CN103171232B - A kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth - Google Patents
A kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth Download PDFInfo
- Publication number
- CN103171232B CN103171232B CN201310091128.9A CN201310091128A CN103171232B CN 103171232 B CN103171232 B CN 103171232B CN 201310091128 A CN201310091128 A CN 201310091128A CN 103171232 B CN103171232 B CN 103171232B
- Authority
- CN
- China
- Prior art keywords
- inside gadget
- leather
- antioxidant
- infusorial earth
- modification infusorial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010985 leather Substances 0.000 title claims abstract description 41
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 230000004048 modification Effects 0.000 title claims abstract description 25
- 238000012986 modification Methods 0.000 title claims abstract description 25
- 239000002131 composite material Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000000853 adhesive Substances 0.000 title claims abstract description 12
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 12
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 13
- 235000009566 rice Nutrition 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 8
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 8
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims abstract description 7
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims abstract description 7
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 7
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 7
- 239000003549 soybean oil Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000004743 Polypropylene Substances 0.000 claims abstract description 4
- 229910052923 celestite Inorganic materials 0.000 claims abstract description 4
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 4
- -1 polypropylene Polymers 0.000 claims abstract description 4
- 229920001155 polypropylene Polymers 0.000 claims abstract description 4
- 238000005507 spraying Methods 0.000 claims abstract description 4
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 claims abstract description 4
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001993 wax Substances 0.000 claims abstract description 4
- 238000005520 cutting process Methods 0.000 claims description 17
- 241000209094 Oryza Species 0.000 claims description 12
- 229920001651 Cyanoacrylate Polymers 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 235000012343 cottonseed oil Nutrition 0.000 claims description 3
- 239000002385 cottonseed oil Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000010304 firing Methods 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 abstract description 6
- 238000009966 trimming Methods 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
A kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth, needing the inside gadget surface spraying binding agent of composite leather, then composite leather, is described binding agent obtained by the raw material of following weight parts: EVA? 57-62, epoxy resin 8-12, C5 Petropols 12-16, microwax 3-5, WPP type polypropylene wax 0.5-1, dimethyl carbonate 1-2, Nano celestite powder 2-4, modification infusorial earth 7-10, modification rice hull ash 2-3, silane coupler KH560? 1.3-1.6, ferrocene 0.2-0.4, n-BMA 0.3-0.6, epoxidized soybean oil 0.4-0.6, antioxidant 264? 0.4-0.6, antioxidant 616? 0.2-0.4, antioxidant 333? 0.2-0.4.The present invention adopts mould pressing process, automatic trimming, and efficiency is high, and meanwhile, adopt particular adhesive, adhesion strength is high, smooth, and Long-Time Service can not bubble.
Description
Technical field
The invention belongs to a kind of Manufacturing Technology for Automotive Parts field, specifically a kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth.
Background technology
Have knit fabric or leather etc. in the decorative material on current arrangements for automotive doors surface, the moulding process of product is mould pressing process or low-pressure injection molding technology.During mold pressing, many employings first cut cloth, mold pressing bound edge again, cutting technologist uses maximum, the methods of everyone cutting are different, so the uniformity of product cannot ensure, the production efficiency of mould pressing process is low, and defect rate is high, use artificial quantity large, the whole production procedure from semi-finished product to finished product is complicated.And the high cost of low-pressure injection molding technology, equipment investment is large, requires high to the extension of leather.
Summary of the invention
The object of this invention is to provide a kind of method that arrangements for automotive doors inside gadget uses the adhesive surface composite leather containing modification infusorial earth.
