
一种高性能防弹防爆汽车，其包含：A high performance bulletproof and explosion proof vehicle comprising:
1-10个车窗的1-3层玻璃，防弹玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；其各片玻璃板之由树脂片粘合；1-3 layers of glass of 1-10 windows, the bulletproof glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass; Each piece of glass plate is bonded by a resin sheet;
汽车的四周的金属板或金属架内，有防弹结构；There is a bulletproof structure in the metal plate or metal frame around the car;
以及动力装置；仪表盘；方向控制器；汽车外壳；汽车底盘；汽车刹车装置；汽车轮胎。And power unit; instrument panel; direction controller; car shell; car chassis; car brakes;
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. Technical effect.
非显而易见的技术效果[3]：本发明有特别的防火防爆效果：如采用加厚的钠钙玻璃的所谓铯钾防火玻璃，可一定时间抗1000℃高温；而且本发明玻璃经过化学强化后，可在更长时间抗1000℃高温；将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力。Non-obvious technical effect [3]: The invention has special fireproof and explosion-proof effects: if the so-called strontium-potassium fire-resistant glass with thick soda-lime glass is used, it can resist 1000 ° C high temperature for a certain period of time; and after the glass of the invention is chemically strengthened, It can withstand high temperatures of 1000 ° C for a longer period of time; it will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased.
非显而易见的技术效果[4]：能有利于在碰到车外着火时，因车玻璃防火而有利于人或车逃离着火区，而增加车内人员安全，并延长驾车逃离的时间机会；Non-obvious technical effects [4]: It can help to prevent people or cars from escaping from the fire zone when the vehicle is hit by fire. It increases the safety of the people inside the vehicle and prolongs the chance of driving away.
具有非显而易见的技术效果。 Has a non-obvious technical effect.
非显而易见的技术效果[5]：在本用途领域中，抗折强度；可实质性的比先有对比技术[1][2][3][4]改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。Non-obvious technical effects [5]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
非显而易见的技术效果[6]：由于本发明可以制造特髙强度的由3层玻璃形成的5-6mm厚的防弹、防爆玻璃，防弹性能也可优于常规的由3层玻璃组成的25mm厚的F79级全玻防弹玻璃(防***的钢芯弹)，本发明还要轻薄4-5倍。由于本发明可以制造特髙强度由3层玻璃组成的仅8-9mm厚全玻防弹玻璃，其防弹性能也可优于常规的由3层玻璃组成的40mm厚F56级(防56/AK47冲锋枪或81步枪的钢芯弹)全玻防弹玻璃；还要轻薄4-5倍，这是其它现有一切现有玻璃不可能作到的新材料性质。Non-obvious technical effect [6]: Since the present invention can manufacture a 5-6 mm thick bulletproof and explosion-proof glass made of 3-layer glass with special strength, the ballistic performance can also be superior to the conventional 25 mm thick composed of 3 layers of glass. The F79 grade full glass bulletproof glass (steel core bullet for anti-pistol), the invention is also light and thin 4-5 times. Since the present invention can manufacture a full-glass bulletproof glass of only 8-9 mm thick composed of three layers of glass, the ballistic performance can also be superior to the conventional 40 mm thick F56 grade consisting of three layers of glass (anti-56/AK47 submachine gun or 81 rifle steel core bullet) full glass bulletproof glass ; also thin and light 4-5 times, which is the new material nature of other existing existing glass.
所以，我们能创意生产出涉及的具有防弹、防爆、防抢劫盗窃及防被伤害、防翻滚被伤害、防撞被伤害、巅覆性的安全水平加华丽又轻巧的新型综合功能汽车组合发明终端产品，具有防弹、防爆、防抢劫盗窃及防被伤害、防翻滚被伤害、华丽又轻巧、防撞的新型综合功能汽车组合发明终端产品，轻巧又外型华丽的汽车生活体验的同时还兼有防范因斧头或钢锤击打，破坏车窗车门的防被盗、防被抢劫、防人身被抢劫者伤害功能，是一种安心又放心的驾车与乘车生活体验特点(人只要在车内就不怕被抢劫，不怕人身被抢劫者伤害，不怕被枪击，不怕被手雷炸)Therefore, we can creatively produce a new comprehensive function car combination invention terminal that is bulletproof, explosion-proof, anti-robbery theft and anti-injury, anti-rolling injury, anti-collision damage, and overwhelming safety level plus gorgeous and light. The product has a new comprehensive function car combination with anti-ballistic, explosion-proof, anti-robbery theft and anti-injury, anti-rolling damage, gorgeous and lightweight, anti-collision, inventing the terminal product, and the light and beautiful car life experience also has both Preventing theft, burglary, and robbing of the window of the window due to the axe or steel hammer hitting is a kind of peace of mind and the feeling of driving and riding life experience (people only need to be in the car) Not afraid of being robbed, not afraid of being injured by the robbers, not afraid of being shot, not afraid of being blown up by grenades)
非显而易见的技术效果[7]：本发明的具有防爆、防抢劫盗窃及防被伤害、防翻滚被伤害、华丽又轻巧、防撞的新型综合功能汽车组合发明终端产品，因兼有防翻滚造成伤害功能的特点：可因本发明防爆玻璃强度是传统普通汽车玻璃的4-5倍[厚度是2倍]等于4-5 X2＝8-10倍，并韧性好，可吸收翻滚力与撞击力；而且还有‘立木撑千斤的力学功效，即等于有普通的玻璃的上、下、左、右方向支撑力和前后或上、下、左、右方向的4-5 X2＝8-10倍防撞击力’，所以 可比常规汽车翻滚时只有A、B、C柱的支撑力大幅上升，所以本发明的防汽车翻滚伤害功能，具有非显而易见的技术效果。Non-obvious technical effect [7]: The invention discloses a new comprehensive function automobile combination end product with explosion-proof, anti-robbery theft and anti-injury, anti-rolling damage, gorgeous and light, anti-collision, which is caused by anti-rolling Characteristics of the damage function: Because the strength of the explosion-proof glass of the invention is 4-5 times that of the conventional ordinary automobile glass [the thickness is 2 times] is equal to 4-5 X2=8-10 times, and the toughness is good, and the rolling force and the impact force can be absorbed. And there is also the mechanical effect of the standing timber support, which is equal to the upper, lower, left and right direction supporting force of ordinary glass and 4-5 X2=8-10 times of front and rear or up, down, left and right directions. Anti-collision force', so The support force of the A, B, and C columns can be greatly increased when the conventional automobile is tumbling, so the anti-vehicle tumbling damage function of the present invention has a non-obvious technical effect.
(F类2)从属权利要求与结抅组合应用发明或要素变化的发明，之33：(Class F 2) Inventions in which the invention or element changes are applied in the dependent claims and the combination, 33:
一种高性能防抢劫、防盗、防爆、防撞击、防滚翻伤害汽车，其包含：A high-performance anti-robbery, anti-theft, explosion-proof, anti-collision, anti-rolling injury car, which includes:
1-10个车窗的1-3层玻璃，防弹玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；1-3 layers of glass of 1-10 windows, bulletproof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass;
以及动力装置；仪表盘；方向控制器；汽车外壳；汽车底盘；汽车刹车装置；汽车轮胎。And power unit; instrument panel; direction controller; car shell; car chassis; car brakes;
非显而易见的技术效果[1]：本发明的具有华丽又轻巧、防撞的新型综合功能汽车组合发明终端产品，轻巧又外型华丽的汽车生活体验的同时，还兼有防范因斧头或钢锤击打，破坏车窗车门的防被盗、防被抢劫、防人身被抢劫者伤害功能，是一种安心又放心的驾车与乘车生活体验特点(人只要在车内就不怕被抢劫，不怕人身被抢劫者伤害)Non-obvious technical effect [1]: The invention has a gorgeous, lightweight and anti-collision new integrated function automobile combination invention terminal product, which is light and attractive, and has a gorgeous car life experience, and also has protection against an axe or a steel hammer. Strike, destroy the anti-stolen, anti-robbery, anti-robbery function of the window of the car window, is a kind of peace of mind and the feeling of driving and riding life experience (people are not afraid of being robbed in the car, not afraid Personal being injured by the robbers)
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. Technical effect.
非显而易见的技术效果[3]：本发明有特别的防火防爆效果：如采用加厚的钠钙玻璃的所谓铯钾防火玻璃，可一定时间抗1000℃高温；而且本发明玻璃经过化学强化后，可在更长时间抗1000℃高温；将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力。Non-obvious technical effect [3]: The invention has special fireproof and explosion-proof effects: if the so-called strontium-potassium fire-resistant glass with thick soda-lime glass is used, it can resist 1000 ° C high temperature for a certain period of time; and after the glass of the invention is chemically strengthened, It can withstand high temperatures of 1000 ° C for a longer period of time; it will greatly enhance the ability to resist bursting when the glass volume in the high temperature region is rapidly increased.
非显而易见的技术效果[4]：能有利于在碰到车外着火时，因车玻璃防火而有利于人或车逃离着火区，而增加车内人员安全，并延长驾车逃离的时间机会；Non-obvious technical effects [4]: It can help to prevent people or cars from escaping from the fire zone when the vehicle is hit by fire. It increases the safety of the people inside the vehicle and prolongs the chance of driving away.
非显而易见的技术效果[5]：在本用途领域中，抗折强度；可实质性的比先有对比技术[1][2][3][4]改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。 Non-obvious technical effects [5]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
非显而易见的技术效果[6]：所以，我们能创意生产出涉及的具有防抢劫盗窃及防被伤害、防翻滚被伤害、防撞被伤害、巅覆性的安全水平加华丽又轻巧的新型综合功能汽车组合发明终端产品，具有防爆、防抢劫盗窃及防被伤害、防翻滚被伤害(因兼有防翻滚造成伤害功能的特点：可因本发明防爆玻璃强度是传统普通汽车玻璃的[厚度是2倍]等于4-5 X2＝8-10倍，并韧性好，可吸收翻滚力与撞击力；而且还有‘立木撑千斤的力学功效，即等于有普通的玻璃的上、下、左、右方向支撑力和前后或上、下、左、右方向的[厚度是2倍]等于4-5 X2＝8-10倍防撞击力’，所以可比常规汽车翻滚时只有A、B、C柱的支撑力大幅上升，所以本发明的防汽车翻滚伤害功能，具有非显而易见的技术效果。)Non-obvious technical effects [6]: Therefore, we can creatively produce new types of anti-robbing theft and anti-injury, anti-rolling damage, anti-collision and injury, and a level of safety plus gorgeous and lightweight. The functional car combination invents the terminal product, which has the characteristics of explosion-proof, anti-robbery theft and anti-injury, anti-rolling and being damaged (because of the anti-rolling damage function): the strength of the explosion-proof glass of the invention is the traditional ordinary automobile glass [thickness is 2 times] equals 4-5 X2=8-10 times, and has good toughness, which can absorb rolling force and impact force; and there is also the mechanical effect of 'standing wood to support kilograms, which means equal to the upper, lower and left sides of ordinary glass. The right direction support force and the front and back or the upper, lower, left and right directions [thickness is 2 times] is equal to 4-5 X2=8-10 times anti-collision force', so only A, B, C columns can be rolled than conventional cars. The support force is greatly increased, so the anti-vehicle tumbling damage function of the present invention has a non-obvious technical effect.)
非显而易见的技术效果[6]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [6]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
(G类1)从属权利要求与结抅组合应用发明或要素变化的发明，之34：(G class 1) The invention of the invention or the change of the element is applied in the dependent claims and the combination, 34:
一种高性能太阳能飞行器，其具有推动飞行的缧旋桨动力的装置，机翼，驾驶控制***装置，和一种薄膜太阳能装置，该装置包含：薄膜太阳能电池；薄膜太阳能装置上的基板玻璃，根据上述权利要求1所述是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃。A high performance solar aircraft having a propeller power for propelling flight, a wing, a driving control system device, and a thin film solar device comprising: a thin film solar cell; a substrate glass on a thin film solar device, According to the invention as claimed in claim 1, a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass are provided.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：本发明一种太阳能飞行器，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可使布满机身机机翼的太阳能玻璃板，比现有一切太阳能玻璃板，更加耐热耐高温。Non-obvious technical effect [2]: A solar powered aircraft of the present invention can be filled with a machine due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in a high temperature region, higher strength, and the like. The solar glass panel of the wing is more heat and temperature resistant than all existing solar glass panels.
非显而易见的技术效果[3]：在本用途领域中，抗折强度；可实质性的比先有对比技术[1][2][3][4]改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。 Non-obvious technical effects [3]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
非显而易见的技术效果[4]：本发明一种太阳能飞行器，由于有强度能上升4-5倍的性能，可使布满机身机机翼的太阳能玻璃板轻薄化为仅1/4-1/5，也可使支撑太阳能玻璃板的框架也轻薄化为仅1/4-1/5；也可使支撑太阳能玻璃板的机身支撑设计大大减轻；又因为传统的太阳能飞行器的上述部分占据了总重量的很大部分，而能产生本发明太阳能飞行器，：Non-obvious technical effect [4]: The solar aircraft of the present invention can reduce the solar glass panel covered with the fuselage wing to only 1/4-1 due to the 4-5 times improvement in strength. /5, can also make the frame supporting the solar glass plate light and thin to only 1/4-1/5; can also greatly reduce the design of the fuselage support supporting the solar glass plate; and because the above part of the traditional solar aircraft occupies A large portion of the total weight, which produces the solar powered aircraft of the present invention,:
(1)或会因为，创新的本发明太阳能飞行器总重量的大幅减少，所以同等的太阳能动力，能取得更长的空中飞行时间；(1) Or because the innovative total weight of the solar aircraft of the present invention is greatly reduced, so the same solar power can achieve longer air flight time;
(2)会或因创新的本发明太阳能飞行器总重量的大幅减少，所以同等的太阳能动力，能取得更快的空中飞行速度；(2) The solar energy of the invention may be greatly reduced due to the innovation, so that the same solar power can achieve faster air flight speed;
(3)或者因创新的本发明太阳能飞行器，在总重量与传统太阳能飞行器一样时，可设计更大面积的本发明轻薄化太阳能板，得到更多的太阳能动力，也能取得更快的空中飞行速度和更长的空中飞行时间。(3) Or because of the innovative solar powered aircraft of the present invention, when the total weight is the same as that of the conventional solar powered aircraft, a larger area of the thin and light solar panel of the present invention can be designed to obtain more solar power and achieve faster air flight. Speed and longer air flight time.
[H]耐用终端工业产品类结抅组合应用发明：[H] Durable terminal industrial products type combination application invention:
外墙建筑装饰类结抅组合应用发明：Exterior wall building decoration type combination application invention:
(H类1)从属权利要求与结抅组合应用发明或要素变化的发明，之35：(Class H) The invention in which the invention or the element change is applied in the dependent claims and the combination of the combination, 35:
一种高性能彩釉平板玻璃与金属层的复合板，其结构组成是：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃，其基板玻璃表面有1-10种色彩的彩釉层，0.1-5mm厚度的金属板材，在上述玻璃板和金属板材之间有一层粘合材料层。The utility model relates to a composite board of high-performance color glaze flat glass and metal layer, wherein the glass composition is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof explosion-proof The flat glass has a glaze layer of 1-10 colors on the surface of the substrate glass, a metal plate with a thickness of 0.1-5 mm, and a layer of adhesive material between the glass plate and the metal plate.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明 有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. Technical effect There is a special building material fireproof and explosion-proof effect, which will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[3]：在建筑物内外墙面安装中，兼有铝塑板和铝板的施工和使用的便利性和轻薄性；又有比铝塑板好很多倍的强度和平整性及几百年不变色的石材和木材的图案纹理。具有非显而易见的技术效果。代表了在建筑物内外墙面安装中，装饰材料的新趋势。Non-obvious technical effects [3]: In the installation of interior and exterior walls of buildings, it has the convenience and lightness of construction and use of aluminum-plastic composite panels and aluminum panels; it also has many times more strength and flatness than aluminum-plastic composite panels. And the pattern texture of stone and wood that does not change color for hundreds of years. Has a non-obvious technical effect. It represents a new trend in decorative materials in the installation of interior and exterior walls of buildings.
非显而易见的技术效果[4]：在本用途领域中，抗折强度；可实质性的比先有对比技术[1][2][3][4]改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。Non-obvious technical effects [4]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
非显而易见的技术效果[5]：在上述更好的与现有技术的品质而且强度可以达到比现有的平板玻璃高4-5倍，这种新的产品性质的发现和产生，使与彩釉层的组合发明产生了可以生产1-3mm的厚度的[等于5-15mm的钙钠玻璃强度]够强度的[一种高性能彩釉平板玻璃与金属层的复合板产品]，对现国家标准的外墙挂板12mm厚的陶瓷产品和25mm厚度的石材产品标准，本发明高强度、轻薄化[4-25倍]的替代，产生能源、资源、物流、仓储的4-25倍的节约的预料不到的效果。Non-obvious technical effects [5]: In the above-mentioned better quality with the prior art and the strength can be 4-5 times higher than the existing flat glass, the discovery and production of this new product property makes color The combined invention of the glaze layer produces a [composite board product of high performance glazed flat glass and metal layer] capable of producing a thickness of 1-3 mm [equal to the strength of calcium-sodium silicate glass of 5-15 mm], for the current country Standard external wall hanging board 12mm thick ceramic products and 25mm thickness stone product standard, the invention of high strength, thin and light [4-25 times] replacement, resulting in energy, resources, logistics, storage 4-25 times savings Unexpected effect.
非显而易见的技术效果[6]：a.一种高性能彩釉平板玻璃与金属层的复合板产品，可以克服铝塑板在外墙使用因塑料板被日晒后，1年就膨胀收缩变形，平整度极差的缺陷；b.可以克服铝塑板图案印刷为有机材料，在外墙1-2年变色不能作外墙的缺陷；c.本发明加铝膜层的复合板，有图案精细，永不褪色，平整度极好，寿命可达50-80年，的优点；Non-obvious technical effect [6]: a. A high-performance color glaze flat glass and metal layer composite board product, which can overcome the expansion and contraction deformation of the aluminum-plastic panel after being used for the outer wall due to the plastic plate being exposed to the sun for one year. Defects with poor flatness; b. It can overcome the printing of aluminum-plastic plate pattern as organic material, and can not be used as the outer wall defect in the outer wall for 1-2 years; c. The composite plate with aluminum film layer of the invention has fine patterns. Never fade, the flatness is excellent, and the life expectancy is 50-80 years.
非显而易见的技术效果[7]：一种高性能彩釉平板玻璃与金属层的复合板产品，能和铝塑板一样安装简便的优点；Non-obvious technical effect [7]: A high-performance color glaze flat glass and metal layer composite board product, which can be installed as easy as aluminum-plastic board;
非显而易见的技术效果[8]：一种高性能彩釉平板玻璃与金属层的复合板产品：a.能和外墙干掛铝板一样安装简便的优点；b.又有外墙干掛铝板作不到的，表 面平整度和出现精细石纹或木纹图案效果；c.或外墙干掛铝板作不到的，各种300年不退色的无机彩釉的黄、兰、灰、白、黑等单色装饰效果；Non-obvious technical effect [8]: A high-performance color glaze flat glass and metal layer composite board product: a. It can be installed as easy as the external wall dry hanging aluminum plate; b. There is also an external wall dry hanging aluminum plate Less than Flatness and appearance of fine stone or wood grain pattern; c. or external wall dry hanging aluminum plate can not be used, all kinds of 300 years of non-fading inorganic color glaze yellow, blue, gray, white, black and other monochrome Decorative effect
(H类2)从属权利要求与结抅组合应用发明或要素变化的发明，之36：(Class H 2) The invention in which the dependent claims and the combination of the invention apply the invention or the element change, 36:
外墙建筑装饰类结抅组合应用发明：Exterior wall building decoration type combination application invention:
一种高性能的、具有在墙面上安装简便结构的、彩釉玻璃复合材料板，其结构组成是，其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其基板玻璃表面有1-10种色彩的彩釉层，0.1-5mm厚度的金属板材，在上述玻璃板和金属板材之间有一层粘合材料层，其特征在于：其制品的复合板的背底面的金属板的2-4条边，比重迭后的表层彩釉装饰平板玻璃制品的边部伸出了10-30mm的距离。A high-performance glazed glass composite material board having a simple structure installed on a wall surface, the structural composition thereof is that the glass is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. , low crystallization rate, application of fireproof and explosion-proof flat glass, the surface of the substrate glass has 1-10 colors of glaze layer, 0.1-5mm thickness of metal plate, there is a layer of bonding material between the glass plate and the metal plate The layer is characterized in that: 2-4 sides of the metal plate on the back bottom surface of the composite board of the product, and the edge of the surface glazed decorative flat glass product of the specific gravity protrudes by a distance of 10-30 mm.
非显而易见的技术效果[1]：发现的低析晶速度晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: Discovered low crystallization rate crystal velocity properties, resulting in high quality and large production technical effects.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has a non-obvious technical effect.
非显而易见的技术效果[4]：在本用途领域中，抗折强度；可实质性的比先有对比技术[1][2][3][4]改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。Non-obvious technical effects [4]: In the field of this application, the flexural strength; can be substantially improved and improved by 1/4 compared to the prior art [1][2][3][4]; The flexural strength of TFT boron-containing glass is increased by about 3 times; the flexural strength of the touch screen glass of 12-15% of aluminum is increased by about 2.4 times; the flexural strength of calcium-sodium glass is about 5 times higher than that of 50Mpa. .
也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
非显而易见的技术效果[5]：在上述更好的与现有技术的品质而且强度可以达到比现有的平板玻璃高4-5倍，这种新的产品性质的发现和产生，使与彩釉层的组合发明产生了可以生产1-2mm的厚度的[等于5-15mm的钙钠玻璃强度]够强度的[一种高性能的、具有在墙面上安装简便结构的、彩釉玻璃复合材料板产 品]，对现国家标准的外墙挂板12mm厚的陶瓷产品和25mm厚度的石材产品标准，本发明高强度、轻薄化[6-25倍]的替代，产生能源、资源、物流、仓储的6-25倍的节约的预料不到的效果。Non-obvious technical effects [5]: In the above-mentioned better quality with the prior art and the strength can be 4-5 times higher than the existing flat glass, the discovery and production of this new product property makes color The combined invention of the glaze layer produces a sufficient strength to produce a thickness of 1-2 mm [equivalent to 5-15 mm of calcium soda glass strength] [a high-performance, glazed glass composite with a simple structure installed on the wall surface) Material board Product], for the current national standard external wall hanging board 12mm thick ceramic products and 25mm thickness stone product standard, the invention is high-strength, light and thin [6-25 times] replacement, generating energy, resources, logistics, warehousing Unexpected results of 6-25 times savings.
非显而易见的技术效果[6]：a.一种高性能的、具有在墙面上安装简便结构的、彩釉玻璃复合材料板产品，可以克服铝塑板在外墙使用因塑料板被日晒后，1年就膨胀收缩变形，平整度极差的缺陷；b.可以克服铝塑板图案印刷为有机材料，在外墙1-2年变色不能作外墙的缺陷；c.本发明加铝膜层的复合板，有图案精细，永不褪色，平整度极好，寿命可达50-80年，的优点；Non-obvious technical effect [6]: a. A high-performance, glazed glass composite board product with a simple structure installed on the wall surface, which can overcome the use of aluminum-plastic composite panels on the outer wall after the plastic panels are exposed to the sun. 1 year, the expansion and contraction deformation, the flatness is very poor; b. can overcome the aluminum-plastic plate pattern printing as an organic material, the outer wall 1-2 years discoloration can not be used as the outer wall defect; c. the invention of the aluminum film layer The composite board has the advantages of fine pattern, never fade, excellent flatness and long life of 50-80 years.
非显而易见的技术效果[7]：一种高性能的、具有在墙面上安装简便结构的、彩釉玻璃复合材料板产品：a.能和外墙干掛铝板一样安装简便的优点；b.又有外墙干掛铝板作不到的，表面平整度和出现精细石纹或木纹图案效果；c.或外墙干掛铝板作不到的，各种300年不退色的无机彩釉的黄、兰、灰、白、黑等单色装饰效果；Non-obvious technical effect [7]: A high-performance, glazed glass composite board with a simple structure installed on the wall: a. It has the same advantages as the dry hanging aluminum panel on the outer wall; b. There is also the effect that the outer wall can not be used for hanging aluminum plates, the surface is flat and has the effect of fine stone or wood grain pattern; c. or the outer wall can not be used for hanging aluminum plates, all kinds of inorganic glazes that are not faded for 300 years. Monochrome decorative effects such as yellow, blue, gray, white, and black;
非显而易见的技术效果[8]：Non-obvious technical effects [8]:
a.能比铝塑板和干掛铝板的安装简便得多，还可以更简便地省去干挂龙骨架及繁杂的安装工序和节约大量安装成本；a. It is much easier to install than aluminum-plastic composite panels and dry-hanging aluminum panels, and it is also easier to omit the dry hanging dragon skeleton and complicated installation process and save a lot of installation costs;
b.采用在背面贴4-6条10cm宽的少量瓷砖胶找平，再对[复合板材的底面金属板材的2-4条边比重叠后的表层玻璃的边部伸出了10-30mm的距离，在这伸出的边部]进行几个打孔后采用膨胀镙钉直接钉入墙体，固定在墙体上，再在边缝打胶，形成石材干挂装修效果。b. Use 4-6 strips of 10cm wide ceramic tile glue on the back to level, and then [the 2-4 sides of the bottom metal sheet of the composite sheet protrudes by 10-30mm from the edge of the overlapped surface glass. In this outstretched side] after several punching, use the expansion boring nail to directly nail into the wall, fix it on the wall, and then glue on the side seam to form the dry hanging decoration effect of the stone.
c.在一定的外墙髙度[如4-60M]，瓷砖及石材施工不许可用粘贴方式；而本发明一种高性能的、具有在墙面上安装简便结构的、彩釉玻璃复合材料板，施工采用的安全牢固的墙上用膨胀镙钉直接钉入墙体，加采用在背面贴4-6条4-8cm宽的少量瓷砖胶找平方式[即安全牢固又省工时又高效的方式为主，少量瓷砖胶找平又粘贴为辅方式]；c. In a certain external wall twist [such as 4-60M], the tile and stone construction is not allowed to be pasted; and the present invention is a high-performance, glazed glass composite material having a simple structure installed on the wall surface. The board, the safe and firm wall used for construction, is directly nailed into the wall with the expansion boring nail, and the 4-6 strips of 4-8cm wide on the back are used to level the way [ie safe and secure, labor-saving and efficient way) Mainly, a small amount of tile adhesive is leveled and pasted as an auxiliary method];
所以本发明，能解决在外墙一定髙度[如4-60M]进行装饰板粘贴安装时：Therefore, the present invention can solve the problem that when the decorative panel is pasted and installed in a certain degree of external wall [such as 4-60M]:
1.粘贴方式快捷放便，但不安全的难题，本发明能克服；1. The pasting method is quick and easy, but the problem is not safe, and the invention can be overcome;
2.石材、瓷砖、铝板的传统干挂龙骨架工艺须然安全，但又有繁杂的安装工序，占用长时间施工时间和有大量安装成本难题，本发明能克服。 2. The traditional dry hanging dragon skeleton process of stone, ceramic tile and aluminum plate must be safe, but it has complicated installation process, occupying long construction time and having a large installation cost problem, and the invention can be overcome.
