CN102786343A - Novel titanium-containing trace element water-soluble fertilizer - Google Patents
Novel titanium-containing trace element water-soluble fertilizer Download PDFInfo
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- CN102786343A CN102786343A CN2012102600716A CN201210260071A CN102786343A CN 102786343 A CN102786343 A CN 102786343A CN 2012102600716 A CN2012102600716 A CN 2012102600716A CN 201210260071 A CN201210260071 A CN 201210260071A CN 102786343 A CN102786343 A CN 102786343A
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Abstract
The invention relates to a novel titanium-containing trace element water-soluble fertilizer and a production method thereof, belonging to the field of trace element water-soluble fertilizers. The novel fertilizer is used to meet demands for trace elements by crops, improve stress resistance of the crops and achieve the purposes of promoting crop growth, increasing output and improving quality. According to the invention, the titanium-containing trace element water-soluble fertilizer is prepared from an EDTA aqueous solution used as a matrix, the chelated titanium element, a variety of chelated trace elements and a small amount of aids through heating with a hot-cold mixing cylinder.
Description
Technical field
The invention belongs to technical field of fertilizers, be specifically related to a kind of novel titaniferous trace element water-soluble fertilizer.
Technical background
China is a large agricultural country, and chemical fertilizer is the material guarantee of agricultural sustainable development, is the basis of increases in grain production.Facts have proved of world agriculture development is used chemical fertilizer and is the soonest, the most effective, most important well stimulation.But use the waste that chemical fertilizer not only causes a large amount of economy and resource for many years unreasonably, even more serious is causes a large amount of good farmland soda acids, chap, groundwater azotate a series of environmental problems such as exceed standard.In addition, nitrate salt exceeds standard in the vegetables, the nitrous oxide emission amount increases in the atmosphere, the environmental problems such as generation of coastal cities red tide phenomenon also use relevant with fertilizer unreasonable.
Because China belongs to the natural disaster country that takes place frequently, and receives the natural disaster weather effect, farm crop also receive the infringement of arid, flood, severe cold, high temperature and nutritional deficiency disease, disease and pest simultaneously.Various little fertilizer of emerging of agricultural materials market in recent years; At present existing its fundamental component of trace element water-soluble property fertilizer all is with the combination of elements such as iron, zinc, manganese, boron, molybdenum, silicon by different ratios, different shape (liquefaction or solid); Though use traditional trace element water-soluble property fertilizer also can reach the purpose of increasing both production and income; But heavy metals exceeding standard; The uncontrolled use of hormones product not only causes the increase of production cost, also causes serious consequences such as quality of agricultural product is inferior, outlet is obstructed.Trace element fertilizer inferior can not fully be absorbed by crop owing to it; Fail to solve the plant physiology nutritional deficiency symptom after using; Cause the peasant to take for originally not lack and abandon causing crop alimentary extremely uneven, serious physiological disease occurs the replenishing of trace element; And cause various bacterium fungal diseases frequently to take place by physiological disease, suffer heavy losses.
The present invention is exactly to above problem and designing, and this product is to solving plant physiology nutritional deficiency disease, improve utilization rate of fertilizer, practicing thrift the mineral substance manure resources, and saline and alkaline, the acidifying of avoiding that soil causes because of excessively applying fertilizer etc. have a significant effect, and are of far-reaching significance.To improving crops quality, exploitation green non-pollution agricultural-food etc. play the effect of the property changed.
Summary of the invention
The present invention relates to a kind of novel titaniferous trace element fertilizer and preparation method thereof; Belong to trace element water-soluble property fertilizer field; In order to satisfy the demand of crop to trace element, increase crop anti-adversity, reach the purpose that promotes plant growth, increase output, improves quality.
The present invention is a matrix with the edta solution, contains various trace elements and little auxiliary, and heating through Cooling or heating jar is made.A kind of titaniferous trace element water-soluble fertilizer provided by the invention; To the scarce limit of prior art, utilize YD 30 (EDTA) as complexing agent, when guaranteeing conventional trace element water-soluble fertilizer effect; With the abundant chelating of titanium elements and trace element; Both improved the trace elements absorbed utilization ratio, and utilized titanium elements again in the intravital mechanism of action of crop, provide a kind of effective, price is low, the nontoxic novel micro unit fertilizer that has no side effect.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is:
With the edta solution is matrix, it is characterized in that, said edta solution concentration is 57.5～75.5%, and contains chelating titanium elements and multiple chelated microelement.