Technical solution of the present invention is as follows:
Arrangements for automotive doors inside gadget uses a method for the adhesive surface composite leather containing modification infusorial earth, it is characterized in that: comprise the following steps:
(1), by diatomite concentration be that the hydrochloric acid solution of 10-12% soaked after 6-8 hour, then spend deionized water to neutral, dry;
Diatomite after drying is calcined 5-8 hour at 500-600 DEG C;
Add in diatomite after firing and be equivalent to the epoxy cotton seed oil acid butyl ester of its weight 1.8-2.2%, the a-cyanoacrylate of 1.5-2.3%, stir 30-40 minute under 3500-4500 rev/min after, oven dry grinds to form nanometer powder, obtains modification infusorial earth for subsequent use;
(2), by rice hull ash concentration be that the hydrogen peroxide solution of 13-15% soaked after 5-7 hour, then spend deionized water to neutral, dry;
Add in rice hull ash be after the drying equivalent to its weight 1-2% epoxidized soybean oil, 2-3% a-cyanoacrylate, stir 30-40 minute under 3500-4500 rev/min after, dry grind to form nanometer powder, obtain modification rice hull ash for subsequent use;
(3), kneader is preheated to wall temperature 190-205 DEG C;
Then add EVA, epoxy resin, C5 Petropols, dimethyl carbonate, silane coupler KH560, ferrocene, n-BMA, antioxidant 264 by weight, mediate 40-60min;
After add surplus stock by weight, at 160-180 DEG C, mediate 30-50min, take out and to cool and to obtain binding agent for subsequent use;
Described binding agent is obtained by the raw material of following weight parts:
EVA57-62, epoxy resin 8-12, C5 Petropols 12-16, microwax 3-5, WPP type polypropylene wax 0.5-1, dimethyl carbonate 1-2, Nano celestite powder 2-4, modification infusorial earth 7-10, modification rice hull ash 2-3, silane coupler KH5601.3-1.6, ferrocene 0.2-0.4, n-BMA 0.3-0.6, epoxidized soybean oil 0.4-0.6, antioxidant 264 0.4-0.6, antioxidant 6160.2-0.4; Antioxidant 3330.2-0.4;
(4), the inside gadget surface spraying binding agent of composite leather is being needed;
(5), by inside gadget to be positioned in counterdie on boss fixing, and to be provided with the annular cavity holding upper die-cutting rule outside counterdie boss around inside gadget;
(6), the leather of rolling be pulled to boss place and cover on inside gadget;
(7), patrix presses down, and applies pressure 20-25Mpa, and patrix die head lower surface coincide with inside gadget surface configuration, and leather compression is fitted in inside gadget surface, molding cycle 10-15 second, pressurize 10-15 second;
(8), employing is manual cuts the unnecessary leather of inside gadget periphery; Or in composite leather process, patrix die head periphery is provided with the cutting knife of elastic telescopic, cutting knife sinks, and extend in described annular cavity, the leather that excision inside gadget periphery is unnecessary;
(9), patrix resilience, take out be compounded with leather upholstery part, manually bound edge is carried out to unnecessary leather, to obtain final product.
Described arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth, it is characterized in that: described EVA is SUMITOMO CHEMICAL KA-31.
Beneficial effect of the present invention is: compared to the prior art, the present invention adopts mould pressing process, automatic trimming, efficiency is high, simultaneously, adopt particular adhesive, the raw materials of binding agent contains modification infusorial earth etc., and adhesion strength is high, is highly suitable for arrangements for automotive doors surface recombination leather, composite effect is smooth, and Long-Time Service can not bubble.
Accompanying drawing explanation
Fig. 1 is mould structure schematic diagram of the present invention.
Detailed description of the invention
See accompanying drawing, mould of the present invention includes patrix 6, counterdie 4, counterdie 4 has and places fixing boss 1 for inside gadget 3, inside gadget 5 is stained with leather, and on counterdie 4, boss 1 periphery is surrounded with the annular cavity 2 holding upper die-cutting rule 3; Upper die-cutting rule 3 is loop configuration, and slip cap is contained in patrix 6 die head periphery, by being arranged on the other driving mechanism on patrix 6, promotes the motion of patrix 6 cutting knife to realize cutting function.Above-mentioned upper die-cutting rule 3 structure also can not be established, and adopts artificial cutting edge.Mould of the present invention has left and right two boss, can carry out the composite leather of two different structure inside gadgets 5 simultaneously.
