CN103351892B - A kind of Environmentally-friebiofuel biofuel for boiler and preparation method thereof - Google Patents
A kind of Environmentally-friebiofuel biofuel for boiler and preparation method thereof Download PDFInfo
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- CN103351892B CN103351892B CN201310338502.0A CN201310338502A CN103351892B CN 103351892 B CN103351892 B CN 103351892B CN 201310338502 A CN201310338502 A CN 201310338502A CN 103351892 B CN103351892 B CN 103351892B
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Abstract
The present invention relates to a kind of Environmentally-friebiofuel biofuel for boiler and preparation method thereof, it is high that this fuel has calorific value, easily lights a fire, and firepower is powerful; Sulfur-bearing is low, little to combustion equipment corrosion, can prolonged boiler work-ing life; High containing oxygen composition, easily form oxygen-enriched combusting, improve efficiency of combustion; Viscosity is low, good fluidity, and do not need during use to preheat, be easily atomized, atomizing particle is tiny, and atomization is good, sufficient combustion, not easily coking, and dust stratification is few, reduces carbon deposit and wearing and tearing, not easily blocks burner; Evenly, burning is balanced, improves burning situation in atomization, reduces NO_x formation; Completely, pollutant emission is few, little to atmospheric pollution, and environment protecting is good in burning.Saving and substitute traditional fossil energy such as boiler mineral fuel and high pollution fuel, is a kind of green biofuels of clean environment firendly.
Description
Technical field
The present invention relates to propellant combination and preparation method thereof, Environmentally-friebiofuel biofuel of especially a kind of Industrial Boiler and preparation method thereof, be a kind of new green environment protection biofuel newly developed, belong to new and renewable sources of energy field.
Background technology
Environmentally-friebiofuel biofuel is a kind of green, renewable energy source that is clean, environmental protection, and being a kind of synthetic fuel oil, is the substitute of conventional mineral petrochemical industry fuel oil.Tap a new source of energy, development substitutes clean fuel, and protection environment for human survival, meets the theory of Sustainable development, scientific development.Save energy, improves energy structure, preserves the ecological environment and tackles climate change, sets up the sustainable energy system based on new and renewable sources of energy, is the fundamental way realizing green low-carbon development.
China is in industrialization, High-speed Urbanization stage, and energy expenditure increases fast, makes a few near limit of the holding capacity of resources and environment, energy external dependence degree is surging, energy security ensures and faces a severe challenge, the energy and environmental problem, has become the important factor of restriction socio-economic development.
Boiler is the thermal hardware with High Temperature High Pressure, and enterprises and institutions and all trades and professions widely use, and along with developing rapidly of economy, the application of boiler is risen just year by year.Boiler is great energy consumption equipment, and the waste gas of burning and exhausting is also air-polluting main source.Along with improving and severe law enforcement for environmental protection of the every environmental protection policy of government, fire coal is forbidden in city proper and ecological Industrial Area, forbids the various high pollution fuel that burns, and implements the management of high pollution fuel Jin Ran district.Traditional boiler oil, as coal, coal tar, heavy oil, residual oil; The fuel such as solar oil, kerosene, artificial coal gas that pollutant load exceedes national regulation limit value is all put into high pollution fuel and is limited use, and this substitutes clean fuel become inevitable for finding.
Traditional boiler oil is all mineral fossil energy, belongs to hydrocarbon polymer, and containing nonhydrocarbon compound, containing colloid, bituminous matter, sulfide, nitride etc., sulfur-bearing is high, and viscosity is large, and oxydant is low.
Fuel oil sulfur-bearing Gao Shihui causes boiler component to corrode, and corrosion can cause structure deteriorate, affects the available rate of boiler, shortens boiler work-ing life.
Fuel efficient is ignition in boiler furnace promptly, the moment that fuel oil is entering burner hearth must be carried out good atomization, with air good mixing and atomization before fuel oil catches fire, very important, to increase the combustion reactions area of fuel oil, the oxygen required for elaioleucite burning can supply in time, make the burning of elaioleucite faster, burning is more abundant, discharges fewer, pollutes lighter.If not good with air mixed in advance before catching fire, atomization badness, is allowed to condition at the burning of burner hearth inner edge mixing limit, then can makes hydrocarbons decompose because of anoxycausis, generate carbon black, form soot.
