CN103242731B - Disconnected hot coating - Google Patents
Disconnected hot coating Download PDFInfo
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- CN103242731B CN103242731B CN201310157566.0A CN201310157566A CN103242731B CN 103242731 B CN103242731 B CN 103242731B CN 201310157566 A CN201310157566 A CN 201310157566A CN 103242731 B CN103242731 B CN 103242731B
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- nephrite
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Abstract
The invention discloses a kind of disconnected hot coating, comprise the resin emulsion of 100 mass parts, particle diameter is hollow glass microballoon 15 ~ 30 mass parts of 60 ~ 120um, and particle diameter is nephrite 5 ~ 15 mass parts of 2 ~ 45um, and particle diameter is titanium dioxide 25 ~ 50 mass parts of 2 ~ 45um; Described hollow glass microballoon, nephrite and titanium dioxide are mixed in resin emulsion.Disconnected hot coating provided by the invention, containing aerogel and nephrite, has disconnected heat, sound insulation, waterproof, anti-dewing function, is easy to brushing at buildings and body surface.The present invention is easy to brushing at buildings and other body surfaces, especially for interior wall and the exterior wall of buildings, can form insulation layer, effectively can cut off the transmission of heat energy after brushing at surface of wall.Brushing is when inner wall of building, and heat then hotter chance is cold then colder; Brushing is when exterior wall, and heat is then colder, meets cold then hotter.Winter, summer energy-saving Be very effective.
Description
Technical field
The present invention relates to disconnected hot coating, be specifically related to one and be easily painted on buildings and other body surfaces, there is the disconnected hot coating of disconnected heat, sound insulation, waterproof, anti-dewing function.
Background technology
The composition of heat insulation material material for feature, is mainly used in building trade with barrier external body heat.As a kind of material of construction, it not only should have disconnected hot merit energy, also should have sound insulation and mildew-resistant, the effects such as antisweat simultaneously.
The raw material of composition section hot material, generally can select the material of low thermal conductivity.But the actual raw-material thermal conductivity used is not low, therefore raw material is made hollow shape, making to form gas cloud in ducted body, give raw material and raw mixture has disconnected hot merit energy, is one of conventional means.
The raw material that heat insulation material material uses, can be divided into organism and the large class of inorganics two substantially.Organic substance has cork, cotton, felt, carbide, rubber etc.; Inorganics comprises asbestos, glass fibre, diatomite, magnesiumcarbonate etc.The heat insulating inner wall of buildings uses the materials such as EPS foam, sponge, asbestos, glass wool usually, has occurred wood powder and waterproof resin to carry out the warming plate that hot pressing is made in the recent period, has been applied on a small quantity on heat insulating inner wall.
Be widely used in the eps foam plate of wall thermal insulating, be normally made up of the resin of 2% and the gas cloud of 95%.It has good water-fast, disconnected heat, sound insulation and shock-absorbing capacity, and shortcoming is that volume is large, transport inconvenience, and cracky is inflammable etc.And meeting Yin Wendu and humidity change, produce condensation in the interior tissue of material, grow enzyme and other pernicious bacteria.
Making of major part heat insulation material material, all because there being raw material foam production operation, causing finished product all to have sizable volume, bringing inconvenience to large-area construction.Also because most of forming material is produced with large gauge, the wasting phenomenon in construction is also very serious.
Recently, although there is the appearance of disconnected hot coating, because disconnected thermal characteristics does not reach the good level of picture eps foam plate etc., also not penetration and promotion in industry.
The Mohs' hardness of nephrite (Nephrite) is 61/2, and proportion (proportion refers to the weight of object and the ratio of its volume) is 2.96, and specific refractory power is 1.61 ~ 1.63, is the single crystal mineral substance with nacre and oiliness gloss.It contains a large amount of magnesium, and energy releasing beneficial, in the far infrared rays of human body, can promote blood circulation and the metabolism of human body, can reduce haemoconcentration, also have good oxidation effect.
The mixture brushed containing nephrite has many patents and comes out.No. 0173546th, Korean Patent, has done relevant elaboration to nephrite on water correction and removal heavy metal effect; No. 0620443rd, Korean Patent and No. 0526908, done associated description to the nephrite coating with far infrared rays release and deodorization functions; No. 0773418th, Korean Patent, to reducing volatile organic compounds and formaldehyde etc. and then hazard substance control having been done related introduction on the nephrite coating of minimum quantity.But in the functional coating field with disconnected heat and soundproof effect containing nephrite, still without any application and the appearance of Patents.
