CN103849044A - Anti-aging masterbatch used for polyethylene and preparation method of anti-aging masterbatch - Google Patents
Anti-aging masterbatch used for polyethylene and preparation method of anti-aging masterbatch Download PDFInfo
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- CN103849044A CN103849044A CN201210594187.3A CN201210594187A CN103849044A CN 103849044 A CN103849044 A CN 103849044A CN 201210594187 A CN201210594187 A CN 201210594187A CN 103849044 A CN103849044 A CN 103849044A
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- master batch
- aging
- aging master
- poly anti
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
This invention discloses anti-aging masterbatch used for polyethylene and a preparation method of the anti-aging masterbatch. The anti-aging masterbatch is composed of the following components in mass percentage: 20%-40% of polyethylene resin, 20%-40% of a light stabilizer, 10-30% of a filling agent, 3%-8% of a compatilizer, 0.5%-3% of a coupling agent, 3%-5% of a dispersant, and 1%-3% of an antioxidant. Compared with the prior art, the anti-aging masterbatch has favorable anti-aging effect and compatibility when applied to modification of polyethylene, the service life can be greatly prolonged, and meanwhile the masterbatch further has a toughening modification function, can be used for greatly improving the impact strength, abrasion resistance, processability and the like of materials, and has very high practical value.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically one is applied to poly anti-aging master batch and preparation method thereof.
Background technology
The plastics that make with pure polyvinyl resin are more aging, particularly illumination or in the situation that being heated aging speed faster, in order to improve poly anti ageing property, normally in polyvinyl resin, add the auxiliary agent such as photostabilizer and oxidation inhibitor, but the application of poly anti-aging auxiliary agent is not simple interpolation and accumulation, but a unified system that needs consider, to ensure its result of use.
Summary of the invention
What the object of the present invention is to provide that a kind of consistency is good, anti ageing property is good and easy to use is applied to poly anti-aging master batch and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: one is applied to poly anti-aging master batch, and its component by mass percent proportioning is: polyvinyl resin 20%～40%, photostabilizer 20%～40%, weighting agent 10%～30%, compatilizer 3%～8%, coupling agent 0.5%～3%, dispersion agent 3%～5%, oxidation inhibitor 1%～3%.
Described photostabilizer is ESCALOL 567 or hindered amine as light stabilizer.
Described weighting agent is the one in glass microballon, calcium carbonate, talcum powder, kaolin, barium sulfate, silicon-dioxide, wollastonite.
Described compatilizer is the one in acetate ethylene copolymer (EVA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethylene-methyl acrylate-glyceryl methacrylate terpolymer (E-MA-GMA).
Described coupling agent is aluminium titanium composite coupler.
Described dispersion agent is the one in low molecular weight polyethylene wax, OP wax, EVA wax, TAS-2A.
Described oxidation inhibitor is hindered phenol antioxygen 1010 or 1076 and the compound of phosphite ester kind antioxidant 168.
Above-mentioned a kind of preparation method who is applied to poly anti-aging master batch is: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mix 10～30 minutes 100 DEG C～120 DEG C of mixing temperatures, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 150 DEG C～180 DEG C, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain one of the present invention and be applied to poly anti-aging master batch.
The invention has the beneficial effects as follows, compared with prior art, use the anti-aging master batch that makes of the present invention to be applied to when PE modified, there is good anti-aging effect and consistency, can greatly increase the service life, also there is toughening modifying function simultaneously, can greatly improve shock resistance, wear resisting property and the processing characteristics etc. of material, there is good practical value.
Embodiment
Further illustrate technical scheme of the present invention below in conjunction with specific embodiment.
Embodiment 1:
One is applied to poly anti-aging master batch, and its component by mass percent proportioning is: the compound 2% of polyvinyl resin 30%, ESCALOL 567 30%, glass microballon 25%, acetate ethylene copolymer (EVA) 6%, aluminium titanium composite coupler 3%, low molecular weight polyethylene wax 4%, hindered phenol antioxygen 1010 and phosphite ester kind antioxidant 168.
Preparation method: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mix 10～30 minutes 100 DEG C～120 DEG C of mixing temperatures, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 150 DEG C～180 DEG C, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain one of the present invention and be applied to poly anti-aging master batch.
