JP6859078B2 - Stick-like oily solid cosmetics - Google Patents
Stick-like oily solid cosmetics Download PDFInfo
- Publication number
- JP6859078B2 JP6859078B2 JP2016220380A JP2016220380A JP6859078B2 JP 6859078 B2 JP6859078 B2 JP 6859078B2 JP 2016220380 A JP2016220380 A JP 2016220380A JP 2016220380 A JP2016220380 A JP 2016220380A JP 6859078 B2 JP6859078 B2 JP 6859078B2
- Authority
- JP
- Japan
- Prior art keywords
- outer layer
- layer portion
- polyglyceryl
- inner layer
- stick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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Images
Landscapes
- Cosmetics (AREA)
Description
本発明は、互いに接する透明な外層部と着色した内層部を有する審美性が高く、滑らかな使用感に優れるスティック状油性固形化粧料に関する。 The present invention relates to a stick-shaped oil-based solid cosmetic having a transparent outer layer portion and a colored inner layer portion in contact with each other, which are highly aesthetically pleasing and have an excellent smooth usability.
油性固形化粧料は、***化粧料、目元化粧料、香料組成物等の化粧料として広く用いられている。化粧料としては、様々な色調や質感を付与する目的で用いられ、ツヤや透明感、着色のよさ等の化粧効果、二次付着しにくい等の機能性に加え、化粧を行うことの楽しさに繋がる化粧料自体の外観の美しさも求められている。このような外観の美しさを特徴とする化粧料の技術も多く提案されている。例えば、上面にすり鉢状の凹部を有する透明な化粧料層を形成し、その上に異なる色に着色された化粧料を積層し、グラデーション模様を有する多色化粧品が提案されており（特許文献１）、略柱状の内芯部の横周辺面全体を外層部で覆ってスティック状とした多重構造を有するスティック状***化粧料が検討・実施されている（特許文献２）。 Oil-based solid cosmetics are widely used as cosmetics such as lip cosmetics, eye cosmetics, and fragrance compositions. As a cosmetic, it is used for the purpose of imparting various color tones and textures, and in addition to cosmetic effects such as gloss, transparency, good coloring, and functionality such as resistance to secondary adhesion, it is fun to apply makeup. The beauty of the appearance of the cosmetics themselves, which leads to the above, is also required. Many cosmetic techniques characterized by such a beautiful appearance have also been proposed. For example, a multicolored cosmetic having a gradation pattern has been proposed by forming a transparent cosmetic layer having a mortar-shaped recess on the upper surface and laminating cosmetics colored in different colors on the transparent cosmetic layer (Patent Document 1). ), Stick-shaped lip cosmetics having a multi-layered structure in which the entire lateral peripheral surface of the substantially columnar inner core portion is covered with an outer layer portion to form a stick shape have been studied and implemented (Patent Document 2).
しかしながら、上記特許文献１の多色化粧品は上下方向に積層されている為、異なる色の化粧料を同時に使用するためには多層形状を崩さなければならない。また、特許文献２の技術においては、硬度の異なる内層部と外層部を用いて多重構造スティック化粧料を得ているが、外層部が透明なものは検討されていなかった。 However, since the multicolored cosmetics of Patent Document 1 are laminated in the vertical direction, the multi-layered shape must be broken in order to use cosmetics of different colors at the same time. Further, in the technique of Patent Document 2, a multi-structure stick cosmetic is obtained by using an inner layer portion and an outer layer portion having different hardness, but a transparent outer layer portion has not been studied.
本発明の課題は、透明な外層部と着色した内層部を有することで審美性を高めたスティック状油性固形化粧料であり、透明な外層部と着色した内層部の境界面が明瞭であり、滑らかな使用感に優れるスティック状油性固形化粧料を提供するものである。 An object of the present invention is a stick-like oil-based solid cosmetic having a transparent outer layer portion and a colored inner layer portion to enhance aesthetics, and the boundary surface between the transparent outer layer portion and the colored inner layer portion is clear. It provides a stick-shaped oily solid cosmetic having an excellent smooth feel.
本発明者らは、上記課題に鑑み、鋭意研究を行った結果、互いに接する透明な外層部と着色した内層部を有するスティック状油性固形化粧料において、外層部にワックスのように常温で固化した際に白色化せず、透明性の高いゲルを作ることができるアミノ酸系ゲル化剤を用いることで外層部の透明性により優れ、炭素数２０〜２６の分岐状高級アルコールを組み合わせることで、本願効果が顕著に得られることを見出し、本発明を完成させるに至った。 In view of the above problems, the present inventors conducted diligent research, and as a result, in a stick-shaped oily solid cosmetic having a transparent outer layer portion and a colored inner layer portion in contact with each other, the outer layer portion was solidified at room temperature like wax. By using an amino acid-based gelling agent that does not whiten and can make a highly transparent gel, the transparency of the outer layer is improved, and by combining a branched higher alcohol having 20 to 26 carbon atoms, the present application We have found that a remarkable effect can be obtained, and have completed the present invention.
すなわち本発明は、互いに接する透明な外層部と着色した内層部を有し、外層部に少なくともジブチルエチルヘキサノイルグルタミド、ジブチルラウロイルグルタミド、（ビスジアルキル（Ｃ１４−１８）アミド（エチレンジアミン／水添ダイマージリノール酸）コポリマーから選ばれる一種または二種以上である（Ａ）アミノ酸系ゲル化剤と、（Ｂ）炭素数２０〜２６の分岐状高級アルコールと、デカイソステアリン酸ポリグリセリル−１０、デカエチルヘキサン酸ポリグリセリル−１０、ジイソステアリン酸ポリグリセリル−１０、ジステアリン酸ポリグリセリル−１０、ノナイソステアリン酸ポリグリセリル−１０、ポリリシノレイン酸ポリグリセリル−６から選ばれる一種または二種以上である成分（Ｃ）グリセリンの重合度が６〜１２であり、脂肪酸が炭素数８〜２２の分岐脂肪酸であるポリグリセリン脂肪酸エステルと、を含有し、前記成分（Ａ）の前記外層部における含有量が、１〜３０質量％であり、前記成分（Ｂ）の前記外層部における含有量が、５〜５０質量％であり、前記成分（Ｃ）の前記外層部における含有量が、５〜４０質量％である、スティック状油性固形化粧料を提供するものである。
また、本発明は、互いに接する透明な外層部と着色した内層部を有し、外層部に少なくともジブチルエチルヘキサノイルグルタミド、ジブチルラウロイルグルタミド、（ビスジアルキル（Ｃ１４−１８）アミド（エチレンジアミン／水添ダイマージリノール酸）コポリマーから選ばれる一種または二種以上である成分（Ａ）アミノ酸系ゲル化剤と、成分（Ｂ）デシルテトラデカノールと、デカイソステアリン酸ポリグリセリル−１０、デカエチルヘキサン酸ポリグリセリル−１０、ジイソステアリン酸ポリグリセリル−１０、ジステアリン酸ポリグリセリル−１０、ノナイソステアリン酸ポリグリセリル−１０、ポリリシノレイン酸ポリグリセリル−６から選ばれる一種または二種以上である成分（Ｃ）グリセリンの重合度が６〜１２であり、脂肪酸が炭素数８〜２２の分岐脂肪酸であるポリグリセリン脂肪酸エステルと、を含有する、スティック状油性固形化粧料を提供するものである。
That is, the present invention has a transparent outer layer portion in contact with each other and a colored inner layer portion, and at least dibutylethylhexanoylglutamide, dibutyllauroylglutamide, (bisdialkyl (C14-18) amide (ethylenediamine / hydrogenated)) are provided in the outer layer portion. One or more of (A) amino acid-based gelling agents selected from dimer dilinoleic acid) copolymers, (B) branched higher alcohols having 20 to 26 carbon atoms , polyglyceryl-10 decaisostearate, and decaethyl. The degree of polymerization of (C) glycerin, which is one or more selected from polyglyceryl hexanoate-10, polyglyceryl diisostearate-10, polyglyceryl distearate-10, polyglyceryl nonaisostearate-10, and polyglyceryl-6 polylysinoleate, is It contains a polyglycerin fatty acid ester which is 6 to 12 and whose fatty acid is a branched fatty acid having 8 to 22 carbon atoms, and the content of the component (A) in the outer layer portion is 1 to 30% by mass. A stick-like oily solid cosmetic having a content of the component (B) in the outer layer portion of 5 to 50% by mass and a content of the component (C) in the outer layer portion of 5 to 40% by mass. Is to provide.
Further, the present invention has a transparent outer layer portion and a colored inner layer portion in contact with each other, and at least dibutylethylhexanoylglutamide, dibutyllauroylglutamide, (bisdialkyl (C14-18) amide (ethylenediamine / water)) are provided in the outer layer portion. One or more of the components (A) amino acid-based gelling agents selected from the (added dimer dinolic acid) copolymer , the component (B) decyltetradecanol, polyglyceryl -10 decaisostearate, and polyglyceryl decaethylhexanoate. One or more components selected from -10, polyglyceryl diisostearate-10, polyglyceryl distearate-10, polyglyceryl nonaisostearate-10, and polyglyceryl-6 polylysinoleate. (C) The degree of polymerization of glycerin is 6-12. , and the fatty acid contains a polyglycerol fatty acid ester is a branched fatty acid having 8 to 22 carbon atoms, there is provided a stick oily solid cosmetic.
さらに、内層部の溶解温度が外層部の溶解温度よりも１０℃以上低いスティック状油性固形化粧料を提供するものである。 Further, the present invention provides a stick-shaped oily solid cosmetic in which the melting temperature of the inner layer portion is lower than the melting temperature of the outer layer portion by 10 ° C. or more.
本発明のスティック状油性固形化粧料は、透明な外層部と着色した内層部を有することで審美性を高めたものであり、透明な外層部と着色した内層部の境界面が明瞭で、しかも滑らかな使用感に優れるものである。 The stick-shaped oily solid cosmetic of the present invention has a transparent outer layer portion and a colored inner layer portion to enhance aesthetics, and the boundary surface between the transparent outer layer portion and the colored inner layer portion is clear, and moreover. It has an excellent smooth feel.
