CN102811697B - Clear or Translucent Composition - Google Patents
Clear or Translucent Composition Download PDFInfo
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- CN102811697B CN102811697B CN201180008653.9A CN201180008653A CN102811697B CN 102811697 B CN102811697 B CN 102811697B CN 201180008653 A CN201180008653 A CN 201180008653A CN 102811697 B CN102811697 B CN 102811697B
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- pidolidone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0233—Distinct layers, e.g. core/shell sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0233—Distinct layers, e.g. core/shell sticks
- A61K8/0237—Striped compositions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/001—Preparations for care of the lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Birds (AREA)
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- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
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Abstract
The present disclosure relates to a clear or translucent composition which takes the form of a solid, a semi-solid or a viscous gel. The inventive composition contains a mixture of at least two amino acid-based gelatinizing agents, at least one polyamide resin, a non ionic, unsaturated fatty alcohol in an amount which reduces the dissolution temperature of the gelatinizing agents to allow processing at or below 115 DEG C., an alkyl dimethicone, and an oil and/or a polymer component. Additional ingredients depending on the application may also be included in the clear or translucent composition. The present disclosure also relates to methods of producing the clear or translucent composition of the disclosure and uses thereof.
Description
Cross reference with related application
The application requires the priority of USSN 13/080,034 of submitting on April 5th, 2011, described patent for all objects by reference entirety integrate with herein.
Technical field
Present disclosure relates to cosmetics, cosmeceutical and personal care field.Especially, cause the combination of components of transparent or semitransparent compositions can use existing manufacturing equipment to process under specificity condition.The process of present disclosure causes the formation of the transparent or semitransparent compositions obtaining in unexpected and highly favourable mode.
Background
Cosmetic formulations or personal care product can be prepared with solid, semisolid or gel combination.For example, use routinely compressed powder rod, gel stick and rod wax.These preparation types have advantage under a stable condition, but, also there is separately shortcoming.Compressed powder rod is known is fragility and rigid, and has the trend that leaves unacceptable dust in beauty treatment after application.Although gel can provide splendid aesthetic features, but they may be unsettled, this is for example, due to for example undesirable interaction between gel and " activity " composition (opacifier and hidroschesis salt), and described gel is generally used for and solidifies this type of rod.Preparation based on wax can also produce due to its hardness, greasy and viscosity and in beauty treatment unacceptable product.Another shortcoming of bar-shaped preparation based on wax is that wax causes opaque preparation, and it disturbs the true color of coloring agent to be presented.In addition, the conventional preparation based on wax is tending towards becoming harder, and compositions is soft and conventionally cause dull (draggy) application.
Another problem of this area is that transparent bar composition is tending towards making one or more solvents perspirations (sweat) under rising temperature conditions.In addition, this type of rod melts under hot conditions, and when at freezing conditions be generally circulation time between the ambient temperature of 25 DEG C, likely becomes muddy.Usually, the temperature of these risings and/or cryogenic temperature occur in the storage of bar shaped article and transportation.
Therefore, the object of disclosure is to provide transparent or semitransparent compositions, and it has sufficient intensity to avoid solvent at high temperature to ooze out from compositions, can between different temperatures, circulate and maintain transparency and transmit true color.
General introduction
An object of disclosure is to provide transparent or semitransparent compositions, and it comprises:
(a) at least 2 kinds based on amino acid whose gelatinizing agent;
(b) fatty alcohol;
(c) at least one polyamide
(d) alkyl-dimethyl silicone oil; With
(e) oil, polymer or its combination,
Wherein said compositions has or lower than the solution temperature of approximately 115 DEG C, and dissolution time occurred in several minutes.
Another object of disclosure relates to the transparent or semitransparent compositions of taking solid, semisolid or viscous gel form.A further embodiment relates to the transparent or semitransparent compositions with bar-shaped form.
An object of disclosure is to produce the transparent or semitransparent rod with repeatability hardness.If there is no this higher excellent intensity, rod cannot take out and be without prejudice from manufacture mould.
In the another one object of disclosure, the transparent or semitransparent compositions of disclosure is cosmetics, cosmeceutical or personal care product.
An object of disclosure is wherein to combine the coloured composition of coloring agent and transparent or semitransparent compositions.Coloring agent can comprise conventional coloring agent together with not together with one or more surface treatments, goniochromatic (goniochromatic) coloring agent, multidimensional pigment, pearl oyster agent (pearlescents) and holographic glitter (holographic glitters).
In a further object of the present invention, the unique combination of component or composition produces transparent or semitransparent compositions, and it uses existing cosmetics manufacturing equipment to process.
Another one object relates to for the manufacture of the method for transparent or semitransparent rod with high excellent intensity.
In a further object of the present invention, the method that produces transparent or semitransparent compositions comprises blending ingredients (a), (b), (c), (d) and (e), thereby produce transparent or semitransparent compositions, wherein (a), (b), (c), (d) and mixture (e) have approximately 115 DEG C or lower solution temperature, and depend on batch size and condition, in approximately 10 approximately 20 minutes, realize.Once should be understood that to dissolve to reach, compositions just can be cooled to the pouring temperature lower than 115 DEG C.
Comprise after illustrative embodiment and embodiment at the following detailed description of reading, these of present disclosure and other objects will become apparent for those skilled in the art.
Describe in detail
Present disclosure relates to transparent or semitransparent compositions, its using method and produces the method for transparent or semitransparent compositions.Compositions can be taked the form of solid, semisolid or gel.Another embodiment relates to transparent or semitransparent compositions and has the other composition of required character.
A further embodiment relates to the synergistic combination of principal component, and it is processed with existing cosmetics manufacturing equipment, and causes the generation of strong bar composition.More specifically, transparent or semitransparent compositions comprises:
(a) at least 2 kinds based on amino acid whose gelatinizing agent;
(b) fatty alcohol;
(c) at least one polyamide
(d) alkyl-dimethyl silicone oil; With oil, polymer or its combination.
