CN103265375A - Zinc-iron-selenium-rich pollution-free organic compound fertilizer - Google Patents
Zinc-iron-selenium-rich pollution-free organic compound fertilizer Download PDFInfo
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Abstract
The invention relates to a zinc-iron-selenium-rich pollution-free organic compound fertilizer. The zinc-iron-selenium-rich pollution-free organic compound fertilizer is characterized by being prepared from the following materials in parts by weight: 80-100 parts of agricultural wastes, 20-30 parts of wild peppers, 20-30 parts of gingko seed coats, 20-30 parts of fructus cnidii and the like. Compared with the prior art, the zinc-iron-selenium-rich pollution-free organic compound fertilizer has the advantages of being good in weeding effect, safe to environment, unlikely to generate weed drug resistance and the like, and is extensive in application prospect.
Description
Technical field
The invention belongs to the nuisanceless fertilizer technical field, relate to a kind of zinc-iron-selenium enriched nuisanceless mixed organic manure.
Background technology
Plant can run into various disease and pests in the occurring in nature process of growth, fungus disease particularly, its kind is many, and disease is serious, and for example gold disease, red gold disease, dark fund disease etc. are generally, comparatively to be difficult to the disease of preventing and treating in many farm crop generations, bring tremendous loss to agriculture production, mainly occur in the parts such as tender seedling, bud, the tip of crop, blade is withered when serious, curls, the browning look, withered.A large amount of chemical means that use are prevented and treated at present, yet domesticly mainly contain the unicity of methyl medication for many years and the singularity of pharmaceutical chemicals be used to the medicament of preventing and treating Powdery Mildew, be easy in use operator and ecotope be made serious harm, and have residual in a large number, easy-clear does not cause injury to edible people, and therefore country is own through banning use of highly toxic pesticide, greatly develop the green non-pollution vegetables, so be badly in need of developing low toxicity even nontoxic public nuisance-free agricultural chemicals.The annual a large amount of underproduction of farm crop that all cause of causing harm of farmland weed.Use chemical herbicide to remain the main means of present weed control, but because a large amount of and unreasonable use chemical herbicide have caused problems such as environmental pollution, pesticide residue and weeds resistance, be subjected to extensive concern.Therefore, exploitation is efficient, the new herbicides of low toxicity, low residue, becomes the problem that presses for solution.From plant, seek biologically active substance, and then the environmentally friendly agricultural chemicals of development of new, be the hot fields of current domestic and international research.
China is large agricultural country, and about 400,000,000 m2 of area take place the crop diseases and pest crop smothering throughout the year, and annual the need produced and used 800,000 tons in agricultural chemicals, and agricultural chemicals has become indispensable factor in the agriculture production.Being extensive use of of agricultural chemicals, though vital role has been played in production development, also occurred such as insect pest, disease the resistance problem, to the pollution of environment and in agricultural and animal products residual and accumulation problem, injure natural enemy, destroy balance of nature, cause insect rampant problem etc. again.This development to novel pesticide has proposed higher requirement.Especially entered since 21 century, along with the cry of people's uphold nature, protection environment, concern food safety is day by day surging, harmless boilogical agricultural chemicals industry and biological control area research have obtained rare opportunity to develop.
Zinc, iron, the necessary trace element of selenium plant play the physiological action of equal importance with macroelement in guaranteeing the plant normal growth growth course, it is stable to have fertilizer efficiency, easily by plant absorbing, and the utilization ratio advantages of higher; Seed of Chinese Soapberry (Sapindus mukurossi Gatren) is a kind of deciduous tree of Sapindaceae (Sapindaceae) Sapindus (Sapindus), originates on the south China Yangtze valley and South East Asia Mainland various places, India and Japan.Studies show that contain multiple secondary metabolite in the Seed of Chinese Soapberry, some have good biological activity, have been widely used in daily use chemicals, medicine and other fields.But not about the report of Seed of Chinese Soapberry extract weeding activity, be not the weedicide product of activeconstituents with Seed of Chinese Soapberry exosper extract more so far.Therefore, exploitation is the plant-sourced weedicide product of activeconstituents with the Seed of Chinese Soapberry extract, has vast market prospect.The plant pesticide that also has at present some to extract in the kuh-seng, but it is unreasonable to fill a prescription, effect is not ideal, is not suitable for suitability for industrialized production, and the fertilizer of prior art only has the trophic function of fertilizer at present, does not have the effect of killing plant insect.Market in urgent need is a kind of to be conducive to environment protection, effectively sterilization, and weeding, and can be fit to the big nuisanceless bactericidal and herbicidal compound of the plant fertilizer of producing.
