CN102977052B - 2-巯基苯并噻唑锰锌及其制备方法、应用 - Google Patents
2-巯基苯并噻唑锰锌及其制备方法、应用 Download PDFInfo
- Publication number
- CN102977052B CN102977052B CN201210553866.6A CN201210553866A CN102977052B CN 102977052 B CN102977052 B CN 102977052B CN 201210553866 A CN201210553866 A CN 201210553866A CN 102977052 B CN102977052 B CN 102977052B
- Authority
- CN
- China
- Prior art keywords
- mercaptobenzothiazole
- zinc
- mnzn
- water
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D277/70—Sulfur atoms
- C07D277/72—2-Mercaptobenzothiazole
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
- C07D277/62—Benzothiazoles
- C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
- C07D277/70—Sulfur atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
供试药剂 | 浓度(ppm)(折纯)/水稀释 | 菌丝平均日扩展长度(mm) | 抑菌率(%) |
50wt%本发明可湿性粉剂 | 67 | 1.53 | 64.82 |
50wt%本发明可湿性粉剂 | 100 | 0.24 | 94.48 |
50wt%本发明可湿性粉剂 | 200 | 0 | 100 |
50wt%多菌灵 | 500 | 2.97 | 31.72 |
空白(清水) | 4.35 |
药剂 | 浓度(ppm)/水稀释 | 药前病指 | 病指 | 防效(%) |
90wt%本发明可湿性粉剂 | 800 | 0 | 10.12 | 84.39 |
50wt%多菌灵 | 1000 | 0 | 39.26 | 39.45 |
70wt%代森锰锌 | 1400 | 0 | 26.56 | 59.04 |
CK | 64.84 |
药剂 | 浓度(ppm)/水稀释 | 药前病指 | 病指 | 防效(%) |
30wt%本发明可湿性粉剂 | 800 | 0 | 12.06 | 82.32 |
70wt%代森锰锌 | 1400 | 0 | 22.28 | 67.34 |
CK | 68.22 |
Claims (9)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210553866.6A CN102977052B (zh) | 2012-12-19 | 2012-12-19 | 2-巯基苯并噻唑锰锌及其制备方法、应用 |
EP13865389.4A EP2937340B1 (en) | 2012-12-19 | 2013-11-30 | 2-mercaptobenzothiazole manganese zinc, preparation method therefor and application thereof |
US14/653,654 US9499501B2 (en) | 2012-12-19 | 2013-11-30 | 2-Mercaptobenzothiazole manganese zinc, preparation method therefor and application thereof |
PCT/CN2013/088245 WO2014094535A1 (zh) | 2012-12-19 | 2013-11-30 | 2-巯基苯并噻唑锰锌及其制备方法、应用 |
MYPI2015001509A MY169032A (en) | 2012-12-19 | 2013-11-30 | 2-mercaptobenzothiazole manganese zinc, preparation method therefor and application thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210553866.6A CN102977052B (zh) | 2012-12-19 | 2012-12-19 | 2-巯基苯并噻唑锰锌及其制备方法、应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102977052A CN102977052A (zh) | 2013-03-20 |
CN102977052B true CN102977052B (zh) | 2014-08-13 |
Family
ID=47851445
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210553866.6A Expired - Fee Related CN102977052B (zh) | 2012-12-19 | 2012-12-19 | 2-巯基苯并噻唑锰锌及其制备方法、应用 |
Country Status (5)
Country | Link |
---|---|
US (1) | US9499501B2 (zh) |
EP (1) | EP2937340B1 (zh) |
CN (1) | CN102977052B (zh) |
MY (1) | MY169032A (zh) |