非显而易见的技术效果[3]：轻薄化性质的彩釉装饰平板玻璃的边部伸出了10-30mm的距离，在这伸出的边部进行打孔后采用镙钉直接钉入木材或砖材或水泯墙体；或与墙体龙骨架固定安装的创新，在内外墙面应用用途中的特点是：[1]安装方式十分简便而快速髙效；[2]产品比石材及瓷砖要轻薄6-20倍；[3]安装后安全性比粘贴墙面的石材及瓷砖高得多，绝不会掉下；[4]又有很髙强度和平整性及几百年不变色的石材和木材的图案纹理；[5]特别合适在木质别墅或低中层建筑的内外墙应用；具有非显而易见的技术效果。代表了在建筑物内外墙面安装中，装饰材料的新趋势。Non-obvious technical effect [3]: The thin and light-colored glazed decorative flat glass has a side extending 10-30mm away, and is punched directly into the wood or brick after the perforated side is punched. The material or the concrete wall; or the innovative installation fixed with the wall dragon skeleton, the characteristics of the inner and outer wall applications are: [1] the installation method is very simple and quick and effective; [2] the product is more than the stone and the tile Light and thin 6-20 times; [3] The safety after installation is much higher than that of the stone and tile attached to the wall, and will never fall; [4] There is also a stone with strong strength and flatness and no discoloration for hundreds of years. And wood pattern texture; [5] is particularly suitable for interior and exterior wall applications in wooden villas or low-rise buildings; with non-obvious technical effects. It represents a new trend in decorative materials in the installation of interior and exterior walls of buildings.
[I]建筑物室内地面用装饰类结抅组合应用发明：[I] Invented indoor floor decoration type knot combination application invention:
从属权利要求与结抅组合应用发明或要素变化的发明，之37：The invention of the invention or the change of the elements is applied in the dependent claims and the combination, 37:
一种高性能的、具有易装拆结构的、彩釉玻璃复合材料地板：A high-performance, glazed glass composite floor with an easy-to-assemble structure:
一种高性能的、具有易装拆结构的、彩釉玻璃复合材料地板，其结构包括，[1]表层彩釉玻璃材料基板，[2]粘合剂层，[3]底板层，其特征在于：表层彩釉玻璃材料基板，是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；底板层的1-2个侧面，底板层有凸出玻璃面的外侧边沿1-25mm的特征；底板层的另外1-2个侧面，底板层有凹入玻璃面边沿1-25mm的特征；凸出或凹入玻璃面的底板层厚度，是底板层材料厚度的10％-90％。A high-performance, glazed glass composite flooring with easy-to-assemble structure, including: [1] surface glazed glass substrate, [2] adhesive layer, [3] bottom layer, features It is: the surface layer of glazed glass material substrate is a high softening point, low differential coefficient of thermal expansion coefficient, low crystallization rate, fireproof and explosion-proof flat glass; 1-2 sides of the bottom layer, the bottom layer has protruding glass The outer edge of the face is 1-25mm; the other 1-2 sides of the bottom layer, the bottom layer has a feature of 1-25mm concave edge of the glass surface; the thickness of the bottom layer of the convex or concave glass surface is the material of the bottom layer 10%-90% of the thickness.
一种高性能的、具有易装拆结构的、彩釉玻璃复合材料地板，其底板层：或者是木材板；或者是金属材料板；或者是木板复合板；或者是木粉粒复合板；或者是树脂材料板。A high-performance, glazed glass composite flooring with an easy-to-assemble structure, the bottom layer: either a wood board; or a metal material board; or a wood board composite board; or a wood powder composite board; or It is a resin material board.
非显而易见的技术效果[1]：发现的低析晶速度性质，产生的高品质大生产的技术效果。Non-obvious technical effects [1]: The low crystallization rate properties found, resulting in the technical effects of high quality and large production.
非显而易见的技术效果[2]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力和延长防火防爆时间及延长着火时间的能力，具有非显而易见的技术效果。 Non-obvious technical effects [2]: In the application place, the present invention compares the prior comparative techniques [1][2][3][4] in the case of high temperature, in the case of high temperature. Due to the higher softening point of the flat glass of the invention, better high temperature zone thermal expansion difference, higher strength and the like, high performance, the shape of the glass can be maintained, and the non-obvious technical effect of fireproofing and fireproofing can be achieved. The invention has the special fireproof and explosion-proof effect of the building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and the ability to prolong the fireproof and explosion-proof time and prolong the ignition time, and has a non-obvious technical effect.
本发明产品，解决了木地板与木类复合地板的材料中，人们渴望解决而又没有获得成功的防火、隔火、延长防火防爆时间及延长着火时间的技术难题，代表着高水平的地面装饰材料技术的发展趋势。The product of the invention solves the technical problem that the wood floor and the wood composite floor material are eager to solve without successful fireproofing, fireproofing, prolonging the fireproof and explosion-proof time and prolonging the ignition time, and represents a high level of ground decoration. The development trend of material technology.
非显而易见的技术效果[3]：比木地板与木类复合地板的优势：Non-obvious technical effects [3]: advantages over wood flooring and wood composite flooring:
本发明，把先有对比技术[1][2][3][4]抗折强度顶点从180Mpa，实质性的改进和提高到抗折强度顶点240Mpa；比先有对比技术[1][2][3][4]抗折强度实质性的改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。The invention compares the apex of the first comparative technique [1][2][3][4] from 180Mpa, substantially improves and improves to the apex of the flexural strength 240Mpa; compared with the prior art [1][2 ][3][4] The flexural strength is substantially improved and improved by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; compared with the existing aluminum-containing 12-15% touch screen glass The flexural strength of 100 Mpa is increased by about 2.4 times; it is about 5 times higher than that of calcium sodium glass.
在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。In this field of application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is lighter than the existing TFT boron-containing glass. 1/3; lighter than calcium sodium glass, 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
所以在本用途领域中，更具高强度；更具轻薄效果：木地板与木类复合地板一般为18mm厚；本发明可在比木材更高抗拆强度时，只4-5mm厚；Therefore, in the field of use, it has higher strength; more light and thin effect: wood floor and wood type composite floor are generally 18mm thick; the invention can be only 4-5mm thick when the resisting strength is higher than wood;
本发明产品，解决了木地板与木类复合地板的材料中，人们渴望解决而又没有获得成功的更具高强度，更具轻薄效果的技术难题，代表着高水平的地面装饰材料技术的发展趋势。The product of the invention solves the technical problem of the high-strength and light-weight effect which is solved by the people who are eager to solve the wooden floor and the wooden composite floor material, and represents the development of the high-level floor decoration material technology. trend.
非显而易见的技术效果[4]：比木地板与木类复合地板的优势：Non-obvious technical effects [4]: advantages over wood flooring and wood composite flooring:
更具耐磨性：由于本发明制品可在650-740℃以下烧结彩釉层，所以可以烧结印刷釉层，可以在釉层加入大量的如30-80％的各种晶体尤其是成本低的石英或钢玉晶体粉或粒，形成史无前例的0.2-3mm的耐磨表层高硬度(石英可达7级的硬度，而加入钢玉则可达9级硬度)，而这在陶瓷生产中作不到的，因为陶瓷的烧成温度在1100℃-1200℃，此时陶瓷表层的石英或钢玉只能变成玻璃相，而在730℃以下，石英或钢玉晶体还可保持结晶相；这还能形成史无前例的装饰玻璃抛光的石英晶体硬度达7级耐磨面表层；具有非显而易见的技术效果。More wear resistance: Since the product of the invention can sinter the color glaze layer below 650-740 ° C, the printing glaze layer can be sintered, and a large amount of various crystals such as 30-80% can be added to the glaze layer, especially the low cost. Quartz or steel jade crystal powder or granules, forming an unprecedented hardness of 0.2-3mm wear-resistant surface layer (quartz can reach 7 grade hardness, while adding steel jade can reach 9 grade hardness), and this is not in ceramic production As a result, since the firing temperature of the ceramic is between 1100 ° C and 1200 ° C, the quartz or steel jade of the ceramic surface can only become the glass phase, and below 730 ° C, the quartz or steel jade crystal can maintain the crystal phase; It can also form an unprecedented decorative glass polished quartz crystal with a hardness of 7 grade wear surface; it has non-obvious technical effects.
本发明产品，解决了木地板与木类复合地板的材料中，人们渴望解决而又没有获得成功的耐磨性和易划花的技术难题，代表着高水平的地面装饰材料技术的发展趋势。 The product of the invention solves the technical problems of the high-level floor decoration material technology in the materials of the wooden floor and the wood composite floor, which people are eager to solve without successful abrasion resistance and easy drawing.
非显而易见的技术效果[5]，比木地板与木类复合地板的优势：Non-obvious technical effects [5], advantages over wood flooring and wood composite flooring:
因为表层基板材料采用浮法工艺，所以更具平整性。Because the surface substrate material is floated, it is more flat.
非显而易见的技术效果[6]，比木地板与木类复合地板的图案表现水平更好：The non-obvious technical effect [6] is better than the pattern of wood flooring and wood composite flooring:
本发明产品，用于设计和替代各类木纹及石纹及地毯产品时，不但强度高，安装运输轻巧方便，还可以采用电脑喷印，有保障形成各种木纹，及石纹，及地毯产品如：羊毛、化纤、丝材质等逼真质感的地毯图案；The product of the invention is used for designing and replacing all kinds of wood grain and stone grain and carpet products, not only has high strength, but is light and convenient to install and transport, and can also be printed by computer to ensure various wood grain and stone grain, and Carpet products such as wool, chemical fiber, silk material and other realistic carpet patterns;
非显而易见的技术效果[7]，比木地板与木类复合地板的优势：Non-obvious technical effects [7], advantages over wood flooring and wood composite flooring:
a.在本发明各块玻璃面和采用树脂材料底板层时，根本不怕完全的水侵，具有传统全木地板与木类复合地板不可比拟的优势；a. In the glass surface of the invention and the bottom layer of the resin material, it is not afraid of complete water intrusion, and has the advantages that the traditional all-wood floor and the wood-type composite floor are incomparable;
b.完全的水侵状态时，本发明就是采用木质材料底板层时，也不会使玻璃边沿从全木地板与木类复合地板之上翅起或变型，具有传统全木地板与木类复合地板不可比拟的优势；b. In the complete water intrusion state, the invention adopts the wooden material floor layer, and does not cause the glass edge to be winged or deformed from the whole wood floor and the wood composite floor, and has the traditional full wood floor and wood composite. Unmatched advantages of the floor;
c.在本发明各块玻璃面的边缝打防水胶，可达本发明完全防水目的，具有传统木地板与木类复合地板不可比拟的优势；c. In the side of each glass surface of the invention, the waterproof glue can be used for the purpose of completely waterproofing the invention, and has the advantages that the traditional wooden floor and the wooden composite floor are incomparable;
解决了木地板与木类复合地板的材料中，人们渴望解决而又没有获得成功的怕水侵的技术难题，代表着高水平的地面装饰材料技术的发展趋势。Solving the technical problems of wood flooring and wood composite flooring, people are eager to solve and have not succeeded in water intrusion, representing the development trend of high-level floor decoration materials technology.
非显而易见的技术效果[8]：Non-obvious technical effects [8]:
本发明比较木纹瓷砖，各种瓷砖，石材粘贴在地面的安装方式；The invention compares the installation manner of wood grain tile, various tiles and stone paste on the ground;
a.本发明由于组合结构创新的特征，所以产生了便于安装的非显而易见的技术效果，可如木地板一样方便安装方式快捷，商费时，省力，50-60平米安装1天；木纹瓷砖，瓷砖，石材50-60平米安装养护要3-5天。a. The invention has the characteristics of innovative combination structure, so that the non-obvious technical effect of the installation is easy, and the installation method is as convenient as the wooden floor, the time is cheap, the labor is saved, the installation is 50-60 square meters for one day; the wood grain tile, Tiles, stone 50-60 square meters installation maintenance to 3-5 days.
b，本发明比较木纹瓷砖，各种瓷砖，石材安装方式，更清洁，卫生，环保；又无收尾的多余的沙，水泥，的请除及运输；b, the present invention compares wood grain tiles, various tiles, stone installation methods, cleaner, hygienic, environmentally friendly; and no excess sand, cement, please remove and transport;
本发明不但有前述的7类技术效果，又能有木地板一样安装方便的技术效果；本发明，解决了地面装饰材料中，人们渴望解决而又没有获得成功的木纹瓷砖，各种瓷砖，石材的安装费时费力不卫生不环保的技术难题，代表着高水平的地面装饰材料技术的发展趋势。The invention not only has the above-mentioned 7 kinds of technical effects, but also has the technical effect of convenient installation of the wooden floor; the invention solves the wood grain tile and various ceramic tiles which are desired to be solved without success in the floor decoration material. The installation of stone is time-consuming, labor-intensive, and environmentally-friendly. It represents the development trend of high-level floor decoration materials technology.
非显而易见的技术效果[9]： Non-obvious technical effects [9]:
本发明比较木纹瓷砖，各种瓷砖，石材粘贴在地面的方式：The invention compares the way of wood grain tiles, various tiles, and stone paste on the ground:
a.本发明折除时：由于组合结构创新的特征，所以产生了便于折除便于二次装修的非显而易见的技术效果，可如木地板一样方便：(50-60平米折除，用扥掍2小时可完成)a. When the invention is dismantled: due to the innovative features of the combined structure, a non-obvious technical effect that facilitates folding and facilitating secondary decoration is produced, which is as convenient as a wooden floor: (50-60 square meters, for use) 2 hours to complete)
b.木纹瓷砖，各种瓷砖，石材，折除时：b. Wood grain tiles, various tiles, stone, when dismantling:
其与地面粘合部，要采用大钻或大锤折除，50-60平米折除，3-5天也不一定可完成；对建筑破坏性大，费拉圾运输量大，不环保；The joint with the ground should be dismantled with a large drill or a sledgehammer, and 50-60 square meters should be dismantled, and 3-5 days may not be completed; the building is highly destructive, and the waste cargo is large and environmentally friendly;
木纹瓷砖，各种瓷砖，石材与地面粘合部，要采用大钻或大锤折除，声响很大，因很挠民，而反响强烈。Wood grain tiles, all kinds of tiles, stone and ground bonding parts, should be removed by large drills or sledge hammers, the sound is very loud, because it is very scratching the people, and the reaction is strong.
本发明不但有前述的7类技术效果，又能有木地板一样拆除方便的技术效果；解决了地面装饰材料中人们渴望解决而又没有获得成功的木纹瓷砖，各种瓷砖，石材的拆除技术难题，代表着高水平的地面装饰材料的技术发展趋势。The invention not only has the above-mentioned 7 kinds of technical effects, but also has the technical effect of dismantling conveniently like a wooden floor; and solves the wood grain tile, various ceramic tiles and stone removal technology which are desired and solved without success in the floor decoration material. The problem represents the technical development trend of high-level floor decoration materials.
非显而易见的技术效果[10]：Non-obvious technical effects [10]:
比较木纹瓷砖，各种瓷砖，石材直接粘贴在水泥地面的安装方式，会在脚下产生太过坚硬的感觉；Comparing wood grain tiles, various tiles, and the way the stone is directly attached to the concrete floor will produce a feeling of being too hard under the feet;
本发明由于下面有一层：或者是木材板；或者是木板复合板；或者是木粉粒复合板；或者是树脂材料的底板层；但因为安装时都会如木地板安装一样，有一层打底的木板层或木条；而就是‘底板层的凹入外部下边部分’与‘一层打底的木板层或木条’之间，由若干小铁钉钉入而形成的安装结合(即如木地板的安装结构方法)，并承受底板层压力；这就能在脚下产生如木地板一样的弹性。The invention has a layer below: either a wood board; or a wood board composite board; or a wood powder composite board; or a bottom layer of a resin material; but since it is installed like a wooden floor, there is a layer of bottoming a layer of wood or a wooden strip; that is, a combination of a 'recessed outer lower portion of the bottom layer' and a layer of bottomed wood or wooden strip, which is formed by a number of small nails (ie, wood) The installation method of the floor) and the pressure of the floor layer; this can produce the same elasticity under the feet as the wooden floor.
非显而易见的技术效果[11]：Non-obvious technical effects [11]:
对于不方便折除的瓷砖或石材地面，本发明还可以快速的，直接拼装在上面；安装施工又比用水泥粘贴干净，效率高，又方便，而且也可产生高仿真的木纹理或石材纹理装饰效果。For tiles or stone floors that are inconvenient to be dismantled, the invention can also be assembled directly on the surface quickly; the installation construction is cleaner than cement, high efficiency, convenient, and can also produce high simulation wood texture or stone texture. Decorative effect.
非显而易见的技术效果[12]：Non-obvious technical effects [12]:
本发明不只是用于仿木纹的产品，尤其用在各种具高仿真的石材图案华丽装饰效果的地面产品时，比较瓷砖，石材产品和直接粘贴在水泥地面的安装方式：非显而易见的技术效果是： The invention is not only used for the imitation wood grain product, especially when used in various ground products with high embellished stone pattern ornate decorative effect, comparing the tile, stone product and directly pasting on the cement floor: non-obvious technology The effect is:
能使，如45x45cm；30x60cm，40x80cm，60x60cm，90x90cm等尺寸的具高仿真的石材图案华丽装饰效果的地面产品，采用本发明，在家居地面、经常换装修的商业门面地面、百货商场地面、酒店地面、连锁店地面等场所，；安装施工和拆除施工都比用水泥粘贴施工干净、达到可以快速直接拼装、高效率又方便、的技术效果；It can be used, such as 45x45cm; 30x60cm, 40x80cm, 60x60cm, 90x90cm and other high-simulation stone pattern gorgeous decorative ground products, using the invention, on the home floor, often changing the commercial facade, department store floor, hotel Ground, chain store ground and other places; installation and demolition construction are cleaner than cement paste construction, to achieve rapid and direct assembly, high efficiency and convenient technical effect;
对于传统石材、瓷砖用水泥粘贴施工和拆除施工方法：[1]工作量大，复杂、混乱、不干净；[2]安装施工时间长、又效率低；[3]而拆除施工更工作量大，复杂、混乱、不干净；[4]拆除施工时间长又效率低的；For traditional stone and tile cement paste construction and demolition construction methods: [1] large workload, complicated, chaotic, and unclean; [2] long installation time and low efficiency; [3] and demolition construction is more labor-intensive , complicated, chaotic, and unclean; [4] long and inefficient to dismantle construction;
所以对传统石材、瓷用水泥粘贴地面安装结抅和安装方法的难题，能有效克服。具有非显而易见的技术效果。Therefore, the problem of the traditional stone and porcelain cement paste floor installation and installation method can be effectively overcome. Has a non-obvious technical effect.
而且本发明，在‘一种高性能的、具有易装拆结构的、彩釉玻璃复合材料地板’用途中，利用这些新性质和利用这些具有易装拆结构的组合发明功能特征，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，是没有被一切先有对比技术公开过。Moreover, the present invention, in the use of a high-performance, glazed glass composite flooring having an easy-to-assemble structure, utilizes these new properties and utilizes the combined inventive functional features of the easy-to-assemble structure to produce Unexpected technical effects are also unclear in common sense and cannot be inferred from common sense. The nature of these new discoveries and the unpredictable technical effects of using these new properties have not been disclosed by all prior art.
本发明的技术方案，在结抅组合应用发明或要素变化的发明According to the technical solution of the present invention, the invention of the invention or the change of the element is applied in the combination
‘一种高性能的、具有易装拆结构的、彩釉玻璃复合材料地板’用途中，因为发现了新材料性质，并利用这些这性质和利用这些具有易装拆结构的组合发明功能特征，产生了上述12种予料不到的技术效果；所以应判断，本发明的技术方案，有实质性的进步性和创造性。'A high-performance, glazed glass composite flooring with easy-to-assemble structure', because of the discovery of new material properties, and the use of these properties and the use of these combined functional features with easy-to-assemble structures, The above 12 kinds of unexpected technical effects are produced; therefore, it should be judged that the technical solution of the present invention has substantial progress and creativity.
[J]高性能的玻璃洗面盆类卫生间装饰类结抅组合应用发明：[J]High-performance glass wash basin type bathroom decoration type knot combination application invention:
从属权利要求与结抅组合应用发明或要素变化的发明，之38：</ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt;
一种采用热变型工艺生产的高性能的玻璃洗面盆，其是对平板玻璃材料由所需的洗面盆型状的模具，采用热变型工艺来生产的高性能的玻璃洗面盆，其特征在于：所述的平板玻璃材料是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃。A high-performance glass wash basin produced by a thermal deformation process, which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold, characterized in that: The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass.
从属权利要求与结抅组合应用发明或要素变化的发明，之39：The invention in which the dependent claims and the combination are applied to the invention or the element change, 39:
一种采用热变型工艺生产的高性能的彩釉玻璃洗面盆，其是对平板玻璃材料由所需的洗面盆型状的模具，采用热变型工艺来生产的高性能的玻璃洗面盆，其 特征在于：所述的平板玻璃材料是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；玻璃上面附着有彩轴层。A high-performance glazed glass wash basin produced by a thermal deformation process, which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold. The utility model is characterized in that: the flat glass material is a high softening point, a low difference of a thermal expansion coefficient in a high temperature zone, a low crystallization rate, a fireproof and explosion-proof flat glass; and a color shaft layer is attached to the glass.
从属权利要求与结抅组合应用发明或要素变化的发明，之40：</ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt;
一种采用热变型工艺生产的高性能的彩釉玻璃抬面板和联体的洗面盆，其结构特征在于：1.平面型状的抬面板；2.其联体的另一个部分，是对平板玻璃材料由所需的洗面盆型状的模具，采用热变型工艺来生产的玻璃洗面盆；3.所述的平板玻璃材料是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；4.玻璃面附着有彩轴层。A high-performance glazed glass lifting panel and a combined wash basin produced by a thermal deformation process, the structural features of which are: 1. a flat-shaped lifting panel; 2. another part of the joint is a flat panel Glass material consists of a desired wash basin-shaped mold, a glass wash basin produced by a thermal deformation process; 3. The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, and a low resolution Crystal speed, fireproof and explosion-proof flat glass; 4. The glass surface is attached with a color shaft layer.
从属权利要求与结抅组合应用发明或要素变化的发明，之41：The invention of the invention or the change of the elements is applied in the dependent claims and the combination, 41:
一种用于卫生间的高性能彩釉玻璃洗面盆台面板，其特征在于：1.其台面玻璃，是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；2.台面的表面或背面有1-10种色彩的彩釉层；3.其台面平面上有一个安装洗面盆的孔；4.其台面下部有支撑装置。A high-performance glazed glass washbasin countertop for a bathroom, characterized in that: 1. The countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, and a low analysis Crystal speed, application of fireproof and explosion-proof flat glass; 2. glazed layer of 1-10 colors on the surface or back of the table; 3. There is a hole for installing the wash basin on the surface of the table; 4. Supporting device at the lower part of the table .
以上四类高性能的玻璃洗面盆类卫生间装饰类结抅组合应用发明，比较传统的钠钙玻璃洗面盆类产品，具有非显而易见的技术效果：The above four types of high-performance glass wash basins are designed to be combined with the invention. Compared with the traditional soda-lime glass washbasin products, they have non-obvious technical effects:
非显而易见的技术效果[1]：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]、在高温区状态下，由于本发明平板玻璃的更高的软化点、更好的高温区热膨胀差值、更高的强度等高性能，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的家具防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Non-obvious technical effects [1]: In the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of high temperature, when it is exposed to fire or high temperature. Due to the higher softening point of the flat glass of the present invention, better thermal expansion difference in the high temperature region, higher strength and the like, the shape of the glass can be maintained, and the fireproof, fireproof, and heat-insulating waves are non-obvious. The technical effect of the invention has the special fireproof and explosion-proof effect of the furniture, which greatly enhances the ability of bursting in the high temperature region when the glass volume is rapidly increased, and has non-obvious technical effects.
非显而易见的技术效果[2]：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。Non-obvious technical effects [2]: In the field of this application, it can also be light and thin at the same intensity, which is 3/4 lighter than the prior art [1][2][3][4]; The existing TFT boron-containing glass is 1/3 lighter and thinner than the calcium-sodium glass.
也能使各种高性能玻璃的强度，比现有钙钠强化玻璃强度，在同等厚度及重量时高5倍。It also enables the strength of various high-performance glasses to be five times higher than the strength of existing calcium-sodium tempered glass at the same thickness and weight.
非显而易见的技术效果[3]，各种高性能彩釉玻璃抬面板产品：a.，外观的高模拟的木纹、石纹的装饰艺术性及合适的产品设计切入点；b.全新的无机型彩釉组 合特高强度玻璃的坚固性耐磨的唯一性技术特征；c.比传统石材或人造石抬面板坚固、又高强度兼轻薄化、又安装方便、又十分环保。Non-obvious technical effects [3], various high-performance glazed glass lifting panels: a., the appearance of high-simulation wood grain, stone artefact and appropriate product design entry point; b. brand new inorganic Glaze set The unique technical characteristics of the sturdy and wear-resistant of the high-strength glass; c. It is stronger than the traditional stone or artificial stone lifting panel, high strength, light and thin, easy to install, and very environmentally friendly.
从属权利要求与结抅组合应用发明或要素变化的发明，之42：The invention in which the dependent claims and the combination are applied to the invention or the element change, 42:
一种用于阳台保护拦的超長玻璃板，其玻璃，是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：阳台保护拦的玻璃板的長度为3-8m。An ultra-long glass plate for a balcony protection barrier, the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is characterized in that the length of the glass plate of the balcony protection barrier is 3-8 m.
非显而易见的技术效果：在本用途领域中，也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。也能使玻璃强度，比现有钙钠玻璃强度在同等重量时高5倍。Non-obvious technical effect: In the field of this application, it can also be light and thin at the same strength, which is 3/4 lighter than the prior comparison technology [1][2][3][4]; compared with the existing TFT Boron-containing glass, light and thin 1/3; lighter than calcium sodium glass, 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight. It also enables the strength of the glass to be five times higher than the strength of the existing calcium soda glass at the same weight.
