CN103276500B - Super cotton-like cashmere double-side fabric and production process thereof - Google Patents
Super cotton-like cashmere double-side fabric and production process thereof Download PDFInfo
- Publication number
- CN103276500B CN103276500B CN201310212993.4A CN201310212993A CN103276500B CN 103276500 B CN103276500 B CN 103276500B CN 201310212993 A CN201310212993 A CN 201310212993A CN 103276500 B CN103276500 B CN 103276500B
- Authority
- CN
- China
- Prior art keywords
- cotton
- cashmere
- dyeing
- acetic acid
- glacial acetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 210000000085 cashmere Anatomy 0.000 title claims abstract description 52
- 239000004744 fabric Substances 0.000 title claims abstract description 50
- 238000004519 manufacturing process Methods 0.000 title description 8
- 229920000742 Cotton Polymers 0.000 claims abstract description 68
- 230000002441 reversible effect Effects 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 66
- 238000004043 dyeing Methods 0.000 claims description 40
- 229960000583 acetic acid Drugs 0.000 claims description 33
- 239000012362 glacial acetic acid Substances 0.000 claims description 33
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 25
- 239000000975 dye Substances 0.000 claims description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 20
- 238000002203 pretreatment Methods 0.000 claims description 20
- 238000005516 engineering process Methods 0.000 claims description 18
- 238000009992 mercerising Methods 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 17
- 238000005406 washing Methods 0.000 claims description 16
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- 229910021529 ammonia Inorganic materials 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 10
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 10
- 229930182490 saponin Natural products 0.000 claims description 10
- 150000007949 saponins Chemical class 0.000 claims description 10
- 235000017550 sodium carbonate Nutrition 0.000 claims description 10
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 9
- 238000012805 post-processing Methods 0.000 claims description 9
- 238000009991 scouring Methods 0.000 claims description 9
- 238000004513 sizing Methods 0.000 claims description 9
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 7
- 239000010446 mirabilite Substances 0.000 claims description 7
- 102000004190 Enzymes Human genes 0.000 claims description 6
- 108090000790 Enzymes Proteins 0.000 claims description 6
- 238000004045 reactive dyeing Methods 0.000 claims description 5
- 238000003287 bathing Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000007670 refining Methods 0.000 claims description 3
- 239000002759 woven fabric Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000004061 bleaching Methods 0.000 claims 2
- 239000000985 reactive dye Substances 0.000 claims 1
- 230000037303 wrinkles Effects 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 17
- 238000001035 drying Methods 0.000 description 11
- RNLQIBCLLYYYFJ-UHFFFAOYSA-N amrinone Chemical compound N1C(=O)C(N)=CC(C=2C=CN=CC=2)=C1 RNLQIBCLLYYYFJ-UHFFFAOYSA-N 0.000 description 7
- 229960002105 amrinone Drugs 0.000 description 7
- 238000013461 design Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000009990 desizing Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000010792 warming Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000009955 starching Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241001062009 Indigofera Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 239000013066 combination product Substances 0.000 description 2
- 229940127555 combination product Drugs 0.000 description 2
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 2
- 230000009245 menopause Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 208000016261 weight loss Diseases 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000003079 width control Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
The invention relates to super cotton-like cashmere double-side fabric. The super cotton-like cashmere double-side fabric is characterized by being made of supercool/cotton blended yarn, cotton/cashmerino blended yarn, and mercerized gassed woolen yarn. The super cotton-like cashmere double-side fabric is in double-side weave; warps are made of 7.3tex Supercool/cotton blended yarn; and accordingly the whole cover of the fabric reveals no warp but weft, the weft front side of the fabric is made of 18.2tex mercerized gassed woolen yarn, and the weft reverse side is made of 18.2tex cotton/cashmerino blended yarn. Super cotton-like fiber is high in strength, wear-resistant, highly breathable, antistatic, wrinkle-resistant, and as warm as cashmerino. With perfect combination of wefts and warps by the special double-side weave, the fabric looks and feels different on two sides.
Description
Technical field
The present invention relates to a kind of super imitative cotton cashmere Double-face fabric and preparation technology thereof.
Background technology
In recent years, global climate is drastic change day by day, more focuses on the comfortableness of textile product while that more and more people pursuing functional.Cashmere product warmth retention property, good hygroscopicity, but its wet-guide quick-drying is poor, under the environment of relative humidity lower than 45%, especially has the indoor of heating installation winter, easily produces electrostatic, and have prodding and itching feeling, wear next to the skin comfortableness difference; In addition, low, the easy pilling of cashmere intensity, easy damaged under basic dyeing environment, need with other fabrics with the use of.How to produce cloth cover gloss, the perspire of smooth, high-strength, wear-resisting, high moisture absorption height, antistatic wrinkle resistance, have the fabric of the cold-proof comfort of merino cashmere concurrently, become the problem of the present invention's research.
Summary of the invention
An object of the present invention is to overcome above-mentioned deficiency, provides a kind of cloth cover gloss, the perspire of smooth, high-strength, wear-resisting, high moisture absorption height, warming super imitative cotton cashmere Double-face fabric.
