CN103275454B - A kind of enhancing high-light ABS matrix material and preparation method thereof - Google Patents
A kind of enhancing high-light ABS matrix material and preparation method thereof Download PDFInfo
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- CN103275454B CN103275454B CN201310188284.7A CN201310188284A CN103275454B CN 103275454 B CN103275454 B CN 103275454B CN 201310188284 A CN201310188284 A CN 201310188284A CN 103275454 B CN103275454 B CN 103275454B
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- matrix material
- coupling agent
- glass microballon
- abs matrix
- light abs
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- 239000011159 matrix material Substances 0.000 title claims abstract description 24
- 230000002708 enhancing effect Effects 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 41
- 239000011521 glass Substances 0.000 claims abstract description 25
- 239000007822 coupling agent Substances 0.000 claims abstract description 19
- 230000004913 activation Effects 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000003112 inhibitor Substances 0.000 claims abstract description 8
- 239000000314 lubricant Substances 0.000 claims abstract description 8
- 230000003647 oxidation Effects 0.000 claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 4
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 4
- 229960004756 ethanol Drugs 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 3
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- -1 Zinic stearas Chemical compound 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000006084 composite stabilizer Substances 0.000 claims description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 2
- 229940113162 oleylamide Drugs 0.000 claims description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000035939 shock Effects 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 9
- 238000001746 injection moulding Methods 0.000 description 8
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
The invention discloses a kind of enhancing high-light ABS matrix material and preparation method thereof, it is made up of the raw material of following weight ratio: ABS resin 50-75%, AS resin 10-25%, Subnano-class glass microballon 10-25%, coupling agent 1-3%, expanding material 1-3%, lubricant 0.5-2%, stablizer 0.5-3%, oxidation inhibitor 0.5-2%.Subnano-class glass microballon coupling agent is infiltrated activation treatment, more evenly mixing in high-speed mixer with ABS resin, expanding material, lubricant, stablizer and oxidation inhibitor etc., finally melt blending is extruded on the twin screw extruder.The ABS composite material that the present invention prepares has good high and low temperature resistance, ageing-resistant performance and resistance to chemical corrosion, excellent glossiness, and intensity is high, shock resistance is good, be easy to the features such as processing, its production process is simple and easy to control, and cost is low, is applicable to suitability for industrialized production.
Description
Technical field
The present invention relates to field of material preparation, be specifically related to one and can obtain enhancing high-light ABS matrix material and preparation method thereof.
Background technology
Along with the development of advancing by leaps and bounds of China's household electrical appliance refrigerator, refrigerator handle panel high-light ABS material have also been obtained and develops rapidly.Refrigerator handle panel is as the important appearance component of the especially high-end refrigerator of domestic refrigerator, require high strength, high gloss and attractive in appearance, common ABS material is difficult to meet this requirement, ABS spray paint and have that cost is high, contaminate environment and be difficult to the problems such as recycling, exploitation strengthens high light and lower-cost refrigerator handle panel ABS material has become the hot issue of industry.
Summary of the invention
The object of the present invention is to provide a kind of high strength, high gloss and lower-cost refrigerator handle panel ABS composite material and preparation method thereof.
Technical scheme provided by the invention is:
A kind of enhancing high-light ABS matrix material, is made up of the raw material of following weight ratio: ABS resin 50-75%, AS resin 10-25%, Subnano-class glass microballon 10-25%, coupling agent 1-3%, expanding material 1-3%, lubricant 0.5-2%, stablizer 0.5-3%, oxidation inhibitor 0.5-2%.
Strengthen a preparation method for high-light ABS matrix material, comprise the following steps:
(1) coupling agent dehydrated alcohol is diluted by 1:1, then the Subnano-class glass microballon weighed up is put in homogenizer and stir, stirring velocity is 1500-2000r/min, pour the coupling agent/ethanol solution configured while stirring into, after solution is all poured into continue stir 10-15min, make solution as far as possible Sized glass microballon reach the effect of activation, by the dry 2-3h at 120-150 DEG C of the glass microballon after activation treatment, be cooled to normal temperature, stand-by;
(2) glass microballon of ABS resin, AS resin, expanding material, lubricant, stablizer, oxidation inhibitor and step (1) activation treatment is placed in homogenizer, rotating speed be 500-1000r/min, temperature stirs 10-20min under being 80-90 DEG C of condition, then compound is sent in twin screw extruder and carry out that melt blending is extruded, cooled, granulation, high-light ABS matrix material must be strengthened.