Embodiment 2:
One is applied to poly anti-aging master batch, and its component by mass percent proportioning is: the compound 3% of polyvinyl resin 20%, ESCALOL 567 40%, calcium carbonate 21%, maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA) 8%, aluminium titanium composite coupler 3%, EVA wax 5%, hindered phenol antioxygen 1076 and phosphite ester kind antioxidant 168.
Preparation method: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mix 10～30 minutes 100 DEG C～120 DEG C of mixing temperatures, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 150 DEG C～180 DEG C, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain one of the present invention and be applied to poly anti-aging master batch.
Embodiment 3:
One is applied to poly anti-aging master batch, and its component by mass percent proportioning is: the compound 1% of polyvinyl resin 40%, hindered amine as light stabilizer 20%, talcum powder 30%, ethylene-methyl acrylate-glyceryl methacrylate terpolymer (E-MA-GMA) 5%, aluminium titanium composite coupler 1%, TAS-2A 3%, hindered phenol antioxygen 1010 and phosphite ester kind antioxidant 168.
Preparation method: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mix 10～30 minutes 100 DEG C～120 DEG C of mixing temperatures, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 150 DEG C～180 DEG C, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain one of the present invention and be applied to poly anti-aging master batch.
Claims (8)
1. one kind is applied to poly anti-aging master batch, it is characterized in that, its component by mass percent proportioning is: polyvinyl resin 20%～40%, photostabilizer 20%～40%, weighting agent 10%～30%, compatilizer 3%～8%, coupling agent 0.5%～3%, dispersion agent 3%～5%, oxidation inhibitor 1%～3%.
2. one according to claim 1 is applied to poly anti-aging master batch, it is characterized in that, described photostabilizer is ESCALOL 567 or hindered amine as light stabilizer.
3. one according to claim 1 is applied to poly anti-aging master batch, it is characterized in that, described weighting agent is the one in glass microballon, calcium carbonate, talcum powder, kaolin, barium sulfate, silicon-dioxide, wollastonite.
4. one according to claim 1 is applied to poly anti-aging master batch, it is characterized in that, described compatilizer is the one in acetate ethylene copolymer (EVA), maleic anhydride (MA) graft phenylethene-ethylene butene-styrene copolymer (SEBS-g-MA), ethylene-methyl acrylate-glyceryl methacrylate terpolymer (E-MA-GMA).
5. one according to claim 1 is applied to poly anti-aging master batch, it is characterized in that, described coupling agent is aluminium titanium composite coupler.
6. one according to claim 1 is applied to poly anti-aging master batch, it is characterized in that, described dispersion agent is the one in low molecular weight polyethylene wax, OP wax, EVA wax, TAS-2A.
7. one according to claim 1 is applied to poly anti-aging master batch, it is characterized in that, described oxidation inhibitor is hindered phenol antioxygen 1010 or 1076 and the compound of phosphite ester kind antioxidant 168.