Two of object of the present invention is the preparation technology providing a kind of super imitative cotton cashmere Double-face fabric.
The object of the present invention is achieved like this:
A kind of super imitative cotton cashmere Double-face fabric, it singes line for raw material with Supercool/ cotton (80/20) blended yarn, cotton/merino cashmere (80/20) blended yarn, mercerising, selects two-sided tissue, and warp thread adopts the super imitative cotton/silk/cotton blended yarn (80/20) of 7.3tex; The aobvious warp of aobvious latitude on overall cloth cover color, broadwise front is that 18.2tex mercerising is singed line, and broadwise reverse side is 18.2tex cotton/merino cashmere (80/20).
Concrete specification is: [Supercool/ cotton (80/20) 7.3tex × 2] × [mercerising singe line 18.2tex × 2+ cotton/merino cashmere (80/20) 18.2tex]/524 (root/10cm) × 472 (root/10cm)/145 ~ 147.5cm 1/3+3/1 reversible twill color-woven fabric.Warp-wise tightness 74%, broadwise front tightness 53.2%, broadwise reverse side tightness 37.6%, total tightness degree 97.8%, Stability Analysis of Structures.
A preparation technology for super imitative cotton cashmere Double-face fabric, the dyeing course in described preparation process comprises:
(1) the grayish green dyeing of Supercool/ cotton, adopts first dye to wash the process route of after stain cotton;
Pre-treatment: boil yarn refining agent 2g/l
Soda ash 2g/l
80℃×30min
Dye is washed: i.e. Supercool stock-dye
Pre-treatment: bleach stable finishing agent CLARITE ONE (Hensel steps) 1.5g/l
Caustic soda 1.5g/l
Hydrogen peroxide 3.5g/l 100 DEG C × 30min
Glacial acetic acid 3g/l 50 DEG C × 10min
Deoxidation enzyme 0.1g/l normal temperature × 15min
Dyeing: disperse red AC-E (Amrinone is grand) 0.12%
Disperse blue AC-E (Amrinone is grand) 0.43%
Disperse yellow AC-E (Amrinone is grand) 0.31%
Glacial acetic acid 2g/l
High temperature levelling agent 1.5g/l 120 DEG C × 15min
Dye is cotton:
Pre-treatment: glacial acetic acid 1g/l
Yarn 60 DEG C × 10min is boiled before dye
Dyeing: Red FN-R 0.13%
Vapour bar 4R indigo plant 0.31%
Vapour clings to yellow FN-ZR 0.45%
Dispersant DK(Huizhou Hua Weixing Fine Chemical Co., Ltd) 1.5g/l
Glauber salt 40g/l
Soda ash 15g/l 60 DEG C × 30min
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent LOCANIT S-A (section is triumphant) 1g/l 90 DEG C × 10min
Glacial acetic acid 0.5g/l
Comfortable finishing agent ULTRAPHIL DCW 1.5g/l 55 DEG C × 20min;
Because Supercool is by chemical modification, regain, hydrophilicity improve, and Dye up-take is high, by test of many times, we use Amrinone grand, reduce dyeing temperature, improve dyeing evenness and COLOR FASTNESS, overcome the easy dyeing flower problem of conventional disperse dyestuff, economize energy.
(2) the doe dyeing of cotton/merino cashmere (80/20):
Pre-treatment: Tea Saponin C-200 2g/l 80 DEG C × 30min
Glacial acetic acid 2g/l 50 DEG C × 10min
Dyeing: active yellow GR (An Nuosu) 0.85%
Active red E-3B(pacifies promise element) 0.4%
Reactive blue BF(pacifies promise element) 0.612%
Dispersant DK(Huizhou Hua Weixing Fine Chemical Co., Ltd) 1g/l
Na
2sO
4(glauber salt) 50g/l
Na
2cO
3(soda ash) 15g/l
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent LOCANIT S-A (section is triumphant) 1g/l 95 DEG C × 10min
Glacial acetic acid 0.5g/l
Softener ZL-520(stands upright in Hangzhou Chemical Co., Ltd.) 3.5g/l 55 DEG C × 20min.
(3) mercerising is singed the dyeing of line off-white:
Pre-treatment: CLARITE ONE 2g/l
Caustic soda 2g/l
Hydrogen peroxide 6g/l 110 DEG C × 30min
Glacial acetic acid 3g/l 50 DEG C × 10min
Deoxidation enzyme 0.1g/l normal temperature 15min
Dyeing: K type active yellow HF-2GR 150%(Korea S Jing Ren) 0.0224%
K type active red HF-6BN (Korea S Jing Ren) 0.004%
The active deep blue K-BF(Korea S Jing Ren of K type) 0.0038%
Dispersant DK(Huizhou Hua Weixing Fine Chemical Co., Ltd) 1g/l
Na
2sO
4(glauber salt) 10g/l
Na
2cO
3(soda ash) 5g/l
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent LOCANIT S-A (section is triumphant) 1g/l 90 DEG C × 10min
Glacial acetic acid 0.5g/l
Softener ZL-520(stands upright in Hangzhou Chemical Co., Ltd.) 3.5g/l 55 DEG C × 20min.
