CN102746768A - Water-borne colorful glass paint and preparation method and application thereof - Google Patents
Water-borne colorful glass paint and preparation method and application thereof Download PDFInfo
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Abstract
The invention discloses a water-borne colorful glass paint and a preparation method and an application thereof. The water-borne colorful glass paint includes two components. A component A is prepared by 30% to 50% of acrylic acid modified epoxy resin, 28.95% to 37% of volatile matter mixed solvent, 12% to 15% of amino resin, 0.3% to 0.6% of wetting dispersant reagent, 5% to 25.9% of pigments, 0% to 0.6% of dust preventive, 0.05% to 0.2% of antifoaming agents, 0.2% to 0.6% of surface additive and 0.1% to 0.5% of thickening agent. A component B is prepared by 90% to 98% of silane coupling agent and 2% to 10% of volatile matter mixed solvent, and belongs to energy saving and environment friendly water-borne glass paint. The preparation method is simple in process. The water-borne colorful glass paint is coated on the surface of glass by utilizing a conventional spray coating method, the thickness of non bubble explosion with one-time construction is large, a layer of paint film of 15 microns to 35 microns thick can be formed after the paint is baked, the curing temperature is low, the curing time is short, the baking range is wide, and the paint film has good adhesion force with glass substrate, high glossiness, good fullness, and excellent media of water, alcohol and the like proof performances.
Description
Technical field
The present invention relates to the glass paint technical field, relate in particular to a kind of hydrate colour glass paint.
Background technology
Along with the continuous progress of scientific and technological level and the continuous enhancing of people's environmental consciousness; It is more and more stricter that people are related to self healthy material requirements to food product pack etc.; Increasing organic solvent and chemical materials are banned use of by the food product pack industry; Solvent based coating withdraws from the food product pack industry gradually, and promoting aqueous, environmental protective coating becomes a kind of inevitable trend.In addition, strengthen management, effectively improve IAQ, become the common recognition of countries in the world building, finishing material.Yet; Present most of producer still continues to use the solvent-borne type glass paint to apply ambetti, building glass; This kind solvent type coating itself is poisonous, and can give out a large amount of objectionable impuritiess (like benzene, ketone, ether, lead, mercury etc.) injury HUMAN HEALTH in process of production and cause environmental pollution.Along with the domestic and international market is more and more stricter to the environmental requirement of artwork, solvent based coating must be replaced by water-borne coatings.
The aqueous glass coating that uses is at present compared with similar solvent-borne type glass paint, and gloss is lower, fullness ratio is relatively poor, thickly is coated with explosive bubble.
Chinese patent CN 102101960 A disclose a kind of high hydroxyl acrylate containing silicone aqueous glass coating emulsion and compound method thereof on June 22nd, 2011.This coating adopts the preparatory emulsification method of monomer to combine semi-continuous seed emulsion polymerization technology; In the acrylic ester emulsion polymerization process, introduce double bond containing carboxylic monomer and double bond containing organosilicon function monomer; Make high hydroxyl acrylate containing silicone emulsion, particle diameter is that 100～180nm, solid content are 40～48%.Be applied to glass surface behind the emulsion adding solidifying agent and under 120 ℃ of conditions, toast the 2h film-forming.
Chinese patent CN 101445330A discloses the transparent antiultraviolet glass paint that the invention discloses a kind of highly transparent and good adhesion and hardness on June 3rd, 2009.This coating is that water nano zinc oxide slurry or oiliness nano zinc oxide slurry, urethane resin and the coatings additive(s) of the platy shaped particle of 5nm formed by particle diameter≤8nm, median size.Visible light is high to transsmissivity of this invention coating, and this invention can effectively prevent intensive ultraviolet to human body, to the radiation of article, aging and problem such as fade.
Chinese patent CN 102311688 A disclose a kind of water transparent heat insulation paint and preparation method thereof on January 11st, 2012.This invention relates to a kind of water transparent heat insulation paint.The excellent benefit of the heat-proof quality of this product, low price can make microwave attenuation again.Can be used in the fields such as glass of building coating.
