CN103170409A - 一种硫化铜矿铜及其伴生元素的精选方法 - Google Patents
一种硫化铜矿铜及其伴生元素的精选方法 Download PDFInfo
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- CN103170409A CN103170409A CN2013100968520A CN201310096852A CN103170409A CN 103170409 A CN103170409 A CN 103170409A CN 2013100968520 A CN2013100968520 A CN 2013100968520A CN 201310096852 A CN201310096852 A CN 201310096852A CN 103170409 A CN103170409 A CN 103170409A
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- Prior art keywords
- flotation
- copper
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- enter
- mine tailing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910001779 copper mineral Inorganic materials 0.000 title abstract description 11
- JESPAFKOCOFQIN-UHFFFAOYSA-N copper;sulfanylidenecopper Chemical compound [Cu].[Cu]=S JESPAFKOCOFQIN-UHFFFAOYSA-N 0.000 title abstract 3
- 238000010187 selection method Methods 0.000 title abstract 3
- 238000005188 flotation Methods 0.000 claims abstract description 113
- 239000010949 copper Substances 0.000 claims abstract description 38
- 239000012141 concentrate Substances 0.000 claims abstract description 35
- 229910052802 copper Inorganic materials 0.000 claims abstract description 35
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 32
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000011084 recovery Methods 0.000 claims abstract description 17
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 14
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 14
- 239000004571 lime Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 19
- 239000003814 drug Substances 0.000 claims description 17
- 239000000686 essence Substances 0.000 claims description 12
- 238000005516 engineering process Methods 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 238000007689 inspection Methods 0.000 claims description 6
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 4
- TUZCOAQWCRRVIP-UHFFFAOYSA-N butoxymethanedithioic acid Chemical compound CCCCOC(S)=S TUZCOAQWCRRVIP-UHFFFAOYSA-N 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical class CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004088 foaming agent Substances 0.000 claims description 2
- 235000019157 thiamine Nutrition 0.000 claims description 2
- -1 thiamines lipid Chemical class 0.000 claims description 2
- 229910052683 pyrite Inorganic materials 0.000 abstract description 7
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011028 pyrite Substances 0.000 abstract description 7
- 239000003513 alkali Substances 0.000 abstract description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 4
- 239000011707 mineral Substances 0.000 abstract description 4
- 239000000178 monomer Substances 0.000 abstract description 4
- 230000002000 scavenging effect Effects 0.000 abstract 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 18
- 229910052750 molybdenum Inorganic materials 0.000 description 18
- 239000011733 molybdenum Substances 0.000 description 18
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 5
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- WUUZKBJEUBFVMV-UHFFFAOYSA-N copper molybdenum Chemical compound [Cu].[Mo] WUUZKBJEUBFVMV-UHFFFAOYSA-N 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- SSISHJJTAXXQAX-ZETCQYMHSA-N L-ergothioneine Chemical compound C[N+](C)(C)[C@H](C([O-])=O)CC1=CNC(=S)N1 SSISHJJTAXXQAX-ZETCQYMHSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052702 rhenium Inorganic materials 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- OIGPMFVSGDDYHS-UHFFFAOYSA-N copper sulfanylidenemolybdenum Chemical compound [S].[Cu].[Mo] OIGPMFVSGDDYHS-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
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- Manufacture And Refinement Of Metals (AREA)
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103736569A (zh) * | 2013-12-13 | 2014-04-23 | 金川集团股份有限公司 | 一种硫化矿的选矿方法 |
