CN103254797A - Photocatalyst water wax and preparation method thereof - Google Patents
Photocatalyst water wax and preparation method thereof Download PDFInfo
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- CN103254797A CN103254797A CN2013101365249A CN201310136524A CN103254797A CN 103254797 A CN103254797 A CN 103254797A CN 2013101365249 A CN2013101365249 A CN 2013101365249A CN 201310136524 A CN201310136524 A CN 201310136524A CN 103254797 A CN103254797 A CN 103254797A
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Abstract
The invention relates to the technical field of furniture wax and in particular relates to photocatalyst water wax and a preparation method thereof. The photocatalyst water wax comprises water-base wax slurry, a bactericide, propylene glycol, nanometer inorganic pigment, an antifoaming agent, water-base resin, AMP (Adenosine Monophosphate) 95 and water, which are mixed under different stirring speeds in batches. The photocatalyst water wax disclosed by the invention can be used for forming a layer of bright protective film on the surface of the furniture, so that the furniture has smoother and brighter color, and has the functions including water resistance, oxidation resistance, ultraviolet ray resistance and the like. Moreover, the harmful substances including formaldehyde and the like in the indoor air can be decomposed and lowered, so that the long-term body health can be protected while the furniture is protected.
Description
Technical field
The present invention relates to furniture wax technical field, particularly relate to a kind of photocatalyst water wax and preparation method thereof.
Background technology
Formaldehyde is generally believed it is indoor first killer by all circles, and it is very serious to human body especially infant, pregnant women, old man and chronic.Its main source has several aspects:
(1), as all kinds of Phenol aldehyde resin wood-based plate of finishing material such as wall dunnage, top ceiling, such as plywood, thin plank, fiberboard and shaving board etc.;
(2), contain formaldehyde composition and the finishing material that might distribute to the external world, such as WALL CLOTH, wallpaper, paint and coating pipe;
(3), indoor display and the daily necessities that might distribute formaldehyde, such as furniture, chemical fibre carpet and porous plastics etc.;
(4), can distribute some material of formaldehyde after the burning, such as cigarette and some organic materialss;
(5), some perfume compound, kill mosquito liquid and also contain the formaldehyde composition;
(6), at home in metope (coating) floor, furniture and some articles for use, pendulum decorations all handle with Antisepticize and mildew preventive in advance for anticorrosion mildew-resistant, most of sanitas is all influential to human body, especially formaldehyde is the most serious to the harm of human body.
These objectionable impuritiess exist in daily life environment and the household goods, and constantly discharge some objectionable impurities, and release period can be above 10 years.If do not eliminate these objectionable impuritiess in the home environment, long-term accumulated has very big threat to HUMAN HEALTH.
At present, remove the method for formaldehyde except ventilation and plant absorbing, mainly contain two kinds: the one, physisorphtion mainly utilizes the PARA FORMALDEHYDE PRILLS(91,95) of activated carbon, Exocarpium cocois (Cocos nucifera L), polymer formaldehyde-trapping agent and so on to carry out physical absorption.Advantage is nontoxic to human body, and shortcoming absorption rate and effect are not too desirable.
The 2nd, chemical process, wherein a kind of is to utilize de-aldehyde agent, directly brushes on sheet material or the seam crossing of sheet material, infiltration sheet material is combined with formaldehyde and is formed solid; This method acts on root, but preferably not being assembled into cupboard, perhaps uses in the making processes of sheet material again, just can reach best effect.If directly cashier's office in a shop brush at finished product, because plate surface is handled, the effect that aldehydes removal liquid infiltrates is bad.Another kind is to utilize spraying, and this benefit is exactly to catch formaldehyde free in the air fast, does not have what taste; But can produce crystallisate after some chemical substance and the formaldehyde effect, may drop on any corner, HUMAN HEALTH is had certain influence; If eaten by mistake, consequence is comparatively serious.