In described preparation process, finishing technique is: washing → liquefied ammonia → pH washing → tentering → fluffing → stentering forming → preshrunk in advance.
Because back weft merino cashmere is not alkaline-resisting, table latitude thick yarn selects mercerising to singe line, and warp-wise selects supercool/ cotton (80/20) 7.3tex without the need to caustic soda mercerising, to reach dimensionally stable by liquid ammonia finishing in addition.
(1) wash: Japanese TSUDAKOMA desizing machine rear car
The speed of a motor vehicle: 50m/min banks up temperature: 60 DEG C
Bank up the time: 45min washing temperature: 95 DEG C
Nonionic penetrant: 2g/L
(2) liquefied ammonia: YAZL-160 liquefied ammonia machine
The speed of a motor vehicle: 20 m/min ammonia largest loop amount: 600Kg/h
Fall width: 144-147cm
(3) pH washing: Japanese TSUDAKOMA desizing machine rear car
The speed of a motor vehicle: 60m/min temperature: 90 DEG C
(4) tentering in advance: German MONFORTS setting machine
The speed of a motor vehicle: 60m/min drying room temperature: 120 DEG C are rolled power: 30N/mm
Fall width: 148CM
(5) fluff: the efficient raising machine of MB476-200
Combination product designs, and front is bright and clean smooth, and reverse side is comfortable warming, and we carry out reverse side fluffing to product after liquid ammonia finishing, improves the wearability of fabric further.
The speed of a motor vehicle: 14m/min tension force: 80 roller speed: 40 turns/min
Carbon roller rotating speed: 1200 turns/min sanding face: anti-
(6) sizing arranges: German MONFORTS setting machine
The speed of a motor vehicle: 50m/min rolls power: 30N/mm
Preliminary drying temperature: 80 DEG C of drying room temperature: 120 DEG C
Air quantity: upper 90% time 80% humidity: 9%
Fall width: 148cm
Citric acid: 0.8g/l DT-508:20g/l
(7) preshrunk: German MONFORTS preshrinking machine
Before conscientiously carrying out product contracting, washing DIMENSIONAL STABILITY is tested, and carries out process monitoring, guarantees that shrink qualification rate reaches 100%.
The speed of a motor vehicle: 50m/min falls width: 145-148cm.
In described preparation technology, without slashing technique.
Compared with prior art, the invention has the beneficial effects as follows:
1) this product had both maintained the original characteristic of polyster fibre on raw material, developed again the Moisture absorbing & quick drying property in its excellent cross section, structural chemistry modification, preferred blending ratio, and fabric is comfortable, is easy to arrange; Preferred cotton/merino cashmere blending ratio, improves the skin-friendly of fabric, warmth retention property and not scratchy; Mercerizing thread of singing is selected to make surface weft yarn, cloth cover gloss;
2) this product is in design concept, selects two-sided tissue, and table back weft floats long line and forms lumen, reduce cross-ventilation, form heat-insulation warm keeping layer, optimize longitude and latitude yarn and configure, overcoming 18.2texX2, to weave latitude crimp large, arranging width reduces with the crimp of 18.2tex weaving yarns latitude little, arrange the problem that width contracting is easy to foaming greatly, both combine, and after reaching finished product washing, cloth cover is smooth, three kinds of materials are shown what one's be, and wearability is good;
3) with Tea Saponin C-200, " boil, refine, bleaching-bathing method " pre-treatment and the senior reactive dyeing of double-active group peace promise element are carried out to cotton/merino cashmere blended yarn, while reducing cashmere loss, reduce bath raio, dyeing flow is short, dyeing evenness is high, and cost is low;
4) use the material modified of novel environment friendly, reduce dyeing temperature, arrange without the need to hydrophilic additive, exempt from starching, use mercerising singe line save dyestuff, Final finishing is not singed, not destarch, not mercerising, reduce BOD discharge, the short low-carbon high-efficiency of production procedure, meets environmental requirement simultaneously.
The super imitative cotton cashmere Double-face fabric of the present invention, high-strength, wear-resisting, the high moisture absorption height perspire of super imitative cotton fiber, antistatic wrinkle resistance, have the warmth retention property of merino cashmere concurrently, be equipped with special two-sided tissue by filling yarn perfect adaptation, fabric two sides gives different visions and enjoys with sensation.
Accompanying drawing explanation
Fig. 1 is 1/3+3/1 reversible twill organization chart of the present invention.
Fig. 2 is 1/3+3/1 reversible twill color effects figure.
Detailed description of the invention
Embodiment 1
The super imitative cotton cashmere Double-face fabric of the one that the present invention relates to, product specification is as follows:
This product is [Supercool/ cotton (80/20) 7.3tex × 2] × [mercerising singe line 18.2tex × 2+ cotton/cashmere (80/20) 18.2tex]/524 (root/10cm) × 472 (root/10cm)/145 ~ 147.5cm 1/3+3/1 reversible twill color-woven fabric.Warp-wise tightness 74%, broadwise front tightness 53.2%, broadwise reverse side tightness 37.6%, total tightness degree 97.8%, Stability Analysis of Structures.