本発明のスティック状油性固形化粧料は油性固形組成物（内層部）と油性固形組成物（外層部）を組み合わせてなる。内層部と外層部は互いに接し、スティックの長軸方向に連続した内層部を外層部が覆うように成型されていれば、内層部及び外層部の形状は特に限定されず、例えば、短軸方向の横断面が円形、四角形、星形等でも良い。 The stick-shaped oily solid cosmetic of the present invention comprises a combination of an oily solid composition (inner layer portion) and an oily solid composition (outer layer portion). As long as the inner layer portion and the outer layer portion are in contact with each other and the outer layer portion is molded so as to cover the inner layer portion continuous in the long axis direction of the stick, the shapes of the inner layer portion and the outer layer portion are not particularly limited, for example, in the minor axis direction. The cross section of the above may be circular, quadrangular, star-shaped, or the like.
本発明における外層部に関する説明を以下に示す。 A description of the outer layer portion in the present invention is shown below.
本発明に用いられる成分（Ａ）のアミノ酸系ゲル化剤は、分子中にアミド結合を有し、油剤を固化するものである。本発明に用いられる成分（Ａ）は、通常化粧料に用いられるものであれば、特に制限されず使用することができる。具体的には、ジブチルエチルヘキサノイルグルタミド、ジブチルラウロイルグルタミド、（ビスジアルキル（Ｃ１４−１８）アミド（エチレンジアミン／水添ダイマージリノール酸）コポリマー等から選ばれる一種または二種以上が好適に用いられる。市販品としては、アミノ酸系油ゲル化剤ＥＢ−２１（味の素社製、融点１８３〜１９６℃）、アミノ酸系油ゲル化剤ＧＰ−１（味の素社製、融点１５０〜１６１℃）等が挙げられる。 The amino acid-based gelling agent of the component (A) used in the present invention has an amide bond in the molecule and solidifies the oil agent. The ingredient (A) used in the present invention can be used without particular limitation as long as it is usually used in cosmetics. Specifically, one or more selected from dibutylethylhexanoylglutamide, dibutyllauroylglutamide, (bisdialkyl (C14-18) amide (ethylenediamine / hydrogenated dimer dilinoleic acid) copolymer and the like) are preferably used. Commercially available products include amino acid-based oil gelling agent EB-21 (manufactured by Ajinomoto Co., Ltd., melting point 183 to 196 ° C.), amino acid-based oil gelling agent GP-1 (manufactured by Ajinomoto Co., Ltd., melting point 150 to 161 ° C.), and the like. Can be mentioned.
本発明に用いられる成分（Ａ）の外層部における含有量は、特に限定されないが、好ましくは１〜３０質量％（以下％と略す）、より好ましくは５〜２０％である。この範囲であると、内層部が外から透けて見える透明性と油剤を固化する成形性の点からより好ましい。 The content of the component (A) used in the present invention in the outer layer portion is not particularly limited, but is preferably 1 to 30% by mass (hereinafter abbreviated as%), and more preferably 5 to 20%. This range is more preferable from the viewpoint of transparency in which the inner layer portion can be seen through from the outside and moldability for solidifying the oil agent.
本発明に用いられる成分（Ｂ）炭素数２０〜２６の分岐状高級アルコールは、通常化粧料に用いられるものであれば、特に制限されず使用することができ、２５℃で液状のものが望ましい。具体的には、オクチルドデカノール、デシルテトラデカノール等が好適に用いられる。市販品としては、リソノール２０ＳＰ、リソノール２４ＳＰ（高級アルコール工業社製）、エヌジェコール２００Ａ、エヌジェコール２４０Ａ（新日本理化社製）等が挙げられる。 The component (B) branched higher alcohol having 20 to 26 carbon atoms used in the present invention can be used without particular limitation as long as it is usually used for cosmetics, and a liquid alcohol at 25 ° C. is desirable. .. Specifically, octyldodecanol, decyltetradecanol and the like are preferably used. Examples of commercially available products include Lysonol 20SP, Lysonol 24SP (manufactured by Higher Alcohol Industry Co., Ltd.), Njecor 200A, Njecor 240A (manufactured by New Japan Chemical Co., Ltd.) and the like.
本発明に用いられる成分（Ｂ）の外層部における含有量は、特に限定されないが、好ましくは５〜５０％、より好ましくは１０〜４０％である。この範囲であると、滑らかな使用感の観点からより好ましい。また、本発明の成分（Ａ）と成分（Ｂ）を組み合わせることで混合物の溶解温度を下げることができるという知見を得ており、製造時の操作性を向上させることに利用できる。 The content of the component (B) used in the present invention in the outer layer portion is not particularly limited, but is preferably 5 to 50%, more preferably 10 to 40%. This range is more preferable from the viewpoint of smooth usability. Further, it has been found that the dissolution temperature of the mixture can be lowered by combining the component (A) and the component (B) of the present invention, and it can be used to improve the operability during production.
本発明の外層部は成分（Ａ）と成分（Ｂ）を必須成分とし、さらに成分（Ｃ）を含有することができ、成分（Ｃ）を含有することで滑らかな使用感により優れ好ましい。 The outer layer portion of the present invention contains the component (A) and the component (B) as essential components, and can further contain the component (C). By containing the component (C), the smooth feeling of use is excellent and preferable.
本発明に用いられる成分（Ｃ）グリセリンの重合度が６〜１２であり、脂肪酸が炭素数８〜２２の分岐脂肪酸であるポリグリセリン脂肪酸エステルは、通常化粧料に用いられるものであれば、特に制限されず使用することができる。具体的には、デカイソステアリン酸ポリグリセリル-１０、デカエチルヘキサン酸ポリグリセリル−１０、 ジイソステアリン酸ポリグリセリル−１０、ジステアリン酸ポリグリセリル−１０、ノナイソステアリン酸ポリグリセリル−１０、ポリリシノレイン酸ポリグリセリル−６等が挙げられる。市販品としては、ＩＳ−１００５Ｐ、ＩＳ−１００９Ｐ、ＣＲ−１００１（阪本薬品工業社製）、ＮＩＫＫＯＬ Ｄｅｃａｇｌｙｎ １０−ＩＳＶ（日光ケミカルズ社製）等が挙げられる。 The polyglycerin fatty acid ester in which the degree of polymerization of the component (C) glycerin used in the present invention is 6 to 12 and the fatty acid is a branched fatty acid having 8 to 22 carbon atoms is particularly suitable as long as it is usually used in cosmetics. It can be used without restrictions. Specific examples thereof include polyglyceryl decaisostearate-10, polyglyceryl decaethylhexanoate-10, polyglyceryl diisostearate-10, polyglyceryl distearate-10, polyglyceryl nonaisostearate-10, and polyglyceryl-6 polylysinorainate. Examples of commercially available products include IS-1005P, IS-1009P, CR-1001 (manufactured by Sakamoto Pharmaceutical Co., Ltd.), NIKKOL Decaglin 10-ISV (manufactured by Nikko Chemicals Co., Ltd.) and the like.
本発明に用いられる成分（Ｃ）の外層部における含有量は、特に限定されないが、好ましくは５〜５０％、より好ましくは１０〜４０％である。この範囲であると、滑らかな使用感の観点から好ましい。 The content of the component (C) used in the present invention in the outer layer portion is not particularly limited, but is preferably 5 to 50%, more preferably 10 to 40%. This range is preferable from the viewpoint of smooth usability.
本発明の外層部は前記成分（Ａ）〜（Ｃ）の他に、本発明の効果を損なわない範囲で、成分（Ａ）〜（Ｃ）以外の油性成分、粉体、界面活性剤、水性成分、紫外線吸収剤、保湿剤、酸化防止剤、美容成分、防腐剤、色素、香料等の通常公知の成分を含有することができる。 In addition to the above components (A) to (C), the outer layer portion of the present invention contains oily components other than the components (A) to (C), powders, surfactants, and aqueous components as long as the effects of the present invention are not impaired. It can contain commonly known ingredients such as ingredients, UV absorbers, moisturizers, antioxidants, cosmetological ingredients, preservatives, pigments and fragrances.