Arrangements for automotive doors inside gadget uses a method for the adhesive surface composite leather containing modification infusorial earth, comprises the following steps:
(1), by diatomite concentration be 12% hydrochloric acid solution soak 6 hours after, then spend deionized water to neutral, dry;
Diatomite after drying is calcined 5 hours at 500 DEG C;
Add in diatomite after firing and be equivalent to the epoxy cotton seed oil acid butyl ester of its weight 1.8%, the a-cyanoacrylate of 2.3%, stir after 30 minutes under 4500 revs/min, dry and grind to form nanometer powder, obtain modification infusorial earth for subsequent use;
(2), by rice hull ash concentration be 15% hydrogen peroxide solution soak 5 hours after, then spend deionized water to neutral, dry;
Add in rice hull ash be after the drying equivalent to its weight 2% epoxidized soybean oil, 3% a-cyanoacrylate, stir after 30 minutes under 4500 revs/min, dry and grind to form nanometer powder, obtain modification rice hull ash for subsequent use;
(3), kneader is preheated to wall temperature 205 DEG C;
Then add EVA, epoxy resin, C5 Petropols, dimethyl carbonate, silane coupler KH560, ferrocene, n-BMA, antioxidant 264 by weight, mediate 60min;
After add surplus stock by weight, at 180 DEG C, mediate 50min, take out and to cool and to obtain binding agent for subsequent use;
Described binding agent is obtained by the raw material of following weight parts (kg):
SUMITOMO CHEMICAL KA-31EVA57, epoxy resin E4412, C5 Petropols 16, microwax 5, WPP type polypropylene wax 1, dimethyl carbonate 2, Nano celestite powder 3.5, modification infusorial earth 10, modification rice hull ash 3, silane coupler KH5601.3, ferrocene 0.4, n-BMA 0.6, epoxidized soybean oil 0.6, antioxidant 264 00.6, antioxidant 6160.4; Antioxidant 3330.4;
(4), the inside gadget surface spraying binding agent of composite leather is being needed;
(5), by inside gadget to be positioned in counterdie on boss fixing, and to be provided with the annular cavity holding upper die-cutting rule outside counterdie boss around inside gadget;
(6), the leather of rolling be pulled to boss place and cover on inside gadget;
(7), patrix presses down, and applies pressure 25Mpa, and patrix die head lower surface coincide with inside gadget surface configuration, and leather compression is fitted in inside gadget surface, molding cycle 10 seconds, pressurize 14 seconds;
(8), employing is manual cuts the unnecessary leather of inside gadget periphery; Or in composite leather process, patrix die head periphery is provided with the cutting knife of elastic telescopic, cutting knife sinks, and extend in described annular cavity, the leather that excision inside gadget periphery is unnecessary;
(9), patrix resilience, take out be compounded with leather upholstery part, manually bound edge is carried out to unnecessary leather, to obtain final product.
Through actual verification, combined efficiency increases by 2 times, and single-piece reduces 3-4 manually, and economic benefit is obvious.
The apparent viscosity of the binding agent of the present embodiment is 4900MPa.s, peel strength 149N/2.5cm, and initial bonding strength reaches No. 5 steel balls, softening point 137 DEG C, open hour 36s, and within 24 hours, thermally-stabilised proterties is stablized.