Special 1/3+3/1 twill two-sided colored woven organization design (see figure 1), warp thread adopts the super imitative cotton/silk/cotton blended yarn of 7.3tex, and the high row of high-strength, high suction, can derive reverse side sweat, guarantee the comfortableness of whole fabric, Stability Analysis of Structures; The aobvious warp of aobvious latitude on overall cloth cover color, product front (light color) to singe line for 18.2tex mercerising, knotless double twisting, and rough abundant, bright and clean smooth, lines is clear, and close structure not slippage is wear-resisting, not easily pilling; Reverse side (dark color) is 18.2tex cotton/cashmere (80/20), soft, next to the skin warming.In addition, the color of product is by apolegamy meticulously, and front is just like the rice field on autumn days, and reverse side, just as the sorghum field in late autumn, shows the Nature color that good harvest is ripe.Double-side different color (see figure 2), is convenient to the collocation of clothing cuff, collar, saves batching; By special finishing, dimensionally stable, for autumn and winter style is first-selected.
Embodiment 2
A preparation technology for super imitative cotton cashmere Double-face fabric, specific as follows:
1, loose winding process
Adopt FADIS metal machine, CROCHI bobbin winder.Warp thread speed of a motor vehicle 900m/min, bobbin density 0.4 ~ 0.42g/cm
3, weft yarn speed of a motor vehicle 750m/min, bobbin density 0.35 ~ 0.38g/cm
3.Because Supercool fiber single fiber intensity is 5.0 ~ 5.2CN/dtex, 3.0 ~ 3.2CN/tex of more general hydrophilic modifying terylene is high, and raw yarn is containing Supercool fiber 80%, and powerful good, little breakage, production efficiency is high.Weft yarn reduces the speed of a motor vehicle, reduces bobbin density, administration measure.
2, dyeing
(1) the grayish green dyeing of Supercool/ cotton (80/20):
All the time design dyeing not destroy based on raw yarn wet-guide quick-drying performance, forbid silicone oil and wax, hydrophilic softening agent in summary, prevent from weaving electrostatic.First dye is adopted to wash the process route of after stain cotton.
Pre-treatment: boil yarn refining agent 2g/l
Soda ash 2g/l
80℃×30min
Dye is washed, i.e. Supercool stock-dye:
Pre-treatment: bleach stable finishing agent CLARITE ONE (Hensel steps) 1.5g/l
Caustic soda 1.5g/l
Hydrogen peroxide 3.5g/l 100 DEG C × 30min
Glacial acetic acid 3g/l 50 DEG C × 10min
Deoxidation enzyme 0.1g/l normal temperature × 15min
Dyeing: disperse red AC-E (Amrinone is grand) 0.12%
Disperse blue AC-E (Amrinone is grand) 0.43%
Disperse yellow AC-E (Amrinone is grand) 0.31%
Glacial acetic acid 2g/l
High temperature levelling agent 1.5g/l 120 DEG C × 15min
Dye is cotton:
Pre-treatment: glacial acetic acid 1g/l
Yarn 60 DEG C × 10min is boiled before dye
Dyeing: Red FN-R 0.13%
Vapour bar 4R indigo plant 0.31%
Vapour clings to yellow FN-ZR 0.45%
Dispersant DK(Huizhou Hua Weixing Fine Chemical Co., Ltd) 1.5g/l
Glauber salt 40g/l
Soda ash 15g/l 60 DEG C × 30min
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent LOCANIT S-A (section is triumphant) 1g/l 90 DEG C × 10min
Glacial acetic acid 0.5g/l
Comfortable finishing agent ULTRAPHIL DCW 1.5g/l 55 DEG C × 20min;
Washing staining fastness reaches 4-5 level, and weathering color fastness reaches 5-6 level, and wet friction COLOR FASTNESS reaches 4-5 level, and capillary effect reaches 10-11cm/30min.
(2) the doe dyeing of cotton/merino cashmere (80/20):
The Tea Saponin C-200 produced with Shanghai Yuan Na carries out " boil, refine, bleaching-bathing method " dyeing to cotton/merino cashmere blended yarn, does not use the chemical article such as caustic soda, hydrogen peroxide, energy-saving and emission-reduction, lower than traditional handicraft production cost.Tea Saponin is a kind of natural plant kind surfactant of good performance, has good emulsification, foaming, dispersion, infiltration, wetting isoreactivity effect.Ensure, in dyeing course, not corrode equipment; To fibrous zero damage; Yarn feel comparatively traditional handicraft is soft, reduces softener consumption 1/3; To cotton/merino cashmere blended yarn, cashmere weight-loss ratio reduces than traditional dyeing process; Because not using chemical assistant, effectively can ensure that achieve the safety in production of textiles ecological, environmental protective, then pacify the senior reactive dyeing of promise element by use double-active group, the compatbility of dyestuff is good, and dyeing evenness, COLOR FASTNESS is good not containing APEO in yarn.The main dyeing to cotton/merino cashmere (80/20) is below inquired into.Dyeing and formula are:
Pre-treatment: Tea Saponin C-200 2g/l 80 DEG C × 30min
Glacial acetic acid 2g/l 50 DEG C × 10min
Dyeing: active yellow GR (An Nuosu) 0.85%
Active red E-3B(pacifies promise element) 0.4%
Reactive blue BF(pacifies promise element) 0.612%
Dispersant DK(Huizhou Hua Weixing Fine Chemical Co., Ltd) 1g/l
Na
2sO
4(glauber salt) 50g/l
Na
2cO
3(soda ash) 15g/l
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent LOCANIT S-A (section is triumphant) 1g/l 95 DEG C × 10min
Glacial acetic acid 0.5g/l
Softener ZL-520(stands upright in Hangzhou Chemical Co., Ltd.) 3.5g/l 55 DEG C × 20min.
