CN102951850B - 一种具有耐磨薄膜的化学钢化玻璃制品的制备方法 - Google Patents
一种具有耐磨薄膜的化学钢化玻璃制品的制备方法 Download PDFInfo
- Publication number
- CN102951850B CN102951850B CN201210484873.5A CN201210484873A CN102951850B CN 102951850 B CN102951850 B CN 102951850B CN 201210484873 A CN201210484873 A CN 201210484873A CN 102951850 B CN102951850 B CN 102951850B
- Authority
- CN
- China
- Prior art keywords
- glass
- preparation
- wear
- toughened glass
- thin film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000005341 toughened glass Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000000126 substance Substances 0.000 title abstract description 15
- 239000011521 glass Substances 0.000 claims abstract description 40
- 238000005342 ion exchange Methods 0.000 claims abstract description 37
- 150000003839 salts Chemical class 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 25
- 238000001816 cooling Methods 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000010409 thin film Substances 0.000 claims description 21
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 12
- 229910001415 sodium ion Inorganic materials 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 229910001414 potassium ion Inorganic materials 0.000 claims description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- 238000003980 solgel method Methods 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 239000006123 lithium glass Substances 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 3
- VVNXEADCOVSAER-UHFFFAOYSA-N lithium sodium Chemical compound [Li].[Na] VVNXEADCOVSAER-UHFFFAOYSA-N 0.000 claims description 2
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 claims description 2
- 238000005728 strengthening Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 21
- 238000000576 coating method Methods 0.000 abstract description 21
- 238000005496 tempering Methods 0.000 abstract description 13
- 238000005452 bending Methods 0.000 abstract description 4
- 238000007747 plating Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 14
- 239000008367 deionised water Substances 0.000 description 13
- 229910021641 deionized water Inorganic materials 0.000 description 13
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 12
- 238000007373 indentation Methods 0.000 description 12
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 11
- 239000010410 layer Substances 0.000 description 10
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 9
- 239000005357 flat glass Substances 0.000 description 9
- 230000035882 stress Effects 0.000 description 9
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 6
- 239000000428 dust Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000005361 soda-lime glass Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 6
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
- 230000006378 damage Effects 0.000 description 5
- 238000013001 point bending Methods 0.000 description 5
- 235000010333 potassium nitrate Nutrition 0.000 description 5
- 239000004323 potassium nitrate Substances 0.000 description 5
- 238000007669 thermal treatment Methods 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 235000010344 sodium nitrate Nutrition 0.000 description 4
- 239000004317 sodium nitrate Substances 0.000 description 4