Said chelating titanium elements titanium content is >=10-30ppm.Obtain to add titanium tetrachloride and edta solution.
Said multiple chelated microelement is respectively zinc, boron, iron, manganese.
Said chelated microelement content is >=100g/ml.Obtain to add YD 30 zinc sodium salt, iron edta sodium salt, YD 30 manganese sodium salt, four water, eight Sodium Tetraboratees.
Its characteristic may further comprise the steps:
1) get titanium tetrachloride 15-30 weight part, slowly join the cold and hot a mixing bowl of the edta solution of 70-85 weight part, mix and stir, making its titanium content is 10-30ppm;
2) continue to add YD 30 zinc sodium salt 15-30 weight part, iron edta sodium salt 20-35 weight part, YD 30 manganese sodium salt 10-30 weight part, EDTA magnesium complex disodium salt 10-30 weight part, edta solution 20-45 weight part mixing stirring; Heat to 65-150 degree centigrade; Cooling also kept 65-90 degree centigrade of temperature 1-4 hour; Add little auxiliary and continue to mix, get YD 30 titanium-containing chelate liquid microelement.
The time of said stirring was not less than 20 minutes.
Said auxiliary agent is a washing composition.
A kind of novel titaniferous trace element water-soluble fertilizer provided by the invention and preparation method thereof; Compared with prior art; Its technological core is to utilize YD 30 (EDTA) as complexing agent; When guaranteeing conventional trace element water-soluble fertilizer effect,, both improved the trace elements absorbed utilization ratio with the abundant chelating of titanium elements and trace element; Utilize titanium elements in the intravital mechanism of action of crop again, provide a kind of effective, price is low, the nontoxic novel micro unit fertilizer that has no side effect.
Embodiment
Below in conjunction with specific embodiment the present invention is further specified.
The invention describes a kind of novel titaniferous trace element water-soluble fertilizer; Be that YD 30 (hereinafter to be referred as the EDTA) aqueous solution with 57.5～75.5% is matrix; And to contain chelating titanium elements and the chelated microelement content that titanium content is 10-30ppm be the multiple chelated microelement of 100g/ml; Wherein, Titanium content is from add titanium tetrachloride and EDTA solution, to extract and obtain, and chelated microelement content is to obtain from adding EDTA zinc sodium salt, EDTA ferrisodium salt, EDTA manganese sodium salt, four water, eight Sodium Tetraboratees.Said multiple chelated microelement is meant zinc, side, iron, manganese, concrete zinc >=60g/L, iron >=20g/L, manganese >=20g/L, boron >=2g/L.
Its making method of the above a kind of novel titaniferous trace element water-soluble fertilizer may further comprise the steps:
1) get titanium tetrachloride 15-30 weight part, slowly join the cold and hot a mixing bowl of the EDTA solution of 70-85 weight part, mix churning time and be not less than 20 minutes, making its titanium content is 10-30ppm;
2) continue to add EDTA zinc sodium salt 15-30 weight part, EDTA ferrisodium salt 20-35 weight part, EDTA manganese sodium salt 10-30 weight part, four water, eight Sodium Tetraborate 10-30 weight parts, EDTA solution 20-45 weight part mixing stirring; And churning time was not less than 20 minutes; And heat to 65-150 degree centigrade; Cooling also kept 65-90 degree centigrade of temperature 1-4 hour, add a spot of detergent builder and continue the time of mixing and be not less than 20 minutes, EDTA titanium-containing chelate liquid microelement.
The supplementary notes of the titanium elements mechanism of action and effect in farm crop
The various countries scientist proves through the lot of test result, after plant is used titanium fertilizer, not only shows better growing way, has improved output, and the growth of plant is also shown many good comprehensive effects.
Its mechanism of action is:
1, improves the activity of nitrogenase, px, nitrate reductase, 2-6 Phosphoric acid esterase in the plant materials, thereby reach the effect that the activation function improves disease resistance.
2, improve chlorophyll, content of carotenoid about 20% in plant leaf surface unit's fresh weight; Make chlorophyll carry out photosynthetic speed and effect raising 10-20%; The ability that makes plant materials support part through photosynthesis self manufacturing is improved, thereby reaches the effect of raising the output.
