CN103666632A - Solid coal combustion improver and preparation method thereof - Google Patents

Solid coal combustion improver and preparation method thereof Download PDF

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Publication number
CN103666632A
CN103666632A CN201310731143.5A CN201310731143A CN103666632A CN 103666632 A CN103666632 A CN 103666632A CN 201310731143 A CN201310731143 A CN 201310731143A CN 103666632 A CN103666632 A CN 103666632A
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China
Prior art keywords
coal combustion
percent
promoting agents
preparation
combustion
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310731143.5A
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Chinese (zh)
Inventor
方建文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshu City No2 Thermal Power Co Ltd
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Changshu City No2 Thermal Power Co Ltd
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Priority to CN201310731143.5A priority Critical patent/CN103666632A/en
Publication of CN103666632A publication Critical patent/CN103666632A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a coal combustion improver and belongs to the technical filed of combustion. The coal combustion improver mainly comprises the following components and materials in weight ratio: 18 to 28 wt percent of calcium chloride, 8 to 18 wt percent of activated carbon, 5 to 15 percent of chromium trioxide, 20 to 30 wt percent of sodium carbonate, 16 to 25 wt percent of bis(pentamethylcyclopentadienyl)eisen and 8 to 16 wt percent of dolomite dust. The invention further discloses a preparation method of the coal combustion improver. The coal combustion improver provided by the invention remarkably increases the temperatures of inner flame and middle flame, improves the combustion efficiency within a combustion area, and obviously reduces flue gas discharge, the ringelman emittance of the flue gas is smaller than 1, and the coal saving rate can reach 17 to 26 percent.

