CN1687280A - New type hot-melt adhesive and preparation method thereof - Google Patents
New type hot-melt adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN1687280A CN1687280A CN 200510040380 CN200510040380A CN1687280A CN 1687280 A CN1687280 A CN 1687280A CN 200510040380 CN200510040380 CN 200510040380 CN 200510040380 A CN200510040380 A CN 200510040380A CN 1687280 A CN1687280 A CN 1687280A
- Authority
- CN
- China
- Prior art keywords
- resin
- recessed soil
- melt adhesive
- new type
- type hot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a new-type thermosol using attapulgite as additive and its preparation method. Its composition includes: main body resin ethylene and polyvinyl acetate copolymer EVA, etc. 20-50%, tackifying resin 20-50%, diluent 10-30%, attapulgite 2-40% and anti-oxidant 0.1-1%. Its preparation method includes the following steps: firstly, melting diluent, adding main body resin, when the main body resin basically molten, progressively adding tackifying resin and making reaction for 0.5-1.5 h at 130-180 deg.C, then adding attapulgite and anti-oxidant, further reacting for 0.5-1 hr., discharging material, forming and granulating so as to obtain the invented product.
Description
Technical field
The present invention relates to a kind of with recessed soil as new type hot-melt adhesive of compound and preparation method thereof.
Background technology
Ethylene-vinyl acetate copolymer (EVA) based hot melt adhesive can be widely used in civil areas such as bookbinding, automatic packaging production line, carpet backing.Along with the raising of production automation degree, the demand of this product is also increasing.
This product is made up of raw materials such as matrix resin, tackifying resin, thinners, and its cost is higher relatively.One of means that reduce cost are to add some fillers in component, filler commonly used is: lime carbonate, silicon powder, talcum powder, white carbon black, the white carbon black of lightweight, metal nitride, metal oxide etc., but the shortcoming of these fillers is or than great, easily sink to the bottom, disperse bad, or too expensive.As United States Patent6,750,55 have provided a kind of semi-conductive tackiness agent that is used for, and wherein contain metal nitride, metal oxide.
Recessed soil, full name attapulgite (Attapulgite) are the fibrous magnesia silicate of waterbearing stratum chain, and only a few countries or area produce such mineral reserve in the world at present.It is abundant that recessed native reserves are economized in China Jiangsu, Anhui etc.Because it has good physical properties and particular structure feature, therefore show as good colloidal property, absorption property and catalytic performance.Extensively be used as sorbent material, loading material of rubber, drilling mud, catalyzer and molecular sieve caking agent, thickening material etc.CN1187461A has provided the deep processing technology of the recessed soil of a kind of high stick, and made recessed soil has designed a kind of with the recessed soil compensation of surface modification elastomeric material technology as the caking agent in the molecular sieve preparation: CN1508197A; United States Patent 6,863,984 is used for the surface of vehicle radiator with recessed soil, plays adsorption to reduce environmental pollution; United States Patent 6,846,358 is used as recessed soil the caking agent of fire door inner layer material.But its application in the hotmelt field does not appear in the newspapers.
Summary of the invention
The objective of the invention is recessed soil is added in the hotmelt, a kind of new type hot-melt adhesive and preparation method thereof is provided, under the situation that other performances of assurance do not reduce, tackify, gain in strength, reduce cost.
Hot melt adhesive of the present invention is formed: matrix resin: 20-50%: tackifying resin: 20-50%; Thinner: 10-30%: recessed soil: 2-40%; Oxidation inhibitor: 0.1-1%.
Described matrix resin is ethene and vinyl acetate copolymer eva, or any one or more combination among itself and ethene and butyl acrylate copolymer EMA, ethene one acrylic copolymer EAA, ethylene ethyl acrylic copolymer EEA, vinylbenzene and isoprene copolymer SIS, copolymer from styrene and butadiene SBS, the amorphous alpha-olefin polymers APAO adds, wherein the VA% of matrix resin is 5-40, and melting index is 15-400.