By above dyeing, cotton/Merino hair yarn COLOR FASTNESS is good, meets yarn-dyed fabric standard-required.We dye to cotton/cashmere (80/20) by using Tea Saponin and the promise senior reactive dyeing of element of double-active group peace and traditional pre-treatment auxiliary agent, the results are shown in following table:
| Pre-treatment auxiliary agent | Wool loss late | Later process softener consumption | Yarn strength |
| Tea Saponin | 2.8% | 2.3g/l | 223.4cN/tex |
| Conventional adjuvants | 5% | 3.5g/l | 212.1cN/tex |
Dyed yarn is disconnected is better than by force traditional handicraft 4 ~ 5%, and cashmere content weight-loss ratio comparatively traditional handicraft is low by 2 ~ 3%, makes fabric contain cashmere amount and greatly improves.
(3) mercerising is singed the dyeing of line off-white:
Pre-treatment: CLARITE ONE 2g/l
Caustic soda 2g/l
Hydrogen peroxide 6g/l 110 DEG C × 30min
Glacial acetic acid 3g/l 50 DEG C × 10min
Deoxidation enzyme 0.1g/l normal temperature 15min
Dyeing: K type active yellow HF-2GR 150%(Korea S Jing Ren) 0.0224%
K type active red HF-6BN (Korea S Jing Ren) 0.004%
The active deep blue K-BF(Korea S Jing Ren of K type) 0.0038%
Dispersant DK(Huizhou Hua Weixing Fine Chemical Co., Ltd) 1g/l
Na
2sO
4(glauber salt) 10g/l
Na
2cO
3(soda ash) 5g/l
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent LOCANIT S-A (section is triumphant) 1g/l 90 DEG C × 10min
Glacial acetic acid 0.5g/l
Softener ZL-520(stands upright in Hangzhou Chemical Co., Ltd.) 3.5g/l 55 DEG C × 20min.
By Experimental Comparison: mercerising line dye amount ratio conventional jack per line yarn dyestuff of singing saves 20%.
3 warpings
Adopt section warping, speed of a motor vehicle 120-140m/min, warping density 0.48g/cm
3.Technique initialization is suitable, and warping efficiency is high, and without barriness, axial plane is smooth.
We to Supercool/ cotton (80/20) blended yarn routinely technique carried out sizing test, the mechanical performance, regain etc. of yarn before and after sizing are concluded, see the following form:
| Before and after operation | Ultimate strength/cN | Filoplume length H/MM | Elongation at break/% |
| Before sizing | 718.5 | 3.8 | 4.5 |
| After sizing | 734.6 | 3.4 | 3.8 |
Because Supercool fibre moisture regain rate reaches 0.54 ~ 0.6%, with cotton with after 80/20 blending ratio blending, overall regain is high, antistatic behaviour is good, and Yarn filoplume is few, in addition powerful high, ABRASION RESISTANCE good, before and after sizing, not obvious realization of comparative effectiveness exempts from starching, low-carbon environment-friendly.
4 weave
Use field, Tianjin coltfoal ZAX-N air-jet loom, machine heald, menopause tablet density in control, use 6 pages of comprehensive, menopause tablets, reduces filoplume and tangle, strict control workshop moisture temperature, temperature controls at 28 ~ 32 DEG C, and humid control ensures fabric positive and negative yarn not bottom drain 65 ~ 70%, strictly controls Set-marks, selvedge width control system is within 1.5cm-2cm, increase waste selvage yarn intensity, be increased to 40 by original 32, prevent sideband latitude.
Rotating speed: 680rpm efficiency: 93%
Warp tension: 1900N
Back rest position: NO.6 before and after height 110mm
Warp stop frame position: NO.10 before and after height NO.5
Opening time: 300 °
Opening amount: 76+4
Heald frame height: 109-2
5 arrange
Finishing technique flow process:
Washing → liquefied ammonia → pH washing → tentering → fluffing → stentering forming → preshrunk in advance
(1) wash: Japanese TSUDAKOMA desizing machine rear car
The speed of a motor vehicle: 50m/min banks up temperature: 60 DEG C
Bank up the time: 45min washing temperature: 95 DEG C
Amylase: 6g/L nonionic penetrant: 8g/L
(2) liquefied ammonia: YAZL-160 liquefied ammonia machine
The speed of a motor vehicle: 20 m/min ammonia largest loop amount: 600Kg/h
Fall width: 144-147cm
(3) pH washing: Japanese TSUDAKOMA desizing machine rear car
The speed of a motor vehicle: 60m/min temperature: 90 DEG C
(4) tentering in advance: German MONFORTS setting machine
The speed of a motor vehicle: 60m/min drying room temperature: 120 DEG C are rolled power: 30N/mm
Fall width: 148CM
(5) fluff: the efficient raising machine of MB476-200
Combination product designs, and front is bright and clean smooth, and reverse side is comfortable warming, and we carry out reverse side fluffing to product after liquid ammonia finishing, dimensionally stable, and cloth cover is smooth, and skin-friendly is good, improves the wearability of fabric further.
