CN103360260B - 一种对苯二甲酸乙二酯的制备工艺和聚酯的制备方法 - Google Patents
一种对苯二甲酸乙二酯的制备工艺和聚酯的制备方法 Download PDFInfo
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- CN103360260B CN103360260B CN201210102371.1A CN201210102371A CN103360260B CN 103360260 B CN103360260 B CN 103360260B CN 201210102371 A CN201210102371 A CN 201210102371A CN 103360260 B CN103360260 B CN 103360260B
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- alcoholysis
- reaction
- alcoholysis reaction
- ethylene glycol
- polyester
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- 229920000728 polyester Polymers 0.000 title claims abstract description 59
- FYIBGDKNYYMMAG-UHFFFAOYSA-N ethane-1,2-diol;terephthalic acid Chemical compound OCCO.OC(=O)C1=CC=C(C(O)=O)C=C1 FYIBGDKNYYMMAG-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000005516 engineering process Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 238000006136 alcoholysis reaction Methods 0.000 claims abstract description 70
- 239000002699 waste material Substances 0.000 claims abstract description 21
- 239000012535 impurity Substances 0.000 claims abstract description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 80
- 238000001914 filtration Methods 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 6
- 239000011343 solid material Substances 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 238000002203 pretreatment Methods 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 24
- QPKOBORKPHRBPS-UHFFFAOYSA-N bis(2-hydroxyethyl) terephthalate Chemical compound OCCOC(=O)C1=CC=C(C(=O)OCCO)C=C1 QPKOBORKPHRBPS-UHFFFAOYSA-N 0.000 abstract description 13
- 239000000126 substance Substances 0.000 abstract description 10
- 238000011084 recovery Methods 0.000 abstract description 7
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000009776 industrial production Methods 0.000 abstract 1
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 30
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000000047 product Substances 0.000 description 11
- 239000002994 raw material Substances 0.000 description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000007599 discharging Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000009418 renovation Methods 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000012691 depolymerization reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000004148 unit process Methods 0.000 description 1
Landscapes
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
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CN201210102371.1A CN103360260B (zh) | 2012-04-10 | 2012-04-10 | 一种对苯二甲酸乙二酯的制备工艺和聚酯的制备方法 |
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CN201210102371.1A CN103360260B (zh) | 2012-04-10 | 2012-04-10 | 一种对苯二甲酸乙二酯的制备工艺和聚酯的制备方法 |
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CN103360260A CN103360260A (zh) | 2013-10-23 |
CN103360260B true CN103360260B (zh) | 2015-04-01 |
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Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106113319A (zh) * | 2016-07-15 | 2016-11-16 | 浙江绿宇环保有限公司 | 含涤废旧纺织品回收再生工艺 |
CN108299626A (zh) * | 2016-07-15 | 2018-07-20 | 浙江绿宇环保股份有限公司 | 含涤废旧纺织品醇解法回收再生工艺 |
CN107266663B (zh) * | 2017-07-03 | 2019-11-22 | 福建锦兴环保科技有限公司 | 一种利用pet粉末生产再生聚酯的工艺 |
CN107523892B (zh) * | 2017-07-20 | 2019-01-15 | 东华大学 | 一种再生聚酯纤维及其制备方法 |
CN107523895B (zh) * | 2017-07-20 | 2019-01-11 | 东华大学 | 一种有色再生聚酯短纤维及其制备方法 |
CN110818886B (zh) * | 2019-12-13 | 2022-02-11 | 中国科学院过程工程研究所 | 一种废弃pet聚酯制备再生食品级pet聚酯的方法 |
CN112646134B (zh) * | 2020-12-10 | 2023-01-20 | 北京服装学院 | 有色废旧聚酯纺织品连续制备可纺级无色再生聚酯的方法 |
CN114000217A (zh) * | 2021-12-03 | 2022-02-01 | 仪征威英化纤有限公司 | 一种清洁抛光材料用再生纤维的制备工艺 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1304924A (zh) * | 2000-07-07 | 2001-07-25 | 中国科学院山西煤炭化学研究所 | 一种解聚聚对苯二甲酸乙二醇酯废料的方法 |
CN101565374A (zh) * | 2009-04-03 | 2009-10-28 | 北京化工大学 | 一种废聚酯的解聚方法 |
CN102250449A (zh) * | 2011-06-27 | 2011-11-23 | 沈阳化工大学 | 利用回收的对苯二甲酸合成饱和聚酯树脂的方法 |
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JPH0616595A (ja) * | 1992-07-02 | 1994-01-25 | Toray Ind Inc | 芳香族ジカルボン酸エステルの回収方法 |
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- 2012-04-10 CN CN201210102371.1A patent/CN103360260B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1304924A (zh) * | 2000-07-07 | 2001-07-25 | 中国科学院山西煤炭化学研究所 | 一种解聚聚对苯二甲酸乙二醇酯废料的方法 |
CN101565374A (zh) * | 2009-04-03 | 2009-10-28 | 北京化工大学 | 一种废聚酯的解聚方法 |
CN102250449A (zh) * | 2011-06-27 | 2011-11-23 | 沈阳化工大学 | 利用回收的对苯二甲酸合成饱和聚酯树脂的方法 |
Non-Patent Citations (2)
Title |
---|
"PET在EG中的醇解反应";杨治伟 等;《北京服装学院学报》;19940430;第14卷(第1期);29-33 * |
"废旧聚酯(PET)的化学循环利用";杨勇 等;《化学进展》;20010131;第13卷(第1期);65-72 * |
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