CN102992689A - 一种高性能的混凝土防护材料及其制备方法 - Google Patents
一种高性能的混凝土防护材料及其制备方法 Download PDFInfo
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- CN102992689A CN102992689A CN2012104315783A CN201210431578A CN102992689A CN 102992689 A CN102992689 A CN 102992689A CN 2012104315783 A CN2012104315783 A CN 2012104315783A CN 201210431578 A CN201210431578 A CN 201210431578A CN 102992689 A CN102992689 A CN 102992689A
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- monomer
- vinyl
- double bond
- emulsion
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- 238000002360 preparation method Methods 0.000 title claims abstract description 32
- 239000000463 material Substances 0.000 title claims abstract description 29
- 239000004574 high-performance concrete Substances 0.000 title claims abstract description 20
- 239000000839 emulsion Substances 0.000 claims abstract description 57
- 239000000178 monomer Substances 0.000 claims abstract description 43
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 34
- 229920000642 polymer Polymers 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 14
- 239000013530 defoamer Substances 0.000 claims abstract description 13
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 7
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 claims abstract description 5
- 229920000570 polyether Polymers 0.000 claims description 37
- 238000006243 chemical reaction Methods 0.000 claims description 21
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 18
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 18
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 17
- 230000001681 protective effect Effects 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 14
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 14
- 238000004581 coalescence Methods 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 12
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 12
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 claims description 11
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 10
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical group [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 10
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 238000004945 emulsification Methods 0.000 claims description 9
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 9
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 9
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000004902 Softening Agent Substances 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 claims description 5
- -1 1-propenyloxy group Chemical group 0.000 claims description 4
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 4
- YTQYIBPZPDYYGW-UHFFFAOYSA-N methyl prop-1-ene-1-sulfonate Chemical compound COS(=O)(=O)C=CC YTQYIBPZPDYYGW-UHFFFAOYSA-N 0.000 claims description 4
- MJYNUMNIZMSVQU-UHFFFAOYSA-N 1-hydroxypropane-1-sulfonic acid;sodium Chemical compound [Na].CCC(O)S(O)(=O)=O MJYNUMNIZMSVQU-UHFFFAOYSA-N 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- RKROSGYAZSTBBG-UHFFFAOYSA-N ethene;pentan-3-one Chemical compound C=C.CCC(=O)CC RKROSGYAZSTBBG-UHFFFAOYSA-N 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 229940065472 octyl acrylate Drugs 0.000 claims description 3
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- XGGMSZVQAVQXJZ-UHFFFAOYSA-N 2-hydroxypropane-1-sulfonic acid;sodium Chemical compound [Na].CC(O)CS(O)(=O)=O XGGMSZVQAVQXJZ-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 2
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 12
- 239000004567 concrete Substances 0.000 abstract description 12
- 239000004014 plasticizer Substances 0.000 abstract description 7
- 230000005012 migration Effects 0.000 abstract description 3
- 238000013508 migration Methods 0.000 abstract description 3
- 238000003763 carbonization Methods 0.000 abstract description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract description 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 230000010220 ion permeability Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 230000035699 permeability Effects 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 7
- 238000010000 carbonizing Methods 0.000 description 7
- 238000010257 thawing Methods 0.000 description 7
- 239000004159 Potassium persulphate Substances 0.000 description 6
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 6
- 238000013019 agitation Methods 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 235000019394 potassium persulphate Nutrition 0.000 description 6
- 235000011089 carbon dioxide Nutrition 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 241000370738 Chlorion Species 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 244000050510 Cunninghamia lanceolata Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
Claims (13)
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CN201210431578.3A CN102992689B (zh) | 2012-11-01 | 2012-11-01 | 一种高性能的混凝土防护材料及其制备方法 |
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CN201210431578.3A CN102992689B (zh) | 2012-11-01 | 2012-11-01 | 一种高性能的混凝土防护材料及其制备方法 |
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CN102992689A true CN102992689A (zh) | 2013-03-27 |
CN102992689B CN102992689B (zh) | 2014-04-02 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103496037A (zh) * | 2013-10-24 | 2014-01-08 | 镇江威信广厦模块建筑有限公司 | 一种混凝土构件的养护方法 |
CN105367698A (zh) * | 2015-11-26 | 2016-03-02 | 湖南工业大学 | 一种弹性防水乳液 |
WO2017050589A1 (en) * | 2015-09-23 | 2017-03-30 | Basf Se | Binder composition for heat-sealable film coatings |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070125534A1 (en) * | 2005-12-01 | 2007-06-07 | Halliburton Energy Services, Inc. | Methods of using wellbore sealant compositions containing cationic latexes |
CN101704981A (zh) * | 2009-11-26 | 2010-05-12 | 浙江新力化工有限公司 | 一种阳离子聚丙烯酸酯乳液及其制备方法 |
-
2012
- 2012-11-01 CN CN201210431578.3A patent/CN102992689B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070125534A1 (en) * | 2005-12-01 | 2007-06-07 | Halliburton Energy Services, Inc. | Methods of using wellbore sealant compositions containing cationic latexes |
CN101704981A (zh) * | 2009-11-26 | 2010-05-12 | 浙江新力化工有限公司 | 一种阳离子聚丙烯酸酯乳液及其制备方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103496037A (zh) * | 2013-10-24 | 2014-01-08 | 镇江威信广厦模块建筑有限公司 | 一种混凝土构件的养护方法 |
CN103496037B (zh) * | 2013-10-24 | 2016-01-20 | 威信广厦模块住宅工业有限公司 | 一种混凝土构件的养护方法 |
WO2017050589A1 (en) * | 2015-09-23 | 2017-03-30 | Basf Se | Binder composition for heat-sealable film coatings |
CN105367698A (zh) * | 2015-11-26 | 2016-03-02 | 湖南工业大学 | 一种弹性防水乳液 |
CN105367698B (zh) * | 2015-11-26 | 2018-04-03 | 湖南工业大学 | 一种弹性防水乳液 |
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CN102992689B (zh) | 2014-04-02 |
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Owner name: JIANGSU SUBOTE NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: BOTE NEW MATERIAL CO., LTD., JIANGSU Effective date: 20140514 |
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Effective date of registration: 20140514 Address after: 211103, No. 59 West Wan An Road, Jiangning District, Jiangsu, Nanjing Patentee after: Jiangsu Subute New Materials Co., Ltd. Patentee after: Panzhihua Bote Building Materials Co., Ltd. Address before: 211103, No. 59 West Wan An Road, Jiangning District, Jiangsu, Nanjing Patentee before: Jiangsu Bote New Materials Co., Ltd. Patentee before: Jiangsu Subute New Materials Co., Ltd. Patentee before: Jiangsu Provincial Architectural Science Institute Ltd. Patentee before: Panzhihua Bote Building Materials Co., Ltd. |
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Address after: No.6 shuiyougang, Gulou District, Nanjing City, Jiangsu Province 210013 Patentee after: JIANGSU SUBOTE NEW MATERIALS Co.,Ltd. Patentee after: PANZHIHUA BOTE BUILDING MATERIAL Co.,Ltd. Address before: 211103, No. 59 West Wan An Road, Jiangning District, Jiangsu, Nanjing Patentee before: JIANGSU SUBOTE NEW MATERIALS Co.,Ltd. Patentee before: PANZHIHUA BOTE BUILDING MATERIAL Co.,Ltd. |