- 229940001516 sodium nitrate Drugs 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000006018 Li-aluminosilicate Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002052 molecular layer Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004549 pulsed laser deposition Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005118 spray pyrolysis Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- -1 tetraethoxy Chemical compound 0.000 description 1
- 238000009997 thermal pre-treatment Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Surface Treatment Of Glass (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210484873.5A CN102951850B (zh) | 2012-11-23 | 2012-11-23 | 一种具有耐磨薄膜的化学钢化玻璃制品的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210484873.5A CN102951850B (zh) | 2012-11-23 | 2012-11-23 | 一种具有耐磨薄膜的化学钢化玻璃制品的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102951850A CN102951850A (zh) | 2013-03-06 |
CN102951850B true CN102951850B (zh) | 2015-04-29 |
Family
ID=47761313
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210484873.5A Expired - Fee Related CN102951850B (zh) | 2012-11-23 | 2012-11-23 | 一种具有耐磨薄膜的化学钢化玻璃制品的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102951850B (zh) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103319083A (zh) * | 2013-05-28 | 2013-09-25 | 苏州安洁科技股份有限公司 | 一种提高便携式电子设备上的玻璃面板强度的方法 |
CN104326648B (zh) * | 2013-12-31 | 2017-08-01 | 东旭集团有限公司 | 一种用于玻璃化学强化的催化剂及其强化液的制备方法 |
TWI535558B (zh) * | 2014-02-05 | 2016-06-01 | 宏益玻璃科技股份有限公司 | 具有化學膜的玻璃基板以及其製作方法 |
CN103922576A (zh) * | 2014-04-18 | 2014-07-16 | 深圳市金怡凯科技有限公司 | 化学钢化添加剂及使用该化学钢化添加剂进行化学钢化的方法 |
CN105522789A (zh) * | 2014-09-30 | 2016-04-27 | 鸿富锦精密工业(深圳)有限公司 | 镀膜玻璃及其制造方法、应用该镀膜玻璃的电子装置 |
CN104496162A (zh) * | 2014-11-19 | 2015-04-08 | 浙江大学 | 一种含铯的化学钢化玻璃的制备方法 |
CN107207334B (zh) | 2015-01-20 | 2021-04-13 | Agc株式会社 | 化学强化玻璃和化学强化玻璃的制造方法 |
WO2016117479A1 (ja) * | 2015-01-20 | 2016-07-28 | 旭硝子株式会社 | ガラス基材の製造方法 |
CN104743867B (zh) * | 2015-03-20 | 2017-09-26 | 武汉理工大学 | 一种等温两步离子交换制备力学敏感玻璃的方法 |
CN107032633A (zh) * | 2017-06-13 | 2017-08-11 | 合肥钢骨玻璃制品有限公司 | 一种具有耐磨薄膜的玻璃制品的制备方法 |
CN109206021B (zh) * | 2017-06-29 | 2020-11-03 | 重庆鑫景特种玻璃有限公司 | 用于玻璃强化的盐浴及其制备方法、强化玻璃和原料玻璃 |
CN107473604A (zh) * | 2017-09-06 | 2017-12-15 | 蚌埠玻璃工业设计研究院 | 一种太阳能电池用抗pid玻璃 |
CN110304839A (zh) * | 2018-03-27 | 2019-10-08 | 蓝思科技股份有限公司 | 一种含锂白色陶瓷玻璃的强化方法及强化组合物 |
CN110304840A (zh) * | 2018-03-27 | 2019-10-08 | 蓝思科技股份有限公司 | 一种含锂玻璃的强化方法及强化组合物 |
CN108819386A (zh) * | 2018-05-03 | 2018-11-16 | 南京朝阳玻璃有限公司 | 防爆玻璃 |
CN110540367B (zh) * | 2018-06-15 | 2022-02-08 | 蓝思科技(长沙)有限公司 | 一种钢化玻璃熔盐及钢化玻璃的处理方法 |
CN111039564B (zh) * | 2018-10-12 | 2022-04-01 | 重庆鑫景特种玻璃有限公司 | 雾面钢化保护玻璃及其制备方法与应用 |
CN111995260B (zh) * | 2019-05-27 | 2022-10-11 | 维达力实业(深圳)有限公司 | 玻璃盖板及其制备方法 |
CN110963715A (zh) * | 2019-12-27 | 2020-04-07 | 深圳市惠乐光电有限公司 | 一种柔性超薄玻璃盖板的化学强化方法 |
CN111348839A (zh) * | 2020-05-14 | 2020-06-30 | 安徽凯盛基础材料科技有限公司 | 表面具有钝化薄膜的玻璃及制备方法 |
CN112079574A (zh) * | 2020-07-22 | 2020-12-15 | 安徽省凤阳县前力玻璃制品有限公司 | 一种耐磨防刮花玻璃制品及其制备工艺 |
CN112358198B (zh) * | 2020-11-24 | 2022-11-18 | 中国建筑材料科学研究总院有限公司 | 一种高碱铝硅酸盐玻璃的复合增强方法 |
CN113416003B (zh) * | 2021-06-23 | 2022-07-08 | 维达力实业(赤壁)有限公司 | 化学钢化剂、微晶陶瓷材料及其制备方法和电子设备 |
CN115871317A (zh) * | 2022-12-30 | 2023-03-31 | 惠州市万合玻璃科技有限公司 | 一种热反射双钢夹层玻璃的制造方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51114414A (en) * | 1975-04-02 | 1976-10-08 | Yamamura Glass Co Ltd | Method of chemically strengthening glass articles which have been treated to have hardwearing properties |