本发明的巅覆性的技术效果在于：建筑用玻璃材料都是钙钠玻璃，强度仅为50Mpa；而本发明髙性能玻璃可达180-240Mpa，达4--5倍的几何倍数的更高的强度，可以使建筑玻璃的防撞击、防爆裂、防各种击打爆性能等、安全性上升4倍-5倍；The technical effect of the coating of the invention is that the glass materials for construction are all sodium soda glass, the strength is only 50Mpa; and the performance glass of the invention can reach 180-240Mpa, and the geometric multiple of 4-5 times is higher. The strength of the building glass can be prevented from impact, explosion-proof, anti-shock performance, etc., and the safety is increased by 4 times -5 times;
可设计成阳台保护拦的玻璃板的長度为3-8m的长度中，不全在3-8m的长度中，被直立的铝合金骨架分割、遮挡；是一种无遮挡全景建筑阳台玻璃，(人坐在阳台的掎子上时眼的髙度只约70cm，可把阳台保护拦的玻璃板的高度设计为0.9m-1.3m，如果有3-8m的长度的横保护拦扶手也高度设计为0.9m-1.3m)；The length of the glass plate which can be designed as a balcony protection barrier is 3-8m in length, not all in the length of 3-8m, and is divided and blocked by the erect aluminum alloy frame; it is an unobstructed panoramic building balcony glass, When sitting on the curtain of the balcony, the eyesight is only about 70cm. The height of the glass plate of the balcony protection barrier can be designed to be 0.9m-1.3m. If there is a horizontal protection armrest with a length of 3-8m, it is also designed to be 0.9m-1.3m);
居住业主们，坐在阳台的掎子上休息时的新功能性生活体验：The new functional life experience of the resident owners sitting on the raft on the balcony:
1]不但能在视觉上展现超大范围的完整的阳台外美丽景观画面(如花园、山景、水景、海景、城市景色)，还能置身于户外大自然空气中，产生巅覆性阳台建筑的新功能性生活体验；1] Not only can visually display a large range of beautiful landscapes outside the balcony (such as garden, mountain, water, sea, city), but also in the outdoor nature of the air, creating a balcony building New functional life experience;
2]因为可产生新的功能性生活体验，能使阳台建筑空间具有：或家人、或与客人共聚的户外美景+茶吧；或家人、或与客人共聚的户外美景+咖啡吧、或家人、或与客人共聚的户外美景+酒吧；或家人、或与客人共聚的户外美景+读书吧；或家人、或与客人共聚的户外美景+电脑吧；创新了阳台建筑空间功能；2]Because it can create a new functional life experience, the balcony building space can have: outdoor scenery + tea bar for family members or guests, or outdoor scenery + coffee bar or family for family, or guests; Or the outdoor beauty + bar with the guests; or the family, or the outdoor scenery + reading bar with the guests; or the family, or the outdoor beauty + computer bar with the guests; innovative balcony building space function;
3]能巅覆各类阳台保护拦建筑玻璃的外立面超長度的整体性观感； 3] It can cover the overall appearance of the façade of various types of balcony protection building glass;
4]能创造新的阳台建筑设计消费市场，开创建筑设计价值的新历史；更能为建筑商及用户带来崭新的价值，具有非显而易见的技术效果：4] can create a new balcony architectural design consumer market, create a new history of architectural design value; more bring new value to builders and users, with non-obvious technical effects:
附图说明DRAWINGS
图1是本发明一种高软化点、低析晶速度、特髙铝无碱、防火防爆平板玻璃的平面示意图；1 is a schematic plan view showing a high softening point, a low crystallization rate, a special aluminum non-alkali, fireproof and explosion-proof flat glass according to the present invention;
图2是本发明一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用的制备工艺的浮法工艺成型的流程示意图；2 is a schematic flow chart of a float process for preparing a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a preparation process of fireproof and explosion proof flat glass;
图3是本发明一种高软化点、低析晶速度、特髙铝无碱、防火防爆平板玻璃的制备工艺的浮法工艺成型的状态的侧剖面示意图。3 is a side cross-sectional view showing a state in which a high softening point, a low crystallization rate, a special aluminum non-alkali, and a fireproof and explosion-proof flat glass are prepared by a float process.
图4是本发明一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用的实施例的尺寸是1220mm×2440mm厚度约2-5mm的已经印刷好预定三个色区的彩釉料形成表层是约0.1-1mm厚度的预定彩釉料图案装饰层的一种彩釉平板玻璃制品的平面示意图。4 is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of the fireproof and explosion proof flat glass. The size of the embodiment is 1220 mm × 2440 mm and the thickness is about 2-5 mm. The color glaze of the three color zones forms a plan view of a glazed flat glass article whose surface layer is a predetermined glaze pattern decorative layer of about 0.1-1 mm thickness.
图5是本发明一种高软化点、低析晶速度、特髙铝无碱、防火防爆平板玻璃，背面是重迭后边部没有超出表层硅酸盐彩釉装饰玻璃尺寸的铝板，通过粘Figure 5 is a high softening point, low crystallization rate, special aluminum non-alkali, fireproof and explosion-proof flat glass of the present invention, the back side is an aluminum plate with overlapping rear side without exceeding the size of the surface silicate glaze decorative glass, through the sticking
合剂相互粘贴复合组成的新型复合板材剖面结构示意图。Schematic diagram of the cross-sectional structure of a new composite sheet composed of a mixture of adhesives.
图6是本发明一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用的，背面是重迭后有2条边比表层硅酸盐彩釉装饰玻璃尺寸各自多伸出了Figure 6 is a high softening point, low temperature coefficient of thermal expansion coefficient of low temperature, low crystallization rate, application of fireproof and explosion-proof flat glass, the back is overlapped with two sides than the surface silicate glaze decoration The glass sizes are each extended.
10-30mm的铝板，相互粘贴复合组成的新型复合板材，在10-30mm伸出部分10-30mm aluminum plate, a new composite sheet composed of a composite of 10-30mm, extending at 10-30mm
上的预定位置打孔后，可进行墙面镙钉安装的立平面结构示意图。After the predetermined position on the hole is punched, a schematic diagram of the vertical plane structure of the wall nail mounting can be performed.
图7是本发明一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，背面是有2条边比表层硅酸盐彩釉装饰玻璃尺寸各自多伸出了10-30mm距离的铝板，相互粘贴复合组成的新型复合板材剖面结构示意图。7 is a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and the application of fireproof and explosion-proof flat glass, the back side has two sides than the surface silicate glaze decorative glass size An aluminum plate with a distance of 10-30 mm is extended, and a cross-sectional structure diagram of a new composite plate composed of a composite material is adhered to each other.
附图标记说明 Description of the reference numerals
1：一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用1: a high softening point, low differential coefficient of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass
2：料仓进料口2: silo inlet
3：料仓3: silo
4：预定配制的混合原料4: Scheduled mixed raw materials
5：原料进入熔池的熔池窑口5: The raw material enters the molten pool kiln mouth of the molten pool
6：熔池窑6: molten pool kiln
7：导流槽7: diversion channel
8：锡槽8: Tin bath
9：过渡辊台9: Transition Roller
10：退火窑10: Annealing kiln
11：切割分装台11: Cutting and dispensing station
12：浮法生产线基体12: float production line substrate
13：表示有彩釉层的高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃13: High-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass with colored glaze layer
14：表示重叠后边部未超出表层高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃边部的铝板14: An aluminum plate with a low-melting-point glaze decorative flat glass edge that does not exceed the surface layer high annealing temperature and high strength
15：表示预定的粘合剂15: indicates a predetermined adhesive
16：表示复合板材的背底铝板的比表层高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃伸出10-30mm的边部中的镙钉安装孔16: indicates that the backing aluminum plate of the composite sheet has a higher annealing temperature than the surface layer, and the environmentally-friendly and energy-saving low-melting glaze decorative flat glass protrudes from the side of the 10-30 mm side.
21：斜线部分表示已印刷的第一色区彩釉料图案区21: the slashed line indicates the printed first color glaze pattern area
31：十字线部分表示已印刷的第二色区彩釉料图案区31: The crosshair portion indicates the printed second color area glaze pattern area
41：小黑点部分表示已印刷的第三色区彩釉料图案区41: The small black dot portion indicates the printed third color area glaze pattern area
141：表示重叠后有2条边比表层高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃各自多伸出了10-30mm距离的铝板141: It means that there are two sides of the low-melting glaze decorative flat glass with two sides that are higher than the surface layer and have a high annealing temperature and high strength.
具体实施方式detailed description
本发明实施例1：(优选无碱产品例) Inventive Example 1: (preferably an alkali-free product example)
按重量百分比计，其氧化铝含量为29.2％，氧化钠含量为0.1％，氧化硅含量为47.2％，氧化钙含量为13％，氧化镁含量为10.5％，其特征在于：氧化硅含量是氧化钙含量的3.6倍，氧化钙含量是氧化镁含量的1.2倍。In terms of weight percent, the alumina content is 29.2%, the sodium oxide content is 0.1%, the silica content is 47.2%, the calcium oxide content is 13%, and the magnesium oxide content is 10.5%, which is characterized by: the silica content is oxidized. The calcium content is 3.6 times and the calcium oxide content is 1.2 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1540℃；本实例排气泡时璃排气泡时102(帕·秒)粘度温度1390℃。抗析强度192Mpa。In the present example, the actual melting time is 10 1.5 (Pa·s) viscosity temperature 1540 ° C; in this example, when the glass bubbles are discharged, the glass temperature is 10 2 (Pa·s) and the viscosity temperature is 1390 ° C. The anti-analytical strength is 192 MPa.
本发明析晶速度会比较慢，在每种玻璃析晶温度区的上线范围，逐步降温的条件下，在60-120分钟后，才会开始析晶。The crystallization rate of the present invention will be relatively slow, and the crystallization will start after 60-120 minutes under the condition that the upper line range of each glass crystallization temperature zone is gradually lowered.
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术2其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the prior art 2 has a difference in thermal expansion rate between 550 ° C and 600 ° C in the high temperature region and 600 ° C to 650 ° C in the high temperature region. Values range from 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之2-5以内。比其它玻璃在高温区的热膨胀率的差值低很多；In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 2-5 parts per million in the high temperature region of 700 ° C to 740 ° C. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;
本发明本实例由于软化点很高，达825℃。This example of the invention has a high softening point of up to 825 °C.
本发明实施例2：(优选无碱产品例)Inventive Example 2: (preferably an alkali-free product example)
按重量百分比计，其氧化铝含量为23.9％，氧化钠含量为0.1％，氧化硅含量为53％，氧化钙含量为15.5％，氧化镁含量为9.5％，其特征在于：氧化硅含量是氧化钙含量的3.9倍，氧化钙含量是氧化镁含量的1.4倍。In terms of weight percent, the alumina content is 23.9%, the sodium oxide content is 0.1%, the silica content is 53%, the calcium oxide content is 15.5%, and the magnesium oxide content is 9.5%, which is characterized by: the silica content is oxidized. The calcium content is 3.9 times and the calcium oxide content is 1.4 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1570℃；本实例实际玻璃排气泡时粘度温度102(帕·秒)1435℃。抗析强度172Mpa。In the present example, the actual melting time is 10 1.5 (Pa·s) viscosity temperature 1570 ° C; in this example, the actual glass discharge bubble viscosity temperature 10 2 (Pa·s) 1435 ° C. The analytical strength is 172 MPa.
本发明析晶温度区的上线范围自然降温的条件下，在每种玻璃析晶温度区的上线范围，逐步降温的条件下，在60-90分钟后，才会开始析晶。Under the condition that the upper line range of the crystallization temperature zone of the invention is naturally cooled, crystallization is started after 60-90 minutes under the condition of gradually lowering the upper line range of each glass crystallization temperature zone.
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术2其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。 This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the prior art 2 has a difference in thermal expansion rate between 550 ° C and 600 ° C in the high temperature region and 600 ° C to 650 ° C in the high temperature region. Values range from 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之2-5.5以内。In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 2-5.5 parts per million in the high temperature range of 700 ° C to 740 ° C.
本发明本实例由于软化点很高，达825℃；The present invention has a high softening point of up to 825 ° C;
本发明实施例3(优选无碱产品例)：Inventive Example 3 (preferably an alkali-free product example):
按重量百分比计，其氧化铝含量为36.5％，氧化钠含量为0.2％，氧化硅含量为40.3％，氧化钙含量为12％，氧化镁含量为11％，其特征在于：氧化硅含量是氧化钙含量的3.35倍，氧化钙含量是氧化镁含量的1.1倍。In terms of weight percent, the alumina content is 36.5%, the sodium oxide content is 0.2%, the silica content is 40.3%, the calcium oxide content is 12%, and the magnesium oxide content is 11%, which is characterized by: the silica content is oxidized. The calcium content is 3.35 times and the calcium oxide content is 1.1 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1660℃；本实例排气泡时102(帕·秒)粘度温度1475℃。抗析强度228Mpa。In the present example, the actual melting time was 10 1.5 (Pa·s) viscosity temperature of 1660 ° C; in this example, the bubble temperature of 10 2 (Pa·s) was 1475 ° C. The anti-analytical strength is 228 MPa.
本发明由于析晶速度会比较慢，析晶温度区的上线范围自然降温的条件下，在每种玻璃析晶温度区的上线范围，逐步降温的条件下，在60-120分钟后，才会开始析晶。In the invention, since the crystallization rate is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled, the upper line range of each glass crystallization temperature zone is gradually lowered under the condition of 60-120 minutes. Start crystallization.
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之2-4以内。比其它玻璃在高温区的热膨胀率的差值低很多；In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 2-4 parts per million in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;
本发明本实例由于软化点大大升高，达840℃；The present invention is greatly increased in softening point by 840 ° C;
本实例也有非常广泛的特种玻璃，电子玻璃，建筑玻璃的用途，也更将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，和能在电子玻璃的显示屏产品应用中，使分辩率水平性质能得到实质性的改进和提升。This example also has a very wide range of special glass, electronic glass, architectural glass, and will greatly enhance the ability to resist bursting when the glass volume in the high temperature zone is rapidly increasing, and can be used in the display of electronic glass display products. The nature of the resolution level can be substantially improved and improved.
本发明实施例4：(优选无碱产品例)Inventive Example 4: (preferably an alkali-free product example)
按重量百分比计，其氧化铝含量为16.5％，氧化钠含量为0.1％，氧化硅含量为52％，氧化钙含量为18％，氧化镁含量为15.4％，其特征在于：氧化硅含量是氧化钙含量的2.9倍，氧化钙含量是氧化镁含量的1.2倍。 In terms of weight percent, the alumina content is 16.5%, the sodium oxide content is 0.1%, the silica content is 52%, the calcium oxide content is 18%, and the magnesium oxide content is 15.4%, which is characterized in that the silica content is oxidized. The calcium content is 2.9 times and the calcium oxide content is 1.2 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1460℃，；本实例排气泡时璃排气泡时102(帕·秒)粘度温度1360℃。抗析强度126Mpa。In the present example, the actual melting time is 10 1.5 (Pa·s) and the viscosity temperature is 1460 ° C. In this example, when the glass bubbles are discharged, the glass temperature is 10 2 (Pa·s) and the viscosity temperature is 1360 ° C. The analytical strength is 126 Mpa.
本发明由于析晶速度会比较慢，析晶温度区的上线范围自然降温的条件下，在每种玻璃析晶温度区的上线范围，逐步降温的条件下，在60-90分钟后，才会开始析晶。In the invention, since the crystallization rate is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled, the upper line range of each glass crystallization temperature zone is gradually lowered under the condition of 60-90 minutes. Start crystallization.
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之6-8以内。比其它玻璃在高温区的热膨胀率的差值低很多；In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is within 6-8 parts per million in the high temperature region of 700 ° C to 740 ° C. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;
本发明本实例软化点较高，达785℃；The softening point of the present invention is as high as 785 ° C;
本发明实施例5： Embodiment 5 of the present invention:
按重量百分比计，其氧化铝含量为24％，氧化钠含量为3.4％，氧化硅含量为49.6％，氧化钙含量为15％，氧化镁含量为10％，其特征在于：氧化硅含量是氧化钙含量的3.8倍，氧化钙含量是氧化镁含量的1.3倍。In terms of weight percent, the alumina content is 24%, the sodium oxide content is 3.4%, the silica content is 49.6%, the calcium oxide content is 15%, and the magnesium oxide content is 10%, which is characterized by: the silicon oxide content is oxidized. The calcium content is 3.8 times and the calcium oxide content is 1.3 times that of the magnesium oxide.
本实例实际溶化时101.5(帕·秒)粘度温度1520℃；本实例排气泡时璃排气泡时102(帕·秒)粘度温度1400℃。抗析强度161Mpa。In the present example, the actual melting time is 10 1.5 (Pa·s) viscosity temperature 1520 ° C; in this example, when the glass bubbles are discharged, the glass temperature is 10 2 (Pa·s) and the viscosity temperature is 1400 ° C. The anti-analytical strength is 161 MPa.
本发明由于氧化钙的含量比例要低很多，而氧化硅的含量比例要高一些，所以本发明析晶速度会比较慢，析晶温度区的上线范围自然降温的条件下，在60-120分钟后，才会在玻璃析晶温度区的上线范围，逐步降温的条件下，的条件下开始析晶。In the present invention, since the content ratio of calcium oxide is much lower, and the content ratio of silicon oxide is higher, the crystallization rate of the present invention is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled under the condition of 60-120 minutes. After that, crystallization will begin under the conditions of the upper line of the glass crystallization temperature zone and the gradual cooling.
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99 以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之1-5.9或6-8以内。比其它玻璃在高温区的热膨胀率的差值低很多；加之本发明本实例软化点大大升高，达765℃；In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million 0.1-0.99 Within the high temperature region of 700 ° C - 740 ° C, the difference in thermal expansion rate is within 1-5.9 or 6-8 parts per million. The difference in thermal expansion rate of the other glass in the high temperature region is much lower; in addition, the softening point of the present invention is greatly increased to 765 ° C;
本发明实施例6： Embodiment 6 of the present invention:
按重量百分比计，其氧化铝含量为20.8％，氧化钠含量为3.2％，氧化硅含量为53％，氧化钙含量为15.5％，氧化镁含量为9.5％，其特征在于：氧化硅含量是氧化钙含量的3.9倍，氧化钙含量是氧化镁含量的1.4倍。In terms of weight percent, the alumina content is 20.8%, the sodium oxide content is 3.2%, the silica content is 53%, the calcium oxide content is 15.5%, and the magnesium oxide content is 9.5%, which is characterized by: the silica content is oxidized. The calcium content is 3.9 times and the calcium oxide content is 1.4 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1510℃；本实例实际玻璃排气泡时粘度温度102(帕·秒)1385℃。抗析强度148Mpa。In this example, the actual melting time is 10 1.5 (Pa·s) viscosity temperature 1510 ° C; in this example, the actual glass discharge bubble viscosity temperature 10 2 (Pa·s) 1385 ° C. The analytical strength is 148 MPa.
本发明由于析晶速度会比较慢，析晶温度区的上线范围自然降温的条件下，在60-90分钟后，才会开始析晶。In the present invention, since the crystallization rate is relatively slow, and the upper line range of the crystallization temperature zone is naturally cooled, crystallization is started after 60-90 minutes.
本发明本实例由于软化点很高，达775℃；The present invention has a high softening point of 775 ° C;
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃和700℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之1-5.9或6-8以内。比其它玻璃在高温区的热膨胀率的差值低很多；In the high temperature range of 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, and the difference between the thermal expansion rates of 650 ° C and 700 ° C in the high temperature range is in parts per million. Within 0.1-0.99, in the high temperature zone 700 ° C - 740 ° C, the difference in thermal expansion rate is within 1-5.9 or 6-8 parts per million. The difference in thermal expansion rate of the other glass in the high temperature region is much lower;
本发明实施例7： Embodiment 7 of the present invention:
按重量百分比计，其氧化铝含量为35.4％，氧化钠含量为2.1％，氧化硅含量为42％，氧化钙含量为12％，氧化镁含量为8.5％，其特征在于：氧化硅含量是氧化钙含量的3.5倍，氧化钙含量是氧化镁含量的1.4倍。In terms of weight percent, the alumina content is 35.4%, the sodium oxide content is 2.1%, the silica content is 42%, the calcium oxide content is 12%, and the magnesium oxide content is 8.5%, which is characterized by: the silica content is oxidized. The calcium content is 3.5 times and the calcium oxide content is 1.4 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1580℃；本实例排气泡时102(帕·秒)粘度温度1425℃。抗析强度213Mpa。In the present example, the actual melting time is 10 1.5 (Pa·s) viscosity temperature 1580 ° C; in this example, the bubble temperature is 10 2 (Pa·s) viscosity temperature 1425 ° C. The anti-segregation strength is 213 MPa.
本发明由于氧化钙(氧化钙含量太高易于析晶，析晶速度还加快)的含量比例要低很多，而氧化硅的含量比例要高一些，所以本发明析晶速度会比较慢，The present invention has a much lower content ratio of calcium oxide (the content of calcium oxide is too high, and the crystallization rate is accelerated), and the content ratio of silicon oxide is higher, so the crystallization rate of the present invention is relatively slow.
析晶温度区的上线范围自然降温的条件下，在60-90分钟后，才会开始析晶。 Under the condition that the upper line of the crystallization temperature zone is naturally cooled, crystallization will start after 60-90 minutes.
本发明本实例软化点很高，达820℃；The softening point of the present invention is as high as 820 ° C;
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之1-5.9或6-8以内。比其它玻璃在高温区的热膨胀率的差值低很多。In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 or 6-8 in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.
本发明实施例8： Embodiment 8 of the present invention:
按重量百分比计，其氧化铝含量为36.5％，氧化钠含量为2.2％，氧化硅含量为40.3％，氧化钙含量为12％，氧化镁含量为9％，其特征在于：氧化硅含量是氧化钙含量的3.35倍，氧化钙含量是氧化镁含量的1.3倍。In terms of weight percent, the alumina content is 36.5%, the sodium oxide content is 2.2%, the silica content is 40.3%, the calcium oxide content is 12%, and the magnesium oxide content is 9%, which is characterized by: the silica content is oxidized. The calcium content is 3.35 times and the calcium oxide content is 1.3 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1630℃；本实例排气泡时102(帕·秒)粘度温度1415℃。抗析强度221Mpa。In the present example, the actual melting time is 10 1.5 (Pa·s) viscosity temperature 1630 ° C; in this example, the bubble temperature is 10 2 (Pa·s) viscosity temperature 1415 ° C. The analytical strength is 221 MPa.
本发明析晶速度会比较慢，析晶温度区的上线范围自然降温的条件下，在60-150分钟后，才会开始析晶。The crystallization rate of the invention will be relatively slow, and the crystallization of the upper line of the crystallization temperature zone will naturally begin after 60-150 minutes.
本发明本实例软化点很高，达830℃。The softening point of the present example of the present invention is as high as 830 °C.
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之1-5.9以内。比其它玻璃在高温区的热膨胀率的差值低很多。In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.
本发明实施例9：(优选无碱产品例)Inventive Example 9: (preferably an alkali-free product example)
按重量百分比计，其氧化铝含量为16.6％，氧化钠含量为0.3％，氧化硅含量为59.3％，氧化钙含量为13.8％，氧化镁含量为10％，其特征在于：氧化硅含量是氧化钙含量的4.3倍，氧化钙含量是氧化镁含量的1.38倍。 In terms of weight percent, the alumina content is 16.6%, the sodium oxide content is 0.3%, the silica content is 59.3%, the calcium oxide content is 13.8%, and the magnesium oxide content is 10%, which is characterized by: the silica content is oxidized. The calcium content is 4.3 times and the calcium oxide content is 1.38 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1580℃；本实例排气泡时102(帕·秒)粘度温度1460℃；抗析强度134Mpa。In this example, the actual melting time is 10 1.5 (Pa·s) viscosity temperature 1580 ° C; in this example, 10 2 (Pa·s) viscosity temperature is 1460 ° C; the anti-segregation strength is 134 Mpa.
本发明析晶速度会比较慢，析晶温度区的上线范围自然降温的条件下，在60-150分钟后，才会开始析晶。The crystallization rate of the invention will be relatively slow, and the crystallization of the upper line of the crystallization temperature zone will naturally begin after 60-150 minutes.
本发明本实例软化点很高，达810℃。The softening point of this example of the present invention is very high, up to 810 °C.
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之1-5.9以内。比其它玻璃在高温区的热膨胀率的差值低很多。In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.
本发明实施例10：(优选无碱产品例)Inventive Example 10: (preferably an alkali-free product example)
按重量百分比计，其氧化铝含量为17.8％，氧化钠含量为0.3％，氧化硅含量为59.3％，氧化钙含量为12.51％，氧化镁含量为10％，其特征在于：氧化硅含量是氧化钙含量的4.7倍，氧化钙含量是氧化镁含量的1.26倍。In terms of weight percent, the alumina content is 17.8%, the sodium oxide content is 0.3%, the silica content is 59.3%, the calcium oxide content is 12.51%, and the magnesium oxide content is 10%, which is characterized by: the silica content is oxidized. The calcium content is 4.7 times and the calcium oxide content is 1.26 times the magnesium oxide content.
本实例实际溶化时101.5(帕·秒)粘度温度1620℃；本实例排气泡时102(帕·秒)粘度温度1480℃；抗析强度138Mpa。In the present example, the actual melting time is 10 1.5 (Pa·s) viscosity temperature 1620 ° C; in this example, 10 2 (Pa·s) viscosity temperature is 1480 ° C; the anti-segregation strength is 138 Mpa.
本发明析晶速度会比较慢，析晶温度区的上线范围自然降温的条件下，在60-150分钟后，才会开始析晶。The crystallization rate of the invention will be relatively slow, and the crystallization of the upper line of the crystallization temperature zone will naturally begin after 60-150 minutes.
本发明本实例软化点很高，达830℃。The softening point of the present example of the present invention is as high as 830 °C.
本实例能使先有对比技术的已知热膨胀差值的性能得到实质性的改进和提高：先有对比技术其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。This example can substantially improve and improve the performance of the known thermal expansion difference of the prior art: the difference in thermal expansion between 600 ° C and 650 ° C in the high temperature region at 550 ° C to 600 ° C. At 1-2.8 or 1-3 parts per million.
本实例在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之1-5.9以内。比其它玻璃在高温区的热膨胀率的差值低很多。 In the high temperature zone 600 ° C - 650 ° C, the difference between the thermal expansion rate of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, in the high temperature range 650 ° C -700 ° C, the difference in thermal expansion rate is in the million Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate is much lower than that of other glasses in the high temperature region.
从上述本发明10实施例，分析本发明如何发现新性质，产生技术效果，克服先有对比技术[1].[2].[3]的缺陷。From the above-described 10 embodiments of the present invention, it is analyzed how the present invention discovers new properties, produces technical effects, and overcomes the drawbacks of the prior art [1].[2].[3].
先有对比技术[1].[2].[3]，其组成，与本发明有交叉、又不完全相同：There is a comparative technique [1].[2].[3] whose composition is different from the present invention and is not identical:
(1)、先有对比技术[1]：本发明人的先有发明：有高退火点及环保节能减排的高强度高平整度低粘度特征的平板玻璃的应用及相关部件，专利号201110060944.4，(1), prior contrast technology [1]: The inventor's prior invention: the application of high-strength, high-level, low-viscosity flat glass with high annealing point and environmental protection and energy saving, and related components, patent number 201110060944.4 ,
(2)、先有对比技术之[2]：本发明人的201510161553.61，一种具有低热膨胀系数的平板玻璃及其制备工艺。(2) First comparative technology [2]: The inventor's 201510161553.61, a flat glass having a low coefficient of thermal expansion and a preparation process thereof.
(3)、先有对比技术之[3]：本发明人的201410408822.3，一种冷却部防析晶方法生产的平板玻璃，(3), prior art [3]: Inventor's 201410408822.3, a flat glass produced by the anti-crystallization method of the cooling portion,
包括本发明与这[1].[2].[3]类玻璃材料，都不同程度的具有两面性的玻璃材料性质的特征：Including the present invention and the glass materials of [1].[2].[3], both of which have different characteristics of the properties of the two-sided glass material:
一面是，这类特定成分的玻璃在强析晶温度范围时DSC曲线中结晶峰尖锐，玻璃从液态向析晶失透转化时间短并速度快，存在易于在冷却工艺段析晶失透的技术难点。On the one hand, the glass of this specific composition has sharp crystallization peaks in the DSC curve at the strong crystallization temperature range, and the conversion time of the glass from liquid to crystallization devitrification is short and fast, and there is a technical difficulty in crystallization and devitrification in the cooling process.
另一面是，又不同程度的具有多种优秀的玻璃材料特征。On the other hand, there are a variety of excellent glass material features to varying degrees.
