CN102910638A - 一种无水偏硼酸锂的制备方法 - Google Patents
一种无水偏硼酸锂的制备方法 Download PDFInfo
- Publication number
- CN102910638A CN102910638A CN2012104590827A CN201210459082A CN102910638A CN 102910638 A CN102910638 A CN 102910638A CN 2012104590827 A CN2012104590827 A CN 2012104590827A CN 201210459082 A CN201210459082 A CN 201210459082A CN 102910638 A CN102910638 A CN 102910638A
- Authority
- CN
- China
- Prior art keywords
- lithium hydroxide
- lithium
- metaborate
- clean liquid
- lithium metaborate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HZRMTWQRDMYLNW-UHFFFAOYSA-N lithium metaborate Chemical compound [Li+].[O-]B=O HZRMTWQRDMYLNW-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 89
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000001035 drying Methods 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims description 35
- 239000004327 boric acid Substances 0.000 claims description 25
- 238000005119 centrifugation Methods 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 238000005352 clarification Methods 0.000 claims description 10
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 claims description 9
- 239000012452 mother liquor Substances 0.000 claims description 8
- 238000006386 neutralization reaction Methods 0.000 claims description 7
- 238000013467 fragmentation Methods 0.000 claims description 6
- 238000006062 fragmentation reaction Methods 0.000 claims description 6
- 238000000746 purification Methods 0.000 claims description 6
- 238000004062 sedimentation Methods 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- 239000010935 stainless steel Substances 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 13
- 239000012535 impurity Substances 0.000 abstract description 4
- -1 inorganic compound lithium metaborate Chemical class 0.000 abstract description 2
- 239000007791 liquid phase Substances 0.000 abstract description 2
- 229960002645 boric acid Drugs 0.000 abstract 4
- 235000010338 boric acid Nutrition 0.000 abstract 4
- 238000009835 boiling Methods 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000000047 product Substances 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229910013184 LiBO Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- PSHMSSXLYVAENJ-UHFFFAOYSA-N dilithium;[oxido(oxoboranyloxy)boranyl]oxy-oxoboranyloxyborinate Chemical compound [Li+].[Li+].O=BOB([O-])OB([O-])OB=O PSHMSSXLYVAENJ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005464 sample preparation method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Abstract
Description
Claims (1)
Priority Applications (1)
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CN201210459082.7A CN102910638B (zh) | 2012-11-15 | 2012-11-15 | 一种无水偏硼酸锂的制备方法 |
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CN201210459082.7A CN102910638B (zh) | 2012-11-15 | 2012-11-15 | 一种无水偏硼酸锂的制备方法 |
Publications (2)
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CN102910638A true CN102910638A (zh) | 2013-02-06 |
CN102910638B CN102910638B (zh) | 2015-01-07 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104016368A (zh) * | 2014-05-30 | 2014-09-03 | 成都开飞高能化学工业有限公司 | X荧光分析用无水硼酸锂熔剂的制备方法 |
CN104326482A (zh) * | 2013-07-23 | 2015-02-04 | 上海中锂实业有限公司 | 制备四氟硼酸锂的方法 |
WO2017107608A1 (zh) * | 2015-12-24 | 2017-06-29 | 中国科学院新疆理化技术研究所 | 偏硼酸锂晶体及制备方法和用途 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1818149A (zh) * | 2005-06-22 | 2006-08-16 | 广州锐鑫锂能新材料科技有限公司 | 用工业级氢氧化锂和硼酸生产高纯高清四硼酸锂晶体技术 |
CN101603203A (zh) * | 2009-07-17 | 2009-12-16 | 中国科学院新疆理化技术研究所 | 八水合偏硼酸锂非线性光学晶体及其制备方法和用途 |
-
2012
- 2012-11-15 CN CN201210459082.7A patent/CN102910638B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1818149A (zh) * | 2005-06-22 | 2006-08-16 | 广州锐鑫锂能新材料科技有限公司 | 用工业级氢氧化锂和硼酸生产高纯高清四硼酸锂晶体技术 |
CN101603203A (zh) * | 2009-07-17 | 2009-12-16 | 中国科学院新疆理化技术研究所 | 八水合偏硼酸锂非线性光学晶体及其制备方法和用途 |
Non-Patent Citations (1)
Title |
---|
WANCHENG ZHU, ET AL.: "Efficient synthesis of orthorhombic lithium borate hydroxide micro-rods and their thermal conversion to lithium borate", 《POWDER TECHNOLOGY》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104326482A (zh) * | 2013-07-23 | 2015-02-04 | 上海中锂实业有限公司 | 制备四氟硼酸锂的方法 |
CN104326482B (zh) * | 2013-07-23 | 2016-05-18 | 上海中锂实业有限公司 | 制备四氟硼酸锂的方法 |
CN104016368A (zh) * | 2014-05-30 | 2014-09-03 | 成都开飞高能化学工业有限公司 | X荧光分析用无水硼酸锂熔剂的制备方法 |
CN104016368B (zh) * | 2014-05-30 | 2015-11-11 | 成都开飞高能化学工业有限公司 | X荧光分析用无水硼酸锂熔剂的制备方法 |
WO2017107608A1 (zh) * | 2015-12-24 | 2017-06-29 | 中国科学院新疆理化技术研究所 | 偏硼酸锂晶体及制备方法和用途 |
US10604863B2 (en) | 2015-12-24 | 2020-03-31 | Xinjiang Technical Institute Of Physics & Chemistry, Chinese Academy Of Sciences | Lithium metaborate crystal, preparation method and use thereof |
Also Published As
Publication number | Publication date |
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CN102910638B (zh) | 2015-01-07 |
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Address after: 430080 Hubei Wuhan Chemical Industry Zone Management Committee (Qingshan metallurgical Avenue No. 11) Applicant after: HUBEI BAIJIERUI ADVANCED MATERIALS Corp. Address before: 437100 +5 building, Changjiang Industrial Park, Wenquan District, Hubei, Xianning Applicant before: HUBEI BAIJIERUI ADVANCED MATERIALS Co.,Ltd. |
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Denomination of invention: A preparation method of anhydrous lithium metaborate Effective date of registration: 20210527 Granted publication date: 20150107 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI BAIJIERUI ADVANCED MATERIALS Corp. Registration number: Y2021420000029 |
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Denomination of invention: A preparation method of anhydrous lithium metaborate Effective date of registration: 20220627 Granted publication date: 20150107 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI BAIJIERUI ADVANCED MATERIALS Corp. Registration number: Y2022420000188 |
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Denomination of invention: Preparation method of anhydrous Lithium metaborate Effective date of registration: 20230630 Granted publication date: 20150107 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI BAIJIERUI ADVANCED MATERIALS Corp. Registration number: Y2023420000285 |
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Denomination of invention: A preparation method of anhydrous lithium metaborate Granted publication date: 20150107 Pledgee: Guanggu Branch of Wuhan Rural Commercial Bank Co.,Ltd. Pledgor: HUBEI BAIJIERUI ADVANCED MATERIALS Corp. Registration number: Y2024980023317 |
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