One of the problem in bar composition field be manufacture and production process in the shortage of the compositions intensity that needs.If there is no enough or sufficient excellent intensity, compositions conventionally can not eject or be impaired in the time ejecting from mould or take out from mould.Compositions of the present invention preferably adopt be increased to 2 kinds of significant quantity of being greater than that this area finds based on amino acid whose gelatinizing agent, be called polyamide and one or more alkyl-dimethyl silicone oil materials of ethylenediamine hydrogenation dimerization dilinoleic acid ester copolymer Bis-Di-C14-18 alkylamide, to form the transparent or semitransparent compositions of disclosure.Of the present invention can have according to the structure of formula (I) based on amino acid whose gel:
Wherein R
1, R
2and R
3c
1-C
20hydrocarbon part, it can be straight chain, branch or ring-type, and can comprise one or more hetero atoms that are selected from oxygen, nitrogen and sulfur.R
1, R
2and R
3select independently in each case, and can be therefore identical or different.Preferably, R
1, R
2and R
3in at least one be C
5-C
20hydrocarbon part, and more preferably, R
1c
6-C
20hydrocarbon part.Usually, R
1, R
2and R
3be selected from independently of one another branch, straight chain or the cyclic alkyl with 320 carbon atoms.R
1, R
2and R
3can for example be selected from independently of one another methyl, ethyl, propyl group (such as n-pro-pyl or isopropyl), butyl (such as normal-butyl, isobutyl group, the tert-butyl group), amyl group (such as n-pentyl, isopentyl, neopentyl, cyclopenta), hexyl, heptyl, octyl group, nonyl, decyl, undecyl, dodecyl, tridecyl, myristyl, pentadecyl etc.In one embodiment, R
1be selected from branch or the straight chained alkyl with 5-16 carbon atom, and R
2and R
3the straight chained alkyl with 3-6 carbon atom independently, i.e. propyl group, butyl, amyl group or hexyl.Preferably, R
1be selected from branch or the straight chained alkyl with 5-16 carbon atom, and R
2and R
3respectively normal-butyl naturally.In one embodiment, R
1be straight chain undecyl, and the compound of formula (I) is dibutyl lauroyl glutamine.In another embodiment, R
1be branch's heptyl, the compound of more specifically 1-ethyl pentyl group, and formula (I) is dibutyl ethyl hexyl acyl group glutamine.
As should be understood as technical staff, in the time that all the components of compositions or component are dissolved completely, dissolve and occur.But, in order to reach the dissolving completely that comprises the prior art compositions based on amino acid whose gel, temperature must be increased to or exceed 130 DEG C, is the very long gelling time of at least 15 hours subsequently, to make compositions enough cooling, so that gelling at the temperature of approximately 23 DEG C-Yue 25 DEG C.Although the amount of one or more that use in prior art compositions based on amino acid whose gel is generally minimum (gellant and oil ratio 1: 100), but still time expand section must be processed under extreme condition as above based on amino acid whose gellant, to reach gel.Especially, as mentioned above and find in prior art, scope is that the approximately 130 DEG C-temperature that exceedes approximately 200 DEG C is generally that those are required based on amino acid whose gelatinizing agent, to become solution.Because dissolve required excessive temperature, need the prior art compositions of these gelatinizing agents to be confined to oil or the polymer of the selection group that can stand excessive temperature.
Another shortcoming that uses these gelatinizing agents is that the general cost of the time of their gellings is extremely long-time.For example, condense or molding (set) for gel of the prior art, required time and temperature will be 25 DEG C approximately 15 hours.Therefore, this area processes these gelatinizing agents because high solution temperature is utilized many energy, considers and obtains required very long time of product and reduce output, has limited operable oil or polymer, and has increased total manufacturing cost.
But the composition of the compositions of present disclosure or the particular combinations of component allow to dissolve at much lower temperature, thereby and need shorter time quantum, there is to obtain the disclosed transparent or semitransparent compositions of improving character that exceedes this area.As previously mentioned, based on the combination of amino acid whose gellant, ethylenediamine hydrogenation dimerization dilinoleic acid ester copolymer Bis-Di-C14-18 alkylamide, fatty alcohol, alkyl-dimethyl silicone oil and oil or polymer, reach or lower than 115 DEG C at large approximate number minute to the dissolving in a few hours, depend on overall batch of size.In addition, normally within approximately 15 hours, compare with the gel of prior art, compositions of the present invention can be condensed in large approximate number minute.Compositions of the present invention can, in span internal cast, ejection and the insertion packaging of 310 minutes, depend on the selection of equipment and condensation condition.
In another embodiment of disclosure, the present composition comprise at least 2 kinds of mixture based on amino acid whose gelatinizing agent based on amino acid whose gelatinizing agent, 3 kinds or more kinds of can be also useful based on amino acid whose gelatinizing agent.Non-limitative example comprises any in known gelatinizing agent, N-acetyl group glutamic acid two lauramides, N-hexanoyl glutamic acid dibutyl amide, N-lauroyl glutamic acid dihexyl amide, N-lauroyl-glutamic acid dihexyl amide and N-acetylamino acids amide.In a particular, the mixture based on amino acid whose gelatinizing agent comprises N-lauroyl-Pidolidone dibutyl amide and N-2-ethyl hexyl acyl group-Pidolidone dibutyl amide.If have 2 kinds based on amino acid whose gelatinizing agent, so they with scope the weight ratio between 1: 3 or 3: 1, and preferably than being 2: 3.But, existing and exceed in 2 kinds of another embodiments based on amino acid whose gelatinizing agent therein, weight ratio is for example 1: 1: 1.Particularly preferred ratio is 2: 3 dibutyl ethyl hexyl acyl group glutamine: dibutyl lauroyl glutamine.
In addition, the mixture based on amino acid whose gelatinizing agent or total amount exceed above-mentioned prior art gellant.Another embodiment of disclosure relates to the compositions comprising based on amino acid whose gellant, the described weight ratio based on amino acid whose gellant with the total composition of the total composition of about 1.5%-approximately 6.0%, about 2.25%-approximately 3.0% or about 3.5%-approximately 5.0%, with this area generally more unsettled bar composition form contrast, its comprise by the weighing scale of total composition be less than 1% based on amino acid whose gelatinizing agent.In addition, the more unsettled bar composition in this area generally adopts one or both based on amino acid whose gellant, and such composition does not comprise polyamide, nonionic fatty alcohol or alkyl-dimethyl silicone oil or derivatives thereof.Synergistic combination based on amino acid whose gellant, ethylenediamine hydrogenation dimerization dilinoleic acid ester copolymer Bis-Di-C14-18 alkylamide and alkyl-dimethyl silicone oil allows to produce more rigid cosmetic stick, it can stand extreme environmental conditions, maintains its integrity simultaneously.In the prior art, excessive temperature is that the dissolving of realization based on amino acid whose gellant is necessary.But simethicone and polyamide resin material are not processed under this type high temp.In addition, polyamide and simethicone help stabilization rod in 2 kinds of modes: first, polyamide makes rod more rigid; And next, the combination of polyamide and simethicone stops rod " perspiration ".In the time that compositions is for example exposed to freezing conditions or high temperature in storage or transportation, compositions will be tending towards becoming haze (hazy), and in the time getting back to environmental condition from arbitrary extreme temperature of listing, may perspire or ooze out solvent.But owing to disclosing the unique combination of composition herein, perspiration and mist are not problems.