3, have the potential priming effect, help the activation of cell nuclear dna, can transfer endogenous hormones and carry, thereby promote differentiation and induce to be infected organization healing and reach the effect of removing poisoning to organic centre,
Its effect is:
1. improved the interior quality of crop and fruit greatly.Can improve on the present agricultural because the situation that the undue dependence quality that chemical fertilizer caused descends significantly after using titanium fertilizer.According to surveying and determination: use the fertile food crop of titanium, protein contnt improves 3-5%: lysine content improves 3-10%: the ascorbic content of fruits improves 3-17%: the content of water-soluble sugar improves 4-15%; Humatite matter is greatly improved.
2. the resistance of crop is strengthened.Improve greatly like drought resisting, waterlogging-resistant, cold-resistant, high temperature resistance, disease-resistant ability.We also find: plant, can suitably be eased through using titanium fertilizer because excessive or improper use receives the poisoning of agricultural chemicals, makes it to recover quickly growing way.
3. can improve the absorption rate of plant to fertilizer in the soil.According to China's comprehensive scientific and technological level determination of agricultural at present, the utilization ratio of China's agricultural crops fertilising is merely about 30%, and the flourishing country of agricultural, the effective rate of utilization of fertilising reaches as high as more than 60%.Behind the fertilising titanium fertilizer, crop can be improved 20%-30% to fertilizer utilization ratio in the soil on former basis.
Below be the fat data of testing of the online publicity of the Chinese Academy of Agricultural Sciences simple substance titanium throughout the country:
1. Xinjiang farming 22 agricultural stations of two teachers (Wang Mingwei, Liu Chunxin etc.): in nineteen ninety wheat is tested, on average increased production about 20%, beet is made an experiment, on average increase production 10%, sugar degree improves 8.1-31.33%
2. Changping County, Beijing clay fertilizer station: in nineteen ninety big green pepper is made an experiment, on average increase production 15.85%
3. Shenyang Inst. of Applied Ecology, Chinese Academy of Sciences: in 1991 soybean is made an experiment, on average increase production 40.7%
4. Chinese Academy of Sciences plant institute (Tang Xike) made an experiment to cucumber in 1991, on average increased production more than 30%
5. agriculture chemical examination institution, Beijing (senior agronomist Chen Bo) made an experiment to cucumber in 1994, on average increased production 21.96%
6. Wuxi City Vegetable Research Institute: in nineteen ninety the Lay green pepper is made an experiment, on average increase production 22.8%
7. Beijing City Agriculture and Forestry Institute clay fertilizer institute: in nineteen ninety wheat, Radix Dauci Sativae Chinese cabbage are made an experiment, on average increase production 21.57%
8. Inner Mongol soil and fertilizer workstation: in 1991 wheat is made an experiment, on average increase production 12.85%
9. upright stone tablet agrotechnical station in the Xian Si of Yanshi, Henan Province: in 1991 corn is made an experiment, on average increase production 25%
10. Wujiang, Jiangsu Xian Songling town agrotechnical station: rape is made an experiment, on average increase production 23.9%
11. Wu County, Suzhou City research of agricultural science institute: tealeaves is tested, on average increased production 27.5%
12. plant protection system of Guangxi Agriculture Univ. (Lu Shennian professor): shatian pomelo, longan, mulberry tree, summer squash, banana are made an experiment, on average increase production 10-25%
13. Wanxian tobacco association: tobacco leaf is made an experiment, on average increase production 24.96-31.29%
14. clay fertilizer station, Anqiu, Shandong county: to cucumber test, raising the output 22.7%
15. academy of agricultural sciences, Beijing: to Chinese cabbage test, raising the output 34.5%
16. agricultural school, Lanzhou, Gansu: to the spinach test, raising the output 22-70%
17. academy of agricultural sciences, Beijing: to cauliflower test, raising the output 30.6%
18. Chengguan District agrotechnical station, Fengjie County, Sichuan: to broccoli test, raising the output 35.22%
19. clay fertilizer station, Anqiu, Shandong county: to celery test, raising the output 22%
20. agrotechnical center, Yutian County, Hebei: to celery test, raising the output 20.8%
21. clay fertilizer station, Changping County, Beijing is to capsicum test, raising the output 26.8%
22. the Chaoyang District Beijing institute of agricultural sciences: to eggplant test, raising the output 43.9%
23. the fertile station of Anqiu, Shandong loam: to tomato test, raising the output 19.6%