Above patent CN 102101960 A, CN 101445330A, CN 102311688 A relate to aqueous glass coating, but not low to gloss of film in the formulating of recipe, poor, thick problems such as quick-fried bubble that are coated with of paint film fullness ratio are done special improvement.
Summary of the invention
The objective of the invention is to overcome the deficiency that prior art exists, provide a kind of strong adhesion, dielectric behaviors such as gloss is high, fullness ratio is good, water-fast, alcohol excellent, have the hydrate colour glass paint of the higher not quick-fried bubble thickness of once construction with glass baseplate.
Another object of the present invention provides the preparation method of hydrate colour glass paint.
Of the present invention also have a purpose to provide the application of hydrate colour glass paint on the surface of glass.
For realizing above-mentioned purpose, the technical scheme that the present invention takes is:
(1) hydrate colour glass paint
A kind of hydrate colour glass paint is made up of A component and B component, and the mass ratio of said A component and B component is: 4:1～7:1;
Said A component forms by the feedstock production of following mass percent: acrylic modified epoxy resin 30～50%, fugitive constituent mixed solvent 28.95～37%, aminoresin 12～15%, wetting dispersing agent 0.3～0.6%, pigment 5～25.9%, dust-proofing agent 0～0.6%, skimmer 0.05～0.2%, surperficial auxiliary agent 0.2～0.6%, thickening material 0.1～0.5%;
Said B component forms by the feedstock production of following mass percent: silane coupling agent 90～98%, fugitive constituent mixed solvent 2～10%.
Fugitive constituent mixed solvent of the present invention forms by the feedstock production of following mass percent: ethylene glycol monobutyl ether 10～20%, butanols 15～25%, ethanol 15～25%, deionized water 30～40%.
Dust-proofing agent of the present invention is a nano fumed silica.
Surperficial auxiliary agent of the present invention is polyether-modified ZGK 5 flow agent.
Silane coupling agent of the present invention is the silane coupling agent that contains reactive methoxy group.
(2) preparation method of hydrate colour glass paint
The preparation method of hydrate colour glass paint of the present invention may further comprise the steps:
1. by said formula ratio preparation fugitive constituent mixed solvent;
2. the preparation of A component: acrylic modified epoxy resin is added in the high speed dispersion still, stir the adding wetting dispersing agent; Add pigment and anti-settling agent, stir; Add said fugitive constituent mixed solvent again, stir; Be ground to fineness≤15 μ m, add aminoresin, skimmer, surperficial auxiliary agent and thickening material, obtain the A component;
3. the preparation of B component: in silane coupling agent, add said fugitive constituent mixed solvent, stir, obtain the B component.
(3) hydrate colour glass paint of the present invention is used for the surface of glass
The A component and the B component of the color aqueous glass paint of the present invention are mixed by said mass ratio, and dilute with water adjustment viscosity to 40～70s adopts conventional spraying method to be coated on glass surface; Under 160～180 ℃ of conditions, toasted 15～25 minutes, glass surface forms the paint film that a layer thickness is 15～35 μ m.
The performance of this paint film is following:
Sticking power according to the regulation of GB/T1720-1988, uses cross-hatching to test, and assay is all more than 1 grade.
Coating color and outward appearance detect according to the regulation of GB/T9761-2008, the requirement of conformance with standard model, and fullness ratio is good.
The method that adopts GB/T 9754-2007 to provide is measured, and when this hydrate colour glass paint used as finish paint, 60o angle gloss reached more than 95%, and gloss is high.
Hardness detects according to the regulation of GB/T6739-2006, and seamless by the standardized measured length of standard method of test with the 3H pencil, the hardness of detected result is more than or equal to 3H, and performance reaches the detection index request.
Alcohol resistance: according to the regulation of GB/T23989-2009, use instrument wipe method B method, wiping 900 times, paint film is not show-through.
Water tolerance: the regulation according to GB/T1733-1993 detects, water-fast 1h, paint film no change.