Claims (2)
1. an arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth, it is characterized in that: comprise the following steps: (1), be that the hydrochloric acid solution of 10-12% soaks after 6-8 hour by diatomite concentration, spend deionized water again to neutral, dry; Diatomite after drying is calcined 5-8 hour at 500-600 DEG C; Add in diatomite after firing and be equivalent to the epoxy cotton seed oil acid butyl ester of its weight 1.8-2.2%, the a-cyanoacrylate of 1.5-2.3%, stir 30-40 minute under 3500-4500 rev/min after, oven dry grinds to form nanometer powder, obtains modification infusorial earth for subsequent use; (2), by rice hull ash concentration be that the hydrogen peroxide solution of 13-15% soaked after 5-7 hour, then spend deionized water to neutral, dry; Add in rice hull ash after the drying and be equivalent to the epoxidized soybean oil of its weight 1-2%, the a-cyanoacrylate of 2-3%, stir 30-40 minute under 3500-4500 rev/min after, dry and grind to form nanometer powder, obtain modification rice hull ash for subsequent use; (3), kneader is preheated to wall temperature 190-205 DEG C; Then add EVA, epoxy resin, C5 Petropols, dimethyl carbonate, silane coupler KH560, ferrocene, n-BMA, antioxidant 264 by weight, mediate 40-60min; After add surplus stock by weight, at 160-180 DEG C, mediate 30-50min, take out and to cool and to obtain binding agent for subsequent use; Described binding agent is obtained by the raw material of following weight parts: EVA57-62, epoxy resin 8-12, C5 Petropols 12-16, microwax 3-5, WPP type polypropylene wax 0.5-1, dimethyl carbonate 1-2, Nano celestite powder 2-4, modification infusorial earth 7-10, modification rice hull ash 2-3, silane coupler KH5601.3-1.6, ferrocene 0.2-0.4, n-BMA 0.3-0.6, epoxidized soybean oil 0.4-0.6, antioxidant 264 0.4-0.6, antioxidant 6160.2-0.4; Antioxidant 3330.2-0.4; (4), the inside gadget surface spraying binding agent of composite leather is being needed; (5), by inside gadget to be positioned in counterdie on boss fixing, and to be provided with the annular cavity holding upper die-cutting rule outside counterdie boss around inside gadget; (6), the leather of rolling be pulled to boss place and cover on inside gadget; (7), patrix presses down, and applies pressure 20-25Mpa, and patrix die head lower surface coincide with inside gadget surface configuration, and leather compression is fitted in inside gadget surface, molding cycle 10-15 second, pressurize 10-15 second; (8), employing is manual cuts the unnecessary leather of inside gadget periphery; Or in composite leather process, patrix die head periphery is provided with the cutting knife of elastic telescopic, cutting knife sinks, and extend in described annular cavity, the leather that excision inside gadget periphery is unnecessary; (9), patrix resilience, take out be compounded with leather upholstery part, manually bound edge is carried out to unnecessary leather, to obtain final product.
2. arrangements for automotive doors inside gadget according to claim 1 uses the method for the adhesive surface composite leather containing modification infusorial earth, it is characterized in that: described EVA is SUMITOMO CHEMICAL KA-31.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310091128.9A CN103171232B (en) | 2013-03-21 | 2013-03-21 | A kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310091128.9A CN103171232B (en) | 2013-03-21 | 2013-03-21 | A kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103171232A CN103171232A (en) | 2013-06-26 |
| CN103171232B true CN103171232B (en) | 2016-03-23 |
Family
ID=48631629
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310091128.9A Active CN103171232B (en) | 2013-03-21 | 2013-03-21 | A kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103171232B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752245A (en) * | 2016-12-26 | 2017-05-31 | 怀宁县三禾保洁服务有限公司 | A kind of lintel renovation is filled up with atomized ash and preparation method thereof |
| CN110845797A (en) * | 2019-12-04 | 2020-02-28 | 佛山市顺德区远熠模塑电器有限公司 | Production process of high-temperature-resistant shell of intelligent dish-washing machine |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687280A (en) * | 2005-06-03 | 2005-10-26 | 江苏工业学院 | New type hot-melt adhesive and preparation method thereof |
