CN103351892A - Environmentally-friendly biofuel for boiler and preparation method thereof - Google Patents
Environmentally-friendly biofuel for boiler and preparation method thereof Download PDFInfo
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- CN103351892A CN103351892A CN2013103385020A CN201310338502A CN103351892A CN 103351892 A CN103351892 A CN 103351892A CN 2013103385020 A CN2013103385020 A CN 2013103385020A CN 201310338502 A CN201310338502 A CN 201310338502A CN 103351892 A CN103351892 A CN 103351892A
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Abstract
The invention relates to an environmentally-friendly biofuel for a boiler and a preparation method thereof. The fuel is high in calorific value, easy to ignite, strong in firepower, low in sulfur content and small in corrosion on combustion equipment to prolong the service life of the boiler; the fuel is high in oxygen content, thereby being easily forming oxygen enriched combustion and improving the combustion efficiency; the fuel is low in viscosity, good in fluidity, free of pre-heating when in use, easy to atomize, small in atomization particles, good in atomization, complete in combustion and unlikely to coke, and little accumulated ash is generated, thereby reducing the accumulated carbon and attrition and preventing the nozzle from being easily blocked; the fuel is uniform in atomization and balanced in combustion so as to improve the combustion environment and reduce the nitrogen oxide generation; and the fuel is complete in combustion, small in pollutant emission, small in air pollution and good in environmental protection effect. The biofuel can be used for saving and replacing such traditional fossil energy sources as mineral fuel and high-pollution fuel, thereby being a clean and environmentally-friendly biofuel.
Description
Technical field
The present invention relates to propellant combination and preparation method thereof, environment friendly biological fuel oil that especially a kind of Industrial Boiler is used and preparation method thereof is a kind of new green environment protection biofuel newly developed, belongs to the new and renewable sources of energy field.
Background technology
The environment friendly biological fuel oil is a kind of green, renewable energy source cleaning, environmental protection, is a kind of synthetic fuel oil, is the substitute of traditional mineral petrochemical industry fuel oil.Tap a new source of energy, development substitutes clean fuel, and the to protect mankind living environment meets the theory of Sustainable development, scientific development.Save energy is improved energy structure, preserves the ecological environment and tackles climate change, sets up the sustainable energy system take new and renewable sources of energy as main body, is the fundamental way that realizes the green low-carbon development.
China is in industrialization, urbanization Rapid development stage, and the energy expenditure rapid growth makes several near limits of holding capacity of resources and environment, the external interdependency of the energy is surging, energy security ensures and faces a severe challenge, and the energy and environmental problem have become the important factor that restricts socio-economic development.
Boiler is the thermal hardware with High Temperature High Pressure, and enterprises and institutions and all trades and professions are widely used, and along with developing rapidly of economy, the application of boiler is risen just year by year.Boiler is great energy consumption equipment, and the waste gas of burning and exhausting also is the air-polluting main source.Along with improving and severe law enforcement for environmental protection of the every environmental protection policy of government, city proper and ecological Industrial Area are forbidden fire coal, and the various high pollution fuel of forbidding burning are implemented high pollution fuel and prohibited the management of combustion district.Traditional boiler oil is such as coal, coal tar, heavy oil, residual oil; Pollutant load surpasses the fuel such as the solar oil, kerosene, artificial coal gas of national regulation limit value and all is put into high pollution fuel and is limited use, and this substitutes clean fuel and become inevitable for seeking.
Traditional boiler oil all is the mineral fossil energy, belongs to hydrocarbon polymer, contains the nonhydrocarbon compound, contains colloid, bituminous matter, sulfide, nitride etc., and sulfur-bearing is high, and viscosity is large, and oxydant is low.
Fuel oil sulfur-bearing Gao Shihui causes boiler component corrosion, and corrosion can cause structure deteriorate, affect the available rate of boiler, shortening boiler work-ing life.
Fuel efficient is ignition in boiler furnace promptly, fuel oil must be carried out good atomizing in the moment that enters burner hearth, fuel oil catch fire before with air good mixing and atomizing, very important, increasing the combustion reactions area of fuel oil, the elaioleucite needed oxygen that burns can be supplied with in time, make the burning of elaioleucite faster, burning is healed fully, and discharging is fewer, and pollution is lighter.Not good with air mixed in advance before if catch fire, atomization badness is allowed to condition at the burning of burner hearth inner edge mixing limit, then can make because of anoxycausis hydrocarbons decompose, generates carbon black, forms soot.
Fuel-viscosity variation is large, poor fluidity, difficult atomizing.Because of the difficulty that atomizes, atomizing particle is large, causes incomplete combustion, and boiler thermal output is reduced, and forms carbon distribution, stops up easily oil nozzle; Fuel oil causes boiler furnace localized hyperthermia high pressure because of the atomizing skewness, and it is unbalanced to burn, and affects the operating performance of boiler.