成分（Ａ）〜（Ｃ）以外の油性成分としては動物油、植物油、合成油等の起源の固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類等が挙げられる。具体的には、流動パラフィン、スクワラン、ポリイソブチレン、ポリブテン等の炭化水素類、オリーブ油、ヒマシ油、ミンク油、マカデミアンナッツ油等の油脂類、ホホバ油、２−エチルヘキサン酸セチル、乳酸イソステアリル、乳酸オクチルドデシル、乳酸オレイル、乳酸ステアリル、リンゴ酸ジイソステアリル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、ロジン酸ペンタエリトリットエステル、ジオクタン酸ネオペンチルグリコール、ジオクタン酸ネオペンチルグリコール、コレステロール脂肪酸エステル、フィトステロール脂肪酸エステル等のエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、ベヘニン酸、イソステアリン酸、オレイン酸等の脂肪酸類、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、ジメチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、オクタメチルシクロテトラシロキサン、トリメチルシロキシケイ酸、高重合度メチルフェニルポリシロキサン、架橋型メチルポリシロキサン、ポリオキシ変性オルガノポリシロキサン、架橋型ポリエーテル変性メチルポリシロキサン、メタクリル変性ポリシロキサン、ステアリル変性メチルポリシロキサン、オレイル変性メチルポリシロキサン、ベヘニル変性メチルポリシロキサン、ポリビニルピロリドン変性メチルポリシロキサン、高重合度ジメチルポリシロキサン、ポリオキシアルキレン・アルキルメチルポリシロキサン・メチルポリシロキサン共重合体、アルコキシ変性ポリシロキサン、架橋型オルガノポリシロキサン、フッ素変性ポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール等のラノリン誘導体等が挙げられ、これらを一種又は二種以上を用いることができる。 Oily components other than the components (A) to (C) include hydrocarbons and fats and oils regardless of the properties of solid oils, semi-solid oils, liquid oils, volatile oils and the like originating from animal oils, vegetable oils, synthetic oils and the like. , Hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorooils, lanolin derivatives and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, polyisobutylene, and polybutene, fats and oils such as olive oil, castor oil, mink oil, and macadamian nut oil, jojoba oil, cetyl 2-ethylhexaneate, and isostearyl lactate. , Octyldodecyl lactic acid, oleyl lactate, stearyl lactic acid, diisostearyl malate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, pentaerythrite rosinate, neopentyl glycol dioctanoate, neopentyl glycol dioctanoate, cholesterol Esters such as fatty acid esters and phytosterol fatty acid esters, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid and oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol and behenyl alcohol. Higher alcohols such as, dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, trimethylsiloxysilicate, highly polymerizable methylphenylpolysiloxane, crosslinked methylpolysiloxane, polyoxy-modified organopoly Siloxane, crosslinked polyether-modified methylpolysiloxane, methacryl-modified polysiloxane, stearyl-modified methylpolysiloxane, oleyl-modified methylpolysiloxane, behenyl-modified methylpolysiloxane, polyvinylpyrrolidone-modified methylpolysiloxane, high-polymerization degree dimethylpolysiloxane, polyoxy Silicones such as alkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymers, alkoxy-modified polysiloxanes, crosslinked organopolysiloxanes, fluorine-modified polysiloxanes, and fluorine-based products such as perfluorodecane, perfluorooctane, and perfluoropolyether. Examples thereof include oils, lanolin, lanolin acetate, lanolin derivatives such as lanolin fatty acid isopropyl and lanolin alcohol, and one or more of these can be used.
粉体としては、化粧料に一般に使用される粉体であれば、球状、板状、針状等の形状、煙霧状、微粒子、顔料級等の粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、金属粉体類、複合粉体類等が挙げられる。具体的に例示すれば、酸化チタン、酸化亜鉛、酸化セリウム、硫酸バリウム等の白色無機顔料、酸化鉄、カーボンブラック、チタン・酸化チタン焼結物、酸化クロム、水酸化クロム、紺青、群青等の有色無機顔料、タルク、白雲母、金雲母、紅雲母、黒雲母、合成雲母、絹雲母（セリサイト）、合成セリサイト、カオリン、炭化珪素、ベントナイト、スメクタイト、無水ケイ酸、酸化アルミニウム、酸化マグネシウム、酸化ジルコニウム、珪ソウ土、ケイ酸アルミニウム、メタケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、窒化ホウ素等の白色体質粉体、二酸化チタン被覆雲母、二酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、オキシ塩化ビスマス、魚鱗箔、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリオレフィン積層フィルム末、ポリエチレンテレフタレート・ポリメチルメタクリレート積層フィルム末等の光輝性粉体、ポリアミド系樹脂、ポリエチレン系樹脂、ポリアクリル系樹脂、ポリエステル系樹脂、フッ素系樹脂、セルロース系樹脂、ポリスチレン系樹脂、スチレン−アクリル共重合樹脂等の合成樹脂、ポリプロピレン系樹脂、ウレタン樹脂等の有機高分子樹脂粉体、ステアリン酸亜鉛、Ｎ−アシルリジン等の有機低分子性粉体、シルク粉末、セルロース粉末等の天然有機粉体、赤色２０１号、赤色２０２号、赤色２０５号、赤色２２６号、赤色２２８号、橙色２０３号、橙色２０４号、青色４０４号、黄色４０１号等の有機顔料粉体、黒色４０１号、褐色２０１号、紫色４０１号、青色１号、青色２号、青色２０３号、青色２０５号、緑色３号、緑色２０１号、緑色２０４号、緑色２０５号、緑色４０１号、緑色４０２号、黄色４号、黄色５号、黄色２０２号（１）、黄色２０２号（２）、黄色２０３号、黄色４０２号、黄色４０３号の（１）、黄色４０６号、黄色４０７号、橙色２０５号、橙色４０２号、赤色２号、赤色３号、赤色１０２号、赤色１０４号（１）、赤色１０５号（１）、赤色１０６号、赤色２２７号、赤色２３０号（１）、赤色２３１号、赤色４０１号、赤色５０２号、赤色５０３号、赤色５０４号、赤色５０６号等のジルコニウム、バリウム又はアルミニウムレーキ等の有機顔料粉体、アルミニウム粉、金粉、銀粉等の金属粉体、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有二酸化珪素、酸化亜鉛含有二酸化珪素等の複合粉体、等が挙げられ、これら粉体はその一種又は二種以上を用いることができ、必要に応じて、フッ素系化合物、シリコーン系化合物、金属石鹸、レシチン、水素添加レシチン、コラーゲン、炭化水素、高級脂肪酸、高級アルコール、エステル、ワックス、ロウ、界面活性剤等を用いて、公知の方法により表面処理を施したり、さらに複合化したものを用いても良い。 As the powder, if it is a powder generally used for cosmetics, it has a spherical shape, a plate shape, a needle shape, etc., a smoke atom shape, fine particles, a pigment grade particle size, a porous particle, a non-porous particle, etc. The structure is not particularly limited, and examples thereof include inorganic powders, glittering powders, organic powders, pigment powders, metal powders, and composite powders. Specifically, for example, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered body, chromium oxide, chromium hydroxide, dark blue, ultramarine, etc. Colored inorganic pigments, talc, white mica, gold mica, red mica, black mica, synthetic mica, silk mica (serisite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, aluminum oxide, magnesium oxide , Zirconium oxide, Soil silicate, Aluminum silicate, Aluminum magnesium metasilicate, Calcium silicate, Barium silicate, Magnesium silicate, Calcium carbonate, Magnesium carbonate, Hydroxyapatite, White constitution powder such as boron nitride, Titanium dioxide coating Mica, titanium dioxide coated bismuth oxychloride, titanium oxide mica, navy blue treated mica titanium, carmine treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate・ Bright powder such as polymethylmethacrylate laminated film powder, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, styrene-acrylic copolymer resin, etc. Synthetic resin, polypropylene resin, organic polymer resin powder such as urethane resin, organic low molecular weight powder such as zinc stearate, N-acylidine, silk powder, natural organic powder such as cellulose powder, Red No. 201 , Red 202, Red 205, Red 226, Red 228, Orange 203, Orange 204, Blue 404, Yellow 401 and other organic pigment powders, Black 401, Brown 201, Purple 401 , Blue 1, Blue 2, Blue 203, Blue 205, Green 3, Green 201, Green 204, Green 205, Green 401, Green 402, Yellow 4, Yellow 5, Yellow 202 (1), Yellow 202 (2), Yellow 203, Yellow 402, Yellow 403 (1), Yellow 406, Yellow 407, Orange 205, Orange 402, Red 2, Red No. 3, Red No. 102, Red No. 104 (1), Red No. 105 (1), Red No. 106, Red No. 227, Red No. 230 (1), Red No. 231, Red No. 401, Red No. 502, Red No. 503 Zylon, barium or aluminum resin such as No., Red No. 504, Red No. 506, etc. Organic pigment powder such as key, metal powder such as aluminum powder, gold powder, silver powder, fine particle titanium oxide coated mica titanium, fine particle zinc oxide coated mica titanium, barium sulfate coated mica titanium, titanium oxide containing silicon dioxide, zinc oxide containing Examples thereof include composite powders such as silicon dioxide, and one or more of these powders can be used. If necessary, fluorine-based compounds, silicone-based compounds, metal soaps, lecithin, hydrogenated lecithin, etc. can be used. , Collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants and the like may be used for surface treatment by a known method, or a compounded product may be used.
界面活性剤としては、化粧料に一般に用いられている界面活性剤であれば、特に限定されず、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等を用いることができる。例えば、グリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ポリオキシエチレン硬化ヒマシ油、ポリオキシアルキレンアルキル共変性オルガノポリシロキサン、ポリエーテル変性オルガノポリシロキサン、レシチン等が挙げられる。 The surfactant is not particularly limited as long as it is a surfactant generally used in cosmetics, such as a nonionic surfactant, an anionic surfactant, a cationic surfactant, and an amphoteric surfactant. Can be used. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, Examples thereof include polyether-modified organopolysiloxane and lecithin.
水性成分としては、水に可溶な成分であれば何れでもよく、水の他に、例えば、エチルアルコール等のアルコール類、プロピレングリコール、１，３−ブチレングリコール、１，２−ペンタジオール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、アロエベラ、ウイッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の植物抽出液が挙げられる。 The aqueous component may be any component that is soluble in water, and in addition to water, for example, alcohols such as ethyl alcohol, propylene glycol, 1,3-butylene glycol, 1,2-pentadiol, and di. Examples thereof include glycols such as propylene glycol and polyethylene glycol, glycerols such as glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose.
紫外線吸収剤としては、例えばベンゾフェノン系、ＰＡＢＡ系、ケイ皮酸系、サリチル酸系等の紫外線吸収剤や、４−ｔｅｒｔ−ブチル−４'−メトキシジベンゾイルメタン、オキシベンゾン等が挙げられ、保湿剤としては、例えばタンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等が挙げられ、酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等が挙げられ、美容成分としては、例えばビタミン類、消炎剤、生薬等が挙げられ、防腐剤としてはパラオキシ安息香酸エステル、フェノキシエタノール等が挙げられる。 Examples of the ultraviolet absorber include benzophenone-based, PABA-based, silicic acid-based, salicylic acid-based ultraviolet absorbers, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone and the like, and examples thereof include moisturizing agents. Examples include proteins, mucopolysaccharides, collagen, elastin, keratin, etc. Antioxidants include, for example, α-tocopherol, ascorbic acid, etc., and beauty ingredients include, for example, vitamins, anti-inflammatory agents, crude drugs, etc. Examples of the preservative include paraoxybenzoic acid ester and phenoxyethanol.