Summary of the invention
The object of the present invention is to provide a kind of disconnected hot coating, there is disconnected heat, sound insulation, waterproof, anti-dewing function, be easy to brushing at buildings and body surface.
For achieving the above object, technical scheme of the present invention is a kind of disconnected hot coating of design, comprise the resin emulsion of 100 mass parts, particle diameter is hollow glass microballoon 15 ~ 30 mass parts of 60 ~ 120um, particle diameter is nephrite 5 ~ 15 mass parts of 2 ~ 45um, and particle diameter is titanium dioxide 25 ~ 50 mass parts of 2 ~ 45um; Described hollow glass microballoon, nephrite and titanium dioxide are mixed in resin emulsion.
Preferably, the proportion of described resin emulsion is 1 ~ 1.5, and the proportion of hollow glass microballoon is 0.1 ~ 0.2, and the proportion of nephrite is 2.9 ~ 3.3, and the proportion of titanium dioxide is 3.8 ~ 4.2.
Preferably, described resin emulsion is the one in acryl resin emulsion, polyaminoester emulsion, epoxy resin latex.
Preferably, described resin emulsion is the one in the acryl resin emulsion of modification, polyaminoester emulsion, epoxy resin latex.
Preferably, also organosilicon crylic acid latex is mixed with in described resin emulsion.
Preferably, also dispersion agent is mixed with in described resin emulsion.
Preferably, 0.5 ~ 3 mass parts thickening material is also mixed with in described resin emulsion.
Be hollow glass microballoon 15 ~ 30 mass parts of 60 ~ 120um containing particle diameter in the resin emulsion of 100 mass parts.When the size of particles of hollow glass microballoon is not enough to range values, the hollow number of plies in film has and reduced, and affects sunlight reflectivity, cannot give full play to its disconnected thermal effect; If size of particles is higher than range values, raw material will be difficult in coating dispersed, and the disconnected thermal characteristics of film there will be locality deviation, and affects the endurance quality of coating.When the addition of hollow glass microballoon is less than specialized range value, the disconnected thermal characteristics of coating can decline to a great extent; If addition is higher than specialized range value, the addition of ACRYLIC EMULSION and other auxiliary agents can be limited to, and causes the elastomeric instability of polysilane.
The proportion of empty glass microsphere is 0.1 ~ 0.2, and lower much than the proportion 1 ~ 1.5 of resin emulsion, coating application is after object, and before dried coating film, glass microsphere has the feature being aggregated in coatingsurface.
Be nephrite 5 ~ 15 mass parts of 2 ~ 45um containing particle diameter in the resin emulsion of 100 mass parts.The chemical composition of nephrite is configured to SiO
2, MgO, CaO, Fe
2o
3, Al
2o
3, Na
2o, TiO
2, K
2o and other micro substance.General silica below 58 parts, magnesium oxide below 24 parts, CaO below 14 parts, Fe
2o
3and Al
2o
3deng metal ingredient less than 5 parts, and other trace mineral.When the size of particles of nephrite is less than mark numerical value, its disconnected thermal effect cannot be played; When being greater than mark numerical value, the high weight of particle can produce sedimentation in coating, and affects dispersed.
The proportion of nephrite is 2.9 ~ 3.3, higher than the proportion 1 ~ 1.5 of resin emulsion, and coating application is after body surface, and film nephrite in dry process of setting can form insulation layer below hollow glass microballoon.
Be titanium dioxide 25 ~ 50 mass parts of 2 ~ 45um containing particle diameter in the resin emulsion of 100 mass parts.Titanium dioxide is as pure white pigment particles, and size of particles is greater than or less than all can to film forming and dispersion when marking numerical range, and disconnected heat waits and produces certain influence.
The proportion of titanium dioxide is 3.8 ~ 4.2, higher than the proportion 1 ~ 1.5 of resin emulsion, and coating application, after body surface, can form titanium dioxide layer below nephrite layer.
For improving glass hollow microballoon in the unit elongation of film and final mixture, nephrite, being uniformly distributed of titanium dioxide, a certain amount of organosilicon crylic acid latex can be added.The interpolation of organosilicon crylic acid latex, also improves the water tolerance of coating and the weather resistance of film.Silicon system acrylic emulsion, in dry film forming process, produces hydration reaction with the moisture in air and hardens, being combined into the silicone elastomer with certain chemical stability.