Another embodiment of disclosure relates to the transparent or semitransparent compositions that comprises at least one fatty alcohol, its can or dissolve based on amino acid whose gelatinizing agent or gellant lower than the temperature of 115 DEG C.Include but not limited to nonionic list or polyunsaturated fat alcohol for one or more nonionic unsaturated fatty alcohols that are dissolved with use.The non-limitative example of the useful fatty alcohol of disclosure comprises oleyl alcohol, octyldodecanol, 2-butyl octanal, 2-hexyldecanol and 2-hendecyl pentadecanol.A particular relates to octyldodecanol.The long-chain of the present composition, unsaturated fatty alcohol are to exist by the amount of the about 0.1%-of the weighing scale of total composition approximately 45%.Other embodiments relate to by the about 15%-of the weighing scale of total composition approximately 30% and the amount of about 16%-approximately 25.5% further.
The selection of fatty alcohol depend on its or lower than 115 DEG C of dissolvings the ability based on amino acid whose gellant.In one embodiment, useful unsaturated fatty alcohol is nonvolatile.Nonvolatile be defined as in this article under 1.0 atmospheric pressure, have at least about 200 DEG C, at least about 205 DEG C with at least about those fatty alcohol of the boiling point of 210 DEG C.Some fatty alcohol of present disclosure has a for example two key (monounsaturated).Their general formula is CH
3(CH
2)
xcH=CH (CH
2)
y-CH
2oH.
Suitable fatty alcohol also comprise undersaturated monobasic straight-chain fatty alcohol, saturated branched fatty alcohol, saturated C8-C12 straight-chain fatty alcohol, and composition thereof.Undersaturated straight-chain fatty alcohol generally has a degree of unsaturation.Two and triunsaturated alkenylene chain can exist with low-level, be less than approximately 5%, be less than approximately 2% or be less than approximately 1% by the gross weight of undersaturated straight-chain fatty alcohol.In specific embodiments, undersaturated straight-chain fatty alcohol has the aliphatic chain length that scope is C12-C22, C12-C18 or C16-C18, for example oleyl alcohol and Palmitoleyl alcohol.The non-limitative example of nonionic unsaturated fatty alcohol comprises those that identify in table 1:
Table 1
In other embodiments, in the time that the present invention takes semisolid or solid form, polyamide provides the structural intergrity of significant level.Polyamide is heavy polymer, it is characterized in that the amido link along strand.These polymer contain the amide monomer being connected by peptide bond, they can be natural or artificially occur, this base polymer is prepared by progressively polymerization or solid phase synthesis, and in some cases, the example of polyamide is nylon and fragrant amide (aramids).Due to its extreme durability and intensity, polyamide is generally used in textile, plastics and the application of multiple automobile.In compositions of the present invention, polyamide also provides gloss or brightness and provides adhesion to target substrate compositions.
Although polyamide ethylenediamine hydrogenation dimerization dilinoleic acid ester copolymer Bis-Di-C14-18 alkylamide is preferred at present, the present invention is not limited to this polyamide.Those skilled in the art can select suitable polyamides resin, and many suitable polymer are disclosed in CTFAHandbook, and the 12nd edition, in 2008, its disclosure is by reference in this merging.These include but not limited to polyamide-1, polyamide-2, Polyamide-3, ethylenediamine/dimerization resinate copolymer dihydro Adeps Bovis seu Bubali amide, ethylenediamine/stearoyl dimerization dilinoleic acid ester copolymer, ethylenediamine/stearoyl dimerization resinate copolymer etc.
A particular of present disclosure relates to the combination of polyamide or compatible polyamide resin, taking scope as by the amount of the about 0.1%-of the weighing scale of total composition approximately 30%, by weight about 10%-approximately 25% and about 15%-approximately 20%.Particularly preferred polyamide is ethylenediamine hydrogenation dimerization dilinoleic acid ester copolymer Bis-Di-C14-18 alkylamide.
In another embodiment, alkyl-dimethyl silicone oil component provides the heat-staple bar composition of disclosure.Except improving the structural strength of disclosed compositions, thereby be easy to from mould, take out outside compositions, alkyl-dimethyl silicone oil and polyamide provide structural intergrity, and rising temperature for example storage or product transport process in, help stop bar composition " perspiration ".The clarification bar composition of this area is tending towards ' perspiration ' or ' outflow ' one or more solvents at rising temperature.These high temperature generally approximately 130 DEG C-exceed between 200 DEG C.In order to overcome these problems of this area, alkyl-dimethyl silicone oil material (it relates to one or more alkyl-dimethyl silicone oil) can be included in the transparent or semitransparent compositions of disclosure.
As this area is to be understood that, alkyl-dimethyl silicone oil can be silicone or oil-soluble, depends on the ratio of x, y and z in following formula.
Along with the value of x and y increases, it is harder and more solvable in silicone oil that alkyl-dimethyl silicone oil becomes.Along with z value increases, alkyl-dimethyl silicone oil will be more solvable in oil for example vegetable oil, mineral oil and ester, also the raise melting temperature of wax of described ester.Along with the value increase of x and the value of z reduce, it is more solvable in silicone that alkyl-dimethyl silicone oil becomes.But along with the value of y and z increases, it is more oily molten that alkyl-dimethyl silicone oil becomes.
As formulation art, technical staff is well-known, and the ratio that changes x, y and z determines that alkyl-dimethyl silicone oil is liquid, soft paste or hard wax.Usually, use the alkyl of higher number, for example 22 carbon, depend on the ratio of x and y, and product will be paste or hard wax.Higher x value reduces the fusing point of product.Meanwhile, have the alkene of 18 carbon-based groups, depend on the ratio of x and y, alkyl-dimethyl silicone oil can be that liquid is to hard wax.There is 16 carbon-based groups or lower normally extremely soft paste of liquid of alkyl.Find, in the time that alkyl-dimethyl silicone oil adds in opacifier, to have the improvement in spf value.Therefore, those of ordinary skill in the art will consider that the factor relevant with results needed determines the definite ratio of x, y and z.To structure be provided or maintain required effect than being adjusted into.The factor that can take in comprises use and the desired form of final products.
A particular of present disclosure relates to the combination of alkyl-dimethyl silicone oil or compatible alkyl-dimethyl silicone oil, taking scope as by the amount of the about 0.1%-of the weighing scale of total composition approximately 30%, by weight about 10%-approximately 25% and about 15%-approximately 20%.Useful alkyl-dimethyl silicone oil has at the alkyl by the about 18%-65% scope of the weighing scale of whole alkyl-dimethyl silicone oil in this disclosure, and simethicone is in the respective range of the about 35%-of the weighing scale of pressing alkyl-dimethyl silicone oil approximately 82%.In another embodiment, the alkyl-dimethyl silicone oil that contains 1-18 carbon, the alkyl-dimethyl silicone oil of for example stearyl simethicone C18 is the most useful.The other non-limitative example of the alkyl-dimethyl silicone oil of present disclosure comprise mountain Yu base simethicone, C-32 alkyl-dimethyl silicone oil, isopropyl phenyl simethicone, cerul simethicone, hydroxypropyl simethicone behenate, cetyl/hexacosyl simethicone and
the D of alkyl-dimethyl silicone oil and J series and Multi Domain silicone (Siltech LLC; Dacula, GA).