本発明における透明とは、１２．５×１２．５×４５ｍｍガラスセルにサンプルを溶融充填したものを、１．５ポイント太さの黒線を書いた白い紙の上に置き、厚さ１２．５ｍｍの上から黒線が見えるものを指す。本発明の外層部は、ガラスセルの上から黒線が見えるものである。 Transparency in the present invention means that a glass cell of 12.5 × 12.5 × 45 mm is melt-filled with a sample and placed on a white paper having a black line with a thickness of 1.5 points. The black line can be seen from above 5 mm. In the outer layer portion of the present invention, a black line can be seen from above the glass cell.
本発明における内層部に関する説明を以下に示す。 A description of the inner layer portion in the present invention is shown below.
本発明の内層部は着色剤を必須成分とし、不透明であるとより好ましい。着色剤としては着色顔料や染料等が挙げられ、一般に化粧料に用いられるものであれば特に制限はなく、その形状（球状、針状、板状等）や粒子径（煙霧状、微粒子、顔料級等）、粒子構造（多孔質、無孔質等）を問わずいずれのものも使用することができる。具体的には、酸化チタン、酸化亜鉛、酸化セリウム、硫酸バリウム等の白色無機顔料、酸化鉄、カーボンブラック、チタン・酸化チタン焼結物、酸化クロム、水酸化クロム、紺青、群青等の有色無機顔料、タルク、白雲母、金雲母、紅雲母、黒雲母、合成雲母、絹雲母（セリサイト）、合成セリサイト、カオリン、炭化珪素、ベントナイト、スメクタイト、無水ケイ酸、酸化アルミニウム、酸化マグネシウム、酸化ジルコニウム、珪ソウ土、ケイ酸アルミニウム、メタケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、窒化ホウ素等の白色体質粉体、二酸化チタン被覆雲母、二酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、オキシ塩化ビスマス、魚鱗箔、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリオレフィン積層フィルム末、ポリエチレンテレフタレート・ポリメチルメタクリレート積層フィルム末等の光輝性粉体、アルミニウム粉、金粉、銀粉等の金属粉体、赤色２０１号、赤色２０２号、赤色２０５号、赤色２２６号、赤色２２８号、橙色２０３号、橙色２０４号、青色４０４号、黄色４０１号等の有機顔料粉体、黒色４０１号、褐色２０１号、紫色４０１号、青色１号、青色２号、青色２０３号、青色２０５号、緑色３号、緑色２０１号、緑色２０４号、緑色２０５号、緑色４０１号、緑色４０２号、黄色４号、黄色５号、黄色２０２号（１）、黄色２０２号（２）、黄色２０３号、黄色４０２号、黄色４０３号の（１）、黄色４０６号、黄色４０７号、橙色２０５号、橙色４０２号、赤色２号、赤色３号、赤色１０２号、赤色１０４号（１）、赤色１０５号（１）、赤色１０６号、赤色２２７号、赤色２３０号（１）、赤色２３１号、赤色４０１号、赤色５０２号、赤色５０３号、赤色５０４号、赤色５０６号等のジルコニウム、バリウム又はアルミニウムレーキ等の有機顔料粉体等が挙げられ、これら粉体はその一種又は二種以上を用いることができる。必要に応じて、フッ素系化合物、シリコーン系化合物、金属石鹸、レシチン、水素添加レシチン、コラーゲン、炭化水素、高級脂肪酸、高級アルコール、エステル、ワックス、ロウ、界面活性剤等を用いて、公知の方法により表面処理を施したり、さらに複合化したものを用いても良い。 It is more preferable that the inner layer portion of the present invention contains a colorant as an essential component and is opaque. Examples of the colorant include color pigments and dyes, and there are no particular restrictions as long as they are generally used in cosmetics, and their shapes (spherical, needle-like, plate-like, etc.) and particle diameters (smoke-like, fine particles, pigments, etc.) are not particularly limited. Any of the class and particle structure (porous, non-porous, etc.) can be used. Specifically, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, iron oxide, carbon black, titanium / titanium oxide sintered products, chromium oxide, chromium hydroxide, dark blue, ultramarine and other colored inorganic pigments. Pigments, talc, white mica, gold mica, red mica, black mica, synthetic mica, silk mica (serisite), synthetic sericite, kaolin, silicon carbide, bentonite, smectite, silicic anhydride, aluminum oxide, magnesium oxide, oxidation White constitution powders such as zirconium, silica soil, aluminum silicate, magnesium aluminum metasilicate, calcium silicate, barium silicate, magnesium silicate, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, titanium dioxide-coated mica, Titanium dioxide coated bismuth oxychloride, titanium oxide titanium oxide, dark blue treated mica titanium, carmine treated mica titanium, bismuth oxychloride, fish scale foil, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / poly Bright powder such as methyl methacrylate laminated film powder, metal powder such as aluminum powder, gold powder, silver powder, red 201, red 202, red 205, red 226, red 228, orange 203, orange 204 Organic pigment powders such as No., Blue No. 404, Yellow No. 401, Black No. 401, Brown No. 201, Purple No. 401, Blue No. 1, Blue No. 2, Blue No. 203, Blue No. 205, Green No. 3, Green No. 201 No., Green No. 204, Green No. 205, Green No. 401, Green No. 402, Yellow No. 4, Yellow No. 5, Yellow No. 202 (1), Yellow No. 202 (2), Yellow No. 203, Yellow No. 402, Yellow No. 403 No. (1), Yellow 406, Yellow 407, Orange 205, Orange 402, Red 2, Red 3, Red 102, Red 104 (1), Red 105 (1), Red 106 Organic pigment powders such as zirconium, barium or aluminum lake such as red No. 227, red No. 230 (1), red No. 231 and red 401, red 502, red 503, red 504 and red 506. Etc., and one or more of these powders can be used. Known methods using fluorine-based compounds, silicone-based compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, etc., if necessary. The surface treatment may be applied to the surface treatment, or a composite product may be used.
本発明において、着色した内層部は、特に限定されないが油剤を固形化剤で固めたものを用いることができる。固形化剤としては、ワックスやゲル化剤を含み、通常化粧料で用いられるものであれば特に限定されず用いることができる。具体的には、固体パラフィンワックス、セレシンワックス、マイクロクリスタリンワックス、エチレン・プロピレンコポリマー、フィッシャートロプシュワックス、カルナウバワックス、キャンデリラワックス、ミツロウ、モクロウ、ゲイロウ、ポリエチレンワックス、ポリプロピレンワックス、モンタンワックス、オゾケライトワックス、ライスワックス、シリコーンワックス等のワックス類、蔗糖脂肪酸エステル、デキストリン脂肪酸エステル、デンプン脂肪酸エステル、イソステアリン酸アルミニウム、１２−ヒドロキシステアリン酸、ビスジオクタデシルアミド（ダイマージリノール酸／エチレンジアミン）コポリマー等が挙げられ、これらの一種または二種以上を用いることができる。 In the present invention, the colored inner layer portion is not particularly limited, but an oil agent solidified with a solidifying agent can be used. The solidifying agent includes a wax and a gelling agent, and can be used without particular limitation as long as it is usually used in cosmetics. Specifically, solid paraffin wax, ceresin wax, microcrystallin wax, ethylene / propylene copolymer, Fishertropsh wax, carnauba wax, candelilla wax, beeswax, mokuro, gay wax, polyethylene wax, polypropylene wax, montan wax, ozoke Waxes such as light wax, rice wax, silicone wax, paraffin fatty acid ester, dextrin fatty acid ester, starch fatty acid ester, aluminum isostearate, 12-hydroxystearic acid, bisdioctadecylamide (diameridinolic acid / ethylenediamine) copolymer, etc. These can be mentioned and one or more of these can be used.
本発明の内層部は、着色剤、固形化剤の他に、本発明の効果を損なわない範囲で、固形化剤以外の油性成分、着色剤以外の粉体、界面活性剤、水性成分、紫外線吸収剤、保湿剤、酸化防止剤、美容成分、防腐剤、色素、香料等の通常公知の成分を含有することができる。 In addition to the colorant and solidifying agent, the inner layer portion of the present invention contains an oil component other than the solidifying agent, a powder other than the colorant, a surfactant, an aqueous component, and ultraviolet rays as long as the effects of the present invention are not impaired. It can contain commonly known ingredients such as absorbents, moisturizers, antioxidants, cosmetological ingredients, preservatives, pigments and fragrances.