The hollow glass microballoon being dispersed in coating top layer can reflect the solar infrared radiant heat of more than 90%, the infrared radiation hot bakers ' that all the other micro-heat energy of about 10% can discharge because of the respiratory function of film and coating, intercept outside coating, intercepted the transmission of outside heat substantially completely.
For preventing the floating of hollow glass microballoon in mixture liquid; For preventing the sedimentation in coating liquid of nephrite powder, titanium dioxide, in 100 mass parts resin emulsions, with the addition of 0.5 ~ 3 mass parts thickening material, stabilize weave construction.If when thickening material addition exceedes or is not enough to mark numerical value, the hollow glass microballoon layer in film, nephrite layer, the arrangement of titanium dioxide layer will be difficult to accomplished.
Advantage of the present invention and beneficial effect are: provide a kind of disconnected hot coating, it contains aerogel and nephrite, has disconnected heat, sound insulation, waterproof, anti-dewing function, is easy to brushing at buildings and body surface.
The present invention is easy to brushing at buildings and other body surfaces, especially for interior wall and the exterior wall of buildings, can form insulation layer, effectively can cut off the transmission of heat energy after brushing at surface of wall.Brushing is when inner wall of building, and heat then hotter chance is cold then colder; Brushing is when exterior wall, and heat is then colder, meets cold then hotter.Winter, summer energy-saving Be very effective.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
The technical scheme that the present invention specifically implements is:
Embodiment 1
In the acryl resin emulsion of 100 mass parts, add hollow glass microballoon 20 mass parts that median size is 80um, adding median size is 30um nephrite powder 8 mass parts, add titanium dioxide 35 mass parts that median size is 25um, add dispersion agent 3 mass parts, mix after adding thickening material 1.5 mass parts, then add 15 mass parts water and fully stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.85.
Embodiment 2
In the acryl resin emulsion of 100 mass parts, add hollow glass microballoon 20 mass parts that median size is 80um, adding median size is 30um nephrite powder 12 mass parts, add titanium dioxide 35 mass parts that median size is 25um, add dispersion agent 3 mass parts, mix after adding thickening material 1.5 mass parts, then add 15 mass parts water and fully stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.87.
Comparative example 1
In the acryl resin emulsion of 100 mass parts, add hollow glass microballoon 20 mass parts that median size is 80um, add titanium dioxide 35 mass parts that median size is 25um, add dispersion agent 3 mass parts, mix after adding thickening material 1.5 mass parts, then add 15 mass parts water fully to stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.82.
Comparative example 2
In the acryl resin emulsion of 100 mass parts, add hollow glass microballoon 20 mass parts that median size is 80um, adding median size is 30um nephrite powder 3 mass parts, add titanium dioxide 35 mass parts that median size is 25um, add dispersion agent 3 mass parts, mix after adding thickening material 1.5 mass parts, then add 15 mass parts water and fully stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.84.
Comparative example 3
In the acryl resin emulsion of 100 mass parts, add hollow glass microballoon 20 mass parts that median size is 80um, adding median size is 30um nephrite powder 18 mass parts, add titanium dioxide 35 mass parts that median size is 25um, add dispersion agent 3 mass parts, mix after adding thickening material 1.5 mass parts, then add 15 mass parts water and fully stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.90.
Comparative example 4
In the acryl resin emulsion of 100 mass parts, add hollow glass microballoon 20 mass parts that median size is 30um, adding median size is 30um nephrite powder 8 mass parts, add titanium dioxide 35 mass parts that median size is 25um, add dispersion agent 3 mass parts, mix after adding thickening material 1.5 mass parts, then add 15 mass parts water and fully stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.87.
The radiation effect of embodiment 1-2 and comparative example 1-4 compares:
By the disconnected hot coating of embodiment 1-2 and comparative example 1-4, with the thickness of 0.8mm, the iron plate being coated in 0.25mm with round brush carries out drying.
Be arranged on by 100w incandescent light below iron plate and (brushed the back side in coating iron plate face down), brushing 10cm place, the iron plate face device aluminium sheet of coating, time segment detects the temperature variations of aluminium sheet.Table 1 is the surface of aluminum plate temperature conditions of incandescent light irradiation iron plate after 1 hour.
Table 1 incandescent light irradiates the surface of aluminum plate temperature conditions of iron plate after 1 hour
As can be seen from Table 1, relative to comparative example 1 and 2, embodiment 1 and 2 has more outstanding radiation effect.With the addition of the comparative example 3 of 18 mass parts nephrite powders, on the contrary than the comparative example 1 of not adding nephrite, show lower radiation effect.Identical constant with embodiment 1 ratio of components, use the comparative example 4 of the hollow glass microballoon that median size is 30um, radiation effect all to some extent obviously reduces than embodiment 1 and 2.