The speed of a motor vehicle: 14m/min tension force: 80 roller speed: 40 turns/min
Carbon roller rotating speed: 1200 turns/min sanding face: anti-
(6) sizing arranges: German MONFORTS setting machine
The speed of a motor vehicle: 50m/min rolls power: 30N/mm
Preliminary drying temperature: 80 DEG C of drying room temperature: 120 DEG C
Air quantity: upper 90% time 80% humidity: 9%
Fall width: 148cm
Citric acid: 0.8g/l water-based ammonia dipersant DT-508:20g/l
(7) preshrunk: German MONFORTS preshrinking machine
Before conscientiously carrying out product contracting, washing DIMENSIONAL STABILITY is tested, and carries out process monitoring, guarantees that shrink qualification rate reaches 100%.
The speed of a motor vehicle: 50m/min falls width: 145-148cm.
3 product qualities detect
Fabric air technology and inside and outside quality standard test report in table 1
Table 1 fabric air technology and inside and outsidely to report at quality standard test
By test, fabric technical requirement meets the requirement of GB18401-2010 " national general safety technical code for textile products " category-B, and inherent and quality index appearance meets the requirement of FZ/T 13007-2008 " yarn-dyed cotton fabric " Grade A.By detecting, the washing size changing rate of fabric controls good, and dyefastness all reaches 4 ~ 5 grades, and machinery is powerful outstanding, and it is good that cashmere content reaches 4.6% warmth retention property; In addition absorbing fast-drying, uvioresistant, wrinkle resistance comparatively same specification kind all have greater advantage.
4 sum up
1) this product had both maintained the original characteristic of polyster fibre on raw material, developed again the Moisture absorbing & quick drying property in its excellent cross section, structural chemistry modification, preferred blending ratio, and fabric is comfortable; Preferred cotton/cashmere blending ratio, improves the skin-friendly of fabric, not scratchy and warmth retention property next to the skin;
2) this product is in design concept, selects two-sided tissue, and optimize longitude and latitude yarn and configure, three kinds of materials are shown what one's be, and cloth cover is smooth, and non-foaming after washing, wearability is good;
3) carry out " boil, refine, bleaching-bathing method " pre-treatment with Tea Saponin C-200 to cotton/merino cashmere blended yarn, re-use the senior reactive dyeing of double-active group peace promise element, while reducing cashmere loss, reduce bath raio, dyeing flow is short, and cost is low;
4) use the material modified and mercerising of novel environment friendly to singe line, arrange without the need to hydrophilic additive, exempt from starching, do not singe, not mercerising, reduce BOD discharge, the short low-carbon high-efficiency of production procedure, meets environmental requirement simultaneously.
Claims (6)
1. the preparation technology of a super imitative cotton cashmere Double-face fabric, it is characterized in that: described fabric singes line for raw material with Supercool/ silk/cotton blended yarn, cotton/merino cashmere blended yarn, mercerising, select two-sided tissue, warp thread adopts 7.3tex Supercool/ silk/cotton blended yarn; To make on overall cloth cover color the aobvious warp of aobvious latitude, broadwise front is that 18.2tex mercerising is singed line, and broadwise reverse side is 18.2tex cotton/merino cashmere blended yarn;
Dyeing course in described preparation technology comprises:
(1) dyeing of Supercool/ cotton, adopts first dye to wash the process route of after stain cotton;
A, pre-treatment: boil yarn refining agent 2g/l
Soda ash 2g/l
80℃×30min
B, dye are washed: i.e. Supercool stock-dye
Pre-treatment: bleaching stibilizer 1.5g/l
Caustic soda 1.5g/l
Hydrogen peroxide 3.5g/l 100 DEG C × 30min
Glacial acetic acid 3g/l 50 DEG C × 10min
Deoxidation enzyme 0.1g/l normal temperature × 15min
Dyeing: dyestuff
Glacial acetic acid 2g/l
High temperature levelling agent 1.5g/l
120℃×15min
C, dye are cotton:
Pre-treatment: glacial acetic acid 1g/l
Yarn 60 DEG C × 10min is boiled before dye
Dyeing: dyestuff
Dispersant 1.5g/l
Glauber salt 40g/l
Soda ash 15g/l 60 DEG C × 30min
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent 1g/l 90 DEG C × 10min
Glacial acetic acid 0.5g/l
Comfortable finishing agent 1.5g/l 55 DEG C × 20min;
(2) dyeing of cotton/merino cashmere:
With Tea Saponin C-200, " boil, refine, bleaching-bathing method " pre-treatment is carried out to cotton/merino cashmere blended yarn, re-uses the reactive dyeing of peace promise element, be specially:
Pre-treatment: Tea Saponin C-200 2g/l 80 DEG C × 30min
Glacial acetic acid 2g/l 50 DEG C × 10min
Dyeing: peace promise element REACTIVE DYES
Dispersant 1g/l
Na
2SO
450g/l
Na
2CO
315g/l
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent 1g/l 95 DEG C × 10min
Glacial acetic acid 0.5g/l
Softener 3.5g/l 55 DEG C × 20min;
(3) mercerising is singed the dyeing of line:
Pre-treatment: bleaching stibilizer 2g/l
Caustic soda 2g/l
Hydrogen peroxide 6g/l 110 DEG C × 30min
Glacial acetic acid 3g/l 50 DEG C × 10min
Deoxidation enzyme 0.1g/l normal temperature 15min
Dyeing: dyestuff
Dispersant 1g/l
Na
2SO
410g/l
Na
2CO
35g/l
Post processing: glacial acetic acid 3g/l 50 DEG C × 10min
Acid scouring agent 1g/l 90 DEG C × 10min
Glacial acetic acid 0.5g/l
Softener 3.5g/l 55 DEG C × 20min.