In other embodiments, polyamide is for providing other structural intergrity to bar composition of the present invention.Ethylenediamine hydrogenation dimerization dilinoleic acid ester copolymer Bis-Di-C14-18 alkylamide is particularly preferred polyamide.This polyamide can with press the about 1%-of weighing scale approximately 35% of total composition/or the amount of about 5%-25% for compositions of the present invention.
In embodiment further, the oil of the transparent or semitransparent compositions of disclosure or polymer can comprise oil or polymer, but also can be multiple oil, multiple polymers or both combinations, the i.e. combination of one or more oil and/or polymer.The oil of disclosure or polymer include but not limited to non-polar oil, polar oil, liquid polymers, solution polymer or its combination.Thereby the oil that is suitable for the transparent or semitransparent compositions for present disclosure of the purposes of this compositions is included in those of formation that fully allow the dissolving of gelatinizing agent after heating and cause gel when cooling.Non-limitative example comprises mineral oil, 2-Methylpentadecane, Jojoba oil (jojoba oils), for example Super Sterol Liquid (Croda Inc. of C10-C30 cholesterol/lanosterol (Lanoesterol) ester; Edison, NJ), ermine oil, cupu oil, Oleum Cocois, Petiolus Trachycarpi seed oil, Camellia oil, Oleum sesami, Oleum Ricini, olive oil, Aloe extract and silicone oil.
More specifically, illustrative ester oil comprises ester such as tridecyl trimellitate, three isooctadecanol citrates, two isooctadecanol maleates, two isooctadecanol fumarates etc.Useful liquid polymers or solution polymer include but not limited to polybutene, Parleam, three iso stearyl polyglyceryl-3-dimerization dilinoleic acid esters, Risorex PGIS 22 etc. in this disclosure.The oil of compositions disclosed herein or polymers compositions can be taking scopes as by the about 20%-of the weighing scale of total composition approximately 70%, more particularly scope is as the amount of the about 32.5%-of total composition approximately 47.5% or the about 42%-of total composition approximately 65%.
Not bound by theory, dissolve and the interests of gelling time and the transparent or semitransparent compositions of low dissolving and gelation temperature (it has the excellent intensity of relative increase and the perspiration character of minimizing) fast in order to obtain to have relatively, and N-lauroyl-Pidolidone dibutyl amide of the weight ratio of 2: 3 fatty alcohol such as octyldodecanol compatible with N-2-ethyl-caproyl-Pidolidone dibutyl amide between 1: 3 or 3: 1 or more specifically with scope particularly based on amino acid whose gelatinizing agent, provide or lower than 115 DEG C and dissolving completely in large approximate number minute.
In another one embodiment, transparent or semitransparent compositions comprises other component.Transparent or semitransparent compositions can comprise antioxidant or its mixture in addition, with not degradation of protection group compound.In a particular, one or more antioxidants can use taking scope as the amount by the about 0.01%-of the weighing scale of total composition approximately 0.5%.In the transparent or semitransparent compositions of disclosure, useful a kind of antioxidant is butylated hydroxytoluene (BHT).But, can use and any antioxidant of other component compatibility of the present composition, include but not limited to potassium sulfite, sodium sulfite, butylated hydroxyanisole etc.Antioxidant can not degraded with protection group compound with effective dose, for example, press the about 0.01%-of weighing scale approximately 0.5% of total composition, about 0.06%-approximately 0.5% and about 0.3%-approximately 0.5% by weight.Embodiment 1 and 2 provides exemplary transparent or semitransparent preparation.
Conventional bar composition adopts high melting-point wax, for example, use paraffin, Cera Flava, Brazil wax, ceresine, crystallite and Tissuemat E, to the compositions with structure is provided.This type of wax has high-melting-point, and produces wherein structure and, by the substrate of the crystal composition of random orientation, cause opaque outward appearance.Therefore, these waxes disturb coloring agent and the color that manifests that obtains is inaccurate.Therefore, in another embodiment of present disclosure, send " true color " with the transparent or semitransparent compositions of conventional coloring agent and/or goniochromatic colorant combination, there is the vibratility (vibrancy) of only observing so far in transparent liquid medium.
The present composition is in the embodiment of colour cosmetic therein, and such as but not limited to lip pomade or lip gloss etc., said composition further comprises one or more stains.Selective staining agent and compound staining agent are to produce required color or effect in art technology.Suitable normal dyeing agent comprises that pigment, color lake and dyestuff are well-known in the art, and is disclosed in C.T.F.A.Cosmetic Ingredient Handbook, and the 1st edition, in 1988, its content is by reference in this merging.Organic pigment comprises for example FD & C dyestuff, D & C dyestuff comprises the red numbering 2,5,6,7,10,11,12,13,30 and 34 of D & C, the yellow numbering 5 of D & C, blue numbering 1, purple numbering 2.Exemplary inorganic pigment includes but not limited to metal-oxide and metal hydroxides, for example magnesium oxide, magnesium hydroxide, calcium oxide, calcium hydroxide, aluminium oxide, aluminium hydroxide, ferrum oxide (α-Fe
2o
3, y-Fe
2o
3, Fe
3o
4, FeO), red iron oxide, yellow iron oxide, black iron oxide, hydrated ferric oxide., titanium dioxide, rudimentary titanium oxide (titanium lower oxide), zirconium oxide, chromium oxide, chromic oxide gel, manganese oxide, cobalt oxide, cerium oxide, nickel oxide and zinc oxide, and composite oxides and complex hydroxide, for example iron titanate, cobalt titanate and cobalt aluminate.Other suitable stains comprise ultramarine (, sulfur-bearing lagoriolite), Prussian blue, manganese violet, bismuthyl chloride, Talcum, Muscovitum, sericite, magnesium carbonate, calcium carbonate, magnesium silicate, aluminium-magnesium silicate, silicon dioxide, mica titanium, ferrum oxide mica titanium, bismuthyl chloride etc.Stain can be to carry out finishing by for example fluoropolymer polymer, to adjust as for example U.S. Patent number 6,471,950,5,482,547 and 4,832, and one or more features of the stain described in 944, the content of described patent is by reference in this merging.The coating that fluoropolymer polymer can be used as on granules of pigments is mixed present disclosure, the surface of at least part of coverage pigment granule of described coating.Suitable pearl pigment includes but not limited to contain titanium dioxide, rudimentary titanium oxide or titanium oxynitrides titanium composite material, bismuthyl chloride and the guanine as titanium component, as U.S. Patent number 5, disclosed in 340,569, the content of described patent is by reference in this merging.
In an embodiment of disclosure, conventional coloring agent adopts taking scope as the amount by the about 0.01%-of the weighing scale of total composition approximately 30%.The true color of seldom seeing in conventional solid preparation is sent in the combination of any this based colorant and transparent or semitransparent compositions disclosed herein.In the another one embodiment of disclosure, in the present composition described herein, useful goniochromatic coloring agent is taking scope as by the amount of the about 0.1%-of the weighing scale of total composition approximately 15%.Goniochromatic coloring agent, also referred to as colour switching pigment (color travel pigment), comprises the basic substrate of the small plate form coated by the alternating layer of high or low refraction index material.Goniochromatic coloring agent is to depend on that visual angle demonstrates the pigment of different colours.