固形化剤以外の油性成分としては動物油、植物油、合成油等の起源の固形油、半固形油、液体油、揮発性油等の性状を問わず、炭化水素類、油脂類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類等が挙げられる。具体的には、流動パラフィン、スクワラン、ポリイソブチレン、ポリブテン等の炭化水素類、オリーブ油、ヒマシ油、ミンク油、マカデミアンナッツ油等の油脂類、ホホバ油、２−エチルヘキサン酸セチル、乳酸イソステアリル、乳酸オクチルドデシル、乳酸オレイル、乳酸ステアリル、リンゴ酸ジイソステアリル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、ロジン酸ペンタエリトリットエステル、ジオクタン酸ネオペンチルグリコール、ジオクタン酸ネオペンチルグリコール、コレステロール脂肪酸エステル、フィトステロール脂肪酸エステル等のエステル類、ステアリン酸、ラウリン酸、ミリスチン酸、ベヘニン酸、イソステアリン酸、オレイン酸等の脂肪酸類、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、ジメチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、オクタメチルシクロテトラシロキサン、トリメチルシロキシケイ酸、高重合度メチルフェニルポリシロキサン、架橋型メチルポリシロキサン、ポリオキシ変性オルガノポリシロキサン、架橋型ポリエーテル変性メチルポリシロキサン、メタクリル変性ポリシロキサン、ステアリル変性メチルポリシロキサン、オレイル変性メチルポリシロキサン、ベヘニル変性メチルポリシロキサン、ポリビニルピロリドン変性メチルポリシロキサン、高重合度ジメチルポリシロキサン、ポリオキシアルキレン・アルキルメチルポリシロキサン・メチルポリシロキサン共重合体、アルコキシ変性ポリシロキサン、架橋型オルガノポリシロキサン、フッ素変性ポリシロキサン等のシリコーン類、パーフルオロデカン、パーフルオロオクタン、パーフルオロポリエーテル等のフッ素系油剤類、ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール等のラノリン誘導体等が挙げられ、これらを一種又は二種以上を用いることができる。 Oily components other than solidifying agents include hydrocarbons, fats and oils, hardened oils, regardless of the properties of solid oils, semi-solid oils, liquid oils, volatile oils, etc. originating from animal oils, vegetable oils, synthetic oils, etc. Examples thereof include ester oils, fatty acids, higher alcohols, silicone oils, fluorooils, and lanolin derivatives. Specifically, hydrocarbons such as liquid paraffin, squalane, polyisobutylene, and polybutene, fats and oils such as olive oil, castor oil, mink oil, and macadamian nut oil, jojoba oil, cetyl 2-ethylhexaneate, and isostearyl lactate. , Octyldodecyl lactic acid, oleyl lactate, stearyl lactic acid, diisostearyl malate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, pentaerythrite rosinate, neopentyl glycol dioctanoate, neopentyl glycol dioctanoate, cholesterol Esters such as fatty acid esters and phytosterol fatty acid esters, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid and oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol and behenyl alcohol. Higher alcohols such as, dimethylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, trimethylsiloxysilicate, highly polymerizable methylphenylpolysiloxane, crosslinked methylpolysiloxane, polyoxy-modified organopoly Siloxane, crosslinked polyether-modified methylpolysiloxane, methacryl-modified polysiloxane, stearyl-modified methylpolysiloxane, oleyl-modified methylpolysiloxane, behenyl-modified methylpolysiloxane, polyvinylpyrrolidone-modified methylpolysiloxane, high-polymerization degree dimethylpolysiloxane, polyoxy Silicones such as alkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymers, alkoxy-modified polysiloxanes, crosslinked organopolysiloxanes, fluorine-modified polysiloxanes, and fluorine-based products such as perfluorodecane, perfluorooctane, and perfluoropolyether. Examples thereof include oils, lanolin, lanolin acetate, lanolin derivatives such as lanolin fatty acid isopropyl and lanolin alcohol, and one or more of these can be used.
着色剤以外の粉体としては、化粧料に一般に使用される粉体であれば、球状、板状、針状等の形状、煙霧状、微粒子、顔料級等の粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、有機粉体類、複合粉体類等が挙げられる。具体的には、ポリアミド系樹脂、ポリエチレン系樹脂、ポリアクリル系樹脂、ポリエステル系樹脂、フッ素系樹脂、セルロース系樹脂、ポリスチレン系樹脂、スチレン−アクリル共重合樹脂等の合成樹脂、ポリプロピレン系樹脂、ウレタン樹脂等の有機高分子樹脂粉体、ステアリン酸亜鉛、Ｎ−アシルリジン等の有機低分子性粉体、シルク粉末、セルロース粉末等の天然有機粉体等が挙げられ、これら粉体はその一種又は二種以上を用いることができ、必要に応じて、フッ素系化合物、シリコーン系化合物、金属石鹸、レシチン、水素添加レシチン、コラーゲン、炭化水素、高級脂肪酸、高級アルコール、エステル、ワックス、ロウ、界面活性剤等を用いて、公知の方法により表面処理を施したり、さらに複合化したものを用いても良い。 As the powder other than the colorant, if it is a powder generally used for cosmetics, it has a spherical shape, a plate shape, a needle shape, etc. It is not particularly limited depending on the particle structure such as quality, and examples thereof include organic powders and composite powders. Specifically, synthetic resins such as polyamide resins, polyethylene resins, polyacrylic resins, polyester resins, fluorine resins, cellulose resins, polystyrene resins, and styrene-acrylic copolymer resins, polypropylene resins, and urethanes. Examples thereof include organic high molecular weight resin powders such as resins, organic low molecular weight powders such as zinc stearate and N-acyllysine, natural organic powders such as silk powder and cellulose powder, and these powders are one or two of them. More than seeds can be used, and if necessary, fluorine-based compounds, silicone-based compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants. The surface treatment may be performed by a known method, or a composite material may be used.
界面活性剤としては、化粧料に一般に用いられている界面活性剤であれば、特に限定されず、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等を用いることができる。例えば、グリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ポリオキシエチレン硬化ヒマシ油、ポリオキシアルキレンアルキル共変性オルガノポリシロキサン、ポリエーテル変性オルガノポリシロキサン、レシチン等が挙げられる。 The surfactant is not particularly limited as long as it is a surfactant generally used in cosmetics, such as a nonionic surfactant, an anionic surfactant, a cationic surfactant, and an amphoteric surfactant. Can be used. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, Examples thereof include polyether-modified organopolysiloxane and lecithin.
水性成分としては、水に可溶な成分であれば何れでもよく、水の他に、例えば、エチルアルコール等のアルコール類、プロピレングリコール、１，３−ブチレングリコール、１，２−ペンタジオール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、アロエベラ、ウイッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の植物抽出液が挙げられる。 The aqueous component may be any component that is soluble in water, and in addition to water, for example, alcohols such as ethyl alcohol, propylene glycol, 1,3-butylene glycol, 1,2-pentadiol, and di. Examples thereof include glycols such as propylene glycol and polyethylene glycol, glycerols such as glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose.
紫外線吸収剤としては、例えばベンゾフェノン系、ＰＡＢＡ系、ケイ皮酸系、サリチル酸系等の紫外線吸収剤や、４−ｔｅｒｔ−ブチル−４'−メトキシジベンゾイルメタン、オキシベンゾン等が挙げられ、保湿剤としては、例えばタンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等が挙げられ、酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等が挙げられ、美容成分としては、例えばビタミン類、消炎剤、生薬等が挙げられ、防腐剤としてはパラオキシ安息香酸エステル、フェノキシエタノール等が挙げられる。 Examples of the ultraviolet absorber include benzophenone-based, PABA-based, silicic acid-based, salicylic acid-based ultraviolet absorbers, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone and the like, and examples thereof include moisturizing agents. Examples include proteins, mucopolysaccharides, collagen, elastin, keratin, etc. Antioxidants include, for example, α-tocopherol, ascorbic acid, etc., and beauty ingredients include, for example, vitamins, anti-inflammatory agents, crude drugs, etc. Examples of the preservative include paraoxybenzoic acid ester and phenoxyethanol.
本発明における溶解温度は、示差走査型熱量計（セイコーインスツルメンツ（株）社製ＤＳＣ６２００）を用い、測定温度１０〜１５０℃、昇温速度５℃／ｍｉｎで測定して得られる融解吸熱カーブの最も高温側に観測されるピークのピークトップを溶解温度とする。 The melting temperature in the present invention is the most of the melting endothermic curve obtained by measuring with a differential scanning calorimeter (DSC6200 manufactured by Seiko Instruments Co., Ltd.) at a measurement temperature of 10 to 150 ° C. and a heating rate of 5 ° C./min. The peak top of the peak observed on the high temperature side is defined as the melting temperature.
内層部の溶解温度が外層部の溶解温度より１０℃以上低いと、外層部の後に内層部を充填する際に外層部が溶け出さないため、境界面が明瞭になる点で望ましい。 When the melting temperature of the inner layer portion is lower than the melting temperature of the outer layer portion by 10 ° C. or more, the outer layer portion does not melt when the inner layer portion is filled after the outer layer portion, so that the boundary surface becomes clear, which is desirable.
本発明のスティック状油性固形化粧料としては、特に限定されないが、口紅、リップクリーム、頬紅、アイカラー、コンシーラー、ファンデーション、美白スティック等とすることができ、より好ましい用途はメーキャップ化粧料である。 The stick-shaped oily solid cosmetic of the present invention is not particularly limited, but may be lipstick, lip balm, blusher, eye color, concealer, foundation, whitening stick, etc., and a more preferable use is a make-up cosmetic.
本発明のスティック状油性固形化粧料の製造方法は、特に限定されるものではないが、例えば次のようにして得ることができる。
油性固形組成物（外層部）は、成分（Ａ）、成分（Ｂ）および成分（Ｃ）を１３０℃以上に加温し溶解させ、必要に応じて有機色素や顔料、パール光沢剤、防腐剤、紫外線吸収剤、香料等を添加して得る。油性固形組成物（内層部）は有機色素や顔料、固形化剤、及び必要に応じて油剤、パール光沢剤、防腐剤、紫外線吸収剤、香料を加熱、混練して得る。スティック型に内層部用の型（以下、内層型と称す）を固定し、１３０℃で加熱溶解した外層部をスティック型に充填する。室温（０〜３０℃）まで冷却した後、内層型を外し、空隙部分に冷却した外層部の上方より、９０℃で加熱溶解した内層部を充填し、内層部を室温まで冷却する。
The method for producing a stick-shaped oily solid cosmetic of the present invention is not particularly limited, but can be obtained, for example, as follows.
In the oily solid composition (outer layer portion), the component (A), the component (B) and the component (C) are heated to 130 ° C. or higher to dissolve them, and if necessary, an organic pigment, a pigment, a pearl brightener, or a preservative. , UV absorber, fragrance, etc. are added. The oily solid composition (inner layer portion) is obtained by heating and kneading an organic pigment, a pigment, a solidifying agent, and, if necessary, an oil agent, a pearl brightener, a preservative, an ultraviolet absorber, and a fragrance. A mold for the inner layer portion (hereinafter referred to as an inner layer type) is fixed to the stick mold, and the outer layer portion heated and melted at 130 ° C. is filled in the stick mold. After cooling to room temperature (0 to 30 ° C.), the inner layer type is removed, and the void portion is filled with the inner layer portion heated and melted at 90 ° C. from above the cooled outer layer portion, and the inner layer portion is cooled to room temperature.