Described tackifying resin can be rosin, polymerized rosin, 145 resins, 138 resins, terpine resin, petroleum resin or hydrogenated petroleum resin;
Described thinner can be paraffin, ceresine, polyethylene wax, Fischer-Tropsch wax;
Described recessed soil is former recessed soil or the recessed soil of viscosity, brighten modified attapulgites such as recessed soil;
Described oxidation inhibitor is 264 (2,6-di-tert-butyl-4-methy phenol) or 1010{ four [β-(3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) propionic acid] pentaerythritol ester }
Preparation method of the present invention is:
At first with the thinner fusing, add matrix resin then, treat to add gradually when matrix resin melts substantially tackifying resin, add recessed soil and oxidation inhibitor behind the reaction 0.5-1.5h down at 130-180 ℃, react the 0.5-1h discharging again, moulding, granulation get product of the present invention.
Advantage of the present invention is:
1, adds recessed soil and can reduce product cost significantly;
2, add recessed soil and can improve product viscosity and softening temperature;
3, add recessed soil and can increase the product bonding strength;
4, add recessed soil and add other fillers and compare, its suspension is good, does not precipitate, and viscosity is big, easily is uniformly dispersed, and helps the hot melt adhesive performance and improves.
Embodiment
The basic product of preparation embodiment 1～8:
Paraffin with 10%, 9.8% ceresine melts, and adds 35% EVA then, treats to add 45%145 gradually when EVA melts substantially
#Tackifying resin, 1010 oxidation inhibitor of adding 0.2% react the 0.5h discharging again behind reaction 1h under 150 ℃, get basic product.
Embodiment 1: get 95 parts of above-mentioned basic products, add former recessed native 5 parts and form.
Embodiment 2～5:
In preparation with embodiment 1, former recessed soil changed into brighten recessed soil, make its content be respectively 5%, 10%, 15%, 20%.
Product proportioning and the test result of embodiment 2～5 see Table 1:
Product proportioning and the test result of table 1 embodiment 2～5
| Embodiment | Basic product | ?1 | ?2 | ?3 | ?4 | ?5 |
| Brighten recessed soil amount (w%) | 0 | ?5 | ?5 | ?10 | ?15 | ?20 |
| Softening temperature (℃) | 74.0 | ?75.0 | ?75.0 | ?75.0 | ?75.5 | ?75.5 |
| Viscosity (mPaS/170 ℃) | 3500 | ?5000 | ?4500 | ?4800 | ?5400 | ?5800 |
| Bonding strength (MPa) | 3.30 | ?3.38 | ?4.84 | ?4.21 | ?4.10 | ?3.83 |
Embodiment 6～8:
In aforesaid basic product, add the recessed soil of viscosity, make its content be respectively 5%, 10%, 20%.Product proportioning and the test result of embodiment 6～8 see Table 2:
Product proportioning and the test result of table 2 embodiment 6～8
| Embodiment | Basic product | ?6 | ?7 | ?8 |
| The recessed soil amount of tackify (w%) | 0 | ?5 | ?10 | ?20 |
| Softening temperature (℃) | 74.0 | ?75 | ?76.5 | ?77.5 |
| Viscosity (mPaS/170 ℃) | 3500 | ?5300 | ?5500 | ?7400 |
| Bonding strength (MPa) | 3.30 | ?4.61 | ?4.61 | ?4.46 |
Embodiment 9:
Ceresine fusing with 9.8%, add 12% EVA, 3% APAO and 15% SIS then, the Gum Rosin that adds 7% terpenes tackifying resin and 20% when treating to melt substantially gradually adds 0.2% 2.6.4 oxidation inhibitor down behind the reaction 1h at 150 ℃, add 33% gradually and brighten recessed soil, react the 0.5h discharging again.
Embodiment 10:
Press embodiment 9 operations, wherein brightening recessed native dosage is 20%.
Comparative Examples
Press embodiment 9 operations, will wherein brighten recessed soil and change talcum powder into.