2. the preparation technology of a kind of super imitative cotton cashmere Double-face fabric according to claim 1, it is characterized in that, in described Supercool/ silk/cotton blended yarn, Supercool fiber is 80:20 with cotton mass ratio, and in described cotton/merino cashmere blended yarn, mass ratio that is cotton and cashmere is 80:20.
3. the preparation technology of a kind of super imitative cotton cashmere Double-face fabric according to claim 1, it is characterized in that, concrete specification is: [Supercool/ cotton 7.3tex × 2] × [mercerising singe line 18.2tex × 2+ cotton/merino cashmere 18.2tex]/524 × 472/145 ~ 147.5cm 1/3+3/1 reversible twill color-woven fabric, warp-wise tightness 74%, broadwise front tightness 53.2%, broadwise reverse side tightness 37.6%, total tightness degree 97.8%.
4. the preparation technology of super imitative cotton cashmere Double-face fabric according to claim 1, is characterized in that: in described preparation technology, finishing technique is: washing → liquefied ammonia → pH washing → tentering → fluffing in advance → sizing arrangement → preshrunk.
5. the preparation technology of super imitative cotton cashmere Double-face fabric according to claim 4, is characterized in that: the finishing agent that described sizing arranging process uses is: citric acid 0.8g/l, water-based ammonia dipersant 20g/l.
6. the preparation technology of super imitative cotton cashmere Double-face fabric according to claim 1, is characterized in that: in described preparation technology, without slashing technique.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310212993.4A CN103276500B (en) | 2013-05-31 | 2013-05-31 | Super cotton-like cashmere double-side fabric and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310212993.4A CN103276500B (en) | 2013-05-31 | 2013-05-31 | Super cotton-like cashmere double-side fabric and production process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103276500A CN103276500A (en) | 2013-09-04 |
| CN103276500B true CN103276500B (en) | 2015-02-18 |
Family
ID=49059108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310212993.4A Expired - Fee Related CN103276500B (en) | 2013-05-31 | 2013-05-31 | Super cotton-like cashmere double-side fabric and production process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103276500B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103469632B (en) * | 2013-09-16 | 2016-03-30 | 上海大学 | A kind of colouring method of super imitative cotton cashmere blended fabrics |
| CN104026781B (en) * | 2014-05-21 | 2015-12-30 | 江阴福斯特纺织有限公司 | High-strength wearable, the high row of high suction, crease-resistant uvioresistant duty dress fabric and production technology |
| CN104726982A (en) * | 2015-03-12 | 2015-06-24 | 浙江米皇羊绒股份有限公司 | High-elongation skin-friendly cashmere yarn |
| CN105239377A (en) * | 2015-11-02 | 2016-01-13 | 长兴县蓉峰纺织有限公司 | Novel super soft anti-pilling silver-loaded wool fabric |
| CN105463675A (en) * | 2015-12-15 | 2016-04-06 | 桐乡市濮院羊毛衫职业技术学校 | Production method for cashmere terylene fabric |
| CN106930110B (en) * | 2017-03-30 | 2019-08-20 | 武汉纺织大学 | A method of improving polypyrrole wool conductive fabric electric conductivity |
| CN109763241B (en) * | 2018-12-27 | 2020-12-15 | 嘉兴市鸣业纺织有限公司 | Production process of weft-elastic water-washed velvet fabric |
| CN109930278A (en) * | 2019-03-28 | 2019-06-25 | 无锡泰伯服饰有限公司 | A kind of wood-fibred/tencel Hair style double-layer fabric |
| CN110158223A (en) * | 2019-05-18 | 2019-08-23 | 鲁泰纺织股份有限公司 | The production technology of cotton wool blended colored woven fabric |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3883276B2 (en) * | 1997-12-05 | 2007-02-21 | 日本フイルコン株式会社 | Industrial two-layer fabric with auxiliary weft arranged on the upper layer fabric |
| CN1506530A (en) * | 2002-12-11 | 2004-06-23 | 内蒙古鄂尔多斯羊绒集团有限责任公司 | Mixed cashmere-cotton fabric dyeing technique in the same bath |
| CN101158080B (en) * | 2007-11-20 | 2010-07-14 | 杨竹园 | Cashmere cotton face fabric production technique |
| CN101792578B (en) * | 2009-12-30 | 2011-12-21 | 北京服装学院 | Polyester fiber with functions of wetting, moisture transmitting and quick drying and fabric thereof |
| CN101949092B (en) * | 2010-09-07 | 2012-04-04 | 吴江市恒润织造厂 | Preparation method of moisture-absorbing, sweat-permeable and anti-crease fabric |