Description

Solid-state coal combustion-promoting agents and preparation method
Technical field
The present invention relates to a kind of coal combustion-promoting agents and preparation method, is specifically a kind of for promoting coal combustion-promoting agents and the preparation method of coal burning quality, minimizing pollutant emission, belongs to field of combustion technology.
Background technology
Heat power plant is in daily production process, and a large amount of coal that unavoidably need to burn for improving coal combustion efficiency, reduce pollutant emission and reducing the phenomenons such as coking, conventionally suitably adds some ignition dopes and improves coal burning in fire coal.Combustion-supporting agent for fuel coal of the prior art, most of formula constituents are single, function singleness, be difficult to mix, and need minute sample to add and cause service routine loaded down with trivial details in use procedure, cannot reach expection combustion-supporting effect.
Summary of the invention
The technical problem that the present invention solves is to overcome above-mentioned defect, provide a kind of formula reasonable, mix, the obvious solid-state coal combustion-promoting agents of combustion-supporting effect and preparation method.
In order to solve the problems of the technologies described above, solid-state coal combustion-promoting agents provided by the invention, by the material of following component and weight ratio, made:
Calcium chloride: 18-28wt%, gac: 8-18wt%, chromium trioxide: 5-15wt%, sodium carbonate: 20-30wt%, full methyl ferrocene: 16-25wt%, ground dolomite: 8-16wt%.
As improvement, described solid-state coal combustion-promoting agents is made by the material of following component and weight ratio: calcium chloride: 23wt%, gac: 14wt%, chromium trioxide: 6wt%, sodium carbonate: 25wt%, full methyl ferrocene: 20wt%, ground dolomite: 12wt%.
The present invention also provides a kind of preparation method of solid-state coal combustion-promoting agents, comprises the following steps:
1), calcium chloride, chromium trioxide, sodium carbonate, the full methyl ferrocene of determining deal are dropped into and are stirred in stirrer after, standing 5-10 hour;
2), in step 1) compound in add again gac, the ground dolomite of determining deal to stir and at least stir 10 minutes in stirrer, obtain coal combustion-promoting agents.
As improvement, described step 1) time of repose in is 8 hours.
Beneficial effect of the present invention is: (1), coal combustion-promoting agents of the present invention have obviously improved the temperature of flame internal flame, middle flame, have improved the efficiency of combustion in combustion zone; (2), coal combustion-promoting agents cost of the present invention is lower, easily stir; (3), the discharge that can obviously lower flue gas, flue gas lingemann blackness < 1; (4), after use coal combustion-promoting agents of the present invention, coal-fired coal saving rate can reach 17-26%.
Embodiment
Below in conjunction with specific embodiment, the present invention is elaborated.
Embodiment 1
Solid-state coal combustion-promoting agents of the present invention is made by the material of following component and weight ratio:
Calcium chloride: 23wt%
Gac: 14wt%
Chromium trioxide: 6wt%
Sodium carbonate: 25wt%
Full methyl ferrocene: 20wt%
Ground dolomite: 12wt%;
Its preparation method comprises the following steps:
1), the calcium chloride of above-mentioned deal, chromium trioxide, sodium carbonate, full methyl ferrocene are dropped into and are stirred in stirrer after, standing 8 hours;
2), in step 1) compound in add again the gac of above-mentioned deal, ground dolomite to stir and at least stir 15 minutes in stirrer, obtain coal combustion-promoting agents.
Embodiment 2
Solid-state coal combustion-promoting agents of the present invention is made by the material of following component and weight ratio:
Calcium chloride: 28wt%
Gac: 8wt%
Chromium trioxide: 7wt%
Sodium carbonate: 20wt%
Full methyl ferrocene: 21wt%
Ground dolomite: 16wt%;
Its preparation method comprises the following steps:
1), the calcium chloride of above-mentioned deal, chromium trioxide, sodium carbonate, full methyl ferrocene are dropped into and are stirred in stirrer after, standing 10 hours;
2), in step 1) compound in add again the gac of above-mentioned deal, ground dolomite to stir and at least stir 21 minutes in stirrer, obtain coal combustion-promoting agents.
Embodiment 3
Solid-state coal combustion-promoting agents of the present invention is made by the material of following component and weight ratio:
Calcium chloride: 22wt%
Gac: 18wt%
Chromium trioxide: 10wt%
Sodium carbonate: 22wt%
Full methyl ferrocene: 18wt%
Ground dolomite: 10wt%;
Its preparation method comprises the following steps:
1), the calcium chloride of above-mentioned deal, chromium trioxide, sodium carbonate, full methyl ferrocene are dropped into and are stirred in stirrer after, standing 5 hours;
2), in step 1) compound in add again the gac of above-mentioned deal, ground dolomite to stir and at least stir 13 minutes in stirrer, obtain coal combustion-promoting agents.
Embodiment 4
Solid-state coal combustion-promoting agents of the present invention is made by the material of following component and weight ratio:
Calcium chloride: 18wt%
Gac: 12wt%
Chromium trioxide: 5wt%
Sodium carbonate: 28wt%
Full methyl ferrocene: 24wt%
Ground dolomite: 13wt%;
Its preparation method comprises the following steps:
1), the calcium chloride of above-mentioned deal, chromium trioxide, sodium carbonate, full methyl ferrocene are dropped into and are stirred in stirrer after, standing 9 hours;
2), in step 1) compound in add again the gac of above-mentioned deal, ground dolomite to stir and at least stir 30 minutes in stirrer, obtain coal combustion-promoting agents.
Embodiment 5
Solid-state coal combustion-promoting agents of the present invention is made by the material of following component and weight ratio:
Calcium chloride: 24wt%
Gac: 10wt%
Chromium trioxide: 12wt%
Sodium carbonate: 30wt%
Full methyl ferrocene: 16wt%
Ground dolomite: 8wt%;
Its preparation method comprises the following steps:
1), the calcium chloride of above-mentioned deal, chromium trioxide, sodium carbonate, full methyl ferrocene are dropped into and are stirred in stirrer after, standing 7 hours;
2), in step 1) compound in add again the gac of above-mentioned deal, ground dolomite to stir and at least stir 24 minutes in stirrer, obtain coal combustion-promoting agents.
Embodiment 6
Solid-state coal combustion-promoting agents of the present invention is made by the material of following component and weight ratio:
Calcium chloride: 21wt%
Gac: 9wt%
Chromium trioxide: 15wt%
Sodium carbonate: 21wt%
Full methyl ferrocene: 25wt%
Ground dolomite: 9wt%;
Its preparation method comprises the following steps:
1), the calcium chloride of above-mentioned deal, chromium trioxide, sodium carbonate, full methyl ferrocene are dropped into and are stirred in stirrer after, standing 6 hours;
2), in step 1) compound in add again the gac of above-mentioned deal, ground dolomite to stir and at least stir 17 minutes in stirrer, obtain coal combustion-promoting agents.
Above-mentioned these embodiments are only for the present invention is described, but do not limit the scope of the invention, and after having read the present invention, those skilled in the art all fall within the application's claims limited range to the modification of the various equivalent form of values of the present invention.