WO (1) | WO2014094535A1 (zh) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103461348B (zh) * | 2012-08-16 | 2015-07-15 | 浙江新农化工股份有限公司 | 一种2-巯基苯并噻唑金属盐的用途 |
CN102977052B (zh) | 2012-12-19 | 2014-08-13 | 河南省新乡市农业科学院 | 2-巯基苯并噻唑锰锌及其制备方法、应用 |
CN103772316B (zh) * | 2013-12-31 | 2016-05-18 | 浙江工业大学 | 一种巯基噻唑类金属化合物的球磨合成方法 |
CN105454249B (zh) * | 2014-09-10 | 2018-03-02 | 浙江新农化工股份有限公司 | 含2‑巯基苯并噻唑锌的杀菌组合物及其制剂和应用 |
CN105394050B (zh) * | 2014-09-10 | 2018-05-08 | 浙江新农化工股份有限公司 | 2-巯基苯并噻唑锌与琥珀酸脱氢酶抑制剂类(sdhi)杀菌剂的组合物 |
CN105432625B (zh) * | 2014-09-10 | 2018-07-27 | 浙江新农化工股份有限公司 | 双唑锌与甾醇脱甲基抑制剂类(DMIs)杀菌剂的组合物及其制剂和应用 |
CN105454250B (zh) * | 2014-09-10 | 2018-01-30 | 浙江新农化工股份有限公司 | 2‑巯基苯并噻唑锌与线粒体细胞色素酶抑制剂类杀菌剂的组合物 |
FR3119844A1 (fr) | 2021-02-16 | 2022-08-19 | Saint-Gobain Glass France | Vitrage anti-feu comprenant une feuille de verre revêtue d’un revêtement intumescent |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4847933A (zh) * | 1971-10-22 | 1973-07-07 | ||
EP0554595A1 (en) * | 1990-12-20 | 1993-08-11 | Ciba-Geigy Ag | Manufacture of surface coatings |
CN101961006A (zh) * | 2010-08-04 | 2011-02-02 | 河北双吉化工有限公司 | 一种代森锰锌水分散粒剂的湿法制备工艺 |
CN101969781A (zh) * | 2007-10-23 | 2011-02-09 | 杜邦公司 | 杀真菌剂化合物及混合物 |
CN102227166A (zh) * | 2008-11-28 | 2011-10-26 | 拜尔农科股份公司 | 包含四唑肟衍生物和杀真菌或杀虫活性物质的农药组合物 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2354771A (en) | 1999-10-01 | 2001-04-04 | Mcbride Ltd Robert | Bactericide combinations in detergents |
US20100233146A1 (en) * | 2002-09-09 | 2010-09-16 | Reactive Surfaces, Ltd. | Coatings and Surface Treatments Having Active Enzymes and Peptides |
CN101172719B (zh) * | 2006-10-31 | 2010-12-08 | 中国石油化工股份有限公司 | 一种阻垢缓蚀剂及其在水处理中的应用 |
CN101514210B (zh) * | 2009-03-10 | 2011-06-29 | 河南省新乡市农业科学院 | 一种具有特定晶型的铜-2-巯基苯并噻唑及其制备方法和在防治农业植物病害中的用途 |
CN102977052B (zh) * | 2012-12-19 | 2014-08-13 | 河南省新乡市农业科学院 | 2-巯基苯并噻唑锰锌及其制备方法、应用 |
-
2012
- 2012-12-19 CN CN201210553866.6A patent/CN102977052B/zh not_active Expired - Fee Related
-
2013
- 2013-11-30 EP EP13865389.4A patent/EP2937340B1/en not_active Not-in-force
- 2013-11-30 US US14/653,654 patent/US9499501B2/en not_active Expired - Fee Related
- 2013-11-30 WO PCT/CN2013/088245 patent/WO2014094535A1/zh active Application Filing
- 2013-11-30 MY MYPI2015001509A patent/MY169032A/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4847933A (zh) * | 1971-10-22 | 1973-07-07 | ||
EP0554595A1 (en) * | 1990-12-20 | 1993-08-11 | Ciba-Geigy Ag | Manufacture of surface coatings |
CN101969781A (zh) * | 2007-10-23 | 2011-02-09 | 杜邦公司 | 杀真菌剂化合物及混合物 |
CN102227166A (zh) * | 2008-11-28 | 2011-10-26 | 拜尔农科股份公司 | 包含四唑肟衍生物和杀真菌或杀虫活性物质的农药组合物 |
CN101961006A (zh) * | 2010-08-04 | 2011-02-02 | 河北双吉化工有限公司 | 一种代森锰锌水分散粒剂的湿法制备工艺 |
