CN103273750B - A kind of low temperature embossment bright gold marble paper and printing method thereof - Google Patents
A kind of low temperature embossment bright gold marble paper and printing method thereof Download PDFInfo
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- CN103273750B CN103273750B CN201310202095.0A CN201310202095A CN103273750B CN 103273750 B CN103273750 B CN 103273750B CN 201310202095 A CN201310202095 A CN 201310202095A CN 103273750 B CN103273750 B CN 103273750B
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Abstract
The invention discloses a kind of embossment bright gold marble paper and printing method thereof, comprise the following steps successively: pattern-making; Make film; Make printing screen version; Dry base stock; Oil at the bottom of upper embossment bright gold: oil at the bottom of dry embossment bright gold; Transfer printing embossment bright gold; Dry embossment bright gold film; The tearable laminate cover of last layer; Dry tearable laminate cover.The embossment bright gold marble paper utilizing said method to print, the surface of its pattern protrudes from plane, and as embossment, stereoeffect is remarkable.
Description
Technical field
The present invention relates to a kind of embossment bright gold marble paper and printing method thereof.
Background technology
Bright gold marble paper has the feature of the performances such as intensity is large, high temperature resistant, rub resistance and bright color, and product is widely used on the product such as pottery, glass ornaments.But the printing of traditional bright gold marble paper adopts high temperature enamel firing process.Its main weak point is: the 1. composition of gold paste mainly precious metals gold, and price is high, causes production cost, product price high.2. glass, ceramic marble paper pigment all contain the heavy metal harmful objects such as lead, cadmium, lithium, unfavorable consumer health.3. the noble metal be not printed onto in pattern interval in the gold paste on glass, pottery can not reclaim, and causes the wasting of resources; Laminate cover is not tearable, namely not recycling, also causes the wasting of resources.4. energy-output ratio is large.Gold paste needs high-temperature baking just can be adhering closely to be attached on thing (pottery, glass etc.), glass golden flower paper must toast in the kiln of 520 °-580 °, ceramic metal marble paper must dry in the kiln of about 900 degree to be copied, and in bake process, consumes a large amount of electric & gas equal energy sources.5. high temperature bright gold is because having limitation by temperature requirement, can not use on the product such as metal, lucite and do exquisite pattern decorative, and high temperature easily causes and is attached thing breakage and scraps simultaneously.6., in high-temperature baking, the class materials such as poly-third ethene in the glued membrane of face volatilize through pyrolytic, easily cause atmosphere pollution.
In order to overcome problem and the shortcoming of above-mentioned bright gold marble paper technique, " a kind of low temperature bright gold marble paper and printing method thereof " (number of patent application: 201210449652.4, now announces, application publication number CN102922889A) has been invented by our company.The printing manufacture method of the low temperature bright gold marble paper of this invention adopts electrochemical aluminum foil bright gold, and adopts tearable laminate cover, and make product gloss more bright-coloured beautiful, material consumption is low, and cost is low, and ratio defective product is high, and accessory substance is recyclable, is conducive to environmental protection; When product is pasted on the thing that is stuck, adopt 60-180 DEG C of low-temperature bake to paste, energy consumption is low.But this invention still exists following weak point and is: the surface of bright gold marble paper is plane, and the pattern of printing does not protrude in the plane, lack stereoeffect.
Summary of the invention
For the technical problem of above-mentioned existence, the invention provides a kind of low temperature embossment bright gold marble paper, there is the pattern that embossment equally has remarkable stereoeffect; A kind of printing method is provided in addition, above-mentioned low temperature embossment bright gold marble paper can be printed out.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is:
A printing method for low temperature embossment bright gold marble paper, is characterized in that, comprise the following steps successively:
(1) pattern-making;
(2) film is made: according to the pattern of the different colours that step (1) makes, make the method for same film according to same color, make film respectively;
(3) make printing screen version: according to the film of the pattern of different colours, make the method for same printing screen version according to same color, make printing screen version respectively;
(4) dry base stock;
(5) oil at the bottom of upper embossment bright gold: the pattern of different colours according to the method for same color printing on same base stock, is printed on different base stock by the silk-screen plate made by step (3) by oil respectively at the bottom of embossment bright gold;
(6) oil at the bottom of dry embossment bright gold: use UV-light photocuring machine to carry out oil at the bottom of the dry embossment bright gold of automatic photocuring;
(7) transfer printing embossment bright gold: according to the needs of the bright gold pattern of different colours, according to same color printing method once, is transferred in electrochemical aluminum foil or orange cold foil paper tinsel on oil at the bottom of step (6) dried bright gold;
(8) dry embossment bright gold film: after each transfer printing bright gold film, dry embossment bright gold film; Dry embossment bright gold film adopts Cycling hot-blast heating passage;
(9) protect gloss oil on: after completing the printing of whole pattern, be coated with one deck gold stamping oil for protection gloss oil; Dry-run protection gloss oil, uses UV-light photocuring machine to carry out automatic photocuring dry-run protection gloss oil;
(10) the tearable laminate cover of last layer;
(11) dry tearable laminate cover.