Summary of the invention
The invention provides a kind of zinc-iron-selenium enriched nuisanceless mixed organic manure and preparation method thereof, it is obtained by the feedstock production of following parts by weight: 80 ~ 100 parts of agricultural wastes, Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part, Sodium Selenite 55-60 part, ferrous sulfate 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part.It comprises the steps: above-mentioned agricultural wastes are piled trapezoidal heap, down punches from the top, and 10～15 of every square metre of hole counts, the material surface covers with gunnysack or straw screen or mat, begins to carry out aerobic fermentation, waits to pile temperature rise to 50 and ℃ picks up counting, and ferments 5～7 days; Carry out turning when the stockpile temperature begins to descend, fermented 5～7 days again, turning in later per 5～7 days was once fermented 35～45 days altogether, and fermenting process is finished; With the above-mentioned organism moisture content baking or dry in the air to 25～35%(wt) of becoming thoroughly decomposed that ferments;
(2) fermenting agent fermented liquid l～5 parts is joined in 95～99 parts of organism that become thoroughly decomposed, regulate moisture content 60～70%(wt), pH 6.5～7.5, abundant mixing, pile high 0.4-0.6 meter long strip shape stockpile, cover gunnysack or straw screen or mat, 25～30 ℃ of the temperature of control stockpile, turning every day once, fermentation culture is 5～8 days altogether, treat to stop after it covers with spore, dry in the air to moisture content 20～22%(wt), mushroom residue, 6%-10% stalk ash and the 600-1000g/T arbuscular mycorrhiza microbial inoculum according to mass percent interpolation 5%-10% obtains biological organic fertilizer then;
(3) get Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part according to described parts by weight, (70%) alcohol reflux that at every turn adds 30 times of amounts of medicinal material total amount, reflux twice, each 3 hours, merge alcohol extract, relative density is 1.6 medicinal extract when being evaporated to 65 ℃ through (0.08Mpa, 60 ℃), spraying drying gets dry extract; The medicinal extract that obtains is scattered in the distilled water by above-mentioned prescription adds Sodium Selenite 55-60 part, ferrous sulfate 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part obtain inorganic fertilizer;
(4) be that the ratio mixing of 3-4:1-2 namely obtains multi-component composite fertilizer with inorganic fertilizer in the biological organic fertilizer in the step (2) and the step (3) according to mass ratio.Described agricultural wastes comprise stalk, bran, rice husk, oil cake, dregs of beans, wood powder, pericarp, weeds, fermenting agent is for producing yellowish fiber Zymomonas mobilis (Cellulomonas flavigena), lactobacterium casei (Lactobacillus casei), Wei Nielande vinelandii (Azotobacter vinelandii), rhizobium leguminosarum (Rhizobium leguminosarum), aspergillus niger (Aspergillus niger), aspergillus oryzae (Aspergillus oryzae), the mixture of special humicola lanuginosa (Humicola insolens), mass ratio is 1: 0.8: 1.2: 1.4:0.6: 0.8:1.2.
Described bacterial classification is commercial commercially available bacterial classification, all can buy by conventional commercial channel.
Bactericidal and herbicidal agent of the present invention can be used for broadcasting the preceding soil treatment of back seedling, prevents and kill off the sterilization idiocratic of farmland weed and wide spectrum.Compared with prior art, it is good, environmentally safe that formulation of the present invention has a herbicidal effect, and weeds characteristics such as be difficult for developing immunity to drugs have a extensive future.Formulation of the present invention is remarkable to the common disease-controlling effect of fruit, wheat, paddy rice and vegetables.Bactericidal and herbicidal agent of the present invention relatively safely to eyes, skin nonirritant, is low toxicity through bright its acute toxicity of day skin test checking to people and animals, easily decomposes in atmosphere and soil, and non-poisonous material is residual; Bactericidal and herbicidal agent of the present invention is little to the influence of farmland natural enemy, helps to keep ecotope, and is more friendly to environment, satisfies the production requirement of crop; The collocation of trace element not only has promoter action to plant growth, and the harmful bacterium in the soil is had killing action, effectively prevents and treats soil-borne disease.
Embodiment
The present invention is described in further detail by the following examples, but should be appreciated that the present invention is not in following examples.