Fuel-viscosity variation is large, poor fluidity, difficult atomization.Because being atomized difficulty, atomizing particle is large, causes incomplete combustion, boiler thermal output is reduced, and forms carbon distribution, easily blocks oil nozzle; Fuel oil, because of atomization skewness, causes boiler furnace localized hyperthermia high pressure, burns unbalanced, affect the operating performance of boiler.
Fuel oil oxydant is low, and because of atomization badness, for hypoxgia during burning, anoxycausis, causes burning insufficient, causes a large amount of carbon granules and oil droplet to amass and falls heated surface at the end of boiler, form dangerous burning, discharge black smoke.
Fuel oil is containing nonhydrocarbon compound, and high containing colloid, bituminous matter, sulfide, amount of nitrides, because of incomplete combustion, cause pollutant load in combustion exhaust to increase, objectionable constituent increase, and dust-laden particulate matter increases.
Oil inflame exhaust gas emission exceedes environmental protection limit value, will cause topsoil, forms haze weather, and reduce Air quality, serious environment pollution, has a strong impact on people's public health and social stability.
Summary of the invention
The object of this invention is to provide a kind of Environmentally-friebiofuel biofuel for boiler, have sulfur-bearing low, calorific value is high, oxydant is high, viscosity is low, good fluidity, is easily atomized, burning completely, pollutant emission is few, little to atmospheric pollution, and environment protecting is good, saving and substitute traditional fossil energy such as boiler mineral fuel and high pollution fuel, is a kind of green biofuels of clean environment firendly.
Another object of the present invention is to provide a kind of method steps of manufacture of Environmentally-friebiofuel biofuel for boiler.
For achieving the above object, the technical scheme provided is as follows in the present invention:
Technical scheme of the present invention, a kind of Environmentally-friebiofuel biofuel for boiler, primarily of the component raw material of following weight percent, is prepared from by certain production method step:
Plam oil: 5%-85%;
Crude benzol: 5%-55%;
Methylal: 5%-65%;
Methyl alcohol: 5%-85%;
Oleic acid: 1%-15%;
Sorbester p17: 0.05%-5%;
Ritalin: 3%-35%;
Potassium permanganate: 0.05%-10%;
Ferrocene: 0.01%-5%.
Technical scheme of the present invention, a kind of Environmentally-friebiofuel biofuel for boiler, the component raw material of weight percent can preferred following ratio formula, is prepared from by certain production method step:
Plam oil: 35%;
Crude benzol: 20%;
Methylal: 15%;
Methyl alcohol: 20%;
Oleic acid: 3%;
Sorbester p17: 0.5%;
Ritalin: 4%;
Potassium permanganate: 2%;
Ferrocene: 0.5%.
Technical scheme of the present invention, a kind of Environmentally-friebiofuel biofuel for boiler, described component raw material plam oil, also known as brown oil, brown skin oil, be the Vegetable oil lipoprotein extracting processing from the palm fibre fruit oil palm tree and obtain, other component raw material is technical grade industrial chemicals.
Technical scheme of the present invention, a kind of Environmentally-friebiofuel biofuel for boiler, the method steps of manufacture is:
(1) various component raw material is measured respectively by above-mentioned formula rate for subsequent use;
(2) first preheated by plam oil, heating and temperature control, between 60 DEG C to 90 DEG C, makes it melt, pumps into normal temperature and pressure
In stirred pot;
(3) turn on agitator, adds component raw material while stirring, is sequentially added into crude benzol, methylal, methyl alcohol, adds rear continuation stirring 10 minutes;
(4) agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into oleic acid, sorbester p17, ritalin, add rear continuation stirring 10 minutes;
(5) agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into potassium permanganate, ferrocene, add rear continuation stirring 10 minutes;
(6) with electrically heated static mixer circulation mixing 30 minutes, after being uniformly mixed, leaving standstill 30 minutes, after filtration, be a kind of Environmentally-friebiofuel biofuel for boiler of the present invention.
Advantage of the present invention and beneficial effect are:
A kind of Environmentally-friebiofuel biofuel, specifically a kind of Environmentally-friebiofuel biofuel of boiler, it is high that this fuel oil has calorific value, easily lights a fire, and firepower is powerful; Sulfur-bearing is low, little to combustion equipment corrosion, can prolonged boiler work-ing life; Oxydant is high, easily forms oxygen-enriched combusting, improves efficiency of combustion; Viscosity is low, good fluidity, and do not need during use to preheat, be easily atomized, atomizing particle is tiny, and atomization is good, sufficient combustion, not easily coking, and dust stratification is few, reduces carbon deposit and wearing and tearing, not easily blocks burner; Completely, pollutant emission is few, little to atmospheric pollution, and environment protecting is good in burning, and saving and substitute traditional fossil energy such as boiler mineral fuel and high pollution fuel, is a kind of green biofuels of clean environment firendly.