Beneficial effect of the present invention:
1, hydrate colour glass paint provided by the invention, dielectric behaviors such as with the strong adhesion of glass baseplate, gloss is high, fullness ratio is good, water-fast, alcohol are excellent.Owing to acrylic acid epoxy modified resin, aminoresin, contain the structure that cross-linked network takes place between the silane coupling agent three of reactive methoxy group to have formed after the crosslinking reaction, improved the sticking power of this coating and glass baseplate.
2, hydrate colour glass paint preparation method provided by the invention, technology is simple.
3, hydrate colour glass paint provided by the invention adopts conventional spraying method to be coated on glass surface, and once the not quick-fried bubble thickness of construction is big, measures according to the method that GB/T13452.2-2008 provides, and thickness can reach 35 μ m.Solidification value is lower, and is promptly curable at 160 ℃.Set time is shorter, in the time of 180 ℃, only needs 15min with regard to curable film-forming.The baking wide ranges in 160 ℃ to 180 ℃ TR, can be toasted, and is curable at 160 ℃, 25min paint film, 180 ℃, the 25min paint film can overbaking.Formed paint film property is excellent, belongs to energy-saving environment-friendly aqueous glass paint, is fit to large-scale commercial prodn.
Embodiment
Embodiment 1:
The hydrate colour glass paint of present embodiment; The A component is: acrylic modified epoxy resin 35.75kg; Wetting dispersing agent 0.4kg, sharp titanium titanium white powder pigment 9.8kg, charcoal blacks 2.8kg, nano fumed silica dust-proofing agent 0.25kg; Fugitive constituent mixed solvent 37kg, aminoresin 13.18kg, polyether-modified ZGK 5 flow agent 0.4kg, skimmer 0.12kg, thickening material 0.3kg.The B component is: contain the silane coupling agent 96kg of reactive methoxy group, fugitive constituent mixed solvent 4kg.
The preparation method of present embodiment hydrate colour glass paint may further comprise the steps:
1. prepare the fugitive constituent mixed solvent: with ethylene glycol monobutyl ether 15kg, butanols 20kg, ethanol 20kg, deionized water 35kg, mixing stirs, and is subsequent use.
2. the preparation of A component: the M-55D acrylic modified epoxy resin 35.75kg that takes by weighing the production of Shenzhen Wei Nuohua chemical materials ltd adds in the high speed dispersion axe; Under agitation add wetting dispersing agent 0.4kg, after stirring, add sharp titanium titanium white powder pigment 9.8kg, charcoal blacks 2.8kg; Nano fumed silica dust-proofing agent 0.25kg; Stir, add the fugitive constituent mixed solvent 37kg of preformulation, stir.
Putting into conventional vertical lapping machine grinds; Test according to the testing method of GB/T1724 with Hegman grind gage; When fineness≤15 μ m; Add aminoresin 13.18kg, polyether-modified ZGK 5 flow agent 0.4kg, skimmer 0.12kg, thickening material 0.3kg, stir, obtain the A component.
3. the preparation of B component: take by weighing the silane coupling agent 96kg that contains reactive methoxy group, add the fugitive constituent mixed solvent 4kg of preformulation, stir, obtain the B component.
With the hydrate colour glass paint of the present invention preparation, according to the A component: the proportioning of B component=5:1 is joined lacquer, and dilute with water adjustment viscosity is to 40s, uses as the finish paint of bottle lacquer.The viscosity of finish paint is used when being coated with-4 glasss, 25 ℃ and is detected according to the method for GB/T1723-1993 regulation.
Adopt the method for spraying that this hydrate colour glass paint is coated in the bottle surface, baking is 15 minutes under 160 ℃ of conditions, and forming a layer thickness on the bottle surface is the paint film of 15 μ m.Formed paint film adhesion is strong, and dielectric behaviors such as gloss is high, fullness ratio is good, water-fast, alcohol are excellent.
Sticking power according to the regulation of GB/T1720-1988, uses cross-hatching to test, and assay is more than 1 grade.
Coating color and outward appearance detect according to the regulation of GB/T9761-2008, the requirement of conformance with standard model, and fullness ratio is good.
The method that adopts GB/T 9754-2007 to provide is measured, and when this hydrate colour glass paint used as finish paint, 60o angle gloss reached more than 95%, and gloss is high.