Described coupling agent can be one or more in silane coupling agent, titanate coupling agent, aluminate coupling agent.
Described solubilizing agent can be one or more in EVA grafted maleic anhydride copolymer, POE grafted maleic anhydride copolymer, phenylethylene-maleic anhydride-glycidyl methacrylate copolymer.
Described lubricant can be one or more in EVA wax, butyl stearate, oleylamide, ethylene bis stearamide, sodium stearate.
Described stablizer can be one or more in calcium stearate, Zinic stearas, barium stearate, calcium-zinc composite stabilizing agent, barium zinc composite stabilizer.
Described oxidation inhibitor can be antioxidant 1076, irgasfos 168, one or more in antioxidant 264.
The blending extrusion temperature of described twin screw extruder is: a district 195-205 DEG C, two district 215-225 DEG C, three district 220-230 DEG C, four district 220-235 DEG C, five district 225-235 DEG C, head 230-240 DEG C; Screw speed 180-220r/min.
Beneficial effect of the present invention:
In the present invention's formula, ABS is general-purpose injection level material, there is satisfactory stability, intensity and shock resistance, AS has good glossiness and rigidity, Subnano-class glass microballon has enhancing, the effect of blast, three has good synergy, the tensile strength of matrix material can be improved, the performance such as shock resistance and glossiness, the present invention utilizes coupling agent to carry out activation treatment glass microballon, make it to strengthen with ABS resin coupling better, expanding material is utilized to increase ABS, consistency between AS and activated glass microballon, thus improve the over-all properties of matrix material.The ABS composite material that the present invention prepares has good high and low temperature resistance, ageing-resistant performance and resistance to chemical corrosion, excellent glossiness, and intensity is high, shock resistance is good, be easy to the features such as processing, its production process is simple and easy to control, and cost is low, is applicable to suitability for industrialized production.
Embodiment
Embodiment 1
A kind of enhancing high-light ABS matrix material, is made up of the raw material of following weight ratio: ABS resin 65%, AS resin 15%, Subnano-class glass microballon 15%, Silane coupling agent KH550 1.5%, EVA grafted maleic anhydride copolymer 1 %, EVA wax 1%, barium stearate 1%, antioxidant 1076 0.5%.
Strengthen a preparation method for high-light ABS matrix material, comprise the following steps:
(1) coupling agent dehydrated alcohol is diluted by 1:1, then the Subnano-class glass microballon weighed up is put in homogenizer and stir, stirring velocity is 2000r/min, pour the coupling agent/ethanol solution configured while stirring into, after solution is all poured into continue stir 10min, make solution as far as possible Sized glass microballon reach the effect of activation, by the dry 3h at 125 DEG C of the glass microballon after activation treatment, be cooled to normal temperature, stand-by;
(2) glass microballon of ABS resin, AS resin, EVA grafted maleic anhydride copolymer, EVA wax, barium stearate, antioxidant 1010 and step (1) activation treatment is placed in homogenizer, rotating speed be 800r/min, temperature stirs 15min under being 85 DEG C of conditions, then compound is sent in twin screw extruder and carry out that melt blending is extruded, cooled, granulation, high-light ABS matrix material must be strengthened.
The blending extrusion temperature of described twin screw extruder is: 200 DEG C, a district, two 210 DEG C, districts, three 225 DEG C, districts, four 230 DEG C, districts, five 230 DEG C, districts, head 235 DEG C; Screw speed 200r/min.