本発明のスティック状油性固形化粧料は、好ましくは直径が９〜３０ｍｍであり、より好ましくは１１〜２０ｍｍであると、使用性が良く好ましい。また、内層部は、好ましくは直径が４〜２０ｍｍであり、より好ましくは５〜１０ｍｍであると、審美性に優れ好ましい。本発明のスティック状油性固形化粧料は、その大きさや形状にもよって異なるが、内層部の断面積が、スティック状油性固形化粧料の断面面積中の１０〜５０％が好ましく、さらには２０〜４０％であると、審美性および使用性において好ましい。 The stick-shaped oily solid cosmetic of the present invention preferably has a diameter of 9 to 30 mm, more preferably 11 to 20 mm, and has good usability. The inner layer portion preferably has a diameter of 4 to 20 mm, more preferably 5 to 10 mm, because of its excellent aesthetics. The stick-shaped oil-based solid cosmetic of the present invention varies depending on its size and shape, but the cross-sectional area of the inner layer portion is preferably 10 to 50% of the cross-sectional area of the stick-shaped oil-based solid cosmetic, and more preferably 20 to 50%. 40% is preferable in terms of aesthetics and usability.
以下に実施例１〜４、参考例５、実施例６、参考例７、比較例１のスティック状口紅をあげて本発明を詳細に説明する。尚、これらは本発明を何ら限定するものではない。
Hereinafter, the present invention will be described in detail with reference to the stick-shaped lipsticks of Examples 1 to 4, Reference Example 5, Example 6, Reference Example 7, and Comparative Example 1. It should be noted that these do not limit the present invention in any way.
［油性固形組成物の製造］
表１に示した成分、含有量の処方の油性固形組成物（外層部）と、表２に示した成分、含有量の処方の油性固形組成物（内層部）を以下の方法で製造した。
[Manufacturing of oily solid composition]
The oily solid composition (outer layer portion) of the composition and content of the composition shown in Table 1 and the oily solid composition (inner layer portion) of the formulation of the component and content shown in Table 2 were produced by the following methods.
得られた油性固形組成物（外層部）１は透明であり、溶解温度は１２５℃であった。 The obtained oily solid composition (outer layer portion) 1 was transparent, and the dissolution temperature was 125 ° C.
得られた油性固形組成物（内層部）１は赤色で不透明であり、溶解温度は８０℃であった。 The obtained oily solid composition (inner layer portion) 1 was red and opaque, and the dissolution temperature was 80 ° C.
（製造方法）
油性固形組成物（外層部）
Ａ．成分（１）〜（７）を、１３５℃にて均一に溶解する。
Ｂ．Ａに（８）を加え、均一に混合した。
油性固形組成物（内層部）
Ａ．成分（１）〜（７）を、９０℃にて均一に溶解する。
Ｂ．Ａに（８）を加え、均一に混合した。
(Production method)
Oily solid composition (outer layer part)
A. Ingredients (1) to (7) are uniformly dissolved at 135 ° C.
B. (8) was added to A and mixed uniformly.
Oily solid composition (inner layer)
A. Ingredients (1) to (7) are uniformly dissolved at 90 ° C.
B. (8) was added to A and mixed uniformly.
＊１：アミノ酸系油ゲル化剤ＧＰ−１（味の素社製）
＊２：リソノール２４ＳＰ（高級アルコール工業社製）
＊３：ＩＳ−１００９Ｐ（阪本薬品工業社製）
＊４：ＡＥＲＯＳＩＬ Ｒ９７６Ｓ（日本アエロジル社製）
＊５：ＥＰＳワックス（日本ナチュラルプロダクツ社製）
＊６：ＣＩＲＥＢＥＬＬＥ １０９Ｌ（ＣＩＲＥＢＥＬＬＥ社製）
＊７：ＰＬＡＮＤＯＯＬ−Ｓ（日本精化社製）
* 1: Amino acid-based oil gelling agent GP-1 (manufactured by Ajinomoto Co., Inc.)
* 2: Lisonol 24SP (manufactured by Higher Alcohol Industry Co., Ltd.)
* 3: IS-1009P (manufactured by Sakamoto Pharmaceutical Co., Ltd.)
* 4: AEROSIL R976S (manufactured by Aerosil Japan)
* 5: EPS wax (manufactured by Japan Natural Products Co., Ltd.)
* 6: CIREBELLE 109L (manufactured by CIREBELLE)
* 7: PLANDOOL-S (manufactured by Nippon Fine Chemical Co., Ltd.)
［スティック状油性固形化粧料の製造］
表１と表２の組成物を組み合わせて、以下の方法で表３に示す実施例１〜４、参考例５、実施例６、参考例７、比較例１を得た。直径１．２ｃｍ×高さ４ｃｍの空隙がある棒状の型に底面積０．６ｃｍ2×高さ４ｃｍの内層型を固定し、油性固形組成物（外層部）を１３０℃以上の温度で溶解して空隙部分に型の高さまで充填する。油性固形組成物（外層部）が固化した後、内層型を外し、９０℃以上の温度で溶解した油性固形組成物（内層部）を充填し、室温まで冷却して固化する。型から容器に装填して、透明な外層部と着色した内層部を有するスティック状油性固形化粧料を得た。
[Manufacturing of stick-shaped oily solid cosmetics]
The compositions of Table 1 and Table 2 were combined to obtain Examples 1 to 4, Reference Example 5, Example 6, Reference Example 7, and Comparative Example 1 shown in Table 3 by the following method. An inner layer mold with a base area of 0.6 cm 2 x height 4 cm is fixed to a rod-shaped mold with a gap of 1.2 cm in diameter x 4 cm in height, and the oily solid composition (outer layer portion) is melted at a temperature of 130 ° C. or higher. Fill the voids to the height of the mold. After the oil-based solid composition (outer layer portion) is solidified, the inner layer type is removed, the oil-based solid composition (inner layer portion) dissolved at a temperature of 90 ° C. or higher is filled, and the mixture is cooled to room temperature and solidified. The mold was loaded into a container to obtain a stick-shaped oily solid cosmetic having a transparent outer layer portion and a colored inner layer portion.
実施例１〜４、参考例５、実施例６、参考例７、比較例１のスティック状口紅について、下記評価方法により評価し、その評価結果を表３に示した。
The stick-shaped lipsticks of Examples 1 to 4, Reference Example 5, Example 6, Reference Example 7, and Comparative Example 1 were evaluated by the following evaluation methods, and the evaluation results are shown in Table 3.
（評価方法）
イ．滑らかな使用感
専門パネル１０名による使用テストを行った。パネル各人が下記絶対評価基準にて７段階に評価し評点をつけ、各試料についてパネル全員の評点合計からその平均値を算出し、下記階判定基準により判定した。
(Evaluation method)
I. Smooth usability A usage test was conducted by 10 specialized panels. Each panel member evaluated and scored on a 7-point scale according to the following absolute evaluation criteria, and for each sample, the average value was calculated from the total score of all the panels and judged according to the following floor criteria.
（評価項目）
実施例１〜４、参考例５、実施例６、参考例７、比較例１に関して、使用時に内層部と外層部が均一に付着し、均等に使用できるかどうかを評価した。
(Evaluation item)
With respect to Examples 1 to 4, Reference Example 5, Example 6, Reference Example 7, and Comparative Example 1, it was evaluated whether or not the inner layer portion and the outer layer portion adhered uniformly during use and could be used evenly.
絶対評価基準
（評点）：（評価）
６ ：非常に良い
５ ：良い
４ ：やや良い
３ ：普通
２ ：やや悪い
１ ：悪い
０ ：非常に悪い
判定基準
（判定）：（評点の平均点）
◎ ：５点を超える ：非常に良好
○ ：３．５点を超え５点以下 ：良好
△ ：１点を超え３．５点以下 ：やや不良
× ：１点以下 ：不良
Absolute evaluation criteria (score): (evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad Judgment criteria (judgment): (Average score)
◎: More than 5 points: Very good ○: More than 3.5 points and 5 points or less: Good △: More than 1 point and 3.5 points or less: Slightly defective ×: 1 point or less: Defective
ロ．境界面の明瞭さ
（評価項目）
実施例１〜４、参考例５、実施例６、参考例７、比較例１に関して、外層部と内層部に明瞭な境界があるかどうかを目視で評価した。
B. Boundary surface clarity (evaluation item)
With respect to Examples 1 to 4, Reference Example 5, Example 6, Reference Example 7, and Comparative Example 1, it was visually evaluated whether or not there was a clear boundary between the outer layer portion and the inner layer portion.
判定基準
（判定）：（評価）
◎ ：境界面が明瞭である
○ ：境界面がやや明瞭である
△ ：境界面がやや不明瞭である
× ：境界面が不明瞭である
Judgment criteria (judgment): (evaluation)
◎: The boundary surface is clear ○: The boundary surface is slightly clear △: The boundary surface is slightly unclear ×: The boundary surface is unclear
表３の結果より明らかなように、実施例の口紅は、滑らかな使用感と、内層部と外層部の境界面が明瞭であり、審美性に優れる口紅であった。一方、成分（Ｂ）を含有しない比較例１は、脆く崩れやすく滑らかな使用感について満足のいくものが得られなかった。また、比較例１に用いた油性固形組成物(外層部)８は溶解温度が１６０℃であり、製造時の操作性において好ましくない結果となった。 As is clear from the results in Table 3, the lipstick of the example was a lipstick having a smooth feeling of use, a clear boundary surface between the inner layer portion and the outer layer portion, and excellent aesthetics. On the other hand, Comparative Example 1 containing no component (B) was not satisfactory in terms of brittleness, fragility, and smooth usability. Further, the oily solid composition (outer layer portion) 8 used in Comparative Example 1 had a melting temperature of 160 ° C., which was an unfavorable result in terms of operability during production.