The test result that embodiment 8-9, Comparative Examples reach with kind import glue sample sees Table 3
| Index | Softening temperature (℃) | Viscosity (mPaS/170 ℃) | Bonding strength (MPa) |
| Comparative Examples | ?80 | ??5000 | ?2.34 |
| Embodiment 9 | ?94 | ??15500 | ?2.63 |
| Embodiment 10 | ?86 | ??6500 | ?2.74 |
| Import glue sample | ?86 | ??6300 | ?2.48 |
Claims (3)
1. a new type hot-melt adhesive is characterized in that its component is: matrix resin: 20-50%; Tackifying resin: 20-50%; Thinner: 10-30%; Recessed soil: 2-40%; Oxidation inhibitor: 0.1-1%;
Wherein said matrix resin is ethene and vinyl acetate copolymer eva, or among itself and ethene and butyl acrylate copolymer EMA, ethene one acrylic copolymer EAA, ethylene ethyl acrylic copolymer EEA, vinylbenzene and isoprene copolymer SIS, copolymer from styrene and butadiene SBS, the amorphous alpha-olefin polymers APAO any one or more combines;
Described tackifying resin is rosin, polymerized rosin, 145 resins, 138 resins, terpine resin, petroleum resin or hydrogenated petroleum resin;
Described thinner is paraffin, ceresine, polyethylene wax, Fischer-Tropsch wax;
Described recessed soil is original soil or modified attapulgite: the recessed soil of viscosity, brighten recessed soil, the recessed soil of acidifying;
Described oxidation inhibitor is 2, i.e. 264 or four [β-(3 ', the 5 '-di-t-butyl-4 '-hydroxy phenyl) propionic acid] pentaerythritol ester promptly 1010 of 6-di-tert-butyl-4-methy phenol.
2. a kind of new type hot-melt adhesive according to claim 1, the VA% that it is characterized in that described matrix resin is 5-40, melting index is 15-400.
3. the method for preparing the described new type hot-melt adhesive of claim 1, it is characterized in that above-mentioned raw materials, at first thinner is melted, add matrix resin then, treat to add gradually when matrix resin melts substantially tackifying resin, add recessed soil and oxidation inhibitor behind the reaction 0.5-1.5h down at 130-180 ℃, react the 0.5-1h discharging again, moulding, granulation form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100403802A CN1304512C (en) | 2005-06-03 | 2005-06-03 | New type hot-melt adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100403802A CN1304512C (en) | 2005-06-03 | 2005-06-03 | New type hot-melt adhesive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1687280A true CN1687280A (en) | 2005-10-26 |
| CN1304512C CN1304512C (en) | 2007-03-14 |
Family
ID=35305322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100403802A Expired - Fee Related CN1304512C (en) | 2005-06-03 | 2005-06-03 | New type hot-melt adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1304512C (en) |
Cited By (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100395301C (en) * | 2006-07-18 | 2008-06-18 | 山东久隆高分子材料有限公司 | Nanometer composite hot melt adhesive for sealing joint in heavy caliber polyethylene pipeline |
| CN101781534A (en) * | 2010-03-03 | 2010-07-21 | 临安市林荫密封材料有限公司 | Automobile hot melt butyl sealant and manufacturing method thereof |
| CN101818035A (en) * | 2010-03-25 | 2010-09-01 | 同济大学 | Hot melt adhesive for quick joint coating of metallic pipeline and preparation method thereof |
| CN101928530A (en) * | 2010-09-02 | 2010-12-29 | 上海天洋热熔胶有限公司 | Edge sealing hot melt adhesive for furniture and preparation method thereof |
| CN101705062B (en) * | 2009-09-23 | 2011-07-13 | 江苏达胜热缩材料有限公司 | 60-DEG corrosion-resistant hot melt adhesive |
| CN101717610B (en) * | 2009-12-17 | 2011-09-07 | 钱建峰 | Hot melt adhesive |
| CN102250574A (en) * | 2010-05-18 | 2011-11-23 | 四川久远科技股份有限公司 | Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline |
| CN101705061B (en) * | 2009-09-25 | 2012-05-02 | 江苏达胜热缩材料有限公司 | Negative 50 DEG C antiseptic hot melt glue and preparation method thereof |