The fuel oil oxydant is low, because of atomization badness, supplies hypoxgia during burning, anoxycausis, and it is insufficient to cause burning, and causes a large amount of carbon granules and oil droplet to amass and falls heated surface at the end of boiler, forms dangerous burning, the discharging black smoke.
Fuel oil contains the nonhydrocarbon compound, contains colloid, bituminous matter, sulfide, amount of nitrides height, because of incomplete combustion, causes pollutant load increase in the combustion exhaust, and objectionable constituent increase, and the dust-laden particulate matter increases.
The oil inflame exhaust gas emission surpasses the environmental protection limit value, will cause topsoil, forms haze weather, reduces Air quality, and serious environment pollution has a strong impact on people's public health and social stability.
Summary of the invention
The purpose of this invention is to provide a kind of boiler environment friendly biological fuel oil, it is low to have a sulfur-bearing, and calorific value is high, oxydant is high, viscosity is low, good fluidity, easily atomizing, burning fully, pollutant emission is few, and is little to atmospheric pollution, and environment protecting is good, saving and substitute boiler with traditional fossil energies such as mineral fuel and high pollution fuel, is a kind of green bio fuel of clean environment firendly.
Another object of the present invention provides the method steps that a kind of boiler is used the manufacture of environment friendly biological fuel oil.
The present invention for achieving the above object, the technical scheme that provides is as follows:
Technical scheme of the present invention, a kind of boiler environment friendly biological fuel oil mainly by the component raw material of following weight percent, is prepared from by certain production method step:
Plam oil: 5%-85%;
Crude benzol: 5%-55%;
Methylal〔Su〕: 5%-65%;
Methyl alcohol: 5%-85%;
Oleic acid: 1%-15%;
Sorbester p17: 0.05%-5%;
Ritalin: 3%-35%;
Potassium permanganate: 0.05%-10%;
Ferrocene: 0.01%-5%.
Technical scheme of the present invention, a kind of boiler environment friendly biological fuel oil, the component raw material of weight percent can preferred following ratio prescription, is prepared from by certain production method step:
Plam oil: 35%;
Crude benzol: 20%;
Methylal〔Su〕: 15%;
Methyl alcohol: 20%;
Oleic acid: 3%;
Sorbester p17: 0.5%;
Ritalin: 4%;
Potassium permanganate: 2%;
Ferrocene: 0.5%.
Technical scheme of the present invention, a kind of boiler environment friendly biological fuel oil, described component raw material plam oil claims again brown oil, brown skin oil, be palm fibre fruit from the oil palm tree extract processing and Vegetable oil lipoprotein, other component raw material is the technical grade industrial chemicals.
Technical scheme of the present invention, a kind of boiler environment friendly biological fuel oil, the method steps of manufacture is:
(1) it is for subsequent use to measure respectively various component raw material by above-mentioned formula rate;
(2) first plam oil is preheated, heating and temperature control makes its fusing between 60 ℃ to 90 ℃, pump into normal temperature and pressure
In the stirred pot;
(3) turn on agitator adds component raw material while stirring, is sequentially added into crude benzol, methylal〔Su〕, methyl alcohol, adds rear continuation and stirs 10 minutes;
(4) during agitator continues to stir, add while stirring component raw material, be sequentially added into again oleic acid, sorbester p17, ritalin, add rear continuation and stirred 10 minutes;
(5) during agitator continues to stir, add while stirring component raw material, be sequentially added into again potassium permanganate, ferrocene, add rear continuation and stirred 10 minutes;
(6) mixed 30 minutes with the circulation of electrically heated static mixer, after mixing, left standstill 30 minutes, be a kind of boiler environment friendly biological fuel oil of the present invention after the filtration.
Advantage of the present invention and beneficial effect are:
A kind of environment friendly biological fuel oil, the environment friendly biological fuel oil used of a kind of boiler specifically, this fuel oil has the calorific value height, easily igniting, firepower is powerful; Sulfur-bearing is low, and is little to combustion equipment corrosion, but prolonged boiler work-ing life; Oxydant is high, easily forms oxygen-enriched combusting, improves efficiency of combustion; Viscosity is low, and good fluidity need not preheat during use, easily atomizing, and atomizing particle is tiny, and atomizing is good, and sufficient combustion is difficult for coking, and dust stratification is few, reduces carbon deposit and wearing and tearing, is difficult for stopping up burner; Burning is complete, and pollutant emission is few, and is little to atmospheric pollution, and environment protecting is good, save to substitute boiler with traditional fossil energies such as mineral fuel and high pollution fuel, and be a kind of green bio fuel of clean environment firendly.