Embodiment 1: the preparation of zinc-iron-selenium enriched nuisanceless mixed organic manure
A kind of zinc-iron-selenium enriched nuisanceless mixed organic manure and preparation method thereof, it is obtained by the feedstock production of following parts by weight: 80 ~ 100 parts of agricultural wastes, Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part, Sodium Selenite 55-60 part, ferrous sulfate 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part.It comprises the steps: above-mentioned agricultural wastes are piled trapezoidal heap, down punches from the top, and 10～15 of every square metre of hole counts, the material surface covers with gunnysack or straw screen or mat, begins to carry out aerobic fermentation, waits to pile temperature rise to 50 and ℃ picks up counting, and ferments 5～7 days; Carry out turning when the stockpile temperature begins to descend, fermented 5～7 days again, turning in later per 5～7 days was once fermented 35～45 days altogether, and fermenting process is finished; With the above-mentioned organism moisture content baking or dry in the air to 25～35%(wt) of becoming thoroughly decomposed that ferments;
(2) fermenting agent fermented liquid l～5 parts is joined in 95～99 parts of organism that become thoroughly decomposed, regulate moisture content 60～70%(wt), pH 6.5～7.5, abundant mixing, pile high 0.4-0.6 meter long strip shape stockpile, cover gunnysack or straw screen or mat, 25～30 ℃ of the temperature of control stockpile, turning every day once, fermentation culture is 5～8 days altogether, treat to stop after it covers with spore, dry in the air to moisture content 20～22%(wt), mushroom residue, 6%-10% stalk ash and the 600-1000g/T arbuscular mycorrhiza microbial inoculum according to mass percent interpolation 5%-10% obtains biological organic fertilizer then;
(3) get Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part according to described parts by weight, (70%) alcohol reflux that at every turn adds 30 times of amounts of medicinal material total amount, reflux twice, each 3 hours, merge alcohol extract, relative density is 1.6 medicinal extract when being evaporated to 65 ℃ through (0.08Mpa, 60 ℃), spraying drying gets dry extract; The medicinal extract that obtains is scattered in the distilled water by above-mentioned prescription adds Sodium Selenite 55-60 part, ferrous sulfate 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part obtain inorganic fertilizer;
(4) be that the ratio mixing of 3-4:1-2 namely obtains multi-component composite fertilizer with inorganic fertilizer in the biological organic fertilizer in the step (2) and the step (3) according to mass ratio.Described agricultural wastes comprise stalk, bran, rice husk, oil cake, dregs of beans, wood powder, pericarp, weeds, fermenting agent is for producing yellowish fiber Zymomonas mobilis (Cellulomonas flavigena), lactobacterium casei (Lactobacillus casei), Wei Nielande vinelandii (Azotobacter vinelandii), rhizobium leguminosarum (Rhizobium leguminosarum), aspergillus niger (Aspergillus niger), aspergillus oryzae (Aspergillus oryzae), the mixture of special humicola lanuginosa (Humicola insolens), mass ratio is 1: 0.8: 1.2: 1.4:0.6: 0.8:1.2.
Described bacterial classification is commercial commercially available bacterial classification, all can buy by conventional commercial channel.
Embodiment 2: the bacteriostatic test effect of zinc-iron-selenium enriched nuisanceless mixed organic manure
The bactericidal and herbicidal fertilizer that the embodiment of the invention 1 makes is prevented and treated rice sheath blight disease, cucumber downy mildew, pears black heart field control effectiveness test:
3 processing are established in each test altogether, 4 repetitions, and each residential quarter area 10m2 carries out test design, wherein A according to the completely random design: the clear water blank; B: 800 times of diluent positive controls of compound derosal; C: the fertile 300 times of diluents of compound of the present invention.Use medicine 4 times, interval 7d.
Investigation content and data processing: every residential quarter is selected 30 samples at random, 7d investigation before using medicine and after the 4th perfusion, record diseased plant number.Carry out the output investigation during results, the single receipts in every residential quarter, weighing separately.
Sickness rate (%)=(the total strain number of diseased plant number/investigation) * 100.
Prevention effect (%)=[(check plot sickness rate-treatment zone sickness rate)/check plot sickness rate] * 100.
Test-results shows that the inequality heteropole is remarkable between pesticide control rice sheath blight disease of the present invention, cucumber downy mildew, pears black heart and the clear water blank; Prevention effect on average reaches 78.3%, to preventing and treating rice sheath blight disease positive effect is arranged, and arrives 85.2%.
Embodiment 3: the controlling weeds test effect of zinc-iron-selenium enriched nuisanceless mixed organic manure
The fertile control of the compound that the embodiment of the invention 1 makes artemisiifolia, the bent grass of crawling, annual bluegrass and Bermuda grass field control effectiveness test:
3 processing are established in each test altogether, 4 repetitions, and each residential quarter area 10m2 carries out test design, wherein A according to the completely random design: the clear water blank; B: 800 times of diluent positive controls of compound derosal; C: the fertile 300 times of diluents of compound of the present invention.Use medicine 4 times, interval 7d.