| CN102604552A (en) * | 2011-12-06 | 2012-07-25 | 福建爱贝思日用品有限公司 | Thermoplastic resin film, as well as production technology, production device and adhesive tool product thereof |
| CN102618211A (en) * | 2012-04-10 | 2012-08-01 | 浙江固特热熔胶有限公司 | Hot melt adhesive used for automotive interiors, and preparation method of hot melt adhesive |
| CN102653665A (en) * | 2012-04-28 | 2012-09-05 | 成都鑫三洋科技发展有限公司 | Hot melt adhesive |
| CN102653666A (en) * | 2012-04-28 | 2012-09-05 | 成都鑫三洋科技发展有限公司 | Method for preparing hot melt adhesive |
| CN102925080A (en) * | 2012-11-29 | 2013-02-13 | 无锡市万力粘合材料有限公司 | Book thermoplastic binding hot melt glue used at low temperature and preparation method thereof |
| CN103013391A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special modified nano expanded vermiculite powder-containing binding agent for compositing leather on surfaces of automotive upholsteries |
| CN103013393A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Special modified nano shale powder-containing binding agent for compositing leather on surfaces of automotive upholsteries |
| CN103013387A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special dioctyl maleate binder for composite woven fabric on surface of automobile interior part |
| CN103013390A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special nano-garamite based binder for compounding synthetic leather on automotive upholstery surface |
| CN103085434A (en) * | 2012-11-22 | 2013-05-08 | 芜湖众力部件有限公司 | Method for compounding woven fabric on surface of car door interior trim part |
| CN103171232A (en) * | 2013-03-21 | 2013-06-26 | 芜湖众力部件有限公司 | Method for compositing leather on surface of bonder used by car door interior parts and containing modified diatomite |
| CN103214194A (en) * | 2013-04-09 | 2013-07-24 | 合肥诚信玻璃有限公司 | Method for sealing vacuum glass by using hot-melt adhesive films for adhesion |
| CN103214984A (en) * | 2013-04-17 | 2013-07-24 | 安徽金门工贸有限公司 | Holt melt adhesive containing nanometer iron ore tailing powder |
| CN103214983A (en) * | 2013-03-21 | 2013-07-24 | 马鞍山市中澜橡塑制品有限公司 | Waterproof hot melt adhesive and preparation method thereof |
| CN103224763A (en) * | 2013-04-17 | 2013-07-31 | 安徽金门工贸有限公司 | Hot melt adhesive containing dioctyl adipate |
| CN103289601A (en) * | 2013-05-07 | 2013-09-11 | 安徽金门工贸有限公司 | Low temperature resistant hot melt adhesive containing modified zeolite powder and preparation method thereof |
| CN103289604A (en) * | 2013-05-07 | 2013-09-11 | 安徽金门工贸有限公司 | Hot melt adhesive containing modified attapulgite and preparation method thereof |
| CN103386462A (en) * | 2013-08-13 | 2013-11-13 | 厦门固特威蜡制品有限公司 | Adhesive wax |
| CN103468165A (en) * | 2013-08-13 | 2013-12-25 | 蚌埠市鸿安精密机械有限公司 | Hot melt adhesive used for optical fiber cables |
| CN103468171A (en) * | 2013-08-13 | 2013-12-25 | 安徽东方金河精密机械制造有限公司 | Hot melt adhesive used for automobile interior decoration parts |
| CN103509494A (en) * | 2013-09-18 | 2014-01-15 | 滁州市光威化工有限公司 | High-viscosity hot melt adhesive |
| CN103509495A (en) * | 2013-09-18 | 2014-01-15 | 滁州市光威化工有限公司 | Hot melt adhesive for cable accessories |
| CN103509498A (en) * | 2013-09-18 | 2014-01-15 | 滁州市光威化工有限公司 | Lead and zinc-containing slag and hot melt adhesive composition |
| CN103571396A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Environmental-friendly hot melt adhesive |
| CN103571389A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Nanometer composite filler hot melt adhesive |
| CN103571384A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Modified ethylene-vinyl-acetate (eva) resin hot melt adhesive |
| CN103571376A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive |
| CN103571388A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | High-temperature-resistant hot melt adhesive |