Claims (4)

1. a solid-state coal combustion-promoting agents, is characterized in that it is made by the material of following component and weight ratio:
Calcium chloride: 18-28wt%
Gac: 8-18wt%
Chromium trioxide: 5-15wt%
Sodium carbonate: 20-30wt%
Full methyl ferrocene: 16-25wt%
Ground dolomite: 8-16wt%.
2. solid-state coal combustion-promoting agents according to claim 1, is characterized in that it is made by the material of following component and weight ratio:
Calcium chloride: 23wt%
Gac: 14wt%
Chromium trioxide: 6wt%
Sodium carbonate: 25wt%
Full methyl ferrocene: 20wt%
Ground dolomite: 12wt%.
3. the preparation method of solid-state coal combustion-promoting agents according to claim 1 and 2, is characterized in that comprising the following steps:
1), calcium chloride, chromium trioxide, sodium carbonate, the full methyl ferrocene of determining deal are dropped into and are stirred in stirrer after, standing 5-10 hour;
2), in step 1) compound in add again gac, the ground dolomite of determining deal to stir and at least stir 10 minutes in stirrer, obtain coal combustion-promoting agents.
4. the preparation method of solid-state coal combustion-promoting agents according to claim 3, is characterized in that: the time of repose described step 1) is 8 hours.
CN201310731143.5A 2013-12-26 2013-12-26 Solid coal combustion improver and preparation method thereof Pending CN103666632A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310731143.5A CN103666632A (en) 2013-12-26 2013-12-26 Solid coal combustion improver and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201310731143.5A CN103666632A (en) 2013-12-26 2013-12-26 Solid coal combustion improver and preparation method thereof

Publications (1)

Publication Number Publication Date
CN103666632A true CN103666632A (en) 2014-03-26

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104293412A (en) * 2014-09-10 2015-01-21 济南大学 Preparation method of coal combustion improver
CN105802696A (en) * 2016-05-25 2016-07-27 常州市东南热电有限公司 Method for promoting coal combustion
CN105802695A (en) * 2016-05-25 2016-07-27 常州市东南热电有限公司 Combustion improver for improving coal combustion efficiency
CN109135867A (en) * 2018-09-19 2019-01-04 郑州市晟火冶金节能材料有限公司 Solid combustion-supporting agent for fuel coal for blast furnace

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101348743A (en) * 2008-09-05 2009-01-21 陈宏谋 Coal-saving devulcanized coke cleaning clean synergistic agent and preparation technique thereof
CN101372642A (en) * 2008-10-29 2009-02-25 陈士进 Efficient coal combustion energy-saving combustion adjuvant and preparation thereof
CN101775323A (en) * 2010-02-09 2010-07-14 上海光铧科技有限公司 Preparation method for coal combustion improver
CN101870899A (en) * 2010-05-21 2010-10-27 广州高成环保科技有限公司 Coal-saving decarburization combustion improver
CN102191110A (en) * 2011-04-19 2011-09-21 宜兴市科奇化工有限公司 Fire coal combustion improver
CN102199466A (en) * 2011-04-21 2011-09-28 江苏锋泰建材科技有限公司 Coal-saving combustion-supporting additive

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101348743A (en) * 2008-09-05 2009-01-21 陈宏谋 Coal-saving devulcanized coke cleaning clean synergistic agent and preparation technique thereof
CN101372642A (en) * 2008-10-29 2009-02-25 陈士进 Efficient coal combustion energy-saving combustion adjuvant and preparation thereof
CN101775323A (en) * 2010-02-09 2010-07-14 上海光铧科技有限公司 Preparation method for coal combustion improver
CN101870899A (en) * 2010-05-21 2010-10-27 广州高成环保科技有限公司 Coal-saving decarburization combustion improver
CN102191110A (en) * 2011-04-19 2011-09-21 宜兴市科奇化工有限公司 Fire coal combustion improver
CN102199466A (en) * 2011-04-21 2011-09-28 江苏锋泰建材科技有限公司 Coal-saving combustion-supporting additive

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104293412A (en) * 2014-09-10 2015-01-21 济南大学 Preparation method of coal combustion improver
CN104293412B (en) * 2014-09-10 2016-06-22 济南大学 Preparation method of coal combustion improver
CN105802696A (en) * 2016-05-25 2016-07-27 常州市东南热电有限公司 Method for promoting coal combustion
CN105802695A (en) * 2016-05-25 2016-07-27 常州市东南热电有限公司 Combustion improver for improving coal combustion efficiency
CN105802696B (en) * 2016-05-25 2019-03-19 常州市东南热电有限公司 A method of promoting coal burning
CN105802695B (en) * 2016-05-25 2019-04-23 常州市东南热电有限公司 A kind of combustion adjuvant improving coal combustion efficiency
CN109135867A (en) * 2018-09-19 2019-01-04 郑州市晟火冶金节能材料有限公司 Solid combustion-supporting agent for fuel coal for blast furnace

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Application publication date: 20140326