先有对比技术[1]技术方案中：氧化硅的含量是氧化钙含量的1.9倍-4.1倍，氧化钙的含量是氧化镁的含量的1.0倍-1.8倍；In the first comparative technology [1] technical solution: the content of silicon oxide is 1.9 times -4.1 times the content of calcium oxide, and the content of calcium oxide is 1.0 times -1.8 times the content of magnesium oxide;
先有对比技术[2]技术方案中：氧化硅的含量是氧化钙含量的4.11倍-5.48倍，氧化钙的含量是氧化镁的含量的0.8倍-1.99倍；In the prior art [2] technical solution: the content of silicon oxide is 4.11 times - 5.48 times of the content of calcium oxide, and the content of calcium oxide is 0.8 times - 1.99 times of the content of magnesium oxide;
先有对比技术[3]技术方案中：氧化硅的含量是氧化钙的1.6-5.8倍、氧化钙的含量是氧化镁的0.8--2.1倍；In the prior art [3] technical solution: the content of silicon oxide is 1.6-5.8 times that of calcium oxide, and the content of calcium oxide is 0.8--2.1 times of magnesium oxide;
本发明属于一种化学产品新用途发明：技术方案中：氧化硅的含量是氧化钙含量的2.51倍-4.8倍，氧化钙的含量是氧化镁的含量的1.0倍-1.8倍；The invention belongs to a new use invention of a chemical product: in the technical solution, the content of silicon oxide is 2.51 times to 4.8 times of the content of calcium oxide, and the content of calcium oxide is 1.0 times to 1.8 times of the content of magnesium oxide;
可见，先有对比技术[1].[2].[3]其组成，与本发明有交叉、又不完全相同：It can be seen that the composition of the prior art [1].[2].[3] is intersected and not identical to the present invention:
[1]区别是：对比技术[2]的1.9倍-4.1倍的前端1.9-2.5倍和对比技术[4]的1.6-5.8倍的前端1.6-2.5倍，在本发明范围外。 [1] The difference is: 1.9 times -4.1 times the front end of the technique [2] 1.9-2.5 times and 1.6-5.8 times the front end of the contrast technique [4] 1.6-2.5 times, outside the scope of the present invention.
[2]区别是：对比技术3的4.11倍-5.48倍的后端4.81倍-5.48倍，对比技术4的1.6-5.8倍的后端4.81倍-5.8倍，在本发明范围外。[2] The difference is: 4.11 times - 5.48 times of the back end of technology 3 is 4.81 times - 5.48 times, and the back end of the technique 4 is 4.81 times - 5.8 times of 1.6 - 5.8 times, which is outside the scope of the present invention.
[3]区别是：对比技术3.4技术方案中：氧化钙的含量是氧化镁的0.8倍-1.99倍；0.8--2.1倍；前、后端都大于本发明1.0倍-1.8倍范围。[3] The difference is: in the technical solution of Comparative Technology 3.4: the content of calcium oxide is 0.8 times to 1.99 times of magnesium oxide; 0.8--2.1 times; both the front and the back end are larger than the range of 1.0 times to 1.8 times of the present invention.
本发明属于一种化学产品新用途发明：The invention belongs to a new invention invention of chemical products:
发现了技术方案中，尤其是在氧化硅是氧化钙的2.51倍-4.8倍；氧化钙是氧化镁1.0倍-1.8倍；的范围时，产生了新的[a.低析晶速度]材料性质；对已知化合物的巳知的[b.高温区热膨胀系数的差值]及[c.软化点]和[d.低粘度与高铝含量下的铝、硅、钙、镁的共熔体的性质]和产生的各种效果。比较先有对比技术[1].[2].[3]，都有实质性的改进和提高。(见实施例1-10)It was found that in the technical solution, especially when the silica is 2.51 to 4.8 times that of calcium oxide; the calcium oxide is 1.0 to 1.8 times of the magnesium oxide; a new [a. low crystallization rate] material property is produced. Known to known compounds [b. difference in thermal expansion coefficient in high temperature zone] and [c. softening point] and [d. co-melt of aluminum, silicon, calcium and magnesium at low viscosity and high aluminum content The nature] and the various effects produced. Compared with the prior art [1].[2].[3], there are substantial improvements and improvements. (See Examples 1-10)
对处于本发明的技术方案的，在氧化硅是氧化钙的2.51倍-4.8倍；氧化钙是氧化镁1.0倍-1.8倍的范围时，发现的上述的a.b.c.d这4个性质，和由于这4个性质产生的，有实质性的改进和提高各种效果；先有对比技术[1].[2].[3]，技术方案中，没有发现和揭示。For the technical solution of the present invention, when the silicon oxide is 2.51 times to 4.8 times that of calcium oxide; when the calcium oxide is 1.0 times to 1.8 times of the magnesium oxide, the above four properties of abcd are found, and The nature of the production, there are substantial improvements and improve various effects; first comparative technology [1]. [2]. [3], technical solutions, no discovery and disclosure.
而先有对比技术[1].[2].[3]，技术方案中，处于本发明的技术方案的，在氧化硅是氧化钙的2.51倍-4.8倍；氧化钙是氧化镁1.0倍-1.8倍的范围的前、后端之外的技术方案，则不能具有[形成对上述的a.b.c.d这4个性质和产生的各种效果，有实质性的改进和提高]，都会存在若干缺陷：However, in the prior art [1].[2].[3], in the technical solution, in the technical solution of the present invention, the silicon oxide is 2.51 times-4.8 times that of calcium oxide; the calcium oxide is 1.0 times of magnesium oxide- The technical solutions other than the front and back ends of the 1.8-fold range cannot have [the formation of the above four properties of abcd and the various effects produced, and substantial improvements and improvements], and there are several defects:
[a]如：[a] such as:
而先有对比技术[1].[2].[3]，技术方案中：如对比技术[2]的4.11倍-5.48倍的后端4.81倍-5.48倍，对比技术[3]的1.6-5.8倍的后端4.81倍-5.8倍，在本发明范围外时，会造成：[d.低粘度与高铝含量下的铝、硅、钙、镁的共熔体的性质不存在的结果；First, there is a comparative technology [1].[2].[3], in the technical solution: 4.11 times - 5.48 times of the back end of the comparison technology [2] 4.81 times - 5.48 times, compared with 1.6 of the comparison technology [3] 5.8 times the back end of 4.81 times -5.8 times, outside the scope of the present invention, may result in: [d. the low viscosity and high aluminum content of the aluminum, silicon, calcium, magnesium co-melt properties are not present;
见对比实施例2：See Comparative Example 2:
对比实施例2：对比技术[3]的技术方案的氧化硅含量是氧化钙含量的4.11倍-5.48倍的后端4.81倍-5.48倍，；对比技术[4]的1.6-5.8倍的后端4.81倍-5.8倍范围中：对比实施例2的[氧化硅含量是氧化钙含量的5.3倍的对比例]。在本发明氧化硅含量是氧化钙含量的2.51-4.8倍范围外。 Comparative Example 2: The technical content of the comparative technique [3] has a silica content of 4.11 times to 5.48 times of the calcium oxide content of 4.11 times to 5.48 times, and a back end of 1.6 to 5.8 times of the comparative technique [4]. In the range of 4.81 times to 5.8 times: Comparative Example 2 [Comparative Example of SiO2 content which is 5.3 times of calcium oxide content]. The silica content of the present invention is outside the range of 2.51 to 4.8 times the calcium oxide content.
对比实施例2：按重量百分比计，其氧化铝含量为20％，氧化钠含量为1％，氧化硅含量为58％，氧化钙含量为11％，氧化镁含量为10％，其特征在于：[氧化硅含量是氧化钙含量的5.3倍]，氧化钙含量是氧化镁含量的1.1倍。实际溶化时101.5(帕·秒)粘度温度太高，采用美国THETA旋转高温粘度计仪测不出；本实例排气泡时102(帕·秒)粘度温度1610℃[比钙钠玻璃排气泡时102(帕·秒)粘度温度1430℃还髙180℃；在大生产时难于排出气泡；Comparative Example 2: In terms of weight percent, the alumina content was 20%, the sodium oxide content was 1%, the silica content was 58%, the calcium oxide content was 11%, and the magnesium oxide content was 10%, which was characterized by: [The content of silicon oxide is 5.3 times that of calcium oxide], and the content of calcium oxide is 1.1 times that of magnesium oxide. When the actual melting time is 10 1.5 (Pa·s), the viscosity temperature is too high, which can not be measured by the US THETA rotary high-temperature viscometer; in this example, the bubble temperature is 10 2 (Pa·s) viscosity temperature is 1610 ° C [than calcium sodium glass row When the bubble is 10 2 (Pa·s), the viscosity temperature is 1430 ° C and 髙 180 ° C; it is difficult to discharge bubbles during large production;
可见对比例2在氧化铝含量仅20％时的粘度温度就这么差，沒百高铝含量下的铝、硅、钙、镁的共熔体的性质。也根本不可能把氧化铝含量加到25-39％，而实现大生产；根本不可能实现180-240Mpa强度的目的。It can be seen that the viscosity temperature of Comparative Example 2 at an alumina content of only 20% is so poor that there is no eutectic property of aluminum, silicon, calcium, and magnesium at a high aluminum content. It is also impossible to add the alumina content to 25-39% to achieve large production; it is impossible to achieve the 180-240 MPa strength.
[b]如：[b]如:
而先有对比技术[1].[2].[3]，技术方案中：如对比技术2的1.9倍-4.1倍的前端1.9-2.5倍和对比技术4的1.6-5.8倍的前端1.6-2.5倍，在本发明范围外时，会造成：对已知化合物的巳知的[a.析晶速度材料性质加快]的结果；The first comparison technology [1].[2].[3], the technical solution: such as 1.9 times -4.1 times the front end of the comparison technology 2 1.9-2.5 times and the front end of the comparative technology 4 1.6-5.8 times 1.6- 2.5 times, outside the scope of the present invention, results in a known knowledge of known compounds [a. faster crystallization rate of material properties];
见对比实施例1：See Comparative Example 1:
对比实施例1：此为先有对比技术[2]技术方案的氧化硅含量是氧化钙含量的1.9倍-4.1倍的前端1.9-2.5倍，和对比技术[4]的1.6-5.8倍的前端1.6-2.5倍范围中，的1.9-2.5倍范围中的，[氧化硅含量是氧化钙含量的2.0倍的对比例]。在本发明氧化硅含量是氧化钙含量的2.51-4.8倍范围外。Comparative Example 1: This is the prior art [2] technical solution, the silicon oxide content is 1.9 times -4.1 times the front end of the calcium oxide content is 1.9-2.5 times, and the front end of the comparative technology [4] is 1.6-5.8 times. In the range of 1.9-2.5 times in the range of 1.6-2.5 times, [the silica content is a comparative example of 2.0 times the calcium oxide content]. The silica content of the present invention is outside the range of 2.51 to 4.8 times the calcium oxide content.
对比实施例1：按重量百分比计，其氧化铝含量为20％，氧化钠含量为8％，氧化硅含量为38％，氧化钙含量为19％，氧化镁含量为15％，其特征在于：[氧化硅含量是氧化钙含量的2.0倍]，氧化钙含量是氧化镁含量的1.3倍。Comparative Example 1: In terms of weight percent, the alumina content was 20%, the sodium oxide content was 8%, the silica content was 38%, the calcium oxide content was 19%, and the magnesium oxide content was 15%, which was characterized by: [The content of silicon oxide is 2.0 times that of calcium oxide], and the content of calcium oxide is 1.3 times that of magnesium oxide.
实际溶化时101.5(帕·秒)粘度温度1440℃；本实例排气泡时102(帕·秒)粘度温度1330℃；The actual melting time is 10 1.5 (Pa·s) viscosity temperature 1440 ° C; in this example, 10 2 (Pa·s) viscosity temperature is 1330 ° C;
抗析强度136Mpa。The anti-semination strength is 136 Mpa.
对比实施例1，软化点很低，为710℃。In Comparative Example 1, the softening point was very low at 710 °C.
对比实施例1：析晶速度会比较快，在玻璃析晶温度区的上线范围，逐步降温的条件下，在10-31分钟内，就会开始析晶。所以在大生产中产生重大的难点；因冷却部的底部、边角，或在成型前的玻璃液区域，就是加了加热装置和测温装 置，但由于因测到温度点到开始加热的加热时间差和玻璃液流动性的不稳，在大生产中，会因析晶速度太快，产生局部析晶，也会造成生产平板玻璃的困难。Comparative Example 1: The crystallization rate will be relatively fast, and in the upper line range of the glass crystallization temperature zone, under gradual cooling conditions, crystallization will begin within 10 to 31 minutes. Therefore, it has great difficulties in large production; because of the bottom of the cooling part, the corners, or the glass area before the molding, the heating device and the temperature measuring device are added. However, due to the difference in heating time from the temperature point to the start of heating and the instability of the fluidity of the molten glass, in the large production, the crystallization rate is too fast, causing local crystallization, which also causes difficulty in producing flat glass. .
对比实施例1：在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。Comparative Example 1: In the high temperature region 550 ° C - 600 ° C, the difference in thermal expansion rate at 600 ° C - 650 ° C is 1-2.8 or 1-3 parts per million.
比本发明在高温区600℃-650℃时，600℃和650℃热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区700℃-740℃时，热膨胀率的差值在百万分之1-5.9以内。比本发明平板玻璃在高温区的热膨胀率的差值低很多。Compared with the present invention, in the high temperature region of 600 ° C - 650 ° C, the difference between the thermal expansion rates of 600 ° C and 650 ° C is within 0.1-0.99 parts per million, and in the high temperature range 650 ° C - 700 ° C, the difference in thermal expansion rate is Within the range of 0.1-0.99, the difference in thermal expansion rate is in the range of 1-5.9 parts per million in the high temperature range of 700 ° C to 740 ° C. The difference in thermal expansion rate of the flat glass in the high temperature region is much lower than that of the present invention.
所以，不能提升平板玻璃在防火、隔火、隔热浪应用中的技术效果。Therefore, the technical effect of the flat glass in the application of fireproof, fireproof and heat insulating waves cannot be improved.
所以不能提升，应用于对玻璃有极高的耐严酷高温要求的各种显示器电子玻璃、显示器低温多晶硅工艺、和卷对卷电子玻璃工艺等用途中，因为在高温区的玻璃体积急速变大而产生爆裂的技术效果。Therefore, it cannot be improved, and it is applied to various display electronic glass, display low-temperature polysilicon process, and roll-to-roll electronic glass process which have extremely high temperature resistance requirements for glass, because the glass volume in the high temperature region is rapidly increasing. The technical effect of bursting.
所以不能提升，应用于手机、平板电脑、手提电脑、台式电脑、电视等液晶显示产品电子玻璃和组合发明终端产品用途中，更高分辩率水平的技术效果。Therefore, it cannot be upgraded and is applied to electronic glass products such as mobile phones, tablet computers, laptop computers, desktop computers, televisions, and the like, and the technical effects of higher resolution levels in the use of electronic glass and combined invention terminal products.
本发明属于一种化学产品新用途发明：The invention belongs to a new invention invention of chemical products:
从前述的本发明10实施例可见，发现了新的[a.低析晶速度]材料性质；对已知化合物的巳知的[b.高温区热膨胀系数的差值]及[c.高软化点]和[d.低粘度与高铝含量下的铝、硅、钙、镁的共熔体的性质]和产生的各种效果。比较先有对比技术[1].[2].[3]，都有实质性的改进和提高，综述如下：It can be seen from the foregoing 10 examples of the present invention that a new [a. low crystallization rate] material property is found; a known compound is known [b. difference in thermal expansion coefficient in a high temperature region] and [c. high softening Point] and [d. properties of eutectic of aluminum, silicon, calcium, and magnesium at low viscosity and high aluminum content] and various effects produced. Compared with the prior comparative techniques [1].[2].[3], there are substantial improvements and improvements, as summarized below:
A.本发明在新用途中，发现了新的玻璃产品[低析晶速度]材料性质，这是公知常识中沒有明确的并不能由常识推论得到的；A. In the new application of the present invention, a new glass product [low crystallization rate] material property is found, which is not clear in common knowledge and cannot be inferred from common sense;
因为，本发明产品及先有对比技术[1][2][3][4]都具有析晶温度的上线[最高点]高于成型温度的特点；是具有两面性特征的玻璃材料：一面是，这类特定成分的玻璃在强析晶温度范围时DSC曲线中结晶峰尖锐，玻璃从液态向析晶失透转化较其它玻璃时间短一些并速度快一些；但另一面又具有粘度低及高铝与硅，钙，镁共熔体性质等多种优秀特征；所以为了研究在大生产中如选择性采用具有析晶速度比较慢的玻璃，就有利于在成型前的冷却工作部玻璃液降温工艺阶段，减少析晶的风险； Because the product of the present invention and the prior comparative techniques [1][2][3][4] have the characteristics that the upper line [highest point] of the crystallization temperature is higher than the molding temperature; it is a glass material having two-sided characteristics: one side is The glass of this specific composition has sharp crystal peaks in the DSC curve at the strong crystallization temperature range, and the glass transition from liquid to crystallization devitrification is shorter and faster than other glasses; but the other side has low viscosity and high Aluminum and silicon, calcium, magnesium eutectic properties and other excellent characteristics; so in order to study the selective use of glass with slow crystallization rate in large production, it is beneficial to cool the glass in the cooling working part before molding. Process stage to reduce the risk of crystallization;
因为，须然要求冷却工作部玻璃液的温度，在工艺控制上一定要髙于析晶温度，也会特别在冷却工作部的液线边沿及拐角和底部这些易于析晶的地方增加一些加热控制装置；但是在冷却工作部的拐角和底部的玻璃液，也会有一些流动较慢的在玻璃析晶温度区的上线范围，逐步降温的条件下，析晶速度比较快的产品，(如先有对比技术[1][2][3][4])，玻璃液在10-31分钟内就产生局部析晶，则会有进入成型阶段使平板玻璃出现局部失透的不合格产品的风险；Because it is necessary to cool the temperature of the glass in the working part, the process must be controlled by the crystallization temperature, and some heating control will be added especially in the liquid crystal edge and the corner and bottom which are easy to devitrify in the cooling working part. The device; however, in the glass liquid at the corners and bottom of the cooling working part, there will also be some products that flow slowly in the upper line range of the glass crystallization temperature zone, and the product with faster crystallization rate under the condition of gradual cooling, (such as There are comparative techniques [1][2][3][4]), the glass will produce partial crystallization within 10 to 31 minutes, there will be the risk of unqualified products entering the forming stage and causing partial devitrification of the flat glass. ;
所以应在大生产中，选择性采用本发明的材料性质：[具有析晶速度比较慢的玻璃液在60-150分钟后内玻璃析晶温度区的上线范围，逐步降温的条件下，都不产生析晶的玻璃材料，比先有对比技术先有对比技术[1][2][3][4]的析晶速度要慢5倍，能在冷却部和成型部尤其尤其为浮法工艺及各种平板玻璃工艺，形成极为重要的精确的比先有对比技术好得多的工艺控制参数，从而才能精确的有把握的控制大生产；从而克服成型阶段使平板玻璃出现局部失透的不合格产品的风险；从而制造无任何因析晶而影响透光率的，高质量的本发明的各种平板玻璃；Therefore, in the large-scale production, the material properties of the present invention should be selectively used: [the glass liquid having a relatively slow crystallization rate after 60-150 minutes, the upper line range of the inner glass crystallization temperature zone, under the condition of gradual cooling, The crystallization of the glass material is 5 times slower than that of the prior art prior art [1][2][3][4], which can be especially used in the cooling section and the forming section. And a variety of flat glass processes, forming extremely important and precise process control parameters that are much better than the prior art, so as to accurately control the large production; thus overcoming the partial devitrification of the flat glass during the forming stage. The risk of a qualified product; thereby producing a high quality sheet glass of the present invention without any crystallization due to its influence on light transmittance;
B.本发明针对已知化合物的巳知的[高温区热膨胀系数的差值]及[软化点]性质和效果，有实质性的改进和提高；B. The present invention has substantial improvements and improvements in the known properties of the known compounds [difference in the coefficient of thermal expansion of the high temperature region] and [softening point] properties and effects;
先有对比技术[1][2][3][4]其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3；其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之1-2.8或1-3。而且不能经受650℃-700℃时的高温区和不能700℃-740℃高温区；Prior to the comparison technique [1] [2] [3] [4] in the high temperature zone 550 ° C -600 ° C, the difference in thermal expansion rate between 600 ° C and 650 ° C is 1-2.8 parts per million or 1-3 When it is in the high temperature region of 550 ° C - 600 ° C, the difference in thermal expansion rate between 600 ° C and 650 ° C is 1-2.8 or 1-3 parts per million. Moreover, it cannot withstand the high temperature zone at 650 ° C - 700 ° C and the high temperature zone of 700 ° C - 740 ° C;
本发明，其在高温区550℃-600℃时，600℃-650℃时热膨胀率的差值在百万分之0.1-0.99以内；在更严酷的高温区650℃-700℃时热膨胀率的差值在百万分之0.1-0.99以内，在更严酷的高温区700℃-740℃时热膨胀率的差值在百万分之1-5.9以内；The invention has a difference in thermal expansion rate between 1500 ° C and 600 ° C in a high temperature region of from 1500 ° C to 650 ° C within a range of from 0.1 to 0.99 parts per million; and a thermal expansion rate in a more severe high temperature region of from 650 ° C to 700 ° C. The difference is between 0.1-0.99 parts per million, and the difference in thermal expansion rate is between 1-5.9 parts per million in the harsher high temperature zone 700 °C-740 °C;
先有对比技术[1][2][3][4]揭示的软化点只为720℃；本发明揭示的软化点只为750-860℃。The softening point disclosed by the prior art [1] [2] [3] [4] is only 720 ° C; the softening point disclosed in the present invention is only 750-860 ° C.
正因为本发明针对[高温区热膨胀系数的差值]及[软化点]性质和效果，有实质性的改进和提高。 The present invention is substantially improved and improved in view of the [difference in the coefficient of thermal expansion of the high temperature region] and the [softening point] properties and effects.
所以本发明玻璃，在应用于：[1]汽车用玻璃；建筑用玻璃；船用玻璃；铁道车厢用玻璃；飞机玻璃；防火、防爆用玻璃；特种玻璃；[2]墙地面用彩釉玻璃装饰板；[3]各种玻璃傢俱；[4]太阳能玻璃应用产品等用途领域时，碰到火灾或高温时，则不易于因在高温区的玻璃体积急速变大而爆裂，能在高温区状态下不能保持玻璃的形状；比较先有对比技术[1][2][3][4]有提升防火、隔火、隔热浪的技术效果的作用；Therefore, the glass of the invention is applied to: [1] automotive glass; architectural glass; marine glass; railway car glass; aircraft glass; fireproof, explosion-proof glass; special glass; [2] wall ground with glazed glass decoration Plate; [3] various glass furniture; [4] solar glass application products and other fields of use, when encountering fire or high temperature, it is not easy to burst due to the rapid increase of the glass volume in the high temperature zone, can be in the high temperature zone state The shape of the glass cannot be maintained; the comparative technology [1][2][3][4] has the effect of improving the technical effect of fire prevention, fire separation and heat insulation;
应用于对玻璃有极高的耐严酷高温要求的各种显示器电子玻璃、显示器低温多晶硅工艺、和卷对卷电子玻璃工艺等用途中，比较先有对比技术[1][2][3][4]，不易因为在高温区的玻璃体积急速变大而产生爆裂；有提升技术水平的技术效果的作用。It is applied to various display electronic glass, display low-temperature polysilicon process, and roll-to-roll electronic glass process, which have extremely high resistance to severe high temperature. The comparison technology is first [1][2][3][ 4], it is not easy to cause bursting due to the rapid increase of the glass volume in the high temperature zone; it has the effect of improving the technical level of the technical effect.
C.正因为本发明针对[高温区热膨胀系数的差值]及[软化点]性质和效果，比较先有对比技术[1][2][3][4]有实质性的改进和提高：C. Because the present invention is directed to the [difference in the coefficient of thermal expansion of the high temperature region] and the [softening point] properties and effects, there are substantial improvements and improvements in the comparison techniques [1][2][3][4].
所以，为更高分辩率水平的手机、平板电脑、手提电脑、台式电脑、电视等液晶显示产品电子玻璃和组合发明终端产品用途中，提供了根本的高分辩率水平的技术支撑。Therefore, it provides a fundamental high-resolution technical support for the use of electronic glass and combined invention terminal products for liquid crystal display products such as mobile phones, tablet computers, laptop computers, desktop computers, and televisions with higher resolution levels.
本发明，代表着高分辩率水平的电子液晶显示玻璃和组合发明终端产品技术发展趋势。The invention represents a technical development trend of electronic liquid crystal display glass and combined invention terminal products with high resolution level.
[D].本发明把低粘度与高铝含量下的铝、硅、钙、镁的共熔体的性质]和产生的各种效果，有实质性的改进和提高：[D]. The present invention provides substantial improvements and improvements in the properties of the eutectic of aluminum, silicon, calcium, and magnesium at low viscosity and high aluminum content.
先有对比技术[1][2][3][4]在实施例中，从来没有揭示本发明在氧化硅是氧化钙的2.51倍-4.8倍；氧化钙是氧化镁1.0倍-1.8倍的范围时，氧化铝超过25％或28％的方案，从来没有揭示抗折强度达到180-240Mpa的技术效果。Prior art [1] [2] [3] [4] In the examples, it has never been revealed that the present invention is 2.51 to 4.8 times that of silicon oxide as calcium oxide; calcium oxide is 1.0 to 1.8 times that of magnesium oxide. In the range, the alumina exceeds 25% or 28%, and the technical effect of the flexural strength of 180-240 MPa has never been revealed.
比较本发明人的先有对比技术[1][2][3][4]的任何实施例和其几十个样品都没有揭示超过抗折强度为180Mpa；所以先有对比技术[1][2][3][4]沒有揭示，本发明发现的有实质性的改进和提高的[低粘度温度和高铝含量下的铝、硅、钙、镁的共熔体的优秀性质和强度性质]后，本发明有实施例揭示(见本发明实施例中有10个为此范围；其中4个超过先有对比技术[1][2][3][4]的抗折强度60-180Mpa；达192Mpa、或221Mpa、或213Mpa、或228Mpa)；所以本发明把先有对 比技术[1][2][3][4]抗折强度顶点从180Mpa，实质性的改进和提高到抗折强度顶点240Mpa。Comparing any of the prior art techniques [1] [2] [3] [4] of the present inventors and its dozens of samples did not reveal that the flexural strength exceeded 180 MPa; therefore, there was a comparative technique [1] [ 2][3][4] does not reveal that the present invention has substantially improved and improved [excellent properties and strength properties of eutectic of aluminum, silicon, calcium and magnesium at low viscosity temperature and high aluminum content] After that, the present invention discloses an embodiment (see 10 in the embodiment of the present invention for this range; 4 of them exceed the flexural strength of the prior comparative technique [1][2][3][4] by 60-180 MPa. ; up to 192Mpa, or 221Mpa, or 213Mpa, or 228Mpa); so the invention will be first Than the technique [1][2][3][4] the flexural strength apex from 180Mpa, substantial improvement and improvement to the flexural strength apex 240Mpa.
所以，本发明在平板玻璃应用中的产品，也比本发明人先有比较技术[1][2][3][4]强度实质性的改进和提高了1/3倍；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。Therefore, the product of the present invention in the application of flat glass is also substantially improved and improved by 1/3 times compared with the inventors of the prior art [1][2][3][4]; The flexural strength of the boron-containing glass is increased by about 3 times, which is about 3 times higher than that of the existing aluminum-containing 12-15% touch screen glass, and about 5 times higher than the calcium-sodium glass bending strength of 50 MPa.
本发明同样强度下也比本发明人先有比较技术[1][2][3][4]轻薄1/3倍；比现有TFT含硼玻璃可轻薄3倍；比传统钠钙玻璃瓶可轻薄5倍；The same strength of the present invention is also 1/3 times lighter than the prior art [1][2][3][4]; it is 3 times lighter than the existing TFT boron-containing glass; compared with the conventional soda lime glass bottle Light and thin 5 times;
a.能克服传统平板玻璃应用中的产品太重太厚不便于使用的重大缺陷；a. It can overcome the major defects of the products in the traditional flat glass application that are too heavy and too thick to be easy to use;
b、本发明平板玻璃和终端组合发明产品的应用中，抗折强度实质性的改进和提高，在非常广泛的平板玻璃用途中，在发明内容中表述了各种非显而易见的技术效果。b. In the application of the invented product of the flat glass and the terminal of the present invention, the flexural strength is substantially improved and improved, and in a very wide range of flat glass applications, various non-obvious technical effects are expressed in the Summary of the Invention.