| CN103571385A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Cold-resistant hot melt adhesive |
| CN103571380A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Hot melt adhesive with low odor |
| CN103571373A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Ageing-resistant hot melt adhesive |
| CN103571383A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | High-insulation hot melt adhesive |
| CN103571390A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Antibacterial hot melt adhesive |
| CN103725226A (en) * | 2013-12-30 | 2014-04-16 | 日邦树脂(无锡)有限公司 | Benzene-free hot-melt adhesive and preparation method thereof |
| CN103788893A (en) * | 2014-01-14 | 2014-05-14 | 安徽金门工贸有限公司 | Hot melt adhesive for medical dialyzing paper |
| CN103788892A (en) * | 2014-01-14 | 2014-05-14 | 安徽金门工贸有限公司 | Hot melt glue for optical fiber cable |
| CN104087209A (en) * | 2014-06-26 | 2014-10-08 | 滁州市光威化工有限公司 | Hot-melt adhesive for high-speed cigarette sealing |
| CN104745122A (en) * | 2015-04-13 | 2015-07-01 | 长城崛起（福建）新材料科技股份公司 | Hot melt adhesive and preparation process thereof |
| CN104893617A (en) * | 2015-05-27 | 2015-09-09 | 合肥卓元科技服务有限公司 | Corrosion-resistant environment-friendly hot-melt adhesive |
| CN105038614A (en) * | 2015-07-31 | 2015-11-11 | 全椒海丰印刷包装有限公司 | Ageing-resistant hot melt adhesive comprising compound anti-oxidants |
| CN105153970A (en) * | 2015-07-10 | 2015-12-16 | 新乡市华洋粘合剂有限公司 | Low temperature hot melting adhesive |
| CN106336833A (en) * | 2016-08-23 | 2017-01-18 | 安徽永大胶业科技发展有限公司 | Environment-friendly hot melt adhesive |
| CN107057636A (en) * | 2017-06-06 | 2017-08-18 | 王京赫 | A kind of PUR and preparation method thereof |
| CN107325754A (en) * | 2017-06-22 | 2017-11-07 | 合肥特丽洁卫生材料有限公司 | A kind of cloth imitating paper special low temperature glue formula |
| CN108424724A (en) * | 2018-03-28 | 2018-08-21 | 上海嘉好胶粘制品有限公司 | A kind of APAO defends material hot melt adhesive and preparation method thereof |
| CN108624257A (en) * | 2018-05-30 | 2018-10-09 | 王召惠 | A kind of modified meerschaum EVA hot-melt adhesive |
| CN108893082A (en) * | 2018-06-14 | 2018-11-27 | 深圳市通产丽星股份有限公司 | A kind of hot melt adhesive and preparation method thereof |
| CN109054703A (en) * | 2018-06-29 | 2018-12-21 | 浙江固特热熔胶有限公司 | A kind of suction pipe positioning glue and preparation method thereof |
| CN109486448A (en) * | 2018-11-17 | 2019-03-19 | 金丽丹 | A kind of preparation method of modified C5 Petropols enhancing EVA hot-melt adhesive |
| CN110343490A (en) * | 2019-07-16 | 2019-10-18 | 顶立新材料科技有限公司 | A kind of preparation method of high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture |
| CN111363417A (en) * | 2020-04-27 | 2020-07-03 | 广州旭川合成材料有限公司 | Degradable coating and preparation method and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5646988B2 (en) * | 2007-04-13 | 2014-12-24 | コーニンクレッカ フィリップス エヌ ヴェ | Correlating clinical events |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1299480A (en) * | 1970-04-27 | 1972-12-13 | Ici Ltd | Process for making joining tapes |
| CN1006552B (en) * | 1985-12-01 | 1990-01-24 | 成都科技大学 | Hot melting adhesive for polyolefin |
| CN1117130C (en) * | 2000-10-26 | 2003-08-06 | 中国石油化工股份有限公司 | Hot fusible adhesive for package |
-
2005
- 2005-06-03 CN CNB2005100403802A patent/CN1304512C/en not_active Expired - Fee Related
Cited By (71)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100395301C (en) * | 2006-07-18 | 2008-06-18 | 山东久隆高分子材料有限公司 | Nanometer composite hot melt adhesive for sealing joint in heavy caliber polyethylene pipeline |
| CN101705062B (en) * | 2009-09-23 | 2011-07-13 | 江苏达胜热缩材料有限公司 | 60-DEG corrosion-resistant hot melt adhesive |
| CN101705061B (en) * | 2009-09-25 | 2012-05-02 | 江苏达胜热缩材料有限公司 | Negative 50 DEG C antiseptic hot melt glue and preparation method thereof |