参考例８：スティックチーク
油性固形組成物（外層部）
成 分 （％）
（１）ジブチルラウロイルグルタミド １５
（２）リンゴ酸ジイソステアリル※８ ５０
（３）トリイソステアリン酸ジグリセリル 残量
（４）デシルテトラデカノール ２０
（５）フェノキシエタノール ０．２
油性固形組成物（内層部）
成 分 （％）
（１）ポリエチレン※９ １０
（２）リンゴ酸ジイソステアリル※８ ５０
（３）トリイソステアリン酸ジグリセリル 残量
（４）ポリブテン※１０ ２０
（５）フェノキシエタノール ０．１
（６）赤色２０１ ０．１
（７）酸化チタン ０．１
（８）ラズベリーエキス ０．１
（９）香料 ０．２
※８：コスモール２２２（日清オイリオ社製）
※９：ＰＥＲＦＯＲＭＡＬＥＮＥ５００（ニューフェーズテクノロジー社製）
※１０：日石ポリブテン１９００Ｆ（ＪＸ日鉱日石エネルギー社製）
Reference Example 8: Stick cheek oily solid composition (outer layer part)
Fraction (%)
(1) Dibutyl Lauroyl Glutamide 15
(2) Diisostearyl malate * 8 50
(3) Diglyceryl triisostearate Remaining amount (4) Decyltetradecanol 20
(5) Phenoxyethanol 0.2
Oily solid composition (inner layer)
Fraction (%)
(1) Polyethylene * 9 10
(2) Diisostearyl malate * 8 50
(3) Diglyceryl triisostearate Remaining amount (4) Polybutene * 10 20
(5) Phenoxyethanol 0.1
(6) Red 201 0.1
(7) Titanium oxide 0.1
(8) Raspberry extract 0.1
(9) Fragrance 0.2
* 8: Cosmall 222 (manufactured by Nisshin Oillio)
* 9: PERFORMALENE500 (manufactured by New Phase Technology)
* 10: Nippon Oil Polybutene 1900F (manufactured by JX Nippon Oil Energy Co., Ltd.)
（製造方法）
油性固形組成物（外層部）
Ａ．成分（１）〜（５）を、１３０℃にて均一に溶解する。
油性固形組成物（内層部）
Ａ．成分（１）〜（４）を、９０℃にて均一に溶解する。
Ｂ．Ａに（５）〜（９）を加え、均一に混合する。
直径１．２ｃｍ×高さ４ｃｍの空隙がある棒状の型に底面積０．６ｃｍ２×高さ４ｃｍの内層型を固定し、油性固形組成物（外層部）を１３０℃以上の温度で溶解して空隙部分に型の高さまで充填する。油性固形組成物（外層部）が固化した後、内層型を外し、９０℃以上の温度で溶解した油性固形組成物（内層部）を充填し、室温まで冷却して固化する。型から容器に装填して、透明な外層部と着色した内層部を有するスティックチークを得た。
(Production method)
Oily solid composition (outer layer part)
A. Ingredients (1) to (5) are uniformly dissolved at 130 ° C.
Oily solid composition (inner layer)
A. Ingredients (1) to (4) are uniformly dissolved at 90 ° C.
B. Add (5) to (9) to A and mix uniformly.
An inner layer mold with a base area of 0.6 cm 2 x height 4 cm is fixed to a rod-shaped mold having a gap of 1.2 cm in diameter x 4 cm in height, and the oily solid composition (outer layer portion) is melted at a temperature of 130 ° C. or higher. Fill the voids to the height of the mold. After the oil-based solid composition (outer layer portion) is solidified, the inner layer type is removed, the oil-based solid composition (inner layer portion) dissolved at a temperature of 90 ° C. or higher is filled, and the mixture is cooled to room temperature and solidified. The mold was loaded into a container to give a stick cheek with a transparent outer layer and a colored inner layer.
得られたスティックチークは、外層部が透明であり、内層部が赤色の不透明なものであった。また、内層部と外層部の境界面が明瞭であり、滑らかな使用感と審美性に優れたものであった。 The obtained stick cheek had a transparent outer layer and a red opaque inner layer. In addition, the boundary surface between the inner layer portion and the outer layer portion was clear, and the smooth usability and aesthetics were excellent.
参考例９：リップクリーム
油性固形組成物（外層部）
成 分 （％）
（１）ジブチルラウロイルグルタミド １０
（２）リンゴ酸ジイソステアリル※８ ４０
（３）トリイソステアリン酸ジグリセリル 残量
（４）デシルテトラデカノール ２０
（５）オクチル酸ポリグリセリル−１０ ２０
（６）メチルフェニルポリシロキサン ５
油性固形組成物（内層部）
成 分 （％）
（１）マイクロクリスタリンワックス※１１ １５
（２）ワセリン ３０
（３）トリイソステアリン酸ジグリセリル 残量
（４）パラメトキシケイヒ酸エチルヘキシル ２０
（５）ポリエチレン※９ ５
（６）赤色２０２ ０．２
（７）黄色４ ０．１
（８）酢酸ＤＬ−α−トコフェロール ０．５
（９）香料 ０．１
※１１：ＬＵＶＡＸ２１９１（日本精蝋社製）
Reference Example 9: Lip balm oily solid composition (outer layer part)
Fraction (%)
(1) Dibutyl Lauroyl Glutamide 10
(2) Diisostearyl malate * 8 40
(3) Diglyceryl triisostearate Remaining amount (4) Decyltetradecanol 20
(5) Polyglyceryl octylate-10 20
(6) Methylphenylpolysiloxane 5
Oily solid composition (inner layer)
Fraction (%)
(1) Microcrystalline wax * 11 15
(2) Vaseline 30
(3) Diglyceryl triisostearate Remaining amount (4) Ethylhexyl paramethoxycinnamon 20
(5) Polyethylene * 9 5
(6) Red 202 0.2
(7) Yellow 4 0.1
(8) DL-α-tocopherol acetate 0.5
(9) Fragrance 0.1
* 11: LUVAX2191 (manufactured by Nippon Seiro Co., Ltd.)
（製造方法）
油性固形組成物（外層部）
Ａ．成分（１）〜（６）を、１３０℃にて均一に溶解する。
油性固形組成物（内層部）
Ａ．成分（１）〜（５）を、９０℃にて均一に溶解する。
Ｂ．Ａに（６）〜（９）を加え、均一に混合する。
直径１．２ｃｍ×高さ４ｃｍの空隙がある棒状の型に底面積０．６ｃｍ２×高さ４ｃｍの内層型を固定し、油性固形組成物（外層部）を１３０℃以上の温度で溶解して空隙部分に型の高さまで充填する。油性固形組成物（外層部）が固化した後、内層型を外し、９０℃以上の温度で溶解した油性固形組成物（内層部）を充填し、室温まで冷却して固化する。型から容器に装填して、透明な外層部と着色した内層部を有するリップクリームを得た。
(Production method)
Oily solid composition (outer layer part)
A. Ingredients (1) to (6) are uniformly dissolved at 130 ° C.
Oily solid composition (inner layer)
A. Ingredients (1) to (5) are uniformly dissolved at 90 ° C.
B. Add (6) to (9) to A and mix uniformly.
An inner layer mold with a base area of 0.6 cm 2 x height 4 cm is fixed to a rod-shaped mold having a gap of 1.2 cm in diameter x 4 cm in height, and the oily solid composition (outer layer portion) is melted at a temperature of 130 ° C. or higher. Fill the voids to the height of the mold. After the oil-based solid composition (outer layer portion) is solidified, the inner layer type is removed, the oil-based solid composition (inner layer portion) dissolved at a temperature of 90 ° C. or higher is filled, and the mixture is cooled to room temperature and solidified. The mold was loaded into a container to give a lip balm with a clear outer layer and a colored inner layer.
得られたリップクリームは、外層部が透明であり、内層部が赤色の不透明なものであった。また、内層部と外層部の境界面が明瞭であり、滑らかな使用感と審美性に優れたものであった。 The obtained lip balm had a transparent outer layer and a red opaque inner layer. In addition, the boundary surface between the inner layer portion and the outer layer portion was clear, and the smooth usability and aesthetics were excellent.
実施例１０：スティックコンシーラー
油性固形組成物（外層部）
成 分 （％）
（１）ジブチルラウロイルグルタミド ２０
（２）イソステアリン酸ポリグリセリル−１０ ３０
（３）トリイソステアリン酸ジグリセリル 残量
（４）オクチルドデカノール ３０
（５）フェノキシエタノール ０．２
油性固形組成物（内層部）
成 分 （％）
（１）ポリエチレン※９ １０
（２）エチレン・プロピレンコポリマー １０
（３）トリイソステアリン酸ジグリセリル 残量
（４）ポリブテン※１０ ２０
（５）酸化鉄 ０．９
（６）ベンガラ ０．５
（７）酸化チタン（平均粒子径２５０ｎｍ） ５
（８）赤色２２６ ０．１
（９）香料 ０．１
Example 10: Stick concealer oily solid composition (outer layer portion)
Fraction (%)
(1) Dibutyl Lauroyl Glutamide 20
(2) Polyglyceryl isostearate-10 30
(3) Diglyceryl triisostearate Remaining amount (4) Octyldodecanol 30
(5) Phenoxyethanol 0.2
Oily solid composition (inner layer)
Fraction (%)
(1) Polyethylene * 9 10
(2) Ethylene-propylene copolymer 10
(3) Diglyceryl triisostearate Remaining amount (4) Polybutene * 10 20
(5) Iron oxide 0.9
(6) Bengala 0.5
(7) Titanium oxide (average particle size 250 nm) 5
(8) Red 226 0.1
(9) Fragrance 0.1
（製造方法）
油性固形組成物（外層部）
Ａ．成分（１）〜（５）を、１３０℃にて均一に溶解する。
油性固形組成物（内層部）
Ａ．成分（１）〜（４）を、９０℃にて均一に溶解する。
Ｂ．Ａに（５）〜（９）を加え、均一に混合した。
直径１．２ｃｍ×高さ４ｃｍの空隙がある棒状の型に底面積０．６ｃｍ２×高さ４ｃｍの内層型を固定し、油性固形組成物（外層部）を１３０℃以上の温度で溶解して空隙部分に型の高さまで充填する。油性固形組成物（外層部）が固化した後、内層型を外し、９０℃以上の温度で溶解した油性固形組成物（内層部）を充填し、室温まで冷却して固化する。型から容器に装填して、透明な外層部と着色した内層部を有するスティックコンシーラーを得た。
(Production method)
Oily solid composition (outer layer part)
A. Ingredients (1) to (5) are uniformly dissolved at 130 ° C.
Oily solid composition (inner layer)
A. Ingredients (1) to (4) are uniformly dissolved at 90 ° C.
B. (5) to (9) were added to A and mixed uniformly.
An inner layer mold with a base area of 0.6 cm 2 x height 4 cm is fixed to a rod-shaped mold having a gap of 1.2 cm in diameter x 4 cm in height, and the oily solid composition (outer layer portion) is melted at a temperature of 130 ° C. or higher. Fill the voids to the height of the mold. After the oil-based solid composition (outer layer portion) is solidified, the inner layer type is removed, the oil-based solid composition (inner layer portion) dissolved at a temperature of 90 ° C. or higher is filled, and the mixture is cooled to room temperature and solidified. The mold was loaded into a container to give a stick concealer with a transparent outer layer and a colored inner layer.