(4)、先有发明之4：本发明人的：201110060913.9，一种高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃。(4) Prior Invention 4: The inventor's: 201110060913.9, a high-annealing high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass.
此先有技术，沒有指出本发明发现的[软化点性质]；也沒有指出本发明发现的[高温区热膨胀系数的差值]的实质性的改进和提高，；也沒有指出本发明发现的[抗折强度性质]的实质性的改进和提高；也没有揭示本发明在彩釉平板玻璃用途中产生的多种予料不到的技术效果。This prior art does not indicate the [softening point property] found by the present invention; nor does it indicate the substantial improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature region] found in the present invention; nor does it indicate the findings of the present invention [ Substantial improvements and improvements in the flexural strength properties; nor the various unexpected technical effects of the present invention in the use of glazed flat glass.
(5)先有对比技术之5：(5) There is a comparison technology 5:
首先对比例，日本国际公开01/034531专利技术方案范围，与本发明不是同一的技术方案范围。First of all, the scope of the technical solution of the Japanese International Publication No. 01/034531 is not the same as the scope of the technical solution of the present invention.
(6)、先有对比技术之6：(6), prior to the comparison of technology 6:
针对对比例US005925583A专利技术要术的比例关系：Proportional relationship to the patented technology of the comparative US005925583A:
范围技术方案与本发明技术要术的比例关系范围技术方案，与本发明不相同的说明：Scope of the technical solution and the technical scope of the present invention, the technical solution is different from the description of the present invention:
(7)先有发明之：(7) First invention:
针对美国专利通报US3929497(1975年12月30日)专利。U.S. Patent No. 3,929,497 (December 30, 1975) patent.
此专利名称就是：适用于纤维生产的可结晶玻璃The patent name is: crystallizable glass for fiber production
(4)、先有发明之4： (4), the first invention 4:
首先对比例，日本国际公开01/034531专利技术方案范围，与本发明不是同一的技术方案范围。First of all, the scope of the technical solution of the Japanese International Publication No. 01/034531 is not the same as the scope of the technical solution of the present invention.
范围技术方案与本发明技术要术的比例关系范围技术方案，与本发明不相同的说明：Scope of the technical solution and the technical scope of the present invention, the technical solution is different from the description of the present invention:
先有对比技术(5).(6).(7)，其组成与本发明在某些其它组成也有多处不同；There are comparative techniques (5).(6).(7), the composition of which differs from the present invention in some other compositions;
最主耍的是，就是若有先有对比技术，其能作为一个与本新用途发明接近的巳知化学产品；但因为本发明发现了新的产品性质和对其原有的性质有实质性的改进和提高；而且产生的非显而易见的技术效果。所以本发明有实质性的创造性。The main thing is that if there is a prior art, it can be used as a chemical product close to this new invention; but because the invention discovers the nature of the new product and its original properties are substantial. Improvements and improvements; and the resulting non-obvious technical effects. Therefore, the present invention is substantially inventive.
本发明属于一种化学产品新用途发明；本发明的发明特点和发明目的概述：The present invention pertains to a novel use of a chemical product; an overview of the inventive features and objects of the invention:
这些不同用途领域中，发现了新的性质，并利用这些性质，产生的予料不到的技术效果简述如下：In these different fields of use, new properties are discovered, and the technical effects that are produced using these properties are briefly described as follows:
(一)(One)
本发明，代表着高分辩率水平的电子液晶显示玻璃和电子液晶显示组合发明终端产品技术发展的趋势。The invention represents a trend in the development of the technology of the end product of the electronic liquid crystal display glass and the electronic liquid crystal display combination invention with high resolution level.
本发明由于发现了有实质性的改进和提升的--[高温区热膨胀系数的差值](即高温下的热膨胀差值性能)及[高软化点的材料性质]；从而利用这些性质，在更高分辩率水平的手机、平板电脑、手提电脑、台式电脑、电视等液晶显示产品电子玻璃和组合发明终端产品用途中，产生了提升产品分辩率水平的予料不到的技术效果。The present invention has found substantial improvements and improvements - [difference in coefficient of thermal expansion in high temperature regions] (i.e., difference in thermal expansion at high temperatures) and [material properties at high softening points]; thereby utilizing these properties, In the use of electronic glass and combined invention terminal products for liquid crystal display products such as mobile phones, tablets, laptops, desktop computers, and televisions with higher resolution levels, there is an unexpected technical effect of improving the product resolution level.
这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。The nature of these new discoveries and the unpredictable technical effects of using these new properties are also unclear in common sense and cannot be inferred from common sense.
也没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4]公开过)；It has not been disclosed by all prior art comparison techniques (including those not disclosed by the prior art [1][2][3][4];
所以，应判断本发明有实质性的进步性和创造性。Therefore, it should be judged that the present invention is substantially progressive and inventive.
1.现有技术难点：TFT-LCD基板玻璃在高温区550℃-630℃时热膨胀率的差值，一般要在百万分之6左右；但钠钙玻璃高温区550℃-600℃时热膨胀率的差值，在百万分之20；如果在对角线40英寸的TFT-LCD彩色液晶屏，产生了百万分之6-20的不适当收缩，就会因为其粘度，弹性特点变化很大而产生弯曲，不规则变 形，和热收缩；就会产生TFT-LCD基板玻璃表面上的某些像素点与前面的彩色滤光膜与偏光片产生对不上的问题，产生液晶屏出现若干黑点的品质问题。1. Difficulties in the prior art: the difference in thermal expansion rate of the TFT-LCD substrate glass in the high temperature region of 550 ° C to 630 ° C is generally about 6 parts per million; but the thermal expansion of the soda lime glass high temperature region at 550 ° C to 600 ° C The difference in rate is 20 parts per million; if the 40-inch diagonal TFT-LCD color LCD screen produces an improper shrinkage of 6-20 parts per million, it will change due to its viscosity and elastic characteristics. Large and curved, irregular Shape, and heat shrinkage; there will be problems with certain pixel points on the surface of the TFT-LCD substrate glass and the front color filter film and polarizer, resulting in quality problems with several black spots on the LCD screen.
TFT-LCD液晶玻璃对内外性能和及寸要求都十分苛刻，TFT-LCD与集成电路蕊片要求相同，甚至于比IC蕊片更严格。因为电路和半导体是在基板玻璃表面形成的，所以需要有同硅片相同或更高的精度。而基板玻璃高温区热膨胀系数的差值越小性质，则越能提高成品率，越能生产高分辩率显示器产品。反之，因为高温区热膨胀系数的差值越大性质，其粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩；就会产生TFT-LCD基板玻璃表面上的某些像素点与前面的彩色滤光膜与偏光片产生对不上的问题，产生液晶屏出现若干黑点的品质问题。TFT-LCD liquid crystal glass is very demanding both internal and external performance and inch requirements. TFT-LCD has the same requirements as integrated circuit chip, even more stringent than IC chip. Since the circuit and the semiconductor are formed on the surface of the substrate glass, it is required to have the same or higher precision as the silicon wafer. The smaller the difference in the thermal expansion coefficient of the high temperature region of the substrate glass, the higher the yield and the higher the resolution display product. On the contrary, because the difference in the coefficient of thermal expansion of the high temperature region is greater, the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; some pixel points on the surface of the TFT-LCD substrate glass are generated. The front color filter film and the polarizer produce a problem that is not good, resulting in a quality problem of several black spots on the liquid crystal panel.
而现有不论先进的低温多晶硅工艺，和所有TFT-LCD工艺在基板玻璃表面加工二极管，薄膜晶体管等为每个相素位提供开关的工艺，这时加热工艺过程的最髙温度为625℃，这就给现有传统基板玻璃造成非常高的难度，因为现有传统TFT-LCD基板玻璃在高温区550℃-630℃时热膨胀率的差值，一般要在百万分之6左右，给加热工艺过程的最髙温度为625℃，只提供了很窄的工艺控制范围。只提供了可以生产低水平清晰度，分辨率约[100-200ppi--即薄膜晶体管每平方英寸的像素位约100-200个]的显示器产品的技术支撑；However, regardless of the advanced low-temperature polysilicon process, and all TFT-LCD processes, the processing of diodes on the surface of the substrate glass, thin film transistors and the like provide a switching process for each phase, and the final temperature of the heating process is 625 ° C. This poses a very high difficulty for the existing conventional substrate glass, because the difference in thermal expansion rate of the conventional TFT-LCD substrate glass in the high temperature region of 550 ° C to 630 ° C is generally about 6 parts per million for heating. The final temperature of the process is 625 ° C, which provides only a narrow process control range. Only provides technical support for display products that can produce low-level resolution with a resolution of approximately [100-200 ppi - that is, about 100-200 pixels per square inch of thin film transistors);
而且由于只能提供了很窄的550℃-630℃时工艺控制范围，在基板玻璃表面加工二极管，薄膜晶体管等为每个相素位提供开关的工艺，所以生产效率和成品率不太好。Moreover, since only a narrow process control range of 550 ° C - 630 ° C is provided, a diode, a thin film transistor, etc. are provided on the surface of the substrate glass to provide a switching process for each phase, so the production efficiency and the yield are not so good.
2.现有技术难点：现有技术本发明人2011年先有对比技术2难点：现有技术本发明先有对比技术2上述难点，有一点进步，主要把高温区材料性质，从的550℃-630℃上升到600℃-650℃；又把热膨胀率的差值从百万分之6左右，缩小到百万分之2-3范围。从而比传统技术，新提供了的工艺控制范围的进步；因为在经过600-650℃之间的急加温，把导电层的薄膜晶体管烧结到TFT-LCD液晶玻璃面之上时，提供了高温区热膨胀系数的更小的差值性质，可以生产高一些的清晰度，分辨率[约400-600ppi--即薄膜晶体管每平方英寸的像素位约400-600个]的显而器产品的技术支撑的技术效果；但由于只能提供600℃-650℃时工艺控制范围，在 基板玻璃表面加工二极管，薄膜晶体管等为400-600ppi-相素位提供开关的工艺，所以生产效率和成品率有缺陷。2. Prior Art Difficulties: The prior art inventors have prior art in 2011. Difficulties in prior art: The prior art has the above difficulties in comparison with the prior art 2, with a little progress, mainly taking the material properties of the high temperature zone from 550 ° C. -630 ° C rose to 600 ° C -650 ° C; and the difference in thermal expansion rate from about 6 parts per million, to 2-3 parts per million range. Therefore, compared with the conventional technology, the newly provided process control range is improved; because the thin film transistor of the conductive layer is sintered above the TFT-LCD liquid crystal glass surface after the rapid heating between 600-650 ° C, the high temperature is provided. The smaller difference in the coefficient of thermal expansion of the region can produce higher definition resolution, and the resolution [about 400-600 ppi - that is, the pixel position of the thin film transistor per square inch is about 400-600] Technical effect of support; but since it can only provide process control range from 600 °C to 650 °C, The substrate glass surface processing diode, thin film transistor, etc. provide a switching process for the 400-600 ppi-phase position, so the production efficiency and the yield are defective.
3.本发明，因为高温区热膨胀系数的差值及高软化点的材料性质，有实质性的改进和提高，在新用途中产生的新效果：3. The present invention, because of the difference in the coefficient of thermal expansion in the high temperature region and the material properties of the high softening point, there is substantial improvement and improvement, and new effects in new applications:
因为TFT-LCD液晶玻璃对内外性能和及寸要求都十分苛刻，TFT-LCD与集成电路蕊片要求相同，甚至于比IC蕊片更严格。因为电路和半导体是在基板玻璃表面形成的，所以需要有同硅片相同或更高的精度。而基板玻璃高温区热膨胀系数的差值性质越小[总间距偏差性能性质越小]，则越能提高成品率，越能生产高分辩率显示器产品。Because TFT-LCD liquid crystal glass is very demanding both internal and external performance and inch requirements, TFT-LCD has the same requirements as integrated circuit chip, even more stringent than IC chip. Since the circuit and the semiconductor are formed on the surface of the substrate glass, it is required to have the same or higher precision as the silicon wafer. The smaller the difference property of the thermal expansion coefficient of the high temperature region of the substrate glass is, the smaller the total pitch deviation performance property is, the higher the yield can be, and the higher the resolution display product can be produced.
反之，因为高温区热膨胀系数的差值越大性质，其粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩；就会产生TFT-LCD基板玻璃表面上的某些像素点与前面的彩色滤光膜与偏光片产生对不上的问题，产生液晶屏出现若干黑点的品质问题。On the contrary, because the difference in the coefficient of thermal expansion of the high temperature region is greater, the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; some pixel points on the surface of the TFT-LCD substrate glass are generated. The front color filter film and the polarizer produce a problem that is not good, resulting in a quality problem of several black spots on the liquid crystal panel.
在电子玻璃用途中，因为是优选的本发明技术中的TFT无碱产品，所以其高温区热膨胀系数的差值--即在更严酷的高温区650℃-700℃时热膨胀率的差值在百万分之0.1-0.99以内，700℃-740℃时热膨胀率的差值在百万分之1-5.9以内，都具有高于一切先有对比技术的性能；In the use of electronic glass, since it is a preferred non-alkali product of the TFT in the present technology, the difference in thermal expansion coefficient of the high temperature region, that is, the difference in thermal expansion rate in the more severe high temperature region of 650 ° C to 700 ° C is Within 0.1-0.99 parts per million, the difference in thermal expansion rate between 700 °C and 740 °C is within 1-5.9 parts per million, which has higher performance than all prior art comparison techniques;
[1]本发明新提供了的工艺控制范围的进步：因为在经过650-700℃或700-740℃之间的急加温，把导电层的薄膜晶体管烧结到TFT-LCD液晶玻璃面之上时，提供了提供了更高温区热膨胀系数的更小的差值性质，现有技术为百万分之6左右；本发明总间距偏差性能为百万分之0.1-0.9；比先有对比技术热膨胀差值小几倍(即总间距偏差性能性能稳定)；所以可以生产高清晰度，分辨率[约800-1600ppi--即薄膜晶体管每平方英寸的像素位约800-1600个]的显而器产品的技术支撑的，非显而易见的高清晰度，高分辨率，产生了非显而易见的技术效果。[1] An advancement in the range of process control newly provided by the present invention: since a thin film transistor of a conductive layer is sintered onto a TFT-LCD liquid crystal glass surface by a rapid heating between 650-700 ° C or 700-740 ° C At the time, a smaller difference property is provided which provides a coefficient of thermal expansion in a higher temperature zone, the prior art is about 6 parts per million; the total pitch deviation performance of the present invention is 0.1-0.9 parts per million; compared with the prior art The difference in thermal expansion is several times smaller (ie, the total pitch deviation performance is stable); therefore, it is possible to produce high definition, resolution [about 800-1600 ppi--that is, the pixel position of the thin film transistor per square inch is about 800-1600]. The technical support of the product, non-obvious high definition, high resolution, produces non-obvious technical effects.
[2]本发明能因在650-700℃和700-740℃严酷髙温工艺条件下，有出色的总间距偏差性能(即高温下的热膨胀差值性能)，现有技术为百万分之6左右；本发明总间距偏差性能为百万分之0.1-0.9；比先有对比技术热膨胀差值小几倍(即 总间距偏差性能性能稳定)；所以工艺的控制范围加大；可加快生产节奏，提高面板的产能，和有更髙合格率的，非显而易见的技术效果。[2] The present invention can have excellent total pitch deviation performance (i.e., thermal expansion difference performance at high temperature) under severe temperature conditions of 650-700 ° C and 700-740 ° C, and the prior art is in parts per million. 6 or so; the total pitch deviation performance of the present invention is 0.1-0.9 parts per million; several times smaller than the difference of the prior art thermal expansion (ie, The total pitch deviation performance is stable); therefore, the control range of the process is increased; the production rhythm can be accelerated, the production capacity of the panel can be improved, and the non-obvious technical effect is obtained with a higher yield.
从而为更高分辩率水平的手机、平板电脑、台式电脑、电视等液晶显示产品电子玻璃及组合发明终端产品用途中，提供了根本的技术支撑、代表着高分辩率水平的电子液晶显示玻璃技术发展趋势。Therefore, it provides the fundamental technical support and electronic liquid crystal display glass technology representing high resolution level for the use of electronic glass and combined invention terminal products of liquid crystal display products such as mobile phones, tablet computers, desktop computers and televisions with higher resolution levels. development trend.
本发明有析晶速度慢的材料性质非显而易见的技术效果：本发明析晶温度区的上线范围并在指定的仪器中的自然降温的条件下，在45分钟-1，5小时后，开始析晶，有析晶速度慢的特征；这能在冷却部和成型部尤其尤其为浮法工艺及各种平板玻璃工艺，形成极为重要的精确的比先有对比技术好得多的工艺控制参数，从而才能精确的有把握的控制大生产。从而制造无任何因析晶而影响透光率的，高质量的本发明电子液晶显示玻璃平板玻璃；产生了非显而易见的技术效果。The invention has the technical effect that the material property of the crystallization rate is slow, which is not obvious: the upper line range of the crystallization temperature zone of the invention is under the condition of natural cooling in the designated instrument, and the analysis starts after 45 minutes - 1 hour and 5 hours. Crystal, which has the characteristics of slow crystallization rate; this can form extremely important and precise process control parameters in the cooling section and the forming section, especially for the float process and various flat glass processes, which are much more important than the prior art. In order to accurately control the large production. Thus, the high-quality electronic liquid crystal display glass plate glass of the present invention without any crystallization due to the influence of crystallization is produced; and a non-obvious technical effect is produced.
(二)(two)
本发明，代表着轻薄化、高强度、高耐磨的电子液晶显示玻璃和组合发明终端产品的技术发展趋势。The invention represents the technical development trend of the thin and light, high-strength, high-wear-resistant electronic liquid crystal display glass and the combined invention terminal product.
本发明由于发现了有实质性的改进和提升的，抗折强度材料性质；从而利用这些性质，在触摸屏电子玻璃和TFT电子玻璃，及手机、平板电脑、手提电脑、台式电脑、电视等，液晶显示的组合发明终端产品用途中，实质性的改进和提髙了轻薄化、高强度、高耐磨的予料不到的技术效果。The present invention has found substantial improvements and enhancements in the properties of the flexural strength material; thereby utilizing these properties, in touch screen electronic glass and TFT electronic glass, and mobile phones, tablet computers, laptop computers, desktop computers, televisions, etc., liquid crystal In the use of the combined invention terminal product shown, the substantial improvement and the technical effect of the light weight, high strength and high wear resistance are not improved.
这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。The nature of these new discoveries and the unpredictable technical effects of using these new properties are also unclear in common sense and cannot be inferred from common sense.
也没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4]公开过)；It has not been disclosed by all prior art comparison techniques (including those not disclosed by the prior art [1][2][3][4];
所以，应判断本发明有实质性的进步性和创造性。Therefore, it should be judged that the present invention is substantially progressive and inventive.
由于本发明，把先有对比，技术[1][2][3][4]抗折强度顶点从180Mpa，实质性的改进和提高到抗折强度顶点240Mpa。As a result of the present invention, the prior art, [1] [2] [3] [4] flexural strength apex is improved from 180 Mpa, and substantially improved to a flexural strength apex of 240 MPa.
所以，本发明在平板玻璃应用中的产品，也比本发明人先有比较技术[1][2][3][4]强度实质性的改进和提高了1/3倍；比现有TFT含硼玻璃抗折强度80 Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；Therefore, the product of the present invention in the application of flat glass is also substantially improved and improved by 1/3 times compared with the inventors of the prior art [1][2][3][4]; Boron-containing glass bending strength 80 Mpa is increased by about 3 times; it is about 2.4 times higher than the existing 12-15% aluminum touch screen glass flexural strength 100Mpa; it is about 2.4 times higher than the existing aluminum-containing 12-15% touch screen glass bending strength 100Mpa. ;
本发明同样强度下也比本发明人先有比较技术[1][2][3][4]轻薄1/3倍；比现有TFT含硼玻璃可轻薄3倍；比现有触摸屏玻璃轻薄2.4倍；The invention is also lighter and thinner than the prior art [1][2][3][4] at the same intensity; it is 3 times lighter than the existing TFT boron-containing glass; lighter than the existing touch screen glass 2.4 times;
在触摸屏电子玻璃和TFT电子玻璃，及手机、平板电脑、手提电脑、台式电脑、电视等，液晶显示的组合发明终端产品用途中，实质性的改进和提髙了轻薄化、高强度、高耐磨技术效果。In touch screen electronic glass and TFT electronic glass, and mobile phone, tablet computer, laptop computer, desktop computer, TV, etc., the combination of liquid crystal display and invention terminal products, substantial improvement and improvement of lightness, high strength and high resistance Grinding technology effect.
(三)(three)
本发明为处于困难的研发期的卷对卷液晶显示新工艺，解决根本难题：The invention is a new process of roll-to-roll liquid crystal display in a difficult development period, solving the fundamental problem:
本发明由于发现了有实质性的改进和提升的[高温区热膨胀系数的差值]及[高软化点]及[抗折强度]的材料性质；从而利用这些性质，使处于困难的研发期的卷对卷液晶显示新工艺的难点能得到克服，产生了本发明能使面板生产方式巅覆性变革，使高效率、降成本、轻薄化、高分辫率新的面板卷对卷的生产工艺，能进入高成品合格率的大生产阶段，有予料不到的技术效果。The present invention has found substantial improvement and improvement of [difference in coefficient of thermal expansion coefficient in high temperature region] and material properties of [high softening point] and [reduction strength]; thereby utilizing these properties, it is difficult to develop during development The difficulty of the new process of roll-to-roll liquid crystal display can be overcome, and the production process of the panel roll-to-roll which can make the panel production mode change and the high efficiency, cost reduction, lightness and thinness and high branching rate are produced. It can enter the large production stage of high finished product qualification rate, and there are unexpected technical effects.
这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。The nature of these new discoveries and the unpredictable technical effects of using these new properties are also unclear in common sense and cannot be inferred from common sense.
也没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4]公开过)；It has not been disclosed by all prior art comparison techniques (including those not disclosed by the prior art [1][2][3][4];
所以，应判断本发明有实质性的进步性和创造性。Therefore, it should be judged that the present invention is substantially progressive and inventive.
现有的TFT-LCD液晶显示面板卷对卷的生产工艺，是处于困难的研发期、。The production process of the existing TFT-LCD liquid crystal display panel roll-to-roll is in a difficult development period.
要达到在更严酷的高温区的急加温工艺阶段，把导电层的薄膜晶体管烧结到TFT-LCD 0.1-0.2mm的很薄的卷对卷的玻璃面之上时，要解决的重大难题是：To achieve a critical heating process in the harsher high temperature region, when the thin film transistor of the conductive layer is sintered onto the thin glass-to-roll glass surface of the TFT-LCD 0.1-0.2 mm, the major problem to be solved is :
a.现有液晶玻璃材料，不能承受一定严酷的高温的性质，在导电层的薄膜晶体管烧结到TFT-LCD 0.1-0.2mm的很薄的液晶玻璃面之上后，会因为长距离的卷对卷收放工艺的强大张力而变型。存在卷对卷收卷后，下工序放卷为平板产品切材时，已经把导电层的薄膜晶体管烧结到TFT-LCD的液晶玻璃也因平面变型不合格，而不能进入下工序的液晶面板生产的重大难题；a. The existing liquid crystal glass material can not withstand the severe high temperature properties. After the thin film transistor of the conductive layer is sintered onto the thin liquid crystal glass surface of the TFT-LCD 0.1-0.2mm, it will be due to the long distance winding pair. The strong tension of the roll retracting process is modified. After the roll-to-roll winding is completed, when the lower process is unwound to cut the flat product, the thin film transistor of the conductive layer has been sintered to the liquid crystal glass of the TFT-LCD, which is also unqualified due to the planar deformation, and cannot enter the liquid crystal panel production of the next process. Major problem
b.在卷对卷的长距离的卷对卷收放工艺生产中，把导电层的薄膜晶体管烧结 到TFT-LCD 0.1-0.2mm的很薄的液晶玻璃面之上；但难于达到薄膜晶体管每平方英寸的像素位约200个分辩率的显而器产品的技术品质，是重大难题；b. Sintering a thin film transistor of a conductive layer in a roll-to-roll long-distance roll-to-roll process It is on the thin LCD glass surface of 0.1-0.2mm of TFT-LCD; however, it is difficult to achieve the technical quality of the display product of about 200 resolutions per square inch of the thin film transistor, which is a major problem;
c要求在卷对卷的工艺生产中，对卷对卷收卷后的0.1-0.2mm的很薄的，已经把导电层的薄膜晶体管烧结到TFT-LCD 0.1-0.2mm的很薄的液晶玻璃面之上液晶玻璃；[1]或因在卷内因膨胀收缩差值大(现有技术为百万分之6左右)，所以在严酷的烧结温度已接近先有对比技术玻璃的转化点温度，而产生粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩。[2]或因玻璃的软化点低在加温时***，而在卷对卷收放工艺中因很强的的张力而变型。[3]或因玻璃的强度差，把变型的部分压裂。c requires a very thin 0.1-0.2mm roll-to-roll after the roll-to-roll process, the thin film transistor of the conductive layer has been sintered to a thin liquid crystal glass of 0.1-0.2mm TFT-LCD Above the surface of the liquid crystal glass; [1] or because of the large difference in expansion and contraction in the coil (the prior art is about 6 parts per million), so the severe sintering temperature is close to the conversion point temperature of the prior art glass. The viscosity is generated, and the elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage. [2] Or because the softening point of the glass is low, it becomes soft when heated, and it is deformed by the strong tension in the roll-to-roll retracting process. [3] Or the part of the variant is fractured due to the difference in strength of the glass.
从而在液晶玻璃卷对卷收卷后，在卷中因收卷必须较紧而产生的卷中0.1-0.2mm的很薄的玻璃，因变型而不平整而在收卷正常的压力下，把变型的部分压裂。所以存在无法形成正常的生产工艺中的重大难题。Therefore, after the liquid crystal glass roll is wound up, the thin glass of 0.1-0.2 mm in the roll which is generated by the winding in the roll is tight, and the deformation is not smooth and under the normal pressure of winding. Partial fracturing of the variant. Therefore, there is a major problem in the formation of a normal production process.
而本发明，因为[高温区热膨胀系数的差值]及[高软化点]及[强度]的材料性质，有实质性的改进和提高，在卷对卷用途中，产生了能克服上述3项难点的新技术效果：However, the present invention has substantial improvement and improvement in material properties of [difference in coefficient of thermal expansion in high temperature region] and [high softening point] and [strength], and in the roll-to-roll application, it is possible to overcome the above three items. Difficult new technology effects:
本发明：this invention:
[1]对在卷对卷的工艺生产中，对卷对卷收卷后的0.1-0.2mm的很薄的，已经把[1] For the roll-to-roll process production, the thin roll of 0.1-0.2mm after the roll-to-roll is wound has been
导电层的薄膜晶体管烧结到TFT-LCD 0.1-0.2mm的很薄的液晶玻璃面之上液晶玻璃，本发明能克服或因在卷内因膨胀收缩差值大(现有技术为百万分之6左右；本发明总间距偏差性能为百万分之0.1-0.9)；本发明不会因严酷的烧结温度已接近先有对比技术玻璃的转化点温度，而产生粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩；而可克服传传材料不能进入下工序的液晶面板生产的重大难题。The thin film transistor of the conductive layer is sintered to the liquid crystal glass above the very thin liquid crystal glass surface of the TFT-LCD 0.1-0.2 mm, and the present invention can overcome or have a large difference due to expansion and contraction in the coil (the prior art is 6 parts per million) The total pitch deviation performance of the present invention is 0.1-0.9 parts per million); the present invention does not cause viscosity due to the severe sintering temperature, which is close to the conversion point temperature of the prior art glass, and the elastic characteristics vary greatly. Bending, irregular deformation, and heat shrinkage; can overcome the major problem of the production of liquid crystal panels that cannot pass the material into the next process.