| CN101717610B (en) * | 2009-12-17 | 2011-09-07 | 钱建峰 | Hot melt adhesive |
| CN101781534A (en) * | 2010-03-03 | 2010-07-21 | 临安市林荫密封材料有限公司 | Automobile hot melt butyl sealant and manufacturing method thereof |
| CN101781534B (en) * | 2010-03-03 | 2012-06-06 | 临安市林荫密封材料有限公司 | Automobile hot melt butyl sealant and manufacturing method thereof |
| CN101818035A (en) * | 2010-03-25 | 2010-09-01 | 同济大学 | Hot melt adhesive for quick joint coating of metallic pipeline and preparation method thereof |
| CN102250574A (en) * | 2010-05-18 | 2011-11-23 | 四川久远科技股份有限公司 | Hot-melt adhesive for preventing corrosion of repaired mouth of pipeline |
| CN101928530A (en) * | 2010-09-02 | 2010-12-29 | 上海天洋热熔胶有限公司 | Edge sealing hot melt adhesive for furniture and preparation method thereof |
| CN102604552A (en) * | 2011-12-06 | 2012-07-25 | 福建爱贝思日用品有限公司 | Thermoplastic resin film, as well as production technology, production device and adhesive tool product thereof |
| CN102618211A (en) * | 2012-04-10 | 2012-08-01 | 浙江固特热熔胶有限公司 | Hot melt adhesive used for automotive interiors, and preparation method of hot melt adhesive |
| CN102653666A (en) * | 2012-04-28 | 2012-09-05 | 成都鑫三洋科技发展有限公司 | Method for preparing hot melt adhesive |
| CN102653665A (en) * | 2012-04-28 | 2012-09-05 | 成都鑫三洋科技发展有限公司 | Hot melt adhesive |
| CN103085434A (en) * | 2012-11-22 | 2013-05-08 | 芜湖众力部件有限公司 | Method for compounding woven fabric on surface of car door interior trim part |
| CN103013391A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special modified nano expanded vermiculite powder-containing binding agent for compositing leather on surfaces of automotive upholsteries |
| CN103013393A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Special modified nano shale powder-containing binding agent for compositing leather on surfaces of automotive upholsteries |
| CN103013387A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special dioctyl maleate binder for composite woven fabric on surface of automobile interior part |
| CN103013390A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Preparation method of special nano-garamite based binder for compounding synthetic leather on automotive upholstery surface |
| CN103085434B (en) * | 2012-11-22 | 2016-08-03 | 芜湖众力部件有限公司 | A kind of method of arrangements for automotive doors inside gadget surface recombination woven fabric |
| CN103013391B (en) * | 2012-11-22 | 2014-06-25 | 芜湖众力部件有限公司 | Preparation method of special modified nano expanded vermiculite powder-containing binding agent for compositing leather on surfaces of automotive upholsteries |
| CN103013393B (en) * | 2012-11-22 | 2014-09-10 | 芜湖众力部件有限公司 | Special modified nano shale powder-containing binding agent for compositing leather on surfaces of automotive upholsteries |
| CN102925080A (en) * | 2012-11-29 | 2013-02-13 | 无锡市万力粘合材料有限公司 | Book thermoplastic binding hot melt glue used at low temperature and preparation method thereof |
| CN103171232A (en) * | 2013-03-21 | 2013-06-26 | 芜湖众力部件有限公司 | Method for compositing leather on surface of bonder used by car door interior parts and containing modified diatomite |
| CN103214983A (en) * | 2013-03-21 | 2013-07-24 | 马鞍山市中澜橡塑制品有限公司 | Waterproof hot melt adhesive and preparation method thereof |
| CN103171232B (en) * | 2013-03-21 | 2016-03-23 | 芜湖众力部件有限公司 | A kind of arrangements for automotive doors inside gadget uses the method for the adhesive surface composite leather containing modification infusorial earth |
| CN103214194A (en) * | 2013-04-09 | 2013-07-24 | 合肥诚信玻璃有限公司 | Method for sealing vacuum glass by using hot-melt adhesive films for adhesion |
| CN103214194B (en) * | 2013-04-09 | 2015-12-23 | 合肥康龄养生科技有限公司 | A kind of method for sealing of the vacuum glass utilizing hot melt adhesive film bonding |