Investigation content and data processing: every residential quarter is selected 30 samples at random, 7d investigation before using medicine and after the 4th perfusion, record diseased plant number.Carry out the output investigation during results, the single receipts in every residential quarter, weighing separately.
Sickness rate (%)=(the total strain number of diseased plant number/investigation) * 100.
Prevention effect (%)=[(check plot sickness rate-treatment zone sickness rate)/check plot sickness rate] * 100.
Test-results shows that the inequality heteropole is remarkable between pesticide control artemisiifolia of the present invention, the bent grass of crawling, annual bluegrass and Bermuda grass and the clear water blank; Prevention effect on average reaches 76.1%, and control Bermuda grass, artemisiifolia are had positive effect, arrives 84.1%, 82.2%.
Embodiment 4: the control cucumber of zinc-iron-selenium enriched nuisanceless mixed organic manure is withered, the sclerotium disease test effect
Withered, the sclerotium disease field control effectiveness test of bactericidal and herbicidal fertilizer control cucumber that the embodiment of the invention 1 makes:
3 processing are established in each test altogether, 4 repetitions, and each residential quarter area 10m2 carries out test design, wherein A according to the completely random design: the clear water blank; B: 800 times of diluent positive controls of compound derosal; C: the fertile 300 times of diluents of compound of the present invention.Use medicine 4 times, interval 7d.
Investigation content and data processing: every residential quarter is selected 30 samples at random, 7d investigation before using medicine and after the 4th perfusion, record diseased plant number.Carry out the output investigation during results, the single receipts in every residential quarter, weighing separately.
Sickness rate (%)=(the total strain number of diseased plant number/investigation) * 100.
Prevention effect (%)=[(check plot sickness rate-treatment zone sickness rate)/check plot sickness rate] * 100.
Test-results shows, pesticide control cucumber of the present invention is withered, the inequality heteropole is remarkable between sclerotium disease test effect and the clear water blank; Prevention effect on average reaches 80.3%.
Claims (5)
1. zinc-iron-selenium enriched nuisanceless mixed organic manure and preparation method thereof, it is characterized in that, it is obtained by the feedstock production of following parts by weight: 80 ~ 100 parts of agricultural wastes, Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part, Sodium Selenite 55-60 part, ferrous sulfate 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part.
2. mixed organic manure according to claim 1, it is characterized in that, it comprises the steps: above-mentioned agricultural wastes are piled trapezoidal heap, down punch from the top, 10～15 of every square metre of hole counts, the material surface covers with gunnysack or straw screen or mat, begins to carry out aerobic fermentation, wait to pile temperature rise to 50 and ℃ pick up counting, fermented 5～7 days; Carry out turning when the stockpile temperature begins to descend, fermented 5～7 days again, turning in later per 5～7 days was once fermented 35～45 days altogether, and fermenting process is finished; With the above-mentioned organism moisture content baking or dry in the air to 25～35%(wt) of becoming thoroughly decomposed that ferments;
(2) fermenting agent fermented liquid l～5 parts is joined in 95～99 parts of organism that become thoroughly decomposed, regulate moisture content 60～70%(wt), pH 6.5～7.5, abundant mixing, pile high 0.4-0.6 meter long strip shape stockpile, cover gunnysack or straw screen or mat, 25～30 ℃ of the temperature of control stockpile, turning every day once, fermentation culture is 5～8 days altogether, treat to stop after it covers with spore, dry in the air to moisture content 20～22%(wt), mushroom residue, 6%-10% stalk ash and the 600-1000g/T arbuscular mycorrhiza microbial inoculum according to mass percent interpolation 5%-10% obtains biological organic fertilizer then;
(3) get Stellera chamaejasme L. 1-15 part, hops 5-10 part, Chinese prickly ash 25-30 part, ginkgo kind skin 25-30 part, Fructus Cnidii 26-30 part, Cortex Meliae 17-30 part, Rangooncreeper Fruit 16-25 part, Turkey-galls 1-15 part, Root of Pubescent Holly 5-15 part, matrine 5-10 part, Seed of Chinese Soapberry exosper 55-60 part according to described parts by weight, (70%) alcohol reflux that at every turn adds 30 times of amounts of medicinal material total amount, reflux twice, each 3 hours, merge alcohol extract, relative density is 1.6 medicinal extract when being evaporated to 65 ℃ through (0.08Mpa, 60 ℃), spraying drying gets dry extract; The medicinal extract that obtains is scattered in the distilled water by above-mentioned prescription adds Sodium Selenite 55-60 part, ferrous sulfate 45-55 part, carbon ammonium 35-45 part, diammonium phosphate 20-30 part, Repone K 5-10 part, zinc sulfate 1-2 part, boric acid 1-2 part, medical stone powder 25-30 part, calcium stone flour 5-10 part, wilkinite 20-25 part, thiocarbamide 5-15 part, diatomite 10-20 part, ground phosphate rock 10-20 part, Sodium salts humic acids 5-15 part obtain inorganic fertilizer;
(4) be that the ratio mixing of 3-4:1-2 namely obtains multi-component composite fertilizer with inorganic fertilizer in the biological organic fertilizer in the step (2) and the step (3) according to mass ratio.