| CN101928530A (en) * | 2010-09-02 | 2010-12-29 | 上海天洋热熔胶有限公司 | Edge sealing hot melt adhesive for furniture and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7892391B2 (en) * | 2004-01-29 | 2011-02-22 | E. I. Du Pont De Nemours And Company | Compositions of ethylene/vinyl acetate copolymers for heat-sealable easy opening packaging |
-
2013
- 2013-03-21 CN CN201310091128.9A patent/CN103171232B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1687280A (en) * | 2005-06-03 | 2005-10-26 | 江苏工业学院 | New type hot-melt adhesive and preparation method thereof |
| CN101928530A (en) * | 2010-09-02 | 2010-12-29 | 上海天洋热熔胶有限公司 | Edge sealing hot melt adhesive for furniture and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103171232A (en) | 2013-06-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103013391B (en) | Preparation method of special modified nano expanded vermiculite powder-containing binding agent for compositing leather on surfaces of automotive upholsteries | |
| CN103013387B (en) | Preparation method of special dioctyl maleate binder for composite woven fabric on surface of automobile interior part | |
| CN103013388B (en) | Special octyl epoxy stearate-containing binding agent for compositing leather on surfaces of automotive upholsteries | |
| CN103087655A (en) | Special epoxy-cotton-oil-containing binding agent for automobile interior ornament surface composite leather | |
| CN103960822B (en) | A kind of lean manufacture method of solid special Thread sewing shoe | |
| WO2011103902A8 (en) | Method for producing a hybrid cushion element, in particular a seat and backrest cushion element for use in a motor vehicle, cushion element and vehicle seat having a cushion element | |
| CN104368758A (en) | Resin surface treatment-based method for preparing V-process EPS foam mold | |
| CN103171232B (en) | A kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth | |
| CN103013389B (en) | Special bonding agent containing rice hull ash for surface composite woven shell fabric of automotive upholstery | |
| CN103013392A (en) | Special epoxidized cottonseed butyl oleate-containing binding agent for compositing woven fabric on surfaces of automotive upholsteries | |
| CN103144400B (en) | A kind of method of roof panel inside gadget surface recombination woven fabric | |
| CN204267576U (en) | Automobile brake chamber rubber fabric clamped film sheet | |
| CN103144402B (en) | A kind of roof panel inside gadget uses the method for adhesive special surface recombination leather | |
| CN103013393B (en) | Special modified nano shale powder-containing binding agent for compositing leather on surfaces of automotive upholsteries | |
| CN103085434B (en) | A kind of method of arrangements for automotive doors inside gadget surface recombination woven fabric | |
| CN202727884U (en) | Rubber coating tire for perambulator | |
| CN103009773B (en) | Method for compounding synthetic leather on upholstery surface of automobile roof panel | |
| CN103213541A (en) | Double-material injection molding foaming light automobile instrument panel ornament | |
| CN102922763A (en) | Manufacture method of multi-color polyurethane (PU) shoe fabric | |
| CN106985421B (en) | A kind of production technology of integrally formed full carbon fibre hub | |
| CN105459318A (en) | Production method of intra-mould integrally formed double-texture shoe sole | |
| CN104632894B (en) | A kind of environmentally-friendly plastic thrust bearing shoe and preparation method thereof | |
| CN103192481A (en) | Method for producing double-material injection molding micro-foaming light-mass automobile decoration | |
| CN103027436B (en) | Preparing method of hemp forming insole | |
| CN202517629U (en) | Novel sole making mold |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190703 Address after: 211112 No. 3 Fengyi Road, Jiling Street, Jiangning District, Nanjing City, Jiangsu Province Patentee after: Ni Shujun Address before: 241009 auto parts road of Yijiang high tech Industrial Development Zone, Wuhu, Anhui Patentee before: Wuhu Zhongli Parts Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191231 Address after: 225306 No.40 Haiyang Road, Taizhou City, Jiangsu Province Patentee after: Taizhou Jinsong Co., Ltd. Address before: 211112 No. 3 Fengyi Road, Jiling Street, Jiangning District, Nanjing City, Jiangsu Province Patentee before: Ni Shujun |