Therefore people are in order to reduce indoor formaldehyde as far as possible, except the starting material that as far as possible adopt environmental protection, also can add the functional agent that some can absorbing formaldehyde in coating for example.But with regard to furniture, for stupid stain, dirt, the removal surface that can fast, thoroughly remove furniture surface slight scratches and grinding vestige, usually also can be at outermost layer wiping one deck wax, make it form the protective membrane of one deck light at furniture surface, make furniture present beautiful color Paint Gloss, have multiple functions such as waterproof, anti-oxidant, uvioresistant simultaneously; But the existence meeting barriers function coating of cere and contacting of air, reduced functional paint except the function of formaldehyde.
Summary of the invention
In order to address the above problem, the objective of the invention is to, provide a kind of can fine protection furniture, the photocatalyst water wax that has formaldehyde function in the good absorption environment simultaneously.
The present invention is achieved through the following technical solutions:
A kind of photocatalyst water wax comprises the following material that calculates according to weight percent:
Preferably, described water-based wax slurry is the one or more combination thing in paraffin, PE wax, PP wax or the palm wax.
Preferably, described water-base resin is minimum film-forming temperature less than 0 ℃ PUD water-base resin.
Preferably, described nano inorganic pigment is nanometer grade silica (SiO
2), nano level aluminium sesquioxide (A1
2O
3), nano level boron oxide (B
2O
3), nano level ferric oxide (Fe
2O
3), nano level magnesium oxide (MgO), nano level titanium oxide (TiO
2) in the one or more combination thing.
Wherein, described nano inorganic pigment is more preferably by comprising that the following material that calculates according to weight percent forms:
Preferably, after described nano inorganic pigment is mixed according to the proportioning of above-mentioned amount by described nanometer grade silica, nano level aluminium sesquioxide, nano level boron oxide, nano level ferric oxide, nano level magnesium oxide, nano level titanium oxide, under 900～1100rpm, stir 30～40min preparation and get.
The method for preparing described photocatalyst water wax comprises being prepared as follows step:
Nano inorganic pigment, water-based wax slurry, sterilant, propylene glycol, nano inorganic pigment, water with above-mentioned amount stirs 8～15min under 500～700rpm earlier;
Add described defoamer then and under 700～100rpm, stir 8～15min;
Add water-base resin when then low whipping speed is constant, stir 5min;
Add described AMP95 at last, under 700～1000rpm, stir 8～15min; Make described photocatalyst water wax.
The present invention includes water-based wax slurry, sterilant, propylene glycol, nano inorganic pigment, defoamer, water-base resin, AMP95 and water, and get by under different stirring velocitys, mix in batches; Wherein water-based wax slurry can be paraffin, PE wax, PP wax, palm wax, mainly is for promoting feel, the protection coated article.Sterilant is not for containing the sterilant that has of formaldehyde, and the effect of propylene glycol mainly is to increase operability; Water is deionized water or tap water, can produce bubble, the preferred organosilicon of defoamer and mineral oil type defoamer in the stirring; Water-base resin is the PUD water-base resin, and minimum film-forming temperature does not contain organic solvent less than 0 ℃.AMP95 is that the pH value is adjusted agent, and adjusting the pH value is 8～9, increases stability in storage.
The present invention adopts nano inorganic pigment, can discharge negative ion, is combined with harmful substances in air and then decomposes to fall objectionable impurities; The composition of the different proportionings of the multiple nano-scale oxide of nano inorganic pigment optimization wherein, such combination is that the different performance according to every kind of material carries out compatibility, guarantee that it discharges the persistence of negative ion, when guaranteeing that described water-based wax is starched objectionable impurities validity such as adsorbing decomposing formaldehyde, guarantee the absorption capacity of decomposition that it is lasting.For nano inorganic pigment can be rested on furniture or the articles for use for a long time, need to add can film forming material (resin) from the objectionable impurities that furniture or articles for use discharge, just can be avoided evaporateing in the air by negative ion decomposition at once.Wax has defencive function, can reduce furniture or articles for use and be subjected to externality (as: scratch or adhesion dust).The solvent-borne type wax organic solvent influence environment that can volatilize is so adopt environment-friendly type water wax.The storage of water is subject to bacterial contamination and smelly, adds the growth that the sterilant that does not contain formaldehyde can suppress bacterium.Do not add essence, do not have smell fully.