Illustrative coloring agent comprises Reflecks
tMmultiDimens ions (BASF Corp.; Florham Park, NJ) pigment, it can cross over the transformation of whole vision spectrum, to provide multiple colour effect by its borosilicate pigment technology, and SpectraFX, it is with from minimum to the obtainable powdery thin slice of great multiple sizes additive (Alsa Corp.; Vernon, CA).Reflecks
tMmultiDimensions pigment is by forming with the coated borsal calcium of silicon dioxide, titanium dioxide and stannum oxide.In a particular of disclosure, goniochromatic coloring agent is added in transparent or semitransparent compositions, to send unique colour effect.These goniochromatic coloring agent scope in granularity is approximately 1 micron to approximately 100 microns, or more specifically, approximately 40 microns to approximately 80 microns, as illustrative by SpectraFX pigment and Reflecks pigment respectively.
A further embodiment relates to the amount of goniochromatic coloring agent useful in the transparent or semitransparent compositions of disclosure, its scope is by the about 0.1%-of the weighing scale of total composition approximately 15%, and in a particular, the weight range of coloring agent is by the about 0.5%-of the weighing scale of total composition approximately 5%.The granularity of the coloring agent using in compositions and amount determine the final optical effect of compositions.As those of ordinary skill in the art are to be understood that, depend on visual angle, the percentage by weight load of Copper/Patina SpectraFX pigment 0.5% causes translucence and the color transition of perceiving from copper/Aerugo to green.But in the time of higher colorant load, because light still less may transmit the fact by compositions, the translucence of compositions reduces.But, depend on visual angle, still there is the color transition of perceiving.
Similarly, in embodiment further, with the Margarita parent form coloring agent of transparent or semitransparent combination of compositions can be opaquer than routine for sending, visible better or more true color effect in bar composition based on wax.Another embodiment relates to the transparent or semitransparent compositions with the holographic glitter that produces unique effect.These glitters comprise that it is polyester sheet holographic relief, vacuum metallization processes those, for example can be from Spectratek Technologies, and those that Inc. (Los Angeles, CA) obtains.Depend on the visual effect of SpectraFX pigment the same way that loading changes, this is also applicable to holographic glitter.When adding fashionable to be less than approximately 2% load by the weighing scale of total composition, produce translucent appearance with the present composition of holographic glitter combination, and it is the same that glitter looks like that they are suspended in compositions, thereby different colours is produced by different glitter granules.But in the time of higher coloring agent load, translucence reduces.
In embodiment further, the mixture combination of transparent or semitransparent compositions and conventional coloring agent and goniochromatic coloring agent, is not dual caryogram as above.In the time that the present composition uses in this type of mode, the general quantity scope of conventional coloring agent is by the about 0.1%-of the weighing scale of total composition approximately 25%, and the goniochromatic coloring agent scope approximately 0.1%-approximately 15% that is total composition.
Another embodiment relates to the preparation method of transparent or semitransparent compositions as described herein.Utilize an embodiment of the conventional machine using to be included in to be enough to approximately 115 DEG C of dissolved constituent or lower temperature is mixed all components simultaneously, comprising:
(a) at least 2 kinds based on amino acid whose gelatinizing agent;
(b) fatty alcohol;
(c) at least one polyamide
(d) alkyl-dimethyl silicone oil; With
(e) oil, polymer or its combination.
Usually, depend on batch size, be dissolved in several minutes to a few hours and occur.Once reach dissolving, the mixture obtaining just can be cooled to lower pouring temperature.In the time that the compositions of fusing starts to become gel, semisolid or solid composite from self-running liquid, represent gelling or adiabatic condensation temperature.Useful gelling or adiabatic condensation temperature scope are approximately 25 DEG C-Yue 80 DEG C, approximately 65 DEG C-Yue 80 DEG C in this disclosure, or in the most useful embodiment, about room temperature or approximately 25 DEG C.Again, required time of transparent or semitransparent compositions gelling is in the scale of several minutes instead of a few hours.Embodiment 2 relates to the example of the method for the transparent or semitransparent compositions that produces present disclosure.
In the further embodiment again of disclosure, first the method relates to blending ingredients (a) and (b), (a) and compounding substances (b) are heated to approximately 115 DEG C or lower temperature at most, thus dissolving mixt.Subsequently,, and dissolve at similar temperature simultaneously or sequentially add each other component (c), (d) and (e), be no more than approximately 115 DEG C.The component (a), (b), (c), (d) and the mixture (e) that obtain are cooling subsequently, to form solid, semisolid or viscous gel compositions.
Another embodiment of disclosure relates to the interpolation of the optional member that promotes other interests to the present composition.Non-limiting activity or functional component can comprise coloring agent, pigment, ultraviolet filter material, moisturizing agent, aromatic (fragrances), insecticide, insecticide, pharmaceutical formulations and cosmetics or known other activity or the functional component of pharmaceutical field.These other compositions can mix with (a), (b), (c), (d) and component (e) simultaneously, or with component (c), (d) with (e) mix, or mix after the mixing of (a), (b), (c), (d) or any or all component (e) simultaneously.In any case other composition must be compatible with the parameter of the present composition, for example or dissolve lower than the temperature of approximately 115 DEG C.Should be understood that optional composition can as by as described in the adding at lower temperature of the physics of material or the form of thermal limit or required end product instruction.Further embodiment relates to and comprises any preceding method that the mixture of fusing or viscous gel is cast to the other step in mould.Once should be understood that and reach dissolving, the compositions obtaining just can be cooled to slightly lower temperature from 115 DEG C, depends on that the form of required filling condition and end product is selected.Usually, such composition is filled or mold in automation equipment, wherein from be poured into mold to eject to the markers scope of packing insert be from 2 to 10 minutes Anywhere.In addition, depend on selected product form and associated attribute of performance, described automation equipment mold temperature can scope be approximately-10 DEG C to approximately 40 DEG C.
Correspondingly, present disclosure relates to the transparent or semitransparent compositions can with numerous application.Especially, the present composition can be painted or not painted cosmetic product, and it is useful especially for being applied to face, lip, eye, cheek and health.In one embodiment, transparent or semitransparent compositions is bar composition, for example, and at bottoming frost (primers), vanishing cream, eye product, lip product, sunscreen or opacifier, antiperspirant, deodorizer etc.Although solid product is widely used in cosmetics, but present disclosure is unique, because be called the further interpolation of fatty alcohol and alkyl-dimethyl silicone oil and the polyamide of octyldodecanol by use, gel formation step is pre-formed at significantly lower temperature, and this causes taking the product of solid, semisolid or viscous gel form.The compositions obtaining is to exceed to adopt one or more any prior aries based on amino acid whose gellant heat-staple.Depend on the special-purpose of transparent or semitransparent compositions, can comprise other composition.