3. multi-component composite fertilizer according to claim 1, it is characterized in that: described agricultural wastes comprise stalk, bran, rice husk, oil cake, dregs of beans, wood powder, pericarp, weeds, fermenting agent is for producing yellowish fiber Zymomonas mobilis (Cellulomonas flavigena), lactobacterium casei (Lactobacillus casei), Wei Nielande vinelandii (Azotobacter vinelandii), rhizobium leguminosarum (Rhizobium leguminosarum), aspergillus niger (Aspergillus niger), aspergillus oryzae (Aspergillus oryzae), the mixture of special humicola lanuginosa (Humicola insolens), mass ratio is 1: 0.8: 1.2: 1.4:0.6: 0.8:1.2.
4. the application of mixed organic manure according to claim 1 in cereal class, fruit tree, vegetables.
5. the application of compound mixing fertilizer according to claim 3 in cereal class, fruit tree, vegetables; It is characterized in that: described crop is cucumber.
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| CN103708862A (en) * | 2013-12-31 | 2014-04-09 | 苏州科大微龙信息技术有限公司 | Ferment humic acid organic selenium fertilizer and preparation method thereof |
| CN103936500A (en) * | 2014-03-26 | 2014-07-23 | 山东省果树研究所 | Fertilizer composition for improving stress resistance of land planted pear trees |
| CN104003787A (en) * | 2014-03-26 | 2014-08-27 | 山东省果树研究所 | Pear tree fertilizer composition for planting in saline-alkali land |
| CN104291971A (en) * | 2014-09-26 | 2015-01-21 | 安徽禾泉种业有限公司 | Zinc-rich special slow-release fertilizer for rice and preparation method thereof |
| CN104402634A (en) * | 2014-12-15 | 2015-03-11 | 青岛百瑞吉生物工程有限公司 | Special fertilizer for cauliflower vegetables |
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| CN106717768A (en) * | 2016-11-16 | 2017-05-31 | 北海市农业科学研究所 | Selenium-rich peanuts implantation methods |
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| CN103708862A (en) * | 2013-12-31 | 2014-04-09 | 苏州科大微龙信息技术有限公司 | Ferment humic acid organic selenium fertilizer and preparation method thereof |
| CN103936500A (en) * | 2014-03-26 | 2014-07-23 | 山东省果树研究所 | Fertilizer composition for improving stress resistance of land planted pear trees |
| CN104003787A (en) * | 2014-03-26 | 2014-08-27 | 山东省果树研究所 | Pear tree fertilizer composition for planting in saline-alkali land |
| CN104003787B (en) * | 2014-03-26 | 2015-09-16 | 山东省果树研究所 | For the pear tree Ru 2006101161 of saltings plantation |
| CN103936500B (en) * | 2014-03-26 | 2016-03-09 | 山东省果树研究所 | For improving the Ru 2006101161 of field planting pear tree resistance |
| CN104291971A (en) * | 2014-09-26 | 2015-01-21 | 安徽禾泉种业有限公司 | Zinc-rich special slow-release fertilizer for rice and preparation method thereof |
| CN104402634A (en) * | 2014-12-15 | 2015-03-11 | 青岛百瑞吉生物工程有限公司 | Special fertilizer for cauliflower vegetables |
| CN106717768A (en) * | 2016-11-16 | 2017-05-31 | 北海市农业科学研究所 | Selenium-rich peanuts implantation methods |
| CN106588500A (en) * | 2016-12-23 | 2017-04-26 | 庆阳敦博科技发展有限公司 | Method for producing biological organic fertilizer by utilizing pericarpium zanthoxyli seed meal |
| CN106699395A (en) * | 2017-01-04 | 2017-05-24 | 桂林桂开生物科技股份有限公司 | Macro-element water soluble fertilizer with insecticidal and bactericidal effects and preparation method thereof |
| CN108002915A (en) * | 2017-12-20 | 2018-05-08 | 贺州市昊辰农业发展有限公司 | High disease resisting rice selenium-rich fertilizer and its preparation method and application |
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