[2]而且有比先有对比技术髙得多的达可优选达800-860℃软化点性质(而先[2] and there is a much higher than the first comparative technology, up to 800-860 ° C softening point properties (and first
有技术加热温度仅630℃，本发明就是上升加热温度为650-700-740℃，也大大低于800-860℃软化点；所以不会因为长距离的卷对卷收放工艺的强大张力而变型或因玻璃的软化点低，在加温时***，而在卷对卷收放工艺中因很强的的张力而变型；而可克服传传材料的液晶面板的重大难题。 The technical heating temperature is only 630 ° C, the invention is that the rising heating temperature is 650-700-740 ° C, and is also much lower than the softening point of 800-860 ° C; therefore, it is not because of the strong tension of the long-distance roll-to-roll retracting process. The modification or the low softening point of the glass is softened when heated, and is changed by the strong tension in the roll-to-roll retracting process; and the major problem of the liquid crystal panel of the transmitted material can be overcome.
[3]因玻璃的[抗折强度]的材料性质，有实质性的改进和提高：比传统用于卷[3] Substantial improvement and improvement due to the material properties of the [flexural strength] of glass: more than traditional
对卷试制的TFT玻璃的只100mpa的强度，本发明人的先有对比技术[2]最高为180mpa的强度；而本发明可达240mpa的强度；所以本发明能克服，在卷中因收卷必须较紧而产生的卷中0.1-0.2mm的很薄的玻璃，因变型而不平整而在收卷正常的压力下，把变型的部分压裂的重大难题。For the strength of only 100 mpa of the trial-produced TFT glass, the inventors' prior art [2] has a strength of up to 180 mpa; and the present invention can reach a strength of 240 mpa; therefore, the present invention can overcome the winding in the roll. A very thin glass of 0.1-0.2 mm in a tightly produced roll, which is not flattened due to the deformation, is a major problem of fracturing the deformed portion under normal pressure of winding.
所以，都能克服处于研发阶段的卷对卷工艺中的上述难题：Therefore, it is possible to overcome the above problems in the roll-to-roll process in the development stage:
a.本发明能克服：存在卷对卷收卷后，下工序放卷为平板产品切材时，已经把导电层的薄膜晶体管烧结到TFT-LCD的液晶玻璃也因平面变型不合格，而不能进入下工序的液晶面板生产的重大难题；产生了非显而易见的技术效果。a. The invention can be overcome: when there is a roll-to-roll winding, when the lower process is unwinding into a flat product, the thin film transistor which has been sintered to the TFT-LCD liquid crystal glass is also unqualified due to the planar deformation, and cannot A major problem in the production of liquid crystal panels entering the next process; producing non-obvious technical effects.
b.本发明能克服：在液晶玻璃卷对卷收卷后，在卷中因收卷必须较紧而产生的卷中0.1-0.2mm的很薄的玻璃，因变型而不平整而在收卷正常的压力下，把变型的部分压裂，所以存在无法形成正常的生产工艺中的重大难题；产生了非显而易见的技术效果。b. The invention can be overcome: after the liquid crystal glass roll is wound up, the thin glass of 0.1-0.2 mm in the roll which is generated due to the tight winding in the roll, is not flattened due to the deformation. Under normal pressure, the deformed part is fractured, so there is a major problem that cannot be formed in a normal production process; a non-obvious technical effect is produced.
本发明能克服处于研发阶段的卷对卷工艺中的的上述难题：The present invention overcomes the above-mentioned problems in the roll-to-roll process at the development stage:
c.在卷对卷的长距离的卷对卷收放工艺生产中，把导电层的薄膜晶体管烧结c. Sintering a thin film transistor of a conductive layer in a roll-to-roll long-winding roll-to-roll process
到TFT-LCD 0.1-0.2mm的很薄的液晶玻璃面之上；但难于达到薄膜晶体管每平方英寸的像素位约200个分辩率的显而器产品的技术品质，是重大难题；It is on the thin LCD glass surface of 0.1-0.2mm of TFT-LCD; however, it is difficult to achieve the technical quality of the display product of about 200 resolutions per square inch of the thin film transistor, which is a major problem;
卷对卷工艺中，必需借助加温工序，把导电层的薄膜晶体管烧结到TFT-LCD的液晶玻璃上，但是现有技术的这个处理过程的温度是600-630℃，是根据现有技术的TFT-LCD的液晶玻璃的总间距偏差性能(即高温下的热膨胀差值性能)550-630℃来确定的；In the roll-to-roll process, the thin film transistor of the conductive layer must be sintered to the liquid crystal glass of the TFT-LCD by means of a heating process, but the temperature of this process of the prior art is 600-630 ° C, which is according to the prior art. The total pitch deviation performance of the liquid crystal glass of the TFT-LCD (ie, the difference in thermal expansion at high temperature) is determined by 550-630 ° C;
因为TFT-LCD液晶玻璃对内外性能和及寸要求都十分苛刻，TFT-LCD与集成电路蕊片要求相同，甚至于比IC蕊片更严格。因为电路和半导体是在基板玻璃表面形成的，所以需要有同硅片相同或更高的精度。而基板玻璃高温区热膨胀系数的差值性质越小[总间距偏差性能性质越小]，则越能提高成品率，越能生产高分辩率显示器产品。Because TFT-LCD liquid crystal glass is very demanding both internal and external performance and inch requirements, TFT-LCD has the same requirements as integrated circuit chip, even more stringent than IC chip. Since the circuit and the semiconductor are formed on the surface of the substrate glass, it is required to have the same or higher precision as the silicon wafer. The smaller the difference property of the thermal expansion coefficient of the high temperature region of the substrate glass is, the smaller the total pitch deviation performance property is, the higher the yield can be, and the higher the resolution display product can be produced.
反之，因为高温区热膨胀系数的差值越大性质，其粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩；就会产生TFT-LCD基板玻璃表面上的某些像 素点与前面的彩色滤光膜与偏光片产生对不上的问题，产生液晶屏出现若干黑点的品质问题。On the contrary, because the difference in the coefficient of thermal expansion of the high temperature region is greater, the viscosity and elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage; some images on the surface of the TFT-LCD substrate glass are generated. The prime point and the front color filter film and the polarizer produce a problem that does not occur, resulting in a quality problem of several black spots on the liquid crystal panel.
因为处理过程的温度如髙于630℃，就会超过现有技术液晶玻璃的总间距偏差性能(即在630℃高温下的热膨胀差值百万分之6左右的性能)，就会产生因为高温区热膨胀系数的液晶玻璃的总间距偏差性能[热膨胀系数差值性质不达要求]，其粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩；就会产生TFT-LCD基板玻璃表面上的某些像素点与前面的彩色滤光膜与偏光片产生对不上的问题，产生液晶屏出现若干黑点的品质问题。Because the temperature of the process, such as 髙 630 ° C, will exceed the total pitch deviation performance of the prior art liquid crystal glass (that is, the difference in thermal expansion at a high temperature of 630 ° C is about 6 parts per million), resulting in high temperature The total pitch deviation performance of the liquid crystal glass with thermal expansion coefficient [the coefficient of thermal expansion coefficient is not up to standard], the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; TFT-LCD substrate glass is produced. Some of the pixels on the surface are inconsistent with the front color filter film and the polarizer, resulting in quality problems with several black spots on the LCD screen.
本发明，因为高温区热膨胀系数的差值的材料性质的液晶玻璃材料：本发明能在比传统的技术的550-630℃或600-650℃的温度条件，有更髙的650-700℃和700-740℃严酷髙温工艺条件下工作；本发明能克服或因在卷内因膨胀收缩差值大的性质(现有技术为百万分之6左右；本发明总间距偏差性能为百万分之0.1-0.9)比先有对比技术热膨胀差值小几倍(即总间距偏差性能性能稳定)有更出色的总间距偏差性能；所以本发明不会因严酷的烧结温度已接近先有对比技术玻璃的转化点温度，而产生粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩；所以本发明，不只工艺的控制范围加大，更具有能承受一定严酷的高温的性质要求在卷对卷的长距离的卷对卷收放工艺生产中，把导电层的薄膜晶体管烧结到TFT-LCD 0.1-0.2mm的很薄的液晶玻璃面之上，能达到薄膜晶体管每平方英寸的像素位约200个分辩率的显而器产品的技术品质目的，更能达到更髙水平的每平方英寸的像素位800--1600分辩率的显而器产品的技术品质目的，本发明能克服重大难题；产生了非显而易见的技术效果。The present invention, because of the difference in thermal expansion coefficient of the high temperature region, the material properties of the liquid crystal glass material: the present invention can be more 650-700 ° C and at a temperature of 550-630 ° C or 600-650 ° C than the conventional technology. Working at 700-740 ° C under severe temperature conditions; the present invention can overcome or have a large difference in expansion shrinkage due to expansion in the coil (the prior art is about 6 parts per million; the total pitch deviation performance of the present invention is in parts per million) 0.1-0.9) has a better total pitch deviation performance than the prior art thermal expansion difference (that is, the total pitch deviation performance is stable); therefore, the present invention is not close to the prior art due to the severe sintering temperature. The transformation point temperature of the glass produces viscosity, and the elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage; therefore, the invention not only has a wider control range but also has the property of being able to withstand certain severe high temperatures. In the roll-to-roll long-winding roll-to-roll process, the thin film transistor of the conductive layer is sintered onto the thin liquid crystal glass surface of 0.1-0.2mm of TFT-LCD, which can achieve the flatness of the thin film transistor. The square inch pixel position is about 200 resolutions. The technical quality of the product is designed to achieve a more ambiguous level of pixel quality per square inch of 800-1600 resolution. The invention overcomes major problems; it produces non-obvious technical effects.
本发明产生的主要的非显而易见的技术效果是：The main non-obvious technical effects produced by the present invention are:
本发明能使处于困难的研发期的TFT-LCD显示面板卷对卷的生产工艺，能克服重大难题，进行大生产阶段；本发明能使面板生产方式巅覆性变革，产生高效率、降成本、轻薄化、高分辫率新的面板生产方式；代表着高水平的电子液晶显示玻璃和液晶显示组合发明终端产品的技术发展趋势。The invention can make the production process of the TFT-LCD display panel roll-to-roll in the difficult development period overcome the major problems and carry out the large production stage; the invention can make the panel production mode change, generate high efficiency and reduce cost. The new panel production method with light weight and high distribution rate represents the technical development trend of the invention of high-level electronic liquid crystal display glass and liquid crystal display combined terminal products.
(四)(four)
本发明能为低温多晶硅液晶显示技术新工艺，解决重大难题： The invention can be a new technology of low temperature polysilicon liquid crystal display technology and solve major problems:
本发明由于发现了有实质性的改进和提升的[高温区热膨胀系数的差值]及[高软化点]及[抗折强度]的材料性质；从而利用这些性质，能为低温多晶硅液晶显示技术新工艺，解决TFT-LCD的液晶玻璃的总间距偏差性能差、在经激光照射后也有平板玻璃变型、成品率不高、液晶显示技术分辩率不髙的重大难题，有予料不到的技术效果。The present invention finds substantial improvement and improvement of [difference in thermal expansion coefficient in high temperature region] and material properties of [high softening point] and [reduction strength]; thereby utilizing these properties, it can be a low temperature polycrystalline silicon liquid crystal display technology The new technology solves the problem that the total pitch deviation performance of the liquid crystal glass of the TFT-LCD is poor, the flat glass is deformed after the laser irradiation, the yield is not high, and the resolution of the liquid crystal display technology is not bad, and there is an unexpected technology. effect.
这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。The nature of these new discoveries and the unpredictable technical effects of using these new properties are also unclear in common sense and cannot be inferred from common sense.
也没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4]公开过)；It has not been disclosed by all prior art comparison techniques (including those not disclosed by the prior art [1][2][3][4];
所以，应判断本发明有实质性的进步性和创造性。Therefore, it should be judged that the present invention is substantially progressive and inventive.
a.低温多晶硅技术新工艺难题1：a. Low-temperature polysilicon technology new process problem 1:
低温多晶硅技术新工艺中，必需借助一道激光照射工序，才能使玻璃基板上的非晶硅结构转变为多晶硅结构。但是现有技术的这个处理过程的温度是600-630℃，是根据现有技术的TFT-LCD的液晶玻璃的总间距偏差性能(即高温下的热膨胀差值性能)550-630℃来确定的；In the new process of low-temperature polysilicon technology, it is necessary to use a laser irradiation process to transform the amorphous silicon structure on the glass substrate into a polysilicon structure. However, the temperature of this process of the prior art is 600-630 ° C, which is determined according to the total pitch deviation performance of the liquid crystal glass of the TFT-LCD of the prior art (ie, the thermal expansion difference performance at high temperature) of 550-630 ° C. ;
因为处理过程的温度如髙于630℃，就会超过现有技术液晶玻璃的总间距偏差性能(即在630℃高温下的热膨胀差值百万分之6左右的性能)，就会产生因为高温区热膨胀系数的液晶玻璃的总间距偏差性能[热膨胀系数差值性质不达要求]，其粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩；就会产生TFT-LCD基板玻璃表面上的某些像素点与前面的彩色滤光膜与偏光片产生对不上的问题，产生液晶屏出现若干黑点的品质问题。Because the temperature of the process, such as 髙 630 ° C, will exceed the total pitch deviation performance of the prior art liquid crystal glass (that is, the difference in thermal expansion at a high temperature of 630 ° C is about 6 parts per million), resulting in high temperature The total pitch deviation performance of the liquid crystal glass with thermal expansion coefficient [the coefficient of thermal expansion coefficient is not up to standard], the viscosity and elastic characteristics vary greatly, resulting in bending, irregular deformation, and heat shrinkage; TFT-LCD substrate glass is produced. Some of the pixels on the surface are inconsistent with the front color filter film and the polarizer, resulting in quality problems with several black spots on the LCD screen.
但是在必需借助的，使玻璃基板上的非晶硅结构转变为多晶硅结构的激光照射工序中，这个630℃的温度，并不能使璃基板上的非晶硅结构转变为多晶硅结构，就是经过产生均匀分布的激光照射后，因作用热能不夠也不能形成很好的非晶硅结构转变为多晶硅结构的成品率效果。成品率不高是主要难题。However, in the laser irradiation process which is necessary to convert the amorphous silicon structure on the glass substrate into the polycrystalline silicon structure, the temperature of 630 ° C does not convert the amorphous silicon structure on the glass substrate into a polycrystalline silicon structure, or is generated. After uniform laser irradiation, the effect of the conversion of the amorphous silicon structure into the polysilicon structure cannot be formed due to insufficient thermal energy. Low yield is the main problem.
b.低温多晶硅技术新工艺难题2：b. Low-temperature polysilicon technology new process problem 2:
低温多晶硅技术新工艺中，在必需借助的，使玻璃基板上的非晶硅结构转变为多晶硅结构的激光照射工序中，因为现有技术的TFT-LCD的液晶玻璃的软化 点低，在经激光照射后也有平板玻璃变型的大量问题产生，是成品率不高的另一个主要难题。In the new process of low-temperature polysilicon technology, in the laser irradiation process necessary to convert the amorphous silicon structure on the glass substrate into a polycrystalline silicon structure, the softening of the liquid crystal glass of the prior art TFT-LCD The low point, a large number of problems with flat glass modification after laser irradiation, is another major problem of low yield.
c.低温多晶硅技术新工艺难题3：c. Low-temperature polysilicon technology new process problem 3:
在低温多晶硅技术新工艺生产中，把导电层的薄膜晶体管烧结到液晶玻璃In the new process of low-temperature polysilicon technology, the thin film transistor of the conductive layer is sintered to the liquid crystal glass.
面之上，因传统的技术在550-630℃高温时的总间距偏差性能(即高温下的热膨胀差值性能)仅是百万分之6左右，只能达到薄膜晶体管每平方英寸的像素位约200个分辩率的显而器产品技术品质，是重大难题；Above the surface, the total pitch deviation performance (that is, the thermal expansion difference performance at high temperature) due to the conventional technology at a high temperature of 550-630 ° C is only about 6 parts per million, and can only reach the pixel position per square inch of the thin film transistor. The technical quality of the product of about 200 resolutions is a major problem;
而本发明，因为高温区热膨胀系数的差值及高软化点的材料性质，有实质性的改进和提高，在低温多晶硅技术用途中，产生了能克服上述3项难点的新技术效果：However, the present invention has substantial improvement and improvement due to the difference in the coefficient of thermal expansion of the high temperature region and the material properties of the high softening point. In the use of the low temperature polysilicon technology, a new technical effect capable of overcoming the above three difficulties is produced:
a.本发明，因为高温区热膨胀系数的差值及高软化点的材料性质的液晶玻a. The present invention, because of the difference in thermal expansion coefficient between the high temperature region and the material properties of the high softening point of the liquid crystal glass
璃材料：[1]本发明能在比传统的技术的550-630℃或600-650℃的温度条件，有更髙的650-700℃和700-740℃严酷髙温工艺条件下工作，並有更出色的总间距偏差性能(即高温下的热膨胀差值性能)，比先有对比技术热膨胀差值小几倍(即总间距偏差性能性能稳定)；[2]而且有比先有对比技术髙得多的达750-860℃软化点性质；Glass material: [1] The invention can work under the conditions of 550-630 ° C or 600-650 ° C of the conventional technology, and has a more severe 650-700 ° C and 700-740 ° C harsh temperature process conditions, and Better overall pitch deviation performance (ie, thermal expansion difference performance at high temperatures), several times smaller than the prior art thermal expansion difference (ie, total pitch deviation performance is stable); [2] and there is a comparison technique Very much 750-860 ° C softening point properties;
所以，对在低温多晶硅技术新工艺中，必需借助一道激光照射工序，才能使玻璃基板上的非晶硅结构转变为多晶硅结构的工艺上，但是现有技术的这个处理过程的温度是600-630℃，升为700-740℃，能根据本发明技术的TFT-LCD的液晶玻璃的总间距偏差性能(即高温下的热膨胀差值性能)700-740℃来确定的；Therefore, in the new process of low-temperature polysilicon technology, it is necessary to use a laser irradiation process to convert the amorphous silicon structure on the glass substrate into a polysilicon structure, but the temperature of the prior art process is 600-630. °C, rise to 700-740 ° C, can be determined according to the total pitch deviation performance of the liquid crystal glass of the TFT-LCD according to the present technology (ie, thermal expansion difference performance at high temperature) 700-740 ° C;
因为处理过程的温度700-740℃，不会超过本发明技术的液晶玻璃的总间距偏差性能(即在700-740℃高温下的热膨胀差值百万分之1-5.9的性能)，就不会产生因为高温区热膨胀系数的液晶玻璃的总间距偏差性能[热膨胀系数差值性质不达要求]，其粘度，弹性特点变化很大而产生弯曲，不规则变形，和热收缩；就不会产生TFT-LCD基板玻璃表面上的某些像素点与前面的彩色滤光膜与偏光片产生对不上的问题，产生液晶屏出现若干黑点的品质问题；Since the temperature of the process is 700-740 ° C, it does not exceed the total pitch deviation performance of the liquid crystal glass of the present invention (that is, the difference in thermal expansion at a high temperature of 700-740 ° C is 1-5.9 parts per million), The total pitch deviation performance of the liquid crystal glass due to the thermal expansion coefficient of the high temperature zone [the coefficient of thermal expansion coefficient difference is not required], and the viscosity and elastic characteristics vary greatly to cause bending, irregular deformation, and heat shrinkage; Certain pixel points on the surface of the TFT-LCD substrate glass are incompatible with the front color filter film and the polarizer, resulting in quality problems of appearing black spots on the liquid crystal panel;
从而在必需借助的，使玻璃基板上的非晶硅结构转变为多晶硅结构的激光照射工序中，这个700-740℃的温度，更能使璃基板上的非晶硅结构转变为多晶硅结 构，经过产生均匀分布的激光照射后，因作用热能大大上升而能形成很好的非晶硅结构转变为多晶硅结构的成品率效果。而克服主要难题；本发明的发现的材料性质，产生了使低温多晶硅技术成品率大大升高的非显而易见的技术效果。代表着高水平的电子液晶显示玻璃和低温多晶硅技术，及液晶显示组合发明终端产品的技术发展趋势。Therefore, in the laser irradiation process which is necessary to convert the amorphous silicon structure on the glass substrate into the polycrystalline silicon structure, the temperature of 700-740 ° C can change the amorphous silicon structure on the glass substrate into the polysilicon junction. After the uniform distribution of the laser light is irradiated, the thermal energy is greatly increased to form a good yield effect of converting the amorphous silicon structure into the polycrystalline silicon structure. Overcoming the main problems; the discovered material properties of the present invention have produced a non-obvious technical effect that greatly increases the yield of low temperature polysilicon technology. It represents the high-level electronic liquid crystal display glass and low-temperature polysilicon technology, and the liquid crystal display combination invention technology development trend of the terminal products.
b.因为本发明技术的TFT-LCD的液晶玻璃的软化点有比先有对比技术髙得多的达750-860℃软化点性质，所以低温多晶硅技术新工艺中，在必需借助的，使玻璃基板上的非晶硅结构转变为多晶硅结构的激光照射工序中，在经激光700-740℃严酷髙温工艺条件下照射后，本发明平板玻璃不会产生变型的问题，成品率能大幅升高，能克服另一个低温多晶硅技术新工艺难题2，产生了非显而易见的技术效果。b. Because the softening point of the liquid crystal glass of the TFT-LCD of the present invention has a softening point property of 750-860 ° C which is much higher than that of the prior art, so in the new process of low-temperature polysilicon technology, it is necessary to make the glass In the laser irradiation process in which the amorphous silicon structure on the substrate is converted into the polycrystalline silicon structure, the plate glass of the present invention does not have a problem of deformation after being irradiated by the laser at a temperature of 700-740 ° C under severe temperature, and the yield can be greatly increased. Can overcome another new low-temperature polysilicon technology process problem 2, resulting in non-obvious technical effects.
b.因为本发明技术的TFT-LCD的液晶玻璃的软化点有比先有对比技术髙得多的达750-860℃软化点性质，所以低温多晶硅技术新工艺中，在必需借助的，使玻璃基板上的非晶硅结构转变为多晶硅结构的激光照射工序中，在经激光700-740℃严酷髙温工艺条件下照射后，本发明平板玻璃不会产生变型的问题，成品率能大幅升高，能克服另一个低温多晶硅技术新工艺难题2，产生了非显而易见的技术效果。b. Because the softening point of the liquid crystal glass of the TFT-LCD of the present invention has a softening point property of 750-860 ° C which is much higher than that of the prior art, so in the new process of low-temperature polysilicon technology, it is necessary to make the glass In the laser irradiation process in which the amorphous silicon structure on the substrate is converted into the polycrystalline silicon structure, the plate glass of the present invention does not have a problem of deformation after being irradiated by the laser at a temperature of 700-740 ° C under severe temperature, and the yield can be greatly increased. Can overcome another new low-temperature polysilicon technology process problem 2, resulting in non-obvious technical effects.
c.本发明，因为高温区热膨胀系数的差值的材料性质的液晶玻璃材料：本发明能在比传统的技术的550-630℃的温度条件，有更髙的650-700℃和700-740℃严酷髙温工艺条件下工作，並有更出色的总间距偏差性能(即高温下的热膨胀差值性能)，比先有对比技术热膨胀差值小几倍，(即总间距偏差性能性能稳定)；所以本发明，不只工艺的控制范围加大，更具有能承受一定严酷的高温的性质要求，把导电层的薄膜晶体管烧结到TFT-LCD 0.1-0.4mm的很薄的液晶玻璃面之上，并能达到薄膜晶体管每平方英寸的像素位约200个分辩率的显而器产品的技术品质目的，和达到更髙水平的每平方英寸的像素位800--1600分辩率的显而器产品的技术品质目的，本发明能克服低温多晶硅技术新工艺难题3；产生了低温多晶硅技术更髙分辩率的非显而易见的技术效果。代表着高水平的电子液晶显示玻璃和液晶显示组合发明终端产品的技术发展趋势。 c. The present invention, because of the difference in thermal expansion coefficient of the high temperature region, the material properties of the liquid crystal glass material: the present invention can be more 650-700 ° C and 700-740 at a temperature of 550-630 ° C than the conventional technology. °C work under severe temperature conditions, and has better overall pitch deviation performance (ie, differential thermal expansion performance at high temperatures), which is several times smaller than the difference in thermal expansion of the prior art (ie, the total pitch deviation performance is stable) Therefore, the invention not only has a larger control range of the process, but also has the requirement of being able to withstand a certain severe high temperature, and the thin film transistor of the conductive layer is sintered on the thin liquid crystal glass surface of the TFT-LCD 0.1-0.4 mm. And can achieve the technical quality of the thin film transistor with a resolution of about 200 resolutions per square inch of the pixel product, and achieve a more advanced level of pixel resolution of 800-1600 resolution per square inch of the product For technical quality purposes, the present invention can overcome the new process problem of low temperature polysilicon technology 3; and produce a non-obvious technical effect of the lower resolution of low temperature polysilicon technology. It represents a high-level electronic liquid crystal display glass and liquid crystal display combination invention technology product development trend.
本发明的发现的材料性质和产生的髙分辩率技术效果，The discovered material properties of the present invention and the resulting 髙 resolution technical effects,
(4)本发明，把先有对比技术[1][2][3][4]抗折强度顶点从180Mpa，实质性的改进和提高到抗折强度顶点240Mpa；比先有对比技术[1][2][3][4]抗折强度实质性的改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。(4) According to the present invention, the first comparative technique [1][2][3][4] has a flexural strength apex from 180 MPa, substantial improvement and improvement to a flexural strength apex of 240 MPa; compared with the prior art [1] ][2][3][4] The flexural strength is substantially improved and improved by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; 12-15% than the existing aluminum containing aluminum The touch screen glass has a flexural strength of 100 Mpa which is increased by about 2.4 times; it is about 5 times higher than that of the calcium sodium glass.
从而能为电子玻璃产品，提供更高强度的产品，或在强度相同时提供轻薄5倍，或轻薄2.5倍，或轻薄1/4的用途；Therefore, it can provide a higher strength product for the electronic glass product, or provide a light and thin 5 times, or a light and thin 2.5 times, or a light and thin 1/4 when the strength is the same;
从而能为手机、平板电脑、手提电脑、台式电脑、电视等液晶显示组合发明终端产品用途中，提供更高强度或轻薄化的效果；Therefore, it can provide higher strength or lighter and thinner effects for the use of a liquid crystal display combination of a mobile phone, a tablet computer, a laptop computer, a desktop computer, a television, and the like;
本发明的技术效果，代表着高水平的电子液晶显示玻璃和液晶显示组合发明终端产品的技术发展趋势。The technical effect of the present invention represents a technical development trend of a high level of electronic liquid crystal display glass and liquid crystal display combined invention terminal products.
(伍)(Wu)
提髙平板玻璃材料和终端产品应用用途的耐高温防火、防爆性能。Improve the high temperature fireproof and explosion-proof performance of flat glass materials and end products.
本发明由于发现了有实质性的改进和提升的[高温区热膨胀系数的差值]及[高软化点]的材料性质；从而利用这些性质，能提髙平板玻璃材料和终端产品应用用途的耐高温防火、防爆性能，有予料不到的技术效果。The present invention has found substantial improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature zone] and the material properties of the [high softening point]; thereby utilizing these properties, it is possible to improve the resistance of the flat glass material and the end product application. High temperature fireproof, explosion-proof performance, there are unexpected technical effects.