The present invention not only has the function of wax fully, can fast, thoroughly remove slight scratches and the grinding vestige in stupid stain, dirt, removal surface of furniture surface, can also form the protective membrane of one deck light at furniture surface, make furniture present beautiful color Paint Gloss, have abilities such as waterproof, anti-oxidant, uvioresistant simultaneously; And by wiping or spraying to furniture; the wax layer is near the furniture side on the one hand; can well decompose with sealing by objectionable impuritiess such as formaldehyde that furniture itself produces; make it can not be distributed in the air; the opposing party's mercolized wax layer is near air side, and containing nano inorganic pigment by it can be under uviolizing, objectionable impurities generation redox reactions such as catalysis formaldehyde, benzene, VOC; thereby decompose the objectionable impurities that reduces in the room air, not only can protect furniture more can protect health healthy for a long time simultaneously.
Concrete embodiment
The present invention is described in further detail below in conjunction with embodiment, understands the present invention to help those skilled in the art.
Embodiment 1
A kind of photocatalyst water wax comprises the following material that calculates according to weight percent: water-based PP wax 25.0%, sterilant 0.3%, propylene glycol 1.5%, nanometer grade silica 3.0%, defoamer 0.15%, water-base resin 12.0%, AMP950.01% and water.
The method for preparing described photocatalyst water wax comprises being prepared as follows step:
Photocatalyst, water-based wax slurry, sterilant, propylene glycol, nano inorganic pigment, water with above-mentioned amount stirs 15min under 700rpm earlier; Add described defoamer then and under 700rpm, stir 15min; Add water-base resin when then low whipping speed is constant, stir 5min; Add described AMP95 at last, under 700rpm, stir 15min and make described photocatalyst water wax.
Embodiment 2
A kind of photocatalyst water wax comprises the following material that calculates according to weight percent: water-based paraffin 30.0%, sterilant 0.2%, propylene glycol 1.0%, nano inorganic pigment 5.0%, defoamer 0.1%, water-base resin 10.0%, AMP950.02% and water.
Wherein, described nano inorganic pigment is by comprising that the following material that calculates according to weight percent mixes and get: nanometer grade silica 1.5%, nano level aluminium sesquioxide 0.5%, nano level boron oxide 0.5%, nano level ferric oxide 1.0%, nano level magnesium oxide 0.5% and nano level titanium oxide 1.0% are stirred 30min prepare and get under 1000rpm.
The method for preparing described photocatalyst water wax comprises being prepared as follows step:
Photocatalyst, water-based wax slurry, sterilant, propylene glycol, nano inorganic pigment, water with above-mentioned amount stirs 10min under 800rpm earlier; Add described defoamer then and under 900rpm, stir 10min; Add water-base resin when then low whipping speed is constant, stir 5min; Add described AMP95 at last, under 800rpm, stir 10min and make described photocatalyst water wax.
Embodiment 3
A kind of photocatalyst water wax comprises the following material that calculates according to weight percent: water-based PE wax 30.0%, sterilant 0.2%, propylene glycol 1.0%, nano inorganic pigment 5.0%, defoamer 0.1%, water-base resin 10.0%, AMP950.02% and water.
Wherein, described nano inorganic pigment is by comprising that the following material that calculates according to weight percent mixes and get: nanometer grade silica 1.2%, nano level aluminium sesquioxide 0.8%, nano level boron oxide 0.3%, nano level ferric oxide 0.8%, nano level magnesium oxide 0.8% and nano level titanium oxide 1.1% are stirred 35min prepare and get under 900rpm.
The method for preparing described photocatalyst water wax comprises being prepared as follows step:
Photocatalyst, water-based wax slurry, sterilant, propylene glycol, nano inorganic pigment, water with above-mentioned amount stirs 10min under 800rpm earlier; Add described defoamer then and under 800rpm, stir 10min; Add water-base resin when then low whipping speed is constant, stir 5min; Add described AMP95 at last, under 800rpm, stir 10min and make described photocatalyst water wax.
