CN103102759B - A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof - Google Patents
A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof Download PDFInfo
- Publication number
- CN103102759B CN103102759B CN201210452274.5A CN201210452274A CN103102759B CN 103102759 B CN103102759 B CN 103102759B CN 201210452274 A CN201210452274 A CN 201210452274A CN 103102759 B CN103102759 B CN 103102759B
- Authority
- CN
- China
- Prior art keywords
- infusorial earth
- modification infusorial
- aqueous
- paint
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof, it is made up of the raw material of following weight parts: acrylic acid ester emulsion 55-65, water-compatible amino resin 8-10, DPG butyl ether 1-3, pure water 10-15, fatty acid polyethylene glycol ester 0.4-0.6, defoamer polypropylene glycerol aether 0.2-0.4, Aerosol OT 0.2-0.6, zinc oxide 0.3-0.5, adhesion promoter BOK-M-208? 0.2-0.4, levelling agent L-350? 0.3-0.5, modification infusorial earth 0.3-0.5, aerosil? 0.1-0.3, aqueous silane coupling agent A800? 0.8-1.2, the aqueous glass paint that the present invention produces without bubble, do not lump, foreign, without precipitated and separated phenomenon, can water infinite dilution, can reduce the cost, environmental protection, paint film have very strong cohesive force and adhesion, wearability is strong at normal temperatures, the modification infusorial earth adding and aerosil are as thickener, strengthened the adhesive force of paint film, the aqueous silane coupling agent adding and adhesion promoter have further strengthened the adhesion of paint film.
Description
Technical field
The present invention relates generally to a kind of paint and preparation method thereof, relates in particular to a kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof.
Background technology
Functional as one, environment-friendly type aqueous coating, it is lucuriant in design that aqueous glass paint has the obvious paint film of decorative effect, be easy to the advantages such as cleaning, be widely used in light fixture, wineglass, vase, bottle, storm lantern, candlestick, glass decoration articles for use etc., but a little less than the permeability of aqueous glass paint because of its solvent, water paint is poor to the wetability of glass, the causes such as the fineness height of substrate surface, cause water paint to be difficult to produce good adhering on glass equipment, seriously hinder the development of glass lacquer, the kind of aqueous glass paint mainly contains polyurethane aqueous dispersion body system at present, water-soluble polypropylene acid resin type, polymerization of acrylic modified polyurethane type, the subject matter existing is poor adhesive force, chemical-resistant is poor, solvent resistance is bad, water boiling resistance is poor.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, and a kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof is provided.
The present invention is achieved by the following technical solutions:
An aqueous glass paint that contains modification infusorial earth, it is made up of the raw material of following weight parts:
Acrylic acid ester emulsion 55-65, water-compatible amino resin 8-10, DPG butyl ether 1-3, pure water 10-15, fatty acid polyethylene glycol ester 0.4-0.6, defoamer polypropylene glycerol aether 0.2-0.4, Aerosol OT 0.2-0.6, zinc oxide 0.3-0.5, adhesion promoter BOK-M-2080.2-0.4, levelling agent L-3500.3-0.5, modification infusorial earth 0.3-0.5, aerosil 0.1-0.3, aqueous silane coupling agent A8000.8-1.2;
The preparation method of described modification infusorial earth is:
10-15% salt acid soak 3-4 hour for diatomite, deionized water washing, then soak 3-4 hour with 10-12% sodium hydroxide solution, then with deionized water washing to neutral, oven dry;
Partial material is soluble in water, add again cumyl peroxide, the epoxidized soybean oil of 1-2%, the ATBC of 2-3%, the 3-5% zinc oxide of diatomite weight 2-3%, high speed 1200-1500 rev/min of stirring, obtain dispersion liquid, dispersion liquid ovendry power is broken into superfines, is described modification infusorial earth.
A preparation method for the aqueous glass paint that contains modification infusorial earth, comprises the following steps:
(1) fatty acid polyethylene glycol ester of the nano-carbon powder of the water-compatible amino resin of above-mentioned weight portion and its quality 0.1-0.2%, 0.3-0.5% is mixed and added in reaction cylinder, under the condition of 400-500 rev/min, be uniformly mixed 3-4 minute;
(2) add again the acrylic acid ester emulsion of above-mentioned weight portion, under the condition of 500-600 rev/min, uniform stirring 8-12 minute;
(3) add DPG butyl ether, pure water, fatty acid polyethylene glycol ester, the defoamer polypropylene glycerol aether of above-mentioned weight portion, under the condition of 1000-1300 rev/min, uniform stirring 8-12 minute;
(4) add Aerosol OT, zinc oxide, adhesion promoter BOK-M-208, levelling agent L-350, the aqueous silane coupling agent A800 of above-mentioned weight portion, under the condition of 500-800 rev/min, uniform stirring 25-35 minute;
(5) add modification infusorial earth, the aerosil of above-mentioned weight portion, stir, obtain described aqueous glass paint.