| CN103214984A (en) * | 2013-04-17 | 2013-07-24 | 安徽金门工贸有限公司 | Holt melt adhesive containing nanometer iron ore tailing powder |
| CN103224763A (en) * | 2013-04-17 | 2013-07-31 | 安徽金门工贸有限公司 | Hot melt adhesive containing dioctyl adipate |
| CN103289601B (en) * | 2013-05-07 | 2016-01-06 | 安徽金门工贸有限公司 | A kind of containing modified zeolite powder low-temperature resistant hot melt glue and preparation method thereof |
| CN103289604A (en) * | 2013-05-07 | 2013-09-11 | 安徽金门工贸有限公司 | Hot melt adhesive containing modified attapulgite and preparation method thereof |
| CN103289601A (en) * | 2013-05-07 | 2013-09-11 | 安徽金门工贸有限公司 | Low temperature resistant hot melt adhesive containing modified zeolite powder and preparation method thereof |
| CN103289604B (en) * | 2013-05-07 | 2016-01-06 | 安徽金门工贸有限公司 | A kind of containing attapulgite modified hot melt adhesive and preparation method thereof |
| CN103468165A (en) * | 2013-08-13 | 2013-12-25 | 蚌埠市鸿安精密机械有限公司 | Hot melt adhesive used for optical fiber cables |
| CN103468171A (en) * | 2013-08-13 | 2013-12-25 | 安徽东方金河精密机械制造有限公司 | Hot melt adhesive used for automobile interior decoration parts |
| CN103386462A (en) * | 2013-08-13 | 2013-11-13 | 厦门固特威蜡制品有限公司 | Adhesive wax |
| CN103509494A (en) * | 2013-09-18 | 2014-01-15 | 滁州市光威化工有限公司 | High-viscosity hot melt adhesive |
| CN103509494B (en) * | 2013-09-18 | 2016-03-23 | 滁州市光威化工有限公司 | A kind of High-viscosity hot melt adhesive |
| CN103509498A (en) * | 2013-09-18 | 2014-01-15 | 滁州市光威化工有限公司 | Lead and zinc-containing slag and hot melt adhesive composition |
| CN103509495A (en) * | 2013-09-18 | 2014-01-15 | 滁州市光威化工有限公司 | Hot melt adhesive for cable accessories |
| CN103571384A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Modified ethylene-vinyl-acetate (eva) resin hot melt adhesive |
| CN103571376A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Anti-corrosion hot melt adhesive |
| CN103571385A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Cold-resistant hot melt adhesive |
| CN103571388A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | High-temperature-resistant hot melt adhesive |
| CN103571383A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | High-insulation hot melt adhesive |
| CN103571373A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Ageing-resistant hot melt adhesive |
| CN103571380A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Hot melt adhesive with low odor |
| CN103571390A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Antibacterial hot melt adhesive |
| CN103571396A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Environmental-friendly hot melt adhesive |
| CN103571389A (en) * | 2013-10-24 | 2014-02-12 | 芜湖众力部件有限公司 | Nanometer composite filler hot melt adhesive |
| CN103725226A (en) * | 2013-12-30 | 2014-04-16 | 日邦树脂(无锡)有限公司 | Benzene-free hot-melt adhesive and preparation method thereof |
| CN103788892A (en) * | 2014-01-14 | 2014-05-14 | 安徽金门工贸有限公司 | Hot melt glue for optical fiber cable |
| CN103788893A (en) * | 2014-01-14 | 2014-05-14 | 安徽金门工贸有限公司 | Hot melt adhesive for medical dialyzing paper |
| CN104087209A (en) * | 2014-06-26 | 2014-10-08 | 滁州市光威化工有限公司 | Hot-melt adhesive for high-speed cigarette sealing |
| CN104745122A (en) * | 2015-04-13 | 2015-07-01 | 长城崛起（福建）新材料科技股份公司 | Hot melt adhesive and preparation process thereof |
| CN104893617A (en) * | 2015-05-27 | 2015-09-09 | 合肥卓元科技服务有限公司 | Corrosion-resistant environment-friendly hot-melt adhesive |
| CN105153970A (en) * | 2015-07-10 | 2015-12-16 | 新乡市华洋粘合剂有限公司 | Low temperature hot melting adhesive |
| CN105038614A (en) * | 2015-07-31 | 2015-11-11 | 全椒海丰印刷包装有限公司 | Ageing-resistant hot melt adhesive comprising compound anti-oxidants |
| CN106336833A (en) * | 2016-08-23 | 2017-01-18 | 安徽永大胶业科技发展有限公司 | Environment-friendly hot melt adhesive |
| CN107057636B (en) * | 2017-06-06 | 2019-01-04 | 王京赫 | A kind of hot melt adhesive and preparation method thereof |