US5279851A (en) * | 1991-04-03 | 1994-01-18 | Nippon Sheet Glass Co., Ltd. | Method of manufacturing a conductive glass with high strength and wear resistance |
CN1211549A (zh) * | 1997-08-16 | 1999-03-24 | 默克专利股份有限公司 | 沉积光学涂层的方法 |
CN101921054A (zh) * | 2010-09-09 | 2010-12-22 | 浙江大学 | 一种用于玻璃的化学钢化增强的熔盐及其应用工艺 |
TW201141808A (en) * | 2010-05-28 | 2011-12-01 | Wintek Corp | Method for strengthening glass and glass using the same |
CN102503101A (zh) * | 2011-11-02 | 2012-06-20 | 成都光明光电股份有限公司 | 添加剂及玻璃的化学钢化工艺 |
-
2012
- 2012-11-23 CN CN201210484873.5A patent/CN102951850B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51114414A (en) * | 1975-04-02 | 1976-10-08 | Yamamura Glass Co Ltd | Method of chemically strengthening glass articles which have been treated to have hardwearing properties |
US5279851A (en) * | 1991-04-03 | 1994-01-18 | Nippon Sheet Glass Co., Ltd. | Method of manufacturing a conductive glass with high strength and wear resistance |
CN1211549A (zh) * | 1997-08-16 | 1999-03-24 | 默克专利股份有限公司 | 沉积光学涂层的方法 |
TW201141808A (en) * | 2010-05-28 | 2011-12-01 | Wintek Corp | Method for strengthening glass and glass using the same |
CN101921054A (zh) * | 2010-09-09 | 2010-12-22 | 浙江大学 | 一种用于玻璃的化学钢化增强的熔盐及其应用工艺 |
CN102503101A (zh) * | 2011-11-02 | 2012-06-20 | 成都光明光电股份有限公司 | 添加剂及玻璃的化学钢化工艺 |
Also Published As
Publication number | Publication date |
---|---|
CN102951850A (zh) | 2013-03-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102951850B (zh) | 一种具有耐磨薄膜的化学钢化玻璃制品的制备方法 | |
US20220274869A1 (en) | Chemically strengthened glass and method for manufacturing chemically strengthened glass | |
CN111087174B (zh) | 一种具有高弹性模量的玻璃陶瓷、强化玻璃陶瓷及其制备方法 | |
CN103214172B (zh) | 化学强化玻璃板的制造方法 | |
EP4036070A1 (en) | Coated microcrystalline glass with improved water-repellent and oil-repellent property, preparation method and application thereof | |
WO2013099620A1 (ja) | 化学強化処理によるガラス基板の反りを低減する方法、および化学強化ガラス基板の製造方法 | |
CN107216032A (zh) | 一种玻璃用组合物和铝硅酸盐玻璃及其制备方法和应用 | |
CN111995243A (zh) | 一种高强度、低脆性的铝硅酸盐玻璃及其强化方法和应用 | |
CN105819684B (zh) | 一种玻璃用组合物、铝硼硅酸盐玻璃及其制备方法和应用 | |
US20180074397A1 (en) | Chemically strengthened glass | |
CN103842309A (zh) | 化学强化玻璃板及其制造方法 | |
CN104556648B (zh) | 铝硅酸盐玻璃的强化方法 | |
TW201213260A (en) | Method for improving heat protection glazings through preventing glass corrosion caused by alkaline attack on glass, and through use of a primer | |
CN110204195A (zh) | 一种超薄玻璃及其制备方法 | |
CN102173580A (zh) | 一种适合化学钢化的高碱镁铝硅酸盐玻璃 | |
CN104803602A (zh) | 一种适合化学强化的高碱高铝硅酸盐玻璃 | |
JP7172790B2 (ja) | 化学強化ガラスの製造方法、溶融塩組成物及び溶融塩組成物の寿命延長方法 | |
CN104039730A (zh) | 化学强化用玻璃基板及其制造方法 | |
JP7247454B2 (ja) | 化学強化ガラスの製造方法及び化学強化ガラス | |
CN104556649A (zh) | 一种用于低碱低铝玻璃化学钢化的熔盐配方及其钢化工艺 | |
CN102718404A (zh) | 一种高应变点硅酸盐玻璃及其应用 | |
CN105621882A (zh) | 一种玻璃用组合物、低脆性化学强化玻璃及其制备方法和应用 | |
WO2024088186A1 (zh) | 一种微晶玻璃、微晶玻璃前驱体及其制备方法 | |
CN104556685A (zh) | 铝硅酸盐玻璃及强化玻璃 | |
JP6428616B2 (ja) | 化学強化ガラスの製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20130306 Assignee: ZHEJIANG JINLIHUA ELECTRIC JOINT-STOCK Ltd. Assignor: Zhejiang University Contract record no.: 2018330000027 Denomination of invention: Preparation method of chemical toughened glass product with wearing-resisting film Granted publication date: 20150429 License type: Common License Record date: 20180327 |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150429 |