Embodiment
Below by specific embodiment the present invention is described in further detail, but is not limited to embodiment, following examples are descriptive, are not determinate, can not limit protection scope of the present invention with this.Below the described deal of each embodiment be the weight deal.
Embodiment 1:
A kind of boiler environment friendly biological fuel oil, it is for subsequent use that component raw material is chosen in by weight metering: plam oil: 20 kilograms; 25 kilograms of crude benzol; Methylal〔Su〕: 20 kilograms; Methyl alcohol: 25 kilograms; Oleic acid: 4 kilograms; Sorbester p17: 0.4 kilogram; Ritalin: 2 kilograms; Potassium permanganate: 3 kilograms; Ferrocene: 0.6 kilogram.
A kind of boiler environment friendly biological fuel oil, the method steps of manufacture is: first plam oil is preheated, be heated to 60 ℃, make its fusing, pump in the normal temperature and pressure stirred pot; Turn on agitator adds component raw material while stirring, is sequentially added into crude benzol, methylal〔Su〕, methyl alcohol, adds rear continuation and stirs 10 minutes; Agitator adds component raw material in continuing to stir while stirring, is sequentially added into oleic acid, sorbester p17, ritalin again, adds rear continuation and stirs 10 minutes; Agitator adds component raw material in continuing to stir while stirring, is sequentially added into potassium permanganate, ferrocene again, adds rear continuation and stirs 10 minutes; Then mixed 30 minutes with the circulation of electrically heated static mixer, after mixing, left standstill 30 minutes, be 100 kilograms of environment friendly biological fuel oils of a kind of boiler of the present invention after the filtration.
Embodiment 2:
A kind of boiler environment friendly biological fuel oil, it is for subsequent use that component raw material is chosen in by weight metering: plam oil: 35 kilograms; 20 kilograms of crude benzol; Methylal〔Su〕: 15 kilograms; Methyl alcohol: 20 kilograms; Oleic acid: 3 kilograms; Sorbester p17: 0.5 kilogram; Ritalin: 4 kilograms; Potassium permanganate: 2 kilograms; Ferrocene: 0.5 kilogram.
A kind of boiler environment friendly biological fuel oil, the method steps of manufacture is: first plam oil is preheated, be heated to 70 ℃, make its fusing, pump in the normal temperature and pressure stirred pot; Turn on agitator adds component raw material while stirring, is sequentially added into crude benzol, methylal〔Su〕, methyl alcohol, adds rear continuation and stirs 10 minutes; Agitator adds component raw material in continuing to stir while stirring, is sequentially added into oleic acid, sorbester p17, ritalin again, adds rear continuation and stirs 10 minutes; Agitator adds component raw material in continuing to stir while stirring, is sequentially added into potassium permanganate, ferrocene again, adds rear continuation and stirs 10 minutes; Then mixed 30 minutes with the circulation of electrically heated static mixer, after mixing, left standstill 30 minutes, be 100 kilograms of environment friendly biological fuel oils of a kind of boiler of the present invention after the filtration.
Embodiment 3:
A kind of boiler environment friendly biological fuel oil, it is for subsequent use that component raw material is chosen in by weight metering: plam oil: 45 kilograms; 15 kilograms of crude benzol; Methylal〔Su〕: 10 kilograms; Methyl alcohol: 20 kilograms; Oleic acid: 2 kilograms; Sorbester p17: 0.6 kilogram; Ritalin: 4 kilograms; Potassium permanganate: 3 kilograms; Ferrocene: 0.4 kilogram.
A kind of boiler environment friendly biological fuel oil, the method steps of manufacture is: first plam oil is preheated, be heated to 80 ℃, make its fusing, pump in the normal temperature and pressure stirred pot; Turn on agitator adds component raw material while stirring, is sequentially added into crude benzol, methylal〔Su〕, methyl alcohol, adds rear continuation and stirs 10 minutes; Agitator adds component raw material in continuing to stir while stirring, is sequentially added into oleic acid, sorbester p17, ritalin again, adds rear continuation and stirs 10 minutes; Agitator adds component raw material in continuing to stir while stirring, is sequentially added into potassium permanganate, ferrocene again, adds rear continuation and stirs 10 minutes; Then mixed 30 minutes with the circulation of electrically heated static mixer, after mixing, left standstill 30 minutes, be 100 kilograms of environment friendly biological fuel oils of a kind of boiler of the present invention after the filtration.
The above only is preferred embodiment of the present invention, and is in order to limit the present invention, within the spirit and principles in the present invention not all, any modification of doing, is equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. a boiler is characterized in that: by the component raw material of following weight percent, be prepared from by certain production method step with environment friendly biological fuel oil and preparation method thereof:
Plam oil: 5%-85%;
Crude benzol: 5%-55%;
Methylal〔Su〕: 5%-65%;
Methyl alcohol: 5%-85%;
Oleic acid: 1%-15%;
Sorbester p17: 0.05%-5%;
Ritalin: 3%-35%;
Potassium permanganate: 0.05%-10%;
Ferrocene: 0.01%-5%.