Preferred as one, oil at the bottom of described embossment bright gold comprises polyamino resin, PU6A resin, polynary chlorine vinegar, monomer, initator, diluent.
Preferred as one, at the bottom of described embossment bright gold, oil is by mass content number, PU6A resin 11-16 part, polyurethane 30-36 part, polynary chlorine vinegar 5-10 part, monomer 5-9 part, initator 2-6 part, diluent 34-40 part.
Preferred as one, described diluent comprises toluene, ethyl ester, DAA, isopropyl alcohol, butyl ester.
As above-mentioned preferably further preferred, in described diluent, by mass content number, toluene 5-8 part, ethyl ester 19-25 part, DAA 0.9-1.5 part, isopropyl alcohol 3-7 part, butyl ester 2-4 part.
The low temperature embossment bright gold marble paper utilizing said method to print out.
Usefulness of the present invention is:
Embossment bright gold marble paper printing method of the present invention and the embossment bright gold marble paper printed out thereof, the surface of its pattern protrudes from plane, and as embossment, stereoeffect is remarkable; Ink, dry embossment bright gold film etc. at the bottom of upper embossment bright gold are mainly printed link and are adopted UV-light photocuring machine to carry out photocuring and Cycling hot-blast heating passage automation drying, significantly reduce energy consumption, significantly reduce the time of heating, cost is low, production efficiency is high, and deviation is less likely to occur in operation, thus, make the steady quality of product, gloss is more bright-coloured beautiful, even.
Detailed description of the invention
The present invention is described in detail below.
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
At the bottom of embossment bright gold of the present invention, oil, comprises polyamino resin, PU6A resin, polynary chlorine vinegar, monomer, initator, diluent.Diluent comprises toluene, ethyl ester, DAA, isopropyl alcohol, butyl ester.
Wherein, the type of PU6A resin is UA606, and model is UXF-9500, and production company is DOW Chemical; Polyurethane type is that 6 palaces can EA, and model is EAM-8002, is all good polyurethane of levelling, adhesive force that a kind of Japanese chemical company produces; The model of polynary chlorine vinegar is 10%VAGH, and DOW Chemical is produced; Monomer is the PET3A that Changxing company produces; Initator comprises 183 types of Hua Tai company production and 651 types of Ying Li company production, and its mass ratio is 1:2; In diluent, toluene model is TOL, ethyl ester model is EA, DAA model is DDA, isopropyl alcohol model is IPA, butyl ester model is BA.
Embodiment 1:
First oil at the bottom of embossment bright gold is prepared, at the bottom of embossment bright gold, oil is by mass content number, by PU6A resin 11 parts, polyurethane 30 parts, polynary chlorine vinegar 10 parts, monomer 5 parts, initator 6 parts, toluene 5 parts, ethyl ester 22 parts, DAA 0.9 part, isopropyl alcohol 6.1 parts, butyl ester 4 parts preparation.
Then a kind of embossment bright gold marble paper of color is printed according to following steps,
(1) pattern-making: the pattern utilizing a kind of color (redness) of computer photograph.
(2) film is made: according to the pattern of computer photograph, make a film.
(3) printing screen version is made: make a printing screen plate.Be preferably the thickening printing screen plate that 1.2mm is thick.
(4) dry base stock: get commercially available water-soluble membranelle base stock and dry base stock.Adopt heat drying, temperature 48 DEG C, drying time: 1 hour.
(5) oil at the bottom of upper embossment bright gold: oil at the bottom of embossment bright gold is printed on base stock with the silk-screen plate that step (3) step makes.
(6) oil at the bottom of dry embossment bright gold: utilize oil at the bottom of the dry embossment bright gold of the automatic photocuring of UV-light photocuring machine, the solid speed of light can reach 4000/hour.