8. a kind of preparation method who is applied to poly anti-aging master batch according to claim 1, it is characterized in that, comprise the following steps: each component is prepared burden by weight proportion, then add in high-speed mixer or ultrasonic generator, mix 10～30 minutes 100 DEG C～120 DEG C of mixing temperatures, again the material mixing is added to twin screw extruder melt blending, melt temperature is controlled at 150 DEG C～180 DEG C, after extruding by twin screw extruder, through overcooling, pelletizing, dry, pack and obtain one of the present invention and be applied to poly anti-aging master batch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594187.3A CN103849044A (en) | 2012-12-04 | 2012-12-04 | Anti-aging masterbatch used for polyethylene and preparation method of anti-aging masterbatch |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594187.3A CN103849044A (en) | 2012-12-04 | 2012-12-04 | Anti-aging masterbatch used for polyethylene and preparation method of anti-aging masterbatch |
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| CN103849044A true CN103849044A (en) | 2014-06-11 |
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| CN201210594187.3A Pending CN103849044A (en) | 2012-12-04 | 2012-12-04 | Anti-aging masterbatch used for polyethylene and preparation method of anti-aging masterbatch |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440419A (en) * | 2016-01-25 | 2016-03-30 | 山东春潮集团有限公司 | Mulching film master batch based on silver anti-aging performance and preparation method thereof |
| CN106084435A (en) * | 2016-06-21 | 2016-11-09 | 爱普特聚合物江苏有限公司 | PE class aging resistance functional agglomerate and preparation method thereof |
| CN109824963A (en) * | 2019-03-08 | 2019-05-31 | 上海魔核新材料科技有限公司 | A kind of anti-aging master batch |
| CN111057292A (en) * | 2019-12-30 | 2020-04-24 | 纳琳威纳米科技南通有限公司 | Nanometer anti-aging master batch |
| CN111073112A (en) * | 2019-12-30 | 2020-04-28 | 广东鲁华新材料科技股份有限公司 | Anti-aging master batch, polyolefin material containing anti-aging master batch, preparation method and application |
| CN111205545A (en) * | 2020-03-20 | 2020-05-29 | 宿迁联盛科技股份有限公司 | Method for preventing auxiliary agent in polyethylene aging-resistant master batch from being separated out |
| CN112876842A (en) * | 2021-01-15 | 2021-06-01 | 宿迁联盛科技股份有限公司 | Preparation method of anti-aging polymer composite material with enhanced core-shell structure |
| CN113462079A (en) * | 2021-07-26 | 2021-10-01 | 江门市严恩化工科技有限公司 | Light stabilizer 3853 master batch capable of preventing precipitation and blooming and preparation method thereof |
| CN113831637A (en) * | 2021-09-16 | 2021-12-24 | 宿迁联盛科技股份有限公司 | Anti-aging master batch for flat filament product and preparation method thereof |
| CN113930003A (en) * | 2021-12-03 | 2022-01-14 | 海信视像科技股份有限公司 | MPPO material, mineral filling master batch and preparation method thereof |
-
2012
- 2012-12-04 CN CN201210594187.3A patent/CN103849044A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440419A (en) * | 2016-01-25 | 2016-03-30 | 山东春潮集团有限公司 | Mulching film master batch based on silver anti-aging performance and preparation method thereof |
| CN106084435A (en) * | 2016-06-21 | 2016-11-09 | 爱普特聚合物江苏有限公司 | PE class aging resistance functional agglomerate and preparation method thereof |
| CN109824963A (en) * | 2019-03-08 | 2019-05-31 | 上海魔核新材料科技有限公司 | A kind of anti-aging master batch |
| CN111057292A (en) * | 2019-12-30 | 2020-04-24 | 纳琳威纳米科技南通有限公司 | Nanometer anti-aging master batch |
| CN111073112A (en) * | 2019-12-30 | 2020-04-28 | 广东鲁华新材料科技股份有限公司 | Anti-aging master batch, polyolefin material containing anti-aging master batch, preparation method and application |
| CN111205545A (en) * | 2020-03-20 | 2020-05-29 | 宿迁联盛科技股份有限公司 | Method for preventing auxiliary agent in polyethylene aging-resistant master batch from being separated out |
| CN112876842A (en) * | 2021-01-15 | 2021-06-01 | 宿迁联盛科技股份有限公司 | Preparation method of anti-aging polymer composite material with enhanced core-shell structure |
| CN113462079A (en) * | 2021-07-26 | 2021-10-01 | 江门市严恩化工科技有限公司 | Light stabilizer 3853 master batch capable of preventing precipitation and blooming and preparation method thereof |
| CN113462079B (en) * | 2021-07-26 | 2023-01-10 | 天津利安隆新材料股份有限公司 | Light stabilizer 3853 master batch capable of preventing precipitation and blooming and preparation method thereof |
| CN113831637A (en) * | 2021-09-16 | 2021-12-24 | 宿迁联盛科技股份有限公司 | Anti-aging master batch for flat filament product and preparation method thereof |
| CN113930003A (en) * | 2021-12-03 | 2022-01-14 | 海信视像科技股份有限公司 | MPPO material, mineral filling master batch and preparation method thereof |
| CN113930003B (en) * | 2021-12-03 | 2023-09-08 | 海信视像科技股份有限公司 | MPPO material, mineral filled master batch and preparation method thereof |
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Application publication date: 20140611 |