2. a kind of boiler environment friendly biological fuel oil according to claim 1 is characterized in that: the component raw material of weight percent can preferred following ratio prescription, is prepared from by certain production method step:
Plam oil: 35%;
Crude benzol: 20%;
Methylal〔Su〕: 15%;
Methyl alcohol: 20%;
Oleic acid: 3%;
Sorbester p17: 0.5%;
Ritalin: 4%;
Potassium permanganate: 2%;
Ferrocene: 0.5%.
3. claim 1 or 2 described a kind of boiler environment friendly biological fuel oils, it is characterized in that: described component raw material plam oil, claim again brown oil, brown skin oil, be palm fibre fruit from the oil palm tree extract processing and Vegetable oil lipoprotein, other component raw material is the technical grade industrial chemicals.
4. claim 1 or 2 described a kind of boiler environment friendly biological fuel oils is characterized in that: be to be made by the method steps of following manufacture:
(1) it is for subsequent use to measure respectively various component raw material by above-mentioned formula rate;
(2) first plam oil is preheated, heating and temperature control makes its fusing between 60 ℃ to 90 ℃, pump into normal temperature and pressure
In the stirred pot;
(3) turn on agitator adds component raw material while stirring, is sequentially added into crude benzol, methylal〔Su〕, methyl alcohol, adds rear continuation and stirs 10 minutes;
(4) during agitator continues to stir, add while stirring component raw material, be sequentially added into again oleic acid, sorbester p17, ritalin, add rear continuation and stirred 10 minutes;
(5) during agitator continues to stir, add while stirring component raw material, be sequentially added into again potassium permanganate, ferrocene, add rear continuation and stirred 10 minutes;
(6) mixed 30 minutes with the circulation of electrically heated static mixer, after mixing, left standstill 30 minutes, be a kind of boiler environment friendly biological fuel oil of the present invention after the filtration.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310338502.0A CN103351892B (en) | 2013-08-06 | 2013-08-06 | A kind of Environmentally-friebiofuel biofuel for boiler and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310338502.0A CN103351892B (en) | 2013-08-06 | 2013-08-06 | A kind of Environmentally-friebiofuel biofuel for boiler and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103351892A true CN103351892A (en) | 2013-10-16 |
| CN103351892B CN103351892B (en) | 2015-09-30 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105950230A (en) * | 2016-04-25 | 2016-09-21 | 杨宝伟 | Green and environment-friendly diesel oil for vehicles and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1155000A (en) * | 1996-01-17 | 1997-07-23 | 呼世滨 | Compounded diesel oil and prepn. method thereof |
| CN1515656A (en) * | 2003-03-11 | 2004-07-28 | 深圳市金海田贸易有限公司 | High-effective energy-saving fuel oil cleaning agent and its production method |
| CN101948702A (en) * | 2010-09-30 | 2011-01-19 | 昆明理工大学 | Alcohol-based biological fuel oil for boiler and preparation method thereof |
| CN101974355A (en) * | 2010-10-18 | 2011-02-16 | 贾崇新 | Biological alcohol ether fuel |
-
2013
- 2013-08-06 CN CN201310338502.0A patent/CN103351892B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1155000A (en) * | 1996-01-17 | 1997-07-23 | 呼世滨 | Compounded diesel oil and prepn. method thereof |
| CN1515656A (en) * | 2003-03-11 | 2004-07-28 | 深圳市金海田贸易有限公司 | High-effective energy-saving fuel oil cleaning agent and its production method |
| CN101948702A (en) * | 2010-09-30 | 2011-01-19 | 昆明理工大学 | Alcohol-based biological fuel oil for boiler and preparation method thereof |
| CN101974355A (en) * | 2010-10-18 | 2011-02-16 | 贾崇新 | Biological alcohol ether fuel |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105950230A (en) * | 2016-04-25 | 2016-09-21 | 杨宝伟 | Green and environment-friendly diesel oil for vehicles and preparation method thereof |
| CN105950230B (en) * | 2016-04-25 | 2018-07-17 | 杨宝伟 | A kind of vehicle environmentally protective diesel oil and preparation method thereof |
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| CN103351892B (en) | 2015-09-30 |
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Effective date of registration: 20190918 Address after: 244000 Anhui city of Tongling Province on the east side of three Avenue (Datong Copper Industry Park) Patentee after: TONGLING LINGYANG CHEMICAL CO., LTD. Address before: Yuxi City, Yunnan province 652700 Xiushan Tonghai County Street No. 34 East River Village Lane Patentee before: Yang Bao Wei |
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