Embodiment
Be described in further detail the present invention below by specific embodiment, but be not limited to embodiment, following examples are descriptive, are not determinate, can not limit protection scope of the present invention with this.Deal described in following embodiment is weight deal.
Embodiment 1:
A kind of Environmentally-friebiofuel biofuel for boiler, it is for subsequent use that component raw material is chosen in metering by weight: plam oil: 20 kilograms; Crude benzol 25 kilograms; Methylal: 20 kilograms; Methyl alcohol: 25 kilograms; Oleic acid: 4 kilograms; Sorbester p17: 0.4 kilogram; Ritalin: 2 kilograms; Potassium permanganate: 3 kilograms; Ferrocene: 0.6 kilogram.
A kind of Environmentally-friebiofuel biofuel for boiler, the method steps of manufacture is: first preheated by plam oil, is heated to 60 DEG C, makes it melt, and pumps in normal temperature and pressure stirred pot; Turn on agitator, adds component raw material while stirring, is sequentially added into crude benzol, methylal, methyl alcohol, adds rear continuation stirring 10 minutes; Agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into oleic acid, sorbester p17, ritalin, add rear continuation stirring 10 minutes; Agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into potassium permanganate, ferrocene, add rear continuation stirring 10 minutes; Then use electrically heated static mixer circulation mixing 30 minutes, after being uniformly mixed, leaving standstill 30 minutes, after filtration, be a kind of Environmentally-friebiofuel biofuel for boiler of the present invention 100 kilograms.
Embodiment 2:
A kind of Environmentally-friebiofuel biofuel for boiler, it is for subsequent use that component raw material is chosen in metering by weight: plam oil: 35 kilograms; Crude benzol 20 kilograms; Methylal: 15 kilograms; Methyl alcohol: 20 kilograms; Oleic acid: 3 kilograms; Sorbester p17: 0.5 kilogram; Ritalin: 4 kilograms; Potassium permanganate: 2 kilograms; Ferrocene: 0.5 kilogram.
A kind of Environmentally-friebiofuel biofuel for boiler, the method steps of manufacture is: first preheated by plam oil, is heated to 70 DEG C, makes it melt, and pumps in normal temperature and pressure stirred pot; Turn on agitator, adds component raw material while stirring, is sequentially added into crude benzol, methylal, methyl alcohol, adds rear continuation stirring 10 minutes; Agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into oleic acid, sorbester p17, ritalin, add rear continuation stirring 10 minutes; Agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into potassium permanganate, ferrocene, add rear continuation stirring 10 minutes; Then use electrically heated static mixer circulation mixing 30 minutes, after being uniformly mixed, leaving standstill 30 minutes, after filtration, be a kind of Environmentally-friebiofuel biofuel for boiler of the present invention 100 kilograms.
Embodiment 3:
A kind of Environmentally-friebiofuel biofuel for boiler, it is for subsequent use that component raw material is chosen in metering by weight: plam oil: 45 kilograms; Crude benzol 15 kilograms; Methylal: 10 kilograms; Methyl alcohol: 20 kilograms; Oleic acid: 2 kilograms; Sorbester p17: 0.6 kilogram; Ritalin: 4 kilograms; Potassium permanganate: 3 kilograms; Ferrocene: 0.4 kilogram.
A kind of Environmentally-friebiofuel biofuel for boiler, the method steps of manufacture is: first preheated by plam oil, is heated to 80 DEG C, makes it melt, and pumps in normal temperature and pressure stirred pot; Turn on agitator, adds component raw material while stirring, is sequentially added into crude benzol, methylal, methyl alcohol, adds rear continuation stirring 10 minutes; Agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into oleic acid, sorbester p17, ritalin, add rear continuation stirring 10 minutes; Agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into potassium permanganate, ferrocene, add rear continuation stirring 10 minutes; Then use electrically heated static mixer circulation mixing 30 minutes, after being uniformly mixed, leaving standstill 30 minutes, after filtration, be a kind of Environmentally-friebiofuel biofuel for boiler of the present invention 100 kilograms.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. an Environmentally-friebiofuel biofuel for boiler, is characterized in that: by the component raw material of following weight percent, is prepared from by certain production method step, and each weight percentages of components sum is 100%;
Plam oil: 5%-85%;
Crude benzol: 5%-55%;
Methylal: 5%-65%;
Methyl alcohol: 5%-85%;
Oleic acid: 1%-15%;
Sorbester p17: 0.05%-5%;
Ritalin: 3%-35%;
Potassium permanganate: 0.05%-10%;
Ferrocene: 0.01%-5%.