Another embodiment of present disclosure relates to the combination of transparent or semitransparent compositions as described herein and the painted lip composition of routine as separate entity, to produce mixing lip product.In another embodiment of present disclosure, transparent or semitransparent compositions can be with routine the present composition combination of the lip pomade based on wax or the disclosure that contains coloring agent.This combination for example may reside in cylindric lip composition, looks down from top view, and half compositions is conventional lip pomade, and second half transparent or semitransparent compositions that is the present invention (together with or be not inconjunction with toner).Another embodiment relates to dual caryogram configuration.For example, the transparent or semitransparent compositions of the present invention can form shell, and conventional lip pomade formation kernel, thereby makes shell around kernel, and it is visible by forming concentrically ringed transparent or semitransparent shell.Similarly, the painted present composition can form kernel, thereby even if make transparent or semitransparent shell around kernel, is also visible from the color of kernel.Unlimited color combination is possible, and special colour effect is possible by mix goniochromatic pigment in outside hyaline test in addition, be complementary, or in specific embodiments, coloring agent is in kernel thereby make they and kernel painted.The loading of coloring agent in different dwell of cams by as application or as storage required final visual effect indicate.The another one embodiment of present disclosure relates to for projecting light onto the light source in clear gel, thereby illuminates gel and other visual effect is provided.The non-limitative example of light source can be incandescent, infrared, laser, fluorescence and natural.In embodiments, the present invention relates to the lip care product of packaging, its comprise the container for holding lip compositions, the lid on container be exposed to air in pot life compositions processed not and with the machinery of container combination for assign group compound from container.Container comprises to be filled according to the pipe of compositions of the present invention and such as LED of the light source in container body, when compositions is for example by removing lid on container or when press voltage regulator or switch exposure, described light source can illuminate compositions.
A further embodiment of disclosure relates to compositions, preferred local solid bar, semisolid or gel, it is cosmetics, personal care product, cosmeceutical or medical preparation, insect repellent or sunscreen product (sun product), wherein compositions comprises the fatty alcohol that is enough to dissolve other components, described other components for example at least 2 kinds based on amino acid whose gelatinizing agent, oil, polymer, antioxidant, aromatic etc.Disclosed compositions can, in product, be sent such as but not limited to colour cosmetic, sun-proof nursing, skin nursing, hair product (shampoo, conditioner, hair spray, mousse and dyestuff/coloring agent), mascara, nial polish, lip dyeing product, vanishing cream, eye cosmetic, skin nursing products, personal hygiene products and topical remedy or activity.
In another embodiment, the compositions of disclosure can also comprise any additive in this area that is generally used for of imagination, for example antioxidant, spice, quintessence oil, stabilizing agent, cosmetic active substances, moisture retention liquid, vitamin, essential fatty acid, lipophilic opacifier, lipophilic polymer and particularly hydrocarbon polymer be poly-alkylene and polyamide for example, for improving other cosmetics smooth or that spreadability, water-resistance and grease resistance, transfer resistance or those skilled in the art are required or cosmeceutical character.The non-limitative example of the optional composition adding comprises: emollient, thickening agent be opacifiers, clay or organic clay, silicon dioxide, cellulose derivative, plasticizer, gel, fatty acid, fat, powder, oil, antiseptic, solvent, surfactant for example; Strese Hofmann's hectorite.; The association polymer of for example acrylate copolymer of synthetic polymer or polyurethanes type; Spreading agent; Dispersant; Antiseptic; Antifoam; Wetting agent; Ultraviolet screening agent; Spice; Filler and extender; Binding agent; Cosmetics or forms of pharmacologically active agents; Moisture retention liquid; Sensory intensifier includes but not limited to powder and oil; Vitamin and derivant thereof; With biologic material and derivant thereof.If the flexibility of compositions and elasticity are treated further to increase again, can also add so plasticizer, it adds conventionally for cosmetic material.Suitable material can comprise low-molecular-weight and high molecular plasticizer, and it is use, solubilising or be dissolved in cosolvent optionally.
Suspension and thickening agent generally comprise silica gel, natural gum, clay, fumed silica, fatty acid soaps and hydrocarbons gel and other compositions (in the time mixing in preparation, described composition is retained on the surface of collenchyme).The for example emollient of non-limitative example that can be preferred for the composition in the compositions of disclosure comprises glycerol, propylene glycol, cyclomethicone, simethicone and emollient and is disclosed in International Cosmetic Dictionary and Handbook the 1st and 2 volumes, editor Wenninger, and G.N.McEwen J.A., Cosmetic, Toiletry, and Fragrance Association, Washington DC, other similar components in 2000, described document is by reference in this merging.
Might not to be that the pigment of one of above-mentioned goniochromatic pigment is interpreted as meaning inorganic or organic, white or colored particles.The stain that can use in the practice of disclosure can comprise pigment, color lake and dyestuff, it is well-known in the art, and is disclosed in Cosmetic Ingredient Handbook, the 1st edition, J.M.Nikitakis, Deng people, Cosmetic, Toiletry, and Fragrance Association, Washington DC, in 1988, its content is by reference in this merging.Depend on the application about compositions, can add pigment, to provide color or without color.
Other embodiments can relate to the present composition with filler, Concha Margaritifera etc., with quality and matt or the glossiness outward appearance of modifying composition.Filler is interpreted as meaning laminar or non-laminar, inorganic or synthetic, colourless or white particle.Concha Margaritifera is interpreted as meaning particularly to produce or synthetic iris granule by the specific Mollusca in its shell.Can comprise any other pearling agent that Muscovitum, ferrum oxide, titanium dioxide and cosmetic field are known for the pearling agent in the practice of disclosure.Such as muffin compositions prototype of the filler being used alone or in combination and the non-limitative example of microsphere comprises: Talcum, corn starch nylon powder, polymethyl methacrylate, politef, zinc stearate, boron nitride, calcium silicates etc.
The compound that is generally used for prevention or minimizing fungus, antibacterial or growth of microorganism in cosmetic field also adds in the compositions of disclosure.By comprising these compounds, the pot-life of compositions is extended.These antifungal or antimicrobial include but not limited to methyl parahydroxybenzoate, butyl p-hydroxybenzoate, dehydro sodium acetate etc.The amount of these antifungal or antimicrobial composition can the component of the negative effect present composition or the amount of required effect effectively to reduce growth.