(7) transfer printing embossment bright gold: utilize dry type laminating machine to be transferred in by commercially available electrochemical aluminum foil on oil at the bottom of step (6) dried bright gold; Dry type laminating machine heating-up temperature is 40 DEG C.The laminating machine roller that the roller of described dry type laminating machine adopts our company to invent, its number of patent application is 201210449652.4.
(8) dry embossment bright gold film: after turning embossment print bright gold film, utilize Cycling hot-blast heating passage dry embossment bright gold film, drying tunnel temperature is 20 DEG C, and drying time is 70 minutes.
(9) protect gloss oil on: after pattern printing, be coated with one deck gold stamping oil for protection gloss oil.
(10) dry-run protection gloss oil: utilize UV-light photocuring machine to carry out photocuring drying.
(11) the tearable laminate cover of last layer; The preferably poly-tearable laminate cover of third ethene.
(12) dry tearable laminate cover.Adopt heat drying, temperature 35 DEG C, 3 hours time.
By above step, obtain the embossment bright gold marble paper of a kind of color (redness).
The equipment such as above-mentioned UV-light photocuring machine, Cycling hot-blast heating passage all can purchased on the market.The specification of this Cycling hot-blast heating passage is 12 meters * 1.2 meters.
Embodiment 2:
First oil at the bottom of embossment bright gold is prepared, at the bottom of embossment bright gold, oil is by mass content number, by PU6A resin 12 parts, polyurethane 35 parts, polynary chlorine vinegar 6 parts, monomer 5.5 parts, initator 4.5 parts, toluene 6.5 parts, ethyl ester 20 parts, DAA 1 part, isopropyl alcohol 6.5 parts, butyl ester 3 parts preparation.
Then the embossment bright gold marble paper of three kinds of color patterns is printed according to following steps,
(1) pattern-making: adopt computer photograph three kinds of patterns is green, blue and orange respectively.
(2) make film: according to the pattern of the different colours of computer photograph, make the method for same film according to same color, make three kinds of films respectively.
(3) make printing screen version: according to the film of the pattern of different colours, make the method for same printing screen version according to same color, make three printing screen versions respectively.Wherein, two needs bright golds, one does not need bright gold.Be preferably and do not thicken making silk-screen plate, thickness 0.5mm.
(4) dry base stock: get commercially available water-soluble membranelle base stock and dry base stock: adopt heat drying, temperature 35 DEG C, drying time: 1.5 hours.
(5) oil at the bottom of the first embossment bright gold upper: first that makes by step (3) the step silk-screen plate needing the embossment bright gold of bright gold, with oily at the bottom of embossment bright gold, is printed on base stock by the pattern of the first color (green);
(6) oil at the bottom of the first embossment bright gold dry: utilize oil at the bottom of the dry embossment bright gold of the automatic photocuring of UV-light photocuring machine, the solid speed of light can reach 4000/hour.
(7) the first embossment bright gold of transfer printing: according to the needs of the bright gold pattern of the first color, be transferred on the dried embossment of step (6) photocuring oil of the gold stamping end with dry type laminating machine by orange cold foil paper tinsel, dry type laminating machine cylinder heating-up temperature is 100 DEG C; The laminating machine roller that the roller of described dry type laminating machine adopts our company to invent, its number of patent application is 201210449652.4.
(8) the first embossment bright gold film dry: after transfer printing embossment bright gold film, utilize Cycling hot-blast heating passage dry embossment bright gold film, drying tunnel temperature is 28 DEG C, and drying time is 50 minutes.
(9) oil at the bottom of upper the second embossment bright gold: second that makes of step (3) silk-screen plate needing bright gold, with oily at the bottom of embossment bright gold, is printed on the pattern of the second color (blueness) on base stock.
(10) oil at the bottom of dry the second embossment bright gold: utilize oil at the bottom of the dry embossment bright gold of the automatic photocuring of commercially available UV-light photocuring machine, the solid speed of light can reach 4000/hour.
(11) transfer printing the second embossment bright gold: according to the needs of the bright gold pattern of the second color (blueness), be transferred on the dried embossment of step (10) photocuring oil of the gold stamping end with dry type laminating machine by orange cold foil paper tinsel, dry type laminating machine cylinder heating-up temperature is 100 DEG C.
(12) dry the second embossment bright gold film: after transfer printing embossment bright gold film, utilize Cycling hot-blast heating passage dry embossment bright gold film, drying tunnel temperature is 28 DEG C, and drying time is 50 minutes.