Non-Patent Citations (4)
Title |
---|
噻唑类硫化促进剂合成进展;殷旭光等;《应用化工》;20110531;第40卷(第5期);第892-896页 * |
李小云等.粗M直接合成促进剂MZ.《河北化工》.1997,(第2期),第8页右栏2.2实验内容部分. |
殷旭光等.噻唑类硫化促进剂合成进展.《应用化工》.2011,第40卷(第5期),第892-896页. |
粗M直接合成促进剂MZ;李小云等;《河北化工》;19971231(第2期);第8页右栏2.2实验内容部分 * |
Also Published As
Publication number | Publication date |
---|---|
US9499501B2 (en) | 2016-11-22 |
MY169032A (en) | 2019-02-04 |
WO2014094535A1 (zh) | 2014-06-26 |
CN102977052A (zh) | 2013-03-20 |
US20160000077A1 (en) | 2016-01-07 |
EP2937340A1 (en) | 2015-10-28 |
EP2937340B1 (en) | 2018-01-03 |
EP2937340A4 (en) | 2016-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102977052B (zh) | 2-巯基苯并噻唑锰锌及其制备方法、应用 | |
CN110372617B (zh) | 一种药用组合物、丙硫菌唑的晶型及其制备方法、应用 | |
CN103392737A (zh) | 寡糖与硫磺作为增效组分的农用组合物 | |
CN102302026A (zh) | 一种含有吡唑醚菌酯与抗生素类化合物的杀菌组合物 | |
US20200277240A1 (en) | Trichoderma-Derived Selenium Nanoparticles Foliar Fertilizer for Reducing Crop Fungal Diseases And Toxin Contamination | |
TW200908882A (en) | Novel crystalline form of 3-(difluormethyl)-1-methyl-N-(3',4',5'-trifluor[1,1'-biphenyl]-2-yl)-1H-pyrazol-4-carboxamide | |
CN106472507A (zh) | 一种植物生长调节组合物、制剂及其应用 | |
CN101946802B (zh) | 一种具有协同增效作用的杀菌剂组合物 | |
CN109897012A (zh) | 一种具有杀菌活性的噻霉酮配合物及其制备方法和应用 | |
CN104542585A (zh) | 杀菌剂组合物及其应用 | |
CN106135263B (zh) | 含有机锌的组合物及其用途 | |
CN107118142A (zh) | 代森锰铜化合物及其制备方法与应用 | |
CN104351231B (zh) | 4-氯肉桂醛缩氨基硫脲在防治植物病害中的应用 | |
CN102835408A (zh) | 苯醚甲环唑与代森锰锌复配的悬浮剂及其制备方法 | |
DE2555730B2 (de) | 8-Oxychinounat-MetaIl-dimethyldithiocarbamat-Komplexe, Verfahren zur Herstellung derselben sowie solche enthaltende antimikrobieue Mittel | |
KR20150070893A (ko) | 달팽이류 방제제 및 이의 방제방법 | |
CN107549180A (zh) | 一种环保型大豆种衣剂及其制备方法 | |
CN106937636A (zh) | 含氟唑环菌胺的杀菌组合物 | |
CN106857510A (zh) | 含苯菌酮的杀真菌组合物 | |
KR20220076820A (ko) | 물리적 증착 방법을 이용한 금속 미네랄 함유 복합 비료 또는 영양제 제조 | |
CN104488909A (zh) | 一种含甲磺酰菌唑和嘧菌酯的复配组合物及制剂 | |
CN102283225B (zh) | 一种含丁香菌酯和保护性杀菌剂的杀菌组合物 | |
CN103875674B (zh) | 杀菌组合物 | |
CN105777647A (zh) | 一种合成1-异丙基甲酰胺-3-(3,5-二氯苯基)乙内酰脲的方法 | |
CN104488926A (zh) | 一种含甲磺酰菌唑和噻呋酰胺的复配组合物及制剂 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Wang Zhenjun Inventor after: Zhang Xu Inventor after: Wang Limin Inventor after: Liu Hongyan Inventor after: Cheng Senxiang Inventor after: Li Mengjiao Inventor before: Wang Zhenjun Inventor before: Zhang Xu Inventor before: Wang Limin Inventor before: Liu Hongyan Inventor before: Cheng Senxiang Inventor before: Li Mengjiao |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140813 Termination date: 20201219 |
|
CF01 | Termination of patent right due to non-payment of annual fee |