Those skilled in the art select optional other compound and/or its quantity by careful by this way certainly, thereby make the interpolation infringement not being conceived to according to the favourable character of the compositions of disclosure or the interpolation infringement not substantially being conceived to.But these materials add in the preparation of disclosure to strengthen in the spreadability of product and the embodiment of emollient therein, preferably above-mentioned material exists with enough low concentration, retains its required character for preparation.These compositions can differently be selected by those skilled in the art, so that preparation has the compositions of required character, and for example compositions intensity, true color optical effect and be relatively equivalent to several minutes approximately 115 DEG C or solution temperatures still less with a few hours.Can also adjust the selection of other composition and concentration thereof, to change required character.In one embodiment, can add aromatic for surperficial object, for example, to make the present composition to consumer's more attractive.
This technology and the present composition can be applicable to extensively various anhydrous and powder product, include but not limited to: vanishing cream, concealer, mascara, rouge, eyeliner, eye shadow, face or health powder and for example sunscreen of skin nursing products and insect repellent.Especially, the compositions of disclosure can comprise cosmetic formulations.An embodiment of disclosure relates to cosmetics vanishing cream, and wherein, except the compositions of disclosure, the preparation of cosmetics vanishing cream can also contain to provide the other thickening agent and the emollient that cover and reach the amount of other required character.
A further embodiment of disclosure comprises the lotion or the bar composition that comprise reflector, absorbent or ultraviolet filter, so that tanned lotion or sunscreen to be provided.The instrument that facilitates that carries sunscreen is in solid stick preparation.Bar-shaped preparation is avoided the shortcoming of lotion.
The another one embodiment of disclosure comprises eyeliner and eye shadow product.For example, when disclosed compositions is now together with goniochromatic pigment, the eyeliner of the compositions of employing disclosure and eye shadow can provide the color variations of increase.
The present composition is packaged into for example test kit or manufactures in article and for the application apparatus of any embodiment of disclosure, selected and manufacture, and adapted to according to the character of compositions to be packaged by those skilled in the art based on its general knowledge.In addition, type of device to be used can particularly its viscosity be associated especially with the denseness of compositions; It can also depend on the character of the constituent existing in compositions, the existence of for example volatile compound.Test kit or manufacture article can include but not limited to the present composition, for applying the device of the present composition, about the purposes of the present composition and the description of application, composition list and/or warning etc.Preferably manufacturing article is present bar composition that.
The content of all patents, patent application, disclosed PCT application and paper, books, list of references, reference manual and the summary of quoting herein by reference entirety merges at this, more fully to describe the relevant technological level of disclosure.
Do not deviate from the scope and spirit of present disclosure because multiple change can make in above-mentioned theme, thus expect contain in above-mentioned description or accessory claim in all themes of defining should be interpreted as the description of present disclosure and illustrate.Many amendments of present disclosure and variation are possible according to instruction above.
Embodiment
Following embodiment further describes and confirms the embodiment in the scope of present disclosure.Embodiment only provides for illustrative purposes, and should not be construed as the restriction of present disclosure, because its many variations are possible and do not deviate from the spirit and scope of disclosure.Following exemplary composition only provides as an example, and never expection is the restriction of disclosure scope.
Embodiment 1
Transparent or semitransparent bar composition
Use rotor-stator High shear device by all the components of qualification in table 2 the temperature of approximately 115 DEG C with about 500-10, the speed of 000rpm is mixed about 5-approximately 15 minutes, or until obtains clear solution.Although can use " routine " blender of low shearing, process will spend the longer time.In clear solution impouring mould, to form transparent or semitransparent bar composition.
Table 2
Composition | Percentage by weight (%) |
EB-21 | 6.00 |
GP-1 | 9.00 |
Octyldodecanol | 85.00 |
Embodiment 2
Transparent or semitransparent bar composition
Use rotor-stator High shear device by all the components of qualification in table 3 the temperature of approximately 115 DEG C with about 500-10, the speed of 000rpm is mixed about 5-approximately 15 minutes, or until obtains clear solution.In clear solution impouring mould, to form transparent or semitransparent bar composition.
Table 3
Composition | Percentage by weight (%) |
Dibutyl ethyl hexyl acyl group glutamine | 2.00 |
Dibutyl lauroyl glutamine | 3.00 |
Octyldodecanol | 28.00 |
Parleam | 38.95 |
Ethylenediamine hydrogenation dimerization dilinoleic acid ester copolymer Bis-Di-C14-18 alkylamide | 15.80 |
Stearyl simethicone | 5.00 |
BHT | 0.25 |
Ethylhexyl methoxy cinnamate | 7.00 |
Embodiment 3
Prepare the method for transparent or semitransparent bar composition
In order to obtain transparent or semitransparent compositions, by combination of components, thus the temperature that makes solution temperature and gelation temperature conventionally find or expect lower than the feature based on indivedual components.The also much shorter of time of components dissolved and formation gel, is equivalent to several minutes to a few hours (batch size is from 100 grams to 2 kilograms).
The mixture of table 2 is heated to the about 5-of temperature approximately 15 minutes of 115 DEG C, or until obtains clear solution.By the preheated mixture of obtained gel concentrate and oil or polymer and other optional components as shown in Table 4 below for example antioxidant, sunscreen and aromatic combination.
Table 4
Composition | Percentage by weight (%) |
The gel concentrate of table 2 | 20-30 |
Alkyl-dimethyl silicone oil | 5-25 |
Polyamide | 5-25 |
Oil | 40-70 |
Antioxidant | 0.01-0.5 |
Sunscreen | 5-7 |
Aromatic | 0-0.5 |
The preparation of obtained fusing is cast in mould, and at approximately-10 DEG C of-Yue 40 DEG C of cooling about 3-10 minute of temperature, to form the transparent or semitransparent bar composition of disclosure.
The compositions of listing in table 5 is the non-limitative example of coloured composition, its can be independently or as the in the situation that of centronucleus lip pomade the part as heterogeneous product use.The compositions of wherein listing in table 5 is served as kernel, and the compositions of table 3 serves as shell, thereby produces formula, in formula, causes by the visible kernel of shell.In this case, preferably use the coloring agent by fluoropolymer polymer processing, with the gamut that suppresses to fill a prescription in transparent outer cover from kernel.
Table 5
Composition | Percentage by weight (%) |
Parleam | 11.70 |
Two isooctadecanol malates | 5.00 |
The sub-oleyl alcohol dimerization of dimerization dilinoleic acid ester | 5.00 |
Stearyl simethicone (MP:28.5-31.0) | 3.60 |
Ethylhexyl methoxy cinnamate | 5.00 |
Tocopherol acetas-SYN | 0.70 |
Octyldodecanol | 17.00 |
Dibutyl ethyl hexyl acyl group glutamine | 1.50 |
Dibutyl lauroyl glutamine | 2.20 |
Ethylenediamine hydrogenation dimerization dilinoleic acid ester copolymer Bis-Di-C14-18 alkylamide | 11.00 |
Parleam/gellant/BHT | 13.00 |
TIT.DIOXIDE/TITANATE TRTD | 1.95 |
D&C RED NO.7-99.2%/FLUORO-SILANE TRTD. | 5.85 |
IRON OXIDES-RED ISOPROP.TIT.TRIISOST.(ITT)TRTD. | 5.20 |
CLOISONNE BLUE FLAMBE#650Z | 4.50 |
TIMICA EXTRA Bright 1500 | 4.80 |
SILICA 2-20MICRO SPHERE MSS 500/3 | 2.00 |
Claims (18)
1. lip pomade; it comprises the translucent shell around painted kernel; thereby making described kernel is visible by described shell; wherein said shell and kernel comprise: N-lauroyl-Pidolidone dibutyl amide, N-2-ethyl hexyl acyl group-Pidolidone dibutyl amide, octyldodecanol, Parleam, ethylenediamine hydrogenated dimer dilinoleic acid ester copolymer Bi s-Di-C14-18 alkylamide and stearyl simethicone, wherein said lip pomade have or lower than the solution temperature of 115 DEG C.