By extruded stock injection moulding machine injection molding standard testing batten and injection moulding model, after testing, batten tensile strength is 55.3MPa, and elongation at break is 12%, and Young's modulus is 3353MPa, and injection moulding model glossiness is high.
Embodiment 2
A kind of enhancing high-light ABS matrix material, is made up of the raw material of following weight ratio: ABS resin 55%, AS resin 20%, Subnano-class glass microballon 20%, silane coupling agent DL6021.5%, POE grafted maleic anhydride copolymer 1 %, ethylene bis stearamide 1.5%, calcium-zinc composite stabilizing agent 0.5%, irgasfos 168 1%.
Strengthen a preparation method for high-light ABS matrix material, comprise the following steps:
(1) coupling agent dehydrated alcohol is diluted by 1:1, then the Subnano-class glass microballon weighed up is put in homogenizer and stir, stirring velocity is 1500r/min, pour the coupling agent/ethanol solution configured while stirring into, after solution is all poured into continue stir 15min, make solution as far as possible Sized glass microballon reach the effect of activation, by the dry 2h at 150 DEG C of the glass microballon after activation treatment, be cooled to normal temperature, stand-by;
(2) glass microballon of ABS resin, AS resin, POE grafted maleic anhydride copolymer, ethylene bis stearamide, calcium-zinc composite stabilizing agent, irgasfos 168 and step (1) activation treatment is placed in homogenizer, rotating speed be 1000r/min, temperature stirs 10min under being 90 DEG C of conditions, then compound is sent in twin screw extruder and carry out that melt blending is extruded, cooled, granulation, high-light ABS matrix material must be strengthened.
The blending extrusion temperature of described twin screw extruder is: 205 DEG C, a district, two 220 DEG C, districts, three 225 DEG C, districts, four 230 DEG C, districts, five 235 DEG C, districts, head 240 DEG C; Screw speed 180r/min.
By extruded stock injection moulding machine injection molding standard testing batten and injection moulding model, after testing, batten tensile strength is 62.4MPa, and elongation at break is 13%, and Young's modulus is 3553MPa, and injection moulding model glossiness is high.
Claims (7)
1. one kind strengthens high-light ABS matrix material, it is characterized in that, be made up of the raw material of following weight ratio: ABS resin 50-75%, AS resin 10-25%, Subnano-class glass microballon 10-25%, coupling agent 1-3%, expanding material 1-3%, lubricant 0.5-2%, stablizer 0.5-3%, oxidation inhibitor 0.5-2%; The preparation method of described enhancing high-light ABS matrix material, comprise the following steps: coupling agent dehydrated alcohol dilutes by 1:1 by (1), then the Subnano-class glass microballon weighed up is put in homogenizer and stir, stirring velocity is 1500-2000r/min, pour the coupling agent/ethanol solution configured while stirring into, continue to stir 10-15min after solution is all poured into, make solution as far as possible Sized glass microballon reach the effect of activation, by the dry 2-3h at 120-150 DEG C of the glass microballon after activation treatment, be cooled to normal temperature, stand-by; (2) glass microballon of ABS resin, AS resin, expanding material, lubricant, stablizer, oxidation inhibitor and step (1) activation treatment is placed in homogenizer, rotating speed be 500-1000r/min, temperature stirs 10-20min under being 80-90 DEG C of condition, then compound is sent in twin screw extruder and carry out that melt blending is extruded, cooled, granulation, high-light ABS matrix material must be strengthened.
2. enhancing high-light ABS matrix material according to claim 1, is characterized in that, described coupling agent can be one or more in silane coupling agent, titanate coupling agent, aluminate coupling agent.
3. enhancing high-light ABS matrix material according to claim 1, it is characterized in that, described expanding material can be one or more in EVA grafted maleic anhydride copolymer, POE grafted maleic anhydride copolymer, phenylethylene-maleic anhydride-glycidyl methacrylate copolymer.
4. enhancing high-light ABS matrix material according to claim 1, is characterized in that, described lubricant can be one or more in EVA wax, butyl stearate, oleylamide, ethylene bis stearamide, sodium stearate.