2. a kind of Environmentally-friebiofuel biofuel for boiler according to claim 1, is characterized in that: the component raw material of weight percent can preferred following ratio formula, is prepared from by certain production method step:
Plam oil: 35%;
Crude benzol: 20%;
Methylal: 15%;
Methyl alcohol: 20%;
Oleic acid: 3%;
Sorbester p17: 0.5%;
Ritalin: 4%;
Potassium permanganate: 2%;
Ferrocene: 0.5%.
3. a kind of Environmentally-friebiofuel biofuel for boiler described in claim 1 or 2, it is characterized in that: described component raw material plam oil, also known as brown oil, brown skin oil, be the Vegetable oil lipoprotein extracting processing from the palm fibre fruit oil palm tree and obtain, other component raw material is technical grade industrial chemicals.
4. a kind of Environmentally-friebiofuel biofuel for boiler described in claim 1 or 2, is characterized in that: be made up of the method steps of following manufacture:
(1) various component raw material is measured respectively by above-mentioned formula rate for subsequent use;
(2) first preheated by plam oil, heating and temperature control, between 60 DEG C to 90 DEG C, makes it melt, and pumps in normal temperature and pressure stirred pot;
(3) turn on agitator, adds component raw material while stirring, is sequentially added into crude benzol, methylal, methyl alcohol, adds rear continuation stirring 10 minutes;
(4) agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into oleic acid, sorbester p17, ritalin, add rear continuation stirring 10 minutes;
(5) agitator continues, in stirring, to add component raw material while stirring, then be sequentially added into potassium permanganate, ferrocene, add rear continuation stirring 10 minutes;
(6) with electrically heated static mixer circulation mixing 30 minutes, after being uniformly mixed, leaving standstill 30 minutes, after filtration, be a kind of Environmentally-friebiofuel biofuel for boiler of the present invention.
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| CN201310338502.0A CN103351892B (en) | 2013-08-06 | 2013-08-06 | A kind of Environmentally-friebiofuel biofuel for boiler and preparation method thereof |
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| CN103351892A CN103351892A (en) | 2013-10-16 |
| CN103351892B true CN103351892B (en) | 2015-09-30 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1155000A (en) * | 1996-01-17 | 1997-07-23 | 呼世滨 | Compounded diesel oil and prepn. method thereof |
| CN1515656A (en) * | 2003-03-11 | 2004-07-28 | 深圳市金海田贸易有限公司 | High-effective energy-saving fuel oil cleaning agent and its production method |
| CN101948702A (en) * | 2010-09-30 | 2011-01-19 | 昆明理工大学 | Alcohol-based biological fuel oil for boiler and preparation method thereof |
| CN101974355A (en) * | 2010-10-18 | 2011-02-16 | 贾崇新 | Biological alcohol ether fuel |
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2013
- 2013-08-06 CN CN201310338502.0A patent/CN103351892B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1155000A (en) * | 1996-01-17 | 1997-07-23 | 呼世滨 | Compounded diesel oil and prepn. method thereof |
| CN1515656A (en) * | 2003-03-11 | 2004-07-28 | 深圳市金海田贸易有限公司 | High-effective energy-saving fuel oil cleaning agent and its production method |
| CN101948702A (en) * | 2010-09-30 | 2011-01-19 | 昆明理工大学 | Alcohol-based biological fuel oil for boiler and preparation method thereof |
| CN101974355A (en) * | 2010-10-18 | 2011-02-16 | 贾崇新 | Biological alcohol ether fuel |
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Effective date of registration: 20190918 Address after: 244000 Anhui city of Tongling Province on the east side of three Avenue (Datong Copper Industry Park) Patentee after: TONGLING LINGYANG CHEMICAL CO., LTD. Address before: Yuxi City, Yunnan province 652700 Xiushan Tonghai County Street No. 34 East River Village Lane Patentee before: Yang Bao Wei |
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