Hardness detects according to the regulation of GB/T6739-2006, and seamless by the standardized measured length of standard method of test with the 3H pencil, the hardness of detected result is more than or equal to 3H, and performance reaches the detection index request.
Alcohol resistance: according to the regulation of GB/T23989-2009, use instrument wipe method B method, wiping 900 times, paint film is not show-through.
Water tolerance: the regulation according to GB/T1733-1993 detects, water-fast 1h, paint film no change.
Method according to GB/T 13452.2-2008 provides is measured, and thickness can reach 15 μ m.Solidification value is lower, and is promptly curable at 160 ℃.Set time is shorter, 15min curable film-forming in the time of 160 ℃.
In like manner, hydrate colour glass paint provided by the invention also can adopt the method for spraying to be coated in the surface of other glass.
Embodiment 2
The hydrate colour glass paint of present embodiment; The A component is: acrylic modified epoxy resin 50kg; Wetting dispersing agent 0.3kg; 5R Pigment red pigment 4.6kg, lithol that maroon pigment 0.4kg, fugitive constituent mixed solvent 28.95kg, aminoresin 15kg, polyether-modified ZGK 5 flow agent 0.6kg, skimmer 0.05kg, thickening material 0.1kg.The B component is: contain the silane coupling agent 98kg of reactive methoxy group, fugitive constituent mixed solvent 2kg.
The preparation method of the hydrate colour glass paint of present embodiment may further comprise the steps:
1. prepare the fugitive constituent mixed solvent: with ethylene glycol monobutyl ether 20kg, butanols 25kg, ethanol 25kg, deionized water 30kg, mixing stirs, and is subsequent use.
2. the preparation of A component: the M-55D acrylic modified epoxy resin 50kg that takes by weighing the production of Shenzhen Wei Nuohua chemical materials ltd adds in the high speed dispersion axe; Under agitation add wetting dispersing agent 0.3kg; After stirring, add 5R Pigment red pigment 4.6kg, lithol that maroon pigment 0.4kg, stir; Add the fugitive constituent mixed solvent 28.95kg of preformulation, stir.
Put into conventional vertical lapping machine and grind, test according to the testing method of GB/T1724 with Hegman grind gage.Add aminoresin 15kg, polyether-modified ZGK 5 flow agent 0.6kg, skimmer 0.05kg, thickening material 0.1kg, stir, obtain the A component.
3. the preparation of B component: take by weighing the silane coupling agent 98kg that contains reactive methoxy group, add the fugitive constituent mixed solvent 2kg of preformulation, stir, obtain the B component.
With the hydrate colour glass paint of the present invention preparation, according to the A component: the proportioning of B component=4:1 is joined lacquer, and dilute with water adjustment viscosity is to 60s, uses as the finish paint of bottle lacquer.The viscosity of finish paint is used when being coated with-4 glasss, 25 ℃ and is detected according to the method for GB/T1723-1993 regulation.
Adopt the method for brushing that this hydrate colour glass paint is coated in the bottle surface, baking is 20 minutes under 170 ℃ of conditions, and forming a layer thickness on the bottle surface is the paint film of 35 μ m.Formed paint film adhesion is strong, and dielectric behaviors such as gloss is high, fullness ratio is good, water-fast, alcohol are excellent.
Sticking power according to the regulation of GB/T1720-1988, uses cross-hatching to test, and assay is more than 1 grade.
Coating color and outward appearance detect according to the regulation of GB/T9761-2008, the requirement of conformance with standard model, and fullness ratio is good.
The method that adopts GB/T 9754-2007 to provide is measured, and when this hydrate colour glass paint used as finish paint, 60o angle gloss reached more than 95%, and gloss is high.
Hardness detects according to the regulation of GB/T6739-2006, and seamless by the standardized measured length of standard method of test with the 3H pencil, the hardness of detected result is more than or equal to 3H, and performance reaches the detection index request.
Alcohol resistance: according to the regulation of GB/T23989-2009, use instrument wipe method B method, wiping 900 times, paint film is not show-through.