| CN107057636A (en) * | 2017-06-06 | 2017-08-18 | 王京赫 | A kind of PUR and preparation method thereof |
| CN107325754A (en) * | 2017-06-22 | 2017-11-07 | 合肥特丽洁卫生材料有限公司 | A kind of cloth imitating paper special low temperature glue formula |
| CN108424724A (en) * | 2018-03-28 | 2018-08-21 | 上海嘉好胶粘制品有限公司 | A kind of APAO defends material hot melt adhesive and preparation method thereof |
| CN108624257A (en) * | 2018-05-30 | 2018-10-09 | 王召惠 | A kind of modified meerschaum EVA hot-melt adhesive |
| CN108893082A (en) * | 2018-06-14 | 2018-11-27 | 深圳市通产丽星股份有限公司 | A kind of hot melt adhesive and preparation method thereof |
| CN109054703A (en) * | 2018-06-29 | 2018-12-21 | 浙江固特热熔胶有限公司 | A kind of suction pipe positioning glue and preparation method thereof |
| CN109054703B (en) * | 2018-06-29 | 2020-11-24 | 浙江固特热熔胶有限公司 | Straw positioning glue and preparation method thereof |
| CN109486448A (en) * | 2018-11-17 | 2019-03-19 | 金丽丹 | A kind of preparation method of modified C5 Petropols enhancing EVA hot-melt adhesive |
| CN110343490A (en) * | 2019-07-16 | 2019-10-18 | 顶立新材料科技有限公司 | A kind of preparation method of high-temperature-resistant thermoplastic hot melt adhesive for edge bonding of furniture |
| CN111363417A (en) * | 2020-04-27 | 2020-07-03 | 广州旭川合成材料有限公司 | Degradable coating and preparation method and application thereof |
| CN111363417B (en) * | 2020-04-27 | 2021-12-10 | 广州旭川合成材料有限公司 | Degradable coating and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1304512C (en) | 2007-03-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1304512C (en) | New type hot-melt adhesive and preparation method thereof | |
| CN103059792B (en) | Polyester elastomer hot melt adhesives and preparation method thereof for bonding polar polymers and metallic materials | |
| CN101210082B (en) | Composition for forming hot-melt adhesive, hot-melt adhesive, and preparing method thereof | |
| CN1264926C (en) | SBS modified asphalt high-self-adhesive waterproof coiled material and its preparing process | |
| CN1289623C (en) | Hot melt adhesive and use thereof | |
| CN112226180A (en) | Hot melt adhesive film for composite shoe sole and preparation method thereof | |
| KR101400648B1 (en) | Waterproof sheet | |
| KR101508888B1 (en) | Waterproof sheet | |
| HU224066B1 (en) | Thermoplastic marking compositions | |
| CN1759156A (en) | Hot melt adhesive composition | |
| CN1041175A (en) | Improved co-extrusion tackiness agent and goods thereof | |
| GB2420348A (en) | Syndiotactic rich polyolefins | |
| KR101611185B1 (en) | Waterproof sheet | |
| EP2399969A1 (en) | Membrane based on a binder compound with tall-oil pitch. | |
| CN85109217A (en) | Hot melting adhesive for polyolefin | |
| CA2925813C (en) | Compositions containing ethylene polymers | |
| CN101870803A (en) | Toughened polyethylene glycol terephthalate and preparation method thereof | |
| CN103483675A (en) | High-elasticity wear-resistant low-smoke halogen-free flame-retardant cable material | |
| US5639545A (en) | Non-bituminous sound deadening material | |
| KR101526244B1 (en) | Adhesive Member Based upon Polyketone and Polyolefin and Adhesion Structure Comprising the Same | |
| CN114410246A (en) | Hot melt adhesive composition and preparation method and application thereof | |
| EP2610292B1 (en) | Method of production of a binder compound | |
| CN1123613C (en) | Hot-fusible high-molecular adhesive and its preparing process | |
| US20210403650A1 (en) | Pre-swelled vinylacetate-ethylene based redispersible polymer powder composition and method for fabricating the same, asphalt composition comprising the same | |
| CN1250638C (en) | Nylon particle toughness increased polypropylene composite material and preparing method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |