CN102922889B - Low-temperature bright golden decal and printing method thereof - Google Patents
Low-temperature bright golden decal and printing method thereof Download PDFInfo
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- CN102922889B CN102922889B CN201210449652.4A CN201210449652A CN102922889B CN 102922889 B CN102922889 B CN 102922889B CN 201210449652 A CN201210449652 A CN 201210449652A CN 102922889 B CN102922889 B CN 102922889B
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Abstract
The invention discloses low-temperature bright golden decal and a printing method thereof. The printing method of the low-temperature bright golden decal successively includes the steps of making patterns, making a film, making a screen printing plate, varnishing golden base ink, transferring bright gold, drying the bright gold, and coating a covering glue film. The low-temperature bright golden decal prepared in the method can achieve low-temperature pasting. When the low-temperature bright golden decal obtained in the preparation method is pasted on a to-be-pasted object, 60-180 DEG C lower-temperature baking pasting is utilized, and energy is obviously saved; as the basking temperature of the low-temperature bright golden decal is low, the requirement of high-temperature resistance of the to-be-pasted object is not high, and the rejection rate of the to-be-pasted object is low; the low-temperature bright golden decal can be tightly attached to a glass surface, a ceramic surface, a paint surface, a metal surface and a plastic surface, and pasting firmness is achieved; production cost is obviously lowered; the low-temperature bright golden decal does not contain heavy metal harmful substances such as lead, cadmium and lithium, and is beneficial for environment protection and customer health; electrochemical aluminum foil of gap portions of the patterns can be recycled, and resources can be saved; and the covering glue film can utilize a polystyrene film which can be tore, and environmental pollution is prevented.
Description
Technical field
The present invention relates to a kind of printing method, specifically a kind of bright gold marble paper printing manufacture method.
Background technology
Bright gold marble paper has the feature of the performances such as intensity is large, high temperature resistant, rub resistance and bright color, and product is widely used on the product such as pottery, glass ornaments.
At present, the printing of known bright gold marble paper adopts high temperature enamel firing process, and its main printing technology step is: computer photograph pattern → film processed → throwing half tone → with silk-screen plate gold paste (noble metal based on gold of content 9%-15%) to be printed on a kind of water-soluble membranelle base stock → paint (leaded in pigment, cadmium, lithium) → last layer gathers the not tearable laminate cover of the third ethene → dry up or naturally dry → bright gold marble paper product.
When using this bright gold marble paper, general using method is: when being pasted on the product such as pottery, glass ornaments, water soaking marble paper 3-5 minute → after attached figuratum glued membrane is separated with water-soluble membranelle base stock → by face glued membrane is attached on pottery or glass surface → venting bubble → dry moisture content → high temperature decoration firing, face glued membrane volatilizees through pyrolytic, gold paste on pattern is then fusible at pottery, glass surface, forms bright gold decorative pattern → finished product.
The main weak point of low temperature bright gold marble paper prepared by this conventional method comprises: the composition mainly precious metals gold of (1) gold paste, and price is high, causes production cost, product price high; (2) pigment that this bright gold marble paper adopts all contains the heavy metal harmful objects such as lead, cadmium, lithium, unfavorable consumer health; (3) noble metal be not printed onto in pattern interval in the gold paste on glass, pottery can not reclaim, and causes the wasting of resources; (4) laminate cover is not tearable, namely not recycling, causes the wasting of resources; (5) energy-output ratio is large: gold paste needs high-temperature baking just can be adhering closely to be attached on thing (pottery, glass etc.), clear glass golden flower paper must toast in the kiln of 520 °-580 °, pottery bright gold marble paper must toast in the kiln of about 900 degree, in bake process, consume a large amount of electric & gas equal energy sources; (6) high temperature bright gold marble paper is because of by temperature requirement, applies and has limitation, can not use on the product such as metal, lucite and do exquisite pattern decorative, and high temperature easily causes and is attached thing breakage and scraps simultaneously; (7) in high-temperature baking, the class materials such as poly-third ethene in laminate cover volatilize through pyrolytic, easily cause atmosphere pollution.
Summary of the invention
One of goal of the invention of the present invention is: for above-mentioned Problems existing, provide a kind of can low-temperature bake is pasted under the condition of 60-180 DEG C the preparation method of bright gold marble paper.
The technical solution used in the present invention is such: a kind of low temperature bright gold marble paper printing method, is characterized in that: comprise the following steps successively:
(1), pattern-making;
(2), film is made: according to the pattern of the different colours that step (1) makes, make the method for same film according to same color, make film respectively;
(3), make printing screen version: according to the film of the design producing of different colours, make the method for same printing screen version according to same color, make printing screen version respectively;
(4), ink at the bottom of upper bright gold: adopt the printing screen version that step (3) makes, with oil of the gold stamping end, according to same color printing method once, respectively the pattern of different colours be printed on same base stock, ink at the bottom of bright gold;
(5), transfer printing bright gold: according to the needs of the bright gold pattern of different colours, according to same color printing method once, electrochemical aluminum foil is transferred in respectively on ink at the bottom of the bright gold that step (4) obtains with laminating machine;
(6), dry bright gold: after each transfer printing bright gold, all carry out drying;
(7), laminate cover is coated with: after step (6) process, be coated with one deck laminate cover.
In above-mentioned steps, according to actual conditions, to base stock before use, after transfer printing bright gold, all can suitably be dried to tack-free degree, effect can be better.
First method of the present invention makes film and printing screen version respectively for different colours, and adopt electrochemical aluminum foil to substitute the gold gold paste of traditional handicraft, and adopt specific method step to combine, the bright gold marble paper obtained can be pasted by low-temperature bake under the condition of 60-180 DEG C, performance can not only reach the performance of traditional handicraft, and some performance is even more excellent.
As preferably: after step (6), print other pattern: other pattern not needing bright gold, other pattern of different colours, by water transfer ink, according to same color printing method once, is printed on base stock by printing screen version respectively that make by step (3).
Further: each printing after other does not need the pattern of bright gold, all carries out drying.
As preferably: after step (4) before step (5), carry out drying to ink at the bottom of bright gold.End ink effect can be ensured like this, be convenient to the carrying out of subsequent process steps, also can natural air drying, but can production efficiency be reduced.
As preferably: in step (5), laminating machine roller heating-up temperature is 40-150 DEG C.Through experimental results demonstrate: electrochemical aluminum foil can not all be transferred on ink at the bottom of bright gold lower than 40 DEG C by temperature, and just wastes energy higher than 150 DEG C, becomes unnecessary, roller, end ink etc. even can be damaged to some extent.
As preferably: before step (7), on base stock, be coated with gold stamping of one deck oil as protection gloss oil.Color more beautiful, more lasting can be made like this.
Further: after being coated with one deck protection gloss oil, to carry out drying.
As preferably: in step (7), laminate cover is tearable laminate cover.Adopt tearable front cover glue, can cut the waste.
Further: described tearable laminate cover is the poly-tearable laminate cover of third ethene.Adopt the laminate cover of poly-third vinyl material, can prevent the pollution of the environment.
Two of object of the present invention is to provide the low temperature bright gold marble paper that a kind of said method makes.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows: the bright gold marble paper that (1) adopts this method to prepare, low temperature can be realized paste, when the low temperature bright gold stained paper pasting that this method obtains is on the thing that is stuck, 60-180 DEG C of low-temperature bake is adopted to paste, remarkable economize energy; Because bright gold marble paper baking temperature is low, to being stuck, article heat-resisting quantity is less demanding, and the scrappage of the article that are stuck is low.(2) purposes of low temperature bright gold marble paper product is more extensive: can close attachment on glass surface, ceramic plane, paint face, metal covering, plastic cover, firm pasting.(3) one-tenth of bright gold is grouped into and replaces the noble metals such as gold by electrochemical aluminum foil, and production cost is significantly reduced.(4) excellent performance of bright gold marble paper that obtains of this method: adhesive capacity is strong, resistance to hundred lattice tests: ISO grade: 0, ASTM grade: 5B, and the edge of otch is completely smooth, and grid edge is without any peeling off; Soaking-resistant: water soaking 10 hours, does not fall, and the performance of above-mentioned performance and traditional Huang Jinliang golden flower paper is suitable; Further, resistance to alcohol immersion: alcohol immersion 3 hours, nondiscolouring, does not fall, and the traditional Huang Jinliang golden flower paper of this Performance Ratio is more superior.(5) pigment composition in ink at the bottom of bright gold and bright gold is epoxy resin and dyestuff etc., not containing heavy metal harmful objects such as lead, cadmium, lithiums, is conducive to environmental protection and consumer health.(6) electrochemical aluminum foil of pattern gap is through recycling, can economize on resources.(7) laminate cover preferably adopts tearable poly-third vinyl film, both economizes on resources, and turn avoid and cause environmental pollution.
Detailed description of the invention
The present invention is described in detail below.
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1:
A printing method for low temperature bright gold marble paper, comprises the following steps successively:
(1), pattern-making: the pattern of computer photograph redness (a kind of color);
(2), film processed: according to the pattern of computer photograph, make a film;
(3), make a plate: make a printing screen version;
(4), commercially available water-soluble membranelle base stock is got and dry base stock: temperature 40-48 DEG C, drying time: 2 hours;
(5), ink at the bottom of upper bright gold: the printing screen version made of step (3), and with oil of the gold stamping end, pattern is printed on the base stock after step (4) process, this oil of gold stamping end, purchased from Dao Er chemistry painting industry Co., Ltd of Shenzhen, is that the DR-gold stamping end is oily;
(6), ink at the bottom of dry bright gold: temperature 48-50 DEG C, drying time: 1 hour;
(7), transfer printing bright gold: be transferred on ink at the bottom of step (6) dried bright gold with commercially available laminating machine by commercially available electrochemical aluminum foil, laminating machine cylinder heating-up temperature is 40 DEG C;
(8), dry bright gold: temperature 35-40 DEG C, drying time: 2.5 hours;
(9), upper protection gloss oil: be coated with gold stamping of one deck oil as protection gloss oil, this gold stamping oil, purchased from purchased from Dao Er chemistry painting industry Co., Ltd of Shenzhen, is DR-gold stamping oil;
(10), dry-run protection gloss oil: temperature 25-28 DEG C, drying time: 3 hours;
(11), upper tearable laminate cover: last layer gathers the tearable laminate cover of the third ethene.
(12), dry laminate cover: temperature 40-42 DEG C, drying time: 1.2 hours, to obtain final product.
embodiment 2
A kind of low temperature bright gold marble paper printing method, comprises the following steps successively:
(1), pattern-making: adopting computer photograph three kinds of color patterns, is green, blue and orange respectively;
(2), film processed: according to the pattern of the different colours of computer photograph, make the method for same film according to same color, make three kinds of films respectively;
(3), plate-making: according to the film of the pattern of different colours, make the method for same printing screen version according to same color, make three printing screen versions respectively.Wherein, two needs bright golds, one does not need bright gold;
(4), commercially available water-soluble membranelle base stock is got and dry base stock: temperature 30-32 DEG C, drying time: 2 hours;
(5), ink at the bottom of the first bright gold upper: the silk-screen plate needing bright gold with first of the making of step (3) step, with oil of the gold stamping end, the pattern of the first color (green) is printed on the first base stock of step (4), this oil of gold stamping end, purchased from Dao Er chemistry painting industry Co., Ltd of Shenzhen, is the two component of EP-17 oil of the gold stamping end;
(6), ink of the dry end: temperature 20-21 DEG C, drying time: 4.5 hours;
(7), the first bright gold of transfer printing: according to the needs of the bright gold pattern of the first color, be transferred on ink at the bottom of step (6) dried bright gold with laminating machine by commercially available electrochemical aluminum foil, laminating machine cylinder heating-up temperature is 150 DEG C;
(8), dry the first bright gold: temperature 15-16 DEG C, drying time: 4.5 hours;
(9), ink at the bottom of upper the second bright gold: second that makes of step (3) silk-screen plate needing bright gold, oily with the gold stamping end, the pattern of the second color (blueness) is printed on the base stock of step (4); This oil of gold stamping end is purchased from print color printing brush Science and Technology Ltd. of Shunde District of Foshan City, and product are called YC-220 gold stamping end oil;
(10), ink at the bottom of dry the second: temperature 32-35 DEG C, drying time: 3.2 hours;
(11), transfer printing the second bright gold: according to the needs of the bright gold pattern of the second color, be transferred on ink at the bottom of the dried the second bright gold of step (10) by electrochemical aluminum foil with laminating machine, laminating machine cylinder heating-up temperature is 100 DEG C;
(12), dry the second bright gold: temperature 48-50 DEG C, drying time: 1 hour;
(13) pattern of the third color (orange), is printed, this pattern does not need bright gold: the 3rd that makes by step (3) does not need the silk-screen plate of bright gold, with commercially available light water transfer ink, the pattern of the third color (orange) not needing bright gold is printed on the base stock of step (4).
(14), the third pattern ink: temperature 32-35 DEG C dry, drying time: 3.2 hours;
(15), upper protection gloss oil: after completing the printing of whole pattern, be coated with gold stamping oil of one deck embodiment 1 as protection gloss oil, this gold stamping oil, purchased from purchased from Dao Er chemistry painting industry Co., Ltd of Shenzhen, is two component gold stamping the oil of PU-;
(16), dry-run protection gloss oil: temperature 36-28 DEG C, drying time: 2.8 hours;
(17), upper tearable laminate cover: the poly-tearable laminate cover of third ethene of last layer embodiment 1;
(18), dry laminate cover: the poly-tearable laminate cover of third ethene of drying steps (17), to obtain final product.
Embodiment 3
A printing method for low temperature bright gold marble paper, comprises the following steps successively:
Cancel step (9), the step (10) of embodiment 1, all the other steps are identical with embodiment 1.
Embodiment 4
A printing method for low temperature bright gold marble paper, comprises the following steps successively:
Cancel step (15), the step (16) of embodiment 2, all the other steps are identical with embodiment 2.
Embodiment 5
When dry base stock, end ink and bright gold, temperature is 15-16 DEG C, and be 5 hours drying time, all the other steps are identical with embodiment 1.
Embodiment 6
When dry base stock, end ink and bright gold, temperature is 48-50 DEG C, and be 1 hour drying time, all the other steps are identical with embodiment 2.
Embodiment 7
When dry base stock, end ink and bright gold, temperature is 35-36 DEG C, and be 3 hours drying time, all the other steps are identical with embodiment 2.
Claims (10)
1. a low temperature bright gold marble paper printing method, is characterized in that: comprise the following steps successively:
(1), pattern-making;
(2), film is made: according to the pattern of the different colours that step (1) makes, make the method for same film according to same color, make film respectively;
(3), make printing screen version: according to the film of the design producing of different colours, make the method for same printing screen version according to same color, make printing screen version respectively;
(4), ink at the bottom of upper bright gold: adopt the printing screen version that step (3) makes, with oil of the gold stamping end, according to same color printing method once, respectively the pattern of different colours be printed on same base stock, ink at the bottom of bright gold;
(5), transfer printing bright gold: according to the needs of the bright gold pattern of different colours, according to same color printing method once, electrochemical aluminum foil is transferred in respectively on ink at the bottom of the bright gold that step (4) obtains with laminating machine;
(6), dry bright gold: after each transfer printing bright gold, all carry out drying;
(7), laminate cover is coated with: after step (6) process, be coated with one deck laminate cover.
2. a kind of low temperature bright gold marble paper printing method according to claim 1, is characterized in that: after step (4) before step (5), carry out drying to ink at the bottom of bright gold
.
3. a kind of low temperature bright gold marble paper printing method according to claim 1, is characterized in that:
In step (5), laminating machine roller heating-up temperature is 40-150 DEG C.
4. a kind of low temperature bright gold marble paper printing method according to claim 1, it is characterized in that: after step (6), print other pattern: other pattern not needing bright gold, the printing screen version made by step (3) is by water transfer ink, according to same color printing method once, respectively other pattern of different colours is printed on base stock.
5. a kind of low temperature bright gold marble paper printing method according to claim 4, is characterized in that: each printing after other does not need the pattern of bright gold, all carries out drying.
6. a kind of low temperature bright gold marble paper printing method according to claim 1, is characterized in that: after completing the printing of whole pattern, be coated with one deck gold stamping oil.
7. a kind of low temperature bright gold marble paper printing method according to claim 6, is characterized in that: carry out drying after being coated with one deck gold stamping oil.
8. a kind of low temperature bright gold marble paper printing method according to claim 1, it is characterized in that: in step (7), laminate cover is tearable laminate cover.
9. a kind of low temperature bright gold marble paper printing method according to claim 8, is characterized in that: described tearable laminate cover is the poly-tearable laminate cover of third ethene.
10. the low temperature bright gold marble paper prepared of a claim 1-9 any one.
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Address after: 646300 Luzhou City, Sichuan province Zhejiang Naxi District Industrial Park B District Lanan Avenue three Xingye Road Patentee after: Luzhou Jin Xin Science and Technology Ltd. Address before: 646300 Luzhou City, Sichuan province Zhejiang Naxi District Industrial Park B District Lanan Avenue three Xingye Road Patentee before: Luzhou Jinxin Printing Co., Ltd. |