Water tolerance: the regulation according to GB/T1733-1993 detects, water-fast 1h, paint film no change.
Method according to GB/T 13452.2-2008 provides is measured, and one-pass film-forming thickness can reach 35 μ m, the not quick-fried bubble of paint film.Solidification value is lower, and is promptly curable at 170 ℃.Set time is shorter, 20min curable film-forming in the time of 170 ℃.
In like manner, hydrate colour glass paint provided by the invention also can adopt the method for brushing to be coated in the surface of other glass.
Embodiment 3
The hydrate colour glass paint of present embodiment, the A component is: acrylic modified epoxy resin 30kg, wetting dispersing agent 0.6kg; Sharp titanium titanium white powder pigment 25.9kg, nano fumed silica dust-proofing agent 0.6kg, fugitive constituent mixed solvent 30kg; Aminoresin 12kg; Polyether-modified ZGK 5 flow agent 0.2kg, skimmer 0.2kg, thickening material 0.5kg.The B component is: contain the silane coupling agent 90kg of reactive methoxy group, fugitive constituent mixed solvent 10kg.
The preparation method of the hydrate colour glass paint of present embodiment may further comprise the steps:
1. prepare the fugitive constituent mixed solvent: with ethylene glycol monobutyl ether 10kg, butanols 15kg, ethanol 15kg, deionized water 40kg, mixing stirs, and is subsequent use.
2. the preparation of A component: the M-55D acrylic modified epoxy resin 30kg that takes by weighing the production of Shenzhen Wei Nuohua chemical materials ltd adds in the high speed dispersion axe; Under agitation add wetting dispersing agent 0.6kg; After stirring, add sharp titanium titanium white powder pigment 25.9kg, nano fumed silica dust-proofing agent 0.6kg, stir; Add the fugitive constituent mixed solvent 30kg of preformulation, stir.
Put into conventional vertical lapping machine and grind, test according to the testing method of GB/T1724 with Hegman grind gage.Add aminoresin 12kg, polyether-modified ZGK 5 flow agent 0.2kg, skimmer 0.2kg, thickening material 0.5kg, stir, obtain the A component.
3. the preparation of B component: take by weighing the silane coupling agent 90kg that contains reactive methoxy group, add the fugitive constituent mixed solvent 10kg of preformulation, stir, obtain the B component.
With the hydrate colour glass paint of the present invention preparation, according to the A component: the proportioning of B component=7:1 is joined lacquer, and dilute with water adjustment viscosity is to 70s, uses as the finish paint of bottle lacquer.The viscosity of finish paint is used when being coated with-4 glasss, 25 ℃ and is detected according to the method for GB/T1723-1993 regulation.
Adopt the method for spraying that this hydrate colour glass paint is coated in the bottle surface, baking is 25 minutes under 180 ℃ of conditions, and forming a layer thickness on the bottle surface is the paint film of 25 μ m.Formed paint film adhesion is strong, and dielectric behaviors such as gloss is high, fullness ratio is good, water-fast, alcohol are excellent.
Sticking power according to the regulation of GB/T1720-1988, uses cross-hatching to test, and assay is more than 1 grade.
Coating color and outward appearance detect the requirement of conformance with standard model according to the regulation of GB/T9761-2008.
Hardness detects according to the regulation of GB/T6739-2006, and seamless by the standardized measured length of standard method of test with the 3H pencil, the hardness of detected result is more than or equal to 3H, and performance reaches the detection index request.
Alcohol resistance: according to the regulation of GB/T23989-2009, use instrument wipe method B method, wiping 900 times, paint film is not show-through.
Water tolerance: the regulation according to GB/T1733-1993 detects, water-fast 1h, paint film no change.
Method according to GB/T 13452.2-2008 provides is measured, and thickness can reach 25 μ m.25min curable film-forming in the time of 180 ℃.Can not produce overbaking.
In like manner, hydrate colour glass paint provided by the invention also can adopt the method for roller coating to be coated in the surface of other glass.
Above-described only is preferred embodiment of the present invention.Should be understood that for the person of ordinary skill of the art, under teachings provided by the present invention, can also make other equivalent modifications and improvement, also should be regarded as protection scope of the present invention.