Embodiment 4
A kind of photocatalyst water wax comprises the following material that calculates according to weight percent: water-based palm wax 30.0%, sterilant 0.2%, propylene glycol 1.0%, nano inorganic pigment 5.0%, defoamer 0.1%, water-base resin 10.0%, AMP95 0.02% and water.
Wherein, described nano inorganic pigment is by comprising that the following material that calculates according to weight percent mixes and get: nanometer grade silica 1.8%, nano level aluminium sesquioxide 0.3%, nano level boron oxide 0.8%, nano level ferric oxide 1.0%, nano level magnesium oxide 0.3% and nano level titanium oxide 0.8% are stirred 30min prepare and get under 1000rpm.
The method for preparing described photocatalyst water wax comprises being prepared as follows step:
Photocatalyst, water-based wax slurry, sterilant, propylene glycol, nano inorganic pigment, water with above-mentioned amount stirs 10min under 800rpm earlier; Add described defoamer then and under 800rpm, stir 10min; Add water-base resin when then low whipping speed is constant, stir 5min; Add described AMP95 at last, under 800rpm, stir 10min and make described photocatalyst water wax.
Embodiment 5
A kind of photocatalyst water wax comprises the following material that calculates according to weight percent:
Water-based wax slurry 32.0%(is comprising paraffin 5.0%, PE wax 5.0% and palm wax 22.0%), sterilant 0.25%, propylene glycol 1.2%, nano inorganic pigment 6.0%, defoamer 0.12%, water-base resin 9.5%, AMP950.25% and water.
Wherein, described nano inorganic pigment is by comprising that the following material that calculates according to weight percent mixes and get: nanometer grade silica 0.5%, nano level aluminium sesquioxide 0.5%, nano level boron oxide 0.5%, nano level ferric oxide 1.0%, nano level magnesium oxide 0.5% and nano level titanium oxide 1.0% are stirred 30min prepare and get under 1000rpm.
The method for preparing described photocatalyst water wax comprises being prepared as follows step:
Photocatalyst, water-based wax slurry, sterilant, propylene glycol, nano inorganic pigment, water with above-mentioned amount stirs 8min under 700rpm earlier; Add described defoamer then and under 1000rpm, stir 8min; Add water-base resin when then low whipping speed is constant, stir 5min; Add described AMP95 at last, under 1000rpm, stir 8min and make described photocatalyst water wax.
Above-described embodiment is preferred embodiment of the present invention, is not to limit the scope of the present invention, so all equivalences of being done with the described structure of claim of the present invention, feature and principle change or modify, all should be included within the claim scope of the present invention.
The present invention is detected with the JC/T1074-2008 method, and its result is as follows:
1, purifying formaldehyde performance:
2, purifying formaldehyde consistency of performance:
As seen from the above table, no matter the present invention is in the purifying formaldehyde performance, still aspect the purifying formaldehyde consistency of performance obvious effects is being arranged, along with the increase of time, detected formaldehyde content reduces, and illustrates that the present invention has the function of decomposing and absorbing formaldehyde.
Claims (7)
1. a photocatalyst water wax is characterized in that, comprises the following material that calculates according to weight percent:
2. photocatalyst water wax according to claim 1 is characterized in that, described water-based wax slurry is the one or more combination thing in paraffin, PE wax, PP wax or the palm wax.
3. photocatalyst water wax according to claim 1 is characterized in that, described water-base resin is minimum film-forming temperature less than 0 ℃ PUD water-base resin.
4. photocatalyst water wax according to claim 1, it is characterized in that described nano inorganic pigment is the one or more combination thing in nanometer grade silica, nano level aluminium sesquioxide, nano level boron oxide, nano level ferric oxide, nano level magnesium oxide, the nano level titanium oxide.