Advantage of the present invention is:
The aqueous glass paint that the present invention produces without bubble, do not lump, foreign, without precipitated and separated phenomenon, can water infinite dilution, can reduce the cost, environmental protection, paint film have very strong cohesive force and adhesion, wearability is strong at normal temperatures, the modification infusorial earth adding and aerosil are as thickener, strengthened the adhesive force of paint film, the aqueous silane coupling agent adding and adhesion promoter BOK-M-208 have further strengthened the adhesion of paint film.
Detailed description of the invention
Embodiment 1
An aqueous glass paint that contains modification infusorial earth, it is made up of the raw material of following weight parts:
Acrylic acid ester emulsion 65, water-compatible amino resin 10, DPG butyl ether 3, pure water 15, fatty acid polyethylene glycol ester 0.6, defoamer polypropylene glycerol aether 0.4, Aerosol OT 0.6, zinc oxide 0.5, adhesion promoter BOK-M-2080.4, levelling agent L-3500.5, modification infusorial earth 0.5, aerosil 0.3, aqueous silane coupling agent A8001.2;
The preparation method of described modification infusorial earth is:
15% salt acid soak 4 hours for diatomite, deionized water washing, then soak 3-4 hour with 12% sodium hydroxide solution, then with deionized water washing to neutral, oven dry;
Partial material is soluble in water, add the cumyl peroxide of diatomite weight 3%, 2% epoxidized soybean oil, 3% ATBC, 5% zinc oxide, 1500 revs/min of stirrings at a high speed, obtain dispersion liquid again, dispersion liquid ovendry power is broken into superfines, is described modification infusorial earth.
A preparation method for the aqueous glass paint that contains modification infusorial earth, comprises the following steps:
(1) nano-carbon powder of the water-compatible amino resin of above-mentioned weight portion and its quality 0.2%, 0.5% fatty acid polyethylene glycol ester are mixed and added in reaction cylinder, under the condition of 500 revs/min, be uniformly mixed 3-4 minute;
(2) add again the acrylic acid ester emulsion of above-mentioned weight portion, under the condition of 600 revs/min, uniform stirring 8-12 minute;
(3) add DPG butyl ether, pure water, fatty acid polyethylene glycol ester, the defoamer polypropylene glycerol aether of above-mentioned weight portion, under the condition of 1000-1300 rev/min, uniform stirring 8-12 minute;
(4) add Aerosol OT, zinc oxide, adhesion promoter BOK-M-208, levelling agent L-350, the aqueous silane coupling agent A800 of above-mentioned weight portion, under the condition of 500-800 rev/min, uniform stirring 25-35 minute;
(5) add modification infusorial earth, the aerosil of above-mentioned weight portion, stir, obtain described aqueous glass paint.
Performance test:
After solidifying, hardness of paint film is 2H, be sprayed at light transmittance on glass is 95%; By the gauze wiping coating 2 minutes that is moistened with clear water, coating is complete not to come off, and it is described, and wearability, adhesive force are good at normal temperatures; Paint is sprayed on plate glass, after film curing, puts into the ultraviolet lamp box that UV-B is housed, test according to GB/T14522-93, select 4 hours dark, under the condition of illumination in 4 hours, test 4 days, xanthochromia E≤6 of paint film, non-foaming, keep certain adhesive force.
Claims (1)
1. an aqueous glass paint that contains modification infusorial earth, it is characterized in that it is made up of the raw material of following weight parts: acrylic acid ester emulsion 55-65, water-compatible amino resin 8-10, DPG butyl ether 1-3, pure water 10-15, fatty acid polyethylene glycol ester 0.4-0.6, defoamer polypropylene glycerol aether 0.2-0.4, Aerosol OT 0.2-0.6, zinc oxide 0.3-0.5, adhesion promoter BOK-M-2080.2-0.4, levelling agent L-3500.3-0.5, modification infusorial earth 0.3-0.5, aerosil 0.1-0.3, aqueous silane coupling agent A8000.8-1.2,
The preparation method of described modification infusorial earth is: 10-15% salt acid soak 3-4 hour for diatomite, deionized water washing, then soak 3-4 hour with 10-12% sodium hydroxide solution, then with deionized water washing to neutral, oven dry; Partial material is soluble in water, add again cumyl peroxide, the epoxidized soybean oil of 1-2%, the ATBC of 2-3%, the 3-5% zinc oxide of diatomite weight 2-3%, high speed 1200-1500 rev/min of stirring, obtain dispersion liquid, dispersion liquid ovendry power is broken into superfines, is described modification infusorial earth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210452274.5A CN103102759B (en) | 2012-11-13 | 2012-11-13 | A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210452274.5A CN103102759B (en) | 2012-11-13 | 2012-11-13 | A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103102759A CN103102759A (en) | 2013-05-15 |
| CN103102759B true CN103102759B (en) | 2016-05-04 |
Family
ID=48310976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210452274.5A Expired - Fee Related CN103102759B (en) | 2012-11-13 | 2012-11-13 | A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103102759B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104341986A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Acid/alkali-corrosion-resistant high-hardness paint for glass doors and preparation method thereof |