得られたスティックコンシーラーは、外層部が透明であり、内層部が肌色の不透明なものであった。また、内層部と外層部の境界面が明瞭であり、滑らかな使用感と審美性に優れたものであった。 The obtained stick concealer had a transparent outer layer and an opaque skin color on the inner layer. In addition, the boundary surface between the inner layer portion and the outer layer portion was clear, and the smooth usability and aesthetics were excellent.
実施例１１：スティックアイカラー
油性固形組成物（外層部）
成 分 （％）
（１）ジブチルラウロイルグルタミド ５
（２）ノナイソステアリン酸ポリグリセリル−１０ ２０
（３）トリイソステアリン酸ジグリセリル 残量
（４）デシルテトラデカノール １０
（５）ミネラルオイル ５０
（６）ポリエチレンテレフタレート
・ポリメチルメタクリレート積層フィルム末 ３
油性固形組成物（内層部）
成 分 （％）
（１）ポリエチレン※９ １０
（２）リンゴ酸ジイソステアリル※８ １０
（３）トリエチルヘキサノイン※１２ 残量
（４）ホウケイ酸（Ｃａ／Ａｌ） １０
（５）ポリメチルシルセスキオキサン※１３ １０
（６）赤色２０２ ３
（７）酸化チタン １
（８）酸化チタン・酸化鉄被覆マイカ ３０
（９）ジメチルポリシロキサン（２０ＣＳ） ４
※１２：ＭＹＲＩＴＯＬ ＧＴＥＨ（ＢＡＳＦ社製）
※１３：トスパール２０００Ｂ（モメンティブ・パフォーマンス・マテリアルズ・ジャパン社製）
Example 11: Stick eye color oily solid composition (outer layer portion)
Fraction (%)
(1) Dibutyl Lauroyl Glutamide 5
(2) Polyglyceryl nonaisostearate-10 20
(3) Diglyceryl triisostearate Remaining amount (4) Decyltetradecanol 10
(5) Mineral oil 50
(6) Polyethylene terephthalate-Polymethylmethacrylate laminated film powder 3
Oily solid composition (inner layer)
Fraction (%)
(1) Polyethylene * 9 10
(2) Diisostearyl malate * 8 10
(3) Triethylhexanoin * 12 Remaining amount (4) Borosilicate (Ca / Al) 10
(5) Polymethylsilsesquioxane * 13 10
(6) Red 202 3
(7) Titanium oxide 1
(8) Titanium oxide / iron oxide coated mica 30
(9) Dimethylpolysiloxane (20CS) 4
* 12: MYRITOR GTEH (manufactured by BASF)
* 13: Tospearl 2000B (manufactured by Momentive Performance Materials Japan)
（製造方法）
油性固形組成物（外層部）
Ａ．成分（１）〜（５）を、１３０℃にて均一に溶解する。
Ｂ．Ａに（６）を加え、均一に混合した。
油性固形組成物（内層部）
Ａ．成分（１）〜（３）を、９０℃にて均一に溶解する。
Ｂ．Ａに（４）〜（９）を加え、均一に混合する。
直径１．２ｃｍ×高さ４ｃｍの空隙がある棒状の型に底面積０．６ｃｍ２×高さ４ｃｍの内層型を固定し、油性固形組成物（外層部）を１３０℃以上の温度で溶解して空隙部分に型の高さまで充填する。油性固形組成物（外層部）が固化した後、内層型を外し、９０℃以上の温度で溶解した油性固形組成物（内層部）を充填し、室温まで冷却して固化する。型から容器に装填して、透明な外層部と着色した内層部を有するスティックアイカラーを得た。
(Production method)
Oily solid composition (outer layer part)
A. Ingredients (1) to (5) are uniformly dissolved at 130 ° C.
B. (6) was added to A and mixed uniformly.
Oily solid composition (inner layer)
A. Ingredients (1) to (3) are uniformly dissolved at 90 ° C.
B. Add (4) to (9) to A and mix uniformly.
An inner layer mold with a base area of 0.6 cm 2 x height 4 cm is fixed to a rod-shaped mold having a gap of 1.2 cm in diameter x 4 cm in height, and the oily solid composition (outer layer portion) is melted at a temperature of 130 ° C. or higher. Fill the voids to the height of the mold. After the oil-based solid composition (outer layer portion) is solidified, the inner layer type is removed, the oil-based solid composition (inner layer portion) dissolved at a temperature of 90 ° C. or higher is filled, and the mixture is cooled to room temperature and solidified. The mold was loaded into a container to give a stick eye color with a transparent outer layer and a colored inner layer.
得られたスティックアイカラーは、外層部が透明であり、内層部が赤色の不透明なものであった。また、内層部と外層部の境界面が明瞭であり、滑らかな使用感と審美性に優れたものであった。
The obtained stick eye color was opaque with a transparent outer layer and a red inner layer. In addition, the boundary surface between the inner layer portion and the outer layer portion was clear, and the smooth usability and aesthetics were excellent.
Claims (3)
前記成分（Ａ）の前記外層部における含有量が、１〜３０質量％であり、
前記成分（Ｂ）の前記外層部における含有量が、５〜５０質量％であり、
前記成分（Ｃ）の前記外層部における含有量が、５〜４０質量％である、
スティック状油性固形化粧料。 It has a transparent outer layer part in contact with each other and a colored inner layer part, and at least dibutylethylhexanoylglutamide, dibutyllauroylglutamide, (bisdialkyl (C14-18) amide (ethylenediamine / hydrogenated dimer dilinoleic acid)) in the outer layer part. One or more components (A) amino acid-based gelling agent selected from copolymers, component (B) branched higher alcohol having 20 to 26 carbon atoms , polyglyceryl -10 decaisostearate, polyglyceryl decaethylhexanoate One or more components selected from -10, polyglyceryl diisostearate-10, polyglyceryl distearate-10, polyglyceryl nonaisostearate-10, and polyglyceryl-6 polylysinoleate. (C) The degree of polymerization of glycerin is 6-12. The fatty acid contains polyglycerin fatty acid ester, which is a branched fatty acid having 8 to 22 carbon atoms.
The content of the component (A) in the outer layer portion is 1 to 30% by mass.
The content of the component (B) in the outer layer portion is 5 to 50% by mass.
The content of the component (C) in the outer layer portion is 5 to 40% by mass.
Stick-like oily solid cosmetics.
The stick-shaped oily solid cosmetic according to claim 1 or 2 , wherein the melting temperature of the inner layer portion is lower than the melting temperature of the outer layer portion by 10 ° C. or more.
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| US11583479B2 (en) | 2018-06-29 | 2023-02-21 | The Procter & Gamble Company | Dual phase products |
| EP3813584A2 (en) * | 2018-06-29 | 2021-05-05 | The Procter & Gamble Company | Dual phase products |
| EP3813768A2 (en) * | 2018-06-29 | 2021-05-05 | The Procter & Gamble Company | Dual phase products |
| CN112384307B (en) | 2018-06-29 | 2023-06-16 | 宝洁公司 | Dual phase product dispenser |
| JPWO2022079886A1 (en) * | 2020-10-16 | 2022-04-21 | ||
| KR102601269B1 (en) * | 2020-12-23 | 2023-11-14 | 주식회사 코스메카코리아 | solid cosmetic composition with improved high-temperature stability and feeling of use and manufacturing method of the same |
| JP2023023936A (en) | 2021-08-06 | 2023-02-16 | 株式会社トキワ | Double-structure bar-shaped cosmetic and method for producing the same |
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| JPS50143641A (en) * | 1974-05-09 | 1975-11-19 | ||
| LU85083A1 (en) * | 1983-11-09 | 1985-07-17 | Oreal | COSMETIC OR PHARMACEUTICAL COMPOSITION IN THE FORM OF A STICK OR STICK CONSISTING OF TWO CONCENTRIC FAT PHASES, ITS PREPARATION METHOD AND CASE FOR ALLOWING ITS STORAGE AND DISTRIBUTION |
| JPH02172904A (en) * | 1988-12-26 | 1990-07-04 | Kobayashi Kose Co Ltd | Production of double stick cosmetic |
| JP2011213677A (en) * | 2010-03-31 | 2011-10-27 | Naris Cosmetics Co Ltd | Oily solid cosmetic |
| WO2012138326A1 (en) * | 2011-04-05 | 2012-10-11 | Avon Products, Inc. | Clear or translucent composition |
| JP2015124181A (en) * | 2013-12-26 | 2015-07-06 | 株式会社コーセー | Oily solid cosmetics |
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