24. Jiangxi Pingxiang City Xiangdong District agriculture and animal husbandry bureau: to tomato test, raising the output 14.59%
25. the agricultural development of Taihe County, Jiangxi is done: to Radix Dauci Sativae test, raising the output 15.4%
26. Danxian County, Guizhou bureau of agriculture: to pea-pods test, raising the output 30.6%
27. Shanghai City aggie: to cowpea test, raising the output 28.1%
28. clay fertilizer station, Anqiu, Shandong county: to kidney bean test, raising the output 15.2%
29. academy of agricultural sciences, Hunan Province: to autumn fresh kidney beans test, raising the output 13.8%
30. Shanghai City aggie; To the test of Pueraria lobota lettuce, raising the output 30.65%
31. clay fertilizer station, Shangzhi City, Heilungkiang: to rice test, raising the output 16.7%
32. saltings, Liaoning Province utilizes institute: to rice test, raising the output 13.8%
33. Heilungkiang plant protection institute: to corn test, raising the output 26%
34. four) Fengjie County, river Jia Gao district agricultural station: to Ipomoea batatas test, raising the output 17.5%
35. ecological center, Liaoning Chinese Academy of Sciences Shenyang: to soy bean test, raising the output 14.8%
36. clay fertilizer station, Inner Mongolia Autonomous Region: to peanut test, raising the output 21.3%
37. the agricultural development of Yongxiu County, Jiangxi is done: to peanut test, raising the output 21.4%
38. clay fertilizer station, Inner Mongolia Autonomous Region: to beet test, raising the output 23.5%
39. Heilungkiang plant protection institute: to beet test, raising the output 18.6%
40. clay fertilizer station, Taihe County, Jiangxi: to sugarcane test, raising the output 10.88%
41. Quzhou County, Hebei bureau of agriculture: to cotton test, raising the output 26-39.3%
42. the agricultural development of Shanggao County, Jiangxi is done: to cotton test, raising the output 26.3-37.8%
43. broad-mouthed receptacle for holding liquid Tianjin, Henan county State Scientific and Technological Commission: to watermelon test, raising the output 13%
44. clay fertilizer station, Inner Mongolia Autonomous Region: to hami melon test, raising the output 30.3%
45. clay fertilizer station, Wanxian Prefecture, Sichuan: to tealeaves test, raising the output 32.2%
46. the agricultural development of Yongxiu County, Jiangxi is done: to peach test, raising the output 20%
47. the agricultural development of Fengcheng county is done: to citrus test, raising the output 22.4%
48. Chengdu, Sichuan second institute of agricultural sciences: to navel orange test, raising the output 26%
49. plant protection system of Guangxi agricultural university: to longan test, raising the output 13.1%
50. plant protection system of Guangxi agricultural university: to banana test, raising the output 27.6%.
Claims (9)
1. a novel titaniferous trace element water-soluble fertilizer is a matrix with the edta solution, it is characterized in that, said edta solution concentration is 57.5～75.5%, and contains chelating titanium elements and multiple chelated microelement.
2. a kind of novel titaniferous trace element water-soluble fertilizer according to claim 1 is characterized in that said chelating titanium elements titanium content is >=10-30ppm.
3. the described a kind of novel titaniferous trace element water-soluble fertilizer of root pick claim 1 is characterized in that said chelated microelement content is >=100g/L.
4. the described a kind of novel titaniferous trace element water-soluble fertilizer of root pick claim 1 is characterized in that said multiple chelated microelement is respectively zinc, iron, manganese, boron.
5. the described a kind of novel titaniferous trace element water-soluble fertilizer of root pick claim 2 is characterized in that, said titanium content obtains for adding titanium tetrachloride and edta solution.
6. root is dug the described a kind of novel titaniferous trace element water-soluble fertilizer of claim 4; It is characterized in that said chelated microelement content obtains for adding YD 30 zinc sodium salt, iron edta sodium salt, YD 30 manganese sodium salt, four water, eight Sodium Tetraboratees.
7. the making method of a novel titaniferous trace element water-soluble fertilizer: it is characterized in that, may further comprise the steps:
1) get titanium tetrachloride 15-30 weight part, slowly join the cold and hot a mixing bowl of the edta solution of 70-85 weight part, mix and stir, making its titanium content is 10-30ppm;
2) continue to add YD 30 zinc sodium salt 15-30 weight part, iron edta sodium salt 20-35 weight part, YD 30 manganese sodium salt 10-30 weight part, four water, eight Sodium Tetraborate 10-30 weight parts, edta solution 20-45 weight part mixing stirring; Heat to 65-150 degree centigrade; Cooling also kept 65-90 degree centigrade of temperature 1-4 hour; Add little auxiliary and continue to mix, get YD 30 titanium-containing chelate liquid microelement.