| CN106280626A (en) * | 2016-08-12 | 2017-01-04 | 太仓市美航涂料有限公司 | A kind of environment-friendly type high adhesion force waterborne glass coatings |
| CN106084944A (en) * | 2016-08-12 | 2016-11-09 | 太仓市美航涂料有限公司 | A kind of preparation method of environment-friendly type high adhesion force waterborne glass coatings |
| CN106752546A (en) * | 2017-02-03 | 2017-05-31 | 安徽华晟涂料有限公司 | A kind of aqueous bottle coating and preparation method thereof |
| CN107353756A (en) * | 2017-09-02 | 2017-11-17 | 苏建 | A kind of waterborne glass coatings containing modification infusorial earth |
| CN107384097A (en) * | 2017-09-02 | 2017-11-24 | 佛山市北朝源科技服务有限公司 | A kind of waterborne glass coatings containing modification infusorial earth |
| CN107502007B (en) * | 2017-09-26 | 2020-04-07 | 重庆华亚家私有限公司 | Modified diatomite water-based environment-friendly paint and preparation method thereof |
| CN113480902B (en) * | 2021-07-14 | 2022-02-25 | 广东康伴新材料科技有限公司 | Ultrahigh alcohol-water-resistance single-component hardware coating and preparation process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550312A (en) * | 2008-09-27 | 2009-10-07 | 深圳市德厚科技有限公司 | Transparent heat insulation coating of alkyd resin glass |
| CN101967325A (en) * | 2010-06-25 | 2011-02-09 | 厦门通士达照明有限公司 | Waterborne glass coating for energy-saving lamp and preparation method thereof |
| CN102061117A (en) * | 2010-12-06 | 2011-05-18 | 上海奇鸣涂料有限公司 | Coating composition coated on glass surfaces and preparation method thereof |
| CN102153928A (en) * | 2011-02-28 | 2011-08-17 | 重庆恒美涂料有限公司 | Aqueous glass paint and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100866370B1 (en) * | 2006-12-18 | 2008-10-31 | (주)디피아이 홀딩스 | Paint composition for a glass and method of manufacturing a paint for a glass using the same |
-
2012
- 2012-11-13 CN CN201210452274.5A patent/CN103102759B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550312A (en) * | 2008-09-27 | 2009-10-07 | 深圳市德厚科技有限公司 | Transparent heat insulation coating of alkyd resin glass |
| CN101967325A (en) * | 2010-06-25 | 2011-02-09 | 厦门通士达照明有限公司 | Waterborne glass coating for energy-saving lamp and preparation method thereof |
| CN102061117A (en) * | 2010-12-06 | 2011-05-18 | 上海奇鸣涂料有限公司 | Coating composition coated on glass surfaces and preparation method thereof |
| CN102153928A (en) * | 2011-02-28 | 2011-08-17 | 重庆恒美涂料有限公司 | Aqueous glass paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103102759A (en) | 2013-05-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103102759B (en) | A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof | |
| CN103102766B (en) | A kind of high adhesion force aqueous glass paint and preparation method thereof | |
| CN102559005A (en) | Waterborne color transparent glass paint and preparation method thereof | |
| CN103102764B (en) | A kind of high abrasion waterborne glass coatings and preparation method thereof | |
| CN104231895A (en) | Preparation method for environment-friendly weatherable road-marking paint | |
| CN103450767A (en) | Super-weather-resistant anti-fouling real stone paint | |
| CN102134434A (en) | High-performance water-based white sealing primer | |
| CN104449273A (en) | Ultraviolet-resistant water-based paint capable of reducing brightness of coating and applied to glass door and preparation method of ultraviolet-resistant water-based paint | |
| CN107721223A (en) | A kind of aqueous, environmental protective coloured silk sand and its preparation technology | |
| CN110183965A (en) | A kind of preparation method of novel aqueous organic silicon stone protective agent | |
| CN104356798A (en) | Intumescent flame-retardant coating for glass door and preparing method of coating | |
| CN103102763B (en) | A kind of environment-friendly water-based glass lacquer and preparation method thereof | |
| CN103194145A (en) | High-solid coating and preparation method thereof | |
| CN102676009B (en) | Anionic ecological multicolour paint and preparation method thereof | |
| CN105237693A (en) | Organic-inorganic hybrid silica modified acrylic resin and coating thereof | |
| CN102876199B (en) | Luminous epoxy paint and preparation method thereof | |
| CN103102787B (en) | A kind of waterborne glass coatings and preparation method thereof | |
| CN109337535A (en) | Color LED-UV glass coating and preparation method thereof | |
| CN111117331A (en) | Colorful water-based paint with fluorescent effect | |
| CN104327625A (en) | Water and corrosion resistant quick-drying aqueous coating for glass doors, and its preparation method | |
| CN110577776A (en) | Desert sand stone-like paint and preparation method thereof | |
| CN109336455B (en) | Colored coated hollow ceramic microsphere material and preparation method thereof | |
| CN103045070B (en) | The formation method of LED water-based lampshade paint and preparation method thereof and paint film | |
| CN109517415A (en) | A kind of water-based anticorrosive paint | |
| CN104974674A (en) | Nano superpolymer high-flame-retardancy anti-aging adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160504 Termination date: 20181113 |