Claims (8)
1. a hydrate colour glass paint is made up of A component and B component, and the mass ratio of said A component and B component is: 4:1～7:1;
Said A component forms by the feedstock production of following mass percent: acrylic modified epoxy resin 30～50%, fugitive constituent mixed solvent 28.95～37%, aminoresin 12～15%, wetting dispersing agent 0.3～0.6%, pigment 5～25.9%, dust-proofing agent 0～0.6%, skimmer 0.05～0.2%, surperficial auxiliary agent 0.2～0.6%, thickening material 0.1～0.5%;
Said B component forms by the feedstock production of following mass percent: silane coupling agent 90～98%, fugitive constituent mixed solvent 2～10%.
2. according to the said hydrate colour glass paint of claim 1; It is characterized in that said fugitive constituent mixed solvent forms by the feedstock production of following mass percent: ethylene glycol monobutyl ether 10～20%, butanols 15～25%, ethanol 15～25%, deionized water 30～40%.
3. according to the said hydrate colour glass paint of claim 1, it is characterized in that said dust-proofing agent is a nano fumed silica.
4. according to the said hydrate colour glass paint of claim 1, it is characterized in that said surperficial auxiliary agent is polyether-modified ZGK 5 flow agent.
5. according to the said hydrate colour glass paint of claim 1, it is characterized in that said silane coupling agent is the silane coupling agent that contains reactive methoxy group.
6. according to the preparation method of the said hydrate colour glass paint of claim 1, it is characterized in that may further comprise the steps:
1. by said formula ratio preparation fugitive constituent mixed solvent;
2. the preparation of A component: acrylic modified epoxy resin is added in the high speed dispersion still, stir the adding wetting dispersing agent; Add pigment and anti-settling agent, stir; Add said fugitive constituent mixed solvent again, stir; Be ground to fineness≤15 μ m, add aminoresin, skimmer, surperficial auxiliary agent and thickening material, obtain the A component;
3. the preparation of B component: in silane coupling agent, add said fugitive constituent mixed solvent, stir, obtain the B component.
7. the surface that is used for glass according to the said hydrate colour glass paint of claim 1.
8. be used for the surface of glass according to the said hydrate colour glass paint of claim 7, it is characterized in that: A component and B component are mixed by said mass ratio, and dilute with water adjustment viscosity to 40～70s adopts conventional spraying method to be coated on glass surface; Under 160～180 ℃ of conditions, toasted 15～25 minutes, glass surface forms the paint film that a layer thickness is 15～35 μ m.
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| CN103102764A (en) * | 2012-11-13 | 2013-05-15 | 合肥市科睦佰水性材料有限公司 | High-wear-resistant water-based glass paint and preparation method thereof |
| CN103819982A (en) * | 2013-06-27 | 2014-05-28 | 山东益利油漆有限公司 | Waterborne wine bottle coating and preparation method thereof |
| CN104293027A (en) * | 2014-09-24 | 2015-01-21 | 晟通科技集团有限公司 | Emulsion-type glass paint |
| CN104530868A (en) * | 2014-12-25 | 2015-04-22 | 广州市诚美涂饰工程有限公司 | Environment-friendly water-based glass paint and preparation method thereof |
| CN106700840A (en) * | 2015-11-13 | 2017-05-24 | 北京爱尔斯姆科技有限公司 | TH-26 galvanizing-replaced high-hardness special water-based paint |
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| CN103102763A (en) * | 2012-11-13 | 2013-05-15 | 合肥市科睦佰水性材料有限公司 | Environment-friendly water-based glass paint and preparation method thereof |
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| CN106700840A (en) * | 2015-11-13 | 2017-05-24 | 北京爱尔斯姆科技有限公司 | TH-26 galvanizing-replaced high-hardness special water-based paint |
| WO2021196736A1 (en) * | 2020-03-30 | 2021-10-07 | 苏州市贝特利高分子材料股份有限公司 | Water-based glass coating material resistant to boiling in boiling water, and preparation method therefor |
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| CN102746768B (en) | 2014-12-10 |
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