The disconnected thermal effect of embodiment 1-2 and comparative example 1-4 compares:
By the disconnected hot coating of embodiment 1-2 and comparative example 1-4, with the thickness of 0.8mm, with round brush brushing on the iron plate thick with 0.25mm, manufacturing specification is the iron sheet case of 300*300*300, then carries out drying.
In the inner side and outer side of above-mentioned iron sheet case, install thermometer respectively, iron sheet case outside temperature, 45 DEG C time, tests the temperature conditions in iron sheet case, as shown in table 2.
Table 2 iron sheet case internal-external temperature difference situation
As can be seen from Table 2, iron sheet case outside temperature is 45 DEG C time, and the internal temperature of embodiment 1 and 2 is respectively 33.5 DEG C and 33.8 DEG C, compares the rising of ratio 1-4 iron sheet case internal temperature, has larger contrast.(45℃-11.5℃＝33.5℃，45℃-11.2℃＝33.8℃)
Embodiment 3
Be in the acryl resin emulsion of 1 at 100 mass parts, proportion, hollow glass microballoon 15 mass parts that interpolation median size is 60um, proportion is 0.1, nephrite powder 5 mass parts that interpolation median size is 2um, proportion is 2.9, titanium dioxide 25 mass parts that interpolation median size is 2um, proportion is 3.8, add organosilicon crylic acid latex 20 mass parts, add dispersion agent 3 mass parts, mix after adding thickening material 0.5 mass parts, then add 15 mass parts water fully to stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.9.
Embodiment 4
Be 1.5 and in the acryl resin emulsion of modification at 100 mass parts, proportion, hollow glass microballoon 30 mass parts that interpolation median size is 120um, proportion is 0.2, nephrite powder 15 mass parts that interpolation median size is 45um, proportion is 3.3, titanium dioxide 50 mass parts that interpolation median size is 45um, proportion is 4.2, add dispersion agent 3 mass parts, mix after adding thickening material 3 mass parts, then add 15 mass parts water fully to stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.89.
Embodiment 5
Be in the polyaminoester emulsion of 1.2 at 100 mass parts, proportion, hollow glass microballoon 25 mass parts that interpolation median size is 100um, proportion is 0.15, nephrite powder 10 mass parts that interpolation median size is 25um, proportion is 13.1, titanium dioxide 35 mass parts that interpolation median size is 35um, proportion is 3.9, add dispersion agent 3 mass parts, mix after adding thickening material 2 mass parts, then add 15 mass parts water and fully stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.85.
Embodiment 6
Be in the polyaminoester emulsion of 1 at 100 mass parts, proportion, hollow glass microballoon 15 mass parts that interpolation median size is 60um, proportion is 0.1, nephrite powder 5 mass parts that interpolation median size is 2um, proportion is 2.9, titanium dioxide 25 mass parts that interpolation median size is 2um, proportion is 3.8, add dispersion agent 3 mass parts, mix after adding thickening material 0.5 mass parts, then add 15 mass parts water and fully stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.87.
Embodiment 7
Be 1.5 and in the polyaminoester emulsion of modification at 100 mass parts, proportion, hollow glass microballoon 30 mass parts that interpolation median size is 120um, proportion is 0.2, nephrite powder 15 mass parts that interpolation median size is 45um, proportion is 3.3, titanium dioxide 50 mass parts that interpolation median size is 45um, proportion is 4.2, add dispersion agent 3 mass parts, mix after adding thickening material 3 mass parts, then add 15 mass parts water fully to stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.89.
Embodiment 8
Be in the epoxy resin latex of 1.3 at 100 mass parts, proportion, hollow glass microballoon 28 mass parts that interpolation median size is 75um, proportion is 0.18, nephrite powder 11 mass parts that interpolation median size is 36um, proportion is 3.2, titanium dioxide 41 mass parts that interpolation median size is 31um, proportion is 3.9, add dispersion agent 3 mass parts, mix after adding thickening material 2.1 mass parts, then add 15 mass parts water fully to stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.88.
Embodiment 9
Be in the epoxy resin latex of 1 at 100 mass parts, proportion, hollow glass microballoon 15 mass parts that interpolation median size is 60um, proportion is 0.1, nephrite powder 5 mass parts that interpolation median size is 2um, proportion is 2.9, titanium dioxide 25 mass parts that interpolation median size is 2um, proportion is 3.8, add dispersion agent 3 mass parts, mix after adding thickening material 0.5 mass parts, then add 15 mass parts water and fully stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.89.