5. enhancing high-light ABS matrix material according to claim 1, is characterized in that, described stablizer can be one or more in calcium stearate, Zinic stearas, barium stearate, calcium-zinc composite stabilizing agent, barium zinc composite stabilizer.
6. enhancing high-light ABS matrix material according to claim 1, is characterized in that, described oxidation inhibitor can be antioxidant 1076, irgasfos 168, one or more in antioxidant 264.
7. enhancing high-light ABS matrix material according to claim 1, is characterized in that, the blending extrusion temperature of described twin screw extruder is: a district 195-205 DEG C, two district 215-225 DEG C, three district 220-230 DEG C, four district 220-235 DEG C, five district 225-235 DEG C, head 230-240 DEG C; Screw speed 180-220r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310188284.7A CN103275454B (en) | 2013-05-20 | 2013-05-20 | A kind of enhancing high-light ABS matrix material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310188284.7A CN103275454B (en) | 2013-05-20 | 2013-05-20 | A kind of enhancing high-light ABS matrix material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103275454A CN103275454A (en) | 2013-09-04 |
| CN103275454B true CN103275454B (en) | 2016-03-16 |
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| CN201310188284.7A Active CN103275454B (en) | 2013-05-20 | 2013-05-20 | A kind of enhancing high-light ABS matrix material and preparation method thereof |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104845018A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | High-strength wear-resistant ABS composite material and preparation method thereof |
| CN104845021A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | ABS/waste porcelain powder composite material and preparation method thereof |
| CN104845020A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | ABS/shell powder composite material and preparation method thereof |
| CN104845016A (en) * | 2015-04-27 | 2015-08-19 | 安徽海纳川塑业科技有限公司 | Fly ash modified ABS composite material and preparation method thereof |
| CN105542379B (en) * | 2015-12-31 | 2018-09-28 | 祥兴(福建)箱包集团有限公司 | A kind of high-impact resists cold ABS tank materials and the preparation method and application thereof |
| CN108070197A (en) * | 2017-12-15 | 2018-05-25 | 广西汇智生产力促进中心有限公司 | Modified kaolin-ABS is corrosion-resistant, the preparation method of explosion-proof composite material |
| CN112961454B (en) * | 2021-02-04 | 2023-10-03 | 九牧厨卫股份有限公司 | ABS composite material and preparation method thereof |
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| CN101570615A (en) * | 2008-04-28 | 2009-11-04 | 上海陈立实业有限公司 | Material of axial fan |
| CN101817966A (en) * | 2009-12-23 | 2010-09-01 | 上海锦湖日丽塑料有限公司 | ABS extrusion board material for automobiles and preparation method thereof |
| CN101875753A (en) * | 2009-10-29 | 2010-11-03 | 深圳市科聚新材料有限公司 | ABS (Acrylonitrile Butadiene Styrene) modified material with high heat resistance, high gloss and flame retardance and preparation method thereof |
| CN102030957A (en) * | 2009-09-29 | 2011-04-27 | 上海金发科技发展有限公司 | High-gloss scratch-resistant and antistatic ABS (acrylonitrile-butadiene-styrene) alloy |
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- 2013-05-20 CN CN201310188284.7A patent/CN103275454B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570615A (en) * | 2008-04-28 | 2009-11-04 | 上海陈立实业有限公司 | Material of axial fan |
| CN102030957A (en) * | 2009-09-29 | 2011-04-27 | 上海金发科技发展有限公司 | High-gloss scratch-resistant and antistatic ABS (acrylonitrile-butadiene-styrene) alloy |
| CN101875753A (en) * | 2009-10-29 | 2010-11-03 | 深圳市科聚新材料有限公司 | ABS (Acrylonitrile Butadiene Styrene) modified material with high heat resistance, high gloss and flame retardance and preparation method thereof |
| CN101817966A (en) * | 2009-12-23 | 2010-09-01 | 上海锦湖日丽塑料有限公司 | ABS extrusion board material for automobiles and preparation method thereof |
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| CN103275454A (en) | 2013-09-04 |
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