这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。The nature of these new discoveries and the unpredictable technical effects of using these new properties are also unclear in common sense and cannot be inferred from common sense.
也没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4]公开过)；It has not been disclosed by all prior art comparison techniques (including those not disclosed by the prior art [1][2][3][4];
所以，应判断本发明有实质性的进步性和创造性。Therefore, it should be judged that the present invention is substantially progressive and inventive.
本发明，因为高温区热膨胀系数的差值及高软化点的材料性质的：The present invention, because of the difference in thermal expansion coefficient of the high temperature region and the material properties of the high softening point:
a.因为高温区热膨胀系数的差值及高软化点750-860℃的材料性质，有实质性的改进和提高：在更严酷的高温区650℃-700℃时热膨胀率的差值在百万分之0.1-0.99以内，在更严酷的高温区700℃-740℃时热膨胀率的差值在百万分之1-5.9或6-8以内。其非显而易见的新技术效果是： a. Because of the difference in thermal expansion coefficient between the high temperature zone and the material properties of the high softening point of 750-860 ° C, there is substantial improvement and improvement: the difference in thermal expansion rate in the more severe high temperature zone 650 ° C -700 ° C is in the millions Within 0.1-0.99, the difference in thermal expansion rate in the more severe high temperature range of 700 ° C - 740 ° C is within 1-5.9 or 6-8 parts per million. Its non-obvious new technology effects are:
大大提升了本发明用作为1.建筑用玻璃；2.汽车用玻璃；3.船用玻璃；4.铁道车厢用玻璃；5飞机玻璃；6.防火、防爆用玻璃；特种玻璃等应用产品用途的耐高温防火、防爆性能；The invention has been greatly improved as 1. glass for construction; 2. glass for automobile; 3. glass for ship; 4. glass for railway car; 5 aircraft glass; 6. glass for fireproofing and explosion-proof; High temperature resistant fireproof and explosion proof performance;
及各种组合发明终端产品如：1.高性能彩釉玻璃傢俱、2.高性能汽車、3.高性能太阳能飞行器、4.高性能太阳能发电装置、等组合发明终端产品应用用途的耐高温防火、防爆性能。And various combinations of invention terminal products such as: 1. high-performance glazed glass furniture, 2. high-performance automotive, 3. high-performance solar aircraft, 4. high-performance solar power generation equipment, and other combined invention end products for high temperature and fire resistance applications Explosion-proof performance.
b.本发明有析晶速度慢的材料性质：非显而易见的技术效果[1]：本发明析晶温度区的上线范围并在指定的仪器中的自然降温的条件下，在45分钟-1，5小时后，才会在玻璃析晶温度区的上线范围，逐步降温的条件下开始析晶，有析晶速度慢的特征；这能在冷却部和成型部尤其尤其为浮法工艺及各种平板玻璃工艺，形成极为重要的精确的比先有对比技术好得多的工艺控制参数，从而才能精确的有把握的控制大生产。从而制造无任何因析晶而影响透光率的，高质量的本发明的上述7种用途的平板玻璃，並为上述的4类组合发明终端产品应用用途提供合格的产品支撑。b. The present invention has a material having a slow crystallization rate: a non-obvious technical effect [1]: the upper line range of the crystallization temperature zone of the present invention and under the condition of natural cooling in a specified instrument, at 45 minutes -1, After 5 hours, the crystallization will start under the condition of the upper line of the glass crystallization temperature zone and gradually lowering the temperature, and the crystallization rate is slow; this can be especially in the cooling part and the forming part, especially the float process and various The flat glass process creates extremely important and precise process control parameters that are much better than the prior art, so that precise production can be controlled with precision and confidence. Thus, the high-quality flat glass of the above seven uses of the present invention, which does not have any crystallinity and which affects the light transmittance, is produced, and provides acceptable product support for the application of the above-mentioned four types of combined invention terminal products.
(六)(six)
本发明由于发现了有实质性的改进和提升的[软化点]性质---“软化点达750-860℃”，和[高温区热膨胀系数的差值]性质---“在更严酷的高温区650℃-700℃时热膨胀率的差值在百万分之0.1-0.99以内，在更严酷的高温区700℃-740℃时热膨胀率的差值在百万分之1-5.9或6-8以内”；The present invention has been found to have substantial improvements and improved [softening point] properties - "softening point up to 750-860 ° C", and [difference in the coefficient of thermal expansion of the high temperature zone] - "in the more severe The difference in thermal expansion between 650 ° C and 700 ° C in the high temperature range is within 0.1-0.99 parts per million, and the difference in thermal expansion rate in the more severe high temperature range of 700 ° C to 740 ° C is 1-5.9 or 6 parts per million. Within -8";
並利用这种材料性质，在各种彩釉平板玻璃的应用的用途中，和多种组合发明终端产品的应用的用途中，产生了予料不到的技术效果。如：By utilizing the properties of this material, unexpected use of technical effects has been produced in the use of various glazed flat glass applications and in the use of various combinations of invented end products. Such as:
(1)一种高性能彩釉平板玻璃的组合发明应用的用途中；一种高性能耐磨彩釉层平板玻璃的组合发明应用的用途中；一种高性能超薄型墙面贴面彩釉平板玻璃的组合发明应用的用途中；一种高性能彩釉玻璃板组合橱柜的组合发明应用的用途中；一种高性能推拉门柜彩釉玻璃面板家俱的组合发明应用的用途中；一种高性能彩釉玻璃板组合衣柜的组合发明应用的用途中；一种高性能彩釉台面玻璃家俱的组合发明应用的用途中；一种高性能彩釉平板玻璃与金属层的复合板的组合发明应用的用途中；一种高性能的、具有在墙面上安装简便结构的、彩 釉玻璃复合材料板的组合发明应用的用途中；一种高性能的、具有易装拆结构的、彩釉玻璃复合材料地板的组合发明应用的用途中；一种采用热变型工艺生产的高性能的彩釉玻璃洗面盆的组合发明应用的用途中；一种采用热变型工艺生产的高性能的彩釉玻璃抬面板和联体的洗面盆的组合发明应用的用途中；一种用于卫生间的高性能彩釉玻璃洗面盆台面板的组合发明应用的用途中；因为产品的[软化点性质]有实质性的提升和改进，和[高温区热膨胀系数的差值]性质的提升和改进。(1) A combination of high-performance color glazed flat glass in the application of the invention; a combination of high-performance wear-resistant glaze flat glass for the application of the invention; a high-performance ultra-thin wall veneer Combination of glazed plate glass for the application of the invention; a combination of a high performance glazed glass plate combination cabinet for the application of the invention; a combination of a high performance sliding door cabinet glazed glass panel furniture; A combination of high-performance color glazed glass panel combination wardrobes for the application of the invention; a combination of high-performance glazed countertop glass furniture for the application of the invention; a combination of a high-performance glazed flat glass and a metal layer composite panel In the use of the invention; a high-performance, color-friendly structure with a simple structure installed on the wall A combination of glazed glass composite panels for use in applications; a high performance, easy to assemble and disassemble, glazed glass composite flooring combination application; a high performance produced by a thermal deformation process Combination of a glazed glass wash basin for the application of the invention; a combination of a high performance glazed glass lifting panel produced by a thermal modification process and a combined wash basin; the use of the invention for a bathroom The combination of high-performance glazed glass washbasin countertops is used in the application of the invention; because of the substantial improvement and improvement of the [softening point property] of the product, and the improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature zone].
所以产生了予料不到的技术效果：在应用场所，本发明在碰到火灾或高温时，尤其比较本人的先有对比技术[1][2][3][4]，在高温区状态下，由于本发明平板玻璃的[更高的软化点]、[更好的高温区热膨胀差值]、[更高的强度等高性能]，可具有保持玻璃的形状，能起到防火、隔火、隔热浪的非显而易见的技术效果；本发明有特别的建材防火防爆效果，将大大增强在高温区的玻璃体积急速变大时抗爆裂的能力，具有非显而易见的技术效果。Therefore, there is an unexpected technical effect: in the application place, the present invention is particularly superior to the prior art [1][2][3][4] in the case of fire or high temperature, in the high temperature zone state. According to the [higher softening point] of the flat glass of the present invention, [better thermal expansion difference in high temperature region], [high performance such as higher strength], the shape of the glass can be maintained, and fireproofing and separation can be achieved. The non-obvious technical effect of fire and heat insulation wave; the invention has special fireproof and explosion-proof effect of building materials, and greatly enhances the ability to resist bursting when the glass volume in the high temperature zone is rapidly increased, and has non-obvious technical effects.
(2)在彩釉平板玻璃用途中，能克服彩釉装饰层，烧结在平板玻璃的工艺难点能：(2) In the use of glazed flat glass, it can overcome the decorative layer of colored glaze and the difficulty in sintering in flat glass:
A.即平板玻璃软化点越低，就会因玻璃热稳定性不好，越易于在彩釉层烧结在平板玻璃的工艺阶段，使平板玻璃产生变型，而这将会产生变型或裂纹或破裂的品质缺陷；A. That is, the lower the softening point of the flat glass, the lower the thermal stability of the glass, the easier it is to sinter the colored glaze layer in the process stage of the flat glass, and the flat glass is deformed, which will cause deformation or crack or crack. Quality defect
B.由于平板玻璃的软化点越低，为了在较低的变型温度以下提供彩釉原料，就越困难，就成本更髙。B. Since the softening point of the flat glass is lower, the more difficult it is to provide the colored glaze raw material below the lower modification temperature, the more costly it is.
C.由于平板玻璃的软化点越低，为了在变型温度以下提供彩釉原料，就越不易发出很好品质的红、兰、绿、黄等色彩，而且彩釉原料的温度越低发色的成本越高。C. Since the softening point of the flat glass is lower, in order to provide the colored glaze raw material below the deformation temperature, it is difficult to emit good quality red, blue, green, yellow and the like, and the lower the temperature of the colored glaze raw material is. The higher the cost.
现有的钠钙平板玻璃的软化点仅525℃；对比文件中本人的先有发明平板玻璃也只发现了软化点最高720℃的材料性质。而本发明发现了软化点达750-860℃的材料性质，所以在一切彩釉平板玻璃用途中，能产生予料不到的：The softening point of the existing soda-lime plate glass is only 525 ° C; the material properties of the soft glass having a softening point of up to 720 ° C have only been found in the prior invention of the flat glass in the comparative document. However, the present invention has found a material having a softening point of 750-860 ° C, so that in all the use of glazed flat glass, it can produce unexpected materials:
1)本发明能使彩釉平板玻璃不产生变型或裂纹或破裂的品质缺陷，有予料不到的技术效果； 1) The invention can make the color glaze flat glass without quality defects of cracking or cracking, and has unexpected technical effects;
2)本发明能克服彩釉原料，因为温度低而成本更髙的难点，有节约生产成本的予料不到的技术效果；2) The invention can overcome the glaze raw materials, because the temperature is low and the cost is more difficult, and there is a technical effect that the production cost is not expected;
3)本发明能克服彩釉原料，因为温度低就越不易发出很好品质的红、兰、绿、黄等色彩的难点，而且能克服彩釉原料的温度越低发色的成本越高的难点；产生更好的品质的红、兰、绿、黄等色彩的予料不到的技术效果，和降彩釉原料成本的予料不到的技术效果。3) The invention can overcome the raw materials of the colored glaze, because the lower the temperature, the more difficult it is to emit the color of red, blue, green, yellow, etc., and the lower the temperature of the raw material of the colored glaze, the higher the cost of color development. Difficulties; the unexpected technical effects of red, blue, green, yellow and other colors that produce better quality, and the unexpected technical effects of reducing the cost of glaze raw materials.
所以，应判断本发明有实质性的进步性和创造性。Therefore, it should be judged that the present invention is substantially progressive and inventive.
与本发明较接近的先有发明之4：对比文件本发明人的：201110060913.9，一种高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃。此先有技术，沒有指出本发明发现的[高软化点性质]的实质性的改进和提高；也沒有指出本发明发现的[高温区热膨胀系数的差值]的实质性的改进和提高；也沒有指出本发明发现的[抗折强度性质]的实质性的改进和提高；Prior Invention 4 which is closer to the present invention: Comparative Document The present inventor: 201110060913.9, a low-melting-point glaze decorative flat glass with high annealing temperature and high strength and environmental protection and energy saving type. This prior art does not indicate a substantial improvement and improvement of the [high softening point property] found by the present invention; nor does it indicate a substantial improvement and improvement of the [difference in the coefficient of thermal expansion of the high temperature region] found by the present invention; Substantial improvements and improvements in the [fracture strength properties] found by the present invention are not indicated;
其也没有揭示本发明利用[高软化点性质]，[高温区热膨胀系数的差值]等新性质，在彩釉平板玻璃应用的用途中和10多种组合发明应用的用途中，产生的多种予料不到的技术效果。It also does not reveal the new properties of the present invention using [high softening point properties], [difference in thermal expansion coefficient in high temperature regions], and in the use of glazed flat glass applications and in the use of more than 10 combined invention applications, Unprecedented technical effects.
而且本化学产品用途发明在各种彩釉平板玻璃新用途中，和多种组合发明终端产品的应用的用途中，利用发现的有实质性的改进和提升的软化点新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。Moreover, the use of the chemical product is invented in various new applications of colored glazed flat glass, and in the application of various combinations of invented end products, using the discovered substantial improvements and improved softening point new properties, resulting in the preparation The technical effects that are not available are also unclear in common sense and cannot be inferred from common sense.
这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，是没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4][4]公开过)；The nature of these new discoveries and the unpredictable technical effects of using these new properties have not been disclosed by all prior art techniques (including those that have not been preceded by comparative techniques [1][2][3][ 4][4] has been published);
(七)(Seven)
对平板玻璃材料和终端产品应用用途的抗折强度实质性及轻薄化性质的改进和提高。Improvements and improvements in the flexural strength and thinning properties of flat glass materials and end products.
本发明由于发现了有实质性的改进和提升的[抗折强度]的材料性质；从而利用这些性质，能提髙平板玻璃材料和终端产品应用用途的轻薄化性能，有予料不到的技术效果。 The present invention has been found to have substantial improvements and improved [fracture strength] material properties; thereby utilizing these properties, it is possible to improve the lightness and thinness properties of flat glass materials and end products applications, and there are unexpected technologies. effect.
这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。The nature of these new discoveries and the unpredictable technical effects of using these new properties are also unclear in common sense and cannot be inferred from common sense.
也没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4]公开过)；It has not been disclosed by all prior art comparison techniques (including those not disclosed by the prior art [1][2][3][4];
所以，应判断本发明有实质性的进步性和创造性。Therefore, it should be judged that the present invention is substantially progressive and inventive.
本发明，把先有对比技术[1][2][3][4]抗折强度顶点从180Mpa，实质性的改进和提高到抗折强度顶点240Mpa；比先有对比技术[1][2][3][4]抗折强度实质性的改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。The invention compares the apex of the first comparative technique [1][2][3][4] from 180Mpa, substantially improves and improves to the apex of the flexural strength 240Mpa; compared with the prior art [1][2 ][3][4] The flexural strength is substantially improved and improved by 1/4; it is about 3 times higher than the existing TFT boron-containing glass bending strength 80Mpa; compared with the existing aluminum-containing 12-15% touch screen glass The flexural strength of 100 Mpa is increased by about 2.4 times; it is about 5 times higher than that of calcium sodium glass.
在本用途领域中，抗折强度；可实质性的比先有对比技术[1][2][3][4]改进和提高了1/4；比现有TFT含硼玻璃抗折强度80Mpa提高了约3倍；比现有含铝12-15％的触摸屏玻璃抗折强度100Mpa提高了约2.4倍；比钙钠玻璃抗折强度50Mpa提高了约5倍。In the field of application, the flexural strength; can be substantially improved and improved by 1/4 compared with the prior art [1][2][3][4]; the flexural strength of the existing boron-containing glass is 80Mpa. It is increased by about 3 times; it is about 2.4 times higher than the existing 20-15% touch screen glass flexural strength 100Mpa; it is about 5 times higher than the calcium sodium glass bending strength 50Mpa.
也可在同等强度时，轻薄化性质，比先有对比技术[1][2][3][4]轻薄为3/4；比现有TFT含硼玻璃，轻薄为1/3；比钙钠玻璃，轻薄为1/5。也能使高性能玻璃强度，比现有钙钠玻璃强度在同等厚度及重量时高5倍。It can also be light and thin at the same strength, which is 3/4 lighter than the prior art [1][2][3][4]; it is 1/3 lighter than the existing TFT boron-containing glass; Sodium glass, light and thin for 1/5. It also enables high-performance glass strength to be five times higher than existing calcium soda glass at the same thickness and weight.
本发明的上述a.b.c几类技术效果，代表着高水平的从而大大提升了本发明用作为建筑用玻璃；汽车用玻璃；船用玻璃；铁道车厢用玻璃；飞机玻璃；防火、防爆用玻璃；特种玻璃；光伏太阳能玻璃；墙地面用彩釉玻璃装饰板等应用产品用途的产品的技术发展趋势。The above-mentioned abc technical effects of the present invention represent a high level, thereby greatly improving the invention for use as architectural glass; automotive glass; marine glass; railway car glass; aircraft glass; fireproof, explosion-proof glass; The technical development trend of products such as photovoltaic solar glass; glazed glass decorative panels for wall and floor applications.
代表着高水平的，如：高性能彩釉玻璃傢俱、高性能汽車、高性能太阳能飞行器、高性能太阳能发电装置、等应用产品用途中组合发明终端产品的技术发展趋势。Representing high-tech, such as high-performance glazed glass furniture, high-performance cars, high-performance solar aircraft, high-performance solar power plants, and other applications, the technical development trend of the combined invention of end products.
(八)(Eight)
本发明揭示了，降低生产中的玻璃析晶速度的新的材料性质The present invention discloses new material properties that reduce the crystallization rate of glass in production.
本发明由于发现了有实质性的改进和提升的[玻璃析晶速度]的新的材料性质；从而利用这些性质，产生了非显而易见的独有的技术效果：尤其比较先有对比 技术[1][2][3][4]，能克服本发明类型产品在大生产中独有的技术弱点形成的析晶造成的缺陷，能进行更好水平的工艺品质控制，提高生产的可行性和产品的合格品率。The present invention has discovered a new material property with substantial improvements and improved [glass crystallization rate]; thus utilizing these properties, a non-obvious unique technical effect is produced: especially prior comparison The technology [1][2][3][4] can overcome the defects caused by the crystallization of the unique technical weakness of the product of the invention, and can carry out a better level of process quality control and improve production. Feasibility and product quality rate.
这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。The nature of these new discoveries and the unpredictable technical effects of using these new properties are also unclear in common sense and cannot be inferred from common sense.
也没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4]公开过)；It has not been disclosed by all prior art comparison techniques (including those not disclosed by the prior art [1][2][3][4];
所以，应判断本发明有实质性的进步性和创造性。Therefore, it should be judged that the present invention is substantially progressive and inventive.
(不是受先有对比技术启示的，就连玻璃析晶速度的新材料性质的测试目的特征和测试设备及测试方法，也是根据本发明类型产品在大生产中独有的技术弱点形成的析晶造成的缺陷，而独创的和首创的)：(Not by the prior art, even the test purpose characteristics and test equipment and test methods of the new material properties of the glass crystallization rate are also the crystallization of the technical weaknesses unique to the large-scale production according to the type of the invention. The resulting defects, while original and original):
因为，本发明产品具有析晶温度的上线[最高点]高于成型温度的特点，所以为了研究在大生产中如选择性采用具有析晶速度比较慢的玻璃，就有利于在成型前的冷却工作部玻璃液降温工艺阶段，减少析晶的风险；因为须然要求冷却工作部玻璃液的温度，在工艺控制上一定要髙于析晶温度，也会特别在冷却工作部的液线边沿及拐角和底部这些易于析晶的地方增加一些加热控制装置；但是在冷却工作部的拐角和底部的玻璃液，也会有一些流动较慢的在玻璃析晶温度区的上线范围，逐步降温的条件下，(如先有对比技术[1][2][3][4])，玻璃液在10-31分钟内就产生局部析晶，则会有进入成型阶段使平板玻璃出现局部失透的不合格产品的风险；Because the product of the present invention has the characteristic that the upper line [highest point] of the crystallization temperature is higher than the molding temperature, in order to study the selective use of glass having a relatively slow crystallization rate in large production, it is advantageous for cooling before molding. The working temperature of the glass liquid cooling process in the working part reduces the risk of crystallization; because it is required to cool the temperature of the glass in the working part, the process must be controlled by the crystallization temperature, especially in the liquid line edge of the cooling working part. Corners and bottoms are easy to devitrify some heating control devices; but in the corners of the cooling work and the bottom of the glass, there will be some slower flow in the glass crystallization temperature range, the gradual cooling conditions Next, (if there is a comparative technique [1] [2] [3] [4]), the glass liquid will be partially devitrified within 10 to 31 minutes, and there will be a partial devitrification of the flat glass in the molding stage. The risk of substandard products;
所以应在大生产中选择性采用本发明的材料性质：[具有析晶速度比较慢的玻璃液在45-60分钟或60-150分钟后内玻璃析晶温度区的上线范围，逐步降温的条件下，都不产生析晶的玻璃材料，比先有对比技术先有对比技术[1][2][3][4]的析晶速度要慢5倍，从而克服成型阶段使平板玻璃出现局部失透的不合格产品的风险。Therefore, the material properties of the present invention should be selectively used in large-scale production: [the upper-line range of the inner glass crystallization temperature zone after the glass liquid having a relatively slow crystallization rate is 45-60 minutes or 60-150 minutes, and the condition of gradually lowering the temperature Underneath, there is no crystallization of the glass material, which is 5 times slower than the prior art prior art [1][2][3][4], thus overcoming the forming stage to make the flat glass appear locally. The risk of devitrified substandard products.
(九)(nine)
本发明在平板玻璃新用途中的创造性： The inventiveness of the invention in the new use of flat glass:
本发明在平板玻璃新用途中，发现了：(1).高温区热膨胀系数的差值及(2).髙软化点，(3).更髙的抗折强度性质；(4)在平板玻璃新用途中，发现了新的玻璃产品[低析晶速度]材料性质；这(1).(2).(3).(4)类性质，有实质性的改进和提高，和利用这些这(1).(2).(3).(4)类性质，产生了予料不到的技术效果。In the new application of the flat glass, the invention finds: (1) the difference of the thermal expansion coefficient in the high temperature zone and (2) the softening point of the crucible, (3) the more flexural strength property; (4) in the flat glass In new applications, new glass products [low crystallization rate] material properties were found; these (1).(2).(3).(4) properties, substantial improvements and improvements, and the use of these (1). (2). (3). (4) The nature of the class has produced unexpected technical effects.
但对上述本发明在平板玻璃新用途中，发现的(1)，(2)，(3)(4)部分的新的性质，不能用‘化学产品中，无论是新产品或已知产品，其性能是产品本身所固有的’的原理的引述，来得出[本发明发现的新的性质]是普通本领域技术人员是容易予见的，是能推断的结论；来否定本化学产品用途发明的实质的进步性和创造性。However, in the new use of the above-mentioned invention in the flat glass, the new properties of the parts (1), (2), (3) (4) found, cannot be used in 'chemical products, whether new products or known products, The performance is a reference to the principle of the product itself, and it is concluded that the [new properties discovered by the present invention] are easily identifiable by those skilled in the art and can be inferred; The substance of progress and creativity.
因为，本化学产品用途发明在平板玻璃新用途中，发现的这(1).(2).(3).(4)类性质和效果，都比较各种先有技术有实质性的改进和提高。都是公知常识中沒有明确的，并不能由常识推论得到的。Because the use of this chemical product is invented in the new use of flat glass, the properties and effects of (1).(2).(3).(4) found are substantially improved compared with various prior art. improve. It is not clear in common knowledge, and it cannot be inferred from common sense.
而且本化学产品用途发明在平板玻璃新用途中，利用这些新性质，产生的予料不到的技术效果，也是公知常识中沒有明确的并不能由常识推论得到的。这些新发现的性质和利用这些新性质，产生的予料不到的技术效果，是没有被一切先有对比技术公开过(也包括没有被先有对比技术[1][2][3][4]公开过)；Moreover, the use of the chemical product in the new use of flat glass, the use of these new properties, the resulting unpredictable technical effects, is also not clear in the common sense and can not be derived from common sense. The nature of these new discoveries and the unpredictable technical effects of using these new properties have not been disclosed by all prior art techniques (including those that have not been preceded by comparative techniques [1][2][3][ 4] published);
本发明权利要求1的技术方案，在平板玻璃新用途中，已知性质(1).(2).(3)有实质性的改进和提高；还发现了玻璃产品(4)[低析晶速度]的新材料性质，并利用这些这性质，产生了予料不到的技术效果；所以应判断，本发明权利要求1的技术方案，和本发明从属权利要求的技术方案，在平板玻璃新用途中，有实质性的进步性和创造性。The technical solution of claim 1 of the present invention, in the new use of flat glass, known properties (1). (2). (3) have substantial improvements and improvements; also found glass products (4) [low crystallization The new material properties of speed], and the use of these properties, produce unexpected technical effects; therefore, it should be judged that the technical solution of claim 1 of the present invention, and the technical solution of the dependent claims of the present invention, in the new flat glass Among the uses, there is substantial progress and creativity.
而且，只要本发明(1).(2).(3).(4)类性质，只要其中之1类性质，有实质性的改进和提高；并只要利用这些其中之1种新性质，产生了说明书中的任何一种涉及提高产品性能、或合格率质量、或提高产量的予料不到的技术效果；就都应判断本发明有实质性的进步性和创造性。Moreover, as long as the properties of the (1).(2).(3).(4) of the present invention are substantially improved and improved as long as one of them is of a nature, and one of these new properties is utilized, Any of the specifications relates to unexpected technical effects of improving product performance, or yield quality, or increasing throughput; it is to be judged that the present invention is substantially progressive and inventive.
就是若发现有其它先有对比技术，其能作为一个与本新用途发明接近的巳知化学产品；但因本化学产品新用途发明，新发现的多种产品性质和由这新发现的多种产品性质产生的多种予料不到的技术效果，说明了本化学产品应用用途发明，是非显而易见的，具有突出的实质性特点和显着的技术进步性和具有创造性。 If it is found that there are other prior art comparison techniques, it can be used as a know-how chemical product close to the invention of this new use; but due to the invention of new uses of this chemical product, the newly discovered various product properties and various new discoveries The various unpredictable technical effects produced by the nature of the product illustrate the invention of the application of the chemical product, which is non-obvious, with outstanding substantive features and significant technological advancement and creativity.
以上所述，仅是为了说明本发明的较佳优选实施例而已，然而其并非是对本发明的限制，任何熟悉本项技术的人员可能利用上述揭示的技术内容加以变更或修饰为等同变化的等效实施例，都可以按不同要求和性能实施本发明一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用。可见，凡是未脱离本发明技术方案的内容，尤其是权利要求之内容，依据本发明的技术实质对以上实施例所作的任何简单修改，等同变化与修饰，均仍属本发明技术方案的范围内。 The above description is only for the purpose of illustrating the preferred embodiments of the present invention, but it is not intended to limit the invention, and any person skilled in the art may change or modify the equivalents of the above-disclosed technical contents. In the embodiment, the high softening point, the low difference of the thermal expansion coefficient of the high temperature zone, the low crystallization rate, and the application of the fireproof and explosion-proof flat glass can be implemented according to different requirements and performances. It can be seen that any simple modifications, equivalent changes and modifications made to the above embodiments in accordance with the technical spirit of the present invention are still within the scope of the technical solutions of the present invention without departing from the technical scope of the present invention. .