(13) pattern of the third color (orange) is printed, this pattern does not need bright gold: the silk-screen plate made by step (3), use light water transfer ink, the pattern of the third color (orange) not needing bright gold is printed on base stock.
(15) protect gloss oil on: after pattern printing, be coated with one deck gold stamping oil for protection gloss oil.
(16) dry-run protection gloss oil: utilize commercially available UV-light photocuring machine to carry out photocuring drying.
(17) the tearable laminate cover of last layer; The preferably poly-tearable laminate cover of third ethene.
(18) dry tearable laminate cover.Adopt heat drying, temperature 35 DEG C, 3 hours time.
Above-mentioned UV-light photocuring machine and Cycling hot-blast heating passage all can be purchased in market.The specification of this Cycling hot-blast heating passage is 12 meters * 1.2 meters.
By above step, obtain the embossment bright gold marble paper of three kinds of colors (green, blue, orange).
Embodiment 3:
First oil at the bottom of embossment bright gold is prepared, at the bottom of embossment bright gold, oil is by mass content number, by PU6A resin 11 parts, polyurethane 36 parts, polynary chlorine vinegar 5 parts, monomer 9 parts, initator 2 parts, toluene 8 parts, ethyl ester 19 parts, DAA 1 part, isopropyl alcohol 7 parts, butyl ester 2 parts preparation.
Then the embossment bright gold marble paper of three kinds of color patterns is printed according to following steps,
(1) pattern-making: adopt computer photograph three kinds of patterns is green, blue and orange respectively.
(2) make film: according to the pattern of the different colours of computer photograph, make the method for same film according to same color, make three kinds of films respectively.
(3) make printing screen version: according to the film of the pattern of different colours, make the method for same printing screen version according to same color, make three printing screen versions respectively.Wherein, two needs bright golds, one does not need bright gold.Be preferably and do not thicken making silk-screen plate, thickness 0.5mm.
(4) dry base stock: get commercially available water-soluble membranelle base stock and dry base stock: adopt heat drying, temperature 42 DEG C, drying time: 1.2 hours.
(5) oil at the bottom of the first embossment bright gold upper: first that makes by step (3) the step silk-screen plate needing the embossment bright gold of bright gold, with oily at the bottom of embossment bright gold, is printed on base stock by the pattern of the first color (green);
(6) oil at the bottom of the first embossment bright gold dry: utilize oil at the bottom of the dry embossment bright gold of the automatic photocuring of UV-light photocuring machine, the solid speed of light can reach 4000/hour.
(7) the first embossment bright gold of transfer printing: according to the needs of the bright gold pattern of the first color, be transferred on the dried embossment of step (6) photocuring oil of the gold stamping end with dry type laminating machine by orange cold foil paper tinsel, dry type laminating machine cylinder heating-up temperature is 150 DEG C; The laminating machine roller that the roller of described dry type laminating machine adopts our company to invent, its number of patent application is 201210449652.4.
(8) the first embossment bright gold film dry: after transfer printing embossment bright gold film, utilize Cycling hot-blast heating passage dry embossment bright gold film, drying tunnel temperature is 24 DEG C, and drying time is 60 minutes.
(9) oil at the bottom of upper the second embossment bright gold: second that makes of step (3) silk-screen plate needing bright gold, with oily at the bottom of embossment bright gold, is printed on the pattern of the second color (blueness) on base stock.
(10) oil at the bottom of dry the second embossment bright gold: utilize oil at the bottom of the dry embossment bright gold of the automatic photocuring of commercially available UV-light photocuring machine, the solid speed of light can reach 4000/hour.
(11) transfer printing the second embossment bright gold: according to the needs of the bright gold pattern of the second color (blueness), be transferred on the dried embossment of step (10) photocuring oil of the gold stamping end with dry type laminating machine by orange cold foil paper tinsel, dry type laminating machine cylinder heating-up temperature is 100 DEG C.
(12) dry the second embossment bright gold film: after transfer printing embossment bright gold film, utilize Cycling hot-blast heating passage dry embossment bright gold film, drying tunnel temperature is 24 DEG C, and drying time is 60 minutes.
(13) pattern of the third color (orange) is printed, this pattern does not need bright gold: the silk-screen plate made by step (3), use light water transfer ink, the pattern of the third color (orange) not needing bright gold is printed on base stock.
(15) protect gloss oil on: after pattern printing, be coated with one deck gold stamping oil for protection gloss oil.