Embodiment 10
Be 1.5 and in the epoxy resin latex of modification at 100 mass parts, proportion, hollow glass microballoon 30 mass parts that interpolation median size is 120um, proportion is 0.2, nephrite powder 15 mass parts that interpolation median size is 45um, proportion is 3.3, titanium dioxide 50 mass parts that interpolation median size is 45um, proportion is 4.2, add dispersion agent 3 mass parts, mix after adding thickening material 3 mass parts, then add 15 mass parts water fully to stir, obtain disconnected hot coating, the proportion of this disconnected hot coating is 0.89.
The radiation effect of embodiment 3-10:
By the disconnected hot coating of embodiment 3-10, with the thickness of 0.8mm, the iron plate being coated in 0.25mm with round brush carries out drying.
Be arranged on by 100w incandescent light below iron plate and (brushed the back side in coating iron plate face down), brushing 10cm place, the iron plate face device aluminium sheet of coating, time segment detects the temperature variations of aluminium sheet.Table 3 is the surface of aluminum plate temperature conditions of incandescent light irradiation iron plate after 1 hour.
Table 3 incandescent light irradiates the surface of aluminum plate temperature conditions of iron plate after 1 hour
The disconnected thermal effect of embodiment 3-10:
By the disconnected hot coating of embodiment 3-10, with the thickness of 0.8mm, with round brush brushing on the iron plate thick with 0.25mm, manufacturing specification is the iron sheet case of 300*300*300, then carries out drying.
In the inner side and outer side of above-mentioned iron sheet case, install thermometer respectively, iron sheet case outside temperature, 45 DEG C time, tests the temperature conditions in iron sheet case, as shown in table 4.
Table 4 iron sheet case internal-external temperature difference situation
Disconnected hot coating provided by the invention, available spraying, roller coating, the multiple forms of construction work such as brush brush are constructed, and liquid is easily painted on body surface.Disconnected hot coating, because raw material proportion is uneven, has storage demixing phenomenon, please fully stirs before using, and the coating property after stirring is stablized, and can not lose the original any function of coating.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (1)
1. disconnected hot coating, it is characterized in that, comprise the resin emulsion of 100 mass parts, particle diameter is hollow glass microballoon 15 ~ 30 mass parts of 60 ~ 120um, and particle diameter is nephrite 5 ~ 15 mass parts of 2 ~ 45um, and particle diameter is titanium dioxide 25 ~ 50 mass parts of 2 ~ 45um; Described hollow glass microballoon, nephrite and titanium dioxide are mixed in resin emulsion;
The proportion of described resin emulsion is 1 ~ 1.5, and the proportion of hollow glass microballoon is 0.1 ~ 0.2, and the proportion of nephrite is 2.9 ~ 3.3, and the proportion of titanium dioxide is 3.8 ~ 4.2;
Described resin emulsion is the one in the acryl resin emulsion of modification, polyaminoester emulsion, epoxy resin latex;
Also organosilicon crylic acid latex is mixed with in described resin emulsion;
Also dispersion agent is mixed with in described resin emulsion;
0.5 ~ 3 mass parts thickening material is also mixed with in described resin emulsion.
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|---|---|---|---|
| CN201310157566.0A CN103242731B (en) | 2013-05-02 | 2013-05-02 | Disconnected hot coating |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310157566.0A CN103242731B (en) | 2013-05-02 | 2013-05-02 | Disconnected hot coating |
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|---|---|
| CN103242731A CN103242731A (en) | 2013-08-14 |
| CN103242731B true CN103242731B (en) | 2015-08-12 |
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| CN201310157566.0A Expired - Fee Related CN103242731B (en) | 2013-05-02 | 2013-05-02 | Disconnected hot coating |
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| GB2531328A (en) * | 2014-10-17 | 2016-04-20 | Kirkstyles Innovation Ltd | Insulated liquid storage vessels |
| CN104277520A (en) * | 2014-10-29 | 2015-01-14 | 安徽朗凯奇建材有限公司 | Heat reflection thermal insulation water-based paint and preparation method thereof |
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| JP6797548B2 (en) * | 2016-04-22 | 2020-12-09 | キヤノン株式会社 | Heat shield film, heat shield paint, and optical equipment |
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| JP7071481B2 (en) * | 2020-11-19 | 2022-05-19 | キヤノン株式会社 | Heat shield film, heat shield paint, and optical equipment |
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