8. the making method of a kind of novel titaniferous trace element water-soluble fertilizer according to claim 7 is characterized in that, the time of said stirring was not less than 20 minutes.
9. the making method of a kind of novel titaniferous trace element water-soluble fertilizer according to claim 7 is characterized in that, said auxiliary agent is a washing composition.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104230452A (en) * | 2013-06-07 | 2014-12-24 | 钛谷（天津）科技有限公司 | Hydrolysis-resistant stable ionic titanium ASIT |
| CN104341234A (en) * | 2013-08-01 | 2015-02-11 | 刘舰艇 | Multi-element compound titanium micro fertilizer |
| CN104529627A (en) * | 2014-12-15 | 2015-04-22 | 陕西大润地农业科技有限公司 | Concentrate capable of promoting growth of green plants |
| CN105254436A (en) * | 2015-11-13 | 2016-01-20 | 钛谷（天津）科技有限公司 | Light energy variable valency ion titanium complex liquid and preparation method thereof |
| CN106673868A (en) * | 2017-02-28 | 2017-05-17 | 洛阳启禾生态农业科技有限责任公司 | Titanium containing water-soluble fertilizer |
| CN114557241A (en) * | 2022-03-02 | 2022-05-31 | 安徽农业大学 | Method for improving ratio of female flowers of crisp melon |
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| CN1257054A (en) * | 1999-12-28 | 2000-06-21 | 张玉梅 | Titanium-containing chelate plant nutrient liquid |
| EP1411036A1 (en) * | 2002-10-17 | 2004-04-21 | Iniciativas Agroindustriales de Teruel, S.L. | Method of obtaining nitrogenated granular fertilizers with a high microelement content and fertilizers obtained thereby |
| CN101429068A (en) * | 2008-12-11 | 2009-05-13 | 东北大学 | Method for producing kalium-nitrogen-sulphur-magnesium-ferrotitanium silicon foliage fertilizer and calcium-sulphur silicon fertilizer with titanium-containing furnace cinder |
| CN102173935A (en) * | 2011-01-25 | 2011-09-07 | 陕西汉唐环保农业有限公司 | Efficient and special organic potassium fertilizer and production method thereof |
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2012
- 2012-07-26 CN CN201210260071.6A patent/CN102786343B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1257054A (en) * | 1999-12-28 | 2000-06-21 | 张玉梅 | Titanium-containing chelate plant nutrient liquid |
| EP1411036A1 (en) * | 2002-10-17 | 2004-04-21 | Iniciativas Agroindustriales de Teruel, S.L. | Method of obtaining nitrogenated granular fertilizers with a high microelement content and fertilizers obtained thereby |
| CN101429068A (en) * | 2008-12-11 | 2009-05-13 | 东北大学 | Method for producing kalium-nitrogen-sulphur-magnesium-ferrotitanium silicon foliage fertilizer and calcium-sulphur silicon fertilizer with titanium-containing furnace cinder |
| CN102173935A (en) * | 2011-01-25 | 2011-09-07 | 陕西汉唐环保农业有限公司 | Efficient and special organic potassium fertilizer and production method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104230452A (en) * | 2013-06-07 | 2014-12-24 | 钛谷（天津）科技有限公司 | Hydrolysis-resistant stable ionic titanium ASIT |
| CN104341234A (en) * | 2013-08-01 | 2015-02-11 | 刘舰艇 | Multi-element compound titanium micro fertilizer |
| CN104529627A (en) * | 2014-12-15 | 2015-04-22 | 陕西大润地农业科技有限公司 | Concentrate capable of promoting growth of green plants |
| CN105254436A (en) * | 2015-11-13 | 2016-01-20 | 钛谷（天津）科技有限公司 | Light energy variable valency ion titanium complex liquid and preparation method thereof |
| CN106673868A (en) * | 2017-02-28 | 2017-05-17 | 洛阳启禾生态农业科技有限责任公司 | Titanium containing water-soluble fertilizer |
| CN114557241A (en) * | 2022-03-02 | 2022-05-31 | 安徽农业大学 | Method for improving ratio of female flowers of crisp melon |
| CN114557241B (en) * | 2022-03-02 | 2023-08-11 | 安徽农业大学 | Method for improving female flower proportion of crisp melon |
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