CN104289317A (zh) * | 2013-07-18 | 2015-01-21 | 厦门紫金矿冶技术有限公司 | 一种难选高硫铜锌硫化矿无抑制剂浮选分离方法 |
CN104759353A (zh) * | 2015-04-10 | 2015-07-08 | 铜陵有色金属集团股份有限公司 | 高硫难选铜矿石分步回收铜矿物的方法 |
CN105057111A (zh) * | 2015-08-28 | 2015-11-18 | 北京矿冶研究总院 | 一种铜硫矿铜硫分离方法 |
CN105268558A (zh) * | 2015-08-19 | 2016-01-27 | 江西理工大学 | 一种高硫低铜复杂硫化铜矿伴生有价组份综合利用的方法 |
CN108525841A (zh) * | 2018-03-12 | 2018-09-14 | 北京矿冶科技集团有限公司 | 一种铜矿石伴生钼选别方法 |
CN109833979A (zh) * | 2019-04-04 | 2019-06-04 | 北京矿冶科技集团有限公司 | 一种从铜精选尾矿中回收辉钼矿的方法 |
CN110560251A (zh) * | 2019-08-09 | 2019-12-13 | 江西铜业集团有限公司 | 用于含钼铜精矿铜钼分离的预处理-磁-浮联合选矿工艺 |
CN111215252A (zh) * | 2020-01-15 | 2020-06-02 | 辽宁科技大学 | 一种枱浮硫化矿混合精矿分离过程中银导向回收选矿方法 |
CN112221719A (zh) * | 2020-10-21 | 2021-01-15 | 厦门紫金矿冶技术有限公司 | 一种低品位铜硫矿石提高伴生金回收率的方法 |
CN112264197A (zh) * | 2020-09-22 | 2021-01-26 | 铜陵有色金属集团股份有限公司 | 一种高磁黄铁矿型铜硫矿石的组合抑制剂及其选矿方法 |
CN113996445A (zh) * | 2021-09-23 | 2022-02-01 | 江西铜业集团有限公司 | 一种低品位伴生钼铜硫矿浮选复合捕收剂及浮选方法 |
Citations (3)
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US4283017A (en) * | 1979-09-07 | 1981-08-11 | Amax Inc. | Selective flotation of cubanite and chalcopyrite from copper/nickel mineralized rock |
RU2398636C1 (ru) * | 2009-07-15 | 2010-09-10 | Совместное предприятие в форме закрытого акционерного общества "Изготовление, внедрение, сервис" | Способ флотационного обогащения сульфидных медно-никелевых руд |
CN101985113A (zh) * | 2010-12-01 | 2011-03-16 | 江西理工大学 | 一种铜镍硫化矿的选矿方法 |
-
2013
- 2013-03-25 CN CN201310096852.0A patent/CN103170409B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4283017A (en) * | 1979-09-07 | 1981-08-11 | Amax Inc. | Selective flotation of cubanite and chalcopyrite from copper/nickel mineralized rock |
RU2398636C1 (ru) * | 2009-07-15 | 2010-09-10 | Совместное предприятие в форме закрытого акционерного общества "Изготовление, внедрение, сервис" | Способ флотационного обогащения сульфидных медно-никелевых руд |
CN101985113A (zh) * | 2010-12-01 | 2011-03-16 | 江西理工大学 | 一种铜镍硫化矿的选矿方法 |
Non-Patent Citations (3)
Title |
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余玮等: "大山选矿厂铜精矿品位提高的生产实践", 《有色金属(选矿部分)》 * |
尹启华等: "德兴铜矿伴生元素综合回收方案确定", 《复杂难处理矿石选矿技术-全国选矿学术会议论文集》 * |
谢捷敏: "柱机联合流程在大山选矿厂精选段的应用研究", 《有色金属(选矿部分)》 * |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104289317B (zh) * | 2013-07-18 | 2017-08-25 | 厦门紫金矿冶技术有限公司 | 一种难选高硫铜锌硫化矿无抑制剂浮选分离方法 |
CN104289317A (zh) * | 2013-07-18 | 2015-01-21 | 厦门紫金矿冶技术有限公司 | 一种难选高硫铜锌硫化矿无抑制剂浮选分离方法 |
CN103736569A (zh) * | 2013-12-13 | 2014-04-23 | 金川集团股份有限公司 | 一种硫化矿的选矿方法 |
CN103736569B (zh) * | 2013-12-13 | 2015-12-09 | 金川集团股份有限公司 | 一种硫化矿的选矿方法 |
CN104759353A (zh) * | 2015-04-10 | 2015-07-08 | 铜陵有色金属集团股份有限公司 | 高硫难选铜矿石分步回收铜矿物的方法 |
CN105268558B (zh) * | 2015-08-19 | 2019-01-11 | 江西理工大学 | 一种高硫低铜复杂硫化铜矿伴生有价组份综合利用的方法 |
CN105268558A (zh) * | 2015-08-19 | 2016-01-27 | 江西理工大学 | 一种高硫低铜复杂硫化铜矿伴生有价组份综合利用的方法 |
CN105057111A (zh) * | 2015-08-28 | 2015-11-18 | 北京矿冶研究总院 | 一种铜硫矿铜硫分离方法 |
CN108525841B (zh) * | 2018-03-12 | 2020-11-06 | 北京矿冶科技集团有限公司 | 一种铜矿石伴生钼选别方法 |
CN108525841A (zh) * | 2018-03-12 | 2018-09-14 | 北京矿冶科技集团有限公司 | 一种铜矿石伴生钼选别方法 |
CN109833979A (zh) * | 2019-04-04 | 2019-06-04 | 北京矿冶科技集团有限公司 | 一种从铜精选尾矿中回收辉钼矿的方法 |
CN109833979B (zh) * | 2019-04-04 | 2021-06-11 | 北京矿冶科技集团有限公司 | 一种从铜精选尾矿中回收辉钼矿的方法 |
CN110560251A (zh) * | 2019-08-09 | 2019-12-13 | 江西铜业集团有限公司 | 用于含钼铜精矿铜钼分离的预处理-磁-浮联合选矿工艺 |
CN111215252A (zh) * | 2020-01-15 | 2020-06-02 | 辽宁科技大学 | 一种枱浮硫化矿混合精矿分离过程中银导向回收选矿方法 |
CN112264197A (zh) * | 2020-09-22 | 2021-01-26 | 铜陵有色金属集团股份有限公司 | 一种高磁黄铁矿型铜硫矿石的组合抑制剂及其选矿方法 |
CN112264197B (zh) * | 2020-09-22 | 2022-11-11 | 铜陵有色金属集团股份有限公司 | 一种高磁黄铁矿型铜硫矿石的组合抑制剂及其选矿方法 |
CN112221719A (zh) * | 2020-10-21 | 2021-01-15 | 厦门紫金矿冶技术有限公司 | 一种低品位铜硫矿石提高伴生金回收率的方法 |
CN113996445A (zh) * | 2021-09-23 | 2022-02-01 | 江西铜业集团有限公司 | 一种低品位伴生钼铜硫矿浮选复合捕收剂及浮选方法 |
CN113996445B (zh) * | 2021-09-23 | 2024-04-23 | 江西铜业集团有限公司 | 一种低品位伴生钼铜硫矿浮选复合捕收剂及浮选方法 |
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