5. photocatalyst water wax according to claim 4 is characterized in that, described nano inorganic pigment is by comprising that the following material that calculates according to weight percent forms:
6. photocatalyst water wax according to claim 5, it is characterized in that, after described nano inorganic pigment is mixed according to the proportioning of above-mentioned amount by described nanometer grade silica, nano level aluminium sesquioxide, nano level boron oxide, nano level ferric oxide, nano level magnesium oxide, nano level titanium oxide, under 900～1100rpm, stir 30～40min preparation and get.
7. prepare the method for any described photocatalyst water wax in the claim 1～6, it is characterized in that, comprise being prepared as follows step:
Nano inorganic pigment, water-based wax slurry, sterilant, propylene glycol, nano inorganic pigment, water with above-mentioned amount stirs 8～15min under 500～700rpm earlier;
Add described defoamer then and under 700～100rpm, stir 8～15min;
Add water-base resin when then low whipping speed is constant, stir 5min;
Add described AMP95 at last, under 700～1000rpm, stir 8～15min and make described photocatalyst water wax.
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|---|---|---|---|
| CN201310136524.9A CN103254797B (en) | 2013-04-18 | 2013-04-18 | A kind of Photocatalyst water wax and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310136524.9A CN103254797B (en) | 2013-04-18 | 2013-04-18 | A kind of Photocatalyst water wax and preparation method thereof |
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| CN103254797A true CN103254797A (en) | 2013-08-21 |
| CN103254797B CN103254797B (en) | 2015-10-28 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106239664A (en) * | 2016-08-25 | 2016-12-21 | 阜南县永兴工艺品有限公司 | A kind of high temperature resistant aging resistance straw treatment fluid and preparation method thereof |
| CN107556915A (en) * | 2017-10-10 | 2018-01-09 | 佛山市三水区白坭镇巨财红木厂 | A kind of wear-resisting paraffin of furniture |
| CN109705727A (en) * | 2018-12-27 | 2019-05-03 | 广东顺德三阳化学有限公司 | A kind of nanometer of protection liquid and preparation method thereof, household items protection product and nano protective film |
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| JP2007070546A (en) * | 2005-09-08 | 2007-03-22 | Matsushita Electric Works Ltd | Natural wax and moisture absorbing and releasing material with decoration given by using the same |
| CN101182402A (en) * | 2006-11-13 | 2008-05-21 | 北京金源化学集团有限公司 | Aqueous antibiotic floor wax |
| CN101597457A (en) * | 2008-06-07 | 2009-12-09 | 济南公泰科技有限公司 | Nanometer photocatalyst aqueous polyester coating for woodenware |
| CN102408828A (en) * | 2011-09-29 | 2012-04-11 | 刘光君 | Nano silicon dioxide modified hard wood wax oil and preparation method thereof |
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2013
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007070546A (en) * | 2005-09-08 | 2007-03-22 | Matsushita Electric Works Ltd | Natural wax and moisture absorbing and releasing material with decoration given by using the same |
| CN101182402A (en) * | 2006-11-13 | 2008-05-21 | 北京金源化学集团有限公司 | Aqueous antibiotic floor wax |
| CN101597457A (en) * | 2008-06-07 | 2009-12-09 | 济南公泰科技有限公司 | Nanometer photocatalyst aqueous polyester coating for woodenware |
| CN102408828A (en) * | 2011-09-29 | 2012-04-11 | 刘光君 | Nano silicon dioxide modified hard wood wax oil and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106239664A (en) * | 2016-08-25 | 2016-12-21 | 阜南县永兴工艺品有限公司 | A kind of high temperature resistant aging resistance straw treatment fluid and preparation method thereof |
| CN107556915A (en) * | 2017-10-10 | 2018-01-09 | 佛山市三水区白坭镇巨财红木厂 | A kind of wear-resisting paraffin of furniture |
| CN109705727A (en) * | 2018-12-27 | 2019-05-03 | 广东顺德三阳化学有限公司 | A kind of nanometer of protection liquid and preparation method thereof, household items protection product and nano protective film |
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|---|---|
| CN103254797B (en) | 2015-10-28 |
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