(16) dry-run protection gloss oil: utilize commercially available UV-light photocuring machine to carry out photocuring drying.
(17) the tearable laminate cover of last layer; The preferably poly-tearable laminate cover of third ethene.
(18) dry tearable laminate cover.Adopt natural air drying.
Above-mentioned UV-light photocuring machine and Cycling hot-blast heating passage all can be purchased in market.The specification of this Cycling hot-blast heating passage is 12 meters * 1.2 meters.
By above step, obtain the embossment bright gold marble paper of three kinds of colors (green, blue, orange).
Embodiment 4:
First oil at the bottom of embossment bright gold is prepared, at the bottom of embossment bright gold, oil is by mass content number, by PU6A resin 16 parts, polyurethane 30 parts, polynary chlorine vinegar 6 parts, monomer 6.5 parts, initator 3 parts, toluene 7 parts, ethyl ester 25 parts, DAA 1.5 parts, isopropyl alcohol 3 parts, butyl ester 2 parts preparation.
Print step with embodiment 2, obtain the embossment bright gold marble paper of three kinds of colors (green, blue, orange).
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Claims (6)
1. a printing method for low temperature embossment bright gold marble paper, is characterized in that, comprise the following steps successively:
(1) pattern-making;
(2) film is made: according to the pattern of the different colours that step (1) makes, make the method for same film according to same color, make film respectively;
(3) make printing screen version: according to the film of the pattern of different colours, make the method for same printing screen version according to same color, make printing screen version respectively;
(4) dry base stock;
(5) oil at the bottom of upper embossment bright gold: the pattern of different colours according to the method for same color printing on same base stock, is printed on different base stock by the silk-screen plate made by step (3) by oil respectively at the bottom of embossment bright gold;
(6) oil at the bottom of dry embossment bright gold: use UV-light photocuring machine to carry out oil at the bottom of the dry embossment bright gold of automatic photocuring;
(7) transfer printing embossment bright gold: according to the needs of the bright gold pattern of different colours, according to same color printing method once, is transferred in electrochemical aluminum foil or orange cold foil paper tinsel on oil at the bottom of step (6) dried bright gold;
(8) dry embossment bright gold film: after each transfer printing bright gold film, dry embossment bright gold film; Dry embossment bright gold film adopts Cycling hot-blast heating passage;
(9) protect gloss oil on: after completing the printing of whole pattern, be coated with one deck gold stamping oil for protection gloss oil; Dry-run protection gloss oil, uses UV-light photocuring machine to carry out automatic photocuring dry-run protection gloss oil;
(10) the tearable laminate cover of last layer;
(11) dry tearable laminate cover.
2. the printing method of a kind of low temperature embossment bright gold marble paper according to claim 1, is characterized in that: oil at the bottom of described embossment bright gold comprises polyamino resin, PU6A resin, polynary chlorine vinegar, monomer, initator, diluent.
3. the printing method of a kind of low temperature embossment bright gold marble paper according to claim 2, it is characterized in that: at the bottom of described embossment bright gold, oil is by mass content number, PU6A resin 11-16 part, polyurethane 30-36 part, polynary chlorine vinegar 5-10 part, monomer 5-9 part, initator 2-6 part, diluent 34-40 part.
4. the printing method of a kind of low temperature embossment bright gold marble paper according to claim 2, is characterized in that: described diluent comprises toluene, ethyl ester, DAA, isopropyl alcohol, butyl ester.
5. the printing method of a kind of low temperature embossment bright gold marble paper according to claim 4, it is characterized in that: in described diluent, by mass content number, toluene 5-8 part, ethyl ester 19-25 part, DAA 0.9-1.5 part, isopropyl alcohol 3-7 part, butyl ester 2-4 part.
6. the low temperature embossment bright gold marble paper of the printing method printing of a low temperature embossment bright gold marble paper according to claim 1.
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CN102964913A (en) * | 2012-11-23 | 2013-03-13 | 东莞市佳烨化工科技有限公司 | Environment-friendly UV (ultraviolet) silk-screen printing anti-counterfeiting ink and preparation method thereof |
CN103102740A (en) * | 2012-12-12 | 2013-05-15 | 张家港威迪森化学有限公司 | Fluorescent ink and preparation method thereof |
CN103073948A (en) * | 2012-12-31 | 2013-05-01 | 中原工学院 | Ink of polycarbonate ink-jet printer for flexible or thin-film solar battery and preparation method of same |
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