Claims (51)

  1. 一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为0.01％--39％，氧化镁含量为7％--20％，氧化硅含量是氧化钙含量的2.51-4.8倍，氧化钙含量是氧化镁含量的1.0-1、8倍，厚度20mm以内的平板玻璃厚薄差在0.01mm-0.4mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of a fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, magnesium oxide The content is 7%-20%, the silicon oxide content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness difference of the flat glass within the thickness of 20 mm is 0.01 mm-0.4. Mm.
  2. 一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为0.01％--39％，氧化钠含量为0.001％--18％，氧化镁含量为7％--20％，氧化硅含量是氧化钙含量的2.51-4.8倍，氧化钙含量是氧化镁含量的1.0-1、8倍，厚度20mm以内的平板玻璃厚薄差在0.01mm-0.4mm。A high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the alumina content is 0.01% - 39% by weight, sodium oxide The content is 0.001%-18%, the magnesium oxide content is 7%-20%, the silica content is 2.51-4.8 times of the calcium oxide content, the calcium oxide content is 1.0-1, 8 times of the magnesium oxide content, and the thickness is 20 mm. The thickness of the flat glass is within the range of 0.01 mm to 0.4 mm.
  3. 根据权利要求1所述的一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：其软化点为750℃-860℃；其抗折强度60-240Mpa。The invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, characterized in that the softening point is 750 ° C - 860 ° C; The folding strength is 60-240Mpa.
  4. 根据权利要求1所述的一种平板玻璃，其特征在于：其高温区低热膨胀率的特征在于：在高温区550℃-600℃时，热膨胀率的差值在百万分之1.2以内，在高温区600℃-650℃时，热膨胀率的差值在百万分之0.1-0.99以内，在高温区650℃-700℃时，热膨胀率的差值在百万分之0.1-0.99以内。A flat glass according to claim 1, wherein the low temperature expansion rate in the high temperature region is characterized by: in the high temperature region 550 ° C - 600 ° C, the difference in thermal expansion rate is within 1.2 parts per million, In the high temperature range of 600 ° C to 650 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million, and in the high temperature range 650 ° C - 700 ° C, the difference in thermal expansion rate is within 0.1-0.99 parts per million.
  5. 根据权利要求1所述的一种平板玻璃，特征在于：在高温区700℃-740℃时，热膨胀率的差值在百万分之1-5.9或6-8以内。A flat glass according to claim 1, wherein the difference in thermal expansion rate is in the range of 1-5.9 or 6-8 parts per million in the high temperature region of 700 ° C to 740 ° C.
  6. 根据权利要求1所述的一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：按重量百分比计，其氧化铝含量为4％--8％或8.1-12％或12.1-23％或23.1-32％或32.1-39％， The invention relates to a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass according to claim 1, characterized in that the alumina content is 4% by weight. --8% or 8.1-12% or 12.1-23% or 23.1-32% or 32.1-39%,
  7. 根据权利要求1-6所述的任一项所述的一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用及制备方法，其特征在于：The method for preparing and preparing a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass according to any one of claims 1-6, characterized in that:
    步骤1，根据权利要求1-6所述的任一项所述的玻璃配方配置所需的各种有预定的成份以及预定的氧化硅、氧化钙、氧化镁之间的特殊比例关系的成份的原料，经混合搅拌之后在对应于各玻璃配方的熔化温度熔化，形成预定的粘度的玻璃液，再均化，澄清，排出气泡，形成可流动的熔融体；Step 1. The various predetermined components required for the glass formulation configuration according to any one of claims 1-6, and predetermined components of a specific ratio between silicon oxide, calcium oxide and magnesium oxide. The raw materials, after mixing and stirring, are melted at a melting temperature corresponding to each glass formulation to form a glass liquid of a predetermined viscosity, and then homogenized, clarified, and discharged to form a flowable melt;
    步骤2，采用浮法工艺、平拉工艺、格法工艺、压延工艺、溢流法工艺、中任一种工艺对玻璃进行成型。In step 2, the glass is formed by a float process, a flat pull process, a lattice process, a calendering process, an overflow process, or any one of the processes.
  8. 根据权利要求7所述的一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用及制备方法，其特征在于：The method for preparing and preparing a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, a fireproof and explosion proof flat glass according to claim 7, wherein:
    所述步骤1包括：The step 1 includes:
    将所备之各类原料，放置于各自的原料容器之中，使各种原料通过原料输送线，经过计量后，按所需比例送入原料混合搅拌装置中，搅拌混合后进入装载配料的大料罆或料仓中；The various raw materials prepared are placed in the respective raw material containers, and the various raw materials are passed through the raw material conveying line, and after being metered, they are fed into the raw material mixing and stirring device at a desired ratio, and after mixing and mixing, the raw materials are loaded. In the magazine or silo;
    使配合好的原料进入熔池中，在对应于各玻璃配方的熔化温度熔化，形成预定的粘度的玻璃液，再均化，澄清，排出气泡，形成可流动的熔融体；Putting the matched raw materials into the molten pool, melting at a melting temperature corresponding to each glass formulation, forming a molten glass of a predetermined viscosity, homogenizing, clarifying, discharging bubbles, and forming a flowable melt;
    步骤2中使用浮法工艺：在本工艺中还须预先备好锡窑，在步骤1的工序后，使熔池的尾部的可流动的熔融体流入锡窑中进行淌平、抛光、拉薄的工艺过程，并经拉边机在工艺规定的方向的导拉和牵引机的牵引，拉出锡槽，并经在玻璃析晶温度区的上线范围，逐步降温的条件下，退火，待冷却后，经切割，即可制得所述玻璃。 The float process is used in step 2: in the process, the tin kiln must be prepared in advance, and after the step of step 1, the flowable melt at the tail of the molten pool is poured into the tin kiln for flattening, polishing, and thinning. The process, and the pulling of the puller in the direction specified by the process and the traction of the tractor, pull out the tin bath, and after annealing in the upper line range of the glass crystallization temperature zone, gradually cool down, to be cooled Thereafter, the glass is obtained by cutting.
  9. 一种高性能彩釉平板玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其基板玻璃表面有1-10种色彩的彩釉层。A high-performance color glazed flat glass, characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the substrate thereof The surface of the glass has a glaze layer of 1-10 colors.
  10. 一种高性能耐磨彩釉层平板玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其基板玻璃表面有1-10种色彩的彩釉层，其特征在于：其表层的釉料层中含有15-70％的石英晶体或氧化铝晶体。A high-performance wear-resistant color glaze flat plate glass, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass The surface of the substrate glass has a glaze layer of 1-10 colors, and the glaze layer of the surface layer contains 15-70% quartz crystal or alumina crystal.
  11. 一种高性能超薄型墙面贴面彩釉平板玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其基板玻璃表面有1-10种色彩的彩釉层，其特征在于：其厚度在0.5-1.5mm。A high-performance ultra-thin wall-faced glazed flat glass, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof For the application of flat glass, the surface of the substrate glass has a glaze layer of 1-10 colors, and the thickness thereof is 0.5-1.5 mm.
  12. 一种高性能船用玻璃窗结构，其特征在于：其窗玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其四周边上安装有树脂边框或金属边框支撑装置。The utility model relates to a high performance marine glazing structure, characterized in that the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass. A resin frame or a metal frame support device is mounted on the periphery of the four sides.
  13. 一种高性能飞机玻璃窗结构，其特征在于：其窗玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其四周边上安装有树脂边框或金属边框支撑装置。A high performance aircraft glazing structure, characterized in that: the window glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass. A resin frame or a metal frame support device is mounted on the periphery of the four sides.
  14. 一种高性能汽车用玻璃窗结构，其特征在于：其汽车窗玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其四周边上安装有树脂边框或金属边框支撑装置。A high-performance glazing structure for an automobile, characterized in that: the automobile glazing is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass The application has a resin frame or a metal frame support device mounted on the periphery thereof.
  15. 一种高性能建筑物玻璃窗结构，其特征在于：其窗玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其四周边上安装有树脂边框或金属边框支撑装置。A high-performance building glazing structure, characterized in that: the window glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass A resin frame or a metal frame support device is mounted on the periphery of the four sides.
  16. 一种高性能中空玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；各层玻璃四周边上粘贴有支撑装置；各层玻璃之间有3-50mm的经抽真空的隔离空间。 A high-performance insulating glass characterized in that: the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass; A support device is attached to the periphery; there is a 3-50 mm vacuumed isolation space between the layers of glass.
  17. 一种高性能建筑物玻璃幕墙，其特征在于：其玻璃幕墙是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其被固定在上金属支撑装置上。A high-performance building glass curtain wall, characterized in that: the glass curtain wall is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is fixed to the upper metal support device.
  18. 一种高性能超大面积的薄玻璃窗或玻璃幕墙，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；其玻璃的厚度为4-10mm，其玻璃的尺寸为3-40平方米，或其玻璃的厚度为10.1-20mm，其玻璃的尺寸为15.1-80平方米；A high-performance super-large area thin glass window or glass curtain wall, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass Application; the thickness of the glass is 4-10mm, the size of the glass is 3-40 square meters, or the thickness of the glass is 10.1-20mm, and the size of the glass is 15.1-80 square meters;
  19. 一种高性能钢化玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，经化学钢化或物理钢化制成。A high-performance tempered glass characterized in that the glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass, chemically tempered or Made of physical tempering.
  20. 一种高性能玻璃，或钢化玻璃，或夾胶玻璃的玻璃台面傢具，其特征在于：其玻璃台面，是由权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃制成，其台面下部有支撑装置。A high-performance glass, or tempered glass, or a glass-top furniture of laminated glass, characterized in that the glass table top is a low difference and a low coefficient of thermal expansion coefficient of a high softening point and a high temperature zone according to claim 1. The crystallization rate, fireproof and explosion-proof flat glass are made, and the lower part of the table has support means.
    一种高性能玻璃，或钢化玻璃，或夾胶玻璃的玻璃台面傢具，其特征在于：其玻璃台面，是由权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃制成，其台面下部有支撑装置。A high-performance glass, or tempered glass, or a glass-top furniture of laminated glass, characterized in that the glass table top is a low difference and a low coefficient of thermal expansion coefficient of a high softening point and a high temperature zone according to claim 1. The crystallization rate, fireproof and explosion-proof flat glass are made, and the lower part of the table has support means.
  21. 一种高性能夹胶玻璃，其特征在于：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其各层玻璃的之间有树脂材料层。A high-performance laminated glass, characterized in that the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass, the layers thereof There is a layer of resin material between the glass.
  22. 一种高性能防弹防爆玻璃，其特征在于，其包括：防弹防爆玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；其各片玻璃板之由树脂片粘合。The utility model relates to a high performance bulletproof and explosion-proof glass, which comprises: bulletproof explosion-proof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, a fireproof and explosion-proof flat glass Application; each of the glass sheets is bonded by a resin sheet.
  23. 一种高性能彩釉玻璃板组合橱柜，其特征在于：其玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其表面或背面有1-10种色彩的彩釉层，平板玻璃四周有金属边框包围，使之形成组合板；在金属边框之间有金属联接装置，使之成为一种彩釉玻璃板组合橱柜。 The invention relates to a high-performance color glazed glass plate combination cabinet, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass There are 1-10 kinds of color glaze layer on the surface or back surface, and the flat glass is surrounded by a metal frame to form a composite board; there is a metal connecting device between the metal frames, making it a glazed glass plate combination cupboard.
  24. 一种高性能推拉门柜玻璃面板家俱，其特征在于：其玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其表面或背面有1-10种色彩的彩釉层，四周有金属边框，金属边框的上下有滚轮。A high-performance sliding door cabinet glass panel furniture, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass There are 1-10 colors of glaze on the surface or back, surrounded by metal frames, and the metal frame has rollers on the top and bottom.
  25. 一种高性能彩釉玻璃板组合衣柜，其特征在于：其玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其表面或背面有1-10种色彩的彩釉层；所述平板玻璃四周有金属边框包围，使之形成组合板；在金属边框之间有金属联接装置，使之成为一种彩釉玻璃板组合衣柜。The utility model relates to a high-performance color glazed glass plate combined wardrobe, characterized in that the glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion-proof flat glass a glaze layer of 1-10 colors on the surface or the back surface; the flat glass is surrounded by a metal frame to form a composite panel; and a metal coupling device is formed between the metal frames to make it a glazed glass Board combination wardrobe.
  26. 一种高性能彩釉台面玻璃家俱，其特征在于：其台面玻璃，是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，台面的表面或背面有1-10种色彩的彩釉层，其台面下部有支撑装置。A high-performance color glazed countertop glass furniture, characterized in that: the countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass Application: There are 1-10 colors of glaze layer on the surface or back of the table top, and there are support devices on the lower part of the table.
  27. 一种高性能光伏太阳能装置，其特征在于：包含太阳能电池，以及玻璃基板或外罩板；玻璃基板或外罩板是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用。A high-performance photovoltaic solar device, comprising: a solar cell, and a glass substrate or a cover plate; the glass substrate or the cover plate is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. Low crystallization rate, application of fireproof and explosion-proof flat glass.
  28. 一种高性能薄膜太阳能装置，该装置包含：薄膜太阳能电池；以及根据上述权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用。A high performance thin film solar device comprising: a thin film solar cell; and a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass according to claim 1 .
  29. 一种采用卷对卷的工艺，来在玻璃基板上生产的簿膜晶体管，及由此生产的液晶显示屏，其包括A roll-to-roll process for producing a film transistor on a glass substrate, and a liquid crystal display produced thereby, including
    液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
    数组基板，该数组基板包括基底，及采用卷对卷的工艺在该基底上生产的像素结构，该基底为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；An array substrate comprising a substrate and a pixel structure produced on the substrate by a roll-to-roll process, wherein the substrate has a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution according to claim 1. Crystal speed, fireproof and explosion-proof flat glass;
    滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板； a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
    液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
    背光源***。Backlight system.
  30. 一种采用卷对卷的工艺，来在玻璃基板上生产的的触摸显示屏，其包括：基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其上附有一层导电膜；A touch display screen produced on a glass substrate by a roll-to-roll process, comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, and a low resolution The application of crystal speed, fireproof and explosion-proof flat glass is provided with a conductive film thereon;
    液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
    数组基板，该数组基板包括基底及在该基底上的像素结构，该基底为玻璃板；An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
    滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
    液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
    背光源***。Backlight system.
  31. 一种采用卷对卷的工艺来生产的高性能的液晶屏或触摸显示屏用的平板玻璃，其包括：A high-performance liquid crystal screen or flat glass for a touch display screen produced by a roll-to-roll process, comprising:
    该玻璃为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；其特征在于：平板玻璃的厚度为0.05-3.5mm，其能收卷在内卷筒直径为20-80cm，其长度在200cm-2000cm或2001-10000cm。The glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature zone, a low crystallization rate, and a fireproof and explosion-proof flat glass according to claim 1; wherein the thickness of the flat glass is 0.05-3.5 mm, and the glass can be collected. The roll has an inner diameter of 20-80 cm and a length of 200 cm-2000 cm or 2001-10000 cm.
  32. 一种高性能低温多晶硅显示屏，其特征在于包括：A high performance low temperature polysilicon display screen comprising:
    液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
    低温多晶硅数组基板，该数组基板包括基底及在该基底上的采用低温多晶硅工艺生产的像素结构，该基底玻璃为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；a low temperature polysilicon array substrate comprising a substrate and a pixel structure produced on the substrate by a low temperature polysilicon process, wherein the base glass has a high softening point and a low difference in thermal expansion coefficient of a high temperature region according to claim 1. Crystallization speed, fireproof and explosion-proof flat glass;
    滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
    液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
    背光源***。Backlight system.
  33. 一种高性能低温多晶硅显示屏用途的平板玻璃，其特征在于包括： A flat glass for high performance low temperature polysilicon display, characterized by comprising:
    该基底玻璃为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；The base glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass;
  34. 一种高性能耐磨又高强度的液晶显示屏，其包括：A high performance wear resistant and high strength liquid crystal display comprising:
    数组基板，该数组基板包括基底及在该基底上的像素结构，该基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；An array substrate comprising a substrate and a pixel structure on the substrate, wherein the substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof explosion-proof plate according to claim 1. Application of glass;
    滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
    液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
    背光源***。Backlight system.
  35. 一种高性能耐磨又高强度的触摸显示屏，其包括：基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其上附有一层导电膜；A high-performance wear-resistant and high-strength touch display screen comprising: a substrate glass according to claim 1 having a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass Application with a conductive film attached thereto;
    液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
    数组基板，该数组基板包括基底及在该基底上的像素结构，该基底为玻璃板；An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
    滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
    液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
    背光源***。Backlight system.
  36. 一种高性能耐磨又高强度的触摸显示屏手机、或触摸显示屏平板计算机、或触摸显示屏笔记本电脑、或触摸显示屏电视、其包括：A high performance wear resistant and high intensity touch display mobile phone, or a touch display tablet computer, or a touch display notebook computer, or a touch display television, comprising:
    基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其上附有一层导电膜；The substrate glass is a high softening point, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and a fireproof and explosion proof flat glass according to claim 1, and a conductive film is attached thereon;
    数组基板，该数组基板包括基底及在该基底上的像素结构，该基底为玻璃板；An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
    滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
    液晶层，夹设在该数组基板和该滤色器基板之间；以及 a liquid crystal layer interposed between the array substrate and the color filter substrate;
    背光源***；Backlight system;
    显示屏包边装置及支撑装置。Display edge device and support device.
  37. 一种先印刷再烧结薄膜晶体管工艺所生产的液晶显示屏，其包括A liquid crystal display screen produced by a process of first printing and re-sintering a thin film transistor, which comprises
    液晶显示屏，该液晶显示屏包括：LCD screen, the LCD screen includes:
    数组基板，该数组基板包括玻璃基底，及采用先在玻璃基底上印刷薄膜晶体管原料，再该玻璃基底上烧结成薄膜晶体管的生产工艺所产生的像素结构；该玻璃基底为权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；An array substrate comprising a glass substrate, and a pixel structure produced by a process for printing a thin film transistor raw material on a glass substrate and then sintering the thin film transistor on the glass substrate; the glass substrate is the one according to claim 1. High softening point, low difference of thermal expansion coefficient in high temperature zone, low crystallization rate, application of fireproof and explosion-proof flat glass;
    滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
    液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
    背光源***。Backlight system.
  38. 一种高性能曲面液晶显示屏，其包括：A high performance curved liquid crystal display comprising:
    基板玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；The substrate glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;
    数组基板，该数组基板包括基底及在该基底上的像素结构，该基底为玻璃板；An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
    滤色器基板，该滤色器基板包括基底以及在该基底上的滤色器层，该基底为玻璃基板；a color filter substrate, the color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
    液晶层，夹设在该数组基板和该滤色器基板之间；以及a liquid crystal layer interposed between the array substrate and the color filter substrate;
    背光源***；Backlight system;
  39. 一种高性能OLED有机发光显示屏，其特征在于包括：权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；A high-performance OLED organic light-emitting display screen comprising: a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass;
    以及有机电激发光器件。And organic electroluminescent devices.
  40. 一种高性能耐磨又高强度的手机、或平板计算机或笔记本电脑或台式计算机的透明玻璃后背外壳，其特征在于：其透明玻璃后背外壳，是采用权利要求1所 述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用。A high-performance wear-resistant and high-strength mobile phone, or a transparent glass back casing of a tablet computer or a notebook computer or a desktop computer, characterized in that the transparent glass back casing is according to claim 1. A high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass.
  41. 一种高性能防弹防爆汽车，其包含：A high performance bulletproof and explosion proof vehicle comprising:
    1-10个车窗的1-3层玻璃，防弹玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；其各片玻璃板之由树脂片粘合；1-3 layers of glass of 1-10 windows, the bulletproof glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion proof flat glass; Each piece of glass plate is bonded by a resin sheet;
    汽车的四周的金属板或金属架内，有防弹结构；There is a bulletproof structure in the metal plate or metal frame around the car;
    以及动力装置；仪表盘；方向控制器；汽车外壳；汽车底盘；汽车刹车装置；汽车轮胎。And power unit; instrument panel; direction controller; car shell; car chassis; car brakes;
  42. 一种高性能防抢劫、防盗、防爆、防撞击、防滚翻伤害汽车，其包含：A high-performance anti-robbery, anti-theft, explosion-proof, anti-collision, anti-rolling injury car, which includes:
    1-10个车窗的1-3层玻璃，防弹玻璃是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；1-3 layers of glass of 1-10 windows, bulletproof glass is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature zone, a low crystallization rate, and an application of fireproof and explosion proof flat glass;
    以及动力装置；仪表盘；方向控制器；汽车外壳；汽车底盘；汽车刹车装置；汽车轮胎。And power unit; instrument panel; direction controller; car shell; car chassis; car brakes;
  43. 一种高性能太阳能飞行器，其具有推动飞行的缧旋桨动力的装置，机翼，驾驶控制***装置，和一种薄膜太阳能装置，该装置包含：薄膜太阳能电池；薄膜太阳能装置上的基板玻璃，根据上述权利要求1所述是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃。A high performance solar aircraft having a propeller power for propelling flight, a wing, a driving control system device, and a thin film solar device comprising: a thin film solar cell; a substrate glass on a thin film solar device, According to the invention as claimed in claim 1, a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass are provided.
  44. 一种高性能彩釉平板玻璃与金属层的复合板，其结构组成是：其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃，其基板玻璃表面有1-10种色彩的彩釉层，0.1-5mm厚度的金属板材，在上述玻璃板和金属板材之间有一层粘合材料层。The utility model relates to a composite board of high-performance color glaze flat glass and metal layer, wherein the glass composition is a high softening point according to claim 1, a low difference of thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof explosion-proof The flat glass has a glaze layer of 1-10 colors on the surface of the substrate glass, a metal plate with a thickness of 0.1-5 mm, and a layer of adhesive material between the glass plate and the metal plate.
  45. 一种高性能的、具有在墙面上安装简便结构的、彩釉玻璃复合材料板，其结构组成是，其玻璃是权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其基板玻璃表面有1-10种色彩的彩釉层，0.1-5mm厚度的金属板材，在上述玻璃板和金属板材之间有一层粘合材料层，其特征在于： A high-performance glazed glass composite material board having a simple structure installed on a wall surface, the structural composition thereof is that the glass is a low difference between a high softening point and a high temperature region thermal expansion coefficient according to claim 1. , low crystallization rate, application of fireproof and explosion-proof flat glass, the surface of the substrate glass has 1-10 colors of glaze layer, 0.1-5mm thickness of metal plate, there is a layer of bonding material between the glass plate and the metal plate Layer, which is characterized by:
    其制品的复合板的背底面的金属板的2-4条边，比重迭后的表层彩釉装饰平板玻璃制品的边部伸出了10-30mm的距离。The 2-4 sides of the metal plate on the back surface of the composite board of the product, the edge of the surface glazed decorative flat glass product of the specific gravity protrudes by a distance of 10-30 mm.
  46. 一种高性能的、具有易装拆结构的、彩釉玻璃复合材料地板，其结构包括，[1]表层彩釉玻璃材料基板，[2]粘合剂层，[3]底板层，其特征在于：表层彩釉玻璃材料基板，是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；底板层的1-2个侧面，底板层有凸出玻璃面的外侧边沿1-25mm的特征；底板层的另外1-2个侧面，底板层有凹入玻璃面边沿1-25mm的特征；凸出或凹入玻璃面的底板层厚度，是底板层材料厚度的10％-90％。A high-performance, glazed glass composite flooring with easy-to-assemble structure, including: [1] surface glazed glass substrate, [2] adhesive layer, [3] bottom layer, features It is: the surface layer of glazed glass material substrate is a high softening point, low differential coefficient of thermal expansion coefficient, low crystallization rate, fireproof and explosion-proof flat glass; 1-2 sides of the bottom layer, the bottom layer has protruding glass The outer edge of the face is 1-25mm; the other 1-2 sides of the bottom layer, the bottom layer has a feature of 1-25mm concave edge of the glass surface; the thickness of the bottom layer of the convex or concave glass surface is the material of the bottom layer 10%-90% of the thickness.
  47. 一种采用热变型工艺生产的高性能的玻璃洗面盆，其是对平板玻璃材料由所需的洗面盆型状的模具，采用热变型工艺来生产的高性能的玻璃洗面盆，其特征在于：所述的平板玻璃材料是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃。A high-performance glass wash basin produced by a thermal deformation process, which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold, characterized in that: The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, and a fireproof and explosion-proof flat glass.
  48. 一种采用热变型工艺生产的高性能的彩釉玻璃洗面盆，其是对平板玻璃材料由所需的洗面盆型状的模具，采用热变型工艺来生产的高性能的玻璃洗面盆，其特征在于：所述的平板玻璃材料是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；玻璃上面附着有彩轴层。A high-performance glazed glass wash basin produced by a thermal deformation process, which is a high-performance glass wash basin produced by a thermal deformation process for a flat glass material from a desired wash basin-shaped mold. It is: the flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, a low crystallization rate, a fireproof and explosion-proof flat glass; a color shaft layer is attached to the glass.
  49. 一种采用热变型工艺生产的高性能的彩釉玻璃抬面板和联体的洗面盆，其结构特征在于：1.平面型状的抬面板；2.其联体的另一个部分，是对平板玻璃材料由所需的洗面盆型状的模具，采用热变型工艺来生产的玻璃洗面盆；3.所述的平板玻璃材料是一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃；4.玻璃面附着有彩轴层。A high-performance glazed glass lifting panel and a combined wash basin produced by a thermal deformation process, the structural features of which are: 1. a flat-shaped lifting panel; 2. another part of the joint is a flat panel Glass material consists of a desired wash basin-shaped mold, a glass wash basin produced by a thermal deformation process; 3. The flat glass material is a high softening point, a low difference in thermal expansion coefficient in a high temperature region, and a low resolution Crystal speed, fireproof and explosion-proof flat glass; 4. The glass surface is attached with a color shaft layer.
  50. 一种用于卫生间的高性能彩釉玻璃洗面盆台面板，其特征在于：1.其台面玻璃，是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用；2.台面的表面或背面有1-10种色彩的彩釉层；3.其台面平面上有一个安装洗面盆的孔；4.其台面下部有支撑装置。 A high-performance glazed glass washbasin countertop for a bathroom, characterized in that: 1. The countertop glass is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature zone, and a low analysis Crystal speed, application of fireproof and explosion-proof flat glass; 2. glazed layer of 1-10 colors on the surface or back of the table; 3. There is a hole for installing the wash basin on the surface of the table; 4. Supporting device at the lower part of the table .
  51. 一种用于阳台保护拦的超長玻璃板，其玻璃，是根据权利要求1所述一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用，其特征在于：阳台保护拦的玻璃板的長度为3-8m。 An ultra-long glass plate for a balcony protection barrier, the glass thereof is a high softening point according to claim 1, a low difference in thermal expansion coefficient of a high temperature region, a low crystallization rate, and an application of fireproof and explosion-proof flat glass. It is characterized in that the length of the glass plate of the balcony protection barrier is 3-8 m.
PCT/CN2015/000508 2014-10-10 2015-07-15 Application of fire-proof explosion-proof plate glass having high softening point, low differential high-temperature region thermal expansion coefficient, and low crystallisation speed WO2016054872A1 (en)

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PCT/CN2015/000795 WO2016086501A1 (en) 2014-12-01 2015-11-16 Application of fire proof and explosion proof plate glass with low difference value between thermal-expansion coefficients in high-temperature region, low crystallization speed, ultra-high strength, and high softening point
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Publication number Priority date Publication date Assignee Title
CN106652826A (en) * 2016-11-24 2017-05-10 成都佳美嘉科技有限公司 Solar liquid crystal advertising display board

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