2. the lip pomade of claim 1, wherein said N-2-ethyl hexyl acyl group-Pidolidone dibutyl amide and N-lauroyl-Pidolidone dibutyl amide are taking scope as 1: 3-3: 1 weight ratio exists.
3. the lip pomade of claim 1, wherein said N-2-ethyl hexyl acyl group-Pidolidone dibutyl amide and N-lauroyl-Pidolidone dibutyl amide exist with the weight ratio of 1: 1.
4. the lip pomade of claim 1, the amount of wherein said octyldodecanol taking scope as described total composition 0.1 % by weight-30 % by weight.
5. the lip pomade of claim 1, it further comprises at least one antioxidant.
6. the lip pomade of claim 5, wherein said antioxidant is butylated hydroxytoluene.
7. the lip pomade of claim 1, it further comprises coloring agent.
8. the lip pomade of claim 7, described coloring agent is: pigment, dyestuff, goniochromatic coloring agent, aluminum salt, pearl oyster agent, glitter or its combination.
9. the lip pomade of claim 8, the amount of described goniochromatic coloring agent taking scope as described total composition 0.5 % by weight-5.0 % by weight.
10. the lip pomade of claim 8, described aluminum salt is aluminum color lake.
The lip pomade of 11. claim 8, described glitter is the polyester sheet of holographic relief, vacuum metallization processes.
The lip pomade of 12. claim 8, described coloring agent is to carry out surface-treated with the combination of fluoropolymer polymer or fluoropolymer polymer.
The lip pomade of 13. claim 11, the amount of polyester sheet described holographic relief, vacuum metallization processes to be less than 2% by the weighing scale of described total composition.
Prepare the method for any one lip pomade in claim 1-13 for 14. 1 kinds, it comprises:
Mix and comprise following component:
N-2-ethyl hexyl acyl group-Pidolidone dibutyl amide, N-lauroyl-Pidolidone dibutyl amide, octyldodecanol, Parleam, ethylenediamine hydrogenated dimer dilinoleic acid ester copolymer Bi s-Di-C14-18 alkylamide and stearyl simethicone; With
Dissolve described component 115 DEG C or lower temperature, thereby produce transparent or semitransparent compositions.
The method of 15. claim 14; wherein first blending ingredients N-2-ethyl hexyl acyl group-Pidolidone dibutyl amide, N-lauroyl-Pidolidone dibutyl amide and octyldodecanol; and 115 DEG C or lower heating, be the interpolation of described ethylenediamine hydrogenated dimer dilinoleic acid ester copolymer Bi s-Di-C14-18 alkylamide, stearyl simethicone and Parleam subsequently.
The method of 16. claim 14, the mixture of wherein said dissolved constituent forms viscous gel, semisolid or solid composite.
The method of 17. claim 16, it further comprises the mixture of described fusing is cast in mould, and can in several minutes, take out, and described mold part is not had to structure or visual defects.
The method of 18. claim 14, it further comprises the composition that interpolation is other: antioxidant, compositions strengthening composition, coloring agent, aromatic, hidroschesis active matter, deodorant activities thing, ultraviolet filter material, antifungal compound, Antimicrobe compound or its combination.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2011/031207 WO2012138326A1 (en) | 2011-04-05 | 2011-04-05 | Clear or translucent composition |
US13/080,034 US20110182834A1 (en) | 2009-12-17 | 2011-04-05 | Clear or Translucent Composition |
US13/080,034 | 2011-04-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102811697A CN102811697A (en) | 2012-12-05 |
CN102811697B true CN102811697B (en) | 2014-10-15 |
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CN201180008653.9A Expired - Fee Related CN102811697B (en) | 2011-04-05 | 2011-04-05 | Clear or Translucent Composition |
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US (1) | US20110182834A1 (en) |
EP (1) | EP2694013B1 (en) |
JP (1) | JP5877892B2 (en) |
CN (1) | CN102811697B (en) |
AR (1) | AR080909A1 (en) |
BR (1) | BR112012014967A8 (en) |
CA (1) | CA2785977A1 (en) |
HK (1) | HK1173663A1 (en) |
MX (1) | MX354166B (en) |
TW (1) | TWI512049B (en) |
WO (1) | WO2012138326A1 (en) |
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-
2011
- 2011-04-05 CA CA2785977A patent/CA2785977A1/en not_active Abandoned
- 2011-04-05 CN CN201180008653.9A patent/CN102811697B/en not_active Expired - Fee Related
- 2011-04-05 BR BR112012014967A patent/BR112012014967A8/en not_active Application Discontinuation
- 2011-04-05 MX MX2012007029A patent/MX354166B/en active IP Right Grant
- 2011-04-05 JP JP2014503635A patent/JP5877892B2/en not_active Expired - Fee Related
- 2011-04-05 EP EP11849905.2A patent/EP2694013B1/en not_active Not-in-force
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- 2011-04-05 US US13/080,034 patent/US20110182834A1/en not_active Abandoned
- 2011-04-11 TW TW100112512A patent/TWI512049B/en not_active IP Right Cessation
- 2011-04-14 AR ARP110101289A patent/AR080909A1/en active IP Right Grant
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2013
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MX354166B (en) | 2018-02-15 |
US20110182834A1 (en) | 2011-07-28 |
TW201241093A (en) | 2012-10-16 |
MX2012007029A (en) | 2012-11-22 |
JP5877892B2 (en) | 2016-03-08 |
WO2012138326A1 (en) | 2012-10-11 |
BR112012014967A8 (en) | 2018-06-19 |
EP2694013A4 (en) | 2014-12-24 |
CN102811697A (en) | 2012-12-05 |
JP2014510136A (en) | 2014-04-24 |
CA2785977A1 (en) | 2012-10-05 |
HK1173663A1 (en) | 2013-05-24 |
TWI512049B (en) | 2015-12-11 |
EP2694013B1 (en) | 2018-07-18 |
EP2694013A1 (en) | 2014-02-12 |
AR080909A1 (en) | 2012-05-16 |
BR112012014967A2 (en) | 2016-04-05 |
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