| CN103014992B (en) * | 2012-12-12 | 2014-03-12 | 江苏阳光集团有限公司 | Worsted plus material with intelligent temperature control function and production method of worsted plus material |
-
2013
- 2013-05-31 CN CN201310212993.4A patent/CN103276500B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN103276500A (en) | 2013-09-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103276500B (en) | Super cotton-like cashmere double-side fabric and production process thereof | |
| CN102383235B (en) | Ecological bacteriostatic breathable smooth tatting fabric | |
| CN106012214B (en) | Jacquard weave cellulose acetate filament man textile fabric and its production method | |
| CN102080295B (en) | Cotton-diacetate cellulose fiber jacquard fabric and processing method thereof | |
| CN103614842B (en) | Coffee carbon multi-component fiber weaving fabric and preparation method thereof | |
| CN104026781B (en) | High-strength wearable, the high row of high suction, crease-resistant uvioresistant duty dress fabric and production technology | |
| CN203320225U (en) | Shell fabric containing mint fibers for summer quilt | |
| CN102797104B (en) | Processing method of Sorona and silk clothes fabric | |
| CN102181990B (en) | Heavy cotton viscose blended dual-elasticity yarn drill fabric and finishing process thereof | |
| CN104131408B (en) | A kind of containing cotton warp-knitted face fabric and processing method thereof | |
| CN101324000B (en) | Production method of memory function lining | |
| CN101481880B (en) | Production method of nostalgic ecological cotton, hemp and blended fabric thereof | |
| CN108532321B (en) | Production process of high-wear-resistance anti-wrinkle jean | |
| CN102561040A (en) | New anti-fluffing and anti-pilling technology for polyester-cotton fabric under special standards | |
| CN102704140A (en) | Chemical fiber fabric and preparation method thereof | |
| CN104073953A (en) | Production method of superfine yarn-dyed cotton carbon Moge fabric with superhigh density | |
| CN113684584B (en) | Preparation method of pure cotton yarn-dyed high-count high-density non-ironing fabric | |
| CN104032444A (en) | Black woolen worsted fabric and production method thereof | |
| CN100485113C (en) | Dyeing method of copper ammonia fiber and tencel interwoven fabric | |
| CN101798724B (en) | Commingled yarn functional fabric and production process thereof | |
| WO2019028805A1 (en) | Method for producing jacquard home-textile fabric with light and thin multilayer structure | |
| CN1962982B (en) | Method for preparing invisible slub mercerized cotton wool jeans fabrics | |
| CN107201590A (en) | A kind of low ratio tencel of use blending adds the woven denim and its technique of cotton stretched fabric | |
| CN1483877B (en) | High-count bamboo-fibril fabric and dyeing-finishing technology thereof | |
| CN103993406B (en) | The ultra-fine special cotton silkworm silk interwoven fabric of low-carbon environment-friendly and production technology thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: JIANGYING PROFESSIONAL TECHNOLOGY COLLEGE Effective date: 20141215 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Liu Suoyin Inventor after: He Jie Inventor after: Yin Yujuan Inventor before: Liu Suoyin Inventor before: Wang Tianrui Inventor before: Hu Baoshuan Inventor before: Yin Yujuan |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LIU SUOYIN WANG TIANRUI HU BAOSHUAN YIN YUJUAN TO: LIU SUOYIN HE JIE YIN YUJUAN |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20141215 Address after: 214443 Jiangsu province Wuxi Shanghai Lingang Economic Development Zone Jiangyin City sub package Road No. 55 Applicant after: Jiangyin Firstextile Co., Ltd. Applicant after: Jiangying Professional Technology College Address before: 214443 Jiangsu province Wuxi Shanghai Lingang Economic Development Zone Jiangyin City sub package Road No. 55 Applicant before: Jiangyin Firstextile Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170405 Address after: 214400 Zhujianglu Road, Jiangyin City, Jiangsu province Lingang street, No. 205, Patentee after: Jiangsu Paula Clothing Co. Ltd. Address before: 214443 Jiangsu province Wuxi Shanghai Lingang Economic Development Zone Jiangyin City sub package Road No. 55 Patentee before: Jiangyin Firstextile Co., Ltd. Patentee before: Jiangying Professional Technology College |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150218 Termination date: 20200531 |